LITHIUM CHLORIDE 1M SOLUTION IN ETHANOL MSDS
CAS No: MSDS
MATERIAL SAFETY DATA SHEET (MSDS)
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier Product form : Mixture : Product code : 4437A
1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
1.2.2. Uses advised against No additional information available
1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba 400005 Mumbai - INDIA T +91 22 6663 6663 - F +91 22 6663 6699 [email protected] - www.lobachemie.com
1.4. Emergency telephone number Emergency number : + 91 22 6663 6663 (9:00am - 6:00 pm)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC Not classified
Adverse physicochemical, human health and environmental effects No additional information available
2.2. Label elements Labelling according to Directive 67/548/EEC or 1999/45/EC No labelling applicable
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2.3. Other hazards No additional information available
SECTION 3: Composition/information on ingredients
3.1. Substance Not applicable
3.2. Mixture
Name Product identifier % Classification according Classification according to Directive 67/548/EEC to Regulation (EC) No. 1272/2008 [CLP] Ethanol (CAS No) 64-17-5 75 - 99 C; R35 Flam. Liq. 3, H226 (EC no) 200-578-6 R10 Skin Corr. 1A, H314 (EC index no) 603- 002-00-5 Lithium chloride (CAS No) 7447-41- 1 - 5 Xn; R22 Acute Tox. 4 (Oral), H302 8 Xi; R36/37/38 Eye Irrit. 2, H319 (EC no) 231-212-3 Skin Irrit. 2, H315 STOT SE 3, H335
Full text of R- and H-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician.
4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage.
4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures
5.1. Extinguishing media Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture No additional information available
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5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders Protective equipment : Use personal protective equipment as required. Emergency procedures : Stop release.
6.2. Environmental precautions Avoid release to the environment.
6.3. Methods and material for containment and cleaning up Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4. Reference to other sections No additional information available SECTION 7: Handling and storage
7.1. Precautions for safe handling Precautions for safe handling : Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. Hygiene measures : Wash ... thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Store in original container. Keep container tightly closed. Store in a dry place.
7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection
8.1. Control parameters No additional information available
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8.2. Exposure controls Hand protection : protective gloves Eye protection : Chemical goggles or face shield Skin and body protection : Wear suitable protective clothing Respiratory protection : Wear appropriate mask
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state : Liquid
Colour : Clear Colorless.
Odour : No data available
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information No additional information available SECTION 10: Stability and reactivity
10.1. Reactivity Thermal decomposition generates : Corrosive vapours.
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10.2. Chemical stability Stable under normal conditions.
10.3. Possibility of hazardous reactions No additional information available
10.4. Conditions to avoid Direct sunlight. Overheating. Open flame.
10.5. Incompatible materials No additional information available
10.6. Hazardous decomposition products Thermal decomposition generates : Corrosive vapours.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
Irritation : Not classified Corrosivity : Not classified Sensitisation : Not classified Repeated dose toxicity : Not classified Carcinogenicity : Not classified Mutagenicity : Not classified Toxicity for reproduction : Not classified
SECTION 12: Ecological information
12.1. Toxicity No additional information available
12.2. Persistence and degradability No additional information available
12.3. Bioaccumulative potential No additional information available
12.4. Mobility in soil No additional information available
12.5. Results of PBT and vPvB assessment No additional information available
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12.6. Other adverse effects No additional information available SECTION 13: Disposal considerations
13.1. Waste treatment methods Product/Packaging disposal : Dispose of contents/container to ... recommendations
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number UN-No. (ADR) : 1170 UN-No. (IMDG) : 1170 UN-No.(IATA) : 1170 UN-No.(ADN) : 1170 UN-No. (RID) : 1170
14.2. UN proper shipping name Proper Shipping Name (ADR) : ETHANOL (ETHYL ALCOHOL) / ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Proper Shipping Name (IMDG) : ETHANOL (ETHYL ALCOHOL) Proper Shipping Name (IATA) : ETHANOL Proper Shipping Name (ADN) : ETHANOL (ETHYL ALCOHOL) Proper Shipping Name (RID) : ETHANOL (ETHYL ALCOHOL) Transport document description (ADR) : UN 1170 ETHANOL (ETHYL ALCOHOL) / ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), 3, II, (D/E) Transport document description (IMDG) : UN 1170 ETHANOL (ETHYL ALCOHOL), 3, II Transport document description (IATA) : UN 1170 ETHANOL, 3, II Transport document description (ADN) : UN 1170 ETHANOL (ETHYL ALCOHOL), 3, II Transport document description (RID) : UN 1170 ETHANOL (ETHYL ALCOHOL), 3, II
14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 3 Danger labels (ADR) : 3
:
IMDG Transport hazard class(es) (IMDG) : 3 Danger labels (IMDG) : 3
:
IATA Transport hazard class(es) (IATA) : 3
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:
ADN Transport hazard class(es) (ADN) : 3 Danger labels (ADN) : 3
:
RID Transport hazard class(es) (RID) : 3 Danger labels (RID) : 3
:
14.4. Packing group Packing group (ADR) : II Packing group (IMDG) : II Packing group (IATA) : II Packing group (ADN) : II Packing group (RID) : II
14.5. Environmental hazards Dangerous for the environment : No Marine pollutant : No Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport Classification code (ADR) : F1 Special provision (ADR) : 144, 601 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container : T4 instructions (ADR) Portable tank and bulk container special : TP1 provisions (ADR) Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 2
www.lobachemie.com 30/08/2013 7/10 LITHIUM CHLORIDE 1M SOLUTION IN ETHANOL Safety Data Sheet Special provisions for carriage - Operation : S2, S20 (ADR) Hazard identification number (Kemler No.) : 33 Orange plates :
Tunnel restriction code (ADR) : D/E EAC code : •2YE
- Transport by sea Special provision (IMDG) : 144 Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A MFAG-No : 127
- Air transport PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity : 1L (IATA) PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L Special provision (IATA) : A3, A58, A180 ERG code (IATA) : 3L
- Inland waterway transport Classification code (ADN) : F1 Special provisions (ADN) : 144, 601 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport Classification code (RID) : F1 Special provision (RID) : 144, 601 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container : T4 instructions (RID) Portable tank and bulk container special : TP1 provisions (RID)
www.lobachemie.com 30/08/2013 8/10 LITHIUM CHLORIDE 1M SOLUTION IN ETHANOL Safety Data Sheet Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 33
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations
Contains no substances with Annex XVII restrictions Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Immission Control Act - 12.BImSchV
Denmark Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2. Chemical safety assessment No additional information available
SECTION 16: Other information
Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour H302 Harmful if swallowed
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H314 Causes severe skin burns and eye damage H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation R10 Flammable R22 Harmful if swallowed R35 Causes severe burns R36/37/38 Irritating to eyes, respiratory system and skin C Corrosive Xi Irritant Xn Harmful
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
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