Chapter 7. the Translation Operator and Momentum
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7. Translation and Momentum, October 9, 2013 1 Chapter 7. The Translation Operator and Momentum §1 Introduction §2 The commutator of position and momentum operators §3 Momentum and translation §4 An outline of what is to follow §5 The translation operator:definition and properties §6 The commutator [ˆx, Gˆ] §7 The evaluation of x pˆ ψ h | | i §8 The energy (Hamiltonian) operator §9 Generalization of translation and momentum operators to three dimensions §10 The energy eigenvalue equation in three dimensions §11 The case of many particles §12 How do we use these? §13 A historical note § 1 Introduction. Our work so far dealt with kinematics. This is very simple in classical mechanics: you define the state by specifying the position and the velocity of each particle. You add to this Newton’s equation and the dynamics is completed. All the rest consists of rewriting Newton equation in a variety of forms. Everything you learned so far has to do with the kinematics of quantum mechanics, which is obviously more complicated than classical kinematics. You know how to describe the state of a system but you do not know how to calculate what the states are and how they evolve in time, because we 7. Translation and Momentum, October 9, 2013 2 do not have explicit, computable expressions for the operators. If we had such expressions we could solve the eigenvalue problems for the operators and obtain the pure states. We are in this situation because we do not have a dynamical law that would do for quantum mechanics what Newton’s law does for classical physics. This chapter introduces such a dynamical law, which consists of an ex- pression for the commutator of the coordinate operator with the momentum operator. This can be used to find a formula for the momentum operator in coordinate representation. We already know the expression for the potential energy operator in coordinate representation. Once we have an expression for momentum we know the kinetic energy and therefore we can write an expression for the total energy (the Hamiltonian). Since all observable can be expressed in terms of position and momentum we can calculate anything we can measure. To derive an expression for the momentum operator we use its connection to the operation of translation. To do this we will spend quite a bit of time defining a translation operator and studying its properties. As a result we derive the relationship h¯ ∂ x pˆ ψ = x ψ (1) h | | i i ∂xh | i This allows us to turn abstract operator eigenvalue problems into eigenvalue problems for explicitly defined differential operators. § 2 The commutator of position and momentum operators. We follow here Dirac and formulate the dynamic law in terms of position and momentum operators. Both quantities are vectors. In what follows we use Cartesian 7. Translation and Momentum, October 9, 2013 3 coordinates, and r1(α) is the x-component of the position vector of particle α, r2(α) is the y-component, and r3(α) is the z-component. The x-, y- and z-components of the momentum operator of the particle α (in Cartesian coordinates) are p1(α), p2(α)and p3(α), respectively. The commutation rules for these operators are given below for a system of N particles. 1. All the components of the position operators, for all particles, commute with each other: [~rˆi(α), ~rˆj (β)]= 0 for i, j = 1, 2, 3 and α, β = 1, 2,...,N (2) 2. All components of the momentum operators, for all particles, commute with each other: ˆ ˆ [~pi(α), ~pj(β)]=0 for i, j = 1, 2, 3 and α, β = 1, 2,...,N (3) 3. Momentum and position operators commute if they refer to different Cartesian components or to different particles. 4. The position and momentum operators do not commute if they refer to the same Cartesian component of the same particle, in which case the commutator is equal to i¯hIˆ where Iˆ is the unit operator. 