MATERIAL SAFETY DATA SHEET Foam Cleaner Aerosol SKU: 99706

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

2. COMPOSITION/INFORMATION ON INGREDIENTS PRODUCT IDENTIFICATION MANUFACTURER Brand Name ...... Foam cleaner aerosol Fellowes (Manufacturing) Inc. Chemical Name ...... Mixture 1789 Norwood Avenue Common Name ...... Foam cleaner aerosol Itasca, IL 60143-1095 Formula ...... Mixture Molecular Weight ...... N/A Product Use...... Antistatic cleaner EMERGENCY TELEPHONE NUMBER Product Identification Number...... N/A (630) 893-1600 or (800) 893-7661 CHEMICAL NAME CAS NUMBER WEIGHT % Butane/Propane Propellant Mixture 5-10 Isopropanol 67-63-0 5-15 2-Butoxyethanol 111-76-2 <3 Proprietary Cleaning Blend Mixture »1 Proprietary Antistatic Agent Proprietary 0.5 Water 7732-18-5 Balance

3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW Foam with a lemon odor. DANGER! Extremely flammable; contents under pressure. May cause eye or skin irritation. May be harmful if inhaled or absorbed through skin.

In case of fire, use foam, dry chemical, sand, or CO2.

(Note: See Section 8 of this MSDS for Exposure Guidelines)

POTENTIAL HEALTH EFFECTS

PRIMARY ROUTE(S) OF ENTRY Inhalation (breathing); skin absorption; eye contact.

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SYMPTOMS OF EXPOSURE Inhalation: ...... Butane/propane acts as a simple asphyxiant and creates an oxygen deficient atmosphere; inhaling high concentratons can cause central nervous system depression. Breathing high concentrations of 2- butoxyethanol may cause respiratory irritation and may cause central nervous system effects (headache, nausea, vomiting, or unconsciousness) and may cause damage to the liver or kidney, or to the blood or lymph systems. Inhaling high concentrations of isopropyl alcohol can cause drowsiness, incoordination, or unconsciousness. Eye Contact:...... Direct contact with 2-butoxyethanol or exposure to its vapors may cause irritation. Redness, burning sensation. Skin Contact:...... May cause irritation. 2-Butoxyethanol is readily absorbed through the skin and may cause liver, kidney, blood or lymph system damage, depending on the duration and level of exposure. Ingestion:...... Headache, nausea, vomiting, dizziness, gastrointestinal upset.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Liver, kidney, and blood diseases; skin disorders.

REPORTED AS CARCINOGEN OR POTENTIAL CARCINOGEN ü Not Applicable ...... OSHA National Toxicology Program (NTP)...... International Agency for Research on Cancer (IARC)

4. FIRST AID MEASURES

INHALATION Remove from area to fresh air. Seek medical attention if respiratory irritation develops or if breathing becomes difficult.

EYE CONTACT Immediately rinse eyes with water. Remove any contact lenses, and continue flushing eyes with running water for at least 15 minutes. Hold eyelids apart to ensure rinsing of the entire surface of the eyes and lids with water. Get immediate medical attention.

SKIN CONTACT Wash affected areas with plenty of water, and soap if available, for several minutes. Remove and clean contaminated clothing and shoes. Seek medical attention if irritation develops or persists.

INGESTION Give 3-4 glasses of water, but DO NOT induce vomiting. If vomiting occurs, give fluids again. Get medical attention to determine whether vomiting or evacuation of stomach is necessary. Do not give anything by mouth to an unconscious or convulsing person.

NOTE TO PHYSICIAN This product contains butane/propane mixture, isopropanol and 2-butoxyethanol which can cause CNS effects or can cause liver, kidney, hematopoietic, or lymph system damage by inhalation or through skin absorption.

5. FIRE FIGHTING MEASURES

Flash Point and Method...... N/A (Gas)

GENERAL HAZARD Gas releases flammable vapors well below ambient temperatures and readily forms flammable mixtures with air. Its vapors may travel long distances to a source of ignition and flash back. Very dangerous fire and explosion hazard when exposed to heat or flame.

EXTINGUISHING MEDIA

Use foam, dry chemical, sand, or CO2.

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SPECIAL FIREFIGHTING INSTRUCTIONS Containers may explode in a fire. Move containers from area if it can be done without risk. Cool fire-exposed containers with water from side.

FIREFIGHTING EQUIPMENT As in any fire, wear NIOSH approved, positive-pressure self-contained breathing apparatus and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Wear appropriate protective equipment (See Section 8).

Remove all sources of ignition. Ventilate area to allow the released gases to dissapate. Absorb remaining liquid with sand or vermiculite; sweep up and place in a compatible container for later disposal. Residue can be washed with water.

