J OURNAL OF Journal of Petrology, 2019, Vol. 60, No. 11, 2131–2168 doi: 10.1093/petrology/egaa002 P ETROLOGY Advance Access Publication Date: 11 April 2020 Original Article
Archean Boninite-like Rocks of the Northwestern Youanmi Terrane, Yilgarn Craton: Geochemistry and Genesis Jack R. Lowrey1,2, Derek A. Wyman 1*, Tim J. Ivanic2, Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021 R. Hugh Smithies2 and Roland Maas3
1School of Geosciences (F09), University of Sydney, Sydney, NSW 2006, Australia; 2Department of Mines and Petroleum, Geological Survey of Western Australia, 100 Plain Street, East Perth, WA 6004, Australia; 3School of Earth Sciences, University of Melbourne, Melbourne, VIC 3010, Australia
*Corresponding author. School of Geosciences (F09), University of Sydney, Sydney, NSW 2006, Australia. Telephone: 61 2 9351 2924. E-mail: [email protected]
Received December 26, 2018; Accepted January 5, 2020
ABSTRACT Rocks with chemical compositions similar to Cenozoic boninites occur in many Archean cratons (boninite-like rocks), but they are rarely well-preserved, well-sampled, or presented within chrono- and chemo-stratigraphic context. This study provides a detailed description of the most extensive and well-preserved Archean boninite-like rocks reported to date. Within the 2820 to 2740 Ma mag- matic suites of the northwest Youanmi Terrane, Yilgarn Craton, boninite-like rocks occur as two distinct units. The first boninite-like unit is thinner (several 10 s of m thick), occurs close to the base of the 2820–2800 Ma Norie Group and includes both volcanic flows and subvolcanic intrusions. The second boninite-like unit is thicker (locally several 100 s m), occurs near the base of the 2800– 2740 Ma Polelle Group and consists of mainly fine-grained volcanic flows with local cumulate units. On average, major and trace element compositions for Youanmi Terrane boninite-like rocks are marginal between basalt, picrite and boninite and they have asymmetrically concave REE patterns, and Th–, Zr–Hf enrichments, similar to many Phanerozoic low-Si boninite suites, but at generally higher MREE–HREE contents. We report over 300 new whole-rock geochemical analyses, and 16 new Sm–Nd isotopic analyses, and associated petrographic evidence, including representative mineral compositions, which we support with published geochemical analyses and several deca- des of fieldwork in our study area. Comparison between Archean boninite-like rocks and Cenozoic boninites shows that most Archean examples had less depleted sources. We consider two possible petrogenetic models for the Youanmi Terrain examples: (1) they reflect variably contaminated komatiites, or (2) they reflect melts of metasomatised refractory mantle, analogous to Phanerozoic boninites. Trace element modelling indicates that crustal contamination could potentially produce rocks with boninite-like compositions, but requires an Al-enriched komatiitic parent liquid, for
which there is no field evidence in our study area. Initial eNdT values in pre-2800 Ma rocks (eNdT -0 4 to þ1 2) are on average slightly higher than those in 2800–2733 Ma examples (eNdT -3 2toþ1 2), compatible with increasing mantle metasomatism involving recycling of 2950 Ma crust. Integration of trace element and Nd isotopic data demonstrates that significant direct crustal as- similation was restricted to felsic magmas. The Th–Nb and Ba–Th systematics of mafic- intermediate rocks reflect fluid- and sediment-derived processes in the mantle, with boninite-like examples being linked primarily to fluid metasomatism. We compare the well-preserved igneous textures and mineralogy of Youanmi Terrane boninite-like rocks with those of their Phanerozoic
counterparts, and based on studies of the latter, suggest that former had similarly hot, H2O-rich parent magmas. The association of boninite-like rocks in the Norie and Polelle Groups with coeval high-Mg andesites, sanukitoids and hydrous mafic intrusions of the Narndee Igneous Complex
VC The Author(s) 2020. Published by Oxford University Press. All rights reserved. For permissions, please e-mail: [email protected] 2131 2132 Journal of Petrology, 2019, Vol. 60, No. 11 strongly suggests a metasomatised mantle source and subduction operating in the Yilgarn be- tween 2820 and 2730 Ma.
