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US 2003OO77962A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2003/0077962 A1 Krzysik et al. (43) Pub. Date: Apr. 24, 2003

(54) ABSORBENT TISSUES PROVIDING SKIN Publication Classification BARRIER ENHANCEMENT (76) Inventors: Duane Gerard Krzysik, Appleton, WI (51) Int. Cl...... D04H 1700; D04H 3/00; (US); Brenda Marie Nelson, Appleton, D04H 5/00; D04H 13/00; WI (US); Beth Anne Lange, Neenah, WI (US); David Roland Otts, (52) U.S. Cl...... 442/100; 442/102; 442/97 Appleton, WI (US) Correspondence Address: (57) ABSTRACT KIMBERLY-CLARK WORLDWIDE, INC. 401 NORTH LAKE STREET NEENAH, WI 54956 A skin barrier-enhancing tissue product, Such as facial (21) Appl. No.: 10/156,161 tissue, bath tissue or paper towels and the like, can be made by applying, on the Surface(s) of the tissue, a lipid-enriched (22) Filed: May 28, 2002 melted based-hydrophobic composition comprising a natural fat or oil, a Sterol or Sterol derivative, an emulsifying Related U.S. Application Data having an HLB range from about 3 to about 6, a humectant, an emollient, a wax, and a Viscosity enhancer, (63) Continuation-in-part of application No. 09/379,777, and thereafter resolidifying the composition to form a dis filed on Aug. 24, 1999. tribution of Solid composition on the Surface(s) of the tissue. US 2003/0077962 A1 Apr. 24, 2003

ABSORBENT TISSUES PROVIDING SKIN 0007 Thus, what is needed in the art is formulation BARRIER ENHANCEMENT chemistry that, when applied from an absorbent tissue, enhances the Skin's barrier function by delivering lipid FIELD OF THE INVENTION chemistry while minimizing the physical damage caused by the rubbing of the Said absorbent tissue on the skin Surface. 0001. The present invention relates to the inclusion of a lipid-enriched hydrophobic lotion on absorbent tissue prod SUMMARY OF THE INVENTION ucts, Such as facial tissue, bath tissue, paper towels, and the like. More particularly, the present invention relates to the 0008. It has now been discovered that a skin barrier enhancement of skin barrier function by the delivery of oil enhancing absorbent tissue product can be made applying, based-hydrophobic compositions from the absorbent tissue on the tissue, an oil based-hydrophobic composition com products to the skin. prising a natural fat or oil, a Sterol or Sterol derivative, a humectant, an emulsifying Surfactant having an HLB range BACKGROUND OF THE INVENTION from about 3 to about 6, an emollient, a wax, and optionally a Viscosity enhancer, and thereafter resolidifying the com 0002 The stratum corneum is the outer-most layer of the position to form a distribution, preferably a uniform distri skin and is responsible for regulating skin water levels and bution, of Solid deposits on the Surface(s) of the tissue. functioning as a barrier against chemicals and other Stressors Because the composition is a Solid at room temperature and found in the environment. The complex arrangement of rapidly Solidifies after deposition, it has less tendency to lipids in the intercellular space of the Stratum corneum is penetrate and migrate into the sheet. Compared to tissues responsible for the establishment of normal barrier function. treated with liquid formulations, this leaves a greater per Multi-layered Structures of cholesterol, ceramides, and fatty centage of the added anhydrous Solid lotion composition on acids, as well as Some other minor lipids, provide the major the Surface of the tissue where it can contact and transfer to barrier to the transport of hydrophilic Substances into the or the user's Skin to provide enhanced skin health benefits. through the skin. The link between the barrier function and Furthermore, a lower add-on amount can be used to deliver skin health is apparent from the skin inflammation caused by the same benefit at a lower cost because of the efficient lipid extraction from the skin. placement of the composition Substantially at the Surface of 0.003 Skin barrier can be damaged due to a number of the product. mechanisms. Physical abrasion, for example caused by the 0009 Hence, in one aspect, the present invention is an oil repeated rubbing of absorbent tissue products on the skin, based-hydrophobic composition comprising from about 0.1 Strips away layers of the skin and thus damages skin barrier. to about 95 weight percent natural fats or , from about Biological fluids, Such as urine, feces, nasal and vaginal 0.1 to about 10 weight percent sterols or sterol dervatives, Secretions, may contain a variety of components that can from about 0.5 to about 20 weight percent of humectant, damage skin barrier. Examples of these components include from about 1 to about 20 weight percent of water-in-oil proteases, lipases, bile acids, and fatty acids. Once the skin emulsifing Surfacant having an HLB range from about 3 to barrier is compromised, these components, in addition to about 6, from about 5 to about 95 weight percent wax, and other constituents of biological fluids, can initiate or exac opitonally from about 30 C to about 100 C and a process erbate skin inflammation. Viscosity of greater than about 50 centipoise. Also, the 0004 Excessive hydration also has a negative impact on composition may have a penetration hardness of from about skin barrier. Frequent contact of the Skin with fluids Such as 5 millimeters to 360 millimeters. nasal Secretion can contribute to increased Skin hydration. 0010. In another aspect, the invention resides in a tissue Increased skin hydration disrupts skin lipid organization in or towel product wherein one or both of the outer surfaces the Stratum corneum. This disruption may increase the skin of the product have solidified deposits of an oil based permeability of irritants, thus increasing the risk of skin hydrophobic composition comprising from about 0.1 to inflammation. about 95 weight percent natural fats or oils, from about 0.1 0005 Absorbent tissue products such as facial tissue and to about 10 weight percent sterol or sterol derivative, from bath tissue have been used to absorb body fluids and leave about 0.5 to about 20 weight percent of humectant, from the skin dry. Absorbent tissue, in addition to absorbing about 1 to about 20 weight percent of water-in-oil emulsi fluids, however, also abrade the skin during use and fre fying Surfactant having an HLB range from about 3 to about quently do not leave the Skin completely dry and free of the 6, from about 5 to about 95 weight percent emollient, from body fluid the tissue is trying to absorb. During frequent about 5 to about 95 weight percent wax, and optionally from nose-blowing or perianal wiping, for example, the skin can about 0 to about 25 weight percent viscosity enhancer. The become So abraded as to appear red and be Sore to the touch. composition may have a melting/freezing point of from To reduce Skin abrasion, tissue additive formulations can be about 30° C. to about 100° C. and a process viscosity of applied to the tissue Such that, in use, the additive formu greater than about 50 centipoise. Also, the composition may lation either provides lubricity causing the tissue to glide have a penetration hardness from about 5 millimeters of acroSS the Surface of the Skin, or leaves the tissue and is penetration to 360 millimeters of penetration. deposited on the Skin. 0011. In another aspect, the invention resides in a method 0006 Once deposited on the skin, these additive formu of making a tissue or towel product comprising: (a) heating lations provide a skin benefit by occluding the skin. Thus, a composition that enhances skin barrier comprising a these formulations provide a short-term benefit by providing natural fat or oil, a Sterol or Sterol derivative, humectant, a an artificial barrier, even though the underlying Stratum water-in-oil emulsifying Surfactant having an HBL range corneum is still damaged. from about 3 to about 6, an emollient, a wax, and optionally US 2003/0077962 A1 Apr. 24, 2003

