Early Inner Solar System Origin for Anomalous Sulfur Isotopes in Differentiated Protoplanets
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Magmatic Sulfides in the Porphyritic Chondrules of EH Enstatite Chondrites
Published in Geochimica et Cosmochimica Acta, Accepted September 2016. http://dx.doi.org/10.1016/j.gca.2016.09.010 Magmatic sulfides in the porphyritic chondrules of EH enstatite chondrites. Laurette Piani1,2*, Yves Marrocchi2, Guy Libourel3 and Laurent Tissandier2 1 Department of Natural History Sciences, Faculty of Science, Hokkaido University, Sapporo, 060-0810, Japan 2 CRPG, UMR 7358, CNRS - Université de Lorraine, 54500 Vandoeuvre-lès-Nancy, France 3 Laboratoire Lagrange, UMR7293, Université de la Côte d’Azur, CNRS, Observatoire de la Côte d’Azur,F-06304 Nice Cedex 4, France *Corresponding author: Laurette Piani ([email protected]) Abstract The nature and distribution of sulfides within 17 porphyritic chondrules of the Sahara 97096 EH3 enstatite chondrite have been studied by backscattered electron microscopy and electron microprobe in order to investigate the role of gas-melt interactions in the chondrule sulfide formation. Troilite (FeS) is systematically present and is the most abundant sulfide within the EH3 chondrite chondrules. It is found either poikilitically enclosed in low-Ca pyroxenes or scattered within the glassy mesostasis. Oldhamite (CaS) and niningerite [(Mg,Fe,Mn)S] are present in ! 60 % of the chondrules studied. While oldhamite is preferentially present in the mesostasis, niningerite associated with silica is generally observed in contact with troilite and low-Ca pyroxene. The Sahara 97096 chondrule mesostases contain high abundances of alkali and volatile elements (average Na2O = 8.7 wt.%, K2O = 0.8 wt.%, Cl = 7000 ppm and S = 3700 ppm) as well as silica (average SiO2 = 63.1 wt.%). Our data suggest that most of the sulfides found in EH3 chondrite chondrules are magmatic minerals that formed after the dissolution of S from a volatile-rich gaseous environment into the molten chondrules. -
Difficult Experiments on Weird Rocks Written by G
PSR Discoveries:Hot Idea: Enstatite Meteorites http://www.psrd.hawaii.edu/Dec99/indarch.html posted December 17, 1999 Difficult Experiments on Weird Rocks Written by G. Jeffrey Taylor Hawai'i Institute of Geophysics and Planetology Enstatite meteorites are a diverse group of strange rocks. They contain little or no oxidized iron, a rare occurrence in the Solar System. Nevertheless, melting experiments on these oxygen-depleted meteorites give clues about magma compositions and core formation in asteroids. Tim McCoy (Smithsonian Institution), Tamara Dickinson (Catholic University), and Gary Lofgren (Johnson Space Center) heated an enstatite chondrite (called Indarch) to a range of temperatures above the temperature of initial melting. They found that the sulfide minerals in the rock melted at 1000o C. This disproved a hypothesis that the calcium sulfide in the rock formed at a very high temperature in the gas-dust cloud from which the planets formed and survived melting in igneous enstatite meteorites. The experiments also indicate that the metallic iron and sulfide minerals begin to form connected networks when only about 20% of the rocky material is melted. This suggests that core formation in the asteroid could have taken place at such low amounts of melting, rather than requiring much higher amounts of melting as some scientists have argued. The experiments also show that igneous enstatite meteorites could have formed from unmelted enstatite chondrites. Reference: McCoy, Timothy J., Tamara L.Dickinson, and Gary E. Lofgren, 1999, Partial melting of the Indarch (EH4) meteorite: A textural, chemical, and phase relations view of melting and melt migration, Meteoritics and Planetary Science, vol. -
Apatite from NWA 10153 and NWA 10645—The Key to Deciphering Magmatic and Fluid Evolution History in Nakhlites
