WO 2012/124795 Al 20 September 2012 (20.09.2012) P O P C T
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(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2012/124795 Al 20 September 2012 (20.09.2012) P O P C T (51) International Patent Classification: tahama 4-chome, Chuo-ku, Osaka-shi, Osaka, 5418550 A01N 51/00 (2006.01) A01P 7/02 (2006.01) (JP). A01N 53/00 (2006.01) A01P 7/04 (2006.01) (81) Designated States (unless otherwise indicated, for every A01P 7/00 (2006.01) kind of national protection available): AE, AG, AL, AM, (21) International Application Number: AO, AT, AU, AZ, BA, BB, BG, BH, BR, BW, BY, BZ, PCT/JP2012/056796 CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, (22) International Filing Date: HR, HU, ID, IL, IN, IS, KE, KG, KM, KN, KP, KR, KZ, 12 March 2012 (12.03.2012) LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, (25) Filing Language: English MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SC, SD, SE, (26) Publication Language: English SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, (30) Priority Data: TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. 201 1-058876 17 March 201 1 (17.03.201 1) JP (84) Designated States (unless otherwise indicated, for every (71) Applicant (for all designated States except US): SUM¬ kind of regional protection available): ARIPO (BW, GH, ITOMO CHEMICAL COMPANY, LIMITED [JP/JP]; GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, 27-1, Shinkawa 2-chome, Chuo-ku, Tokyo, 1048260 (JP). UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, (72) Inventor; and DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (75) Inventor/Applicant (for US only): TANAKA, Yoshito LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, [JP/JP]; c/o SUMITOMO CHEMICAL COMPANY LIM SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, ITED, 2-1, Takatsukasa 4-chome, Takarazuka-shi, Hyogo, GW, ML, MR, NE, SN, TD, TG). 6658555 (JP). Published: (74) Agents: NAKAYAMA, Tohru et al; c/o Sumitomo — with international search report (Art. 21(3)) Chemical Intellectual Property Service, Limited, 5-33, Ki- © (54) Title: PEST CONTROL COMPOSITION AND PEST CONTROL METHOD (57) Abstract: The present invention provides a pest control composition containing a combination of (E) - 1 - (2 - chloro - 1, 3 - thiazol - 5 -ylmethyl) - 3 -methyl - 2 - nitroguanidine (clothianidin) and [2, 5-dioxo-3- (2-propynyl) - 1 - imidazolidinyl] methyl 2, 2 - dimethyl - 3 - (2 -methyl - 1 -propenyl) cyclopropanecarboxylate (imiprothrin). DESCRIPTION PEST CONTROL COMPOSITION AND PEST CONTROL METHOD Technical Field The present invention relates to a pest control composition and a control method of pests. Background Art Hitherto, various compounds are known as active ingredient of harmaful arthropod control composition (See e.g., Patent Literature 1 and 2). Citation List Patent Literature Patent Literature 1 : US 5,034,404 Patent Literature 2 : US 4,176,189 Summary of the Invention Problems to be Solved by the Invention An object of the present invention is to provide a pest control composition and control method of pests having an excellent control effect on pests. Means for Solving the Problems The present inventors studied intensively to find a pest control composition having an excellent control effect on pests, and as a result, found that a composition containing a combination of (E) -1- (2-chloro-l, 3-thiazol-5- ylmethyl) -3-methyl-2-nitroguanidine (hereinafter refered to as the Guanidine Compound) and [2, 5-dioxo-3- (2-propynyl) -1- imidazolidinyljmethyl 2 ,2-dimethyl-3- (2-methyl-l- propenyl )cyclopropanecarboxylate (hereinafter refered to as the Ester Compound) has an excellent pest control effect, and led to the invention. The present invention includes: [1] A pest control composition containing a combination of the Guanidine Compound and the Ester Compound as active ingredients . [2] The pest control composition according to [1], wherein the weight ratio of the Guanidine Compound to the Ester Compound is within the range of from 50 : 1 to 1 : 50. [3] A control method of pests which comprises applying effective amount of the Guanidine Compound and the Ester Compound . [4] The control method of pest according to [3], wherein the weight ratio of the Guanidine Compound to the Ester Compound is within the range of from 50 : 1 to 1 : 50. Effect of the Invention Pest can be controlled by using the pest control composition of the present invention. Mode for Carrying Out the Invention The pest control composition of the present invention is characterized by containing the combination of the Guanidine Compound and the Ester Compound. The Guanidine Compound can be produced, for example, by process discribed