Key words: Archean boninite; Archean subduction; mantle metasomatism; crustal contamination
INTRODUCTION Like komatiites and komatiitic basalts, boninitic melts The beginning of modern-style plate tectonics is a sub- can have high-MgO (e.g. up to 20 wt % MgO; Walker & ject of much debate, and one of the most contested Cameron 1983), but incompatible lithophile elements arguments is whether some Archean greenstones are are much higher than in komatiites. For example, analogous to modern volcanic arcs, or that their similar- Cenozoic boninites typically have very characteristic Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021 ities are superficial (Barley et al., 1984, 1989; Campbell concave REE patterns, and Th/Nb ratios higher than & Hill 1988; Condie 2005a, 2005b; Smithies et al., 2005; those inferred for MORB-OIB mantle. However, similar B-dard 2006, 2018; Pearce 2008; Be´ dard et al., 2013; characteristics would be expected in komatiitic melts Wyman 2013). Many Archean greenstone sequences contaminated by felsic crust, and so differentiating contain volcanic rocks that are chemically similar to between boninite and contaminated komatiite can be modern arc rocks (Basalt–Andesite–Dacite–Rhyolite; difficult. This is particularly pertinent for Archean BADR), yet such chemical signatures could be superim- boninite-like and low-Ti basalt (LOTI) suites, which form posed on non-arc melts by crustal contamination or by a component of greenstone sequences in many cratons mixing with crustally-derived melts (Pearce, 2008; Said and have been cited as strong evidence for modern- & Kerrich, 2010; Barnes et al., 2012; Barnes & Van style subduction processes in the Archean (Fan & Kranendonk 2014). Kerrich, 1997; Kerrich et al., 1998; Boily & Dion, 2002; To assess whether arc-like characteristics in evolved Polat et al., 2002; Manikyamba et al., 2005; Smithies BADR rocks were indeed derived from subduction- 2002; Smithies et al., 2004, 2005; Wyman & Kerrich, metasomatised mantle, it is necessary to first con- 2012; Angerer et al., 2013; Turner et al., 2014). In many strain the composition of their inferred mantle source. Archean greenstone terranes, it is unclear whether vol- High-Mg mafic volcanic rocks (including boninites) are canism occurred in an oceanic or continental setting, particularly useful in this respect because their compo- because pre-existing crust cannot be identified. Under sitions are relatively close to those of their primary such circumstances, tectonic models must rely heavily melts. A potential disadvantage of using highly mag- on inferences from sedimentary provenance, inherited nesian samples to trace primary magma composition zircon geochronology and isotopic compositions, and is their intrinsically low concentrations of incompatible whole-rock geochemistry, with potentially ambiguous trace elements, which are easily modified by alteration results and conflicting interpretations (e.g. Arndt et al., and/or small amounts of crustal contamination. 