Bohmian Trajectories of the Two-Electron Helium Atom
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Relational Quantum Mechanics
Relational Quantum Mechanics Matteo Smerlak† September 17, 2006 †Ecole normale sup´erieure de Lyon, F-69364 Lyon, EU E-mail: [email protected] Abstract In this internship report, we present Carlo Rovelli’s relational interpretation of quantum mechanics, focusing on its historical and conceptual roots. A critical analysis of the Einstein-Podolsky-Rosen argument is then put forward, which suggests that the phenomenon of ‘quantum non-locality’ is an artifact of the orthodox interpretation, and not a physical effect. A speculative discussion of the potential import of the relational view for quantum-logic is finally proposed. Figure 0.1: Composition X, W. Kandinski (1939) 1 Acknowledgements Beyond its strictly scientific value, this Master 1 internship has been rich of encounters. Let me express hereupon my gratitude to the great people I have met. First, and foremost, I want to thank Carlo Rovelli1 for his warm welcome in Marseille, and for the unexpected trust he showed me during these six months. Thanks to his rare openness, I have had the opportunity to humbly but truly take part in active research and, what is more, to glimpse the vivid landscape of scientific creativity. One more thing: I have an immense respect for Carlo’s plainness, unaltered in spite of his renown achievements in physics. I am very grateful to Antony Valentini2, who invited me, together with Frank Hellmann, to the Perimeter Institute for Theoretical Physics, in Canada. We spent there an incredible week, meeting world-class physicists such as Lee Smolin, Jeffrey Bub or John Baez, and enthusiastic postdocs such as Etera Livine or Simone Speziale. -
The E.P.R. Paradox George Levesque
Undergraduate Review Volume 3 Article 20 2007 The E.P.R. Paradox George Levesque Follow this and additional works at: http://vc.bridgew.edu/undergrad_rev Part of the Quantum Physics Commons Recommended Citation Levesque, George (2007). The E.P.R. Paradox. Undergraduate Review, 3, 123-130. Available at: http://vc.bridgew.edu/undergrad_rev/vol3/iss1/20 This item is available as part of Virtual Commons, the open-access institutional repository of Bridgewater State University, Bridgewater, Massachusetts. Copyright © 2007 George Levesque The E.P.R. Paradox George Levesque George graduated from Bridgewater his paper intends to discuss the E.P.R. paradox and its implications State College with majors in Physics, for quantum mechanics. In order to do so, this paper will discuss the Mathematics, Criminal Justice, and features of intrinsic spin of a particle, the Stern-Gerlach experiment, Sociology. This piece is his Honors project the E.P.R. paradox itself and the views it portrays. In addition, we will for Electricity and Magnetism advised by consider where such a classical picture succeeds and, eventually, as we will see Dr. Edward Deveney. George ruminated Tin Bell’s inequality, fails in the strange world we live in – the world of quantum to help the reader formulate, and accept, mechanics. why quantum mechanics, though weird, is valid. Intrinsic Spin Intrinsic spin angular momentum is odd to describe by any normal terms. It is unlike, and often entirely unrelated to, the classical “orbital angular momentum.” But luckily we can describe the intrinsic spin by its relationship to the magnetic moment of the particle being considered. -
Solving the Schrödinger Equation for Helium Atom and Its Isoelectronic
