Novel Trends in PAH Size Distribution in NGC2023
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Messengers from Outer Space
The complete absence of national laboratories for standardizing radiation measurements and the lack of physics departments in most radiotherapy centres in Latin America warrant the setting up of one or more regional dosimetry facilities, the functions of which would be primarily to calibrate dosimeters; to provide local technical assistance by means of trained staff; to check radiation equipment and dosimeters; to arrange a dose-intercomparison service; and to co-operate with local personnel dosimetry services. To be most effective, this activity should be in the charge of local personnel, with some initial assistance in the form of equipment and experts provided by the Agency. Although the recommendations were presented to the IAEA as the or ganization responsible for the setting up of the panel, the participants re commended that the co-operation of the World Health Organization and the Pan-American Health Organization should be invited. It was also suggested that the panel report be circulated to public health authorities in the countries represented. MESSENGERS FROM OUTER SPACE Although no evidence has yet been confirmed of living beings reaching the earth from space, it has been estimated that hundreds of tons of solid matter arrive every day in the form of meteorites or cosmic dust particles. Much is destroyed by heat in the atmosphere but fragments recovered can give valuable information about what has been happening in the universe for billions of years. Some of the results of worldwide research on meteorites were given at a symposium in Vienna during August. During six days of discussions a total of 73 scientific papers was present ed and a special meeting was held for the purpose of improving international co-operation in the research. -
Communications to the Editor 6499
Communications to the Editor 6499 Nbenzyloxycarbonyl benzyl ester 7. 368 (1971). (17) D. M. Brunwin and G. Lowe, J. Chem. SOC., Perkin Trans. 1, 1321 (34) Computer programs used for these calculations were the X-ray 1972 (1973). system, Technical Report TR-192, Computer Science Center, University (18) R. B. Woodward, "Recent Advances in the Chemistry of p-Lactam Anti- of Maryland, College Park, Md. biotics", Chem. SOC., Spec. Pub/., NO. 28, 167-180 (1977). (35) C. K. Johnson, ORTEP, Oak Ridge National Laboratory, Report ORNL- (19) D. B. Bryan, R. F. Hall, K. G. Holden, W. F. Huffman, and J. G. Gleason, J. 3794. Am. Chem. SOC., 99,2353 (1977). (36) R. M. Sweet in "Cephalosporins and Penicillins", E. H. Flynn, Ed.. Academic (20)T. W. Doyle, J. L. Dowlas, B. Beleau. J. Mennier. and B. Luh. Can. J. Chem., Press, New York, N.Y., 1972, p. 297. 55, 2873 (1977). - (37) X-ray data from H. E. Applegate, J. E. Dolfini, M. S.Puar, W. A. Slusarchyk. (21) F DiNinno. T. R. Beattie, and B. G. Christensen, J. Org. Chem, 42, 1960 and B. Toeplitz, J. Org. Chem., 39, 2794 (1974). (19771\.- ,. (38) Nonfused 4-thioazetidin-2-one intermediates in the synthesis of 6P-ac- (22) Related reductions in penicillin derivatives give predominantly Cis-sJDsli- ylaminopenem esters, e.g., 4~-acetylthio-3P-phenoxyacetylaminoazeti- tded products: J. C. Sheehan and Y. S. Lo, J. Org. Chem., 38, 3227 (19731; din-2-one or terf-butyl 2-(4@-acetyithio-2-oxo-3~-phenoxyacetylamino- F. DiNinno, unpublisned resdts. l-azetidinyl)-2-hydroxyacetate in CH~CIP,show the p-lactam band at 1782 (23) K. -
The Water on Mars Vanished. This Might Be Where It Went
The water on Mars vanished. This might be where it went. timesofindia.indiatimes.com/home/science/the-water-on-mars-vanished-this-might-be-where- it-went-/articleshow/81599751.cms NYT News Service | Mar 20, 2021, 10:32 IST Mars was once wet, with an ocean’s worth of water on its surface. Today, most of Mars is as dry as a desert except for ice deposits in its polar regions. Where did the rest of the water go? Some of it disappeared into space. Water molecules, pummeled by particles of solar wind, broke apart into hydrogen and oxygen atoms, and those, especially the lighter hydrogen atoms, sped out of the atmosphere, lost to outer space. A tall outcropping