minerals Article Apatite from NWA 10153 and NWA 10645—The Key to Deciphering Magmatic and Fluid Evolution History in Nakhlites Łukasz Birski 1,*, Ewa Słaby 1, Elias Chatzitheodoridis 2, Richard Wirth 3, Katarzyna Majzner 4, Gabriela A. Kozub-Budzy ´n 5, Jiˇrí Sláma 6, Katarzyna Liszewska 1, Izabela Kocjan 7 and Anna Zagórska 7 1 Institute of Geological Sciences, Polish Academy of Sciences, Research Centre in Warsaw, Twarda 51/55, 00-818 Warsaw, Poland; [email protected] (E.S.); [email protected] (K.L.) 2 Department of Geological Sciences, School of Mining and Metallurgical Engineering, National Technical University of Athens, 9 Heroon Polytechneiou, 15780 Zografou, Athens, Greece; [email protected] 3 Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum GFZ, Telegrafenberg, 14473 Potsdam, Germany; [email protected] 4 Faculty of Chemistry, Jagiellonian University, Raman Imaging Group, Gronostajowa 2, 30-387 Cracow, Poland; [email protected] 5 Faculty of Geology, Geophysics and Environmental Protection, AGH University of Science and Technology, Mickiewicza 30, 30-059 Cracow, Poland; [email protected] 6 Institute of Geology Academy of Sciences of the Czech Republic Rozvojová 269, 165 00 Prague Czech Republic; [email protected] 7 Institute of Geological Sciences, Polish Academy of Sciences, Research Centre in Cracow, Senacka 1, 31-002 Cracow, Poland; [email protected] (I.K.); [email protected] (A.Z.) * Correspondence: [email protected] Received: 10 September 2019; Accepted: 7 November 2019; Published: 10 November 2019 Abstract: Apatites from Martian nakhlites NWA 10153 and NWA 10645 were used to obtain insight into their crystallization environment and the subsequent postcrystallization evolution path. -
Constraints on the Depth and Thermal Vigor of Melting in the Martian Mantle
PUBLICATIONS Journal of Geophysical Research: Planets RESEARCH ARTICLE Constraints on the depth and thermal vigor 10.1002/2014JE004745 of melting in the Martian mantle Key Points: Justin Filiberto1 and Rajdeep Dasgupta2 • Mantle potential temperature calculated for Gale Crater rocks 1Department of Geology, Southern Illinois University, Carbondale, Illinois, USA, 2Department of Earth Science, Rice • 1450 ± 70°C may represent global Noachian mantle temperature University, Houston, Texas, USA • Consistent with simple convective cooling of the interior of Mars Abstract Studies of rocks in Gale Crater and clasts within the Martian meteorite breccia Northwest Africa (NWA) 7034 (and paired stones) have expanded our knowledge of the diversity of igneous rocks that make up the Martian crust beyond those compositions exhibited in the meteorite collection or Correspondence to: J. Filiberto, analyzed at any other landing site. Therefore, the magmas that gave rise to these rocks may have been fi[email protected] generated at significantly different conditions in the Martian mantle than those derived from previously studied rocks. Here we build upon our previous models of basalt formation based on rocks analyzed in Citation: Gusev Crater and Meridiani Planum to the new models of basalt formation for compositions from Gale Filiberto, J., and R. Dasgupta (2015), Crater and a clast in meteorite NWA 7034. Estimates for the mantle potential temperature, TP based on Constraints on the depth and thermal vigor of melting in the Martian mantle, Noachian age rock analyses in Gale Crater, Gusev Crater, and Bounce Rock in Meridiani Planum, and a J. Geophys. Res. Planets, 120, vitrophyre clast in NWA 7034 are within error, which suggests that the calculated average TP of 1450 ± 70°C doi:10.1002/2014JE004745. -
Chapter 5: Shock Metamorphism and Impact Melting
5. Shock Metamorphism and Impact Melting ❖❖❖ Shock-metamorphic products have become one of the diagnostic tools of impact cratering studies. They have become the main criteria used to identify structures of impact origin. They have also been used to map the distribution of shock-pressures throughout an impact target. The diverse styles of shock metamorphism include fracturing of crystals, formation of microcrystalline planes of glass through crystals, conversion of crystals to high-pressure polymorphs, conversion of crystals to glass without loss of textural integrity, conversion of crystals to melts that may or may not mix with melts from other crystals. Shock-metamorphism of target lithologies at the crater was first described by Barringer (1905, 1910) and Tilghman (1905), who recognized three different products. The first altered material they identified is rock flour, which they concluded was pulverized Coconino sandstone. Barringer observed that rock flour was composed of fragmented quartz crystals that were far smaller in size than the unaffected quartz grains in normal Coconino sandstone. Most of the pulverized silica he examined passed through a 200 mesh screen, indicating grain sizes <74 µm (0.074 mm), which is far smaller than the 0.2 mm average detrital grain size in normal Coconino (Table 2.1). Fairchild (1907) and Merrill (1908) also report a dramatic comminution of Coconino, although only 50% of Fairchild’s sample of rock flour passed through a 100 mesh screen, indicating grain sizes <149 µm. Heterogeneity of the rock flour is evident in areas where sandstone clasts survive within the rock flour. The rock flour is pervasive and a major component of the debris at the crater. -