2001 vs Smithies et al., 2004). The best-known examples of Phanerozoic boninites, Here we present new whole-rock chemical and Sm– such as those in the Cenozoic Izu- Ogasawara-Mariana Nd isotopic data and investigate the petrogenesis of arcs, or the Tonga Ridge, are exclusively found in sub- high-Mg mafic volcanic rocks from a 2820–2735 Ma vol- duction zone settings, where they are mainly associated cano–sedimentary sequence near Meekatharra, in the with the embryonic stages of subduction. Boninites in Youanmi Terrane of the Yilgarn Craton, Western ophiolites are commonly thought to be representative Australia. Previous work identified a volcanic unit with of oceanic crust that formed in such settings (e.g. boninite-like compositions within this sequence Crawford et al., 1989; Pearce & Robinson, 2010; Haase (Wyman & Kerrich, 2012) and this study confirms that et al., 2015). Typically regarded as products of mantle boninite-like rocks are both laterally extensive and flux-melting, some authors have proposed that bonin- more representative of the Meekatharra Formation than ites, like komatiites, may additionally require anomal- previously appreciated. In addition, we describe a ously high melting temperatures, and have suggested newly identified occurrence of boninite-like rocks that upwelling hot refractory mantle plume-material is formed during the early stages of magmatism at drawn into the mantle wedge where it interacts with hy- c.2820 Ma. Unlike most Archean boninite-like rocks drous fluids and partial melts released from subducting described to date, the examples in the northwestern crust (e.g. Taylor et al., 1994; Portnyagin et al., 1997; Youanmi Terrane are remarkably well-preserved (low Macpherson & Hall 2001; Falloon et al., 2008; grade, greenschist facies metamorphism in some) and Kanayama et al., 2012). A similar model has also been retain much of their primary igneous mineralogy. This proposed for ultra-depleted Al-enriched komatiites in allows the rocks to be placed within a chemostrati- the Commondale greenstone belt, South Africa (Wilson, graphic framework that can be used for comparisons 2003a, 2003b), which plot as boninites in the new with modern volcanic settings. The new results, com- scheme of Pearce & Reagan (2019). bined with existing chemical and isotopic data from the Journal of Petrology, 2019, Vol. 60, No. 11 2133 western Youanmi Terrane, are used to further assess assigned to the Singleton Formation, overlain by a se- the petrogenesis of these magmas against the compet- quence of intermediate volcanic and sedimentary units, ing crustally-contaminated komatiite and embryonic including jaspilitic banded iron formations, cherts, and subduction models. shales, all assigned to the Yaloginda Formation. The mafic–ultramafic metavolcanic rocks of the Singleton Formation (now mostly talc–chlorite–tremo- GEOLOGICAL BACKGROUND lite–serpentine schists) have been interpreted by most The chronostratigraphic and magmatic framework of previous studies to have a komatiitic association the northwestern Youanmi Terrane (northern (Jackson, 1990; Reudavey, 1990, Watkins & Hickman, Murchison Domain) was recently revised by Van 1990; Barley et al., 2000; Hallberg, 2000; Pidgeon & Kranendonk et al. (2013). Archean supracrustal rocks Hallberg, 2000; Van Kranendonk et al., 2013). Barley are defined as the Murchison Supergroup, which is div- et al. (2000) invoked mantle plume ascent beneath Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021 ided into three main stratigraphic successions: (1) most- subduction-modified lithosphere to account for their ly felsic volcanic and sedimentary rocks from 2 98– trace element signatures and high volatile content, as 2 92 Ga; (2) voluminous (ultra)mafic to felsic volcanic reflected by pyroclastic occurrences. Wyman (2019), and (volcano-) sedimentary rocks (Norie Group, c.2820– however, argued that the rocks were similar to picrites 