a Viscosity enhancer, to a temperature above the melting about 95 weight percent of wax, and from about 0 to about point of the composition, causing the composition to melt; 25 weight percent of Viscosity enhancer. (b) uniformly applying the melted composition to one or 0015 The composition may have a melting point from both Surfaces of the tissue or towel web in Spaced-apart about 30 C to about 100° C. The composition may have a deposits; and (c) resolidifying the deposits of the melted penetration hardness of from about 5 millimeters to about composition. The composition may have a melting point 360 millimeters. The add-on amount of the composition is ranging from about 30° C. to about 100° C. from about 0.5 to about 30 weight percent based on the weight of Said product. The add-on amount of the compo DETAILED DESCRIPTION OF THE Sition may also be expressed as from about 0.1 grams per INVENTION meter squared (g/m) to about 30 g/m of the tissue or towel 0012. The stratum corneum is the outermost layer of the product, and more preferably from about 0.5 g/m· to about skin and is responsible for regulating skin water levels and 25 g/m·. functioning as a barrier against infection, chemicals, and 0016. The natural fat or oil used in the composition may other StreSS agents found in the environment. The complex include Sunflower oil, borage oil, or avocado oil. The Sterol arrangement of lipids in the intercellular Space of the Stratum or Sterol derivative used in the composition may include Soy corneum is responsible for the establishment of this skin Sterol, cholesterol, or lanasterol. The humectant used in the barrier function. Multi-layered structures of cholesterol, composition may include glycerin, , or Starch ceramides and fatty acids as well as Some other minor lipids hydrolysate. The emulsifying Surfactant used in the compo provide the major barrier to the transport of Substances into Sition may include Sorbitan oleate, Sorbitan trioleate or or through the skin. The overall structure of the stratum Sorbitan Stearate. The emollient used in the composition may corneum acts as the front line barrier of the skin. The link include petrolatum, mineral oil, or Stearyl . The wax between the skin barrier function and skin health is apparent used in the composition may include cerasin, OZokerite, or from skin inflammation caused when the lipids contained in microcrystalline wax. The Viscosity enhancer used in the the skin are lost or otherwise absent from the skin, thereby composition may include ethylene/vinyl acetate copolymer impairing the skin barrier function. When the skin barrier or polyethylene. function is impaired, the other layers of the skin may be injured and exhibit a response to that injury, typically 0017 Another embodiment of the present invention is a evidenced in the form of inflammation. The lipid containing method of making a tissue or towel product having two outer compositions of the present invention may also include Surfaces comprising: (a) heating a composition that Sterols, Sterol derivatives or mixtures of both which may act enhances skin barrier comprising a natural fat or oil, Sterol in combination with naturally occurring fats and oils and/or or Sterol derivative, a humectant, an emulsifying Surfactant the lipids of the present invention to provide skin barrier having an HLB range from about 3 to about 6, an emollient, enhancement and Skin barrier recovery. By replenishing skin a wax, and Viscosity enhancer, to a temperature above the lipids, the compositions of the present invention provides a melting point of the composition, causing the composition to skin health benefit by improving the skin barrier functions melt; (b) applying the melted composition to one or both also referred to as enhancing skin barrier function. Surfaces of a tissue or towel web in Spaced-apart deposits, and, (c) resolidifying said deposits of the melted composi 0013 Moisturizers are defined as substances which tion. increase the Stratum corneum water content. While high water content typically indicates a high degree of moistur 0018. The composition may have a melting point of from ization, it is not an indication of good barrier function. For about 30°C to about 100° C. The resolidified composition example, mucous membranes are moist with an extremely may have a penetration hardness of from about 5 to about high water content but exhibit a poor barrier function. 360 millimeters. The melted composition may be applied by Additionally, roughneSS and Scaling of the skin evidence an printing. abnormally descquamating Stratum corneum. However, Such 0019. Another embodiment of the present invention is a Symptoms do not correlate with the Status of the skin barrier skin barrier enhancing composition comprising from about function. While moisturizers will temporarily decrease vis 0.1 to about 95 weight percent of natural fats or oils, from ible Scaling and roughness of the Skin, they typically offer about 0.1 to about 10 weight percent of sterol or sterol little or no enhancement of the skin barrier function. Despite derivative, from about 1 to about 20 weight percent of the potential efficacy of Some lipids as moisturizer ingredi water-in-oil emulsifying Surfactant having an HLB range ents, it is known that many of the individual lipids actually from about 3 to about 6, from about 0.5 to about 20 weight impede repair of the skin barrier function when applied to percent of humectant, from about 5 to about 95 weight damaged skin. percent of emollient, from about 5 to about 95 weight 0.014. One embodiment of the present invention is a percent of wax, and from about 0 to about 25 weight percent tissue or towel product having two outer Surfaces. One or of Viscosity enhancer. both outer Surfaces of the product have solidified deposits of a composition that enhances skin barrier. The composition 0020. The composition may have a melting point from may comprise from about 0.1 to about 95 weight percent of about 30° C. to about 100° C. The resolidified composition natural fats or oils, from about 0.1 to about 10 weight may have a penetration hardness of from about 5 millimeters percent of sterols or sterol derivatives, from about 1 to about to about 360 millimeters. 20 weight percent of water-in-oil emulsifying Surfactant 0021. The natural fat or oil of the composition may be having an HLB range from about 3 to about 6, from about Selected from the group consisting of avocado oil, apricot 0.5 to about 20 weight percent of humectant, from about 5 oil, babasSu oil, borage oil, camelia oil, canola oil, castor to about 95 weight percent of emollient, from about 5 to oil, chamomile, , corn oil, cottonseed oil, evening US 2003/0077962 A1 Apr. 24, 2003 primrose oil, hemp Seed, hydrogenated cottonseed oil, point of the particular compositions. Typically, proceSS hydrogenated palm kernal oil, maleated Soybean oil, mead temperatures are approximately 5 C above the melting owfoam oil, palm kernal oil, phospholipids, rapeseed oil, point of the composition. palmitic acid, Stearic acid, linoleic acid, rose hip oil, rose hip 0025 Examples of suitable viscosity enhancers for use in oil, Safflower, Sunflower oil, Soybean oil, Sweet almond, combination with the compositions and products of the PROLIPID 141 (proprietary blend of glyceryl Stearate, fatty present invention include, for example: polyolefin resins, acids, fatty , and phospholipids), or derivatives of polyolefin polymers, lipophilic/oil thickeners, ethylene/vi natural fats or oils (Such as , lauryl alcohol, nyl acetate copolymers, organically modified clays, poly myristyl alcohol, and benenyl alcohol, and the like), as well ethylene, Silica, Silica Sillylate, Silica methyl silylate; colloi as mixtures thereof. (PROLIPID is commercially available dal silicone dioxide; alkyl hydroxy ethyl cellulose; other from International Specialty Products located in Wayne, N.J. organically modified celluloses, glycol montanate; PEG-12 PROLIPID is