Product Safety Data Sheet s3

PRODUCT SAFETY DATA SHEET

The information given in this Data Sheet refers to the Liquid Hardener Component (Hardener) used in the products listed below by Trade Name. Some of the systems are filled and no data is given on the fillers as they are not Dangerous Substances. All data refers to the Liquid, Wet and Uncured state.

Supplier Coo-Var Lockwood Street, HULL HU2 OHN Telephone No. 01482-328053 Fax No. 01482-219266 ------1. SUBSTANCE IDENTIFICATION TACKCOTE Q/109/1 - HARDENER ------2. CHEMICAL COMPOSITION

Description Formulated Aliphatic Amine Dangerous components CAS No. Designation % Index R phrases 9046-10-0 Polyalkyl amine < 50 C R34 140-31-8 Aminoethylpiperazine < 10 C R21/22-R34-R43 25154-52-3 Nonyl Phenyl < 50 C R22-R34 90-72-2 Tris-2,4,6-(Dimethyl aminoethyl) phenol < 5 Xn R22-R36/38 ------3. HAZARDS IDENTIFICATION

Hazard designation C Corrosive Information pertaining to particular dangers for man and environment R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R36/38 Irritating to eyes and skin R43 May cause sensitisation by skin contact. ------4. FIRST AID MEASURES

General information Remove soiled clothing immediately. After inhalation Move victim to fresh air and allow to rest. In case of breathing difficulties or distress, seek medical attention. After skin contact Remove contaminated clothing. Wash immediately with plenty of soap and water. In case of persistent irritation/rash, seek medical attention. After eye contact Rinse immediately with plenty of water, continuing for 15 minutes and seek medical attention. After swallowing Immediately rinse mouth with water and seek medical attention. If this is not immediately available, drink one or two pints of water. ------

5. FIRE-FIGHTING MEASURES

Suitable extinguishing agents Powder, foam, Carbon Dioxide. Special hazards Harmful gases and vapours. Protective equipment Wear self-contained breathing apparatus. ------Page 1 of 4 6. ACCIDENTAL RELEASE MEASURES

Safety precautions Avoid skin and eye contact. Wear goggles/visor, impervious gloves and protective clothing. Use in well ventilated areas. Measures for environmental protection Do not allow product to reach sewage system or any water course. Prevent seepage into sewage system, workpits and cellars. Inform respective authorities in case of seepage into water course or sewage system. Measures for cleaning/collecting Cover spills with sand, earth or sodium bisulphate to neutralise and reduce vapour. Dispose contaminated material as waste according to Item 13. Ensure adequate ventilation. ------7. HANDLING AND STORAGE

Handling Ensure good ventilationexhaust system at the work place. Storage Store in cool location. General Keep receptacle tightly sealed. Store in cool, dry conditions. ------8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure limits None established Monitoring method None Respiratory protection Air purifying respirator mask in poorly ventilated areas. Hand protection Impervious gloves Eye protection Goggles/glasses Skin protection Overalls Hygiene measures Keep away from foodstuffs, beverages and feed. Remove all soiled/contaminated clothing immediately. Wash hands before breaks and at the end of work. Avoid contact with eyes and skin ------9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Liquid Colour Straw Odour Ammoniacal, irritating Value/Range Unit Method Boiling point No data Flash point >105 0C Closed cup Ignition temperature No data Auto-ignition temp. No data Explosive limits No data Vapour pressure No data Density 1.05 g/cm3 Viscosity 6.0 - 8.0 Poise Solids content 100 % Solvent content 0 % Water solubility Insoluble 20oC ------

10. STABILITY AND REACTIVITY

Stability Stable if used according to specifications Conditions to avoid High temperatures Materials to avoid Strond acids, strong oxidising agents, amines Hazardous decomposition Toxic nitrogen and carbon oxides produced in fire Products Ammonia when heated. Incomplete combustion may cause toxins.