THE JOURNAL OF CHEMICAL PHYSICS 127, 224104 ͑2007͒ Solving the Schrödinger equation for helium atom and its isoelectronic ions with the free iterative complement interaction „ICI… method ͒ Hiroyuki Nakashima and Hiroshi Nakatsujia Quantum Chemistry Research Institute, Kyodai Katsura Venture Plaza 106, Goryo Oohara 1-36, Nishikyo-ku, Kyoto 615-8245, Japan and Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan ͑Received 31 July 2007; accepted 2 October 2007; published online 11 December 2007͒ The Schrödinger equation was solved very accurately for helium atom and its isoelectronic ions ͑Z=1–10͒ with the free iterative complement interaction ͑ICI͒ method followed by the variational principle. We obtained highly accurate wave functions and energies of helium atom and its isoelectronic ions. For helium, the calculated energy was −2.903 724 377 034 119 598 311 159 245 194 404 446 696 905 37 a.u., correct over 40 digit accuracy, and for H−,itwas−0.527 751 016 544 377 196 590 814 566 747 511 383 045 02 a.u. These results prove numerically that with the free ICI method, we can calculate the solutions of the Schrödinger equation as accurately as one desires. We examined several types of scaling function g and initial function 0 of the free ICI method. The performance was good when logarithm functions were used in the initial function because the logarithm function is physically essential for three-particle collision area. The best performance was obtained when we introduce a new logarithm function containing not only r1 and r2 but also r12 in the same logarithm function. -
Many-Electron System I – Helium Atom and Pauli Exclusion Principle
Lecture 17 Many-electron System I { Helium Atom and Pauli Exclusion Principle Study Goal of This Lecture • Helium atom - many electron wavefunctions • Helium atom - variational ground state (screening) • Eigenstates of a two-spin system 17.1 Helium Atom Helium atom includes two electrons moving around a fixed nucleus with charge Z = 2, we can write down the Hamiltonian as: 2 2 2 2 ^ ~ 2 2 1 Ze Ze e H = − (r1 + r2) − ( + − ) 2me 4π0 r1 r2 r12 2 2 2 2 2 ~ 2 1 Ze ~ 2 1 Ze e = − r1 − − − r2 − + 2me 4π0 r1 2me 4π0 r2 4π0r12 (17.1) | {z } | {z } | {z } H^1 H^2 H^12 = H^1 + H^2 + H^12: 1 If H^12 = 0(or neglected) then the problem is exactly solved. Recall that for a total system composes of independent sub-systems H^T = H^1 + H^2 + ··· ; (17.2) and we can firstly solve all ^ n n n Hnφm = Emφm; (17.3) then the solution of H^T is the product states Y n = φ : (17.4) n If consider as many-electrons, i.e. H^n for the n-th electron. Then the product solu- tion is a natural "independent electron" solution. Even when the electron-electron interactions are non-zero, we will see the independent electorn approximation is a good starting point. Let's consider the Helium atom, we know: H^1φ1 = E1φ1; (17.5) H^2φ2 = E2φ2; and total E = E1 + E2. φ1; φ2 are Helium hydrogen-like atomic orbitals. We know the two ground states (neglect spin for a moment.) H^1φ1s(1) = E1sφ1s(1); (17.6) H^2φ1s(2) = E1sφ1s(2); number 1 and 2 denotes electorn 1 and electron 2 respectively. -
Bouncing Oil Droplets, De Broglie's Quantum Thermostat And
Preprints (www.preprints.org) | NOT PEER-REVIEWED | Posted: 28 August 2018 doi:10.20944/preprints201808.0475.v1 Peer-reviewed version available at Entropy 2018, 20, 780; doi:10.3390/e20100780 Article Bouncing oil droplets, de Broglie’s quantum thermostat and convergence to equilibrium Mohamed Hatifi 1, Ralph Willox 2, Samuel Colin 3 and Thomas Durt 4 1 Aix Marseille Université, CNRS, Centrale Marseille, Institut Fresnel UMR 7249,13013 Marseille, France; hatifi[email protected] 2 Graduate School of Mathematical Sciences, the University of Tokyo, 3-8-1 Komaba, Meguro-ku, 153-8914 Tokyo, Japan; [email protected] 3 Centro Brasileiro de Pesquisas Físicas, Rua Dr. Xavier Sigaud 150,22290-180, Rio de Janeiro – RJ, Brasil; [email protected] 4 Aix Marseille Université, CNRS, Centrale Marseille, Institut Fresnel UMR 7249,13013 Marseille, France; [email protected] Abstract: Recently, the properties of bouncing oil droplets, also known as ‘walkers’, have attracted much attention because they are thought to offer a gateway to a better understanding of quantum behaviour. They indeed constitute a macroscopic realization of wave-particle duality, in the sense that their trajectories are guided by a self-generated surrounding wave. The aim of this paper is to try to describe walker phenomenology in terms of de Broglie-Bohm dynamics and of a stochastic version thereof. In particular, we first study how a stochastic modification of the de Broglie pilot-wave theory, à la Nelson, affects the process of relaxation to quantum equilibrium, and we prove an H-theorem for the relaxation to quantum equilibrium under Nelson-type dynamics. -
