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Publications in Refereed Journals, Cynthia M. Friend

2013

227. Stowers, K. J., Madix, R. J., and Friend, C. M. “From Model Studies on Au(111) to Working Conditions with Unsupported Nanoporous Gold Catalysts: Oxygen-Assisted Coupling Reactions” J. Cat. vol. 308, 131-142, 2013.

226. Stephen C. Jensen, Katherine R. Phillips, Elizabeth C. Landis, C.M. Friend, “Norrish Type I photochemistry for butyrophenone on TiO2.” Phys. Chem. Chem. Phys. 2013, 15(14), 5193-5201; DOI:10.1039/c3cp44602f

225. Stephen C. Jensen, C.M. Friend, “The dynamic roles of interstitial and surface defects in oxidation and reduction reactions on titania.” Topics in Catalysis 2013, 56(15- 17), 1377-1388; DOI: 10.1007/s11244-013-0135-x

224. Bingjun Xu, R.J. Madix, C.M. Friend, “Alkyl groups as synthetic vehicles in gold- mediated oxidative coupling reactions.” Phys. Chem. Chem. Phys. 2013; DOI: 10.1039/C3CP43956A.

223. Katherine R. Phillips, Stephen C. Jensen, Martin Baron, Shao-Chun Li, Cynthia M. Friend. “Sequential Photo-oxidation of Methanol to Methyl Formate on TiO2(110)” J. Am. Chem. Soc. 2013, 135 (2), 574-577; DOI: 10.1021/ja3106797.

2012 222. Elizabeth C. Landis, Katherine C. Phillips, Eric Mazur, Cynthia M. Friend, “Formation of Nanostructured TiO2 by femtosecond laser irradiation of titanium in O2” J. Applied Physics. 2012, 112(6), 63108-63108-5; DOI: 10.1063/1.4752276

221. Cassandra G.F. Siler, Bingjun Xu, Robert J. Madix, C.M. Friend, “Role of Surface- Bound Intermediates in the Oxygen-Assisted Synthesis of Amides by Metallic Silver and Gold” J. Am Chem. Soc. 2012, 134 (30), 12604-12610; DOI: 10.1021/ja303178z .

220. Stephen C. Jensen, Alex Shank, R.J. Madix, and C.M. Friend, “Butyrophenone on O-TiO2(110): One-Dimensional Motion in a Weakly Confined Potential Well”, ACS Nano 2012, 6(4), 2925-2930; DOI: 10.1021/nn300949q.

219. Juan Carlos Rodriguez-Reyes, Cynthia M. Friend, Robert J. Madix, “Origin of the selectivity in the gold-mediated oxidation of benzyl alcohol.” Surf. Sci. 2012, 606 15-16 1129-1134; DOI: 10.1016/j.susc.2012.03.013.

218. Bingjun Xu, R.J. Madix, C.M. Friend. “Dual-Function of Alcohols in Gold- Mediated Selective Coupling of Amines and Alcohols”, Chemistry—A European Journal, 2012, 18 (8), 2313-2318; DOI:10.1002/chem.201103232. Publications in Refereed Journals, Cynthia M. Friend

2011 217. Kathryn Kosuda, Arne Wittstock, C. M. Friend and Marcus Bäumer, “Oxygen- Mediated Coupling of Alcohols over Nanoporous Gold Catalysts at Ambient Pressures, Ang. Chem. Int. Ed. 2011, 51(7), 1698-1701; DOI: 10.1002/anie.201107178.

216. Bingjun Xu, R.J. Madix, and C.M. Friend, “Activated Metallic Gold as an Agent for Direct Methoxycarbonylation”, J. Am. Chem. Soc., 2011, 133 (50), 20378-20383; DOI: 10.1021/ja207389z.

215. R.J. Madix and C.M. Friend, “Interfacial Chemistry Gold’s Enigmatic Surface”, Nature, 2011 479 482-483.

214. Stephen C. Jensen, Jan Haubrich, Alex Shank, Cynthia M. Friend, et al., “Carbonyl Coupling: Defects and O2 Make or Break the Essential Reaction Intermediate on Titanium Dioxide”, Chemistry-A European Journal, 2011, 17 ( 30), 8309-8312; DOI: 10.1002/chem.201101094.

213. Bingjun Xu, Cynthia M. Friend, Robert J. Madix, “A paradigm for predicting selective oxidation on noble metals: oxidative catalytic coupling of amines and aldehydes on metallic gold”, Faraday Discussions, 2011, 152, 241-252; DOI: 10.1039/c1fd00012h.

212. Bingjun Xu, Cynthia M. Friend, “Oxidative coupling of alcohols on gold: Insights from experiments and theory” Faraday Discussions, 2011, 152, 307-320; DOI: 10.1039/c1fd00015b.

211. Thomas A. Baker, Bingjun Xu, Stephen C. Jensen, Cynthia M. Friend, et al. “Role of defects in propene adsorption and reaction on a partially O-covered Au(111) surface ”, Catalysis Science & Technology, 2011, 1 ( 7) 1166-1174; DOI: 10.1039/c1cy00076d.

210. Jan Haubrich, Efthimios Kaxiras, Cynthia M. Friend, “The role of surface and subsurface point defects for chemical model studies on TiO2(110).” Chem.—A European Journal, 117, 4496-4506 2011, DOI: 10.1002/chem.201002588.

209. Bingjun Xu, Efthimios Kaxiras, Cynthia M. Friend, “Theoretical Study of O- assisted coupling of methanol on Au(111), J. Phys. Chem. C, 2011, 115 (9), 3703- 3708; DOI: 10.1021/jp110835w.

208. Lauren Benz, Jan Haubrich, Stephen C. Jensen, Cynthia M. Friend, “Molecular Imaging of Reductive Coupling Reactions: Interstitial-mediated Coupling of Benzaldehyde on TiO2(110)”, ACS Nano, 2011; DOI: 10.1021/nn103144u.

207. Thomas A. Baker, Xiaoying Liu, and C.M. Friend, “The Mystery Of Gold’s Chemical Activity: Local Bonding, Morphology And Reactivity Of Atomic Oxygen”, Physical Chemistry-Chemical Physics (Invited Perspective Article; Selected for inside cover art), 2011, 13, 34-46; DOI: 10.1039/C0CP01514H). Publications in Refereed Journals, Cynthia M. Friend

2010

206. Bingjun Xu, R.J. Madix, and C.M. Friend, “Achieving Optimum Selectivity in Oxygen Assisted Alcohol Cross-Coupling on Gold”, J. Am. Chem. Soc. 2010, 132, 16571-16580; DOI: 10.1021/ja106706v.

205. Xiaoying Liu, Thomas A. Baker, and C.M. Friend, “Effect of Molecular Structure on the Epoxidaiton of Allylic Olefins by Atomic Oxygen on Au.” Dalton Trans. 2010, 39 8521-8526; DOI: 10.1039/C0DT00047G.

204. Bingjun Xu, Jan Haubrich, Cassandra G. Freyschlag, Robert J. Madix and Cynthia M. Friend. ”Oxygen-assisted cross-coupling of methanol with alkyl alcohols on metallic gold”, Chem. Sci., 2010, 1, 310-314; DOI: 10.1039/C0SC00214C. (Selected for cover of journal.)

203. Xiaoying Liu and C.M. Friend, “Selective Oxidation of Cyclohexanol and 2- Cyclohexen-1-ol on O/Au(111): The Effect of Molecular Structure”, Langmuir, 2010, 16552-16557; DOI: 10.1021/la1015302.

