HYDROGEN TECHNOLOGY STATE of the ART Andrew J
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HYDROGEN TECHNOLOGY STATE OF THE ART Andrew J. Pimm, Junfeng Yang, Katarina Widjaja & Tim T. Cockerill SEPTEMBER 2019 Contents Nomenclature ............................................................................................................. 3 1 Introduction ......................................................................................................... 4 1.1 Current Interest in Hydrogen ......................................................................... 4 1.2 Realising the Potential .................................................................................. 4 1.3 Transitioning to Hydrogen ............................................................................. 4 1.4 Aims and Objectives ..................................................................................... 5 2 Hydrogen Production .......................................................................................... 6 2.1 Steam Methane Reforming ........................................................................... 6 2.2 Electrolysis .................................................................................................... 8 2.3 Gasification of Coal, Biomass and Waste ................................................... 10 3 Hydrogen Projects for Domestic and Industrial Use .......................................... 11 4 Hydrogen Applications in Transport .................................................................. 15 4.1 Hydrogen Refuelling Stations ...................................................................... 17 5 Hydrogen Transportation Methods .................................................................... 18 5.1 Liquid and Gaseous Hydrogen – Truck Transport ....................................... 18 5.2 Gaseous Hydrogen – Pipeline Transport .................................................... 20 5.3 Ship and Rail Transport .............................................................................. 22 6 Hydrogen Storage ............................................................................................. 23 6.1 Cavern Storage ........................................................................................... 23 6.2 Tank Storage ............................................................................................... 27 7 Greenhouse Gas Emissions from Hydrogen ..................................................... 29 8 Energy System Integration of Hydrogen in the UK ............................................ 31 8.1 Questions and Challenges .......................................................................... 31 8.2 Quantities of Hydrogen Required for Applications ....................................... 31 8.3 Interactions with Other Energy Vectors and Resources .............................. 34 8.4 Managing the Transition .............................................................................. 35 9 Conclusions and Key Challenges ...................................................................... 39 References ............................................................................................................... 40 2 Nomenclature AGN Australian Gas Networks ATR Autothermal Reforming CAES Compressed Air Energy Storage CCS Carbon Capture and Storage CHP Combined Heat and Power FCEV Fuel Cell Electric Vehicle FCH JU Fuel Cells and Hydrogen Joint Undertaking GHG Greenhouse Gas HGV Heavy Goods Vehicle ICE Internal Combustion Engine IMRP Iron Mains Replacement Program LPG Liquefied Petroleum Gas NG Natural Gas PEM Polymer Electrolyte Membrane SGT Siemens Gas Turbine SMR Steam Methane Reforming SOE Solid Oxide Electrolysis 3 1 Introduction 1.1 Current Interest in Hydrogen The potential of hydrogen as a vector for low carbon energy has been apparent for many years, but it has only recently been recognised as offering a convincing pathway for the decarbonisation of the heating, transport and industrial sectors. Interest from UK policy makers has grown rapidly over the last 2-3 years, partly due to a realisation that wholesale electrification would require transformation of the electricity industry. In addition, recent announcements [1] of an intention to move to a zero net carbon economy will necessitate a large decommissioning of natural gas systems over the next 30 years, providing a 'window of opportunity' for the substitution of sustainably produced hydrogen. 1.2 Realising the Potential Realising hydrogen's unquestionable potential represents a formidable challenge, because it currently plays an almost insignificant role in the energy sector. This contrasts with some alternatives, such as electrification and bioenergy, which already have significant supply chains and industrial eco-systems in place. Given the poorly developed status of hydrogen, it may superficially appear more attractive to scale-up these alternative vectors rather than develop a set of new technologies. However there are significant constraints on all the alternatives. Indigenous bioenergy supplies are intrinsically limited, and if imported, may have substantial environmental impacts. Full electrification would require roughly 3-fold increase in low-carbon generation capacity, representing a policy challenge of the same order of magnitude as deploying hydrogen in place of natural gas. For these reasons the challenge of hydrogen deployment is worth exploring further, for now at least, while recognising that some current fossil energy demands may be more effectively satisfied by other sustainable sources. 1.3 Transitioning to Hydrogen Smoothly transitioning to an energy sector that fully embodies hydrogen will require a clear understanding of those applications to which it is well-suited and equally of those to which it is not. A "whole systems" approach is vital therefore, as developing this understanding touches on the nature of those applications and the characteristics of other sustainable sources. More widely, the feasibility of any transition plan depends on the time required, and existence of the appropriate expertise, to develop the necessary suite of technologies; the existence of appropriate manufacturing capabilities within the economy; the development of a workforce with specialist trade skills and the deployment of infrastructure systems. In these respects, hydrogen represents primarily an integrational, rather than a fundamental challenge. Most of the low-TRL fundamentals are well understood, with respect to the physical and chemical properties of the gas, as well as its combustion behaviour and its interactions with a wide range of materials. A large array of 4 engineering research and design expertise is readily available for the development of new technologies, with much tacit-knowledge that can be carried over from the fossil based energy, process and other industries. However at the moment sustainable hydrogen is not available at a scale, there is no distribution infrastructure, and apart from some industrial niches, application technologies are only available in proof-of- concept forms. The real challenge therefore is to facilitate this 'integrational transition' by developing the key elements of a large scale hydrogen eco-system with low associated greenhouse gas (GHG) emissions. 1.4 Aims and Objectives The aims of this document therefore is to briefly review the current ‘state of the art’ across most essential technical components of the hydrogen ecosystem, in support of the Round 1 Strength In Places “Developing the UK Hydrogen Corridor (H2CORE)” proposal. Our review begins by looking at techniques for hydrogen production. Sections 3 and 4 consider end users, covering applications in industry, domestic and transport contexts. Connecting producers and users will be discussed in the next two sections, which look at transmission and storage. The final two main sections introduce a wider perspective by summarising the current understanding of GHG emissions from hydrogen energy systems, as well as approaches for integration into the energy system at scale. 5 2 Hydrogen Production Globally around 70 Mt of dedicated hydrogen is produced annually, 76% from natural gas and almost all of the rest (23%) from coal [2]. Because it readily forms covalent compounds with most non-metallic elements, only tiny amounts of hydrogen exist as a gas in the Earth’s atmosphere (less than 1 part per million by volume). Instead, it exists naturally in water (H2O) and natural gas (CH4), so the main approaches to producing large quantities of hydrogen rely on these resources. Gas reforming takes natural gas and extracts the hydrogen, leaving a carbon waste stream that, for low- carbon hydrogen production, must be stored through carbon capture and storage (CCS). Electrolysis uses electricity to separate hydrogen from water, leaving oxygen that can either be used elsewhere or vented to atmosphere. Hydrogen can also be produced through gasification of coal, biomass, and waste, whereby heat is applied to produce a hydrogen-rich syngas, from which the hydrogen may be separated. 2.1 Steam Methane Reforming Steam methane reforming (SMR) is the most mature hydrogen production process, having been used commercially for many decades. It involves a catalytic conversion of methane to hydrogen and carbon dioxide, and consists of a steam reforming step, in which methane is reacted with steam at high temperature to produce carbon monoxide and hydrogen, followed by a water-gas shift reaction, where carbon monoxide is reacted with steam to produce carbon dioxide and more hydrogen. Finally, a pressure