Table 1 OODR Excitation Data of the Li2 33Sg+ State
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3 + Table 1 OODR excitation data of the Li2 3 g state. 3 + Intermediate levels Probe Freq. 3 g levels Calc.–Obs. A/b υ N (cm-1) Term value υ N (cm-1) (cm-1) 7 b 19 5 16245.634 33489.130 9 5 Li2 -0.044 7 b 19 7 16235.756 33494.669 9 6 Li2 -0.022
7 b 19 7 16249.659 33508.572 9 8 Li2 -0.030
7 b 19 10 16235.264 33526.260 9 10 Li2 -0.135
7 b 19 5 16483.496 33726.991 10 5 Li2 0.034
7 b 19 7 16473.531 33732.444 10 6 Li2 0.074
7 b 19 7 16487.537 33746.45 10 8 Li2 -0.207
7 b 19 10 16472.653 33763.653 10 10 Li2 -0.041
7 b 19 5 16717.780 33961.276 11 5 Li2 0.080
7 b 19 7 16707.750 33966.663 11 6 Li2 0.118
7 b 19 7 16721.310 33980.223 11 8 Li2 0.114
7 b 19 10 16706.473 33997.473 11 10 Li2 0.017
7 b 19 5 16948.440 34191.937 12 5 Li2 0.119
7 b 19 10 16936.700 34227.700 12 10 Li2 0.038
7 b 19 5 17175.520 34419.016 13 5 Li2 0.086
7 b 19 10 17163.292 34454.292 13 10 Li2 0.040
7 b 19 5 17398.938 34642.434 14 5 Li2 0.040
7 b 19 10 17386.263 34677.263 14 10 Li2 -0.012
7 A 16 12 17000.321 34927.316 15 13 Li2 -0.021
7 b 19 5 17834.679 35078.175 16 5 Li2 -0.073
7 b 19 10 17821.053 35112.049 16 10 Li2 -0.074
7 b 19 5 18046.947 35290.443 17 5 Li2 -0.129
7 b 19 10 18032.812 35323.808 17 10 Li2 -0.074
7 b 19 5 18255.389 35498.885 18 5 Li2 -0.123
7 b 19 10 18240.802 35531.798 18 10 Li2 -0.068
7 b 19 5 18459.963 35703.459 19 5 Li2 -0.036
7 b 19 10 18444.876 35735.872 19 10 Li2 0.066
7 b 19 10 18645.120 35936.116 20 10 Li2 0.222
6 b 9 32 16725.791 32091.626 1 32 Li2 0.116
6 b 9 32 17005.214 32371.049 2 32 Li2 0.048
6 b 9 32 17280.682 32646.517 3 32 Li2 -0.071
6 b 9 32 17551.932 32917.767 4 32 Li2 -0.007
6 b 9 32 18082.596 33448.431 6 32 Li2 -0.258
6 b 9 32 18341.199 33707.034 7 32 Li2 0.182 6 b 15 19 16602.720 33343.684 7 19 Li2 -0.026
6 b 15 19 16862.359 33603.323 8 19 Li2 0.047
6 b 15 19 17119.304 33860.268* 9 19 Li2 -1.361 b 12 23 16523.829 32303.216* 3 23 6Li7Li -0.870 b 12 23 16790.508 32569.895 4 23 6Li7Li -0.054 b 12 23 17052.635 32832.022 5 23 6Li7Li -0.193 b 12 23 17310.570 33089.957 6 23 6Li7Li 0.065 b 12 23 17564.827 33344.214 7 23 6Li7Li 0.184 * These data are excluded from the fits due to perturbations. 6 The Li2 data are from Xie et al., J. Mol. Spectrosc. 117 (1986) 228-244. 7 The Li2 data are from Yiannopoulou et al., J. Chem. Phys. 102 (1995) 3024-3031. 3 Table 2 OODR excitation data of the Li2 1 g state.
3 Intermediate Probe Freq. 1 g levels Calc.Dun-Obs. Calc.BOB-Obs. levels (cm-1) (cm-1) (cm-1) A/b υ N Term value υ N (cm-1)
7 b 19 5 15364.219 32607.715 9 4 Li2 0.006 -0.024
7 b 19 5 15368.760 32612.256 9 5 Li2 0.233 0.210
7 b 19 5 15374.728 32618.224 9 6 Li2 -0.016 -0.030
7 A 13 4 15368.867 32612.265 9 5 Li2 0.224 0.201
7 b 19 7 15365.978 32624.858 9 7 Li2 0.020 0.016
7 b 19 10 15350.107 32641.103 9 9 Li2 -0.036 -0.016
7 b 19 10 15359.418 32650.414 9 10 Li2 0.168 0.202
7 b 19 10 15370.112 32661.108 9 11 Li2 -0.065 -0.016
7 A 13 11 15350.063 32641.105 9 9 Li2 -0.038 -0.018
7 A 13 11 15359.377 32650.419 9 10 Li2 0.163 0.197
7 A 13 11 15370.074 32661.116 9 11 Li2 -0.073 -0.024
7 A 13 4 15611.205 32854.603 10 4 Li2 0.126 0.084
7 A 13 4 15615.927 32859.325 10 5 Li2 0.118 0.085
7 A 13 4 15621.596 32864.994 10 6 Li2 0.103 0.080
7 b 19 7 15606.172 32865.085 10 6 Li2 0.012 -0.011
7 b 19 7 15612.781 32871.694 10 7 Li2 -0.001 -0.013
7 b 19 7 15620.334 32879.247 10 8 Li2 -0.020 -0.019
7 A 13 7 15620.539 32879.243 10 8 Li2 -0.016 -0.015
7 b 19 10 15616.526 32907.522 10 11 Li2 -0.073 -0.025
7 A 13 11 15596.686 32887.728 10 9 Li2 -0.030 -0.014
7 A 13 11 15606.112 32897.154 10 10 Li2 -0.047 -0.016
7 A 13 11 15616.481 32907.523 10 11 Li2 -0.074 -0.026
7 A 13 11 15596.688 32887.73 10 9 Li2 -0.032 -0.016
7 A 13 11 15606.116 32897.158 10 10 Li2 -0.051 -0.020
7 A 13 11 15616.476 32907.518 10 11 Li2 -0.069 -0.021
7 A 13 11 15840.072 33131.114 11 9 Li2 -0.020 -0.006
7 A 13 11 15849.393 33140.435 11 10 Li2 -0.040 -0.008
7 A 13 11 15859.639 33150.682 11 11 Li2 -0.061 -0.012
7 b 19 10 16317.18 33608.176 13 9 Li2 -0.008 0.009
7 b 19 10 16326.293 33617.289 13 10 Li2 -0.032 0.003
7 b 19 10 16336.307 33627.303 13 11 Li2 -0.053 0.001
7 b 19 10 16781.365 34072.361 15 9 Li2 -0.118 -0.098
7 b 19 10 16800.001 34090.997 15 11 Li2 -0.115 -0.059 7 A 13 11 16790.180 34081.222 15 10 Li2 -0.101 -0.063
7 b 19 5 17025.252 34268.748 16 4 Li2 -0.113 -0.159
7 b 19 5 17029.662 34272.938 16 5 Li2 0.092 0.057
7 b 19 5 17034.951 34278.227 16 6 Li2 0.076 0.052
7 b 19 5 17249.243 34492.741 17 4 Li2 0.108 0.065
7 b 19 5 17253.606 34497.102 17 5 Li2 0.090 0.056
7 b 19 5 17253.603 34497.099 17 5 Li2 0.093 0.059
7 b 19 5 17258.824 34502.319 17 6 Li2 0.083 0.061
7 b 19 7 17249.465 34508.378 17 7 Li2 0.100 0.091
7 b 19 7 17256.417 34515.329 17 8 Li2 0.091 0.095
7 A 13 11 17232.246 34523.288 17 9 Li2 -0.062 -0.042
7 A 13 11 17240.937 34531.979 17 10 Li2 -0.084 -0.048
7 A 13 11 17250.489 34541.532 17 11 Li2 -0.106 -0.054
7 b 19 5 17901.993 35145.489 20 4 Li2 0.070 0.036
7 b 19 5 17911.208 35154.705 20 6 Li2 0.063 0.045
7 b 19 10 17883.861 35174.857 20 9 Li2 -0.012 -0.001
7 b 19 10 17892.240 35183.236 20 10 Li2 -0.032 -0.011
7 b 19 10 17901.442 35192.438 20 11 Li2 -0.045 -0.014
7 b 19 5 18112.874 35356.370 21 4 Li2 0.035 0.006
7 b 19 5 18117.017 35360.513 21 5 Li2 0.027 0.005
7 b 19 5 18121.989 35365.485 21 6 Li2 0.016 0.000
7 b 19 10 18094.332 35385.328 21 9 Li2 0.003 0.010
7 b 19 10 18102.599 35393.596 21 10 Li2 -0.010 0.005
7 b 19 10 18111.686 35402.682 21 11 Li2 -0.019 0.003
7 b 19 5 18320.341 35563.837 22 4 Li2 0.005 -0.016
7 b 19 5 18324.429 35567.925 22 5 Li2 0.001 -0.016
7 b 19 5 18329.335 35572.831 22 6 Li2 -0.006 -0.017