Helium Atom, Approximate Methods
Helium Atom, Approximate Methods 22nd April 2008 I. The Helium Atom and Variational Principle: Approximation Methods for Complex Atomic Systems The hydrogen atom wavefunctions and energies, we have seen, are deter- mined as a combination of the various quantum "dynamical" analogues of classical motions (translation, vibration, rotation) and a central-force inter- action (i.e, the Coulomb interaction between an electron and a nucleus). Now, we consider the Helium atom and will see that due to the attendant 3-body problem for which we cannot determine a close-for, first-principles analytic solution, we will have to find recourse in approximate methods. The Helium atom has 2 electrons with coordinates r1 and r2 as well as a single nucleus with coordinate R. The nuclues carries a Z = +2e charge. The Schrodinger equation is: 2 2 2 h¯ 2 h¯ 2 h¯ 2 1 2 (R; r1; r2) + −2M r − 2me r − 2me r ! 2e2 2e2 e2 + (R; r ; r ) = E (R; r ; r ) −4π R r − 4π R r 4π r r 1 2 1 2 o j − 1j o j − 2j o j 1 − 2j! where the symbol "nabla", when squared, is given by: @2 @2 @2 2 = + + r @x2 @y2 @z2 Keep in mind that the R, r, and r represent the Cartesian coordinates of each paticle. This is a 3-body problem and such problems are not solved exactly. Thus, the problem will be reformulated in terms of 2 variables. The first approximations: Mme , fix the nucleous at the origin (R) = 0. Thus, the Schrodinger equation in relative variables is: 1 2 2 2 h¯ 2 2 2e 1 1 e 1 2 (r1; r2) + + (r1; r2) = E (r1; r2) 2me −∇ − r −4πo r1 r2 4πo r2 r1 j − j Recall that the 2, representing the kinetic energy operator, in spherical r polar coordinates is: 1 @ @ 1 @ @ 1 @2 r2 + sinθ + 2 @r 1 @r 2 @θ 1 @θ 2 2 2 r1 1 1 r1sinθ1 1 1 r1sin θ1 @φ1 The Independent Electron Approximation to Solving the Helium Atom Schrodinger Equation If we neglect electron-electron repulsion in the Helium atom problem, we can simplify and solve the effective 2-body problem. -
5.1 Two-Particle Systems
5.1 Two-Particle Systems We encountered a two-particle system in dealing with the addition of angular momentum. Let's treat such systems in a more formal way. The w.f. for a two-particle system must depend on the spatial coordinates of both particles as @Ψ well as t: Ψ(r1; r2; t), satisfying i~ @t = HΨ, ~2 2 ~2 2 where H = + V (r1; r2; t), −2m1r1 − 2m2r2 and d3r d3r Ψ(r ; r ; t) 2 = 1. 1 2 j 1 2 j R Iff V is independent of time, then we can separate the time and spatial variables, obtaining Ψ(r1; r2; t) = (r1; r2) exp( iEt=~), − where E is the total energy of the system. Let us now make a very fundamental assumption: that each particle occupies a one-particle e.s. [Note that this is often a poor approximation for the true many-body w.f.] The joint e.f. can then be written as the product of two one-particle e.f.'s: (r1; r2) = a(r1) b(r2). Suppose furthermore that the two particles are indistinguishable. Then, the above w.f. is not really adequate since you can't actually tell whether it's particle 1 in state a or particle 2. This indeterminacy is correctly reflected if we replace the above w.f. by (r ; r ) = a(r ) (r ) (r ) a(r ). 1 2 1 b 2 b 1 2 The `plus-or-minus' sign reflects that there are two distinct ways to accomplish this. Thus we are naturally led to consider two kinds of identical particles, which we have come to call `bosons' (+) and `fermions' ( ). -
8 the Variational Principle