of rock, with layered deposits of sediments in the distance, marking a remnant of an ancient, long-vanished river delta in Jezero Crater, are pictured in this undated image taken by NASA's Mars rover Perseverance. (Reuters) But most of the water, a new study concludes, went down, sucked into the red planet’s rocks. And there it remains, trapped within minerals and salts. Indeed, as much as 99% of the water that once flowed on Mars could still be there, the researchers estimated in a paper published this week in the journal Science. Data from the past two decades of robotic missions to Mars, including NASA ’s Curiosity rover and the Mars Reconnaissance Orbiter, showed a wide distribution of what geologists call hydrated minerals. “It became very, very clear that it was common and not rare to find evidence of water alteration,” said Bethany Ehlmann, a professor of planetary science at the California Institute of Technology and one of the authors of the paper. -
AIKO ADAMSON Properties of Amine-Boranes and Phosphorus
DISSERTATIONES CHIMICAE AIKO ADAMSON AIKO UNIVERSITATIS TARTUENSIS 138 Properties of amine-boranes and phosphorus analogues in the gas phase Properties AIKO ADAMSON Properties of amine-boranes and phosphorus analogues in the gas phase Tartu 2014 ISSN 1406-0299 ISBN 978-9949-32-627-3 DISSERTATIONES CHIMICAE UNIVERSITATIS TARTUENSIS 138 DISSERTATIONES CHIMICAE UNIVERSITATIS TARTUENSIS 138 AIKO ADAMSON Properties of amine-boranes and phosphorus analogues in the gas phase Institute of Chemistry, Faculty of Science and Technology, University of Tartu. Dissertation is accepted for the commencement of the Degree of Doctor philo- sophiae in Chemistry on June 18, 2014 by the Doctoral Committee of the Institute of Chemistry, University of Tartu. Supervisor: prof. Peeter Burk (PhD, chemistry), Institute of Chemistry, University of Tartu, Estonia Opponent: prof. Holger Bettinger (PhD), University Tuebingen, Germany Commencement: August 22, 2014 at 10:00, Ravila 14a, room 1021 This work has been partially supported by Graduate School „Functional materials and technologies” receiving funding from the European Social Fund under project 1.2.0401.09-0079 in University of Tartu, Estonia. Publication of this dissertation is granted by University of Tartu ISSN 1406-0299 ISBN 978-9949-32-627-3 (print) ISBN 978-9949-32-628-0 (pdf) Copyright: Aiko Adamson, 2014 University of Tartu Press www.tyk.ee CONTENTS LIST OF ORIGINAL PUBLICATIONS ....................................................... 6 1. INTRODUCTION .................................................................................... -
The Protection of Frequencies for Radio Astronomy 1
JOURNAL OF RESEARCH of the National Bureau of Standards-D. Radio Propagation Vol. 67D, No. 2, March- April 1963 b The Protection of Frequencies for Radio Astronomy 1 R. 1. Smith-Rose President, International Scientific Radio Union (R eceived November 5, 1962) The International T elecommunications Union in its Geneva, 1959 R adio R egulations r recognises the Radio Astronomy Service in t he two following definitions: N o. 74 Radio A st1" onomy: Astronomy based on t he reception of waves of cos mi c origin. No. 75 R adio A st1"onomy Se1"vice: A service involving the use of radio astronomy. This service differs, however, from other r adio services in two important respects. 1. It does not itself originate any radio waves, and therefore causes no interference to any other service. L 2. A large proportion of its activity is conducted by the use of reception techniques which are several orders of magnit ude )]).ore sensitive than those used in other ra dio services. In order to pursue his scientific r esearch successfully, t he radio astronomer seeks pro tection from interference first, in a number of bands of frequencies distributed t hroughout I t he s p ~ct run:; and secondly:. 1~10r e complete and s p ec i~c prote.ction fOl: t he exact frequency bands III whIch natural radIatIOn from, or absorptIOn lD, cosmIc gases IS known or expected to occur. The International R egulations referred to above give an exclusive all ocation to one freq uency band only- the emission line of h ydrogen at 1400 to 1427 Mc/s. -
What Are Cosmic Rays?!