Radar-Enabled Recovery of the Sutter's Mill Meteorite, A
RESEARCH ARTICLES the area (2). One meteorite fell at Sutter’sMill (SM), the gold discovery site that initiated the California Gold Rush. Two months after the fall, Radar-Enabled Recovery of the Sutter’s SM find numbers were assigned to the 77 me- teorites listed in table S3 (3), with a total mass of 943 g. The biggest meteorite is 205 g. Mill Meteorite, a Carbonaceous This is a tiny fraction of the pre-atmospheric mass, based on the kinetic energy derived from Chondrite Regolith Breccia infrasound records. Eyewitnesses reported hearing aloudboomfollowedbyadeeprumble.Infra- Peter Jenniskens,1,2* Marc D. Fries,3 Qing-Zhu Yin,4 Michael Zolensky,5 Alexander N. Krot,6 sound signals (table S2A) at stations I57US and 2 2 7 8 8,9 Scott A. Sandford, Derek Sears, Robert Beauford, Denton S. Ebel, Jon M. Friedrich, I56US of the International Monitoring System 6 4 4 10 Kazuhide Nagashima, Josh Wimpenny, Akane Yamakawa, Kunihiko Nishiizumi, (4), located ~770 and ~1080 km from the source, 11 12 10 13 Yasunori Hamajima, Marc W. Caffee, Kees C. Welten, Matthias Laubenstein, are consistent with stratospherically ducted ar- 14,15 14 14,15 16 Andrew M. Davis, Steven B. Simon, Philipp R. Heck, Edward D. Young, rivals (5). The combined average periods of all 17 18 18 19 20 Issaku E. Kohl, Mark H. Thiemens, Morgan H. Nunn, Takashi Mikouchi, Kenji Hagiya, phase-aligned stacked waveforms at each station 21 22 22 22 23 Kazumasa Ohsumi, Thomas A. Cahill, Jonathan A. Lawton, David Barnes, Andrew Steele, of 7.6 s correspond to a mean source energy of 24 4 24 2 25 Pierre Rochette, Kenneth L. -
Diopside-Bearing EL6 EET 90102: Insights from Rare Earth Element Distributions
Geochimica et Cosmochimica Acta, Vol. 67, No. 3, pp. 543–555, 2003 Copyright © 2003 Elsevier Science Ltd Pergamon Printed in the USA. All rights reserved 0016-7037/03 $22.00 ϩ .00 PII S0016-7037(02)01117-1 Diopside-bearing EL6 EET 90102: Insights from rare earth element distributions 1, 2 3 4 CHRISTINE FLOSS, *ROBERT A. FOGEL, YANGTING LIN, and MAKOTO KIMURA 1Laboratory for Space Sciences and the Department of Earth and Planetary Sciences, Washington University, St. Louis, MO 63130, USA 2Department of Earth and Planetary Sciences, American Museum of Natural History, New York, NY 10024, USA 3Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China 4Astrophysics and Planetary Science, Faculty of Science, Ibaraki University, Mito 310-8512, Japan (Received December 17, 2001; accepted in revised form July 25, 2002) Abstract—EET 90102 is the first known diopside-bearing EL6 chondrite. Diopside occurs in most aubrites and is occasionally found as rare small grains in unequilibrated enstatite chondrites, but is unknown from equilibrated enstatite chondrites. We have carried out a study of the rare earth element (REE) distributions in EET 90102, with a specific emphasis on diopside, in order to better understand its origin in this meteorite. We also present data for Ca-rich pyroxenes from two unequilibrated (EH3) enstatite chondrites for comparison. Our data show that diopside and other silicates in EET 90102 exhibit volatility-related anomalies indicative of formation under highly reducing conditions. Such anomalies have not previously been observed in EL6 chondrites, although they are common in unequilibrated enstatite chondrites. Diopside in EET 90102 probably formed by metamorphic equilibration of enstatite and oldhamite. -
Sulfides in Enstate Chondrites
