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Society, Materials, and the Environment: the Case of Steel
metals Review Society, Materials, and the Environment: The Case of Steel Jean-Pierre Birat IF Steelman, Moselle, 57280 Semécourt, France; [email protected]; Tel.: +333-8751-1117 Received: 1 February 2020; Accepted: 25 February 2020; Published: 2 March 2020 Abstract: This paper reviews the relationship between the production of steel and the environment as it stands today. It deals with raw material issues (availability, scarcity), energy resources, and generation of by-products, i.e., the circular economy, the anthropogenic iron mine, and the energy transition. The paper also deals with emissions to air (dust, Particulate Matter, heavy metals, Persistant Organics Pollutants), water, and soil, i.e., with toxicity, ecotoxicity, epidemiology, and health issues, but also greenhouse gas emissions, i.e., climate change. The loss of biodiversity is also mentioned. All these topics are analyzed with historical hindsight and the present understanding of their physics and chemistry is discussed, stressing areas where knowledge is still lacking. In the face of all these issues, technological solutions were sought to alleviate their effects: many areas are presently satisfactorily handled (the circular economy—a historical’ practice in the case of steel, energy conservation, air/water/soil emissions) and in line with present environmental regulations; on the other hand, there are important hanging issues, such as the generation of mine tailings (and tailings dam failures), the emissions of greenhouse gases (the steel industry plans to become carbon-neutral by 2050, at least in the EU), and the emission of fine PM, which WHO correlates with premature deaths. Moreover, present regulatory levels of emissions will necessarily become much stricter. -
The Role of Alloying Elements on the Fabricability of Austenitic Stainless Steel
The Role of Alloying Elements on the Fabricability of Austenitic Stainless Steel John C. Tverberg, P.E. Metals and Materials Consulting Engineers Mukwonago, Wisconsin How many times have fabrication problems developed when a new coil or a new heat of steel is put in production? The problems can be tearing, cracking, scratching, poorer weld penetration, poor electropolished surface or a host of other problems. The usual procedure to determine the source of the problem is a hardness test, tensile test, and metallographic cross section and to review the mill test reports. Sometimes the source of the problem is spotted, but most often nothing out of the ordinary is found. In these cases the problem lies in the composition of the steel even when the alloy is within the specified composition of the steel. Alloy Design Austenitic stainless steels are designed to give corrosion resistance in many environments, resistance to hydrogen and 885º F (475º C) embrittlement, good strength, good ductility and low hardness. In its simplest form stainless steel is iron with 12% minimum chromium. This is what makes stainless steel rust resistant and allows the passive film to develop. Stainless steel exists in three metallurgical conditions depending on composition and heat treatment: ferritic, martensitic and austenitic. These names refer to the crystallographic structure: ferrite is body-centered cubic, austenite is face-centered cubic and martensite is a distorted tetragonal which is the distorted face-centered cubic structure being changed into a body-centered structure. The characteristics of these structures are tabulated in Table I and are illustrated in Figure 1. -
Primary Mill Fabrication
Metals Fabrication—Understanding the Basics Copyright © 2013 ASM International® F.C. Campbell, editor All rights reserved www.asminternational.org CHAPTER 1 Primary Mill Fabrication A GENERAL DIAGRAM for the production of steel from raw materials to finished mill products is shown in Fig. 1. Steel production starts with the reduction of ore in a blast furnace into pig iron. Because pig iron is rather impure and contains carbon in the range of 3 to 4.5 wt%, it must be further refined in either a basic oxygen or an electric arc furnace to produce steel that usually has a carbon content of less than 1 wt%. After the pig iron has been reduced to steel, it is cast into ingots or continuously cast into slabs. Cast steels are then hot worked to improve homogeneity, refine the as-cast microstructure, and fabricate desired product shapes. After initial hot rolling operations, semifinished products are worked by hot rolling, cold rolling, forging, extruding, or drawing. Some steels are used in the hot rolled condition, while others are heat treated to obtain specific properties. However, the great majority of plain carbon steel prod- ucts are low-carbon (<0.30 wt% C) steels that are used in the annealed condition. Medium-carbon (0.30 to 0.60 wt% C) and high-carbon (0.60 to 1.00 wt% C) steels are often quenched and tempered to provide higher strengths and hardness. Ironmaking The first step in making steel from iron ore is to make iron by chemically reducing the ore (iron oxide) with carbon, in the form of coke, according to the general equation: Fe2O3 + 3CO Æ 2Fe + 3CO2 (Eq 1) The ironmaking reaction takes place in a blast furnace, shown schemati- cally in Fig. -