of 4 11. TOXICOLOGICAL INFORMATION

Acute toxicity LD/Lc50 values that are relevant for classification Components Type Value (mg/kg) Species Aminoethylpiperazine Oral 1470-2140 Rat Dermal 880-1260 Rabbit Tris-2,4,6-(Dimethyl aminoethyl) phenol Oral 1670 Rat Dermal >1400 Rabbit Polyalkylene amine Oral 2855 Rat Dermal 2980 Rabbit Nonyl phenyl Oral 1900 Rat Dermal 2140 Rabbit Primary irritant effects On the skin Irritant to skin and risk of burns On the eye Corrosive, may cause irreversible damage Inhalation Irritating to respiratory tract Ingestion Moderate acute toxicity. Risk of burns on mucous membranes. May cause nausea, vomiting and diarrhoea. Sensitisation Sensitisation possible. ------12. ECOLOGICAL INFORMATION

Biodegradability Not readily biodegradible Aquatic toxicity No data General notes Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. ------13. DISPOSAL CONSIDERATIONS

Substance Burn in compliance with operative regulations in a hazardous waste incinerator. Do not dispose of with household garbage. Do not allow to reach sewage system. Container Can be re-used after cleaning. Dispose of washing solution in the same way as the product. ------14. TRANSPORT INFORMATION

Land transport Amines, liquid, Corrosive NOS* ADR/RID Class 8 Maritime transport Amines, liquid, Corrosive NOS* IMDG Class 8 Air transport Amines, liquid, Corrosive NOS* ICAO-TI/IATA-DGR Class 8 UN/ID Number 2735 Packaging group III ------Page 3 of 4 15. REGULATIONS

Markings according to EC guidelines This product has been classified and marked in accordance with EC Directives/Ordinance on Hazardous materials. Code letter and hazard designation of product C Corrosive Contains Nonyl phenol Risk (R) and Safety phrases (S) R21/22 Harmful in contact with skin and if swallowed R34 Causes burns. R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. S26 In case of contact with eyes, rinse immediately with plenty of water. S28 After contact with skin, wash immediately with plenty of water and soap. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. ------16. OTHER INFORMATION

The information contained herein is based on our recent present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. ------DATE OF ISSUE JANUARY 1998 – REV. 1 Page 4 of 4

TACKCOTE Q/109/1 HARDNER 99 PRODUCT SAFETY DATA SHEET

This information given in this Data Sheet refers to the Liquid Resin Component (Base) used in the products listed below by Trade Name. Some of the systems are filled and no data is given on the fillers as they are not Dangerous Substances. All data refers to the products in the Liquid, Wet or Uncured state.

Supplier Coo-Var Lockwood Street, Hull HU2 OHN Telephone 01482-328053 Fax 01482-219266 ------1. SUBSTANCE IDENTIFICATION TACKCOTE – BASE Q/109/1 – BASE

------2. CHEMICAL COMPOSITION

Dangerous components CAS NO Designation % Index R-phrases 55492-52-9 BPF-epoxy resin; MW < 700 50-100 Xi 36/38-43 25068-38-6 BPA-epoxy resin; MW< 700 10-24.9 Xi 36/38-43 68081-84-5 C13/C15-Alkylglycidylether EINECS: 268-358-2 10-24.9 Xi, N 36/38-43-51/53 ------3. HAZARDS IDENTIFICATION

Hazard Designation Xi Irritant N Dangerous for the environment Information pertaining to particular dangers for man and environment R36/38 Irritating to eyes and skin R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Contains epoxy constituents. See information supplied by the manufacturer. ------4. FIRST AID MEASURES

General information Immediately remove any clothing soiled by the product. After inhalation Seek medical treatment in case of complaints. After skin contact Immediately wash with water and soap and rinse thoroughly. After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult your doctor. After swallowing Seek medical treatment. A person vomiting while lying on their back should be turned on their side. ------

5. FIRE FIGHTING MEASURES

Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Special hazards caused by the material, its products of combustion or flue gases: Formation of toxic gases is possible during heating or in case of fire. Carbon monoxide (CO) Protective equipment No special measures required Page 1 of 4 6. ACCIDENTAL RELEASE MEASURES

Person-related safety precautions Not required Measures for environmental protection Prevent liquid entering sewers, basements and workpits. Measures for cleaning/collecting Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust) ------7. HANDLING AND STORAGE