7. HANDLING AND STORAGE

HANDLING Wear appropriate protective equipment (See Section 8). Avoid contact with eyes, skin, or clothing. Avoid breathing vapors or mist. Frequent or prolonged contact with the skin could cause defatting, leading to dry cracking. The use of an emollient cream is recommended after prolonged skin contact. Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.

STORAGE Store in a cool (below 120 °F), dry place. Keep away from sources of ignition.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS Use local exhaust or general dilution ventilation to maintain exposures below established permissible exposure levels.

PERSONAL PROTECTION

Respirator: ...... For prolonged exposures, consult an industrial hygienist or other technically qualified person to determine whether respiratory protection is required for the specific work conditions. Eye Protection:....Wear safety glasses if there is a potential for spraying this product into the eyes. Gloves:...... Use rubber gloves if this product will be handled several times daily. The use of an emollient cream is recommended after skin contact.

EXPOSURE CONTROLS

COMPONENT OSHA PEL ACGIH TLV

TWA STEL TWA STEL

Isopropyl Alcohol 400 ppm N/E 200 ppm 400 ppm

2-Butoxyethanol 50 ppm [skin] N/E 25 ppm [skin] N/E

Butane 800 ppm N/E 800 ppm N/E

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Propane 1,000 ppm N/E 2500 ppm N/E

9. PHYSICAL AND CHEMICAL PROPERTIES

State...... Aerosol Color...... White foam Odor...... Lemon Boiling Point °F ...... N.D. Pressure...... 70 psi Specific Gravity @ 20° C...... 0.98 Water Solubility ...... Soluble pH...... »9.5

10. STABILITY AND REACTIVITY

REACTIVITY Stable

INCOMPATIBILITIES Strong Oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS

Thermal decomposition will produce CO, CO2, and oxides of nitrogen.

CONDITIONS TO AVOID Sources of ignition.

11. TOXICOLOGICAL INFORMATION

For Isopropyl Alcohol RTECS NT8050000 Inhalation LCLo (rat)...... 16,000 ppm/4 hr Inhalation LCLo (mouse)...... 12,800 ppm/3 hr Oral LD50 (rat)...... 5,045 mg/kg Oral LC50 (mouse)...... 3,600 mg/kg Oral LDLo (human) ...... 14,432 mg/kg (Difficulty in breathing; coma) Oral LDLo (human) ...... 3,570 mg/kg (Respiratory depression) Oral LDLo (human) ...... 5,272 mg/kg (Chronic pulmonary edema or congestion) Oral LDLo (dog)...... 1,537 mg/kg (Nausea or vomiting) Dermal LD50 (rabbit)...... 12,800 mg/kg Skin irritation (rabbit) ...... Mild Eye Irritation (rabbit) ...... Severe in one study; moderate in two other studies.

For 2-Butoxyethanol RTECS KJ8575000 Inhalation LC50 (rat) ...... 450 ppm/4 hr. Inhalation LC50 (mouse)...... 700 ppm/7 hr. Inhalation TCLo (human) ...... 195 ppm/8 hr. (gastrointestinal effects) 100 ppm (Eye, smell, lungs, thorax, respiration effects) Oral LD50 (rat)...... 470 mg/kg

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Oral LD50 (mouse)...... 1,230 mg/kg Oral LD50 (rabbit) ...... 300 mg/kg Oral TDLo (woman) ...... 600 mg/kg

Dermal LD50 (rabbit)...... 220 mg/kg Dermal LD50 (guinea pig)..230 mg/kg Skin irritation (rabbit) ...... Mild Eye Irritation (rabbit) ...... Severe in one study; moderate in a second. Hazardous Substance Data Bank The lethal oral dose of various ethylene glycols in humans is approximately 1.4 ml/kg.

For Butane RTECS EJ4200000 3 Inhalation LC50 (rat) ...... 658 gm/m /4 hr 3 Inhalation LC50 (mouse)...... 680 gm/m /2 hr Hazardous Substances Data Bank Respiratory exposure of mice to 27% (270,000 ppm) for 2 hrs. caused death in 40% of the animals and 31% caused 60% mortality. In dogs, lethality was observed at concentrations of 200,000-250,000 ppm; anesthesia and relaxation preceded death... There was only a small margin of safety between the anesthetic and lethal concentration. (Snyder, E, "Browning's Toxicology and Metabolism of Industrial Solvents," 2nd Ed. Vol 1, 1987, p. 270) Butane appears to be mildly to moderately irritating to the rabbit skin. (Ibid., p. 271) The mutagenic potential of n -butane was evaluated in vitro at several concentrations using Ames Salmonella microsome assay. n-Butane was not mutagenic. (Kirwin, CJ, et al., J. Soc. Cosmet. Chem., 31, 367-70 (1980))