The Role of Zirconium in Microalloyed Steels
The Role of Zirconium in Microalloyed Steels T N Baker Department of Mechanical and Aerospace Engineering The University of Strathclyde, Glasgow G1 1XJ, UK. E-mail:[email protected]. Abstract Recently there has been a renewed interest in the addition of zirconium to microalloyed steels. It has been used since the early 1920’s, but has never been universally employed, as have niobium, titanium or vanadium. The functions of zirconium in steelmaking are associated with a strong chemical affinity, in decreasing order, for oxygen, nitrogen, sulphur and carbon. Historically, the main use of additions of zirconium to steel was for combination preferentially with sulphur and so avoid the formation of manganese sulphide, known to have a deleterious influence of the impact toughness of wrought and welded steel. Modern steelmaking techniques have also raised the possibility that zirconium additions can reduce the austenite grain size and increase dispersion strengthening, due to precipitation of zirconium carbonitrides, or in high nitrogen vanadium-zirconium steels, vanadium nitride. This review gathers information on the compounds of zirconium identified in steels together with crystallographic data and solubility equations. Also brief accounts of the role of sulphides and particles in general on austenite grain size control and toughness are included. Keywords: Zirconium compounds, mechanical properties, impact, microstructure 1 1 Introduction The term microalloying, as applied to steels, is generally accepted as emanating from the paper by Beiser1 published in 1959, which reported the results of small additions of niobium to commercial heats of a carbon steel. However, it has not been recognized that microalloying as such, first occurred some 35 years earlier, when small additions of zirconium were added to plain carbon steels, and the effects reported by Feild2 and by Beckett3. -
Inclusions Properties at 1673 K and Room Temperature with Ce Addition
www.nature.com/scientificreports OPEN Inclusions properties at 1673 K and room temperature with Ce addition in SS400 steel Received: 13 January 2017 Fei Pan 1,2,3, Hao-Long Chen4, Yen-Hsun Su1, Yen-Hao Su 5 & Weng-Sing Hwang1 Accepted: 13 April 2017 Inclusion species formed in SS400 steel with Ce-addition was predicted by thermodynamic calculation. The Published: xx xx xxxx analysis of the inclusion morphology and size distribution was carried out by applying Scanning Electron Microscopy (SEM) and Transmission Electron Microscope (TEM). Nano-Fe3O4 particles were also found in cerium-deoxidized and -desulfurized steel and their shapes were nearly spherical. The complex Ce2O3 inclusions covering a layer of 218 nm composed by several MnS particles with similar diffraction pattern. Most importantly, the complex Ce2O3 characterized by using TEM diffraction is amorphous in the steel, indicating that Ce2O3 formed in the liquid iron and then MnS segregated cling to it. Nonmetallic inclusions with high melting point in steel could be harmful in production of high grade wire, spring, and bearing steels1, 2. Inclusions larger than 10 µm are probable to lower the yield strength obviously and also decrease tensile strength3. However, the yield strength and tensile strength would increase remarkably for steels with inclusions less than 0.3 µm3. Adding a or several metal elements into steel has been exploited by steel manufactures in order to form finer grain structures in steel and to improve the performance of the steel4. Titanium5, Aluminium6 and Magnesium7 have been studied a lot as deoxidizers and their functions have also been researched a lot to improve the strength of steel. -
Iron and Steel: Introduction
Iron and Steel: Introduction Iron is cheap and strong and the most used metal in the world. Iron, as produced in the blast furnace is called pig iron. This is brittle because it contains about 4% carbon and other non-metal impurities. Most of this iron is converted into a variety of steels by removing nearly all the carbon, and adding small quantities of different metals. The different steels are alloys which are mixtures of metals. They have different properties such as toughness, hardness, corrosion resistance, etc. Some background The method of using carbon to reduce iron oxide to iron was very probably discovered accidentally in prehistoric camp fires. Here, charcoal would have been the source of carbon. The iron was used to make tools and weapons and gave its name to the Iron Age. Early in the 18th century, Abraham Darby in Shropshire discovered a method of converting coal to coke as a source of carbon. This led to the modern blast furnace. In the mid-19th century, Henry Bessemer developed a steel-making process that used oxygen to burn off some of the carbon in cast iron. The Basic Oxygen Steelmaking process was introduced in the 1950s and now accounts for about two-thirds of steel production. Did you know? Stainless steel contains about 18% chromium. About three-quarters of food and drinks cans are made of steel. A car tyre contains over ½ kg of steel wire. About 400 million tonnes of steel are recycled every year worldwide. Iron and Steel: Introduction | 1 . -
ARCHAEOLOGY DATASHEET 302 Steelmaking
