Membrane Separation Fundamentals and Applications Dr. Andre R. Da Costa ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

CM4990/CM5900 Course Syllabus ​ ​​ ​ ​ Separation Fundamentals and Applications ​ ​ ​ ​ ​ ​ ​ ​ Curricular Designation: Elective ​ ​

Catalogue Description: ​ ​ Membrane technology provides the process industries with novel methods of separation for purification, effluent control, water reuse and recovery of valuable components in applications ranging from chemical/petrochemical to environmental and . Membrane often lead to process intensification and are building blocks to address the grand societal challenges of energy, water, food, health and climate change, i.e. sustainability. This course will enable students to understand and solve membrane-based separation problems by acquiring in-depth knowledge in membrane processes/separation mechanisms, transport models, membrane permeability computations, membrane types, properties and modules, membrane reactors, system design, industrial applications and economics. ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Credits: 3.0 Semesters Offered: Spring ​ ​ ​ ​ ​ ​

Pre-Requisites for CM4990: ​ ​ ​ ​ Undergraduate Senior: Students must be enrolled or have completed the following courses, depending on their major: ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ – CM3120 Transport/Unit Operations 2 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Environmental Engineering - CEE4502 Principles & Design ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Biomedical Engineering - ENG3200 Thermo Fluids ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Mechanical Engineering - MEEM 3201 - Introductory Fluid Mechanics & Heat Transfer ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Materials Science & Engineering – MY3110 Materials Processing II ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Level: Undergraduate Senior and Graduate (Chemical, Environmental, Biomedical, Mechanical and Materials Science & Engineering) ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Textbook (Required): ​ ​ 1

Membrane Separation Fundamentals and Applications Dr. Andre R. Da Costa ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

rd Richard W. Baker, “Membrane Technology and Applications”, 3 ​ edition, John Wiley & Sons, Ltd, United Kingdom, 2012 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Other References (Optional): ​ ​ ​ ​ W. S. Winston Ho and Kamalesh K. Sirkar (Editors), “Membrane Handbook”, Chapman & Hall, Ney York, 1992 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Norman N. Li, Anthony G. Fane, W.S. Winston Ho and Takeshi Matsuura, (Editors), “Advanced Membrane Technology”, John Wiley & ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Sons, Inc., New Jersey, 2008 ​ ​ ​ ​ ​ ​ ​ ​

Marcel Mulder, “Basic Principles of Membrane Technology”, Kluwer Academic Publishers, 1996 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Journal of Membrane Science, Industrial & Engineering Chemistry Research, AIChE Journal, , Biotechnology Progress, ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​​ ​ ​ ​ ​ ​ LAMGMUIR, Separation science and Technology ​ ​​ ​ ​ ​ ​ ​ ​ ​

Course Objectives: ​ ​

● Acquire in-depth knowledge in the areas of membrane separation mechanisms, transport models, membrane permeability ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ computations, membrane types and modules, membrane contactors / reactors and applications. ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ● Develop skills in applying transport models for the calculation of membrane permeability, flux, and the extent of separation for ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ various membrane separation systems. ​ ​ ​ ​ ​ ​ ● Be able to determine the types of experimental data needed for the calculation of membrane permeability parameters. ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ● To be able to calculate membrane process performance and analyze membrane separation characteristics ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ● Be able to select membrane processes for solving separation problems in the following applications: ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ o Water and Wastewater ​ ​ ​ ​ o Biotechnology and Biomedical Engineering ​ ​ ​ ​ ​ ​ o Gas Separations ​ ​ o Membrane Contactors and Reactors ​ ​ ​ ​ ​ ​ o Environmental and Energy ​ ​​ ​ ​ ​

Topics Covered: ​ ​

1. Overview of Membrane Science and Technology ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 1.1. Historical Development of ​ ​ ​ ​ ​ ​ ​ ​ 2

Membrane Separation Fundamentals and Applications Dr. Andre R. Da Costa ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

