Gasoline Safety Educator's Guide
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Module III – Fire Analysis Fire Fundamentals: Definitions
Module III – Fire Analysis Fire Fundamentals: Definitions Joint EPRI/NRC-RES Fire PRA Workshop August 21-25, 2017 A Collaboration of the Electric Power Research Institute (EPRI) & U.S. NRC Office of Nuclear Regulatory Research (RES) What is a Fire? .Fire: – destructive burning as manifested by any or all of the following: light, flame, heat, smoke (ASTM E176) – the rapid oxidation of a material in the chemical process of combustion, releasing heat, light, and various reaction products. (National Wildfire Coordinating Group) – the phenomenon of combustion manifested in light, flame, and heat (Merriam-Webster) – Combustion is an exothermic, self-sustaining reaction involving a solid, liquid, and/or gas-phase fuel (NFPA FP Handbook) 2 What is a Fire? . Fire Triangle – hasn’t change much… . Fire requires presence of: – Material that can burn (fuel) – Oxygen (generally from air) – Energy (initial ignition source and sustaining thermal feedback) . Ignition source can be a spark, short in an electrical device, welder’s torch, cutting slag, hot pipe, hot manifold, cigarette, … 3 Materials that May Burn .Materials that can burn are generally categorized by: – Ease of ignition (ignition temperature or flash point) . Flammable materials are relatively easy to ignite, lower flash point (e.g., gasoline) . Combustible materials burn but are more difficult to ignite, higher flash point, more energy needed(e.g., wood, diesel fuel) . Non-Combustible materials will not burn under normal conditions (e.g., granite, silica…) – State of the fuel . Solid (wood, electrical cable insulation) . Liquid (diesel fuel) . Gaseous (hydrogen) 4 Combustion Process .Combustion process involves . – An ignition source comes into contact and heats up the material – Material vaporizes and mixes up with the oxygen in the air and ignites – Exothermic reaction generates additional energy that heats the material, that vaporizes more, that reacts with the air, etc. -
Safety Data Sheet
Coghlan’s Magnesium Fire Starter #7870 SAFETY DATA SHEET This Safety Data Sheet complies with the Canadian Hazardous Product Regulations, the United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR 1910 (OSHA HCS), and the European Union Directives. 1. Product and Supplier Identification 1.1 Product: Magnesium Fire Starter 1.2 Other Means of Identification: Coghlan’s #7870 1.3 Product Use: Fire starter 1.4 Restrictions on Use: None known 1.5 Producer: Coghlan’s Ltd., 121 Irene Street, Winnipeg, Manitoba Canada, R3T 4C7 Telephone: +1(204) 284-9550 Facsimile: +1(204) 475-4127 Email: [email protected] Supplier: As above 1.6 Emergencies: +1(877) 264-4526 2. Hazards Identification 2.1 Classification of product or mixture This product is an untested preparation. GHS classification for this preparation is based upon its use as a fire starter by making shavings and small particulate from the metal block. As shipped in mass form, this preparation is not considered to be a hazardous product and is not classifiable under the requirements of GHS. GHS Classification: Flammable Solids, Category 1 2.2 GHS Label Elements, including precautionary statements Pictogram: Signal Word: Danger Page 1 of 11 October 18, 2016 Coghlan’s Magnesium Fire Starter #7870 GHS Hazard Statements: H228: Flammable Solid GHS Precautionary Statements: Prevention: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280: Wear protective gloves, eye and face protection Response: P370+P378: In case of fire use water as first choice. Sand, earth, dry chemical, foam or CO2 may be used to extinguish. -
The Art of Reading Smoke for Rapid Decision Making