8 The Variational Principle 8.1 Approximate solution of the Schroedinger equation If we can’t find an analytic solution to the Schroedinger equation, a trick known as the varia- tional principle allows us to estimate the energy of the ground state of a system. We choose an unnormalized trial function Φ(an) which depends on some variational parameters, an and minimise hΦ|Hˆ |Φi E[a ] = n hΦ|Φi with respect to those parameters. This gives an approximation to the wavefunction whose accuracy depends on the number of parameters and the clever choice of Φ(an). For more rigorous treatments, a set of basis functions with expansion coefficients an may be used. The proof is as follows, if we expand the normalised wavefunction 1/2 |φ(an)i = Φ(an)/hΦ(an)|Φ(an)i in terms of the true (unknown) eigenbasis |ii of the Hamiltonian, then its energy is X X X ˆ 2 2 E[an] = hφ|iihi|H|jihj|φi = |hφ|ii| Ei = E0 + |hφ|ii| (Ei − E0) ≥ E0 ij i i ˆ where the true (unknown) ground state of the system is defined by H|i0i = E0|i0i. The inequality 2 arises because both |hφ|ii| and (Ei − E0) must be positive. Thus the lower we can make the energy E[ai], the closer it will be to the actual ground state energy, and the closer |φi will be to |i0i. If the trial wavefunction consists of a complete basis set of orthonormal functions |χ i, each P i multiplied by ai: |φi = i ai|χii then the solution is exact and we just have the usual trick of expanding a wavefunction in a basis set. -
1 the Principle of Wave–Particle Duality: an Overview
3 1 The Principle of Wave–Particle Duality: An Overview 1.1 Introduction In the year 1900, physics entered a period of deep crisis as a number of peculiar phenomena, for which no classical explanation was possible, began to appear one after the other, starting with the famous problem of blackbody radiation. By 1923, when the “dust had settled,” it became apparent that these peculiarities had a common explanation. They revealed a novel fundamental principle of nature that wascompletelyatoddswiththeframeworkofclassicalphysics:thecelebrated principle of wave–particle duality, which can be phrased as follows. The principle of wave–particle duality: All physical entities have a dual character; they are waves and particles at the same time. Everything we used to regard as being exclusively a wave has, at the same time, a corpuscular character, while everything we thought of as strictly a particle behaves also as a wave. The relations between these two classically irreconcilable points of view—particle versus wave—are , h, E = hf p = (1.1) or, equivalently, E h f = ,= . (1.2) h p In expressions (1.1) we start off with what we traditionally considered to be solely a wave—an electromagnetic (EM) wave, for example—and we associate its wave characteristics f and (frequency and wavelength) with the corpuscular charac- teristics E and p (energy and momentum) of the corresponding particle. Conversely, in expressions (1.2), we begin with what we once regarded as purely a particle—say, an electron—and we associate its corpuscular characteristics E and p with the wave characteristics f and of the corresponding wave. -
Theoretical Physics Group Decoherent Histories Approach: a Quantum Description of Closed Systems
Theoretical Physics Group Department of Physics Decoherent Histories Approach: A Quantum Description of Closed Systems Author: Supervisor: Pak To Cheung Prof. Jonathan J. Halliwell CID: 01830314 A thesis submitted for the degree of MSc Quantum Fields and Fundamental Forces Contents 1 Introduction2 2 Mathematical Formalism9 2.1 General Idea...................................9 2.2 Operator Formulation............................. 10 2.3 Path Integral Formulation........................... 18 3 Interpretation 20 3.1 Decoherent Family............................... 20 3.1a. Logical Conclusions........................... 20 3.1b. Probabilities of Histories........................ 21 3.1c. Causality Paradox........................... 22 3.1d. Approximate Decoherence....................... 24 3.2 Incompatible Sets................................ 25 3.2a. Contradictory Conclusions....................... 25 3.2b. Logic................................... 28 3.2c. Single-Family Rule........................... 30 3.3 Quasiclassical Domains............................. 32 3.4 Many History Interpretation.......................... 34 3.5 Unknown Set Interpretation.......................... 36 4 Applications 36 4.1 EPR Paradox.................................. 36 4.2 Hydrodynamic Variables............................ 41 4.3 Arrival Time Problem............................. 43 4.4 Quantum Fields and Quantum Cosmology.................. 45 5 Summary 48 6 References 51 Appendices 56 A Boolean Algebra 56 B Derivation of Path Integral Method From Operator -