Sulfides in Enstatite Chondrites: Indicators of Impact History Kristyn Hill1,2, Emma Bullock2, Cari Corrigan2, and Timothy McCoy2 1Lock Haven University of Pennsylvania, Lock Haven, PA 17745, USA 2National Museum of Natural History, Department of Mineral Sciences, Washington D.C. 20013, USA Introductton Results Discussion Enstatite chondrites are a class of meteorites. They are Determining the history of the parent body of a referred to as chondrites because of the spherical Impact Melt, Slowly Cooled chondritic meteorite often includes distinguishing whether chondrules found in the matrix of the meteorites. Enstatite aa bb cc d d or not the meteorite was impact melted, and the cooling chondrites are the most highly reduced meteorites and rate. contain iron-nickel metal and sulfide bearing minerals. The Impact melts are distinguishable by the texture of the matrix is made up of silicates, enstatite in particular. There metal and sulfide assemblages. A meteorite that was are usually no oxides found, which supports the idea that impact melted will contain a texture of euhedral to these formed in very oxygen poor environments. The subhedral silicates, like enstatite, protruding into the metal enstatite chondrites in this study are type 3, meaning they or sulfides (figure 2). Some textures will look shattered are unmetamorphosed and not affected by fluids. (figure 2b). Meteorites that contain the mineral keilite are Studying enstatite chondrites will help us determine the PCA 91125 ALHA 77156 PCA 91444 PCA 91085 also an indicator of impact melts (figure 3). Keilite only evolution of their parent bodies which formed at the occurs in enstatite chondrite impact-melt rocks that cooled beginning of our solar system. -
Invited Review
INVITED REVIEW Presolar grains from meteorites: Remnants from the early times of the solar system Katharina Lodders a,* and Sachiko Amari b a Planetary Chemistry Laboratory, Department of Earth and Planetary Sciences and McDonnell Center for the Space Sciences, Washington University, Campus Box 1169, One Brookings Drive, St. Louis, MO 63130, USA b Department of Physics and McDonnell Center for the Space Sciences, Washington University, Campus Box 1105, One Brookings Drive, St. Louis, MO 63130, USA Received 5 October 2004; accepted 4 January 2005 Abstract This review provides an introduction to presolar grains – preserved stardust from the interstellar molecular cloud from which our solar system formed – found in primitive meteorites. We describe the search for the presolar components, the currently known presolar mineral populations, and the chemical and isotopic characteristics of the grains and dust-forming stars to identify the grains’ most probable stellar sources. Keywords: Presolar grains; Interstellar dust; Asymptotic giant branch (AGB) stars; Novae; Supernovae; Nucleosynthesis; Isotopic ratios; Meteorites 1. Introduction The history of our solar system started with the gravitational collapse of an interstellar molecular cloud laden with gas and dust supplied from dying stars. The dust from this cloud is the topic of this review. A small fraction of this dust escaped destruction during the many processes that occurred after molecular cloud collapse about 4.55 Ga ago. We define presolar grains as stardust that formed in stellar outflows or ejecta and remained intact throughout its journey into the solar system where it was preserved in meteorites. The survival and presence of genuine stardust in meteorites was not expected in the early years of meteorite studies. -
Metabolic Engineering of Plant Volatiles Natalia Dudareva1 and Eran Pichersky2
COBIOT-516; NO OF PAGES 9 Available online at www.sciencedirect.com Metabolic engineering of plant volatiles Natalia Dudareva1 and Eran Pichersky2 Metabolic engineering of the volatile spectrum offers enormous Metabolic engineering requires a basic understanding of potential for plant improvement because of the great the biochemical pathways and the identification of the contribution of volatile secondary metabolites to reproduction, genes and enzymes involved in the synthesis of volatile defense and food quality. Recent advances in the identification compounds. In the last decade a renewed interest in these of the genes and enzymes responsible for the biosynthesis of questions combined with technical advances have led to volatile compounds have made this metabolic engineering both a large increase in the number of plant volatiles highly feasible. Notable successes have been reported in identified as well as remarkable progress in discovering enhancing plant defenses and improving scent and aroma the genes and enzymes of volatile biosynthesis. Numer- quality of flowers and fruits. These studies have also revealed ous attempts have been made to modulate volatile pro- challenges and limitations which will be likely surmounted as files in plants via metabolic