202. Thomas A. Baker, Efthimios Kaxiras, C.M. Friend, “Insights from Theory on the Relationship Between Surface Reactivity and Gold Atom Release”, Top. Cat., 2010, 53 (5-6): 365-377; DOI: 10.1007/s11244-010-9446-3.

201. J.A. Haubrich, Ryan G. Quiller, Lauren Benz, L, Z. Liu, and C.M. Friend, “In Situ Ambient Pressure Studies of the Chemistry of NO2 and Water on Rutile TiO2(110)”, Langmuir, 2010, 26 (4): 2445-2451; DOI: 10.1021/la904141k.

200. X. Liu, C.M. Friend, “Competing Epoxidation and Allylic Hydrogen Activation: trans-β-Methylstyrene Oxidation on Au(111),” J. Phys. Chem. C, 2010, 26(4) 2445-2451; DOI: 10.1021/jp9121529.

199. A. Wittstock, V. Zielasek, J. Biener, C. M. Friend, and M. Bäumer, “Nanoporous gold catalysts for selective gas-phase oxidative coupling of methanol at low temperature,” Science, 2010, 327, 319-322; DOI: 10.1126/science.1183591.

198. B. Xu, L. Zhou, R. J. Madix, and C. M. Friend, “Highly selective acylation of dimethylamine mediated by oxygen atoms on metallic gold surfaces,” Angew. Chem. Int. Ed., 2010, 49, 394-398; DOI: 10.1002/anie.200905642.

197. R. G. Quiller, X. Liu, and C. M. Friend, “Mechanistic insights into selectivity control for heterogeneous olefin oxidation: Styrene oxidation on Au(111),” Chemistry— An Asian Journal, 2010, 5, 78-86; DOI: 10.1002/asia.200900399.

196. L. Zhou, C. G. Freyschlag, B. Xu, C. M. Friend, and R. J. Madix, “Direct selective oxygen-assisted acylation of amines driven by metallic silver surfaces: dimethylamine with formaldehyde,” Chem. Comm. 2010, 46, 704-706; DOI: 10.1039/b921066k. Publications in Refereed Journals, Cynthia M. Friend

195. T. A. Baker, C. M. Friend, and E. Kaxiras, “Local bonding effects in the oxidation of CO on oxygen-covered Au(111) from ab initio molecular dynamics simulations,” J. Chem. Theor. Comput., 2010, 6, 279-287; DOI: 10.1021/ct9004596.

194. B. Xu, X. Liu, J. Haubrich, and C. M. Friend, “Vapour-phase gold-surface-mediated coupling of aldehydes with methanol,” Nature Chem., 2010, 2, 61-65; DOI: 10.1038/NCHEM.467.

2009 193. L. Benz, J. Haubrich, R. G. Quiller, S. C. Jensen, and C. M. Friend, "McMurry chemistry on TiO2(110): Reductive C=C coupling of benzldehyde driven by titanium interstitials,” J. Am. Chem. Soc., 2009, 131, 15026–15031.

192. B. K. Min, X. Deng, X. Liu, C. M. Friend, and A. R. Alemozafar, “Tuning reactivity and selectivity for olefin oxidation through local O bonding on Au,” Chem. Cat. Chem., 2009, 1, 116-121.

191. T. A. Baker, B. Xu, X. Liu, E. Kaxiras, and C. M. Friend, “Nature of oxidation of the Au(111) surface. Experimental and theoretical investigation.” J. Phys. Chem. C., 2009, 113, 16561-16564.

190. V. Zielasek, B. Xu, X. Liu, M. Bäumer and C. M. Friend, “The Absence of Subsurface Oxygen Effects in the Oxidation of Olefins on Au: Styrene Oxidation over Sputtered Au(111).” J. Phys. Chem. C, 2009, 113, 8924-8929.

189. X. Liu, B. Xu, J. Haubrich, R. Madix, and C. M. Friend, “Surface-mediated self- coupling of ethanol on gold.” J. Am. Chem. Soc., 2009, 131, 5757-5759.

188. L. Benz, J. Haubrich, R. G. Quiller, and C. M. Friend, "Acrolein coupling on reduced TiO2(110): The effect of surface oxidation and the role of subsurface defects." Surf. Sci, 2009, 603, 1010-1017.

187. R. G. Quiller, L. Benz, J. Haubrich, M. E. Colling, and C. M. Friend, "Surface Chemistry of Organic Pollutants: Styrene, Ozone, and Water on TiO2(110)." J. Phys. Chem. B., 2009, 113, 2063-2070.

186. T. A. Baker, C. M. Friend, and E. Kaxiras, “Atomic Oxygen Adsorption on Au(111) with Defects.” J. Phys. Chem. C., 2009, 113, 3232-3238.

185. B. Xu, X. Liu, J. Haubrich, R. J. Madix, and C. M. Friend, “Selectivity Control in Gold-Mediated Esterification of Methanol.” Angew. Chem., Int. Ed., 2009, 48, 4206- 4209. Publications in Refereed Journals, Cynthia M. Friend

184. T. A. Baker, C. M. Friend, and E. Kaxiras, “Effects of chlorine and oxygen coverage on the structure of the Au(111) Surface.” J. Chem. Phys. 2009, 130, Art. No. 084701.

2008 183. X. Liu, R. J. Madix, and C. M Friend, “Unraveling molecular transformations on surfaces: a critical comparison of oxidation reactions on coinage metals.” Chemical Society Reviews 2008, 37(10), 2243-2261.

182. R. J. Madix, C. M. Friend, and X. Liu, “Anticipating Catalytic Oxidation Reactions on Gold at High Pressure (Including Liquid Phase) From Ultrahigh Vacuum Studies.” J. Catalysis. 2008, 258 (2), 410-413.

181. T. A. Baker, C. M. Friend, and E. Kaxiras, “Chlorine Interaction with Defects on the Au(111) Surface: a First-Principles Theoretical Investigation.” J. Chem. Phys. 2008, 129, 104702.

180. R. G. Quiller, T. A. Baker, X. Deng, M. E. Colling, B. K. Min, and C. M. Friend, “Transient Hydroxyl Formation from Water on Oxygen-covered Au(111).“ J. Chem. Phys. 2008, 129 064702.

179. X. Deng, S. Y. Quek, M. M. Biener, J. Biener, D.-H. Kang, R. Schalek, E. Kaxiras, and C. M. Friend, “Selective Thermal Reduction of Single-Layer MoO3 Nanostructures on Au(111).“ Surf. Sci. 2008, 602(6), 1166-1174.

178. T. A. Baker, C. M. Friend, and E. Kaxiras, “The Nature of Cl Bonding on the Au(111) Surface: Evidence of a Mainly Covalent Interaction.” J. Am. Chem. Soc. 2008, 130(12), 3720-3721.

177. X. Deng and C. M. Friend, “Selectivity Switch for Nitrogen Functionalization of Styrene on Au(111).“ Surf. Sci. 2008, 602(5), 1066-1071.

176. W. Gao, T. A. Baker, L. Zhou, D. S. Pinnaduwage, E. Kaxiras, and C. M. Friend, “Chlorine Adsorption on Au(111): Chlorine Overlayer or Surface Chloride?” J. Am. Chem. Soc. 2008, 130(11), 3560-3565.