WhatWWhatWhhaatt areaarearree CosmicCCosmicCoossmmiicc Rays?!RRays?!Raayyss??!! By Hayanon Translated by Y. Noda and Y. Kamide Supervised by Y. Muraki ᵶᵶᵋᵰᵿᶗᶑᵘᴾᴾᵱᶇᶀᶊᶇᶌᶅᶑᴾᶍᶄᴾᵡᶍᶑᶋᶇᶁᴾᵰᵿᶗᶑᵋᵰᵿᶗᶑᵘᵘᴾᴾᵱᶇᶀᶊᶊᶇᶌᶅᶑᴾᶍᶄᴾᵡᶍᶑᶋᶇᶁᴾᵰᵿᶗᶑ Have you ever had an X-ray examination Scientists identified three types at the hospital? In 1896, a German of radiation: positively-charged alpha physicist, W. C. Röntgen, astonished people particles, negatively-charged beta particles, with an image of bones captured through and uncharged gamma rays. In 1903, M. the use of X-rays. He had just discovered Curie along with her husband, P. Curie, and the new type of rays emitted by a discharge Becquerel, won the Nobel prize in physics. device. He named them X-rays. Because Furthermore, M. Curie was awarded the of their high penetration ability, they are Nobel prize in chemistry in 1911. able to pass through flesh. Soon after, it Certain types of radiation including was found that excessive use of X-rays can X-rays are now used for many medical cause harm to bodies. purposes including examining inside the In that same year, a French scientist, body, treating cancer, and more. Radiation, A. H. Becquerel, found that a uranium however, could be harmful unless the compound also gave off mysterious rays. amount of radiation exposure is strictly To his surprise, they could penetrate controlled. wrapping paper and expose a photographic The work with radium by M. Curie later film generating an image of the uranium led to the breakthrough discovery of compound. The uranium rays had similar the radiation coming from space. These characteristics as those of X-rays, but were cosmic rays were discovered by an Austrian determined to be different from them. -
Problems with Panspermia Or Extraterrestrial Origin of Life Scenarios As Found on the IDEA Center Website At
Problems with Panspermia or Extraterrestrial Origin of Life Scenarios As found on the IDEA Center website at http://www.ideacenter.org Panspermia is the theory that microorganisms or biochemical compounds from outer space are responsible for originating life on Earth and possibly in other parts of the universe where suitable atmospheric conditions exist. Essentially, it is a hypothesis which states that life on earth came from outer space. It has been popularized in countless science fiction works, however some scientists, including the discoverer of the structure of DNA, Francis Crick, have advocated panspermia. There are generally about 3 different "flavors" of panspermia: 1. Naturalistic Panspermia where life evolves on another planet, and naturally gets ejected off the planet and come to rest on earth. 2. Directed Panspermia where intelligent life on other planets intentionally seeded other planets with their own form of life. 3. Intelligent Design Panspermia, where intelligent beings from another planet came to earth and designed life here. Each type of panspermia will be briefly discussed below: 1. Naturalistic Panspermia where life evolves on another planet, and naturally gets ejected off the planet and come to rest on earth. Naturalistic panspermia has gained popularity because some have recognized that life on earth appears very soon after the origin of conditions which would allow it to exist. Many scientists believed that if life had originated on earth it would have taken many hundreds of millions, or even billions of years to do so. Life appears perhaps less than 200 million after the origin of conditions at which life could exist. -
Icr Annual Report 2005