HANDLING Information for safe handling Ensure good ventilation/exhaustion at the workplace. Information about protection against explosions and fires No special measures required. STORAGE Requirements to be met by storerooms and containers No special requirements Information about storage in one common storage facility Not required Further information about storage and storage conditions Keep container tightly sealed. STORAGE CLASS Class according to regulation on flammable liquids Void ------8 EXPOSURE CONTROLS AND PERSONAL PROTECTION Additional information about design of technical systems No further data; See item 7. Components with critical values that require monitoring at the workplace The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. CAS No. Designation of material Type Value Unit Not required.

PERSONAL PROTECTIVE EQUIPMENT General protective and hygienic measures Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with eyes and skin. Breathing equipment Not required Protection of hands Protective gloves Eye protection Safety glasses ------9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Fluid Colour Light yellow Smell Nearly odourless Value/Range Unit Method Change in condition Boiling point/boiling range > 200 0C Flash point > 100 0C

Danger of explosion Product is not explosive Density at 200C 1.1 g/cm3 Solubility in/Miscibility with water Insoluble Viscosity Dynamic at 250C 1300 mPas ------10. STABILITY AND REACTIVITY Thermal decomposition/conditions to be avoided To avoid thermal decomposition do not overheat. Dangerous reactions Reacts with amines and reacts with catalysts Dangerous products of decomposition No dangerous decomposition products known Page 2 of 4 ------11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY Primary irritant effect On the skin Irritant for skin and mucous membranes On the eye Irritant effect Sensitisation Sensitisation possible by skin contact. Additional toxicological information The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Irritant ------12. ECOLOGICAL INFORMATION

General notes Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. ------13. DISPOSAL CONSIDERATIONS

PRODUCT Recommendation Hand over to disposers of hazardous waste.

UNCLEANED PACKAGINGS Recommendation Disposal must be made according to official regulations. ------14. TRANSPORT INFORMATION

Land transport ADR/RID and GGVS/GGVE (Cross-border/domestic) ADR/RID-GGVS/E Class 9 various dangerous materials and objects Number/Letter 11c Kemler Number 90 UN-Number 3082 Label 9 Designation of goods ENVIRONMENTAL HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (EPOXY RESIN) Maritime transport IMDG/GGVSea: IMDG/GGVSea Class: 9 Page 9028 UN Number 3082 Packaging Group III EMS Number ----- MFAG ----- Marine Pollutant Yes Correct Technical Name ENVIRONMENTAL HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (EPOXY RESIN) Air transport ICAO-TI and IATA-DGR: ICAO/LATA Class: 9 UN Number 3082 Packaging Group III Correct Technical Name ENVIRONMENTAL HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (EPOXY RESIN)

of 4 15. REGULATORY INFORMATION

Designation according to EC guidelines The product has been classified and labelled in accordance with EC Directives. Code letter and hazard designation of product Xi Irritant N Dangerous for the environment Hazard-determining components of labelling BPF-epoxy resin; MW < 700 BPA epoxy resin; MW < 700 C13/C15-Alkylglycidyl ether Risk (R) and safety phrases (S) R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse affects in the aquatic environment. S25 Avoid contact with eyes. S28 After contact with skin, wash immediately with plenty of soap and water. S37/39 Wear suitable gloves and eye/face protection. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Special designation of certain preparations Contains epoxy constituents. See information supplied by the manufacturer. ------16. OTHER INFORMATION

The information contained herein is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally contractual relationship. ------DATE OF ISSUE JANUARY 1998 – REV. 2 Page 4 of 4

TACKOTE BASE 99

The information given on this technical data sheet is correct to the best of our knowledge. Due to the policy of continuous improvement and modernisation to the product range some of the details may be subject to alteration without notice. If in any doubt please contact COO-VAR TECHNICAL services on 01482-328053 .

The details shown are of a technical nature and are not designed as instructions for use. For this information please read and understand details given on the containers and the relevant product brochures.

Should you require any information contact your stockist or Coo-Var directly.