2007 175. S. Y. Quek, M. M. Biener, J. Biener, J. Bhattacharjee, C. M. Friend, U. V. Waghmare, and E. Kaxiras, “Structure of incommensurate gold sulfide monolayer on Au(111).” J. Chem. Phys. 2007, 127(10), 104704/1-104704/8.

174. W. Gao, L. Zhou, D. S. Pinnaduwage, and C. M. Friend, ”Interaction of Chlorine with Au-O Surface Complexes.” J. Phys. Chem. C, 2007, 111(26), 9005-9007. Publications in Refereed Journals, Cynthia M. Friend

173. B. K. Min and C. M. Friend, “Heterogeneous Gold-Based Catalysis for Green Chemistry: Low-Temperature CO Oxidation and Propene Oxidation.” Chem. Rev., 2007, 107(6), 2709-2724.

172. S. H. Wiedemann, D.-H. Kang, R. G. Bergman, and C. M. Friend, “Cyclopropylmethyl/Cyclobutyl Rearrangements on Surfaces: Evidence for Transient Cation Formation near O-Covered Mo(110).” J. Am. Chem. Soc. 2007, 129(15), 4666- 4677.

171. M. M. Biener, J. Biener, and C. M. Friend, “Sulfur-Induced Mobilization of Au Surface Atoms on Au(111) Studied by Real-Time STM.” Surf. Sci., 2007, 601(7), 1659- 1667.

170. M. A. Sheehy, B. R. Tull, C. M. Friend, and E. Mazur, “Chalcogen Doping of Silicon via Intense Femtosecond-Laser Irradiation.” Mat. Sci. Eng. B, 2007, 137(1-3), 289-294.

169. X. Liu, A. Klust, R. J. Madix, and C. M. Friend, “Structure Sensitivity in the Partial Oxidation of Styrene, Styrene Oxide, and Phenylacetaldehyde on Silver Single Crystals.” J. Phys. Chem. C, 2007, 111(9), 3675-3679.

168. D. S. Pinnaduwage, L. Zhou, W. Gao and C. M. Friend, “Chlorine Promotion of Styrene Epoxidation on Au(111).” J. Am Chem. Soc. 2007, 129(7), 1872-1873.

167. X. V. Zhang, S. P. Ellery, C. M. Friend, H. D. Holland, F. M. Michel, Martin A. A. Schoonen and S. T. Martin, “Photodriven Reduction and Oxidation Reactions on Colloidal Semiconductor Particles: Implications for Prebiotic Synthesis.” J. Photochem. Photobiol. A 2007, 185(2-3), 301-311. 2006 166. X. Deng, T. A. Baker, and C. M. Friend, “A Pathway for NH Addition to Styrene Promoted by Gold.” Angew. Chem. Int. Ed. Engl. 2006, 45(42), 7075-7078.

165. X. Liu, R. J. Madix, and C. M. Friend, “Surface-Mediated NH and N Addition to Styrene on Ag(110).” J. Am. Chem Soc. 2006, 128(44), 14266-14267.

164. J. Biener, M. M. Biener, T. Nowitzki, A. V. Hamza, C. M. Friend, V. Zielasek, and M. Bäumer, “On the Role of Oxygen in Stabilizing Low-Coordinated Au Atoms.” ChemPhysChem., 2006, 7(9), 1906-1908.

163. S. Y. Quek, C. M. Friend, and E. Kaxiras, “Active Role of Buried Ultrathin Oxide Layers in Adsorption of O2 on Au Films.” Surf. Sci. 2006, 600(17), 3388-3393.

162. S. Y. Quek, M. M. Biener, J. Biener, J. Bhattacharjee, C. M. Friend, U. V. Waghmare, and E. Kaxiras, “Rich Coordination Chemistry of Au Adatoms in Gold Sulfide Monolayer on Au(111).” J. Phys. Chem B 2006, 110(32), 15663-15665. Publications in Refereed Journals, Cynthia M. Friend

161. X. Deng, B. K. Min, X. Liu, and C. M. Friend, “Partial Oxidation of Propene on Oxygen-Covered Au(111).” J. Phys. Chem B 2006, 110(32), 15982-15987.

160. B. K. Min, A. R. Alemozafar, D. Pinnaduwage, X. Deng, and C. M. Friend, “Efficient CO Oxidation at Low Temperature on Au(111).” J. Phys Chem B 2006, 110(40), 19833-19838.

159. B. R. Tull, J. E. Carey, M. A. Sheehy, C. M. Friend, and E. Mazur, “Formation of Silicon Nanoparticles and Web-like Aggregates by Femtosecond Laser Ablation in a Background Gas.” Appl. Phys. A 2006, 83(3), 341-346. 2005 158. M. M. Biener, J. Biener, and C. M. Friend, “Novel Synthesis of Two-Dimensional TiS2 Nanocrystallites on Au(111).” J. Chem. Phys. 2005, 122(3), 034706/1-034706/6. 157. Y.-S. Jun, T. A. Kendall, S. T. Martin, C. M. Friend, and J. J. Vlassak, “Heteroepitaxial Nucleation and Oriented Growth of Manganese Oxide Islands on Carbonate Minerals under Aqueous Conditions.” Env. Sci. Tech. 2005, 39(5), 1239-1249. 156. M. M. Biener, J. Biener, and C. M. Friend, “Revisiting the S-Au(111) Interaction: Static or Dynamic?” Langmuir 2005, 21(5), 1668-1671. 155. S. Y. Quek, M. M. Biener, J. Biener, C. M. Friend, and E. Kaxiras, “Tuning Electronic Properties of Novel Metal Oxide Nanocrystals Using Interface Interactions: MoO3 Monolayers on Au(111).” Surf. Sci. 2005, 577(2-3), L71-L77.

154. L. J. Deiner, D.-H. Kang, and C. M. Friend, “Low-Temperature Reduction of NO2 on Oxidized Mo(110).” J. Phys. Chem. 2005, 109(26), 12826-12831. 153. M. M. Biener, J. Biener, R. Schalek, and C. M. Friend, “Surface Alloying of Immiscible Metals: Mo on Au(111) studied by STM.” Surf. Sci. 2005, 594(1-3), 221-230. 152. M. M. Biener, J. Biener, and C. M. Friend, “Enhanced Transient Reactivity of an O- Sputtered Au(111) Surface.” Surf. Sci. 2005, 590(2-3), L259-L265. 151. M. A. Sheehy, L. Winston, J. E. Carey, C. M. Friend, and E. Mazur, “Role of the Background Gas in the Morphology and Optical Properties of Laser-Microstructured Silicon.” Chem. Mater. 2005, 17(14), 3582-3586. 150. J. Biener, E. Farfan-Arribas, M. Biener, C. M. Friend, and R. J. Madix, “Synthesis of TiO2 Nanoparticles on the Au(111) Surface.” J. Chem. Phys. 2005, 123(9), 094705/1- 094705/6. 149. E. Farfan-Arribas, J. Biener, C. M. Friend, and R. J. Madix, “Reactivity of Methanol on TiO2 Nanoparticles Supported on the Au(111) Surface.” Surf. Sci. 2005, 591(1-3), 1-12. 148. B. K. Min, X. Deng, D. Pinniduwage, R. Schalek, and C. M. Friend, “Oxygen- Induced Restructuring with Release of Gold Atoms from Au(111).” Phys Rev. B, 2005, 72(12), 121410/1-121410/4. 147. B. K. Min, R. G. Quiller, L. J. Deiner, and C. M. Friend, “Water Dissociation Associated with NO2 Coadsorption on Mo(110)-(1x6)-O: Effect of Coverage and Electronic Properties of Oxygen.” J. Phys. Chem. B 2005, 109(43), 20463-20468. Publications in Refereed Journals, Cynthia M. Friend