2800 Ma; Polelle Group, 2800–2735 Ma); and (3) silici- from Phanerozoic ophiolites and that pyroclastic occur- clastic and mafic volcanic rocks (Glen Group, c.2735– rences were the product of magma mixing with wet 2710 Ma), which unconformably overlie the Polelle crustal melts. Group. Two main geodynamic models are proposed for Mafic intrusions of the 2820–2815 Ma Meeline Suite, volcanism between c.2820 and 2735 Ma, including rift- including the Lady Alma Igneous Complex in the ing and mantle upwelling, leading to autochthonous Gabanintha region (Figs 2 and 3) and the voluminous crustal growth (Watkins & Hickman, 1990; Ivanic et al., Windimurra and Youanmi Igneous Complexes (approxi- 2012; Van Kranendonk et al., 2013), and hydrous melt- mately 100 km south of the study area; Ivanic et al., ing in a subduction zone environment (Wyman, 2019) 2017), are broadly coeval with the Singleton Formation. or a combination of the two (Champion & Cassidy, The Singleton Formation is overlain by a c.2 km thick 2002; Wyman & Kerrich, 2012). The stratigraphic rela- sequence of intermediate to felsic volcanic rocks tionships of the Murchison Supergroup are summar- assigned to the Yaloginda Formation. U–Pb zircon dat- ised in Fig. 1. ing of these volcanic rocks in the study area yielded The field area for this work lies between the towns of ages ranging from c.2815 6 7 to 2806 6 4Ma (Wang, Cue and Meekatharra, where several geological map- 1998; Wingate et al., 2011). In this area, the Yaloginda ping and geochronological studies (Watkins & Formation consists of porphyritic basaltic andesites Hickman, 1990; Wang et al., 1998; Hallberg, 2000; near its base, overlain by porphyritic and volcaniclastic Pidgeon & Hallberg, 2000; Romano, 2018) have estab- (medium–coarse grained breccia) andesite to dacite lished the ages of the geological units (Fig. 2). Two and fine-grained rhyolitic tuffs. areas with well-exposed stratigraphic intervals were Numerous fine-grained interflow sediments (promin- studied in detail: ent ridges of jaspilitic banded iron formation, cherts, shales and siltstones) are locally intruded by mafic– 1. Outcrops in the Gabanintha Mining District (approxi- ultramafic sills. A c.1500 m thick unit of these sediments mately 40 km SE of Meekatharra; Figs 2 and 3) ex- marks the boundary between the Yaloginda Formation pose the transition between two chemically distinct and the overlying Polelle Group. The abundance of thick suites of mafic–ultramafic volcanic rocks in the ridges of finely laminated banded iron formation, shale Singleton Formation. Most rocks are metamor- and chert indicates an extended period (at least locally) phosed to greenschist facies, but preserve primary of volcanic quiescence between the Norie and Polelle characteristics such as vesicles and relict igneous Groups. crystal boundaries. 2. Outcrops in the Polelle Syncline (approximately 10 km SE of Meekatharra; Fig. 2) expose the upper Polelle Group Norie Group (Yaloginda Formation) to upper Polelle The Polelle Group in the study area consists of the basal Group (Greensleeves Formation). The rocks in this Meekatharra Formation and the overlying Greensleeves area experienced only low-grade metamorphic over- Formation (Fig. 1). The Polelle Group is exposed printing (prehnite-pumpellyite to lower greenschist throughout much of the northwestern Youanmi facies) and are generally well-preserved, retaining Terrane, but is best preserved in the Polelle Syncline