ISSN 1342-0321 IAREFM ICR ANNUAL REPORT 2005 Volume 12 Institute for Chemical Research Kyoto University ICR ANNUAL REPORT 2005 (Volume 12) - ISSN 1342-0321 - This Annual Report covers from 1 January to 31 December 2005 Editors: Professor: OZAWA, Fumiyuki Professor: KANAYA, Toshiji Associate Professor: NISHIDA, Koji Associate Professor: GOTO, Susumu Editorial Staff: Public Relations Section: TSUGE, Aya GENMA, Mieko KOTANI, Masayo Published and Distributed by: Institute for Chemical Research (ICR), Kyoto University Copyright 2006 Institute for Chemical Research, Kyoto University Enquiries about copyright and reproduction should be addressed to: ICR Annual Report Committee, Institute for Chemical Research, Kyoto University Note: ICR Annual Report available from the ICR Office, Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan Tel: +81-(0)774-38-3344 Fax: +81-(0)774-38-3014 E-mail [email protected] URL http://www.kuicr.kyoto-u.ac.jp/index.html Uji Library, Kyoto University Tel: +81-(0)774-38-3011 Fax: +81-(0)774-38-4370 E-mail [email protected] URL http://lib.kuicr.kyoto-u.ac.jp/homepage/english/homepageeng.html Printed by: Nakanishi Printing Co., Ltd. Ogawa Higashi-iru, Shimodachiuri, Kamigyo-ku, Kyoto 602-8048, Japan TEL:+81-(0)75-441-3155 FAX:+81-(0)75-417-2050 ICR AN NU AL REPORT 2005 Institute for Chemical Research Kyoto University Volume 12 Pref ace Institute for Chemical Research at Kyoto University has Moreover, we are encouraging community education to celebrated its 79th anniversary in October 2005. Initially, communicate the signifi cance and appeal of cutting-edge the size of the Institute was not substantial and it contained research through our “Chemical Research for High School only a limited number of laboratories, but growth soon ac- Students” and “Open Campus” programs. -
Owning Outer Space Ezra J
Northwestern Journal of International Law & Business Volume 20 Issue 1 Fall Fall 1999 Owning Outer Space Ezra J. Reinstein Follow this and additional works at: http://scholarlycommons.law.northwestern.edu/njilb Part of the Air and Space Law Commons Recommended Citation Ezra J. Reinstein, Owning Outer Space, 20 Nw. J. Int'l L. & Bus. 59 (1999-2000) This Article is brought to you for free and open access by Northwestern University School of Law Scholarly Commons. It has been accepted for inclusion in Northwestern Journal of International Law & Business by an authorized administrator of Northwestern University School of Law Scholarly Commons. Owning Outer Space Ezra J. Reinstein * I. INTRODUCTION What do we want from space? We want the knowledge we can gain from scientific research; we can learn much about the Earth and its inhabitants, as well as the universe around us, by studying space. We want to explore, to satisfy the thirst for adventure and conquest imagined in countless science fiction books and films. We want to improve our collective lot down here on Earth. Space offers the potential for practically limitless wealth, some already being exploited, some we may only harness in the distant future, and un- doubtedly some we cannot begin to guess. Already the wealth of space is being developed in the form of telecommunications and remote satellite ob- servation. The private-sector investment in telecommunications satellites alone was projected to total $54.3 billion (including launch) between 1996 and 20001 -- and this figure doesn't include other commercial space ven- tures, nor does it include investment in Russian and Chinese satellites. -
Crater: How Cosmic Rays Affect Humans
Lunar Reconnaissance Orbiter: (CRaTER) Audience CRaTER: Grades 6-8 How Cosmic Rays Affect Time Recommended 30-45 minutes Humans AAAS STANDARDS • 1B/1: Scientific investigations usually involve the col- lection of relevant evidence, the use of logical reasoning, Learning Objectives: and the application of imagination in devising hypoth- • Students will be able to describe why cosmic rays are dangerous to eses and explanations to make sense of the collected evidence. astronauts. • Students will learn to design a scientific instrument. • 3A/M2: Technology is essential to science for such purposes as access to outer space and other remote • Students will think critically about how to protect astronauts from cosmic locations, sample collection and treatment, measurement, rays. data collection and storage, computation, and communi- cation of information. NSES STANDARDS Preparation: Content Standard A (5-8): Abilities necessary to do scien- None tific inquiry: c. Use appropriate tools to gather, analyze and inter- pret data. Background Information: d. Develop descriptions and explanations using On their trips to and from the Moon, Apollo astronauts saw small white flashes