The Art of Reading Smoke for Rapid Decision Making Dave Dodson teaches the art of reading smoke. This is an important skill since fighting fires in the year 2006 and beyond will be unlike the fires we fought in the 1900’s. Composites, lightweight construction, engineered structures, and unusual fuels will cause hostile fires to burn hotter, faster, and less predictable. Concept #1: “Smoke” is FUEL! Firefighters use the term “smoke” when addressing the solids, aerosols, and gases being produced by the hostile fire. Soot, dust, and fibers make up the solids. Aerosols are suspended liquids such as water, trace acids, and hydrocarbons (oil). Gases are numerous in smoke – mass quantities of Carbon Monoxide lead the list. Concept #2: The Fuels have changed: The contents and structural elements being burned are of LOWER MASS than previous decades. These materials are also more synthetic than ever. Concept #3: The Fuels have triggers There are “Triggers” for Hostile Fire Events. Flash point triggers a smoke explosion. Fire Point triggers rapid fire spread, ignition temperature triggers auto ignition, Backdraft, and Flashover. Hostile fire events (know the warning signs): Flashover: The classic American Version of a Flashover is the simultaneous ignition of fuels within a compartment due to reflective radiant heat – the “box” is heat saturated and can’t absorb any more. The British use the term Flashover to describe any ignition of the smoke cloud within a structure. Signs: Turbulent smoke, rollover, and auto-ignition outside the box. Backdraft: A “true” backdraft occurs when oxygen is introduced into an O2 deficient environment that is charged with gases (pressurized) at or above their ignition temperature. -
Fire Research Work in Britain and France
This r'.r • i preo^red for i::' ; r::"d -c; purp::c: i,:>i to be referenced in any publication. ^ NATIONAL BUREAU OF STANDARDS REPORT 3962 FIHE RESEARCH WORK IN BRITAIN AND FRANCE by Ao F. Robertson U. S. DEPARTMENT OF COMMERCE NATIONAL DUREAU OF STANDARDS U. S. DEPARTMENT OF COMMERCE Sinclair Weeks, Secretary NATIONAL BUREAU OF STANDARDS A. V. Astin, Director cover of this report. Electricity. Resistance and Reactance Measurements, Electrical Instruments. Magnetic Measurements. Electrochemistry. Optics and Metrology. Photometry and Colorimetry. Optical Instruments. Photographic Technology. Length. Engineering Metrology. Heat and Power. Temperature Measurements. Thermodynamics. Cryogenic Physics. Engines and Lubrication. Engine Fuels. Cryogenic Engineering. Atomic and Radiation Physics. Spectroscopy. Radiometry. Mass Spectrometry. Solid State Physics. Electron Physics. Atomic Physics. Neutron Measurements. Infrared Spectros- copy. Nuclear Physics. Radioactivity. X-Ray. Betatron. Nucleonic Instrumentation. Radio- logical Equipment. Atomic Energy Commission Radiation Instruments Branch. Chemistry. Organic Coatings. Surface Chemistry. Organic Chemistry. Analytical Chemistry. Inorganic Chemistry. Electrodeposition. Gas Chemistry. Physical Chemistry. Thermochemistry. Spectrochemistry. Pure Substances. Mechanics. Sound. Mechanical Instruments. Fluid Mechanics. Engineering Mechanics. Mass and Scale. Capacity, Density, and Fluid Meters. Combustion Control. Organic and Fibrous Materials. Rubber. Textiles. Paper. Leather. Testing and Specifica- -
Material Safety Data Sheet
MATERIAL SAFETY DATA SHEET Page 1 Speedy Clean, LLC 24 Hour Emergency #: 800-255-3924 4550 Ziebart Place Telephone Number: 702-736-6500 Las Vegas, NV 89103 PRODUCT: RESCUE 911 - WHITE Section 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER ................................................. SPEEDY CLEAN, LLC 4550 ZIEBART PLACE LAS VEGAS, NV 89103 PRODUCT NAME................................................... RESCUE 911 - WHITE CHEMICAL FAMILY................................................ ORGANIC COATING. MOLECULAR WEIGHT........................................... NOT APPLICABLE. CHEMICAL FORMULA........................................... NOT APPLICABLE. TRADE NAMES & SYNONYMS.............................. RESCUE 911 - WHITE PRODUCT USES.................................................... COATING. FORMULA/LAB BOOK #......................................... 002-21-270. Section 02: COMPOSITION/INFORMATION INGREDIENTS Hazardous Ingredients % Exposure Limit C.A.S.