generally described in U.S. Pat. No. 5,849,315 carnauba; Co-Cio alkyl hydroxyStearyl Stearate; polyper to Rerek et al. which issued Dec. 15, 1998; which is herein fluoromethylisopropylether montan wax, and, mixtures of incorporated by reference to the extent it is consistent these compounds. Many of the Solidifying agents described herewith.) The sterol or sterol derivative of the composition herein have also been found to provide the same benefits to may be selected from the group consisting of cholesterol, the compositions described herein as the Viscosity enhanc Sitosterol, Stigmasterol, ergosterol, lanasterol, Soy Sterol, CS. avocado Sterols, Sterol esters, and the like, as well as 0026. The amount of the natural fats or oils used in the mixtures thereof. The emulsifying Surfactant of the compo composition may be from about 0.1 to about 95 weight Sition may be Selected from the group consisting of Sorbitan percent. The amount of the sterol or sterol derivative used in oleate, Sorbitan Sesquioleate, Sorbitan Stearate, Sorbitan tris the composition may be from about 0.1 to about 10 percent. terate, Sorbitan trioleate, and the like, as well as mixtures The amount of the emulsifying Surfactant used in the com thereof. position may be from about 1 to about 20 weight percent. 0022. The humectant of the composition may be selected The amount of the humectant used in the composition may from the group consisting of glycerin, hydrogenated Starch be from about 0.5 to about 20 weight percent. The amount hydrolysate, propylene glycol, Sodium PCA, Sodium lactate, of the emollient used in the composition may be from about Sorbitol, and the like, as well as mixtures thereof. The 5 to about 95 weight percent. The amount of the wax used emollient of the composition may be Selected from the group in the composition may be from about 5 to about 95 weight consisting of mineral oil, petrolatum, Stearyl alcohol, cet percent. The amount of the Viscosity enhancer used in the earyl alcohol, , behenyl alcohol, octyldode composition may be from about 0 to about 25 weight canol, cosmetic esters, and the like, as well as mixtures percent. thereof. 0027. One embodiment of the composition comprises 0023 The wax of the composition may be selected from about 10 weight percent Sunflower oil, about 0.8 weight the group consisting of carnuba, cerasin, cetyl esters, micro percent Soy Sterol, about 1 weight percent Sorbitan oleate, crystalline wax, montan wax, OZokerite, Synthetic wax, and about 5 weight percent glycerin, about 43.2 weight percent the like, as well as mixtures thereof. The Viscosity enhancer petrolatum, about 20 weight percent Stearyl alcohol, and of the composition may be Selected from the group consist about 20 weight percent cerasin. ing of polyolefins resins, polyolefin polymers, ethylene/ 0028. Another embodiment of the composition comprises Vinyl acetate copolymers, polyethylene, and the like, as well about 10 weight percent borage oil, about 0.8 weight percent as mixtures thereof. Soy Sterol, about 1 weight percent Sorbitan oleate, about 5 weight percent glycerin, about 43.2 weight percent petrola 0024. The viscosity enhancers can be added to increase the melt point Viscosity of the compositions. Increasing the tum, about 20 weight percent Stearyl alcohol, and about 20 melt point Viscosity gives better Stability of the compositions weight percent cerasin. on the bodyfacing materials of the articles. The Viscosity 0029. Another embodiment of the composition comprises enhancers also improve the Stability of the compositions at about 10 weight percent avocado oil, about 0.8 weight the stability temperature at least about 100° F (37.8° C) and percent Soy Sterol, about 1 weight percent Sorbitan oleate, more specifically of about 130° F (54.5° C). Having high about 5 weight percent glycerin, about 43.2 weight percent viscosity (>50,000 centipoise) at elevated temperatures pre petrolatum, about 20 weight percent Stearyl alcohol, and vents the compositions from migrating into or away from the about 20 weight percent cerasin. materials to which they are applied. However, the Viscosity enhancer component also provides a low viscosity (<5,000 0030. Another embodiment of the composition comprises centipoise) for the compositions under high shear and at about 2 weight percent PROLIPID 141 (International Spe processing temperatures. The Viscosity enhances Suitable for cialty Products, Wayne, New Jersey), about 10 weight use with the present invention are capable of providing a percent Sunflower oil, about 1 weight percent Soy Sterol, desirable Viscosity to the compositions of the present inven about 1 weight percent Sorbitan oleate, about 5 weight tion, depending on Shear and temperature conditions. The percent glycerin, about 32 weight percent petrolatum, about Viscosity enhancers are Suitable for use for many composi 15 weight percent behenyl alcohol, about 32 weight percent tions having a range of melting points. While it is desirable cerasin, and about 2 weight percent Viscosity polyethylene. for compositions of the present invention to have increased 0031) Another embodiment of the composition comprises viscosity under “hot box car stability conditions, the about 2 weight percent PROLIPID 141 (International Spe increased Viscosity can be maintained, in part, through the cialty Products, Wayne, New Jersey), about 30 weight use of one or more Viscosity enhancers up to the melting percent Sunflower oil, about 3 weight percent Soy Sterol, US 2003/0077962 A1 Apr. 24, 2003 about 5 weight percent Sorbitan oleate, about 5 weight 0040 b) transferring at least a portion of the com percent Sorbitol, about 10 weight percent petrolatum, about position during use of the tissue or towel product; 10 weight percent behenyl alcohol, about 30 weight percent oZokerite, and about 5 weight percent polyethylene. 0041 c) repeating steps a) and b) with one or more additional tissue or towel product with Sufficient 0032) Another embodiment of the composition comprises frequency to enhance/restore/maintain the skin bar about 5 weight percent lanolin, about 20 weight percent rier in an area of Skin contacted by the tissue or towel Sunflower oil, about 3 weight percent cholesterol, about 5 product, relative to Skin contacted by an equivalent weight percent Sorbitan Stearate, about 5 weight percent tissue or towel product that does not comprise the hydrogenated Starch hydrolysate, about 2 weight percent skin barrier enhancing/frestoring/maintaining com petrolatum, about 5 weight percent octyldodecanol, about position. The Skin barrier enhancing/restoring/main 15 weight percent Stearyl alcohol, about 30 weight percent taining composition of the method comprises from microcrystalline wax, and about 5 weight percent ethylene/ about 0.1 to about 95 weight percent of natural fats Vinyl acetate copolymer. or oils, from about 0.1 to about 10 weight percent of sterols and sterol derivatives, from about 1 to about 0033. Another embodiment of the composition comprises 20 weight percent of water-in-oil emulsifying Sur about 27 weight percent avocado oil, about 3 weight percent factant having an HLB range from about 3 to about avocadin or avocado Sterols, about 2 weight percent Sorbitan 6, from about 0.5 to about 20 weight percent of trioleate, about 15 weight percent glycerin, about 17 weight humectant, from about 5 to about 95 weight percent percent petrolatum, about 18 weight percent cetyl alcohol, of emollient, from about 5 to about 95 weight percent and about 18 weight percent cerasin. of wax, and from about 0 to about 25 weight percent 0034. Another embodiment of the composition comprises of Viscosity enhancer. about 15 weight percent avocado oil, about 5 weight percent 0042. The composition may have a melting point from Sterol esters, about 10 weight percent Sorbitan trioleate, about 30° C. to about 100° C. The resolidified composition about 8 weight percent glycerin, about 2 weight percent may have a proceSS