both igneous textures and in many cases primary (Fig. 2). In this locality the Meekatharra Formation com- mineralogy. prises four discrete units (Fig. 1). The basal unit is the Lordy Basalt Member, which is dominated by high-Mg Norie Group basalt with coarse acicular pyroxene phenocrysts and, The Norie Group in the study area (Fig. 2) consists of a locally, pyroxene spinifex textures. This is overlain by basal sequence of mafic–ultramafic volcanic rocks the Bassetts Volcanic Member, a high-Mg mafic 2134 Journal of Petrology, 2019, Vol. 60, No. 11 Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021
Fig. 1. Stratigraphic relationships of the Murchison Supergroup (modified after Ivanic, 2016; see also Romano, 2018). volcanic unit with boninite-like chemical compositions The 2799 6 7 Ma Narndee Igneous Complex, 100 km and textural characteristics (see also Wyman & Kerrich, south of the study area, is intruded immediately prior to 2012) that typically contains abundant fine acicular pyr- or coincident with the Meekatharra Formation and oxene phenocrysts and, locally, orthopyroxene-rich cu- hosts similar volumes of high-Mg lithologies (Ivanic mulate layers. The Bassetts Volcanic Member is et al., 2015). Importantly, Narndee gabbros contain overlain by the Stockyard Basalt Member, which is abundant igneous hornblende, with mantle-like H–O dominated by lower-Mg tholeiitic basalt that is typically isotopic ratios, reflecting the presence of (locally) massive, but locally contains pillow structures and hydrated mantle at the time of the Meekatharra vesicles. The youngest member of the Meekatharra Formation high-Mg magmatic activity. Formation is the Bundle Volcanic Member, which is a The basal unit of the Greensleeves Formation, the high-Mg basalt to basaltic andesite unit that consists of Woolgra Andesite Member, consists of interbedded vol- a sequence of several flows, internally zoned into platy canic flows, fragmental units, and volcanogenic sedi- pyroxene spinifex-textured flow tops and olivine-rich mentary units, ranging in composition from basaltic cumulate bases (Lowrey et al., 2017). andesite to dacite. Flows and volcanic fragmental rocks Journal of Petrology, 2019, Vol. 60, No. 11 2135 Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021
Fig. 2. Interpreted bedrock geology map of the northwest Youanmi Terrane (i.e. north Murchison Domain), Yilgarn Craton (modi- fied after Lowrey et al., 2017). This map shows the distribution of supracrustal groups and co-genetic intrusive suites, available geo- chronological data, major structural features and significant localities. Interpretation is based on 1:100,000 mapping by the Geological Survey of Western Australia (GSWA), and supplemented by our interpretation of aeromagnetic and Landsat multispec- tral images. Coordinates are relative to GDA94/MGA Z50. Geochronology sample sources (Wang, 1998; Pidgeon & Hallberg, 2000; Geological Survey of Western Australia, 2018). Inset abbreviations: MD, Murchison Domain; SCD, Southern Cross Domain; YT, Youanmi Terrane; NT, Narryer Terrane; SWT, South West Terrane; EGS, Eastern Goldfields Superterrane. are locally amygdular and typically porphyritic, with eu- ages (2761–2734 Ma; Van Kranendonk et al., 2013) indi- hedral plagioclase, clinopyroxene and, locally, horn- cate a c.20 Ma period of apparently continuous felsic blende phenocrysts, which commonly form volcanism. Numerous hornblende-rich tonalite plutons glomerocrysts (Hallberg et al., 1976). U–Pb in zircon assigned to the Cullculli Suite (dominantly 2760– 2136 Journal of Petrology, 2019, Vol. 60, No. 11 Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021
