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Zinc Bromide

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Zinc Bromide Common Name: ZINC BROMIDE CAS Number: 7699-45-8 RTK Substance number: 2027 DOT Number: NA 9156 Date: October 1986 Revision: October 1998 -------------------------------------------------------------------------- -------------------------------------------------------------------------- HAZARD SUMMARY WORKPLACE EXPOSURE LIMITS * Zinc Bromide can affect you when breathed in and by No occupational exposure limits have been established for Zinc passing through your skin. Bromide. This does not mean that this substance is not * Contact can irritate and burn the eyes and skin. harmful. Safe work practices should always be followed. * Breathing Zinc Bromide can irritate the nose, throat and lungs causing coughing and/or shortness of breath. * It should be recognized that Zinc Bromide can be absorbed * Exposure to Zinc Bromide can cause headache, personality through your skin, thereby increasing your exposure. changes (such as depression), poor appetite, lethargy and confusion. WAYS OF REDUCING EXPOSURE * Skin rash can occur with repeated exposure. * Where possible, enclose operations and use local exhaust ventilation at the site of chemical release. If local exhaust IDENTIFICATION ventilation or enclosure is not used, respirators should be Zinc Bromide is an odorless white powder. It is used in worn. photography, rayon manufacturing and medicine. * Wear protective work clothing. * Wash thoroughly immediately after exposure to Zinc REASON FOR CITATION Bromide and at the end of the workshift. * Zinc Bromide is on the Hazardous Substance List because * Post hazard and warning information in the work area. In it is cited by DOT, DEP, HHAG, and EPA. addition, as part of an ongoing education and training effort, * Definitions are provided on page 5. communicate all information on the health and safety hazards of Zinc Bromide to potentially exposed workers. HOW TO DETERMINE IF YOU ARE BEING EXPOSED The New Jersey Right to Know Act requires most employers to label chemicals in the workplace and requires public employers to provide their employees with information and training concerning chemical hazards and controls. The federal OSHA Hazard Communication Standard, 1910.1200, requires private employers to provide similar training and information to their employees. * Exposure to hazardous substances should be routinely evaluated. This may include collecting personal and area air samples. You can obtain copies of sampling results from your employer. You have a legal right to this information under OSHA 1910.1020. * If you think you are experiencing any work-related health problems, see a doctor trained to recognize occupational diseases. Take this Fact Sheet with you. ZINC BROMIDE page 2 of 6 This Fact Sheet is a summary source of information of all Any evaluation should include a careful history of past and potential and most severe health hazards that may result from present symptoms with an exam. Medical tests that look for exposure. Duration of exposure, concentration of the substance damage already done are not a substitute for controlling and other factors will affect your susceptibility to any of the exposure. potential effects described below. --------------------------------------------------------------------------- Request copies of your medical testing. You have a legal right to this information under OSHA 1910.1020. HEALTH HAZARD INFORMATION WORKPLACE CONTROLS AND PRACTICES Acute Health Effects The following acute (short-term) health effects may occur Unless a less toxic chemical can be substituted for a hazardous immediately or shortly after exposure to Zinc Bromide: substance, ENGINEERING CONTROLS are the most effective way of reducing exposure. The best protection is to * Contact can irritate and burn the eyes and skin. enclose operations and/or provide local exhaust ventilation at * Breathing Zinc Bromide can irritate the nose and throat the site of chemical release. Isolating operations can also causing coughing and wheezing. reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is Chronic Health Effects sometimes necessary. The following chronic (long-term) health effects can occur at some time after exposure to Zinc Bromide and can last for In evaluating the controls present in your workplace, consider: months or years: (1) how hazardous the substance is, (2) how much of the substance is released into the workplace and (3) whether Cancer Hazard harmful skin or eye contact could occur. Special controls * According to the information presently available to the New should be in place for highly toxic chemicals or when Jersey Department of Health and Senior Services, Zinc significant skin, eye, or breathing exposures are possible. Bromide has not