Viscosity greater than about 50 centi petrolatum, about 55 weight percent of a blend of ozokerite poise. The resolidified composition may have a penetration and cetyl esters, and about 5 weight percent polyethylene. hardness of from about 5 to about 360 millimeters. The The blend of ozokerite and cetyl esters comprises about 90 method may further comprise using a tissue or towel product weight percent oZokerite and about 10 weight percent cetyl having a skin-barrier enhancing/restoring/maintaining com eSterS. position by the user on each use occasion. The method may 0.035 Another embodiment of the composition comprises further comprise using a tissue or towel product which does about 25 weight percent borage oil, about 10 weight percent not comprise a skin-barrier enhancing/restoring/maintaining avocadin or avocado Sterols, about 5 weight percent Sorbitan composition by the user intermittently. The method may trioleate, about I weight percent glycerin, about 11 weight further comprise using the tissue or towel product compris percent petrolatum, about 10 weight percent Stearyl alcohol, ing a skin-barrier enhancing/restoring/maintaining compo about 36 weight percent cerasin, and about 2 weight percent Sition by a user whose skin is compromised and with polyethylene. Sufficient frequency to improve skin-barrier function. 0043. The amount of a natural fat or oil or a mixture of 0036) Another embodiment of the composition comprises natural fats or oils in the oil based-hydrophobic composition about 25 weight percent Sunflower oil, about 3 weight can be from about 0.1 to about 95 weight percent, more percent lanasterol, about 2 weight percent Sorbitan trioleate, specifically from about 5 to about 75 weight percent, more about 5 weight percent glycerin, about 15 weight percent specifically from about 10 to about 50 weight percent. As petrolatum, about 10 weight percent Stearyl alcohol, about used herein, the phrase natural fats or oils is understood to 10 weight percent behenyl alcohol, about 45 weight percent include fats, oils, essential oils, fatty acids, fatty alcohols, microcrystallin wax, and about 5 weight percent polyethyl phospholipids, and mixtures thereof. AS used herein, Suit CC. able natural fats or oils include, but are not limited to, the 0037 Another embodiment of the composition comprises following materials classified according to CTFA designa about 35 weight percent avocado oil, about 3 weight percent tions: Sitosterol about 5 weight percent Sorbitan trioleate, about 5 0044) Fats and Oils: Apricot Kernel Oil, Avocado Oil, weight percent glycerin, about 1 weight percent petrolatum, Babassu Oil, Borage Seed Oil, Butter, C-Cls Acid Trig about 10 weight percent Stearyl alcohol, about 21 weight lyceride, Camelia Oil, Ca Caprylic/Capric/Linoleic Triglyc percent oZokerite, and about 10 weight percent polyethyl eride, Caprylic/Capric/Stearic Triglyceride, Caprylic/Capric CC. Triglyceride, Carrot Oil, Cashew Nut Oil, Castor Oil, Cherry 0.038 Another embodiment of the present invention is a Pit Oil, Chia Oil, Cocoa Butter, Coconut Oil, Cod Liver Oil, method for enhancing/restoring/maintaining the skin barrier Corn Germ Oil, Corn Oil, Cottonseed Oil, Co-C,8 Triglyc erides, Egg Oil, Epoxidized Soybean Oil, Evening Primrose function of a user. The method comprises the Steps of: Oil, Glyceryl Triacetyl Hydroxystearate, Glyceryl Triacetyl 0039 a) contacting a tissue or towel product on the Ricinoleate, Glycosphingolipids, Grape Seed Oil, Hazelnut skin of Said user wherein Said material comprises a Oil, Human Placental Lipids, Hybrid Safflower Oil, Hybrid skin barrier enhancing/restoring/maintaining compo Sunflower Seed Oil, Hydrogenated Castor Oil, Hydroge Sition that provides a skin barrier enhancing/restor nated Castor Oil Laurate, Hydrogenated Coconut Oil, ing/maintaining benefit upon transfer of the compo Hydrogenated Cottonseed Oil, Hydrogenated C-C Trig Sition to the user's skin; lycerides, Hydrogenated Fish Oil, Hydrogenated Lard, US 2003/0077962 A1 Apr. 24, 2003

Hydrogenated Menhaden Oil, Hydrogenated Mink Oil, Camellia oil, Canola oil, Castor Oil, Coconut oil, Corn Oil, Hydrogenated Orange Roughy Oil, Hydrogenated Palm Cottonseed Oil, Evening Primrose Oil, Hydrogenated Cot Kernel Oil, Hydrogenated Palm Oil, Hydrogenated Peanut tonseed Oil, Hydrogenated Palm Kernal Oil, Maleated Soy Oil, Hydrogenated Shark Liver Oil, Hydrogenated Soybean bean Oil, Meadowfoam Oil, Palm Kernal Oil, Phospholip Oil, Hydrogenated Tallow, Hydrogenated Vegetable Oil, ids, Rapeseed Oil, Palmitic Acid, Stearic Acid, Linoleic Lard, Lauric/Palmitic/Oleic Triglyceride, Lanolin and Lano Acid, Rose Hip Oil, Sunflower Oil, Soybean Oil, PROLIPID lin derivatives, Lesquerella Oil, Linseed Oil, Macadamia 141 (proprietary blend of Glyceryl Stearate, Fatty Acids, Nut Oil, Maleated Soybean Oil, Meadowfoam Seed Oil, Fatty Alcohols, and Phospholipids from International Spe Menhaden Oil, Mink Oil, Moringa Oil, Mortierella Oil, cialty Products, Wayne, New Jersey), derivatives of natural Neatsfoot Oil, Oleic/Linoleic Triglyceride, Oleic/Palmitic/ fats or oils (such as Stearyl Alcohol, Lauryl Alcohol, Myri Lauric/Myristic/Linoleic Triglyceride, Oleostearine, Olive Styl Alcohol, Benenyl Alcohol, and the like), and the like, as Husk Oil, Olive Oil, Omental Lipids, Orange Roughy Oil, well as mixtures thereof. , Palm Oil, Peach Kernel Oil, Peanut Oil, Pengawar Djambi Oil, Pentadesma Butter, Phospholipids, 0049. The amount of a sterol or sterol derivative or Pistachio Nut Oil, Placental Lipids, Rapeseed Oil, Rice Bran mixture of sterols or sterol derivatives in the oil based Oil, Safflower Oil, Sesame Oil, Shark Liver Oil, Shea Butter, hydrophobic composition can be from about 0.1 to about 10 Soybean Oil, Sphingolipids, Sunflower Seed Oil, Sweet weight percent, more specifically from about 0.5 to about 5 Almond Oil, Tall Oil, Tallow, Tribehenin, Tricaprin, Trica weight percent, and Still more Specifically from about 0.8 to prylin, Triheptanoin, Trihydroxymethoxystearin, Trihydrox about 1 weight percent. AS used herein, Suitable Sterols and yStearin, Trisononanoin, TriSOStearin, Trilaurin, Trilinolein, sterol derivatives include, but are not limited to, the follow Trilinolenin, Trimyristin, Trioctanoin, Triolein, Tripalmitin, ing materials: -sterols having a tail on the 17 position and Trisebacin, Tristearin, Triundecanoin, Vegetable Oil, Walnut having no polar groups, for example cholesterol, Sitosterol, Oil, Wheat Bran Lipids, Wheat Germ. Oil, Zadoary Oil, and Stigmasterol, and ergosterol, as well as Co-Co choles terol/lanosterol esters, cholecalciferol, cholesteryl hydrox the like, as well as mixtures thereof. yStearate, cholesteryl isoStearate, cholesteryl Stearate, 7-de 0.045 Fatty Acids: Arachidic Acid, Arachidonic Acid, hydrocholesterol, dihydrocholesterol, dihydrocholesteryl Behenic Acid, Capric Acid, Caproic Acid, Caprylic Acid, octylidecanoate, dihydrolanosterol, dihydrolanosteryl octy Coconut Acid, Corn Acid, Cottonseed Acid, Hydrogenated idecanoate, ergocalciferol, tall oil Sterol, Soy Sterol acetate, Coconut Acid, Hydrogenated Menhaden Acid, Hydroge lanasterol, Soy Sterol, avocado Sterols, Sterol esters, and the nated Tallow Acid, HydroxyStearic Acid, ISOStearic Acid, like, and Sourced from natural extracts (Such as avocadin and , Linoleic Acid, Linolenic Acid, Linseed Acid, lanolin, and the like), as well as mixtures thereof. Myristic Acid, Oleic Acid, Palmitic Acid, Palm Kernel Acid, Pelargonic Acid, Ricinoleic Acid, Soy Acid, Stearic Acid, 0050. The amount of water-in-oil emulsifying surfactant/ Tall Oil Acid, Tallow Acid, Undecanoic Acid, Undecylenic Surfactant combinations having an HLB range from about 3 Acid, Wheat Germ Acid, and the like, as well as mixtures to about 6 in the oil based-hydrophobic composition can be thereof. from about 1 to about 20 weight percent, more specifically 0046) Fatty Alcohols: Behenyl Alcohol, Cg-C Alcohols, from about 2 to about 10 weight percent, and still more C2-C. Alcohols, Ca-Cs Alcohols, Ca-C, Alcohols, C specifically from about 3 to about 8 weight percent. Emul Cs Alcohols, Caprylic Alcohol, Cetearyl Alcohol, Cetyl Sifying are employed typically in cosmetic Alcohol, Coconut Alcohol, Decyl Alcohol, Hydrogenated preparations to form emulsions of various components. The Tallow Alcohol, Lanolin Alcohol, Lauryl Alcohol, Myristyl immiscible phase, Such as water and water Soluble/disperS Alcohol, , Palm Alcohol, Palm Kernel Alco ible materials, is dispersed as droplets in the continuous hol, Stearyl Alcohol, Tallow Alcohol, Tridecyl Alcohol, and phase, Such as an oil. the like, as well as mixtures thereof. 