engineering to enhance direct our understanding of plant volatile network improves. and indirect plant defense and to improve scent and Addresses aroma quality of flowers and fruits [2–5]. While a few 1 Department of Horticulture and Landscape Architecture, Purdue projects have been successful in achieving the desired University, West Lafayette, IN 47907, United States goals, many other attempts have resulted in meager 2 Department of Molecular, Cellular and Developmental Biology, University of Michigan, 830 North University Street, Ann Arbor, MI enhancement of volatiles or in other unpredicted meta- 48109, United States bolic consequences such as further metabolism of the intended end products or deleterious effects on plant Corresponding author: Dudareva, Natalia ([email protected]) growth and development. -
The Nakhlite Meteorites: Augite-Rich Igneous Rocks from Mars ARTICLE
ARTICLE IN PRESS Chemie der Erde 65 (2005) 203–270 www.elsevier.de/chemer INVITED REVIEW The nakhlite meteorites: Augite-rich igneous rocks from Mars Allan H. Treiman Lunar and Planetary Institute, 3600 Bay Area Boulevard, Houston, TX 77058-1113, USA Received 22 October 2004; accepted 18 January 2005 Abstract The seven nakhlite meteorites are augite-rich igneous rocks that formed in flows or shallow intrusions of basaltic magma on Mars. They consist of euhedral to subhedral crystals of augite and olivine (to 1 cm long) in fine-grained mesostases. The augite crystals have homogeneous cores of Mg0 ¼ 63% and rims that are normally zoned to iron enrichment. The core–rim zoning is cut by iron-enriched zones along fractures and is replaced locally by ferroan low-Ca pyroxene. The core compositions of the olivines vary inversely with the steepness of their rim zoning – sharp rim zoning goes with the most magnesian cores (Mg0 ¼ 42%), homogeneous olivines are the most ferroan. The olivine and augite crystals contain multiphase inclusions representing trapped magma. Among the olivine and augite crystals is mesostasis, composed principally of plagioclase and/or glass, with euhedra of titanomagnetite and many minor minerals. Olivine and mesostasis glass are partially replaced by veinlets and patches of iddingsite, a mixture of smectite clays, iron oxy-hydroxides and carbonate minerals. In the mesostasis are rare patches of a salt alteration assemblage: halite, siderite, and anhydrite/ gypsum. The nakhlites are little shocked, but have been affected chemically and biologically by their residence on Earth. Differences among the chemical compositions of the nakhlites can be ascribed mostly to different proportions of augite, olivine, and mesostasis. -
Team Studies Rare Meteorite Possibly from the Outer Asteroid Belt 20 December 2012
Team studies rare meteorite possibly from the outer asteroid belt 20 December 2012 The asteroid approached on an orbit that still points to the source region of CM chondrites. From photographs and video of the fireball, Jenniskens calculated that the asteroid approached on an unusual low-inclined almost comet-like orbit that reached the orbit of Mercury, passing closer to the sun than known from other recorded meteorite falls. "It circled the sun three times during a single orbit of Jupiter, in resonance with that planet," Jenniskens said. Based on the unusually short time that the asteroid was exposed to cosmic rays, there was not much time to go slower or faster around the sun. That puts the original source asteroid very (Phys.org)—Scientists found treasure when they close to this resonance, in a low inclined orbit. studied a meteorite that was recovered April 22, 2012 at Sutter's Mill, the gold discovery site that "A good candidate source region for CM chondrites led to the 1849 California Gold Rush. Detection of now is the Eulalia asteroid family, recently the falling meteorites by Doppler weather radar proposed as a source of primitive C-class asteroids allowed for rapid recovery so that scientists could in orbits that pass Earth," adds Jenniskens. study for the first time a primitive meteorite with little exposure to the elements, providing the most pristine look yet at the surface of primitive asteroids. An international team of 70 researchers reported in today's issue of Science that this meteorite was classified as a Carbonaceous-Mighei or CM-type carbonaceous chondrite and that they were able to identify for the first time the source region of these meteorites.