evidence. of light while in the dark—even with their eyes closed. They usually saw no e. Think critically and logically to make relationships more than a couple each minute, although at least one astronaut saw so many between evidence and explanations he had trouble sleeping. What caused these flashes? Content Standard E (5-8): Science and Technology: b. Technology is essential to science, because it The answer is cosmic rays. Because of their high speeds, thousands of these provides instruments and techniques that enable observations of objects and phenomena that cosmic rays were passing through the bodies of the Apollo astronauts every are otherwise unobservable due to factors such second. -
On the Impact of Excited State Antiaromaticity Relief in a Fundamental
On the Impact of Excited State Antiaromaticity Relief in a Fundamental Benzene Photoreaction Leading to Substituted Bicyclo[3.1.0]hexenes Tomáš Slanina,1,2 Rabia Ayub,1,‡ Josene Toldo,1,‡ Johan Sundell,3 Wangchuk Rabten,1 Marco Nicaso,1 Igor Alabugin,4 Ignacio Fdez. Galván,5 Arvind K. Gupta,1 Roland Lindh,5,6 Andreas Orthaber,1 Richard J. Lewis,7 Gunnar Grönberg,7 Joakim Bergman3,* and Henrik Ottosson1,* 1 Department of Chemistry – Ångström Laboratory, Uppsala University, SE-751 20, Uppsala, Sweden. 2 Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo námĕstí 2, 16610 Prague 6, Czech Republic 3 Medicinal Chemistry, Research and Early Development Cardiovascular, Renal and Metabolism, BioPharmaceuticals R&D, AstraZeneca, Gothenburg, Sweden. 4 Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306-4390, USA, 5 Department of Chemistry – BMC, Uppsala University, 751 23, Uppsala, Sweden, 6 Uppsala Center for Computational 7 Chemistry – UC3, Uppsala University, 751 23, Uppsala Sweden, Medicinal Chemistry, Research and Early Development Respiratory, Inflammation and Autoimmune, BioPharmaceutical R&D, AstraZeneca Gothenburg, Sweden. ‡ These authors contributed equally. Table of contents 1. Materials and Methods ..................................................................................................................... 3 1.1 General information ..................................................................................................................... -
Impact of Excited-State Antiaromaticity Relief in a Fundamental Benzene
This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited. pubs.acs.org/JACS Article Impact of Excited-State Antiaromaticity Relief in a Fundamental Benzene Photoreaction Leading to Substituted Bicyclo[3.1.0]hexenes ∇ ∇ Tomaś̌Slanina, Rabia Ayub, Josene Toldo, Johan Sundell, Wangchuk Rabten, Marco Nicaso, Igor Alabugin, Ignacio Fdez. Galvan,́ Arvind K. Gupta, Roland Lindh, Andreas Orthaber, Richard J. Lewis, Gunnar Grönberg, Joakim Bergman,* and Henrik Ottosson* Cite This: J. Am. Chem. Soc. 2020, 142, 10942−10954 Read Online ACCESS Metrics & More Article Recommendations *sı Supporting Information ABSTRACT: Benzene exhibits a rich photochemistry which can provide access to complex molecular scaffolds that are difficult to access with reactions in the electronic ground state. While benzene is aromatic in its ground state, it is antiaromatic in its lowest ππ* excited states. Herein, we clarify to what extent relief of excited-state antiaromaticity (ESAA) triggers a fundamental benzene photoreaction: the photoinitiated nucleophilic addition of solvent to benzene in acidic media leading to substituted bicyclo[3.1.0]hex-2-enes. The reaction scope was probed experimentally, and it was found that silyl-substituted benzenes provide the most rapid access to bicyclo[3.1.0]hexene derivatives, formed as single isomers with three stereogenic centers in yields up to 75% in one step. Two major mechanism hypotheses, both involving ESAA relief, were explored through quantum chemical calculations and experiments. The first mechanism involves protonation of excited-state benzene and subsequent rearrange- ment to bicyclo[3.1.0]hexenium cation, trapped by a nucleophile, while the second involves photorearrangement of benzene to benzvalene followed by protonation and nucleophilic addition.