0051. The preferred surfactants include, but are not lim 0047. Essential Oils: Anise Oil, Balm Mint Oil, Basil Oil, ited to: Sorbitan monooleate, glyceryl Stearate, Sorbitan Bee Balm Oil, Bergamot Oil, Birch Oil, Bitter Almond Oil, Sequioleate, Sorbitan trioleate, Sorbitan Stearate, Sorbitan Bitter Orange Oil, Calendula Oil, California Nutmeg Oil, triStearate, and the like, as well as mixtures thereof. Caraway Oil, Cardamom Oil, Chamomile Oil, Cinnamon 0052 The amount of humectant in the oil based-hydro Oil, Clary Oil, Cloveleaf Oil, Clove Oil, Coriander Oil, phobic composition can be from about 0.5 to about 20 Cypress Oil, Eucalyptus Oil, Fennel Oil, Gardenia Oil, weight percent, more Specifically from about 1 to about 15 Geranium Oil, Ginger Oil, Grapefruit Oil, Hops Oil, Hyptis weight percent, and Still more specifically from about 3 to Oil, Indigo Bush Oil, Jasmine Oil, Juniper Oil, Kiwi Oil, about 10 weight percent. Humectants are typically cosmetic Laurel Oil, Lavender Oil, Lemongrass Oil, Lemon Oil, ingredients used to increase the water content of the tip Linden Oil, Lovage Oil, Mandarin Orange Oil, Matricaria layers of the skin. This group of materials includes primarily Oil, Musk Rose Oil, Nutmeg Oil, Olibanum, Orange Flower hydroscopic ingredients. AS used herein, Suitable humec Oil, Orange Oil, Patchouli Oil, Pennyroyal Oil, Peppermint tants include, but are not limited to, the following materials: Oil, Pine Oil, Pine Tar Oil, Rose Hips Oil, Rosemary Oil, Acetamide MEA, Aloe Vera Gel, Arginine PCA, Chitosan Rose Oil, Rue Oil, Sage Oil, Sambucus Oil, Sandalwood PCA, Copper PCA, Corn Glycerides, Dimethyl Imidazoli Oil, Sassafras Oil, Silver Fir Oil, Spearmint Oil, Sweet dinone, Fructose, Glucamine, Glucose, Glucose Glutamate, Marjoram Oil, Sweet Violet Oil, Tar Oil, Tea Tree Oil, Glucuronic Acid, Glutamic Acid, Glycereth-7, Glycereth-1 Thyme Oil, Wild Mint Oil, Yarrow Oil, Ylang Ylang Oil, and 2, Glycereth-20, Glycereth-26, Glycerin, Honey, Hydroge the like, as well as mixtures thereof. nated Honey, Hydrogenated Starch Hydrolysate, Hydro 0.048. The preferred natural oils include, but not limited lyzed Corn Starch, Lactamide MEA, Lactic Acid, Lactose to: Avocado Oil, Apricot Oil, Babassu Oil, Borage Oil, Lysine PCA, , Methyl Gluceth-10, Methyl Gluceth US 2003/0077962 A1 Apr. 24, 2003

20, PCA, PEG-2 Lactamide, PEG-10 Propylene Glycol, the need for external cooling means Such as chill rolls, if the Polyamino Sugar Condensate, Potassium PCA, Propylene composition is heated to a temperature only slightly above Glycol, Propylene Glycol Citrate, Saccharide Hydrolysate, or at the melting point of the composition. However, exter Saccharide Isomerate, Sodium ASpartate, Sodium Lactate, nal means such as chill rolls, either before or after the Sodium PCA, Sorbitol, TEA-Lactate, TEA-PCA, Urea, application of melt, can be used if desired to accelerate , and the like, as well as mixtures thereof. resolidification. Such instantaneous resolidification tends to 0053. The preferred humectants include, but are not lim impede penetration of the composition into the tissue and ited to: Glycerin, Hydrogenated Starch Hydrolysate, Propy retain it on the Surface of the tissue, which is advantageous. For example, the temperature of the melted composition can lene glycol, Sodium PCA, Sodium Lactate, Sorbitol and the advantageously be above the melting point about 10 C. or like, as well as mixtures thereof. less, more specifically about 5 C. or less and still more 0.054 The amount of emollient in the oil based-hydro specifically about 2 C. or less. As the temperature of the phobic composition may be from about 5 to about 95 weight melted composition approaches the melting point, the vis percent, more specifically from about 15 to about 80 weight cosity of the melted composition generally increases, which percent, and still more specifically from about 20 to about 65 further enhances the tendency of the melted composition to weight percent. AS used herein, Suitable emollients include, be retained on the Surface. but are not limited to, the following materials: mineral oil, mineral jelly, petrolatum, cosmetic esters (isoproyl palmi 0060 A unique feature of the compositions of the present tate, isopropyl myristate, isopropyl adipate, C-C ben invention is that an oil may be dispersed within a Solid matrix. During formulation, a liquid is Suspended within a Zoate, Stearyl benzoate, behenyl benzoate, octyl palmitate liquid in a continuous phase at elevated temperatures and and the like), glyceryl esters, alkoxylated carboxylic acids, under agitation. However, upon cooling, the continuous alkoxylated alcohols, fatty alcohols (lauryl alcohol, myristyl phase crystallizes into a Solid (crystalline) continuous phase alcohol, cetyl alcohol, Stearyl alcohol, ceateryl alcohol, matrix with the dispersed phase (oil) Suspended in the behenyl alcohol, octyl , and the like), lanolin and crystalline continuous phase matrix. This may also allow for lanolin derivatives, natural oils, base oils, Silicones, orga the oil to be applied without the need of an activation agent, nofunctional Silicones, hydrogenated vegetable oils, and the Such as water. AS Such, the addition of an activation agent to like, as well as mixtures thereof. the compositions of the present invention or to products 0.055 The preferred emollients include, but are not lim treated with or containing the compositions of the present ited to: Mineral Oil, Petrolatum, cosmetic esters, fatty alco invention is not required for the benefits of the compositions hols and the like, as well as mixtures thereof. of the present invention to be realized. 0056. The amount of wax in the oil based-hydrophobic 0061 For purposes herein, “melting point” is the tem composition can be from about 5 to about 95 weight percent, perature at which the majority of the melting occurs, it being more specifically from about 10 to about 75 weight percent, recognized that melting actually occurs over a range of and still more specifically from about 20 to about 60 weight temperatures. The melting point of the compositions of this percent. AS used herein, Suitable waxes include, but are not invention can be from about 30° C. to about 100° C., more limited to, the following materials: natural and Synthetic specifically from about 40 C. to about 90° C., and still more waxes, Such as bayberry wax, beeswax, Co alkyl dimethi specifically from about 50° C. to about 70° C. cone, candelilla wax, carnuaba, ceresin, Setyl esters, hydro 0062. In addition, for purposes herein, “penetration hard genated cottonseed oil, hydrogenated jojoba oil, hydroge ness” is the needle penetration in millimeters according to nated jojoba wax, hydrogenated microcrystalline wax, ASTM D 1321, “Needle Penetration of Petroleum Waxes. hydrogenated rice bran wax, japan wax, jojoba butter, jojoba Lower needle penetration hardneSS values correspond to esters, jojoba wax, lanolin wax, microcrystalline wax, mink harder materials. The penetration hardness of the composi wax, montan acid wax, montan wax, ouricury wax, Ozok tions of this invention can be from about 5 to 360 millime erite, paraffin, PEG-6 beeswax, PEG-8 beeswax, rice bran ters, more specifically from about 5 to about 200 millime wax, shellac wax, spent grain wax, Steryl dimethicone ters, more specifically from about 5 to about 150 Synthetic beeswax, Synthetic candelilla wax, Synthetic car millimeters, and still more specifically from about 5 to about nuba wax, Synthetic japan wax, Synthetic jojoba wax, Syn 100 millimeters. (Formulations having a needle penetration hardness greater than 360 millimeters cannot be measured thetic wax, and the like, as well as mixtures thereof. using ASTM method D 1321). 