146. X. Deng, B. K. Min, A. Guloy, and C. M. Friend, “Enhancement of O 2 Dissociation on Au(111) by Adsorbed Oxygen: Implications for Oxidation Catalysis.” J. Am. Chem. Soc. 2005, 127(25), 9267-9270. 145. B. K. Min, A .R. Alemozafar, M. M. Biener, J. Biener, and C. M. Friend, “Reaction of Au(111) with Sulfur and Oxygen: Scanning Tunneling Microscopic Study.” Topics in Catalysis 2005, 36(1-4), 77-90. 144. X. Deng and C. M. Friend, “Selective Oxidation of Styrene on an Oxygen-Covered Au(111).” J. Am. Chem. Soc. 2005, 127(49), 17178-17179. 143. L.J. Deiner, D.-H. Kang, and C.M. Friend ˝Promotion of Formaldehyde Production by oxidation of Mo(110) by NO2.” J. Phys. Chem. B., 2005,109 (16), 8085-8090. 2004 142. B. Flemmig, I. Kretzschmar, C. M. Friend, and Roald Hoffman, “The Cyclopropylmethyl-3-butenyl Rearrangement on Mo(110): A Radical Clock on a Surface?” J. Phys. Chem. A, 2004, 108(15), 2972-2981. 141. L. J. Deiner, A. S. Y. Chan, M. A. Sheehy, and C. M. Friend, “The Reaction of CH3NO2 on O-covered Mo(110): The Effect of Oxygen on Product Distribution.” Surf. Sci. 2004, 555(1-3), L127-L132.

140. M. M. Biener and C. M. Friend, “Heteroepitaxial Growth of Novel MoO3 Nanostructures on Au(111).” Surf. Sci. 2004, 559(2-3), L173-L179. 139. X. V. Zhang, S. T. Martin, C. M. Friend, M. A. A. Schoonen, and H. D. Holland, “Mineral-Assisted Pathways in Prebiotic Synthesis: Photoelectrochemical Reduction of Carbon(+IV) by Manganese Sulfide.” J. Am. Chem. Soc. 2004, 126(36), 11247-11253. 138. M. M. Biener, J. Biener, R. Schalek, and C. M. Friend, “Growth of Nanocrystalline MoO3 on Au(111) studied by in-situ STM.” J. Chem. Phys. 2004, 121(23), 12010-12016. 137. D.-H. Kang and C.M. Friend, “Sensitivity of Methylthiolate Desulfurization Selectivity to Reaction Temperature and Hydroxyl Coverage.” Langmuir 2004, 20(26), 11443-11449. 2003 136. Z. Song, T. Cai, J. A. Rodrigues, J. Hrbek, A. S. Y. Chan, and C. M. Friend, “A Novel Growth Mode of Mo on Au(111) from a Mo(CO)6 Precursor: An STM Study.” J. Phys. Chem. B 2003, 107(4), 1036-1043. 135. R. Younkin, J. E. Carey, J. A. Levinson, and C. M. Friend, “Infrared Absorption by Conical Silicon Microstructures Made in a Variety of Background Gases using Femtosecond-Laser Pulses.” J. Appl. Phys. 2003, 93(5), 2626-2629. 134. M. Y. Shen, C. H. Crouch, J. E. Carey, R. Younkin, E. Mazur, M. Sheehy, and C. M. Friend, “Formation of Regular Arrays of Silicon Microspikes by Femtosecond Laser Irradiation through a Mask.” Appl. Phys. Lett. 2003, 82, 1715-1717. 133. I. N. Remediakis, E. Kaxiras, M. Chen, and C. M. Friend, “Dinitrosyl Formation as an Intermediate Stage of the Reduction of NO in the Presence of MoO3.” J. Chem. Phys. 2003, 118(13), 6046-6051. Publications in Refereed Journals, Cynthia M. Friend

132. L. J. Deiner and C. M. Friend, “Modification of Dehydrogenation Activity of Nickel on O-covered Mo(110).” Surf. Sci. 2003, 539(1), 21-30. 131. L. J. Deiner, J. G. Serafin, C. M. Friend, S. G. Weller, J. A. Levinson, and R. E. Palmer, “Insight into the Partial Oxidation of Propene: The Reactions of 2-Propen-1-ol on Clean and O-Covered Mo(110).” J. Am. Chem. Soc. 2003, 125(43), 13252-13257.

2002 130. I. Kretzschmar and C. M. Friend, “Effect of Coadsorbed Species and Temperature on Competitive Reaction Channels for Nascent Radicals: c-C3H7CH2SH on Mo(110)- (6x1)-O.” J. Phys. Chem. B 2002, 106(3), 663-672. 129. I. Kretzschmar and C. M. Friend, “Kinetic Control of Surface Reactions: Regioselectivity in the Reaction of 2-Methylcyclopropanemethanol on Mo(110)-(6x1)- O.” J. Phys. Chem. B, 2002, 106 (33), 8407-8414. 128. A. S. Y. Chan, L. J. Deiner, and C. M. Friend, “Insight into the Catalytic Reduction of NO by Methane: The Reaction of Nitromethane on Oxidized Mo(110).” J. Phys. Chem. B 2002, 106(51), 13318-13325. 2001 127. M. Chen, C. M. Friend, and E. Kaxiras, “The Chemical Nature of Surface Point Defects on MoO3(010): Adsorption of Hydrogen and Methyl." J. Am. Chem. Soc. 2001, 123(10), 2224-2230. 126. F. C. Nart and C. M. Friend, “Facile Reduction of NO via Dinitrosyl on Highly Oxidized Mo(110): Sensitivity to Local Structure and Defects.” J. Phys. Chem. B 2001, 105(14), 2773-2778. 125. L. J. Deiner, S. L. Wilcke, C. M. Friend, and F. C. Nart, “Potential Intermediate in CH4–Assisted Reduction of Nitric Oxide: The Reactions of Methyl Nitrite on Oxidized Mo(110).” Surf. Sci. 2001, 477, L301-L307. 124. J. A. Levinson, I. Kretzschmar, M. A. Sheehy, L. J. Deiner, and C. M. Friend, “Rearrangement as a Probe for Radical Formation: Bromomethylcyclopropane on Oxygen-Covered Mo(110)." Surf. Sci. 2001, 479, 273-286. 2000 123. M. Chen, C. M. Friend, and E. Kaxiras, “A Density Functional Theory Study of Site-specific Methyl Reaction on MoO3(010): The Effects of Methyl Coverage." J. Chem. Phys. 2000, 112, 9617-9623. 122. K. T. Queeney and C. M. Friend, “Site-Selective Surface Reactions: Hydrocarbon Oxidation Processes on Oxidized Mo(110).” J. Phys. Chem. 2000, 104, 409-415. 121. F. C. Nart, S. Kelling and C. M. Friend, “Oxygen Lability on Thin Oxide Films on Mo(110).” J. Phys. Chem. B, 2000, 104, 3212-3218. 120. K. T. Queeney and C. M. Friend, “Site-Selective Surface Reactions: Nitric Oxide Reduction on Mo(110).” ChemPhysChem 2000, 1, 116 – 125. Publications in Refereed Journals, Cynthia M. Friend

119. I. Kretzschmar, J. A. Levinson and C. M. Friend, “Hydroxymethylcyclopropane on Oxygen-covered Mo(110): A Radical Clock on a Surface." J. Am. Chem. Soc. 2000, 122, 12395-12396. 1999 118. J. D. Batteas, T. S. Rufael, and C. M. Friend, “Influence of Surface Modifiers on the Thermal Decomposition of Methanethiol on Fe(110).” Langmuir 1999, 15, 2391- 2397.