7 b 19 10 18301.455 35592.451 22 9 Li2 -0.042 -0.038
7 b 19 10 18309.613 35600.609 22 10 Li2 -0.047 -0.038
7 b 19 10 18318.579 35609.576 22 11 Li2 -0.050 -0.038
7 b 19 5 18524.332 35767.828 23 4 Li2 0.010 -0.001
7 b 19 5 18528.427 35771.923 23 5 Li2 -0.052 -0.060
7 b 19 5 18533.267 35776.763 23 6 Li2 -0.054 -0.059
7 b 19 10 18505.111 35796.107 23 9 Li2 -0.060 -0.057
7 b 19 10 18513.157 35804.153 23 10 Li2 -0.055 -0.051
7 b 19 10 18521.954 35812.950 23 11 Li2 0.000 0.004
7 b 19 10 18713.190 36004.186 24 10 Li2 -0.025 -0.024
7 b 19 10 18721.810 36012.806 24 11 Li2 0.095 0.091
7 b 19 10 18901.854 36192.849 25 9 Li2 0.013 0.023 7 b 19 10 18909.679 36200.676 25 10 Li2 0.035 0.037
7 b 19 10 18918.291 36209.287 25 11 Li2 0.053 0.046
7 b 19 10 18705.476 35996.472* 24 9 Li2
7 b 9 3 18494.363 32848.267 10 2 Li2 -0.140 -0.193
7 b 2 3 20751.951 32850.929 10 3 Li2 0.028 -0.021
7 b 7 4 19116.012 32850.99 10 3 Li2 -0.033 -0.082
7 b 13 3 17300.289 32854.706 10 4 Li2 0.023 -0.019
7 b 18 4 15886.481 32854.815 10 4 Li2 -0.086 -0.128
7 b 9 5 18493.648 32859.407 10 5 Li2 0.036 0.003
7 b 13 6 17286.004 32859.437 10 5 Li2 0.006 -0.027
7 b 5 5 19763.469 32865.109 10 6 Li2 -0.012 -0.035
7 b 10 5 18193.285 32865.086 10 6 Li2 0.011 -0.012
7 b 7 6 19122.002 32871.730 10 7 Li2 -0.037 -0.049
7 b 11 7 17881.078 32871.705 10 7 Li2 -0.012 -0.024
7 b 5 7 19759.822 32879.198 10 8 Li2 0.029 0.030
7 b 11 7 17888.625 32879.252 10 8 Li2 -0.025 -0.024
7 b 11 8 17886.816 32887.768 10 9 Li2 -0.070 -0.054
7 b 11 9 17875.119 32887.678 10 9 Li2 0.020 0.036
7 b 11 10 17871.736 32897.181 10 10 Li2 -0.074 -0.043
7 b 5 10 19751.389 32907.549 10 11 Li2 -0.100 -0.052
7 b 7 12 19092.875 32918.838 10 12 Li2 -0.113 -0.047
7 b 5 14 19706.984 32931.069 10 13 Li2 -0.137 -0.053
7 b 9 14 18460.377 32944.225 10 14 Li2 -0.156 -0.053
7 b 24 3 15526.851 34041.012 15 4 Li2 0.120 0.072
7 b 25 7 15269.656 34050.835 15 6 Li2 0.081 0.055
7 b 15 8 17896.652 34064.314 15 8 Li2 -0.066 -0.062
7 b 23 8 15771.450 34072.238 15 9 Li2 0.005 0.025
7 b 15 10 17889.936 34081.136 15 10 Li2 -0.015 0.023
7 b 13 12 18445.461 34090.930 15 11 Li2 -0.048 0.008
7 b 15 14 17872.609 34125.555 15 14 Li2 -0.113 0.003
7 b 23 5 16225.315 34502.329 17 6 Li2 0.073 0.051
7 b 26 8 15495.647 34523.225 17 9 Li2 0.001 0.021
7 b 26 10 15483.732 34531.915 17 10 Li2 -0.020 0.016
7 b 27 10 15260.876 34541.548 17 11 Li2 -0.122 -0.070
6 b 9 32 16334.14 31699.975 3 31 Li2 0.039 -0.047
6 b 9 32 16370.791 31736.626 3 32 Li2 -0.004 -0.076
6 b 9 32 16408.512 31774.347 3 33 Li2 -0.060 -0.116
6 b 9 32 16614.301 31980.136 4 31 Li2 0.067 0.038
6 b 9 32 16650.516 32016.351 4 32 Li2 0.044 0.029 6 b 9 32 16687.779 32053.614 4 33 Li2 0.019 0.018
6 b 9 32 16926.537 32292.372 5 32 Li2 -0.001 0.030
6 b 9 32 16963.377 32329.212 5 33 Li2 -0.029 0.012
6 b 9 32 17432.086 32797.921 7 31 Li2 0.124 0.200
6 b 9 32 17467.171 32833.006 7 32 Li2 -0.008 0.071
6 b 9 32 17503.161 32868.996 7 33 Li2 -0.032 0.046
6 b 9 32 17958.653 33324.488 9 31 Li2 -0.028 0.040
6 b 9 32 17992.797 33358.632 9 32 Li2 -0.036 0.018
6 b 9 32 18027.923 33393.758 9 33 Li2 -0.035 -0.001
6 b 9 32 18216.300 33582.135 10 31 Li2 -0.093 -0.060
6 b 9 32 18249.962 33615.797 10 32 Li2 -0.024 -0.016
6 b 9 32 18284.667 33650.502 10 33 Li2 -0.020 -0.043
6 b 9 32 18470.026 33835.861 11 31 Li2 0.013 -0.011
6 b 9 32 18503.338 33869.173 11 32 Li2 0.027 -0.034
6 b 9 32 18537.610 33903.445 11 33 Li2 0.050 -0.058
6 b 15 19 15424.575 32165.539 6 18 Li2 0.048 -0.059
6 b 15 19 15446.008 32186.972 6 19 Li2 0.096 0.002
6 b 15 19 15468.648 32209.612 6 20 Li2 0.037 -0.044
6 b 15 19 15697.684 32438.648 7 18 Li2 0.052 -0.040
6 b 15 19 15718.927 32459.891 7 19 Li2 0.035 -0.040
6 b 15 19 15741.260 32482.224 7 20 Li2 0.016 -0.043
6 b 15 19 15967.047 32708.011 8 18 Li2 0.027 -0.050
6 b 15 19 15988.044 32729.008 8 19 Li2 0.002 -0.055
6 b 15 19 16010.115 32751.079 8 20 Li2 -0.022 -0.059
6 b 15 19 16494.320 33235.284 10 18 Li2 0.122 0.072
6 b 15 19 16514.894 33255.858 10 19 Li2 0.017 -0.012
6 b 15 19 16536.378 33277.342 10 20 Li2 0.051 0.043
6 b 15 19 16752.387 33493.351 11 18 Li2 0.087 0.044
6 b 15 19 16772.801 33513.765 11 19 Li2 -0.109 -0.131
6 b 15 19 16793.903 33534.867 11 20 Li2 0.045 0.042
6 b 15 19 17006.625 33747.589 12 18 Li2 0.108 0.066
6 b 15 19 17026.631 33767.595 12 19 Li2 0.070 0.048
6 b 15 19 17047.676 33788.64 12 20 Li2 0.019 0.014
6 b 15 19 17503.779 34244.743 14 18 Li2 0.109 0.048
6 b 15 19 17523.280 34264.244 14 19 Li2 0.081 0.033
6 b 15 19 17543.777 34284.741 14 20 Li2 0.057 0.019 b 12 23 15305.246 31084.633 2 22 6Li7Li 0.008 0.006 b 12 23 15330.465 31109.852 2 23 6Li7Li 0.003 -0.008 b 12 23 15356.734 31136.121 2 24 6Li7Li 0.004 -0.015 b 12 23 15582.684 31362.071 3 22 6Li7Li 0.013 0.019 b 12 23 15607.622 31387.009 3 23 6Li7Li 0.011 0.015 b 12 23 15633.600 31412.987 3 24 6Li7Li 0.014 0.016 b 12 23 15856.605 31635.992 4 22 6Li7Li -0.028 -0.007 b 12 23 15856.587 31635.974 4 22 6Li7Li -0.010 0.011 b 12 23 15856.618 31636.005 4 22 6Li7Li -0.041 -0.020 b 12 23 15881.271 31660.658 4 23 6Li7Li -0.035 -0.010 b 12 23 15881.247 31660.634 4 23 6Li7Li -0.011 0.014 A 5 24 15881.039 31660.651 4 23 6Li7Li -0.028 -0.003 A 5 24 15881.039 31660.651 4 23 6Li7Li -0.028 -0.003 b 12 23 15906.969 31686.356 4 24 6Li7Li -0.041 -0.011 b 12 23 15906.962 31686.349 4 24 6Li7Li -0.034 -0.004 b 12 23 15906.946 31686.333 4 24 6Li7Li -0.018 0.012 * These data are excluded from the fits due to perturbations. 6 The Li2 data are from Xie et al., J. Mol. Spectrosc. 117 (1986) 228-244. 7 The Li2 data are from Yiannopoulou et al., J. Mol. Spectrosc. 172 (1995) 567-572 and Russier et al., J. Mol. Spectrosc. 184 (1997) 129-139. 3 Table 3 OODR excitation data of the Li2 2 g state.