0057 The preferred waxes include but are not limited to: carnuba, cerasin, cetyl esters, microcrystalline wax, montan 0063. The hardness of the formulations of this invention wax, OZokerite, Synthetic wax, and the like, as well as is important for two reasons. First, the softer the formulation mixtures thereof. the more mobile the formulation will be, making the for mulation more likely to migrate to the inner plies of the 0.058 Optionally, the amount of viscosity enhancer in the tissue, which is not desirable. Secondly, Softer formulations oil based-hydrophobic composition can be from about 0 to tend to be more greasy/oily to the touch, which is also leSS about 25 weight percent, more specifically from about 5 to desirable. In general, formulations having a needle penetra about 20 weight percent, and Still more specifically from tion hardness of from about 200 to 360 millimeters feel about 10 to about 15 weight percent. As used herein, Suitable creamy to slightly greasy with less Smoothness (depending Viscosity enhancers include, but are not limited to, the on additives). Formulations that have needle penetration following materials: the group consisting of polyolefins hardness values of from about 5 to about 200 millimeters resins, polyolefin polymers, ethylene/vinyl acetate copoly feel silky to creamy and very Smooth (depending on addi mers, polyethylene and the like, as well as mixtures thereof. tives). 0059 Resolidification of the melted oil based-hydropho 0064. The melt point viscosity and/or the process tem bic composition can occur almost instantaneously, without perature Viscosity of the formulations or compositions of US 2003/0077962 A1 Apr. 24, 2003 this invention is important for two reasons: First, the higher 0068 The compositions of the present invention may be the melt point Viscosity or the process temperature Viscosity applied to the entire outer Surface(s) of the tissue or towel as it is applied to the outside Surface of the diaper liner, the product or portions thereof. The compositions of the present formulation is less likely to penetrate through to the inner invention may be applied non-uniformly to the Outer Surface ply(s) of the tissue. The less formulation penetrates through of the tissue or towel product. The term “non-uniformly”, the tissue, the more there is on the Surface of the tissue where as used herein, refers to the amount, pattern of distribution, it can readily transfer to the users skin Surface. Secondly, the thickness of the application, areas of non-coverage, or the higher the viscosity of the formulation above or at the like, for which the composition can be varied over the outer melting point of the formulation, the less likely the formu Surface(s) of the tissue or towel product. lation will migrate at typical or adverse Storage conditions. 0069. Also as used herein, a “tissue product” can be a 0065. In order to better enhance the benefits to consum facial tissue, bath tissue, paper towel, dinner napkin or the ers, additional ingredients can be used. The classes of like. The tissue products of this invention can be one-ply, ingredients and their corresponding benefits include, without two-ply, three-ply or more. In all cases, the composition is limitation: antiacne actives (a drug product used to reduce applied to one or both outer Surfaces of the product after the the number of acne blemishes, acne pimples, blackheads, product has been dried. The composition can be applied after and whiteheads); antifoaming agents (reduce the tendency of the plies are brought together or prior to bringing the plies foaming during processing); antimicrobial actives, antifun together. The individual plies can be layered or blended gal actives, antiseptic actives; antioxidants (product integ (homogeneous) creped or uncreped, throughdried or wet rity to prevent oxidation of the natural oils or other formu pressed. lation ingredients); astringents-cosmetic (induce a tightening or tingling Sensation on skin); astringent-drug (a drug product which checkS Oozing, discharge, or bleeding EXAMPLES when applied to Skin or mucous membrane and works by 0070 The following examples are presented to provide a coagulating protein); biological additives (enhance the per more detailed understanding of the invention. The particular formance or consumer appeal of the product including materials and parameters are exemplary and are not intended Vitamins); colorants (impart color to the product), deodor to limit the scope of the invention. The following formulas ants (reduce or eliminate unpleasant odor and protect against are used in Examples 1-4. the formation of malodor on body Surfaces); emollients (help to maintain the Soft, Smooth, and pliable appearance of the skin by their ability to remain on the skin surface or in the Stratum corneum to act as lubricants, to reduce flaking, weight percent and to improve the skin's appearance); film formers (to hold active ingredients on the Skin by producing a continuous Formula 1 film on skin upon drying); fragrances (consumer appeal); Petrolatum 93.7% natural moisturizing agents (NMF) and other skin moistur Glycerin 5% izing ingredients known in the art; Skin conditioning agents, PROLIPID 141 1.0% skin exfoliating agents (ingredients that increase the rate of (International Specialty Products, Wayne, NJ) skin cell turnover Such as alpha hydroxy acids and beta Tocopherol acetate O.3% hydroxyacids); Skin protectants (a drug product which pro Formula 2 tects injured or exposed skin or mucous membrane Surface Petrolatum 88.7% from harmful or annoying stimuli), Solvents (liquids Glycerin 5% employed to dissolve components found useful in the coS PROLIPID 141 1.0% (International Specialty Products, Wayne, NJ) metics or drugs); Sunscreens (ingredients that absorb at least Tocopherol acetate O.3% 85 percent of the light in the UV range at wavelengths from Avocadin (CRODA) 5.0% 290 to 420 manometers, but transmit UV light at wave Formula 3 lengths longer than 420 manometers); and, Surfactants (as cleansing agents, Solubilizing agents, Suspending agents, Petrolatum 83.7% and Wetting agents). Glycerin 5% Tocopherot acetate O.3% Sunflower oil 9.2% 0.066 The total tissue add-on of the composition can be Soy sterol O.8% from about 0.5 to about 40 weight percent, more specifically PROLIPID 141 (ISP) 1.0% from about 5 to about 30 weight percent, and more specifi (International Specialty Products, Wayne, NJ) cally from about 10 to about 15 weight percent, based on the Formula 4 weight of the tissue. The add-on amount will depend upon the desired effect of the composition on the product Petrolatum 100% attributes and the Specific composition. A preferred method Formula 5 to uniformly apply the heated composition to the Surface of Petrolatum 85.4% the tissue web is rotogravure printing, either direct or Glycerin 5% indirect (offset), because it is a more precise exact printing Glyceryl monoleate 3% proceSS and offers maximum control of the composition Borage oil 3% Soy sterol 3% distribution and transfer rate. However, other printing meth Aloe O.3% ods, but not limited to, flexographic printing or spraying Tocopherol acetate O.3% Such as WEKO, can be used. Formula 6

0067. As used herein, all recited ranges of amounts, Petrolatum 86.4 temperatures, molecular weights and penetration hardnesses Glycerin 5% are intended to include all Sub-ranges within the recited Glyceryl monoleate 3% ranges, even though not specifically Stated. US 2003/0077962 A1 Apr. 24, 2003

