1 Revision 2 2 K-Bentonites: A Review 3 Warren D. Huff 4 Department of Geology, University of Cincinnati, Cincinnati, OH 45221 USA 5 Email:
[email protected] 6 Keywords: K-bentonite, bentonite, tephra, explosive volcanism, volcanic ash 7 Abstract 8 Pyroclastic material in the form of altered volcanic ash or tephra has been reported and described 9 from one or more stratigraphic units from the Proterozoic to the Tertiary. This altered tephra, 10 variously called bentonite or K-bentonite or tonstein depending on the degree of alteration and 11 chemical composition, is often linked to large explosive volcanic eruptions that have occurred 12 repeatedly in the past. K-bentonite and bentonite layers are the key components of a larger group of 13 altered tephras that are useful for stratigraphic correlation and for interpreting the geodynamic 14 evolution of our planet. Bentonites generally form by diagenetic or hydrothermal alteration under 15 the influence of fluids with high Mg content and that leach alkali elements. Smectite composition is 16 partly controlled by parent rock chemistry. Studies have shown that K-bentonites often display 17 variations in layer charge and mixed-layer clay ratios and that these correlate with physical 18 properties and diagenetic history. The following is a review of known K-bentonite and related 19 occurrences of altered tephra throughout the time scale from Precambrian to Cenozoic. 20 Introduction 21 Volcanic eruptions are often, although by no means always, associated with a profuse output 22 of fine pyroclastic material, tephra. Tephra is a term used to describe all of the solid material 23 produced from a volcano during an eruption (Thorarinsson, 1944).