3 Intermediate Probe Freq. 2 g levels Calc.BOB-Obs. Calc.Dun-Obs. levels (cm-1) (cm-1) (cm-1) A/b υ N Term value (cm- υ N 1)
7 b 19 5 12701.181 29944.677 0 4 Li2 -0.029 0.005
7 b 19 5 12704.443 29947.939 0 5 Li2 -0.035 -0.003
7 b 19 5 12708.337 29951.827 0 6 Li2 -0.018 0.013
7 b 19 10 12676.440 29967.436 0 9 Li2 -0.018 0.006
7 b 19 10 12682.941 29973.938 0 10 Li2 -0.022 -0.002
7 b 19 10 12690.060 29981.056 0 11 Li2 0.004 0.020
7 b 19 5 12887.526 30131.021 1 4 Li2 -0.029 -0.012
7 b 19 5 12890.792 30134.288 1 5 Li2 -0.039 -0.023
7 b 19 5 12894.689 30138.182 1 6 Li2 -0.025 -0.012
7 b 19 10 12862.812 30153.808 1 9 Li2 -0.033 -0.028
7 b 19 10 12869.323 30160.319 1 10 Li2 -0.042 -0.041
7 b 19 10 12876.443 30167.439 1 11 Li2 -0.015 -0.018
7 b 19 5 13071.577 30315.073 2 4 Li2 0.011 0.018
7 b 19 5 13074.866 30318.361 2 5 Li2 -0.019 -0.013
7 b 19 5 13078.764 30322.259 2 6 Li2 -0.008 -0.005
7 b 19 10 13046.902 30337.898 2 9 Li2 -0.024 -0.031
7 b 19 10 13053.412 30344.409 2 10 Li2 -0.031 -0.043
7 b 19 10 13060.546 30351.542 2 11 Li2 -0.015 -0.031
7 b 19 10 13228.809 30519.806 3 9 Li2 -0.001 -0.014
7 b 19 10 13235.342 30526.338 3 10 Li2 -0.030 -0.047
7 b 19 10 13242.459 30533.455 3 11 Li2 0.003 -0.021
7 b 19 5 13433.338 30676.834 4 4 Li2 0.029 0.034
7 b 19 5 13440.519 30684.015 4 6 Li2 0.015 0.013
7 b 19 10 13408.672 30699.668 4 9 Li2 -0.019 -0.035
7 b 19 10 13422.32 30713.316 4 11 Li2 -0.019 -0.046
7 b 19 10 13422.303 30713.299 4 11 Li2 -0.002 -0.029
7 b 19 5 13611.161 30854.657 5 4 Li2 0.046 0.054
7 b 19 5 13618.330 30861.826 5 6 Li2 0.040 0.040
7 b 19 10 13586.485 30877.481 5 9 Li2 -0.005 -0.020
7 b 19 10 13600.126 30891.122 5 11 Li2 -0.005 -0.034
7 b 19 5 13787.044 31030.540 6 4 Li2 0.057 0.069
7 b 19 5 13790.316 31033.812 6 5 Li2 0.039 0.047
7 b 19 5 13794.210 31037.706 6 6 Li2 0.048 0.051
7 b 19 7 13778.792 31037.705 6 6 Li2 0.049 0.052 7 b 19 7 13783.367 31042.280 6 7 Li2 0.025 0.023
7 b 19 7 13788.545 31047.458 6 8 Li2 0.047 0.039
7 b 19 10 13762.337 31053.333 6 9 Li2 0.019 0.004
7 b 19 10 13768.830 31059.826 6 10 Li2 0.018 -0.004
7 b 19 10 13775.97 31066.966 6 11 Li2 0.015 -0.015
7 b 19 5 13961.044 31204.540 7 4 Li2 0.060 0.077
1 7 b 19 5 13963.504 31207.814 7 5 Li2
7 b 19 5 13968.201 31211.697 7 6 Li2 0.052 0.059
7 b 19 7 13952.806 31211.719 7 6 Li2 0.030 0.037
7 b 19 7 13957.344 31216.257 7 7 Li2 0.039 0.040
7 b 19 7 13962.589 31221.502 7 8 Li2 -0.012 -0.017
7 b 19 10 13936.348 31227.344 7 9 Li2 -0.013 -0.027
7 b 19 10 13949.926 31240.922 7 11 Li2 0.023 -0.008
7 b 19 10 14108.454 31399.450 8 9 Li2 0.012 0.000
7 b 19 10 14122.064 31413.060 8 11 Li2 -0.001 -0.033
7 b 19 5 15132.826 32376.322 14 5 Li2 0.007 0.036
7 b 19 5 15136.672 32380.168 14 6 Li2 0.004 0.023
7 b 19 7 15121.254 32380.167 14 6 Li2 0.005 0.024
7 b 19 7 15130.861 32389.774 14 8 Li2 -0.002 -0.007
7 b 19 10 15104.509 32395.505 14 9 Li2 0.022 0.003
7 b 19 10 15117.980 32408.976 14 11 Li2 -0.034 -0.084
7 b 19 5 15289.818 32533.314 15 4 Li2 0.022 0.060
7 b 19 5 15293.028 32536.524 15 5 Li2 0.006 0.035
7 b 19 5 15296.855 32540.351 15 6 Li2 0.011 0.029
7 b 19 7 15281.444 32540.357 15 6 Li2 0.005 0.023
7 b 19 7 15285.926 32544.839 15 7 Li2 -0.010 -0.003
7 b 19 7 15291.034 32549.947 15 8 Li2 -0.014 -0.021
7 b 19 10 15264.717 32555.713 15 9 Li2 -0.042 -0.064
7 b 19 10 15271.151 32562.147 15 10 Li2 -0.105 -0.144
7 b 19 10 15278.098 32569.094 15 11 Li2 -0.050 -0.105
7 b 19 5 15605.370 32848.866 17 4 Li2 0.049 0.086
7 b 19 5 15608.564 32852.060 17 5 Li2 0.027 0.055
7 b 19 5 15612.371 32855.867 17 6 Li2 0.026 0.042
7 b 19 7 15596.959 32855.872 17 6 Li2 0.021 0.037
7 b 19 7 15601.405 32860.318 17 7 Li2 0.013 0.016
7 b 19 7 15606.483 32865.396 17 8 Li2 0.004 -0.008
7 b 19 10 15580.118 32871.114 17 9 Li2 -0.015 -0.044
7 b 19 10 15580.130 32871.126 17 9 Li2 -0.027 -0.056
7 b 19 10 15593.423 32884.419 17 11 Li2 -0.038 -0.103 7 b 19 10 15593.412 32884.408 17 11 Li2 -0.027 -0.092
7 b 19 10 15735.430 33026.426 18 9 Li2 -0.017 -0.048
7 b 19 10 15741.736 33032.732 18 10 Li2 -0.019 -0.069
7 b 19 10 15748.679 33039.675 18 11 Li2 -0.033 -0.103
7 b 19 5 16663.317 33906.813 24 5 Li2 -0.034 -0.003
7 b 19 5 16666.975 33910.471 24 6 Li2 0.000 0.017
7 b 19 10 16634.164 33925.159 24 9 Li2 0.059 0.024
7 b 19 10 16647.055 33938.051 24 11 Li2 0.046 -0.032
7 b 19 5 16804.653 34048.149 25 4 Li2 0.020 0.064
7 b 19 5 16807.753 34051.249 25 5 Li2 -0.018 0.014
7 b 19 5 16811.397 34054.893 25 6 Li2 0.010 0.029
7 b 19 10 16778.490 34069.486 25 9 Li2 0.087 0.054
7 b 19 10 16784.799 34075.795 25 10 Li2 -0.118 -0.172
7 b 19 10 16791.474 34082.470 25 11 Li2 -0.085 -0.160
7 b 19 5 16947.485 34190.981 26 4 Li2 0.115 0.161
7 b 19 5 16950.549 34194.045 26 5 Li2 0.097 0.131
7 b 19 7 16938.825 34197.738 26 6 Li2 0.056 0.077
7 b 19 7 16947.849 34206.762 26 8 Li2 0.156 0.144
2 7 b 19 10 16919.82 34210.862 26 9 Li2
7 b 19 10 16927.429 34218.425 26 10 Li2 0.031 -0.020
7 b 19 10 16933.767 34224.763* 26 11 Li2
7 b 19 5 17235.633 34479.129 28 6 Li2 -0.162 -0.138
7 b 19 10 17202.453 34493.449 28 9 Li2 -0.056 -0.081
7 b 19 10 17208.618 34499.614 28 10 Li2 -0.220 -0.264
7 b 19 10 17215.143 34506.139 28 11 Li2 -0.150 -0.214
7 b 19 5 17367.142 34610.638 29 4 Li2 0.031 0.078
7 b 19 5 17370.098 34613.594 29 5 Li2 0.068 0.105
7 b 19 7 17358.226 34617.139 29 6 Li2 0.113 0.138
7 b 19 7 17367.215 34626.128 29 8 Li2 0.090 0.085
3 7 b 19 10 17339.361 34630.388 29 9 Li2
7 b 19 10 17346.55 34637.546 29 10 Li2 0.010 -0.029
7 b 19 10 17352.770 34643.766* 29 11 Li2
7 b 19 10 17477.322 34768.318 30 9 Li2 -0.065 -0.084
7 b 19 10 17489.823 34780.819 30 11 Li2 -0.123 -0.177
7 A 15 24 34888.075* 30 22 Li2
7 b 19 5 17905.111 35148.607 33 4 Li2 0.000 0.038
7 b 19 5 17911.560 35155.056 33 6 Li2 -0.033 -0.012
7 b 19 10 17878.064 35169.060 33 9 Li2 -0.064 -0.076
7 b 19 10 17890.286 35181.282 33 11 Li2 -0.087 -0.123 7 b 19 5 18035.569 35279.065 34 4 Li2 0.167 0.199
7 b 19 5 18042.151 35285.647 34 6 Li2 -0.044 -0.026
7 b 19 10 18008.572 35299.568 34 9 Li2 -0.088 -0.099
7 b 19 10 18020.661 35311.657 34 11 Li2 -0.063 -0.094
7 b 19 5 18164.813 35408.309 35 4 Li2 -0.013 0.012
7 b 19 5 18167.719 35411.215 35 5 Li2 -0.042 -0.023
7 b 19 7 18155.687 35414.600 35 6 Li2 0.023 0.035
7 b 19 7 18164.311 35423.224 35 8 Li2 0.015 0.012
7 b 19 10 18136.735 35427.731* 35 9 Li2
7 b 19 10 18149.366 35440.362 35 11 Li2 0.067 0.042
7 b 19 5 18292.339 35535.835 36 4 Li2 -0.048 -0.032
7 b 19 5 18298.608 35542.104 36 6 Li2 -0.036 -0.029
7 b 19 10 18264.799 35555.795 36 9 Li2 -0.048 -0.058
7 b 19 10 18276.690 35567.686 36 11 Li2 0.001 -0.018
7 b 19 5 18417.496 35660.992* 37 4 Li2
7 b 19 5 18424.059 35667.555* 37 6 Li2