Example 2 -continued 0076 Lipid-enriched formulations for treatment of absor weight percent bent tissue enhance Skin moisturization as measured by conductance. Borage oil 3% Soy sterol 1% PROLIPID 141 (ISP) 1.0% 0077 All studies were conducted in a temperature and (International Specialty Products, Wayne, NJ) humidity controlled room (71+5 F. 40%+5relative humid Aloe O.3% ity). Tocopherol acetate O.3% Formula 7 Conductance Petrolatum 44% Mineral oil 10.8% 0078 Fifteen microliters of lipid-enriched formulation Cerasin 10% for an absorbent tissue was topically applied to the Volar Stearyl alcohol 25% forearm. Conductance measurements were obtained using Isopropyl palmitate 3% Sunflower oil 3% the Skicon instrument at 1, 2, 4, and 6 hours. Mean con Soy sterol 3% ductance values are expressed in Table 2. A pair-wise Dimethicone 1% comparison for each time period using univariate ANOVAS Aloe Extract O.1% was applied. Vitamin E acetate O.1% Formula 8 TABLE 2 Petrolatum 36% Mineral oil 10.8% Conductance- Lipid-enriched formulations for absorbent tissues Cerasin 10% Stearyl alcohol 25% Baseline 1 Hour 2 Hour 4 Hour 6 Hour Glycerin 5% Mean Mean Mean Mean Mean Glyceryl mono-oleate 3% Isopropyl palmitate 3% Formula 1 202 370: 357-k 335* 31 O* Sunflower oil 3% Formula 2 220 344* 349* 333* 319* Soy sterol 3% Formula 3 220 342* 340* 333* 32O: Dimethicone 1% Untreated 200 22O 235 232 223 Aloe Extract O.1% Vitamin E acetate O.1% *denotes significantly different than untreated site. 0079 The above data clearly demonstrates that the lipid Example 1 enriched formulations improve Skin barrier moisturization. 0071 Lipid-enriched formulations for treatment of absor Example 3 bent tissue promote barrier repair as measured by TEWL. 0080 Lipid-enriched formulations for treatment of absor 0.072 All studies were conducted in a temperature and bent tissue enhance Skin moisturization as measured by humidity controlled room (71+5 F. 40%+5% relative conductance. humidity). 0081 All studies were conducted in a temperature and humidity controlled room (71+5 F.; 40%+5% relative 0073 Transepidermal Water Loss (TEWL) humidity). 0.074 The volar forearm of 24 panelists was abraded by an emery cloth to increase TEWL levels to 18-20 g/m·h. Conductance After abrasion, fifteen microliters of a lipid-enriched formu lation was topically applied to the volar forearm. TEWL 0082 Fifteen microliters of a lipid-enriched absorbent measurements were obtained using a Dermalab evaporim tissue formulation was topically applied to the Volar fore eter instrument at 1, 2, and 4 hours. Mean TEWL values are arm. Conductance measurements were obtained at 1, 2, 4, expressed in Table 1. Repeated measures ANOVA was used and 6 hours. Mean conductance values for the baseline, 4, to adjust for the repeated TEWL measures. and 6 hour timepoints are expressed in Table 3. A pair-wise comparison for each time period using univariate ANOVAS TABLE 1. was applied. TEWL g/m/hr Results- Lipid-enriched absorbent tissue formulations TABLE 3 PIR 1 Hour 2 Hour 4 Hour Mean Mean Mean Mean Conductance-Absorbent tissue formulations

Formula 1 19.8 6.6* 6.6* 7.9% Baseline 4 Hour 6 Hour Formula 2 18.3 6.4* 6.6* 7.3% Mean Mean Mean Formula 3 19.2 6.5* 6.5* 7.18 Untreated 19.2 15.2 14.3 14.3 Formula 4 187 243 247 Formula 5 179 281* 289* *denotes significantly different than untreated site. Formula 6 195 295* 297: Untreated 194 210 215 0075. The above data clearly demonstrates that the lipid *denotes significantly different than untreated site. enriched formulations improve Skin barrier repair. US 2003/0077962 A1 Apr. 24, 2003

0.083. The above data clearly demonstrates that the lipid from about 0.1 to about 10 weight percent of sterols or enriched formulations improve Skin barrier moisturization. sterol derivatives; Example 4 from about 1 to about 20 weight percent of water-in-oil emulsifying Surfactant having an HLB range from Repetitive Wiping With an Absorbent Tissue about 3 to about 6; Treated with a Hydrophobic Lipid-Enriched from about 0.5 to about 20 weight percent of humectant; Formula Reduces Barrier Damage Compared to an Untreated Absorbent Tissue from about 5 to about 95 weight percent of emollient; 0084 Absorbent tissue treated with a hydrophobic lipid from about 5 to about 95 weight percent of wax; and, from enriched formula was repetitively wiped on the side of the about 0 to about 25 weight percent of viscosity face to determine the extent of barrier damage as measured enhancer. by TEWL. The study consisted of repetitively wiping the 2. The product of claim 1, wherein Said composition has face of 10 panelists with the absorbent tissues for a total of a melting point from about 30 C. to about 100° C. 15 wiping cycles. The wiping cycles were timed to be 3. The product of claim 1, wherein Said composition has approximately 30 minutes apart with each wiping cycle a penetration hardness of from about 5 millimeters to about consisting of 20 wipes. A baseline TEWL reading and 360 millimeters. TEWL readings after every two wiping cycles were obtained 4. The product of claim 1, wherein the add-on amount of for each panelist using the Dermalab evaporimeter. The said composition is from about 0.5 to about 30 weight change in TEWL between wiping cycles was determined for percent based on the weight of Said product. each treatment. 5. The material of claim 1, wherein the add-on amount of Said composition is from about 0.1 grams per meter Squared (g/mi) to about 30 g/m· of said material. 6. The product of claim 1, wherein said natural fat or oil Estimated increase is Sunflower oil. Treatment in TEWL/wiping cycle 7. The product of claim 1, wherein said natural fat or oil Absorbent tissue treated with formula 7 42* is borage oil. Absorbent tissue treated with formula 8 4.3* 8. The product of claim 1, wherein said natural fat or oil non-treated absorbent tissue 6.4 is avocado oil. 9. The product of claim 1, wherein said sterol or sterol *denotes statistically different than non-treated absorbent tissue derivative is Soy Sterol. 10. The product of claim 1, wherein said sterol or sterol 0085 Repetitive wiping with the absorbent tissues derivative is cholesterol. treated with the lipid-enriched hydrophobic formulas 11. The product of claim 1, wherein said sterol or sterol resulted in leSS Skin barrier damage compared to the derivative is lanasterol. untreated absorbent tissue. 12. The product of claim 1, wherein Said humectant is 0.086 Thus, the Examples representatively illustrate that glycerin. the lipid-enriched hydrophobic composition of the present 13. The product of claim 1, wherein said humectant is invention may provide absorbent tissue products having Sorbitol. improved Softness as well as providing improved protection 14. The product of claim 1, wherein said humectant is of the skin barrier function. Accordingly, the different hydrogenated Starch hydrolysate. aspects of the present invention can advantageously provide 15. The product of claim 1, wherein said emulsifying absorbent tissue products which, when compared to con Surfactant is Sorbitan oleate. ventional tissue products, are Softer and have improved 16. The product of claim 1, wherein said emulsifying protection of skin barrier function. Such absorbent tissue Surfactant is glyceryl Stearate. products can advantageously be used for absorbent tissue 17. The product of claim 1, wherein said emulsifying products, Such as facial tissue, bath tissue, paper towels, and Surfactant is Sorbitan Stearate. the like. 18. The product of claim 1, wherein said emollient is 0087 While the invention has been described in detail petrolatum. with respect to the Specific aspects thereof, it will be 19. The product of claim 1, wherein said emollient is appreciated that those skilled in the art, upon attaining an mineral oil. understanding of the foregoing, may readily conceive of 20. The product of claim 1, wherein said emollient is alterations to, variations of, and equivalents to these aspects. Stearyl alcohol. Accordingly, the Scope of the present invention should be 21. The product of claim 1, wherein Said wax is cerasin. assessed as that of the appended claims and any equivalents 22. The product of claim 1, wherein Said wax is OZokerite. thereto. 23. The product of claim 1, wherein said wax is micro crystalline wax. 24. The product of claim 1, wherein said viscosity 1. A tissue or towel product having two outer Surfaces, enhancer is ethylene/vinyl acetate copolymer. wherein one or both Outer Surfaces of Said product have a 25. The product of claim 1, wherein said viscosity composition that enhances skin barrier comprising: enhancer is polyethylene. 26. A method of making a tissue or towel product having from about 0.1 to about 95 weight percent of natural fats two outer Surfaces comprising: (a) heating a composition or oils, that enhances Skin barrier comprising a natural fat or oil, US 2003/0077962 A1 Apr. 24, 2003