Fig. 3. Interpreted bedrock geology map of Gabanintha Mining District (see Fig. 2 for regional context). This map shows the distri- bution of geochemical samples discussed in this section.
2740 Ma; Van Kranendonk et al., 2013) intrude the Norie and Polelle Groups within the Meekatharra-Mt greenstone stratigraphy and are broadly coeval with Magnet greenstone belt (Fig. 2). Most samples were col- this period of volcanism. lected from outcrops during this study (301 samples) with care taken to avoid weathered, altered, veined or highly metamorphosed rocks. The Polelle Group sam- ples (sub-greenschist to greenschist) are better pre- SAMPLE SELECTION AND ANALYTICAL served than those from the Norie Group (greenschist to PROCEDURES locally granulite facies). Whole rock major, minor and trace element The samples were crushed by jaw crusher, milled concentrations using a low-Cr steel mill and then analysed at three Our study is based on a large set of whole-rock chem- Western Australian laboratories; Australian Laboratory ical analyses for 445 samples of volcanic rocks from the Services (ALS), Intertek Genalysis Laboratory Services Journal of Petrology, 2019, Vol. 60, No. 11 2137
Pty Ltd (Genalysis), and Bureau Veritas (BV). In addition using Eichrom TRU- and LN-resin (Pin & Santos to the samples collected during this study, we also re- Zalduegui, 1997). Total blanks (0 1 ng Nd, 0 016 ng Sm) port compositions for an additional 144 samples col- were negligible compared to sample sizes and no blank lected by GSWA during a previous mapping campaign corrections were applied. All isotopic data were (Watkins & Hickman, 1990) that were crushed in a plate acquired on a Nu Plasma multi-collector ICP-MS, with jaw crusher, milled in a tungsten-carbide mill and ana- sample introduction via a Glass Expansion low-uptake lysed together with our samples by ALS and Genalysis. PFA nebulizer and Cetac Aridus desolvator. Major and minor elements (Si, Ti, Al, Cr, Fe, Mn, Mg, Instrumental mass bias for data collected in static mode Ca, Sr, Ba, Na, K, and P) were determined by X-ray was corrected by internal normalization to fluorescence spectrometry (ALS method ME-XRF26, 146Nd/145Nd ¼ 2 0719425 (equivalent to the more famil- Genalysis method FB1/XRF; BV method XRF202). For iar 146Nd/144Nd ¼ 0 7219; Vance & Thirlwall, 2002) and 152 147 this purpose, fused discs were prepared by fusing a Sm/ Sm ¼ 1 .78307, respectively, using the expo- Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021 1:10 sample-flux mix (LiBO2, LiB4O7 and LiNO3 flux) at nential law as part of an online iterative spike subtrac- 1025–1100 C (depending on laboratory). Loss on igni- tion/internal normalization procedure. 143Nd/144Nd in tion was determined by thermogravimetric analysis unknowns and quality controls was adjusted to a nom- (ALS method ME-GRA05, Genalysis method TGA, BV inal 143Nd/144Nd ¼ 0 511860 for the La Jolla Nd stand- method LOI-1000). ALS and Genalysis determined litho- ard, which was analysed every fourth run and yielded phile trace element concentrations by fusing the sample measured (mass bias-corrected) ratios in the ranges with a flux mix (LiBO2, LiB4O7) then dissolving in acid 0 511848–0 511871, 0 511862–0 511884 and 0 511919– and analysis by ICP-MS (for Cs, Rb, Ba, Sr, Th, U, Nb, 