# LD/50, Route,Species LC/50 Route,Species HEPTANE 15 - 40 400 ppm 142-82-5 >15000 mg/kg ORAL-RAT NOT AVAILABLE TOLUENE 10-30 50 ppm 108-88-3 5000 mg/kg ORAL - RAT 8000 ppm (4 hr) INHAL - RAT ACETONE 5 - 20 750 ppm 67-64-1 >9750 mg/kg ORAL - RAT >16,000 ppm (4 hr) INHAL - RAT PETROLEUM DISTILLATES 1-5 100 ppm 8052-41-3 5 g/kg ORAL-RAT 5500 mg/m3 INHAL-RAT (STODDARD SOLVENT) PROPYLENE GLYCOL METHYL 1-5 N/E 108-65-6 8500 mg/kg ORAL - RAT >4345 ppm (6 hr) INHAL - ETHER ACETATE RAT DIMETHYL ETHER 10-30 1000 ppm 115-10-6 NOT APPLICABLE 164000 ppm (4h) RAT - INHAL ISOBUTANE 5-10 1000 ppm 75-28-5 NOT APPLICABLE 142,500 ppm (4h) INHAL - RAT PROPANE 5-10 1000 ppm 74-98-6 >5000 mg/kg NOT AVAILABLE DERMAL-RABBITS Section 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY: INGESTION............................................................. MAY CAUSE HEADACHE, NAUSEA, VOMITING AND WEAKNESS. -
Fuel Properties Comparison
Alternative Fuels Data Center Fuel Properties Comparison Compressed Liquefied Low Sulfur Gasoline/E10 Biodiesel Propane (LPG) Natural Gas Natural Gas Ethanol/E100 Methanol Hydrogen Electricity Diesel (CNG) (LNG) Chemical C4 to C12 and C8 to C25 Methyl esters of C3H8 (majority) CH4 (majority), CH4 same as CNG CH3CH2OH CH3OH H2 N/A Structure [1] Ethanol ≤ to C12 to C22 fatty acids and C4H10 C2H6 and inert with inert gasses 10% (minority) gases <0.5% (a) Fuel Material Crude Oil Crude Oil Fats and oils from A by-product of Underground Underground Corn, grains, or Natural gas, coal, Natural gas, Natural gas, coal, (feedstocks) sources such as petroleum reserves and reserves and agricultural waste or woody biomass methanol, and nuclear, wind, soybeans, waste refining or renewable renewable (cellulose) electrolysis of hydro, solar, and cooking oil, animal natural gas biogas biogas water small percentages fats, and rapeseed processing of geothermal and biomass Gasoline or 1 gal = 1.00 1 gal = 1.12 B100 1 gal = 0.74 GGE 1 lb. = 0.18 GGE 1 lb. = 0.19 GGE 1 gal = 0.67 GGE 1 gal = 0.50 GGE 1 lb. = 0.45 1 kWh = 0.030 Diesel Gallon GGE GGE 1 gal = 1.05 GGE 1 gal = 0.66 DGE 1 lb. = 0.16 DGE 1 lb. = 0.17 DGE 1 gal = 0.59 DGE 1 gal = 0.45 DGE GGE GGE Equivalent 1 gal = 0.88 1 gal = 1.00 1 gal = 0.93 DGE 1 lb. = 0.40 1 kWh = 0.027 (GGE or DGE) DGE DGE B20 DGE DGE 1 gal = 1.11 GGE 1 kg = 1 GGE 1 gal = 0.99 DGE 1 kg = 0.9 DGE Energy 1 gallon of 1 gallon of 1 gallon of B100 1 gallon of 5.66 lb., or 5.37 lb. -
Complete Copy
Table of Contents...........................................................................................................Page DIVISION 100 - General Specifications ......................................................................... 1 Section 101 - Abbreviations, Acronyms, & Terms.......................................................... 2 Section 102 - Definitions................................................................................................. 8 Section 103 - Intent of Contract.................................................................................... 15 Section 104 - Maintenance for Traffic.......................................................................... 16 Section 105 - Control of Materials ............................................................................... 17 Section 106 - Measurement & Payment........................................................................ 22 DIVISION 150 - Engineering......................................................................................... 27 Section 160 - Quality Control & Quantity Measurement ............................................. 28 Section 161 - Certification for Quality & Quantity ...................................................... 31 Section 170 - Construction Staking, L-Line.................................................................. 32 Section 171 - Construction Staking, Offset L-Line ....................................................... 42 Section 173 - Construction Staking, Location Line ..................................................... -
Common Fire Hazards