Sterol or Sterol derivative, a humectant, an emulsifying 39. The composition of claim 30, wherein said wax is Surfactant having an HLB range from about 3 to about 6, an Selected from the group consisting of carnuba, cerasin, cetyl emollient, a wax, and Viscosity enhancer, to a temperature esters, microcrystalline wax, montan wax, OZokerite, Syn above the melting point of Said composition, causing Said thetic wax, and mixtures thereof. composition to melt; (b) applying Said melted composition 40. The composition of claim 30, wherein said viscosity to one or both Surfaces of a tissue or towel web; and, (c) enhancer is Selected from the group consisting of polyole resolidifying Said melted composition. fins resins, polyolefin polymers, ethylene/vinyl acetate 27. The method of claim 26, wherein said has a melting point of from about 30° C. to about 100° C. copolymers, polyethylene, and mixtures thereof. 28. The method of claim 26, wherein said resolidified 41. The composition of claim 30, wherein the amount of composition has a penetration hardness of from about 5 to said natural fats or oils is from about 0.1 to about 95 weight about 360 millimeters. percent. 29. The method of claim 26, wherein said melted com 42. The composition of claim 30, wherein the amount of position is applied by printing. said sterol or sterol derivative is from about 0.1 to about 10 30. A skin barrier enhancing composition comprising percent. from about 0.1 to about 95 weight percent of natural fats or 43. The composition of claim 30, wherein the amount of oils, from about 0.1 to about 10 weight percent of sterol or said emulsifying surfactant is from about 1 to about 20 sterol derivative, from about 1 to about 20 weight percent of weight percent. water-in-oil emulsifying Surfactant with an HLB range from about 3 to about 6, from about 0.5 to about 20 weight percent 44. The composition of claim 30, wherein the amount of of humectant, from about 5 to about 95 weight percent of said humectant is from about 0.5 to about 20 weight percent. emollient, from about 5 to about 95 weight percent of wax, 45. The composition of claim 30, wherein the amount of and from about 0 to about 25 weight percent of viscosity said emollient is from about 5 to about 95 weight percent. enhancer. 46. The composition of claim 30, wherein the amount of 31. The composition of claim 30, wherein said composi said wax is from about 5 to about 95 weight percent. tion has a melting point from about 30° C. to about 100 C. 32. The composition of claim 30, wherein said resolidified 47. The composition of claim 30, wherein the amount of composition has a penetration hardness of from about 5 said viscosity enhancer is from about 0 to about 25 weight millimeters to about 360 millimeters. percent. 33. The composition of claim 30, wherein said natural fat 48. A method for enhancing/restoring/maintaining skin or oil is Selected from the group consisting of avocado oil, barrier function Skin of a user, comprising the Steps of: apricot oil, babasSu oil, borage oil, camelia oil, canola oil, castor oil, chamomile, coconut oil, corn oil, cottonseed oil, a) contacting a tissue or towel product on said skin of Said evening primrose oil, hemp Seed, hydrogenated cottonseed user wherein Said product comprises a skin barrier oil, hydrogenated palm kernal oil, maleated Soybean oil, enhancing/restoring/maintaining composition that pro meadowfoam oil, palm kernal oil, phospholipids, rapeseed vides a skin barrier enhancing/restoring/maintaining oil, palmitic acid, Stearic acid, linoleic acid, rose hip oil, benefit upon transfer of Said composition to Said user's Safflower, Sunflower oil, Soybean oil, Sweet almond, or skin; derivatives of natural fats or oils. Such as Stearyl alcohol, lauryl alcohol, myristyl alcohol, and benenyl alcohol, and b) transferring at least a portion of said composition mixtures thereof. during use of Said tissue or towel product; and, c) 34. The composition of claim 30, wherein said sterol or repeating steps a) and b) with one or more additional Sterol derivative is Selected from the group consisting of tissue or towel product with Sufficient frequency to cholesterol, Sitosterol, Stigmasterol, ergosterol, lanasterol, enhance/restore/maintain Said Skin barrier in an area of Soy Sterol, avocado Sterols, Sterol esters, and mixtures skin contacted by Said liner or tissue material, relative thereof. to Skin contacted by an equivalent tissue or towel 35. The composition of claim 30 wherein said sterol is product that does not comprise Said skin barrier Selected from natural eXtracts that contain Sterols or Sterol enhancing/restoring/maintaining composition, wherein derivatives Selected from the group consisting of lanolin, Said skin barrier enhancing/restoring/maintaining com avocadin, and mixtures thereof. position comprises: from about 0.1 to about 95 weight 36. The composition of claim 30, wherein said emulsify percent of natural fats or oils, from about 0.1 to about ing Surfactant is Selected from the group consisting of: 10 weight percent of Sterols and Sterol derivatives, from Sorbitan oleate, Sorbitan Sesquioleate, glyceryl Stearate, Sor about I to about 20 weight percent of water-in-oil bitan Stearate, Sorbitan tristerate, Sorbitan trioleate, and emulsifying Surfactant having an HLB range from mixtures thereof. about 3 to about 6, from about 0.5 to about 10 weight 37. The composition of claim 30, wherein said humectant percent of humectant, from about 5 to about 95 weight is Selected from the group consisting of glycerin, hydroge percent of emollient, from about 5 to about 95 weight nated Starch hydrolysate, propylene glycol, Sodium PCA, percent of wax, and from about 0 to about 25 weight Sodium lactate, Sorbitol, and mixtures thereof. percent of Viscosity enhancer. 38. The composition of claim 30, wherein said emollient 49. The method of claim 48, wherein said composition is Selected from the group consisting of mineral oil, petro having a melting point from about 30° C. to about 100 C. latum, Stearyl alcohol, cetearyl alcohol, cetyl alcohol, behe 50. The method of claim 48, wherein said resolidified nyl alcohol, octyldodecanol, cosmetic esters, and mixtures composition has a process Viscosity greater than about 50 thereof. centipoise. US 2003/0077962 A1 Apr. 24, 2003

51. The method of claim 48, wherein said resolidified restoring/maintaining composition are used by Said user composition has a penetration hardness of from about 5 to intermittently. about 360 millimeters. 54. The method of claim 48, wherein said tissue or towel 52. The method of claim 48, wherein said tissue or towel product comprising Said Skin-barrier enhancing/restoring/ product comprising Said Skin-barrier enhancing/restoring/ maintaining composition are used by a user whose skin is maintaining composition are used by Said user on each use compromised and are used with Sufficient frequency to occasion. improve skin-barrier function. 53. The method of claim 48, wherein said tissue or towel product which do not comprise a skin-barrier enhancing/ k k k k k