been tested for its ability to cause cancer in In addition, the following control is recommended: animals. Reproductive Hazard * Where possible, automatically transfer Zinc Bromide from drums or other storage containers to process containers. * According to the information presently available to the New Jersey Department of Health and Senior Services, Zinc Good WORK PRACTICES can help to reduce hazardous Bromide has not been tested for its ability to affect exposures. The following work practices are recommended: reproduction. * Workers whose clothing has been contaminated by Zinc Other Long-Term Effects Bromide should change into clean clothing promptly. * Exposure to Zinc Bromide can cause headache, personality * Contaminated work clothes should be laundered by changes (such as depression), poor appetite, lethargy and individuals who have been informed of the hazards of confusion. exposure to Zinc Bromide. * Skin rash can occur with repeated exposure. * Eye wash fountains should be provided in the immediate * Zinc Bromide can irritate the lungs. Repeated exposure work area for emergency use. may cause bronchitis to develop with cough, phlegm, and/or * If there is the possibility of skin exposure, emergency shortness of breath. shower facilities should be provided. * On skin contact with Zinc Bromide, immediately wash or MEDICAL shower to remove the chemical. At the end of the workshift, wash any areas of the body that may have contacted Zinc Medical Testing Bromide, whether or not known skin contact has occurred. If symptoms develop or overexposure is suspected, the * Do not eat, smoke, or drink where Zinc Bromide is following may be useful: handled, processed, or stored, since the chemical can be * Lung function tests. swallowed. Wash hands carefully before eating or smoking. * Use a vacuum or a wet method to reduce dust during clean- up. DO NOT DRY SWEEP. ZINC BROMIDE page 3 of 6 PERSONAL PROTECTIVE EQUIPMENT * Be sure to consider all potential exposures in your workplace. You may need a combination of filters, WORKPLACE CONTROLS ARE BETTER THAN prefilters, cartridges, or canisters to protect against different PERSONAL PROTECTIVE EQUIPMENT. However, for forms of a chemical (such as vapor and mist) or against a some jobs (such as outside work, confined space entry, jobs mixture of chemicals. done only once in a while, or jobs done while workplace * Where the potential for high exposure exists, use a controls are being installed), personal protective equipment may MSHA/NIOSH approved supplied-air respirator with a full be appropriate. facepiece operated in a pressure-demand or other positive- pressure mode. For increased protection use in combination OSHA 1910.132 requires employers to determine the with an auxiliary self-contained breathing apparatus appropriate personal protective equipment for each hazard and operated in a pressure-demand or other positive-pressure to train employees on how and when to use protective mode. equipment. QUESTIONS AND ANSWERS The following recommendations are only guidelines and may not apply to every situation. Q: If I have acute health effects, will I later get chronic health Clothing effects? * Avoid skin contact with Zinc Bromide. Wear protective A: Not always. Most chronic (long-term) effects result from gloves and clothing. Safety equipment suppliers/ repeated exposures to a chemical. manufacturers can provide recommendations on the most protective glove/clothing material for your operation. Q: Can I get long-term effects without ever having short-term * All protective clothing (suits, gloves, footwear, headgear) effects? should be clean, available each day and put on before work. A: Yes, because long-term effects can occur from repeated exposures to a chemical at levels not high enough to make Eye Protection you immediately sick. * Wear impact resistant eye protection with side shields or goggles when there is a hazard from flying particles. Q: What are my chances of getting sick when I have been * Wear a face shield along with goggles when working with exposed to chemicals? corrosive, highly irritating or toxic substances. A: The likelihood of becoming sick from chemicals is increased as the amount of exposure increases. This is Respiratory Protection determined by the length of time and the amount of IMPROPER USE OF RESPIRATORS IS DANGEROUS. material to which someone is exposed. Such equipment should only be used if the employer has a written program that takes into account workplace conditions, Q: When are higher exposures more likely? requirements for worker training, respirator fit testing and A: Conditions which increase risk of exposure include dust medical exams, as described in OSHA 1910.134. releasing operations (grinding, mixing, blasting, dumping, etc.), other physical
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