7 b 19 10 18390.368 35681.364 37 9 Li2 0.137 0.128
7 b 19 10 18402.288 35693.284 37 11 Li2 0.068 0.055
7 b 19 10 18515.210 35806.206* 38 9 Li2
7 b 19 10 18526.059 35817.055* 38 11 Li2
7 b 19 10 18637.443 35928.439* 39 9 Li2
7 b 19 10 18649.286 35940.282* 39 11 Li2
7 b 19 10 18757.905 36048.901 40 9 Li2 0.085 0.085
7 b 19 10 18769.444 36060.439 40 11 Li2 0.123 0.142
4 7 b 19 5 18905.055 36149.051 41 4 Li2
7 b 19 5 18911.534 36155.030 41 6 Li2 -0.064 -0.081
7 b 19 10 18877.250 36168.246 41 9 Li2 -0.123 -0.114
7 b 19 10 18887.709 36178.705* 41 11 Li2
6 b 9 32 14950.335 30316.17 0 31 Li2 0.139 0.172
6 b 9 32 14998.215 30364.050 0 33 Li2 0.010 -0.023
6 b 9 32 15151.608 30517.443 1 31 Li2 0.031 0.063
6 b 9 32 15199.478 30565.313 1 33 Li2 -0.092 -0.116
6 b 9 32 15350.067 30715.902 2 31 Li2 -0.001 0.032
6 b 9 32 15397.905 30763.740 2 33 Li2 -0.113 -0.126
6 b 9 32 15545.899 30911.734 3 31 Li2 -0.031 0.003
6 b 9 32 15593.707 30959.542 3 33 Li2 -0.150 -0.154
6 b 9 32 15738.960 31104.795 4 31 Li2 0.187 0.221
6 b 9 32 15786.789 31152.624 4 33 Li2 -0.006 -0.002 6 b 9 32 16352.129 31717.964 7 33 Li2 -0.062 -0.051
6 b 9 32 16488.648 31854.483 8 31 Li2 0.010 0.021
6 b 9 32 16535.96 31901.795 8 33 Li2 -0.032 -0.024
6 b 9 32 16670.446 32036.281 9 31 Li2 0.012 0.012
6 b 9 32 16717.645 32083.480 9 33 Li2 -0.045 -0.042
6 b 9 32 16850.016 32215.851 10 31 Li2 0.113 0.100
6 b 9 32 16897.055 32262.890 10 33 Li2 0.073 0.070
6 b 9 32 17027.639 32393.474 11 31 Li2 0.070 0.044
6 b 9 32 17074.506 32440.341 11 33 Li2 0.046 0.037
6 b 9 32 17203.192 32569.027 12 31 Li2 0.041 0.003
6 b 9 32 17249.951 32615.786 12 33 Li2 -0.044 -0.060
6 b 9 32 17376.393 32742.228* 13 31 Li2
6 b 9 32 17423.128 32788.963 13 33 Li2 0.094 0.074
6 b 9 32 17548.125 32913.960 14 31 Li2 0.102 0.044
6 b 9 32 17594.447 32960.282 14 33 Li2 0.077 0.055
6 b 9 32 17717.680 33083.515 15 31 Li2 0.065 0.002
6 b 9 32 18050.902 33416.737 17 31 Li2 0.018 -0.041
6 b 9 32 18096.577 33462.412 17 33 Li2 -0.019 -0.018
6 b 9 32 18214.545 33580.380 18 31 Li2 0.064 0.016
6 b 9 32 18260.047 33625.882 18 33 Li2 -0.043 -0.021
6 b 9 32 18421.621 33787.456 19 33 Li2 -0.095 -0.044
6 b 9 32 18536.320 33902.155 20 31 Li2 -0.063 -0.067
6 b 9 32 18581.265 33947.100 20 33 Li2 -0.131 -0.042
6 b 15 19 15236.388 31977.352 10 18 Li2 -0.093 0.049
6 b 15 19 15265.365 32006.329 10 20 Li2 -0.099 0.007
6 b 15 19 15414.653 32155.617 11 18 Li2 -0.065 0.063
6 b 15 19 15443.565 32184.529 11 20 Li2 -0.085 0.003
6 b 15 19 15590.994 32331.958 12 18 Li2 -0.102 0.011
6 b 15 19 15619.806 32360.77 12 20 Li2 -0.110 -0.039
6 b 15 19 15765.349 32506.313 13 18 Li2 -0.114 -0.017
6 b 15 19 15794.055 32535.019 13 20 Li2 -0.112 -0.058
6 b 15 19 16443.484 33184.448 17 18 Li2 -0.061 -0.015
6 b 15 19 16471.723 33212.687 17 20 Li2 -0.048 -0.051
6 b 15 19 16608.258 33349.222 18 18 Li2 0.000 0.037
6 b 15 19 16636.381 33377.345 18 20 Li2 -0.003 -0.015
6 b 15 19 16771.208 33512.172 19 18 Li2 0.025 0.057
6 b 15 19 16799.201 33540.165 19 20 Li2 0.015 -0.002
6 b 15 19 16932.288 33673.252 20 18 Li2 0.073 0.102
6 b 15 19 16960.186 33701.150 20 20 Li2 0.012 -0.006 6 b 15 19 17248.985 33989.949 22 18 Li2 0.118 0.152
6 b 15 19 17276.680 34017.644 22 20 Li2 -0.047 -0.057
6 b 15 19 17404.672 34145.636 23 18 Li2 0.062 0.103
6 b 15 19 17432.023 34172.987 23 20 Li2 0.078 0.079
6 b 15 19 17558.424 34299.388 24 18 Li2 0.121 0.174
6 b 15 19 17585.656 34326.62 24 20 Li2 0.088 0.104 b 12 23 14724.916 30504.303 2 22 6Li7Li 0.065 0.108 b 12 23 14757.583 30536.97 2 24 6Li7Li 0.040 0.057 b 12 23 14913.997 30693.384 3 22 6Li7Li 0.037 0.066 b 12 23 14946.647 30726.034 3 24 6Li7Li 0.019 0.022 b 12 23 15100.801 30880.188 4 22 6Li7Li -0.008 0.009 b 12 23 15100.817 30880.204 4 22 6Li7Li -0.024 -0.007 b 12 23 15116.804 30896.191 4 23 6Li7Li -0.040 -0.036 b 12 23 15116.809 30896.196 4 23 6Li7Li -0.045 -0.041 b 12 23 15133.452 30912.839 4 24 6Li7Li -0.048 -0.057 b 12 23 15133.463 30912.850 4 24 6Li7Li -0.059 -0.068 b 12 23 15285.324 31064.711 5 22 6Li7Li 0.014 0.019 b 12 23 15317.922 31097.309 5 24 6Li7Li -0.004 -0.025 b 12 23 15467.729 31247.116 6 22 6Li7Li 0.010 0.002 b 12 23 15500.285 31279.672 6 24 6Li7Li -0.006 -0.041 b 12 23 15648.077 31427.464 7 22 6Li7Li -0.020 -0.040 b 12 23 15648.078 31427.465 7 22 6Li7Li -0.021 -0.041 b 12 23 15663.908 31443.295 7 23 6Li7Li 0.062 0.027 b 12 23 15663.903 31443.290 7 23 6Li7Li 0.067 0.032 b 12 23 15680.584 31459.971 7 24 6Li7Li -0.036 -0.085 b 12 23 15826.326 31605.713 8 22 6Li7Li 0.023 -0.012 b 12 23 15858.776 31638.163 8 24 6Li7Li 0.004 -0.060
* These data are excluded from the fits due to perturbations. 6 The Li2 data are from Xie et al., J. Mol. Spectrosc. 117 (1986) 228-244. 7 The Li2 data are from Yiannopoulou et al., J. Chem. Phys. 103 (1995) 5898-5903 and Li et al., J. Chem. Phys. 105 (1996) 9859-9863. 1,2,3,4 These data are questionable and excluded from the fits because the intermediate term values derived from the upper levels and probe frequencies do not agree with the known intermediate term values. Table 4 Differences between calculated term values and experimental data of the Li2 3 + 3 g state. 3 + intermediate levels Probe 3 g levels Calc.Dun-Obs. Calc.RKR-Obs. A/b υ N Freq. (cm- Term value υ N (cm-1) (cm-1) 1) (cm-1) 7 b 19 5 16245.634 33489.130 9 5 -0.044 -0.107 Li2 7 b 19 7 16235.756 33494.669 9 6 -0.022 -0.085 Li2
7 b 19 7 16249.659 33508.572 9 8 -0.030 -0.095 Li2
7 b 19 10 16235.264 33526.260 9 10 -0.135 -0.204 Li2
7 b 19 5 16483.496 33726.991 10 5 0.034 -0.040 Li2
7 b 19 7 16473.531 33732.444 10 6 0.074 0.000 Li2
7 b 19 7 16487.537 33746.450 10 8 -0.207 -0.282 Li2
7 b 19 10 16472.653 33763.653 10 10 -0.041 -0.121 Li2
7 b 19 5 16717.780 33961.276 11 5 0.080 -0.006 Li2
7 b 19 7 16707.750 33966.663 11 6 0.118 0.032 Li2
7 b 19 7 16721.310 33980.223 11 8 0.114 0.026 Li2
7 b 19 10 16706.473 33997.473 11 10 0.017 -0.074 Li2
7 b 19 5 16948.440 34191.937 12 5 0.119 0.019 Li2
7 b 19 10 16936.700 34227.700 12 10 0.038 -0.067 Li2
7 b 19 5 17175.520 34419.016 13 5 0.086 -0.028 Li2
7 b 19 10 17163.292 34454.292 13 10 0.040 -0.079 Li2
7 b 19 5 17398.938 34642.434 14 5 0.040 -0.089 Li2
7 b 19 10 17386.263 34677.263 14 10 -0.012 -0.146 Li2
7 A 16 12 17000.321 34927.316 15 13 -0.021 -0.182 Li2
7 b 19 5 17834.679 35078.175 16 5 -0.073 -0.233 Li2
7 b 19 10 17821.053 35112.049 16 10 -0.074 -0.240 Li2
7 b 19 5 18046.947 35290.443 17 5 -0.129 -0.304 Li2
7 b 19 10 18032.812 35323.808 17 10 -0.074 -0.254 Li2
7 b 19 5 18255.389 35498.885 18 5 -0.123 -0.314 Li2
7 b 19 10 18240.802 35531.798 18 10 -0.068 -0.267 Li2
7 b 19 5 18459.963 35703.459 19 5 -0.036 -0.273 Li2
7 b 19 10 18444.876 35735.872 19 10 0.066 -0.187 Li2