0 511969 in the three analytical sessions, respectively. Ta, Zr, Hf, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, After adjustment, the JNd-1 Nd standard averaged Tm, Yb and Lu at both laboratories, and Cr, V at ALS 0 512120 6 14 (2sd, n ¼ 6) while the USGS basalt BCR-2 only; ALS method ME-MS81, Genalysis method FB6/ yielded 147Sm/144Nd ¼ 0 1382 6 2 (2sd, n ¼ 4) and MS), or ICP-OES (Cr, V, Sc at Genalysis only, method 143Nd/144Nd ¼ 0 512625 6 17 (2sd, n ¼ 6); these results FB6/OE). ALS and Genalysis determined base metal are consistent with long-term averages and with TIMS/ concentrations by dissolving samples with a 4-acid mix- MC-ICP-MS reference numbers. External precisions for 147 144 143 144 ture (HClO4, HNO3, HF and HCl) followed by analysis via Sm/ Nd and Nd/ Nd are 60 2% and 60 004% ICP-AES (Co, Cu, Ni, Pb, Sc and Zn; ALS method (2sd), respectively. eNd values were calculated using 4ACD81), ICP-OES (Cu, Ni, and Zn; Genalysis method the CHUR parameters of Bouvier et al. (2008): 4 A/OE) or ICP-MS (Co and Pb; Genalysis method 4 A/ 147Sm/144Nd ¼ 0 1960, 143Nd/144Nd ¼ 0 512632* (*ad MS). BV determined lithophile element and base metal justed to the La Jolla value used here). 147Sm/144Nd and concentrations by laser ablation on the fused discs pre- 143Nd/144Nd in modern depleted mantle (DM) are 0 2136 pared for XRF (BV method LA101). and 0 513163, respectively, and are based on a linear Data reproducibility at the three laboratories is evolution from eNd ¼0at4 56 Ga to eNd¼þ10 at the broadly comparable. Total uncertainties for major ele- present (modified from Goldstein et al., 1984). The ments are 1 5%, those for minor elements are < 2 5% 147Sm decay constant is 6 54x10-12 yr1. Age corrections (at concentrations > 0 1 wt %) and those for trace ele- (eNdT) are based on U–Pb zircon ages where available ments are 10% (Lu 6 20%). Major elements are (see Table 2); otherwise, generic ages of 2820 Ma are re-calculated to anhydrous concentrations. Primitive used for Singleton Formation samples, 2815 Ma for mantle abundances are those of Sun & McDonough Yaloginda Formation samples and 2800 Ma for (1989). The elemental compositions of selected samples Meekatharra Formation samples. are presented in Table 1, while the complete set of Results are presented in Table 2 and are included in results, including sample locations, are included in digital format in Electronic Appendix 2 (together with Supplementary Data Electronic Appendix 1; supple- data published by the Geological Survey of Western mentary data are available for downloading at http:// Australia, 2019). Unpublished Nd isotopic data for 12 www.petrology.oxfordjournals.org. samples from similar aged geologic units in the south western Youanmi Terrane were obtained by identical methods and are compared to our data in the discus- Sm–Nd isotope analytical methodology sion section (‘Sm–Nd isotopic variation’). These will be Sm–Nd isotopic compositions for 16 samples were presented in a subsequent publication that presents acquired at the University of Melbourne, following them in their geological context. Maas et al. (2015) and Mole et al. (2018). Powders (c.0 1 g) were weighed into Krogh-type PTFE vessels and mixed with a 149Sm-150Nd tracer calibrated against RESULTS the Caltech Sm–Nd mixed normal solution (Wasserburg Petrography and mineral chemistry et al., 1981). Samples were dissolved at high pressure Petrographic descriptions are limited here to