2015 International Nuclear Atlantic Conference - INAC 2015 São Paulo, SP, Brazil, October 4-9, 2015 ASSOCIAÇÃO BRASILEIRA DE ENERGIA NUCLEAR - ABEN ISBN: 978-85-99141-06-9 COLOR CHANGE OF GEMSTONES BY EXPOSURE TO GAMMA RAYS Giovanna L. C. de Lima1 and Fernando S. Lameiras2 1 Centro de Desenvolvimento da Tecnologia Nuclear (CDTN) Campus da UFMG - Pampulha Av. Antônio Carlos 6627 31270-901 Belo Horizonte, MG
[email protected] 2 Centro de Desenvolvimento da Tecnologia Nuclear (CDTN) Campus da UFMG - Pampulha Av. Antônio Carlos 6627 31270-901 Belo Horizonte, MG
[email protected] ABSTRACT A gem is appreciated by collectors and, when polished, widely used for jewelry manufacturing. For example, when quartz naturally or artificially acquires a color it becomes a gemstone (smoky quartz, morion, citrine, amethyst, or prasyolite). The presence of chromophore elements in a quartz sample was analysed by Fourier transform infrared spectrometry (FTIR). With a semi-quantitative analysis of the absorption FTIR spectra, it was possible to predict if colorless quartz has the potential to develop color when exposed to ionizing radiation and heat. Specific absorption bands show the presence of chromophore elements in quartz such as aluminum, iron, hydrogen, sodium, or lithium. Considering the ratio of the heights of the absorption bands of these elements, it was possible to predict the color quartz can develop. Samples of irradiated dark and light violet fluorites were analyzed by FTIR and energy-dispersive X-rays spectroscopy. The light violet samples has higher content of calcium relative to fluorine, as well higher content of hydroxyl, probably replacing fluorine in crystal lattice.