7 b 19 10 18645.120 35936.116 20 10 0.222 -0.281 Li2
6 b 9 32 16725.791 32091.626 1 32 0.116 -1.149 Li2
6 b 9 32 17005.214 32371.049 2 32 0.048 -1.144 Li2
6 b 9 32 17280.682 32646.517 3 32 -0.071 -1.197 Li2
6 b 9 32 17551.932 32917.767 4 32 -0.007 -1.075 Li2 6 b 9 32 18082.596 33448.431 6 32 -0.258 -1.236 Li2
6 b 9 32 18341.199 33707.034 7 32 0.182 -0.766 Li2
6 b 15 19 16602.720 33343.684 7 19 -0.026 -0.210 Li2
6 b 15 19 16862.359 33603.323 8 19 0.047 -0.144 Li2
6 b 15 19 17119.304 33860.268* 9 19 -1.361 -1.562 Li2 b 12 23 16523.829 32303.216* 3 23 -0.870 0.566 6Li7Li b 12 23 16790.508 32569.895 4 23 -0.054 -0.348 6Li7Li b 12 23 17052.635 32832.022 5 23 -0.193 -0.481 6Li7Li b 12 23 17310.570 33089.957 6 23 0.065 -0.217 6Li7Li b 12 23 17564.827 33344.214 7 23 0.184 -0.098 6Li7Li * These data are excluded from the fits due to perturbations. 6 The Li2 data are from Xie et al., J. Mol. Spectrosc. 117 (1986) 228-244. 7 The Li2 data are from Yiannopoulou et al., J. Chem. Phys. 102 (1995) 3024-3031. Table 5 Differences between caculated term values and experimental data of the Li2 3 1 g state. 3 1 g levels Calc.Dun-Obs. Calc.BOB-Obs. Calc.RKR-Obs. Calc.DPF-Obs. υ N Term value (cm-1) (cm-1) (cm-1) (cm-1) (cm-1) 7 9 4 32607.715 0.006 -0.024 -0.014 -0.018 Li2 7 9 5 32612.256 0.233 0.210 0.220 0.215 Li2
7 9 6 32618.224 -0.016 -0.030 -0.019 -0.026 Li2
7 9 5 32612.265 0.224 0.201 0.211 0.206 Li2
7 9 7 32624.858 0.020 0.016 0.027 0.018 Li2
7 9 9 32641.103 -0.036 -0.016 -0.006 -0.019 Li2
7 9 10 32650.414 0.168 0.202 0.212 0.197 Li2
7 9 11 32661.108 -0.065 -0.016 -0.007 -0.025 Li2
7 9 9 32641.105 -0.038 -0.018 -0.008 -0.021 Li2
7 9 10 32650.419 0.163 0.197 0.207 0.192 Li2
7 9 11 32661.116 -0.073 -0.024 -0.015 -0.033 Li2
7 10 4 32854.603 0.126 0.084 0.090 0.116 Li2
7 10 5 32859.325 0.118 0.085 0.091 0.115 Li2
7 10 6 32864.994 0.103 0.080 0.087 0.109 Li2
7 10 6 32865.085 0.012 -0.011 -0.004 0.018 Li2
7 10 7 32871.694 -0.001 -0.013 -0.007 0.014 Li2
7 10 8 32879.247 -0.020 -0.019 -0.013 0.005 Li2
7 10 8 32879.243 -0.016 -0.015 -0.009 0.009 Li2
7 10 11 32907.522 -0.073 -0.025 -0.019 -0.009 Li2
7 10 9 32887.728 -0.030 -0.014 -0.008 0.008 Li2
7 10 10 32897.154 -0.047 -0.016 -0.011 0.003 Li2
7 10 11 32907.523 -0.074 -0.026 -0.020 -0.010 Li2
7 10 9 32887.730 -0.032 -0.016 -0.010 0.006 Li2
7 10 10 32897.158 -0.051 -0.020 -0.015 -0.001 Li2
7 10 11 32907.518 -0.069 -0.021 -0.015 -0.005 Li2
7 11 9 33131.114 -0.020 -0.006 -0.005 0.019 Li2
7 11 10 33140.435 -0.040 -0.008 -0.008 0.013 Li2
7 11 11 33150.682 -0.061 -0.012 -0.012 0.006 Li2
7 13 9 33608.176 -0.008 0.009 -0.007 -0.002 Li2
7 13 10 33617.289 -0.032 0.003 -0.013 -0.008 Li2
7 13 11 33627.303 -0.053 0.001 -0.016 -0.012 Li2
7 15 9 34072.361 -0.118 -0.098 -0.140 -0.148 Li2 7 15 11 34090.997 -0.115 -0.059 -0.100 -0.104 Li2
7 15 10 34081.222 -0.101 -0.063 -0.105 -0.111 Li2
7 16 4 34268.748 -0.113 -0.159 -0.217 -0.231 Li2
7 16 5 34272.938 0.092 0.057 -0.002 -0.014 Li2
7 16 6 34278.227 0.076 0.052 -0.006 -0.015 Li2
7 17 4 34492.741 0.108 0.065 -0.013 -0.008 Li2
7 17 5 34497.102 0.090 0.056 -0.020 -0.013 Li2
7 17 5 34497.099 0.093 0.059 -0.018 -0.010 Li2
7 17 6 34502.319 0.083 0.061 -0.016 -0.005 Li2
7 17 7 34508.378 0.100 0.091 0.015 0.030 Li2
7 17 8 34515.329 0.091 0.095 0.020 0.040 Li2
7 17 9 34523.288 -0.062 -0.042 -0.118 -0.093 Li2
7 17 10 34531.979 -0.084 -0.048 -0.124 -0.093 Li2
7 17 11 34541.532 -0.106 -0.054 -0.130 -0.093 Li2
7 20 4 35145.489 0.070 0.036 -0.110 0.035 Li2
7 20 6 35154.705 0.063 0.045 -0.099 0.056 Li2
7 20 9 35174.857 -0.012 -0.001 -0.144 0.033 Li2
7 20 10 35183.236 -0.032 -0.011 -0.155 0.031 Li2
7 20 11 35192.438 -0.045 -0.014 -0.158 0.038 Li2
7 21 4 35356.370 0.035 0.006 -0.164 0.035 Li2
7 21 5 35360.513 0.027 0.005 -0.165 0.039 Li2
7 21 6 35365.485 0.016 0.000 -0.169 0.041 Li2
7 21 9 35385.328 0.003 0.010 -0.159 0.073 Li2
7 21 10 35393.596 -0.010 0.005 -0.164 0.077 Li2
7 21 11 35402.682 -0.019 0.003 -0.168 0.084 Li2
7 22 4 35563.837 0.005 -0.016 -0.210 0.030 Li2
7 22 5 35567.925 0.001 -0.016 -0.209 0.035 Li2
7 22 6 35572.831 -0.006 -0.017 -0.211 0.039 Li2
7 22 9 35592.451 -0.042 -0.038 -0.231 0.039 Li2
7 22 10 35600.609 -0.047 -0.038 -0.233 0.046 Li2
7 22 11 35609.576 -0.050 -0.038 -0.234 0.054 Li2
7 23 4 35767.828 0.010 -0.001 -0.220 0.035 Li2
7 23 5 35771.923 -0.052 -0.060 -0.279 -0.021 Li2
7 23 6 35776.763 -0.054 -0.059 -0.278 -0.015 Li2
7 23 9 35796.107 -0.060 -0.057 -0.278 0.002 Li2
7 23 10 35804.153 -0.055 -0.051 -0.274 0.013 Li2
7 23 11 35812.950 0.000 0.004 -0.223 0.073 Li2
7 24 10 36004.186 -0.025 -0.024 -0.311 -0.033 Li2
7 24 11 36012.806 0.095 0.091 -0.201 0.084 Li2 7 25 9 36192.849 0.013 0.023 -0.477 -0.129 Li2
7 25 10 36200.676 0.035 0.037 -0.476 -0.119 Li2
7 25 11 36209.287 0.053 0.046 -0.483 -0.115 Li2
7 24 9 35996.472* -0.539 Li2
7 10 2 32848.267 -0.140 -0.193 -0.187 -0.160 Li2
7 10 3 32850.929 0.028 -0.021 -0.014 0.012 Li2
7 10 3 32850.990 -0.033 -0.082 -0.075 -0.049 Li2
7 10 4 32854.706 0.023 -0.019 -0.012 0.013 Li2
7 10 4 32854.815 -0.086 -0.128 -0.122 -0.096 Li2
7 10 5 32859.407 0.036 0.003 0.009 0.033 Li2
7 10 5 32859.437 0.006 -0.027 -0.021 0.003 Li2
7 10 6 32865.109 -0.012 -0.035 -0.028 -0.006 Li2
7 10 6 32865.086 0.011 -0.012 -0.005 0.017 Li2
7 10 7 32871.730 -0.037 -0.049 -0.043 -0.022 Li2
7 10 7 32871.705 -0.012 -0.024 -0.018 0.003 Li2
7 10 8 32879.198 0.029 0.030 0.036 0.054 Li2
7 10 8 32879.252 -0.025 -0.024 -0.018 0.000 Li2
7 10 9 32887.768 -0.070 -0.054 -0.048 -0.032 Li2
7 10 9 32887.678 0.020 0.036 0.042 0.058 Li2
7 10 10 32897.181 -0.074 -0.043 -0.038 -0.024 Li2
7 10 11 32907.549 -0.100 -0.052 -0.046 -0.036 Li2
7 10 12 32918.838 -0.113 -0.047 -0.042 -0.035 Li2
7 10 13 32931.069 -0.137 -0.053 -0.048 -0.045 Li2
7 10 14 32944.225 -0.156 -0.053 -0.050 -0.050 Li2
7 15 4 34041.012 0.120 0.072 0.030 0.012 Li2
7 15 6 34050.835 0.081 0.055 0.013 -0.001 Li2
7 15 8 34064.314 -0.066 -0.062 -0.104 -0.115 Li2
7 15 9 34072.238 0.005 0.025 -0.017 -0.025 Li2
7 15 10 34081.136 -0.015 0.023 -0.019 -0.025 Li2
7 15 11 34090.930 -0.048 0.008 -0.033 -0.037 Li2
7 15 14 34125.555 -0.113 0.003 -0.041 -0.036 Li2
7 17 6 34502.329 0.073 0.051 -0.026 -0.015 Li2
7 17 9 34523.225 0.001 0.021 -0.055 -0.030 Li2
7 17 10 34531.915 -0.020 0.016 -0.060 -0.029 Li2
7 17 11 34541.548 -0.122 -0.070 -0.146 -0.109 Li2
6 3 31 31699.975 0.039 -0.047 0.073 -0.091 Li2
6 3 32 31736.626 -0.004 -0.076 0.071 -0.076 Li2
6 3 33 31774.347 -0.060 -0.116 0.063 -0.065 Li2
6 4 31 31980.136 0.067 0.038 0.147 -0.009 Li2 6 4 32 32016.351 0.044 0.029 0.163 0.020 Li2
6 4 33 32053.614 0.019 0.018 0.181 0.053 Li2
6 5 32 32292.372 -0.001 0.030 0.151 0.032 Li2