117. M. Chen, C. M. Friend, and R. A. van Santen, “The Adsorption of Methyl on Rh10 Clusters: Selective C-H Bond Weakening.” Catalysis Today 1999, 50, 621-627. 116. M. Chen, P. G. Clark, Jr., T. Mueller, C. M. Friend, and E. Kaxiras, “Resolving Discrepancies Between LEED and STM Through ab-initio Calculations: Surface and Bonding of Sulfur on Mo(110).” Phys. Rev. B. 1999, 60, 11783-11788. 115. P. G. Clark, Jr. and C. M. Friend, “Interface Effects on the Growth of Cobalt Nanostructures on Molybdenum-based Substrates." J. Chem. Phys. 1999, 111, 6991- 6996. 114. C.M. Friend, K.T. Queeney, D.A. Chen, “Structure and Reactivity of Thin Film Oxides and Metals.” 1999, Applied Surf. Sci., 142 (1-4), 99-105. 1998 113. K. T. Queeney and C. M. Friend, “The Role of Oxygen Vacancies in Methanol Reaction on Oxidized Mo(110).” J. Phys. Chem. B, 1998, 102, 5178-5181. 112. D. A. Chen and C. M. Friend, “Changing Reactivity of a Bimetallic Surface via Oxidation: Reactions of Methanol on Oxygen-Covered Co Thin Films.” J. Phys. Chem. B 1998, 102, 106-110. 111. D. A. Chen and C. M. Friend, “Modifying Selectivity of Thin Films by Intervening Nonmetallic Layers: Reactions of Ethanol-d6 on Supported Co Films." Surf. Sci. 1998, 412-413, 364-373. 110. D. A. Chen and C. M. Friend, “Controlling Deoxygenation Selectivity by Surface Modification: Reactions of Ethanol on Oxygen- and Sulfur-Covered Mo(110)." J. Am. Chem. Soc. 1998, 120, 5017-5023. 109. D. A. Chen, C. M. Friend, and X. Xu, “Desulfurization of Benzenethiol on Co- Mo(110) Phases." Surf. Sci. 1998, 395, L221-226. 108. A. W. Holbert, J. D. Batteas, A. Wong-Foy, T. S. Rufael, and C. M. Friend, “Passivation of Fe(110) via Phosphorous Deposition: The Reactions of Trimethylphosphite." Surf. Sci. 1998, 401, L437-443. 107. K. T. Queeney and C. M. Friend, “Comment on ‘Methanol on O/Mo(110): Specific Site for Methyl Radical Formation’ by S. C. Street, G. Lui and D.W. Goodman [Surf. Sci. 385 (1997) L971]." Surf. Sci. 1998, 407, 293-295. 106. M. Chen, U. V. Waghmare, C. M. Friend, and E. Kaxiras, “A Density Functional Study of Clean and Hydrogen-covered α-MoO3(010): Electronic Structure and Surface Relaxation." J. Chem. Phys. 1998, 109, 6854-6860. Publications in Refereed Journals, Cynthia M. Friend

105. K. T. Queeney and C. M. Friend, “Competing Pathways for Methoxy Decomposition on Oxygen-covered Mo(110)." J. Chem. Phys. 1998, 109, 6067-6074. 104. K. T. Queeney, S. Pang, and C. M. Friend, “Spectroscopic Evidence for Perturbed NO Dimers on Oxidized Mo(110)." J. Chem. Phys. 1998, 109, 8058-8061. 103. K. T. Queeney and C. M. Friend, “Conversion of Nitrosyls to Dinitrosyls During NO Adsorption on Oxygen-modified Mo(110)." Surf. Sci. 1998, 414, L957-L963. 102. K. T. Queeney and C. M. Friend, “Stabilization of Nitrosyls by Surface Oxygen: Structure and Reactivity of NO on Oxygen-Modified Mo(110).” J. Phys. Chem. B, 1998, 102, 9251-9257. 101. K. T. Queeney, C. R. Arumainayagam, A. Balaji, and C.M. Friend, “Carbon- Carbon Coupling from Formaldehyde Reaction on Mo(110)." Surf. Sci. 1998, 418, L31- L38. 100. D. A. Chen and C. M. Friend, “Selective and Nonselective Dehydrogenation in Primary Alcohols: Reactions of Ethanol and 1-Propanol on Co-covered Mo(110).” Langmuir 1998, 14, 1451-1457. 1997 99. C. W. J. Bol, J. D. Kovacs, M. Chen, and C. M. Friend, “Control of Reaction Selectivity via Surface Oxygen Coverage: Thermal Decomposition of Azomethane on Rh(111).” J. Phys. Chem. 1997, 101, 6436-6442. 98. K. T. Queeney, D. A. Chen, and C. M. Friend, “Probing the Role of Oxygen Coordination in Hydrocarbon Oxidation: Methyl Radical Addition to Oxygen on Mo(110)." J. Am. Chem. Soc. 1997, 119, 6945-6946. 97. D. A. Chen and C. M. Friend, “Adsorbate-Induced Structural Changes of Metal Thin Films: Cobalt-Oxygen and Cobalt-Sulfur Overlayers on Mo(110)." Surf. Sci. 1997, 371, 131-142. 96. C. M. Friend and D. A. Chen, “Fundamental Studies of Hydrodesulfurization by Metal Surfaces.” Polyhedron 1997, 16, 3165-3175. 95. M. Chen, S. P. Bates, R. A. Van Santen, and C. M. Friend, “The Chemical Nature of Atomic Oxygen Adsorbed on Rh(111) and Pt(111): A Density Functional Study.” J. Phys. Chem. 1997, 101, 10051-10057. 94. D. Chen and C. M. Friend, “Competition between C-O Bond Scission and Retention in Methanol Reaction on Co-covered Mo(110).” J. Phys. Chem. 1997, 101, 5712-5716. 93. T. S. Rufael, J. D. Batteas, and C. M. Friend, “The Influence of Surface Oxidation on the Reactions of Methanol on Fe(110).” Surf. Sci. 1997, 384, 156-167.