in US 5,034,404. A compound selling on the market in the name of clothianidin (common name) can be used for the Guanidine Compound. The Ester Compound can be produced, for example, by process discribed in, for example, US 4,176,189 and US 4 , 827, 020. In the Ester Compound, there are isomers derived from two asymmetric carbon atoms at the 1-position and the 3- position on the cyclopropane ring. Each isomer having pest control activity or a mixture of those isomers in an arbitrary ratio which has pest control activity is included in the present invention. A compound selling on the market in the name of imiprothrin (common name) ([2, 5-dioxo-3- (2-propynyl) -1- imidazolidinyl]methyl (1R) -cis/trans-3- (2-methyl-l- propenyl )-2 ,2-dimethylcyclopropanecarboxylate) can be used for the Ester Compound. Examples of pests on which the pest control composition of the present invention has a control effect include harmful arthropod pest such as harmful insects and harmful acarines, and more specifically, the following pests: Lepidoptera insect pests: Pyralidae such as Chilo suppressalis , Cnaphalocrosis medinalis, Plodia interpunctella , and Ephestia kuehniella; Noctuidae such as Spodoptera litura, Pseudaletia separata, and Mamestra brassicae; Pieridae such as Pieris rapae crucivora; Tortricidae such as Adoxopheyes spp.; Carposinidae; Lyonetiidae; Lymantriidae; Antographa; Agrotis spp., such as Agrotis segetum and Agrotis ipsilon; Helicoverpa spp.; Heliothis spp.; Plutella xylostella; Parnara guttata; Tinea pellionella; Tineola bisselliella , etc . Diptera insect pests: Culex spp. such as Culex pipiens pallens and Culex tritaeniorhynchus ; Aedes spp. such as Aedes aegypti and Aedes albopictus; Anopheles spp. such as Anopheles sinensis ; Chironomidae; Muscidae such as Musca domestica , Muscina stabulans and Fannia canicularis; Calliphoridae; Sarcophagidae; Anthomyiidae such as Delia phatura and Delia antiqua; Tephritidae; Agromyzidae; Drosophilidae; Psychodidae; Phoridae; Simuliidae; Tabanidae; Stomoxyidae; Ceratopogpnnidae, etc. Blattaria insect pests: Blattella germanica, Periplaneta fuliginosa, Periplaneta americana, Periplaneta brunnea, Blatta orientalis , etc. Hymenoptera insect pests: Formicidae such as Camponotus japonicus , Tetramorium tsushimae, Lasius niger, Pachycondyla chinensis , Monomorium intrudens , Lasius fuji, Monomorium pharaonis , Formica fusca japonica , Ochetellus glaber, Pristomyrmex punctatus , Pheidole noda, and Linepith ema humile; Vespidae such as Polistes (Polistes chinensis , Polistes riparius , Polistes jadwigae, Polistes rothneyi , Polistes nipponensis , Polistes snelleni, and Polistes japonicus) , Vespa mandarinia, Vespa simillima xanthoptera, Vespa analis, Vespa crabro, Vespa ducalis, Vespula flaviceps lewisi, Vespula shidai, and Dolichovespula media; Bethylidae; Tenthredinidae such as Athalia rosae ruficornis, etc. Siphonaptera insect pests: Ctenocephalides canis, Ctenocephalides felis, Pulex irritans , etc. Anoplura insect pests: Pediculus humanus, Phthirus pubis, Pediculus humanus captis, Pediculus humanus corporis etc. Psocoptera insect pests: psocid Isoptera insect pests: Subterranean termites such as Reticulitermes speratus , Coptoterm.es formosanus , Reticulitermes flavipes , Reticulitermes hesperus, Reticulitermes virginicus, Reticulitermes tibialis , Heterotermes aureus; drywood termites such as Incisitermes minor; and rottenwood termites such as Zootermopsis nevadensis . Hemiptera insect pests: Delphacidae such as Laodelphax striatellus , Nilaparvara lugens and Sogatella furcifera; Deltocephalidae such as Nephotettix cincticeps and Nephotettix virescens; Aphididae; Pentatomidae such as Nezara antennata , Riptortus clavatus , Eysarcoris lewisi, Eysarcoris parvus, Plautia stali, Halyomorpha mista, Stenotus rubrovittatus , and Trigonotylus caelestialium; Aleyrodidae; Coccidae; Cimicidae such as Cinex lectularius; Tingidae; Psyllidae, etc . Coleoptera insect pests: Attagenus unicolor; Anthrenus verbasci; corn rootworms such as Diabrotica virgifera virgifera and Dabrotica undecimpunctaca howardi; scarabaeidae such as Anomala cuprea and Anomala rufocuprea; Curculionidae such as Sitophilus zeamais, Lissorhoptrus oryzophilus , Anthonomus grandis grandis and Callosobruchus cheninsis; Tenebrionidae such as Tenebrio molitor and Tribolium castaneum; Chrysomelidae such as Oulema oryzae, Phyllotreta striolata and Aulacophora femoralis; Anobiidae; Epilachna spp. such as Henosepilachna vigintioctopunctata ; Lyctidae; Bostrychidae; Ptinidae; Cerambycidae Paederus fuscipes; etc . Thysanoptera insect pests: Thrips palmi, Frankliniella occidentalis , Thrips hawaiiensis , etc. Orthoptera insect pests: Gryllotalpidae, Acrididae,