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Coesite SiO2 c 2001 Data Publishing, version 1.2 ° Crystal Data: Monoclinic, pseudohexagonal. Point Group: 2=m: As irregular to nearly rectangular grains, up to 3 mm.

Physical Properties: : 010 and 012 , suspected. : Subconchoidal. Hardness = 7.5{8 D(meas.) = n.d. fD(cgalc.) =f 2.92g

Optical Properties: Transparent. Color: Colorless. Luster: Vitreous. Optical Class: Biaxial (+) (synthetic). Orientation: X = b; Z c = 4±{6±. Dispersion: r < v: ^ ® = 1.5940(5) ¯ = 1.5955(5) ° = 1.5990(5) 2V(meas.) = 64± 2V(calc.) = 66±340 Cell Data: : C2=c: a = 7.143(2) b = 12.383(3) c = 7.143(2) ¯ = 120:00(3)± Z = 16 X-ray Powder Pattern: Synthetic. (ICDD 14-654). 3.09 (100), 3.43 (30), 1.71 (12), 1.345 (12), 2.69 (10), 1.70 (10), 1.545 (10)

Chemistry: (1)

SiO2 99.56 TiO2 0.00 Al2O3 0.05 FeO 0.03 MnO 0.00 MgO 0.00

Na2O 0.04 K2O 0.00 Total 99.68

(1) Roberts Victor mine, South Africa; by electron microprobe, average of four analyses.

Polymorphism & Series: , , , and are polymorphs.

Occurrence: Formed at pressures in excess of 20 kbar, as ¯ne-grained intergrowths with quartz and silica glass in impact metamorphosed rocks and . A primary phase in grospydite (kyanite-garnet-clinopyroxene) in , and intergrown with quartz as inclusions in garnet and clinopyroxene within of high-grade metamorphic terranes.

Association: Quartz, stishovite, silica glass, kyanite, , garnet, sanidine, muscovite, talc, rutile, dolomite.

Distribution: From , Coconino Co., , USA. At the NÄordlinger Ries crater, Bavaria, Germany. In the Kara structure, Pay-Khoy, Russia. In Italy, in the Dora-Maira massif, Parigi, near Martiniana Po, Piedmont. From Grytting, Selje district, Norway. In the , Rub' al Khali, Saudi Arabia. At Dabie Mountain, west of Qianshan, Anhwei Province, China. In the Roberts Victor diamond mine, near Kimberley, Cape Province, and near Bosho®, Orange Free State, South Africa.

Name: For Loring Coes, Jr. (1915{ ), American chemist, who synthesized the material prior to the discovery of a natural occurrence.

Type Material: n.d.

References: (1) Frondel, C. (1962) Dana's system of mineralogy, (7th edition), v. III, silica , 310{316. (2) Sclar, C.B., L.C. Carrison, and C.M. Schwartz (1962) Optical crystallography of . Amer. Mineral., 47, 1292{1302. (3) Gibbs, G.V., C.T. Prewitt, and K.J. Baldwin (1977) A study of the structural chemistry of coesite. Zeits. Krist., 145, 108{123. (4) Smyth, J.R. and C.J. Hatton (1977) A coesite-sanidine grospydite from the Roberts Victor kimberlite. Earth and Planetary Science Letters, 34, 284{290. All rights reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise without the prior written permission of Mineral Data Publishing.