For Propane Hazardous Substances Data Bank Acute exposures of humans to 250, 500, or 1,000 ppm for periods of 1 minute to 8 hours did not produce any untoward physiological effects as determined by serial EKG's and continuous monitoring of modified V5 by telemetry during exposure. (Steward, RD, et al., Environ. Health Perspect., 26, 275-85 (1978)) The effects of propane were studied in guinea pigs exposed to 24-000-29,000 ppm and 47,000-55,000 ppm for periods of 5, 30, 60, and 120 minutes; at the lower concentration, irregular breathing was observed and at the higher concentration, tremors were evident during the first 5 minutes of exposure. Stupor was commonly observed in the animals exposed for longer periods of time (up to 2 hours). All animals recovered from the propane exposure and there were no pathological signs of organ toxicity at necropsy. In these studies, a CNS depressant ...effect for propane was not seen until exposure levels were about 50,000 ppm. (Snyder, E, "Browning's Toxicology and Metabolism of Industrial Solvents," 2nd Ed. Vol 1, 1987, p. 263)

12. ECOLOGICAL INFORMATION

For 2-Butoxyethanol LC50 (96hr) bluegill: 1490 mg/L. Cond: Static, 23 degrees C. LC50 (24hr) goldfish: 1650-1700 mg/L. LC50 (24hr) water flea: 1720 mg/L.

For Isopropyl Alcohol LC50(96hr) fathead minnow (29 days old): 94900-10400 mg/L. Cond: Flow-through, 24.4-24.6 degrees C, pH 7.09, 52.5 mg/L CaCO3. LC50(96hr) fathead minnow (31 days old): 61200-65500 mg/L. Cond: Flow-through, 24.6 degrees C, pH 7.87, 44

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CaCO3. EC50 (5 min) Photobacterium phosphoreum: 35390 ppm Microtox test.

13. DISPOSAL CONSIDERATIONS

RCRA Waste Code:...... D001 for the filled containers, as sold; empty containers are Not Regulated.

14. TRANSPORT INFORMATION This product, as sold, is banned from land disposal without prior treatment. DOT Proper Shipping Name ...... Consumer Commodity DOT Hazard Class...... ORM-D DOT I.D. Number...... None Packing Group...... None Label(s)...... None

TDGR Proper Shipping Name ...... Consumer Commodity TDGR Hazard Class...... Not regulated

15. REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) ü Hazardous Non-Hazardous

SARA HAZARD CATEGORIES (40 CFR 370) ü Acute ü Chronic ü Fire ü Pressure Reactive None

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (CPR Section (33)) This product has been classified according to the hazard criteria of the Controlled Products Regulations, and the MSDS contains all required information. ü Controlled Product - Classification: D2B, B1...... Not a Controlled Product

SARA TOXIC SUBSTANCES (40 CFR 372)

Chemical Name CAS Number %

Glycol ethers, including 2-Butoxyethanol 111-76-2 3 TOXIC SUBSTANCES CONTROL ACT The chemicals in this product are either listed in, or exempt from, the US TSCA Chemical Inventory and Canadian DSL. 2- Butoxyethanol is subject to the Preliminary Assessment Information Rule (40 CFR 712.30 (w)) and Health and Safety Data Reporting (40 CFR 716.120(a)). Isopropyl alcohol is subject to Health and Safety Data Reporting (40 CFR 716.120(a)), and to a Chemical Test Rule (40 CFR 799.2325). TSCA - Section 12(b) - Export Notification (Isopropyl alcohol). STATE REGULATIONS Florida Hazardous Substance List...... 2-Butoxyethanol, isopropyl alcohol - Present Massachusetts Right To Know List.2-Butoxyethanol, isopropyl alcohol, butane, propane - Present Minnesota Hazardous Substance List...... 2-Butoxyethanol (skin notation), isopropyl alcohol, butane, propane - Present New Jersey Right To Know List...... 2-Butoxyethanol - Substance No. 0275 Isopropyl Alcohol - Substance No. 1076 Butane - Substance No. 0273; Special Hazard - Flammable Propane - Substance No. 1594; Special Hazard -Flammable

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Pennsylvania Right To Know List...... 2-Butoxyethanol, isopropyl alcohol (Environmental Hazard), butane, propane - Present

16. OTHER INFORMATION

ABBREVIATIONS C - Ceiling limit N/A - Not applicable N/D - Not determined N/E - Not established N/K - Not known RQ - Reportable Quantity TPQ - Threshold Planning Quantity

Date Revised:...... November 5, 1998 Replaces...... July 22, 1995

REVISION INFORMATION Sections 1 & 15 - Added Canadian information. Section 5 - Revised firefighting equipment. Section 8 - Updated ACGIH TLV for isopropanol and 2-Butoxyethanol Section 11 & 12 - Information added.

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