6 5 33 32329.212 -0.029 0.012 0.162 0.052 Li2
6 7 31 32797.921 0.124 0.200 0.275 0.201 Li2
6 7 32 32833.006 -0.008 0.071 0.166 0.089 Li2
6 7 33 32868.996 -0.032 0.046 0.165 0.085 Li2
6 9 31 33324.488 -0.028 0.040 0.082 0.031 Li2
6 9 32 33358.632 -0.036 0.018 0.076 0.016 Li2
6 9 33 33393.758 -0.035 -0.001 0.076 0.008 Li2
6 10 31 33582.135 -0.093 -0.060 -0.041 -0.080 Li2
6 10 32 33615.797 -0.024 -0.016 0.016 -0.033 Li2
6 10 33 33650.502 -0.020 -0.043 0.005 -0.053 Li2
6 11 31 33835.861 0.013 -0.011 -0.022 -0.040 Li2
6 11 32 33869.173 0.027 -0.034 -0.035 -0.060 Li2
6 11 33 33903.445 0.050 -0.058 -0.045 -0.079 Li2
6 6 18 32165.539 0.048 -0.059 -0.047 -0.161 Li2
6 6 19 32186.972 0.096 0.002 0.014 -0.100 Li2
6 6 20 32209.612 0.037 -0.044 -0.031 -0.144 Li2
6 7 18 32438.648 0.052 -0.040 -0.030 -0.069 Li2
6 7 19 32459.891 0.035 -0.040 -0.031 -0.072 Li2
6 7 20 32482.224 0.016 -0.043 -0.033 -0.077 Li2
6 8 18 32708.011 0.027 -0.050 -0.043 -0.029 Li2
6 8 19 32729.008 0.002 -0.055 -0.049 -0.040 Li2
6 8 20 32751.079 -0.022 -0.059 -0.054 -0.049 Li2
6 10 18 33235.284 0.122 0.072 0.065 0.124 Li2
6 10 19 33255.858 0.017 -0.012 -0.020 0.033 Li2
6 10 20 33277.342 0.051 0.043 0.033 0.080 Li2
6 11 18 33493.351 0.087 0.044 0.027 0.090 Li2
6 11 19 33513.765 -0.109 -0.131 -0.150 -0.091 Li2
6 11 20 33534.867 0.045 0.042 0.021 0.075 Li2
6 12 18 33747.589 0.108 0.066 0.036 0.102 Li2
6 12 19 33767.595 0.070 0.048 0.015 0.079 Li2
6 12 20 33788.640 0.019 0.014 -0.022 0.040 Li2
6 14 18 34244.743 0.109 0.048 -0.019 0.084 Li2
6 14 19 34264.244 0.081 0.033 -0.038 0.069 Li2
6 14 20 34284.741 0.057 0.019 -0.057 0.055 Li2
2 22 31084.633 0.008 0.006 0.022 0.010 6Li7Li 2 23 31109.852 0.003 -0.008 0.012 0.012 6Li7Li 2 24 31136.121 0.004 -0.015 0.009 0.023 6Li7Li 3 22 31362.071 0.013 0.019 0.034 -0.025 6Li7Li 3 23 31387.009 0.011 0.015 0.033 -0.015 6Li7Li 3 24 31412.987 0.014 0.016 0.038 0.003 6Li7Li 4 22 31635.992 -0.028 -0.007 0.008 -0.017 6Li7Li 4 22 31635.974 -0.010 0.011 0.026 0.001 6Li7Li 4 22 31636.005 -0.041 -0.020 -0.005 -0.030 6Li7Li 4 23 31660.658 -0.035 -0.010 0.008 -0.009 6Li7Li 4 23 31660.634 -0.011 0.014 0.032 0.015 6Li7Li 4 23 31660.651 -0.028 -0.003 0.015 -0.002 6Li7Li 4 23 31660.651 -0.028 -0.003 0.015 -0.002 6Li7Li 4 24 31686.356 -0.041 -0.011 0.010 0.002 6Li7Li 4 24 31686.349 -0.034 -0.004 0.017 0.009 6Li7Li 4 24 31686.333 -0.018 0.012 0.033 0.025 6Li7Li * These data are excluded from the fits due to perturbations. 6 The Li2 data are from Xie et al., J. Mol. Spectrosc. 117 (1986) 228-244. 7 The Li2 data are from Yiannopoulou et al., J. Mol. Spectrosc. 172 (1995) 567-572 and Russier et al., J. Mol. Spectrosc. 184 (1997) 129-139. Table 6 Differences between calculated term values and experimental data of the Li2 3 2 g state. 3 2 g levels Calc.Dun-Obs. Calc.BOB-Obs. Calc.RKR-Obs. Calc.DPF-Obs. υ N Term value (cm-1) (cm-1) (cm-1) (cm-1) (cm-1) 7 0 4 29944.677 0.005 -0.029 -0.014 0.049 Li2 7 0 5 29947.939 -0.003 -0.035 -0.020 0.036 Li2
7 0 6 29951.827 0.013 -0.018 -0.002 0.045 Li2
7 0 9 29967.436 0.006 -0.018 0.001 0.014 Li2
7 0 10 29973.938 -0.002 -0.022 -0.002 -0.002 Li2
7 0 11 29981.056 0.020 0.004 0.026 0.010 Li2
7 1 4 30131.021 -0.012 -0.029 0.012 0.040 Li2
7 1 5 30134.288 -0.023 -0.039 0.003 0.026 Li2
7 1 6 30138.182 -0.012 -0.025 0.017 0.033 Li2
7 1 9 30153.808 -0.028 -0.033 0.012 0.002 Li2
7 1 10 30160.319 -0.041 -0.042 0.003 -0.017 Li2
7 1 11 30167.439 -0.018 -0.015 0.033 0.001 Li2
7 2 4 30315.073 0.018 0.011 0.075 0.063 Li2
7 2 5 30318.361 -0.013 -0.019 0.045 0.030 Li2
7 2 6 30322.259 -0.005 -0.008 0.057 0.037 Li2
7 2 9 30337.898 -0.031 -0.024 0.042 0.005 Li2
7 2 10 30344.409 -0.043 -0.031 0.035 -0.009 Li2
7 2 11 30351.542 -0.031 -0.015 0.053 0.000 Li2
7 3 9 30519.806 -0.014 -0.001 0.083 0.015 Li2
7 3 10 30526.338 -0.047 -0.030 0.055 -0.017 Li2
7 3 11 30533.455 -0.021 0.003 0.088 0.011 Li2
7 4 4 30676.834 0.034 0.029 0.129 0.037 Li2
7 4 6 30684.015 0.013 0.015 0.114 0.020 Li2
7 4 9 30699.668 -0.035 -0.019 0.080 -0.017 Li2
7 4 11 30713.316 -0.046 -0.019 0.081 -0.020 Li2
7 4 11 30713.299 -0.029 -0.002 0.098 -0.003 Li2
7 5 4 30854.657 0.054 0.046 0.160 0.034 Li2
7 5 6 30861.826 0.040 0.040 0.153 0.027 Li2
7 5 9 30877.481 -0.020 -0.005 0.108 -0.016 Li2
7 5 11 30891.122 -0.034 -0.005 0.108 -0.015 Li2 7 6 4 31030.540 0.069 0.057 0.182 0.029 Li2
7 6 5 31033.812 0.047 0.039 0.163 0.011 Li2
7 6 6 31037.706 0.051 0.048 0.172 0.022 Li2
7 6 6 31037.705 0.052 0.049 0.173 0.023 Li2
7 6 7 31042.280 0.023 0.025 0.150 0.001 Li2
7 6 8 31047.458 0.039 0.047 0.171 0.024 Li2
7 6 9 31053.333 0.004 0.019 0.143 -0.003 Li2
7 6 10 31059.826 -0.004 0.018 0.141 -0.001 Li2
7 6 11 31066.966 -0.015 0.015 0.138 -0.002 Li2
7 7 4 31204.540 0.077 0.060 0.195 0.022 Li2
1 7 7 5 31207.814 0.171 Li2
7 7 6 31211.697 0.059 0.052 0.187 0.018 Li2
7 7 6 31211.719 0.037 0.030 0.165 -0.004 Li2
7 7 7 31216.257 0.040 0.039 0.173 0.007 Li2
7 7 8 31221.502 -0.017 -0.012 0.122 -0.041 Li2
7 7 9 31227.344 -0.027 -0.013 0.120 -0.041 Li2
7 7 11 31240.922 -0.008 0.023 0.155 0.002 Li2
7 8 9 31399.450 0.000 0.012 0.153 -0.017 Li2
7 8 11 31413.060 -0.033 -0.001 0.137 -0.024 Li2
7 14 5 32376.322 0.036 0.007 0.176 0.000 Li2
7 14 6 32380.168 0.023 0.004 0.172 0.000 Li2
7 14 6 32380.167 0.024 0.005 0.173 0.001 Li2
7 14 8 32389.774 -0.007 -0.002 0.165 0.001 Li2
7 14 9 32395.505 0.003 0.022 0.188 0.029 Li2
7 14 11 32408.976 -0.084 -0.034 0.128 -0.020 Li2
7 15 4 32533.314 0.060 0.022 0.194 0.017 Li2
7 15 5 32536.524 0.035 0.006 0.177 0.004 Li2
7 15 6 32540.351 0.029 0.011 0.181 0.011 Li2
7 15 6 32540.357 0.023 0.005 0.175 0.005 Li2
7 15 7 32544.839 -0.003 -0.010 0.161 -0.006 Li2
7 15 8 32549.947 -0.021 -0.014 0.155 -0.007 Li2
7 15 9 32555.713 -0.064 -0.042 0.125 -0.031 Li2
7 15 10 32562.147 -0.144 -0.105 0.060 -0.091 Li2
7 15 11 32569.094 -0.105 -0.050 0.114 -0.031 Li2
7 17 4 32848.866 0.086 0.049 0.223 0.045 Li2
7 17 5 32852.060 0.055 0.027 0.202 0.026 Li2
7 17 6 32855.867 0.042 0.026 0.200 0.028 Li2
7 17 6 32855.872 0.037 0.021 0.195 0.023 Li2
7 17 7 32860.318 0.016 0.013 0.186 0.019 Li2 7 17 8 32865.396 -0.008 0.004 0.176 0.014 Li2
7 17 9 32871.114 -0.044 -0.015 0.155 -0.001 Li2
7 17 9 32871.126 -0.056 -0.027 0.143 -0.013 Li2
7 17 11 32884.419 -0.103 -0.038 0.128 -0.016 Li2
7 17 11 32884.408 -0.092 -0.027 0.139 -0.005 Li2
7 18 9 33026.426 -0.048 -0.017 0.155 -0.004 Li2
7 18 10 33032.732 -0.069 -0.019 0.151 -0.002 Li2
7 18 11 33039.675 -0.103 -0.033 0.134 -0.011 Li2
7 24 5 33906.813 -0.003 -0.034 0.141 -0.067 Li2
7 24 6 33910.471 0.017 0.000 0.175 -0.027 Li2
7 24 9 33925.159 0.024 0.059 0.231 0.053 Li2
7 24 11 33938.051 -0.032 0.046 0.214 0.056 Li2
7 25 4 34048.149 0.064 0.020 0.193 -0.019 Li2