92. K. T. Queeney and C. M. Friend, “Dinitrosyl Intermediate for N2O Formation from Reaction of NO on Mo(110)." J. Chem. Phys. 1997, 107, 6432-6442. 1996 91. M. K. Weldon, P. Uvdal, C. M. Friend, and B. C. Wiegand, “Effect of Surface Modification on the Structure and Reactivity of Cyclohexane on Mo(110)." Surf. Sci. 1996, 355, 71-84. Publications in Refereed Journals, Cynthia M. Friend

90. M. E. Napier and C. M. Friend, “The Effect of Fluorination on Thiol Reactivity: Reaction of 4,4,4-Trifluorobutanethiol on Mo(110).” Langmuir 1996, 12, 1800-1807. 89. B. C. Wiegand, M. E. Napier, C. M. Friend, and P. Uvdal, “Ion and Radical Rearrangements as a Probe of the Mechanism of a Surface Reaction: The Desulfurization of Cyclopropylmethanethiol and 3-Butene-1-thiol on Mo(110)." J. Am. Chem. Soc. 1996, 118, 2962-2968. 88. D. A. Chen, C. M. Friend, and H. Xu, “Reactions of Methanethiol on Cobalt- Covered Mo(110).” Langmuir 1996, 12, 1528-1534. 87. B. C. Wiegand, C. M. Friend, P. Uvdal, and M. E. Napier, “Facile Homolytic C-S Bond Breaking: The Reaction of 2-Propene-1-thiol on Mo(110).” Surf. Sci. Lett. 1996, 355, L311-L318. 86. M. K. Weldon and C. M. Friend, “Probing Surface Reaction Mechanisms Using Chemical and Vibrational Methods: Alkyl Oxidation and Reactivity of Alcohols on Transition Metal Surfaces.” Chem. Rev. 1996, 96, 1391-1441. 85. P. Uvdal, M. K. Weldon and C. M. Friend, “Surface-induced Bond Anharmonicity Probed through a Two-Phonon Bound State: Methoxide Adsorbed on Mo(110).” Phys. Rev. B 1996, 53, 5007-5010. 84. K. T. Queeney, C. R. Arumainayagam, M. K. Weldon, C. M. Friend, and M. Q. Blumberg, “Differential Reactivity and Structure of Mono- and Dialkoxides: The Reactions of Ethylene Glycol on Mo(110)." J. Am. Chem. Soc. 1996, 118, 3896-3904. 83. C. W. J. Bol and C. M. Friend, “Control of Oxidation Selectivity by Alkyl Substitution: The Reactions of t-Butyl Iodide and t-Butanethiol on Rh(111)-p(2x1)-O.” Surf. Sci. Lett. 1996, 364, L549-L554. 82. C. W. J. Bol, X. Xu, and C. M. Friend, “Role of Intermolecular Interactions in Determining Structure and Reactivity on Surfaces: Benzenethiol on Rh(111).” Langmuir 1996, 12, 6083-6090. 81. D. A. Chen and C. M. Friend, “Alcohol Chemistry as a Probe of Mixed Metal Phases: Reactions of 2-Propanol on Cobalt-covered Mo(110).” J. Phys. Chem. 1996, 100, 17640-17647. 1995 80. C. W. J. Bol and C. M. Friend, "Selective Oxygen Addition with Sulfur Removal: The Reactions of 2-Propanethiol on Rh(111)-p(2x1)-O." Surf. Sci.. 1995, 322, L271- L274. 79. P. Uvdal, A. D. MacKerell Jr., B. C. Wiegand, and C. M. Friend, “Surface-Induced Alteration of Adsorbate Electronic Structure and Intramolecular Vibrational Coupling: The Vibrational Spectrum of 2-Propoxide on Mo(110).” Phys. Rev. B 1995, 51, 7844- 7848. 78. M. E. Napier and C. M. Friend, “Effect of Fluorination on Thiol Reactivity: Reaction of 2,2,2-Trifluoroethanethiol on Mo(110).” J. Phys. Chem. 1995, 99, 8750-8757. Publications in Refereed Journals, Cynthia M. Friend

77. C. W. J. Bol and C. M. Friend, “The Effects of Oxygen on Selectivity: The Reactions of 2-Propyl Thiolate on Oxygen-Covered Rh(111)." J. Am. Chem. Soc. 1995, 117, 5351- 5358.

76. C. W. J. Bol and C. M. Friend, “Partial Oxidation of C1-Hydrocarbons on Oxygen- covered Rh(111): Formaldehyde from Methylene.” Surf. Sci. 1995, 337, L800-L806. 75. M. J. Calhorda, P. E. M. Lopes, and C. M. Friend, “Theoretical Studies of Ethylene Adsorption and Oxidation on Clean and Oxygen Covered Rhodium(111).” J. Molec. Catal. 1995, 97, 157-172. 74. C. W. J. Bol and C. M. Friend, “Controlling Selectivity in Alkyl Oxidation with Oxygen Coverage: The Reactions of Ethyl and 2-Propyl Iodide on Oxygen-Covered Rh(111).” J. Phys. Chem. 1995, 99, 11930-11936. 73. M. K. Weldon and C. M. Friend, “A Novel Method for Product Identification in Complex Surface Reactions using Infrared Absorption Spectroscopy.” Rev. Sci. Instr. 1995, 66, 5192-5195. 72. C. W. J. Bol and C. M. Friend, “C-O Bond Formation by Direct Addition of Methyl Radicals to Surface Oxygen on Rh(111)." J. Am. Chem. Soc. 1995, 117, 8053-8054. 71. M. K. Weldon, P. Uvdal, C. M. Friend, and J. G. Serafin, “Decoupling of Vibrational Modes as a Structural Tool: Coverage-Induced Reorientation of Methoxide on Mo(110)." J. Chem. Phys. 1995, 103, 5075-5084. 70. C. W. J. Bol and C. M. Friend, “Effects of Oxygen Coverage on the Partial Oxidation of Methylene: Reactions of Diiodomethane on Oxygen-Covered Rh(111)." J. Am. Chem. Soc. 1995, 117, 11572-11579. 1994 69. M. K. Weldon and C. M. Friend, "The Isomerization and Tautomerization of Azomethane on Mo(110)." Surf. Sci. 1994, 310, 95-102. 68. M. K. Weldon, M. E. Napier, B. C. Wiegand, C. M. Friend, and P. Uvdal, "The Role of Disulfide Linkages in Desulfurization Chemistry: The Reactions of Benzenethiol on a Sulfur-Covered Mo(110) Surface." J. Am. Chem. Soc. 1994, 116, 8328-8334.

67. H. Yang, J. L. Whitten, and C. M. Friend, “Adsorption of CH3O on Ni(111)." Surf. Sci. 1994, 313, 295-307. 66. P. Uvdal, M. K. Weldon, and C. M. Friend, “Adsorbate Symmetry and Fermi Resonances of Methoxide Adsorbed on Mo(110) as Studied by Surface Infrared Spectroscopy.” Phys. Rev. B 1994, 50, 12258-12261. 65. M. K. Weldon and C. M. Friend, “Spectroscopic Characterization of Surface Methylene on Mo(110)." Surf. Sci. 1994, 321, L202-L208. 1993 64. H. Xu and C. M. Friend, "Effect of Sulfur on Desulfurization Kinetics and Selectivity: 2,5-Dihydrothiophene on Mo(110)-(4x1)-S." J. Phys. Chem. 1993, 97, 3584- 3590. Publications in Refereed Journals, Cynthia M. Friend