On Relational Quantum Mechanics Oscar Acosta University of Texas at El Paso, [email protected]
University of Texas at El Paso DigitalCommons@UTEP Open Access Theses & Dissertations 2010-01-01 On Relational Quantum Mechanics Oscar Acosta University of Texas at El Paso, [email protected] Follow this and additional works at: https://digitalcommons.utep.edu/open_etd Part of the Philosophy of Science Commons, and the Quantum Physics Commons Recommended Citation Acosta, Oscar, "On Relational Quantum Mechanics" (2010). Open Access Theses & Dissertations. 2621. https://digitalcommons.utep.edu/open_etd/2621 This is brought to you for free and open access by DigitalCommons@UTEP. It has been accepted for inclusion in Open Access Theses & Dissertations by an authorized administrator of DigitalCommons@UTEP. For more information, please contact [email protected]. ON RELATIONAL QUANTUM MECHANICS OSCAR ACOSTA Department of Philosophy Approved: ____________________ Juan Ferret, Ph.D., Chair ____________________ Vladik Kreinovich, Ph.D. ___________________ John McClure, Ph.D. _________________________ Patricia D. Witherspoon Ph. D Dean of the Graduate School Copyright © by Oscar Acosta 2010 ON RELATIONAL QUANTUM MECHANICS by Oscar Acosta THESIS Presented to the Faculty of the Graduate School of The University of Texas at El Paso in Partial Fulfillment of the Requirements for the Degree of MASTER OF ARTS Department of Philosophy THE UNIVERSITY OF TEXAS AT EL PASO MAY 2010 Acknowledgments I would like to express my deep felt gratitude to my advisor and mentor Dr. Ferret for his never-ending patience, his constant motivation and for not giving up on me. I would also like to thank him for introducing me to the subject of philosophy of science and hiring me as his teaching assistant. -
Path Integral Implementation of Relational Quantum Mechanics
Path Integral Implementation of Relational Quantum Mechanics Jianhao M. Yang ( [email protected] ) Qualcomm (United States) Research Article Keywords: Relational Quantum mechanics, Path Integral, Entropy, Inuence Functional Posted Date: February 18th, 2021 DOI: https://doi.org/10.21203/rs.3.rs-206217/v1 License: This work is licensed under a Creative Commons Attribution 4.0 International License. Read Full License Version of Record: A version of this preprint was published at Scientic Reports on April 21st, 2021. See the published version at https://doi.org/10.1038/s41598-021-88045-6. Path Integral Implementation of Relational Quantum Mechanics Jianhao M. Yang∗ Qualcomm, San Diego, CA 92121, USA (Dated: February 4, 2021) Relational formulation of quantum mechanics is based on the idea that relational properties among quantum systems, instead of the independent properties of a quantum system, are the most fundamental elements to construct quantum mechanics. In the recent works (J. M. Yang, Sci. Rep. 8:13305, 2018), basic relational quantum mechanics framework is formulated to derive quantum probability, Born’s Rule, Schr¨odinger Equations, and measurement theory. This paper gives a concrete implementation of the relational probability amplitude by extending the path integral formulation. The implementation not only clarifies the physical meaning of the relational probability amplitude, but also gives several important applications. For instance, the double slit experiment can be elegantly explained. A path integral representation of the reduced density matrix of the observed system can be derived. Such representation is shown valuable to describe the interaction history of the measured system and a series of measuring systems.