7 25 5 34051.249 0.014 -0.018 0.155 -0.053 Li2
7 25 6 34054.893 0.029 0.010 0.183 -0.019 Li2
7 25 9 34069.486 0.054 0.087 0.258 0.080 Li2
7 25 10 34075.795 -0.172 -0.118 0.051 -0.117 Li2
7 25 11 34082.470 -0.160 -0.085 0.082 -0.075 Li2
7 26 4 34190.981 0.161 0.115 0.286 0.078 Li2
7 26 5 34194.045 0.131 0.097 0.268 0.064 Li2
7 26 6 34197.738 0.077 0.056 0.227 0.029 Li2
7 26 8 34206.762 0.144 0.156 0.325 0.142 Li2
2 7 26 9 34210.862 1.692 Li2
7 26 10 34218.425 -0.020 0.031 0.198 0.033 Li2
7 26 11 34224.763* 0.530 Li2
7 28 6 34479.129 -0.138 -0.162 0.001 -0.181 Li2
7 28 9 34493.449 -0.081 -0.056 0.105 -0.058 Li2
7 28 10 34499.614 -0.264 -0.220 -0.060 -0.214 Li2
7 28 11 34506.139 -0.214 -0.150 0.009 -0.137 Li2
7 29 4 34610.638 0.078 0.031 0.188 0.010 Li2
7 29 5 34613.594 0.105 0.068 0.225 0.051 Li2
7 29 6 34617.139 0.138 0.113 0.270 0.099 Li2
7 29 8 34626.128 0.085 0.090 0.246 0.085 Li2
3 7 29 9 34630.388 1.359 Li2
7 29 10 34637.546 -0.029 0.010 0.165 0.017 Li2
7 29 11 34643.766* 0.499 Li2
7 30 9 34768.318 -0.084 -0.065 0.084 -0.062 Li2
7 30 11 34780.819 -0.177 -0.123 0.024 -0.113 Li2
7 30 22 34888.075* 2.433 Li2 7 33 4 35148.607 0.038 0.000 0.114 0.026 Li2
7 33 6 35155.056 -0.012 -0.033 0.082 -0.016 Li2
7 33 9 35169.060 -0.076 -0.064 0.053 -0.065 Li2
7 33 11 35181.282 -0.123 -0.087 0.030 -0.103 Li2
7 34 4 35279.065 0.199 0.167 0.264 0.206 Li2
7 34 6 35285.647 -0.026 -0.044 0.055 -0.020 Li2
7 34 9 35299.568 -0.099 -0.088 0.013 -0.096 Li2
7 34 11 35311.657 -0.094 -0.063 0.039 -0.097 Li2
7 35 4 35408.309 0.012 -0.013 0.065 0.041 Li2
7 35 5 35411.215 -0.023 -0.042 0.037 0.001 Li2
7 35 6 35414.600 0.035 0.023 0.103 0.054 Li2
7 35 8 35423.224 0.012 0.015 0.096 0.015 Li2
7 35 9 35427.731* 0.753 Li2
7 35 11 35440.362 0.042 0.067 0.151 0.010 Li2
7 36 4 35535.835 -0.032 -0.048 0.009 0.023 Li2
7 36 6 35542.104 -0.029 -0.036 0.023 0.004 Li2
7 36 9 35555.795 -0.058 -0.048 0.014 -0.076 Li2
7 36 11 35567.686 -0.018 0.001 0.064 -0.084 Li2
7 37 4 35660.992* 0.731 Li2
7 37 6 35667.555* 0.404 Li2
7 37 9 35681.364 0.128 0.137 0.176 0.098 Li2
7 37 11 35693.284 0.055 0.068 0.108 -0.047 Li2
7 38 9 35806.206* -0.550 Li2
7 38 11 35817.055* 0.363 Li2
7 39 9 35928.439* -0.309 Li2
7 39 11 35940.282* -0.485 Li2
7 40 9 36048.901 0.085 0.085 0.011 0.055 Li2
7 40 11 36060.439 0.142 0.123 0.042 -0.057 Li2
4 7 41 4 36149.051 -0.320 Li2
7 41 6 36155.030 -0.081 -0.064 -0.263 0.158 Li2
7 41 9 36168.246 -0.114 -0.123 -0.341 -0.115 Li2
7 41 11 36178.705* 0.662 Li2
6 0 31 30316.170 0.172 0.139 0.868 0.067 Li2
6 0 33 30364.050 -0.023 0.010 0.960 0.061 Li2
6 1 31 30517.443 0.063 0.031 0.642 0.009 Li2
6 1 33 30565.313 -0.116 -0.092 0.700 -0.004 Li2
6 2 31 30715.902 0.032 -0.001 0.499 0.017 Li2
6 2 33 30763.740 -0.126 -0.113 0.534 0.003 Li2 6 3 31 30911.734 0.003 -0.031 0.369 0.014 Li2
6 3 33 30959.542 -0.154 -0.150 0.364 -0.018 Li2
6 4 31 31104.795 0.221 0.187 0.496 0.245 Li2
6 4 33 31152.624 -0.002 -0.006 0.389 0.128 Li2
6 7 33 31717.964 -0.051 -0.062 0.050 0.015 Li2
6 8 31 31854.483 0.021 0.010 0.046 0.020 Li2
6 8 33 31901.795 -0.024 -0.032 0.009 0.013 Li2
6 9 31 32036.281 0.012 0.012 0.001 -0.003 Li2
6 9 33 32083.480 -0.042 -0.045 -0.065 -0.035 Li2
6 10 31 32215.851 0.100 0.113 0.063 0.073 Li2
6 10 33 32262.890 0.070 0.073 0.003 0.049 Li2
6 11 31 32393.474 0.044 0.070 -0.012 0.008 Li2
6 11 33 32440.341 0.037 0.046 -0.063 -0.008 Li2
6 12 31 32569.027 0.003 0.041 -0.065 -0.040 Li2
6 12 33 32615.786 -0.060 -0.044 -0.184 -0.122 Li2
6 13 31 32742.228* 0.214 Li2
6 13 33 32788.963 0.074 0.094 -0.068 0.000 Li2
6 14 31 32913.960 0.044 0.102 -0.033 0.006 Li2
6 14 33 32960.282 0.055 0.077 -0.099 -0.023 Li2
6 15 31 33083.515 0.002 0.065 -0.075 -0.027 Li2
6 17 31 33416.737 -0.041 0.018 -0.113 -0.034 Li2
6 17 33 33462.412 -0.018 -0.019 -0.185 -0.065 Li2
6 18 31 33580.38 0.016 0.064 -0.054 0.046 Li2
6 18 33 33625.882 -0.021 -0.043 -0.191 -0.047 Li2
6 19 33 33787.456 -0.044 -0.095 -0.218 -0.046 Li2
6 20 31 33902.155 -0.067 -0.063 -0.138 0.013 Li2
6 20 33 33947.100 -0.042 -0.131 -0.221 -0.019 Li2
6 10 18 31977.352 0.049 -0.093 0.042 -0.136 Li2
6 10 20 32006.329 0.007 -0.099 0.014 -0.140 Li2
6 11 18 32155.617 0.063 -0.065 0.070 -0.102 Li2
6 11 20 32184.529 0.003 -0.085 0.025 -0.123 Li2
6 12 18 32331.958 0.011 -0.102 0.033 -0.134 Li2
6 12 20 32360.770 -0.039 -0.110 -0.002 -0.145 Li2
6 13 18 32506.313 -0.017 -0.114 0.020 -0.142 Li2
6 13 20 32535.019 -0.058 -0.112 -0.005 -0.143 Li2
6 17 18 33184.448 -0.015 -0.061 0.076 -0.070 Li2
6 17 20 33212.687 -0.051 -0.048 0.059 -0.058 Li2
6 18 18 33349.222 0.037 0.000 0.138 -0.002 Li2
6 18 20 33377.345 -0.015 -0.003 0.106 -0.003 Li2 6 19 18 33512.172 0.057 0.025 0.166 0.031 Li2
6 19 20 33540.165 -0.002 0.015 0.127 0.025 Li2
6 20 18 33673.252 0.102 0.073 0.215 0.087 Li2
6 20 20 33701.150 -0.006 0.012 0.128 0.035 Li2
6 22 18 33989.949 0.152 0.118 0.266 0.151 Li2
6 22 20 34017.644 -0.057 -0.047 0.077 0.004 Li2
6 23 18 34145.636 0.103 0.062 0.212 0.103 Li2
6 23 20 34172.987 0.079 0.078 0.207 0.140 Li2
6 24 18 34299.388 0.174 0.121 0.273 0.168 Li2
6 24 20 34326.620 0.104 0.088 0.221 0.158 Li2
2 22 30504.303 0.108 0.065 0.213 0.003 6Li7Li 2 24 30536.970 0.057 0.040 0.224 -0.020 6Li7Li 3 22 30693.384 0.066 0.037 0.177 0.006 6Li7Li 3 24 30726.034 0.022 0.019 0.184 -0.008 6Li7Li 4 22 30880.188 0.009 -0.008 0.124 -0.018 6Li7Li 4 22 30880.204 -0.007 -0.024 0.108 -0.034 6Li7Li 4 23 30896.191 -0.036 -0.040 0.099 -0.047 6Li7Li 4 23 30896.196 -0.041 -0.045 0.093 -0.052 6Li7Li 4 24 30912.839 -0.057 -0.048 0.099 -0.051 6Li7Li 4 24 30912.850 -0.068 -0.059 0.088 -0.062 6Li7Li 5 22 31064.711 0.019 0.014 0.137 0.017 6Li7Li 5 24 31097.309 -0.025 -0.004 0.125 0.008 6Li7Li 6 22 31247.116 0.002 0.010 0.125 0.021 6Li7Li 6 24 31279.672 -0.041 -0.006 0.106 0.014 6Li7Li 7 22 31427.464 -0.040 -0.020 0.088 -0.003 6Li7Li 7 22 31427.465 -0.041 -0.021 0.087 -0.004 6Li7Li 7 23 31443.295 0.027 0.062 0.164 0.082 6Li7Li 7 23 31443.290 0.032 0.067 0.169 0.087 6Li7Li 7 24 31459.971 -0.085 -0.036 0.061 -0.012 6Li7Li 8 22 31605.713 -0.012 0.023 0.123 0.043 6Li7Li 8 24 31638.163 -0.060 0.004 0.088 0.030 6Li7Li * These data are excluded from the fits due to perturbations. 6 The Li2 data are from Xie et al., J. Mol. Spectrosc. 117 (1986) 228-244. 7 The Li2 data are from Yiannopoulou et al., J. Chem. Phys. 103 (1995) 5898-5903 and Li et al., J. Chem. Phys. 105 (1996) 9859-9863. 1,2,3,4 These data are questionable and excluded from the fits because the intermediate term values derived from the upper levels and probe frequencies do not agree with the known intermediate term values. 7 3 Table 7 EMO Potential Curve of the Li2 1 g state.