63. H. Xu, P. Uvdal, C. M. Friend, and J. Stöhr, "The Adsorption of 2,5-Dihydro- thiophene on Mo(110)-p(4x1)-S: Ring Orientation as Determined by NEXAFS." Surf. Sci. 1993, 289, L599-L603. 1992 62. X. Xu and C. M. Friend, "Selective β-Elimination in the Reaction of 2-Propanol to Acetone on Rh(111)-p(2x1)-O." Surf. Sci. 1992, 260, 14-22. 61. X. Xu and C. M. Friend, "Enhanced Kinetic Stability of γ-C-H Bonds in Surface Alkoxides: The Reactions of tert-Butyl Alcohol on Clean and Oxygen-Covered Rh(111)." Langmuir 1992, 8, 1103-1111. 60. B. C. Wiegand, P. Uvdal, and C. M. Friend, "Probing the Kinetics for Thiol Desulfurization: The Reactions of 2-Methyl-propanethiol on Mo(110)." J. Phys. Chem. 1992, 96, 4527-4533. 59. P. Uvdal, B. C. Wiegand, J. G. Serafin and C. M. Friend, "Isotopic Labeling as a Tool to Establish Intramolecular Vibrational Coupling: The Reaction of 2-Propanol on Mo(110)." J. Chem. Phys. 1992, 97, 8727-8735. 58. B. C. Wiegand and C. M. Friend, "Model Studies of Desulfurization Reactions on Metal Surfaces and in Organometallic Complexes.” Chem. Rev. 1992, 92, 491-504. 57. B. C. Wiegand, P. Uvdal, and C. M. Friend, "The Local Structure of Adsorbed Methyl Thiolate: The Reactions of Methanethiol on Mo(110)." Surf. Sci. 1992, 279, 105- 112. 56. B. C. Wiegand, P. Uvdal, J. G. Serafin and C. M. Friend, "Competition between C-O and 1-C-H Bond Scission during Deoxygenation: The Reactions of 1-Propanol on Mo(110)." J. Phys. Chem. 1992, 96, 5063-5069. 1991 55. A. C. Liu and C. M. Friend, "Evidence for Facile and Selective Desulfurization: The Reactions of 2,5-Dihydrothiophene on Mo(110)." J. Am. Chem. Soc. 1991, 113, 820-826. 54. X. Xu and C. M. Friend, "Partial Oxidation without Allylic C-H Bond Activation: The Conversion of Propene to Acetone on Rh(111)-p(2x2)-O." J. Am. Chem. Soc. 1991, 113, 6779-85. 53. C. M. Friend and X. Xu, "Reactions on Transition Metal Surfaces." Ann. Rev. Phys. Chem. 1991, 42, 251-278. 52. B. C. Wiegand, P. E. Uvdal, J. G. Serafin, and C. M. Friend, "Selective α-C-H Bond Cleavage in Alkoxides: 2-Propanol on Mo(110)." J. Am. Chem. Soc. 1991, 113, 6686- 6687. 51. X. Xu and C. M. Friend, "Partial Oxidation of Olefins: Conversion of Isobutene to tert-Butyl Alcohol on Oxygen-Covered Rh(111)." J. Phys. Chem. 1991, 95, 10753- 10759. 50. X. Xu and C. M. Friend, "The Effect of Rhodium Environment on Oxidation Mechanism: Conversion of Norbornene to Norbornanone on Rh(111)-p(2x1)-O." J. Am. Chem. Soc. 1991, 113, 8572-8573. Publications in Refereed Journals, Cynthia M. Friend

49. F. A. Flitsch, J. R. Swanson, and C. M. Friend, "Thermal and Photoinduced Decomposition of W(CO)6 on W(110)." Surf. Sci. 1991, 245, 85-95. 1990 48. M. Calhorda, R. Hoffmann, and C. M. Friend, "Adsorption and Reactions of Cyclic Sulfides on Mo(110)." J. Am. Chem. Soc. 1990, 112, 50-61. 47. J. R. Swanson, F. A. Flitsch, and C. M. Friend, "Evidence for Photochemical Quenching by a Surface: Laser Induced Decomposition of W(CO)6 on Si(111)-(7x7)." Surf. Sci. 1990, 226, 147-168. 46. A. C. Liu, C. M. Friend, and J. Stöhr, “The Orientation of Phenoxide on Oxygen- precovered Mo(110)." Surf. Sci. 1990, 236, L349-L352. 45. A. C. Liu, J. Stöhr, C. M. Friend, and R. J. Madix, “A Critical Interpretation of the Near edge X-Ray Absorption Fine Structure of Chemisorbed Benzene." Surf. Sci. 1990, 235, 107-115. 44. X. Xu and C. M. Friend, “Selective Oxidation Reactions on Rh(111)-p(2x2)-O: The Conversion of Styrene to Acetophenone." J. Am. Chem. Soc. 1990, 112, 4571-4573. 1989 43. J. G. Serafin and C. M. Friend, "Reactivity of Pyridine on Mo(110): C-H and C-N Bond Activation." J. Phys. Chem. 1989, 93, 1998-2004. 42. J. G. Serafin and C. M. Friend, "Carbon-Oxygen Bond Strength as a Control of Reaction Kinetics: Phenol on Mo(110)." Surf. Sci. 1989, 209, L163-L175. 41. J. R. Swanson, F. A. Flitsch, and C. M. Friend, "Low Energy Electron Induced Decomposition on Surfaces: W(CO)6 on Si(111)-(7x7)." Surf. Sci. 1989, 215, L293- L296. 40. J. G. Serafin and C. M. Friend, "Inhibition of C-H and C-O Bond Activation by Surface Oxygen: Stabilization of Phenoxide in the Reaction of Phenol on Oxygen Precovered Mo(110)." J. Am. Chem. Soc. 1989, 111, 4233-4239. 39. A. C. Liu and C. M. Friend, "Alkane Activation: The Adsorption and Reaction of Ethane on W(100)." Surf. Sci. 1989, 216, 33-48. 38. J. G. Serafin and C. M. Friend, "Controlling Factors in Deoxygenation Kinetics and Selectivity: The Reactions of Ethylene Oxide on Mo(110)." J. Am. Chem. Soc. 1989, 111, 6019-6026. 37. X. Xu and C. M. Friend, "The Role of Coverage in Determining Adsorbate Stability: Phenol Reactivity on Rh(111)." J. Phys. Chem. 1989, 93, 8072-8080. 36. B. C. Wiegand, C. M. Friend, and J.T. Roberts, "Adsorbate Thermodynamics as a Determinant of Reaction Mechanism: Pentamethylene Sulfide on Mo(110)." Langmuir 1989, 5, 1292-1298. 35. J. G. Serafin and C. M. Friend, "Evidence for Formation of Gaseous Methyl Radicals in the Decomposition of Methoxide on Oxygen-Precovered Mo(110)." J. Am. Chem. Soc. 1989, 111, 8967-8969. Publications in Refereed Journals, Cynthia M. Friend