1.2. Types of Membranes ​ ​ ​ ​ 1.3. Membrane Processes ​ ​ 2. Membrane Transport Theory ​ ​ ​ ​ 2.1. The - Model ​ ​ ​ ​ ​ ​ 2.2. Structure-Permeability Relationships in Solution-Diffusion Membranes ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 2.3. Pore-Flow Membranes ​ ​ ​ ​ 3. Membranes and Modules ​ ​ ​ ​ 3.1. Isotropic Membranes ​ ​ ​ ​ 3.2. Anisotropic Membranes ​ ​ ​ ​ 3.3. Inorganic Membranes ​ ​ ​ ​ 3.4. Liquid Membranes ​ ​ ​ ​ 3.5. Hollow Fiber Membranes ​ ​ ​ ​ ​ ​ 3.6. Membrane Modules ​ ​ ​ ​ 4. Concentration Polarization and ​ ​ ​ ​ ​ ​ 4.1. Concentration Polarization in Liquid Separation Processes ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 4.2. Gel Layer Model ​ ​ ​ ​ ​ ​ 4.3. Osmotic Pressure Model ​ ​ ​ ​ ​ ​ 4.4. Boundary Layer Resistance Model ​ ​ ​ ​ ​ ​ ​ ​ 4.5. Concentration Polarization in Gas Separation Processes ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 4.6. ​ ​ ​ ​ 4.7. Fouling Control ​ ​ ​ ​ 5. Membrane Processes: Theory, System Design, Applications and Economics ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 5.1. , Pressure-Retarded Osmosis and ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 5.2. ​ ​ 5.3. ​ ​ 5.4. Gas Separation ​ ​ ​ ​ 5.5. Pervaporation ​ ​ 5.6. Ion Exchange Membrane Processes ​ ​ ​ ​ ​ ​ ​ ​ 5.6.1. 5.6.2. Membranes ​ ​ ​ ​ 5.6.3. Membranes in Chlor-Alkali Processes ​ ​ ​ ​ ​ ​ 5.7. Membrane Contactors ​ ​ ​ ​ 3

Membrane Separation Fundamentals and Applications Dr. Andre R. Da Costa ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

5.8. Membrane ​ ​ 5.9. Membrane Reactors and Membrane Bioreactors ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 5.10. Carrier Facilitated Transport ​ ​ ​ ​ ​ ​ 5.11. Submerged Membranes ​ ​ 5.12. Medical Applications of Membranes ​ ​ ​ ​ ​ ​

Course Times: MWF 1-2pm or 3-4pm (Lecture 3 hours/week for 14 weeks) ​ ​ ​ ​ ​ ​​ ​ ​ ​ ​ ​ ​​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Location: TBD ​ ​

Website: Canvas ​ ​

Contribution of Course to Curriculum: Engineering ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Instructor: Dr. Andre R. Da Costa, Professor and Herbert H. Dow Chair in Chemical Process Safety ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Office: 202F Chemical Sciences and Engineering Building; Phone: 906-487-3576; E-mail: [email protected] ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​​ Office Hours: By Appointment ​ ​ ​ ​ ​ ​

Grading:

Homework / Project: 20% ​ ​ ​ ​ Mid-term Exam I (Late February): 25% ​ ​ ​ ​ ​ ​ ​ ​ Mid-term Exam II (Early April): 25% ​ ​ ​ ​ ​ ​ ​ ​ Final Exam (Late April): 30% ​ ​ ​ ​ ​ ​

Letter Grades will be assigned following this schedule: ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 92-100% A 70-74% C 85-91% AB 65-69% CD 80-84% B 60-64% D 75-79% BC <60% F

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Membrane Separation Fundamentals and Applications Dr. Andre R. Da Costa ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

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Membrane Separation Fundamentals and Applications Dr. Andre R. Da Costa ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Course Assignments ​ ​

Read the Chapter Sections assigned for the day BEFORE coming to class for best results ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Week Date Topics Chapter.Sectio Assignments n (Baker) Monday January 15, 2018 Martin Luther King Jr. Day ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 1 Wednesday January 17, 2018 Overview: Types of Membranes and Processes 1.1-1.3 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Friday January 19, 2018 The Solution-Diffusion Model 2.1, 2.2 HW1 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday January 22, 2018 The Solution-Diffusion Model 2.1, 2.2 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 2 Wednesday January 24, 2018 Structure-Permeability Relationships 2.3 ​ ​ ​ ​ ​ ​ ​ ​ Friday January 26, 2018 Pore Flow Membranes 2.4 HW2 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday January 29, 2018 Isotropic and Anisotropic Membranes 3.1-3.3 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 3 Wednesday January 31, 2018 Isotropic and Anisotropic Membranes 3.1-3.3 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Friday February 2, 2018 Inorganic, Liquid and Hollow Fiber Membranes 3.4-3.6 HW3 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday February 5, 2018 Membrane Modules 3.7-3.9 ​ ​ ​ ​ ​ ​ ​ ​ 4 Wednesday February 7, 2018 Membrane Modules 3.7-3.9 ​ ​ ​ ​ ​ ​ ​ ​ Friday February 9, 2018 Class Cancelled: Winter Carnival Recess ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday February 12, 2017 Concentration Polarization & Mass Transfer Models 4 + Handout ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 5 Wednesday February 14, 2018 Concentration Polarization & Mass Transfer Models 4 + Handout ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Friday February 16, 2018 Membrane Fouling and Fouling Control Handout HW4 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday February 19, 2018 Reverse Osmosis and Pressure-Retarded Osmosis 5, 13.8 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​​ ​ 6 Wednesday February 21, 2018 Nanofiltration 5, 13.8 ​ ​ ​ ​ ​ ​ ​ ​​ ​ Friday February 23, 2018 Review for Midterm Exam 1 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday February 26, 2018 Midterm Exam 1, Class Cancelled ​ ​ ​ ​ ​ ​ ​ ​​ ​ ​ ​ ​ ​ ​ ​ ​ 7 Wednesday February 28, 2018 Ultrafiltration 6 ​ ​ ​ ​ ​ ​ Friday March 2, 2018 Ultrafiltration 6 HW5 ​ ​ ​ ​ ​ ​