INTRODUCTION TO FIRE INSPECTION PRINCIPLES AND PRACTICES COMMON FIRE HAZARDS TERMINAL OBJECTIVES The students will be able to: 1. Recognize the presence of fire hazards in structures. 2. Recognize the presence of hazardous materials or processes. ENABLING OBJECTIVES The students will: 1. Define fire hazard. 2. Identify types of hazards. 3. Recognize common ignition sources. 4. Recognize and categorize hazardous materials. COMMON FIRE HAZARDS SM FH-2 COMMON FIRE HAZARDS HAZARDS A hazard is something that poses danger, peril, risk, or difficulty. On the golf course a lake can be a hazard. A wet floor can be a slipping hazard. This module covers three other types of hazards: common fire hazards, special fire hazards, and hazardous materials. Part of this module covers fire hazards and part hazardous materials. The term fire hazard is used by both fire professionals and the lay public. What does it mean? Any actions, materials, or conditions that might increase the size or severity of a fire or that might cause a fire to start are called fire hazards. The hazard might be a fuel that is easy to ignite or a heat source like a defective appliance. The hazard could be an action like thawing a pipe with a torch or an omission like failing to have a wood stove chimney cleaned. Common fire hazards are found in most occupancies and are not associated with any special occupancy. Smoking, trash, electrical appliances, storage, and heating are common to most occupancy types. However, smoke-free workplaces are making smoking a less common problem. Special fire hazards are linked to some specific process or activity in particular occupancies. -
Fusee, Backfiring - No Perchlorate (NPC) Identification: Formulation the NPC Fusee Will Have the Following Symbol on It
SAFETY DATA SHEET 1. Product and Company Identification Fusee, Backfiring - No Perchlorate (NPC) Identification: Formulation The NPC fusee will have the following symbol on it: Synonyms: Backfire Torches (p/n 4100) NSN#: 1370-00-294-1279 Identified Use: Forest fire control Use Advised Against: Do not use indoors or inside a vehicle Manufacturers Information Orion Safety Products 28320 St. Michaels Rd EMERGENCY CHEMTREC Easton, MD 21601 800-637-7807 1-800-424-9300 410-822-0318 2. Hazards Identification GHS Classifications Skin Irritation Category 2 H315 Eye Irritation Category 2A H319 STOT - Single Exposure Category 3 H335 GHS Label Elements Pictograms Hazard Statements H315 /319 Causes skin and serious eye irritation H335 May cause respiratory irritation Signal Word Warning Precautionary Statements P301/315 IF SWALLOWED: Get immediate medical advice /attention. P103 Keep out of reach of children P302/352 IF ON SKIN: Wash with plenty of soap and water. P261 Avoid breathing dust/smoke. P304/340/342 IF INHALED: Remove victim to fresh air and keep at rest in a position P264 Wash hands thoroughly after handling. comfortable for breathing If experiencing respiratory symptoms: Call a P270 Do not eat, drink or smoke when using this product. POISON CENTER or doctor / physician. P271 Use only outdoors or in a well-ventilated area. P305/338/351 IF IN EYES: Rinse cautiously with water for several minutes. Remove P280 Wear protective eye protection contact lenses, if present and easy to do. Continue rinsing. P370 In case of fire: use water deluge P333/313 If skin irritation or rash occurs, get medical advice / attention. -
2012-2015 Ryan White Part B Program Comprehensive Plan
2012-2015 Ryan White Part B Program Comprehensive Plan Table of Contents Acronyms ............................................................................................................................... 1 Acknowledgements ................................................................................................................ 5 Introduction ............................................................................................................................ 6 WV Comprehensive Planning Process .......................................................................... 6 Executive Summary ............................................................................................................... 7 1. Where Are We Now: What is our Current System of Care? ................................... 8 HIV/AIDS In West Virginia-Epidemiologic Trends ..................................................... 