1988 34. C. M. Friend and J. G. Serafin, "Bonding and Reactivity of Acetonitrile on W(100)- (5x1)-C." J. Chem. Phys., 1988, 88, 4037-4045. 33. J. T. Roberts and C. M. Friend, "Vibrational Studies of 1-Propanethiol on Mo(110): Spectroscopic Evidence for Low Temperature Thiolate Formation." Surf. Sci. 1988, 198, L321-L328. 32. J. T. Roberts and C. M. Friend, "Desulfurization of Ethylene Sulfide on Mo(110): The Roles of Ring Size and Strain in Adsorbate Reaction Selectivity." Surf. Sci. 1988, 202, 405-432. 31. J. T. Roberts and C. M. Friend, "Spectroscopic Identification of Surface Phenyl Thiolate and Benzyne on Mo(110)." J. Chem. Phys. 1988, 88, 7172-7180. 30. J. T. Roberts and C. M. Friend, "Reactions of Ethanethiol on Mo(110): Formation and Decomposition of a Surface Alkyl Thiolate." J. Phys. Chem. 1988, 92, 5205-5213. 29. J. G. Serafin and C. M. Friend, "Evidence for Nitrile Hydrogenation on W(100)- (5x1)-C: Spectroscopic Studies of Surface Intermediates Derived from HCN." J. Phys. Chem. 1988, 92, 6694-6700. 28. C. M. Friend and J. T. Roberts, "Deduction of Reaction Mechanisms for Surface Processes: Desulfurization of Organic Sulfides and Thiols on Mo(110)." Accts. Chem. Res. 1988, 21, 394-400. 27. P. A. Stevens, R. J. Madix, and C. M. Friend, "Adsorbate Structural Determination of CO and HCNH Using C-K Edge NEXAFS on W(100)-(5x1)-C." Surf. Sci. 1988, 205, 187-206. 26. A. C. Liu and C. M. Friend, "The Structure and Reactivity of Chemisorbed Aromatics: Spectroscopic Studies of Benzene on Mo(110)." J. Chem. Phys. 1988, 89, 4396-4405. 1987 25. J. R. Swanson, C. M. Friend, and Y. J. Chabal, "Laser-assisted Deposition of Iron on Si(111)-(7x7): The Mechanism and Energetics of Fe(CO)5 Decomposition." J. Chem. Phys. 1987, 87, 5028-5037. [Erratum J. Chem. Phys. 1988, 89, 2593.] 24. J. T. Roberts and C. M. Friend, "The Reactions of Thiophene on Mo(110) and Mo(110)-p(2x2)-S." Surf. Sci. 1987, 186, 201-218. 23. J. T. Roberts and C. M. Friend, "Coadsorption as a Probe of Mechanism: Cyclic Sulfides and Straight Chain Thiols on Mo(110)." J. Am. Chem. Soc. 1987, 109, 4423- 4424. 22. C. M. Friend, J. G. Serafin, E. K. Baldwin, P. A. Stevens, and R. J. Madix, "Bonding and Adsorption Structure of CO on W(100)-(5x1)-C." J. Chem. Phys. 1987, 87, 1847- 1850. 21. E. K. Baldwin and C. M. Friend, "Alteration in Dissociation Energetics for π- Acceptor Adsorbates: N2O, NO, N2 and O2 on W(100)-p(5x1)-C." J. Phys. Chem., 1987, 91, 3821-3827. Publications in Refereed Journals, Cynthia M. Friend

20. A. C. Liu and C. M. Friend, "Alkane Activation: Adsorption and Reaction of n- Butane on Clean and Carbided W(100)." J. Chem. Phys., 1987, 87, 4975-4985. 19. J. T. Roberts and C. M. Friend, "Ring Size and Strain as a Control of Reaction Selectivity: Ethylene Sulfide on Mo(110)." J. Am. Chem. Soc. 1987, 109, 7899-7900.

18. J. T. Roberts and C. M. Friend, "Desulfurization of Saturated C3S Molecules on Mo(110): The Effect of Ring Strain." J. Am. Chem. Soc. 1987, 108, 3872-3882. 1986 17. K. A. Pearlstine and C. M. Friend, "Alteration in Surface Reaction Selectivity of Nitriles. 1. HCN on W(100) and W(100)-(5x1)-C." J. Phys. Chem. 1986, 90, 4341-4343. 16. K. A. Pearlstine and C. M. Friend, "Alteration in Surface Reaction Selectivity of Nitriles. 2. CH3CN on W(100) and W(100)-(5x1)-C." J. Phys. Chem. 1986, 90, 4344- 4347. 15. A. C. Liu and C. M. Friend, "Computer-controlled Mass Spectral Search for Reaction Products in a Thermal Desorption Experiment." Rev. Sci. Instrum. 1986, 57(8), 1519-1522. 14. K. A. Pearlstine and C. M. Friend, "Surface Chemistry of Alkyl Amines. 1. Ethylamine and Triethylamine on W(100), W(100)-(5x1)-C, and W(100)-(2x1)-O." J. Am. Chem. Soc. 1986, 108, 5837-5842. 13. K. A. Pearlstine and C. M. Friend, "Surface Chemistry of Alkyl Amines. 2. Methylamine and Trimethylamine on W(100), W(100)-(5x1)-C and W(100)-(2x1)-O." J. Am. Chem. Soc. 1986, 108, 5842-5847. 12. J. T. Roberts and C. M. Friend, "Model Hydrodesulfurization Reactions: Saturated C4S Molecules on Mo(110)." J. Am. Chem. Soc. 1986, 108, 7204-7210. 1985 11. E. K. Baldwin and C. M. Friend, “Reaction of NO on W(100), W(100)-p(2x2)-O, and W(100)-p(2x1)-O Surfaces: A Nondissociative Pathway for N-N Bond Formation.” J. Phys. Chem. 1985, 89, 2576-2581. 10. K. A. Pearlstine and C. M. Friend, "C-C Bond Activation: Cycloheptatriene Reaction on W(100), W(100)-(5x1)-C, and W(100)-(2x1)-O." J. Am. Chem. Soc. 1985, 107, 5898- 5901. 1983 9. D. A. Outka, C. M. Friend, S. Jorgensen, and R. J. Madix, "Adsorption and Hydrogenation of Acetylene on Cu(110) and Cu(110)-O Surfaces.” J. Am. Chem. Soc. 1983, 105, 3468-3472. 8. D. A. Outka, S. W. Jorgensen, C. M. Friend, and R. J. Madix, "Adsorption and Reaction of Cyanogen on Clean and Oxygen-Dosed Cu(110) Surfaces.” J. Molec. Catal. 1983, 21, 375-387. Publications in Refereed Journals, Cynthia M. Friend

1982 7. R. M. Wexler, M.-C. Tsai, C. M. Friend, and E. L. Muetterties, "Pyridine Coordination Chemistry of Nickel and Platinum Surfaces." J. Am. Chem. Soc. 1982, 104, 2034-2038. 6. M.-C. Tsai, C. M. Friend, and E. L. Muetterties, "Dehydrogenation Processes on Nickel and Platinum Surfaces. Conversion of Cyclohexane, Cyclohexene, and Cyclohexadiene to Benzene." J. Am. Chem. Soc. 1982, 104, 2539-2543. 5. M.-C. Tsai, J. Stein, C. M. Friend, and E. L. Muetterties, "Chemistry of Cyclic Olefins and Polyenes on Nickel and Platinum Surfaces.” J. Am. Chem. Soc. 1982, 104, 3533- 3534. 1981 4. C. M. Friend, J. Stein, and E. L. Muetterties, "Coordination Chemistry of Metal Surfaces. 2. Chemistry of CH3CN and CH3NC on Nickel Surfaces." J. Am. Chem. Soc. 1981, 103, 767-772. 3. C. M. Friend and E. L. Muetterties, "Coordination Chemistry of Metal Surfaces. Benzene and Toluene Interactions with Nickel Surfaces." J. Am. Chem. Soc. 1981, 103, 773-779.

2. C. M. Friend, E. L. Muetterties, and J. L. Gland, "Vibrational Studies of CH 3CN and CH3NC Adsorbed on Ni(111) and Ni(111)-C Surfaces." J. Phys. Chem. 1981, 85, 3256- 3262. 1980 1. C. M. Friend, R. M. Gavin, E. L. Muetterties, and M.-C. Tsai, "Coordination Chemistry of Metal Surfaces - Carbon Monoxide Chemisorption States on Pt(111)." J. Am. Chem. Soc. 1980, 102, 1717-1719.

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