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Membrane Separation Fundamentals and Applications Dr. Andre R. Da Costa ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Monday March 5, 2018 Microfiltration 7 ​ ​ ​ ​ ​ ​ 8 Wednesday March 7, 2018 Gas Separation 8 ​ ​ ​ ​ ​ ​ ​ ​ Friday March 9, 2018 Gas Separation 8 ​ ​ ​ ​ ​ ​ ​ ​ Break March 12 - 16, 2018 No Classes. Spring Break No ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Assignments Monday March 19, 2018 Pervaporation 9 ​ ​ ​ ​ ​ ​ 9 Wednesday March 21, 2018 Work Homework Problems in Class ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Friday March 23, 2018 Electrodialysis 10.1-10.5 HW6 ​ ​ ​ ​ ​ ​ Monday March 26, 2018 Fuel Cell Membranes & Chlor-Alkali Processes 10.6-10.8 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 10 Wednesday March 28, 2018 Membrane Contactors 13.5+Handout ​ ​ ​ ​ ​ ​ ​ ​ Friday March 30, 2018 Membrane Contactors 13.5+Handout HW7 ​ ​ ​ ​ ​ ​ ​ ​ Monday April 2, 2018 13.5+Handout HW7 ​ ​ ​ ​ ​ ​ ​ ​ 11 Wednesday April 4, 2018 Membrane Reactors and Membrane Bioreactors 13.6+Handout HW7 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Friday April 6, 2018 Membrane Bioreactors and Submerged Membranes 13.6+Handout HW8 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday April 9, 2018 Review for Midterm Exam 2 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 12 Wednesday April 11, 2018 Midterm Exam 2, Class Cancelled ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Friday April 13, 2018 Carrier Facilitated Transport 11 HW9 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday April 16, 2018 Carrier Facilitated Transport 11 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 13 Wednesday April 18, 2018 Medical Applications of Membranes 6.6.2+Handout ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Friday April 20, 2018 Medical Applications of Membranes 12 HW10 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Monday April 23, 2018 Analysis of Aspen Plus Membrane Simulation 12 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ 14 Wednesday April 25, 2018 Review Lab Membrane Unit Operation Handout ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Friday April 27, 2018 Review for Final Exam ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Finals April 30 – May 4, 2018 Final Exam ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

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Membrane Separation Fundamentals and Applications Dr. Andre R. Da Costa ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Relationship of Course to Program Outcomes ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ Outcome Contribution a) An ability to apply knowledge of mathematics, basic science and engineering science Substantial ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ b) An ability to design and conduct experiments as well as to analyze and interpret data Moderate ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ c) An ability to design a system, component or process to meet needs within realistic constraints Substantial ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ d) An ability to function on multidisciplinary teams Minimal ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ e) An ability to identify, formulate, and solve engineering problems Substantial ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ f) An understanding of professional and ethical responsibility Moderate ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ g) An ability to communicate effectively Minimal ​ ​ ​ ​ ​ ​ ​ ​ h) The broad education necessary to understand the impact of engineering solutions in a global, Substantial ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ economic, environmental, and social context. ​ ​ ​ ​ ​ ​ ​ ​ i) A recognition of the need for, and the ability to engage in lifelong learning Minimal ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ j) A knowledge of contemporary issues Moderate ​ ​ ​ ​ ​ ​ ​ ​ k) An ability to use the techniques, skills, and modern engineering tools necessary for engineering Substantial ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ practice

Prepared by: Dr. Andre R. Da Costa September 15, 2017 ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

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