8 Unmet Need ................................................................................................................. 24 2010 Unmet Need Framework Report ......................................................................... 27 Early Identification of Individuals with HIV/AIDS (EIIHA) ...................................... 43 Prevention Programs .................................................................................................... 49 Partner Services ........................................................................................................... 50 Continuum of Care ...................................................................................................... -
A Review of the Fire and Explosion Hazards of Particulates†
KONA Powder and Particle Journal No. 31 (2014) 53–81/Doi:10.14356/kona.2014010 Review Paper A Review of the Fire and Explosion Hazards of Particulates † Saul M. Lemkowitz 1* and Hans J. Pasman 2 1 Department of Chemical Engineering, Delft University of Technology, the Netherlands 2 Mary Kay O’Connor Process Safety Center, Department of Chemical Engineering of Texas A&M University, USA Abstract Particulate fires and explosions cause substantial loss of life and property. With the goal of understanding, preventing, or at least mitigating particulate fire and explosion hazards, we review basics. We distinguish between ‘hazard’ and ‘risk’ and discuss the fire and explosion hazards of particulates, the many factors determining such hazards, hazard indexes, and ways to reduce fire and explosion hazards. While our primary goal is to improve safety, we briefly discuss how fundamental knowledge can be extracted from weapon technology based on particulate combustion. We review the prevention of and protection against particulate explosions and discuss ongoing and future research. Keywords: fire, explosion, (nano)particles, hazard indexes, prevention, protection, modeling 1. Introduction; hazard versus risk pressure, temperature), size and strength of containment, (distance to) possible ‘targets’, good management, adher- Although the basics are well understood, fires and ex- ence to legislation, etc. Here we discuss particle hazards plosions of solid particulates (powders, ‘dusts’) and liquid and their reduction. The more extensive concept of parti- particulates (‘mists’), especially the former, continue to cle risk falls outside the scope of this review1). cause considerable material damage and loss of life. Parti- cle safety therefore remains important. -
Automotive Gasoline Cas # 8006-61-9
AUTOMOTIVE GASOLINE CAS # 8006-61-9 Agency for Toxic Substances and Disease Registry ToxFAQs September 1996 This fact sheet answers the most frequently asked health questions (FAQs) about automobile gasoline. For more information, call the ATSDR Information Center at 1-888-422-8737. This fact sheet is one in a series of summaries about hazardous substances and their health effects. This information is important because this substance may harm you. The effects of exposure to any hazardous substance depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other chemicals are present. SUMMARY: Exposure to automotive gasoline most likely occurs from breathing its vapor at a service station while filling a car’s fuel tank. At high levels, automotive gasoline is irritating to the lungs when breathed in and irritating to the lining of the stomach when swallowed. Exposure to high levels may also cause harmful effects to the nervous system. Automotive gasoline has been found in at least 23 of the 1,430 National Priorities List sites identified by the Environmental Protection Agency (EPA). What is automotive gasoline? � Other chemicals in gasoline dissolve in water after spills to surface waters or underground storage tank leaks into (Pronounced ô ) the groundwater. 't;-miftlv gasf;-len' The gasoline discussed in this fact sheet is automotive used � In surface releases, most chemicals in gasoline will prob as a fuel for engines in cars. Gasoline is a colorless, pale brown, or ably evaporate; others may dissolve and be carried away by water; a few will probably stick to soil.