ARCHAEOLOGY DATASHEET 302 Steelmaking Introduction A single forging produced ‘shear steel’, a second operation Although an important aspect of medieval and earlier resulted in ‘double shear steel’ and so-on. societies, the manufacture of steel was industrialised during Furnace design changed over time, and also appears to the post-medieval period. Many complementary techniques have shown some regional variation. The first English steel were developed which often operated at the same time on furnaces were built at Coalbrookdale (Shropshire) by Sir the same site; there were also close links with other Basil Brooke in c1615 and c1630. These were circular in ironworking processes. This datasheet describes pre-20th plan with a central flue. They probably contained a single century steelmaking processes in the UK, their material chest and would have had a conical chimney. Other 17th- remains and metallurgical potential. century cementation furnaces were located in and around Birmingham, Wolverhampton, Stourbridge and Bristol, but Carbon steel and other alloys none of these have been excavated. The north-east became Until the late 19th century, steel was, like other types of the main area of cementation steelmaking in the late 17th iron, simply an alloy of iron and carbon (HMS datasheet and early 18th centuries. Ambrose Crowley established 201). There was considerable variation in the nature of several cementation steelworks, and others followed. Of ‘steel’ and in the properties of individual artefacts. Cast these, the oldest standing structure is at Derwentcote iron, smelted in the blast furnace usually had a carbon (County Durham), built in 1734. Unlike the West Midlands content of 5-8%, making it tough but brittle. -
Refractory Coatings for Containment of Molten Reactive Metals and Their Alloys
REFRACTORY COATINGS FOR CONTAINMENT OF MOLTEN REACTIVE METALS AND THEIR ALLOYS Hui Su B.E. Northeast University of Technology, Shenyang, China, 1984 M.E. Northeast University of Technology, Shenyang, China, 1987 A dissertation submitted to the faculty of the Oregon Graduate Institute of Science & Technology in partial fulfillment of the requirements for the degree Doctor of Philosophy in Materials Science October 1996 The Dissertation "Refractory Coatings for Containment of Molten Reactive Metals and Their Alloys" by Hui Su has been examined and approved by following Examination Committee: Milton R. Scholl, ~hesisAdvisor Assistant Professor James T. ~tanle~;~hesi;p".&r . President, Material Soft ,& David G. Atteridge Professor - - Jack H. Devletian Professor ACKNOWLEDGMENT I would like to express my sincerest appreciation to my thesis advisors, Dr. Milton Scholl and Dr. James T. Stanley, for their guidance, support and patience through this work. I also wish to thank the other members of my dissertation committee, Dr. David Atteridge and Dr. Jack H. Devletian for their time and effort spent as committee members and examining my dissertation and sharing their professional opinions. I am grateful to Dr. Don Mc Murchie for his invaluable help in the plasma spraying laboratory. I would also like to acknowledge Dr. Jack Mccarthy and Mr. Steven Brooks for their help and cooperation in SEM and TEM analysis and melting experiments. I would like to express my appreciation to Dr. Paul Clayton, my four year SPC chairman, for his invaluable advice and help in my course curriculum. I also would like to thank Department Head Dr. Bill Wood for his help, especially for the final year financial support. -
Studies of NRIM Continuous Steelmaking Process*
UDC 669.18-932 Studies of NRIM Continuous Steelmaking Process* By Ry uichi NAKAGAWA:* S hiro YOS HIMATSU:* Taklly a UEDA:* Tatsllro M ITSUI, ** Akira FUKUZA WA:* A kira S ATO:* and TS llyoshi OZAKI** Synopsis K.)U- 13) The fundamental aspect q! the development of the NRIM multi-stage (2) Tank type continuous steelmaking process at trough type continuous steelmaking process and the results of its recent IRSID (France )14- 16) operations are presented in this jJaper. Though the scale of the plant used (3) Single stage trough type continuous steel was small (7.8 tlhr in hot metal flow rate), a suitable sejJaration of the making process (WORCRA process) at CRA (Austral steelmaking reactions to each stage of the continuous steelmaking furnace ia)17 - 20) and the know-how qf its ojJeration were satiifactorily obtained. As the (4) Single stage trough type continuous steel result of the separation, that is, silicon and phosphorus were mostly removed making process at Bethlehem Steel Co. (U.S.A. )21) in the first stage so that the final carbon level was controlled mainly in the second stage, the product with phosphorus as low as 0.005% (dephosjJhori (5) Single stage multi-chamber type continuous z ation rate 96% ) was obtained with comparable amount of lime to that steelmaking process at MISiS (U.S.S.R.)22) of the conventional batch type steelmaking processes. The industrializ a (6) Multi-stage trough type continuous steelmak tion of this process is confirmed to be feasible. ing process at NRIM (Japan)23- 34) In NRIM the research on the continuous steelmak I. -
Effective Method for Preparing Low-Oxygen Titanium Ingot By