3 1 g state R (Å) Term value (cm-1) 1.8000 43296.04767 1.9000 40816.95953 2.0000 38534.18358 2.1000 36536.76989 2.2000 34860.67427 2.3000 33502.21906 2.4000 32433.9335 2.5000 31617.89039 2.6000 31014.71334 2.7000 30588.47208 2.8000 30308.56701 2.9000 30149.81041 3.0000 30091.66009 3.1000 30117.22600 3.2000 30212.37909 3.3000 30365.08614 3.4000 30564.97167 3.5000 30803.05126 3.6000 31071.56827 3.7000 31363.87708 3.8000 31674.33667 3.9000 31998.19755 4.0000 32331.47947 4.1000 32670.84519 4.2000 33013.47848 4.3000 33356.97393 4.4000 33699.24413 4.5000 34038.44673 4.6000 34372.93171 4.7000 34701.20686 4.8000 35021.91870 4.9000 35333.84496 5.0000 35635.89497 5.1000 35927.11452 5.2000 36206.69225 5.3000 36473.96528 5.4000 36728.42255 5.5000 36969.70502 5.6000 37197.60221 5.7000 37412.04534 5.8000 37613.09741 5.9000 37800.94080 6.0000 37975.86310 6.1000 38138.24198 6.2000 38288.52963 6.3000 38427.23743 6.4000 38554.92137 6.5000 38672.16847 6.6000 38779.58451 6.7000 38877.78327 6.8000 38967.37725 6.9000 39048.96982 7.0000 39123.14895 7.1000 39190.48213 7.2000 39251.51265 7.3000 39306.75678 7.4000 39356.70205 7.5000 39401.80617 7.6000 39442.49675 7.7000 39479.17142 7.8000 39512.19845 7.9000 39541.91767 8.0000 39568.64168 7 3 Table 8 EMO Potential Curve of the Li2 2 g state.
3 2 g state R (Å) Term value (cm-1) R (Å) Term value (cm-1) 1.8000 48722.12688 5.6600 33050.24231 1.8200 47268.24730 5.6800 33096.28686 1.8400 45999.42919 5.7000 33142.24550 1.8600 44886.98750 5.7200 33188.11363 1.8800 43907.18122 5.7400 33233.88674 1.9000 43040.26898 5.7600 33279.56046 1.9200 42269.76165 5.7800 33325.13053 1.9400 41581.82794 5.8000 33370.59281 1.9600 40964.81935 5.8200 33415.94326 1.9800 40408.88872 5.8400 33461.17796 2.0000 39905.68256 5.8600 33506.29309 2.0200 39448.09169 5.8800 33551.28491 2.0400 39030.04826 5.9000 33596.14980 2.0600 38646.35984 5.9200 33640.88422 2.0800 38292.57302 5.9400 33685.48473 2.1000 37964.86092 5.9600 33729.94796 2.1200 37659.92988 5.9800 33774.27066 2.1400 37374.94173 6.0000 33818.44962 2.1600 37107.44872 6.0200 33862.48175 2.1800 36855.33870 6.0400 33906.36400 2.2000 36616.78888 6.0600 33950.09342 2.2200 36390.22643 6.0800 33993.66713 2.2400 36174.29487 6.1000 34037.08232 2.2600 35967.82523 6.1200 34080.33623 2.2800 35769.81124 6.1400 34123.42621 2.3000 35579.38776 6.1600 34166.34963 2.3200 35395.81213 6.1800 34209.10395 2.3400 35218.44790 6.2000 34251.68668 2.3600 35046.75060 6.2200 34294.09540 2.3800 34880.25527 6.2400 34336.32773 2.4000 34718.56557 6.2600 34378.38135 2.4200 34561.34422 6.2800 34420.25402 2.4400 34408.30455 6.3000 34461.94353 2.4600 34259.20316 6.3200 34503.44771 2.4800 34113.83349 6.3400 34544.76447 2.5000 33972.02014 6.3600 34585.89175 2.5200 33833.61397 6.3800 34626.82754 2.5400 33698.48786 6.4000 34667.56988 2.5600 33566.53295 6.4200 34708.11684 2.5800 33437.65552 6.4400 34748.46655 2.6000 33311.77422 6.4600 34788.61718 2.6200 33188.81775 6.4800 34828.56693 2.6400 33068.72294 6.5000 34868.31405 2.6600 32951.43303 6.5200 34907.85682 2.6800 32836.89638 6.5400 34947.19357 2.7000 32725.06530 6.5600 34986.32264 2.7200 32615.89516 6.5800 35025.24244 2.7400 32509.34366 6.6000 35063.95138 2.7600 32405.37027 6.6200 35102.44793 2.7800 32303.93580 6.6400 35140.73058 2.8000 32205.00208 6.6600 35178.79786 2.8200 32108.53175 6.6800 35216.64831 2.8400 32014.48811 6.7000 35254.28051 2.8600 31922.83505 6.7200 35291.69309 2.8800 31833.53700 6.7400 35328.88467 2.9000 31746.55897 6.7600 35365.85393 2.9200 31661.86658 6.7800 35402.59955 2.9400 31579.42612 6.8000 35439.12027 2.9600 31499.20463 6.8200 35475.41481 2.9800 31421.16995 6.8400 35511.48196 3.0000 31345.29087 6.8600 35547.32050 3.0200 31271.53715 6.8800 35582.92925 3.0400 31199.87960 6.9000 35618.30705 3.0600 31130.29019 6.9200 35653.45276 3.0800 31062.74207 6.9400 35688.36528 3.1000 30997.20963 6.9600 35723.04350 3.1200 30933.66850 6.9800 35757.48635 3.1400 30872.09564 7.0000 35791.69279 3.1600 30812.46926 7.0200 35825.66179 3.1800 30754.76887 7.0400 35859.39233 3.2000 30698.97525 7.0600 35892.88344 3.2200 30645.07037 7.0800 35926.13414 3.2400 30593.03743 7.1000 35959.14349 3.2600 30542.86071 7.1200 35991.91056 3.2800 30494.52557 7.1400 36024.43445 3.3000 30448.01837 7.1600 36056.71427 3.3200 30403.32633 7.1800 36088.74916 3.3400 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7.7200 36858.53716 3.8800 29846.73056 7.7400 36883.45236 3.9000 29849.91462 7.7600 36908.10756 3.9200 29854.52415 7.7800 36932.50264 3.9400 29860.53712 7.8000 36956.63754 3.9600 29867.93082 7.8200 36980.51222 3.9800 29876.68194 7.8400 37004.12665 4.0000 29886.76659 7.8600 37027.48088 4.0200 29898.16033 7.8800 37050.57496 4.0400 29910.83822 7.9000 37073.40898 4.0600 29924.77488 7.9200 37095.98309 4.0800 29939.94449 7.9400 37118.29745 4.1000 29956.32090 7.9600 37140.35226 4.1200 29973.87762 7.9800 37162.14778 4.1400 29992.58789 8.0000 37183.68428 4.1600 30012.42472 8.0200 37204.96209 4.1800 30033.36097 8.0400 37225.98156 4.2000 30055.36933 8.0600 37246.74309 4.2200 30078.42242 8.0800 37267.24712 4.2400 30102.49281 8.1000 37287.49413 4.2600 30127.55308 8.1200 37307.48464 4.2800 30153.57584 8.1400 37327.21919 4.3000 30180.53378 8.1600 37346.69840 4.3200 30208.39970 8.1800 37365.92289 4.3400 30237.14656 8.2000 37384.89336 4.3600 30266.74752 8.2200 37403.61052 4.3800 30297.17594 8.2400 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4.9200 31343.97110 8.7800 37829.06672 4.9400 31388.27946 8.8000 37840.93447 4.9600 31432.81642 8.8200 37852.58909 4.9800 31477.56806 8.8400 37864.03247 5.0000 31522.52084 8.8600 37875.26654 5.0200 31567.66166 8.8800 37886.29324 5.0400 31612.97779 8.9000 37897.11454 5.0600 31658.45685 8.9200 37907.73245 5.0800 31704.08689 8.9400 37918.14898 5.1000 31749.85626 8.9600 37928.36620 5.1200 31795.75370 8.9800 37938.38616 5.1400 31841.76828 9.0000 37948.21096 5.1600 31887.88940 9.0200 37957.84272 5.1800 31934.10678 9.0400 37967.28356 5.2000 31980.41044 9.0600 37976.53564 5.2200 32026.79073 9.0800 37985.60114 5.2400 32073.23829 9.1000 37994.48223 5.2600 32119.74401 9.1200 38003.18112 5.2800 32166.29909 9.1400 38011.70003 5.3000 32212.89499 9.1600 38020.04118 5.3200 32259.52341 9.1800 38028.20682 5.3400 32306.17633 9.2000 38036.19920 5.3600 32352.84595 9.2200 38044.02059 5.3800 32399.52469 9.2400 38051.67326 5.4000 32446.20523 9.2600 38059.15949 5.4200 32492.88045 9.2800 38066.48156 5.4400 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