5. These statements are summarized by the equation [ˆri(α), pˆj (β)] = i¯hδij δαβIˆ for i, j = 1, 2, 3 and α, β = 1, 2,...,N (4) where Iˆ is the unit operator. We can simplify Eq. 4 to state that [ˆri(α), pˆi(α)] = i¯hIˆ for i = 1, 2, 3 and α = 1, 2,...,N (5) 7. Translation and Momentum, October 9, 2013 4 and all other commutators are zero. In this chapter we use Eqs. 2–4 to derive an expression for the momentum operator in the coordinate representation. Once we do this, we can derive expressions for operators representing any observable. § 3 Momentum and translation. The idea for the procedure by which we find an equation for momentum has its origin in classical mechanics. It is based on the obvious observation that if the forces acting on a system do not depend on the location of the system (i.e. the space is uniform), the same experiment performed in two different regions of space must give the same result. Saying that the experiments are identical but they are performed in different places means that one experiment can be replicated by translating the other. One can easily prove, by using Newton’s equation, that this statement leads to momentum conservation. This is a simple incarnation of a general theorem, due to Emmy Noether1, which connects all conserved quantities in mechanics (and other branches of physics) to transformations that change the look of the equations but do not change the physics of the system. The fact that identical experiments performed here and performed there must give identical results, leads to conservation of linear momentum. The fact that in the absence of a torque in an experiment does not change if it is described by a 1Noether’s career is a heart-breaking example of irrational discrimination against a woman of great talent who did excellent mathematics while working unpaid in G¨ottingen. Hilbert and Klein wanted to hire her onto the faculty, but the appointment was vetoed by the humanities professors. The reason: the presence of a woman would be too disruptive. Never mind that she was already present and the university seemed to survive the disrup- tion. After Hitler came to power she emigrated to the United States and worked at Bryn Mawr College where she was much appreciated. 7. Translation and Momentum, October 9, 2013 5 coordinate system rotated with respect to another one, leads to conservation of angular momentum. The fact that an experiment done today must give the same results as the same experiment done tomorrow, leads to energy conservation. In this chapter I use the connection between momentum and translation to find a computable expression for the momentum operator in the coordinate representation. § 4 An outline of what is to follow. Here is an outline of how we use the translation operator to find out how the momentum operator acts on a pure state of position. We define a translation operator Tˆ(λ) x x + λ (6) | i≡ | i that moves a particle from a position x to a position x + λ. I will then prove that, if λ is an infinitesimal distance then iλ Tˆ(λ)= Iˆ Gˆ (λ infinitesimal) (7) − h¯ where Iˆ is the unit operator, i = √ 1, and Gˆ is a Hermitian operator defined − by Eq. 7. Gˆ is called the infinitesimal generator of translation. Next we show that the commutator ofx ˆ with Gˆ is [ˆx, Gˆ]=i¯h (8) This means that Gˆ has the same commutation relation as momentump ˆ and therefore it must be equal to it. It follows that we can write iλ Tˆ(λ)= Iˆ pˆ (λ infinitesimal) (9) − h¯ 7. Translation and Momentum, October 9, 2013 6 which implies h¯ Iˆ Tˆ(λ) pˆ = − (λ infinitesimal) (10) i λ ! Our goal is thus achieved: we know how the operators in the right-hand side of Eq. 10 act on a pure state x (see Eq. 6), therefore we know howp ˆ acts on | i x . This knowledge is exploited to derive explicit expressions forp ˆ x and | i | i for x pˆ ψ , where ψ is an arbitrary ket. Once we know this, we can write h | | i | i explicit expressions for operators representing any classical quantity of the form f(p) where f is a function and p is the momentum. We already know how to represent, in coordinate representation, opera- tors that are functions of position. This makes it possible to derive expres- sions for the operators representing the Hamiltonian H = p2/2m + V (x) or the angular momentum L~ = ~r ~p. × § 5 The translation operator:definition and properties. We already defined the translation operator Tˆ(λ) through Tˆ(λ) x = x + λ (11) | i | i Here x is a pure state of the coordinate. A particle in this state is located | i at x. The translation operator Tˆ(λ) acting on x creates a pure state x+λ | i | i in which we are certain that the particle is located at x + λ. For simplicity of notation, we work with a system consisting of one particle, moving in one dimension. Generalizing to many particles in three dimensions is straightfor- ward. For future use, we need to establish the following properties of Tˆ(λ). 7. Translation and Momentum, October 9, 2013 7 Property 1. Tˆ(λ)−1 = Tˆ( λ) (12) − Property 2. Tˆ(λ) is a unitary operator. Property 3. Tˆ(λ)† = Tˆ( λ) (13) − Property 4. If λ is arbitrarily small then iλ Tˆ(λ)= Iˆ Gˆ + (λ2) (14) − h¯ O where Gˆ is a Hermitian operator.