[Research Paper] 대한금속 · 재료학회지 (Korean J. Met. Mater.), Vol. 59, No. 3 (2021) pp.149-154 DOI: 10.3365/KJMM.2021.59.3.149 Effective Method for Preparing Low-Oxygen Titanium Ingot by Combined Powder Deoxidation and Vacuum Arc Melting Processes Jung-Min Oh1, Jaeyeol Yang2, Jaesik Yoon2, and Jae-Won Lim1,* 1Division of Advanced Materials Engineering and Research Center for Advanced Materials Development, College of Engineering, Jeonbuk National University, Jeonju 54896, Republic of Korea 2Division of Earth and Environmental Science, Korea Basic Science Institute, Cheongju 28119, Republic of Korea Abstract: In this study, an effective method is demonstrated for fabricating titanium sputtering targets, which are used to fabricate thin films in the semiconductor industry. The method is an alternative to the existing electron beam melting (EBM) process under high vacuum. Titanium sputtering targets used in the production of semiconductors must have very low concentrations of gaseous impurities, especially oxygen, as well as metal impurities. Currently, the oxygen concentration in titanium sputtering targets used for industrial purposes is less than 400 ppm. To develop an effective alternative method, powder metallurgy and melting processes were performed to prepare a low-oxygen titanium ingot with less than 400 ppm oxygen. First, titanium powder was deoxidized using calcium vapor, and then the powder was subjected to vacuum arc melting (VAM). The oxygen in the titanium powder was reduced with calcium vapor from an initial concentration of 2200 ppm to 800 ppm, and the resulting powder was melted using VAM, resulting in titanium ingots with low oxygen content, 400 ppm or less. It was also confirmed that all lattice constants, i.e., d, a, c, and c/a, decreased as oxygen concentration decreased in both the titanium powder and the ingots. -
Yields of Rare Earths in the Process of Smelting Steels by Magnesia Crucible
Advances in Engineering Research, volume 120 International Forum on Energy, Environment Science and Materials (IFEESM 2017) Yields of rare earths in the process of smelting steels by magnesia crucible Ya-Bo Li 1,2, a, Ji-Peng Zhao 2,b and Shao-kang Liu3,c 1School of Materials Science and Engineering, Jiangsu University, Zhenjiang, China 2 Tongyu Heavy Industry Co., Ltd., Yucheng, China 3Jiangsu Yonggang Group Co., Ltd, Zhangjiagang, China [email protected], [email protected], [email protected] Keywords: lanthanum; cerium; magnesia crucible; inclusion; liquid steel Abstract. Two types of steels containing rare earths (RE) were smelted by the vacuum induction furnace with magnesia crucible, RE metals were added in liquid steel at the end of the smelting process, chemical compositions of the test steels were analyzed, and inclusions were observed by scanning electron microscope with energy dispersive spectrometer. The experimental results show that the yields of RE have no direct relationship with the oxygen and sulphur contents, but decrease with the increasing of RE addition amounts. The reaction between RE and MgO (the material of the crucible) is the major RE consumption mode, parts of the outer refractory are peeled off and become inclusions in the test steels. Because of the excessively active chemical properties, rare earths trend to react with refractory materials and metallurgical slag. Therefore, it is very difficult to utilize RE in the industrial production processes with con-casting, adding RE in the non-slag and non-refractory special processes may be feasible. Introduction Many beneficial functions of rare earths in ferrous materials were found, such as liquid steel deeply cleaning, inclusions modifying, solidification structure improving, and micro-alloying [1-3]. -
Thermodynamic and Kinetic Simulation of Y2o3 and Y2s3 Nonmetallic Phase Formation in Liquid Steel
J. Min. Metall. Sect. B-Metall., 56 (1) (2020) 11-25 Journal of Mining and Metallurgy, Section B: Metallurgy TherModynaMIc and kIneTIc SIMulaTIon of y2o3 and y2S3 nonMeTallIc phaSe forMaTIon In lIquId STeel S. Gerasin, d. kalisz *, J. Iwanciw * AGH University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland (Received 26 March 2019; accepted 30 August 2019) Abstract The current work deals with the phenomenon of non-metallic inclusions as a result of the addition of yttrium to the liquid steel as an alloying component. The order of introducing individual components determines their final content in steel, and this problem was analyzed using the WYK_Stal program developed at AGH. The study of Y2O3 and Y2S3 phase precipitation and the relationship between the addition of Y, Al, Ca, O, and S in molten steel was studied using the thermodynamic models based on Wagner’s formalism. The introductions of yttrium prior to aluminum brought about huge losses, and it mainly occurred due to the formation of oxides. The low oxygen content in the metal bath promotes the formation of yttrium sulphide. When yttrium is introduced after aluminum and calcium, yttrium is used for the precipitation of its sulfide, and in this way the manganese sulfide formation is reduced. Keywords: Yttrium; Non-metallic precipitate; Steel; Computer simulation 1. Introduction A much more advanced solution is represented by the quasichemical model. The following example shows The non-metallic phase being formed in liquid steel a model for a three-component system, e.g. AOx-BOy- during its deoxidization mainly consists of iron oxides, CO2, where it analyzes formation of pairs of atoms, i.e.