mafic vol- (2 5 ml 3:1 HF-HNO3, 48 h, 160 C; 2x dry-down with canic suites, which are the focus of the discussion sec- conc. HNO3;2 5 ml 6 M HCl, 24 h, 160 C); clear solutions tion below. Compositions for Meekatharra Formation were obtained in all cases. Sm and Nd were extracted pyroxenes and Cr-spinels are tabulated and discussed Table 1: Major, minor and selected trace-element data for representative samples of Norie and Polelle Group volcanic rocks 2138 Geological unit: Norie Group, lower Singleton Formation Norie Group, upper Norie Norie Norie Group, Singleton Formation Group, Group, Yaloginda Formation Quinns Yaloginda Basalt For-mation Lithology: Basalt picrite to Ol dolerite/gabbro basalt High HFSE tholeiitic basaltic andesite to andesite orthocumulate to Px cumulate (LOTI-boninite-like) basalt to rhyolite (high-Mg andesite)
Sample ID: 218818 221772 218820 221769 221770 221759 221754 221755 221758 221746 221752 217739 217748 227208 217765 217768 %(anhydrous) Al2O3 10 37 8 40 4 66 6 29 4 07 10 68 14 63 10 75 10 98 15 66 12 60 14 26 14 34 11 88 15 07 14 23 CaO 10 27 9 71 4 87 8 46 4 78 10 69 5 73 5 97 7 24 10 97 10 60 8 90 0 05 6 76 5 15 5 95 Fe2O3(Total Fe) 12 46 12 87 13 76 13 17 12 64 11 32 9 52 10 47 10 68 10 89 12 17 10 20 3 85 11 07 8 31 3 93 K2O0 29 0 04 0 03 0 04 0 02 0 54 1 50 0 31 0 07 0 31 0 27 0 25 0 68 0 62 2 01 0 12 MgO 10 32 16 00 28 78 23 49 31 62 14 01 13 85 19 06 17 87 7 54 10 51 6 40 4 14 11 73 6 72 5 40 MnO 0 20 0 19 0 15 0 16 0 20 0 18 0 18 0 18 0 19 0 16 0 21 0 14 0 01 0 14 0 12 0 07 Na2O2 21 1 62 0 21 0 77 0 16 0 92 1 86 0 87 0 87 2 03 1 55 2 36 0 51 1 78 3 72 7 34 P2O5 0 08 0 07 0 04 0 06 0 04 0 03 0 02 0 02 0 02 0 09 0 05 0 24 0 02 0 14 0 16 0 13 SiO2 52 68 50 24 46 92 46 83 45 95 51 32 52 63 52 28 51 91 51 63 51 48 56 02 76 10 55 09 58 02 62 17 TiO2 1 11 0 86 0 59 0 74 0 51 0 32 0 10 0 11 0 16 0 72 0 54 1 20 0 29 0 79 0 68 0 64 LOI 1 12 2 67 01 3 34 7 87 1 43 3 56 2 41 1 55 1 75 1 53 100 22 99 7 100 03 2 52 0 93 ppm Cs 0 14 0 20 10 20 20 20 68 0 48 0 06 0 10 20 10 15 0 10 57 0 18 Rb 9 40 51 80 81 16 637 65 91 77 6 85 518 411 446 12 9 Ba 70 893 7675 811 758 7 335 14 532 586 968 3 130 5 146 5 251 7 670 31 2 Th 0 75 0 30 21 0 20 10 4 bdl 0 07 0 39 1 0 81 99 8 12 23 23 5 43 U0 17 0 10 1 0 1 0 10 1 bdl 0 02 0 14 0 20 20 44 2 12 0 40 81 0 92 Nb 3 62 51 81 60 91 10 21 0 38 0 72 81 57 822 93 25 66 6 Sr 120 44 337 838 418 736 76836 855 9 128 163 6 115 25 9 293 7 212 31 1 Pb Bdl 0 93 0 50 8 bdl bdl bdl bdl 1 81 3 bdl 6 6 43 3 Hf 2 1 30 81 0 60 70 18 0 22 0 52 1 61 14 315 31 72 63 5 Zr 72 44 32 35 23 22 5 7 5 17 60 42 162 512 60 108 137 Y19 612 88 79 96 411 14 44 4 08 5 618 717 146 2 117 515 615 719 Ta 0 10 2 bdl 0 30 40 3 bdl 0 02 0 04 0 60 40 41 40 20 30 4 La 5 14 13 12 51 62 10 27 0 54 1 91 6 4 11237 910 316 517 Ce 12 89 56 5 33 14 10 46 1 22 4 68 12 27 626 59221 63033 8 Pr 1 91 1 30 97 0 90 60 70 07 0 19 0 62 1 51 3 92 11 72 93 43 4 02 Nd 9 47 34 64 83 13 60 33 0 86 2 52 7 45 817 652 412 212 615 Petrology of Journal Sm 2 85 1 91 37 1 81 0 80 09 0 24 0 51 81 44 85 14 95 2 92 64 3 35 Eu 1 01 0 60 46 0 60 40 30 07 0 10 21 0 60 51 56 4 16 0 60 81 0 9 Gd 3 28 2 61 53 2 1 31 40 24 0 34 0 72 42 16 75 16 75 3 2 74 3 06 Tb 0 56 0 40 20 30 20 20 06 0 07 0 10 40 41 18 2 86 0 50 38 0 41 Dy 3 41 2 31 48 2 21 11 90 50 59 0 82 92 88 01 18 25 2 62 48 2 63 Ho 0 66 0 50 29 0 40 30 40 16 0 16 0 19 0 60 71 74 4 10 60 49 0 57 Er 1 97 1 30 82 1 20 91 10 54 0 46 0 73 2 1 85 37 13 15 1 81 58 1 8
Tm 0 27 0 20 12 0 20 10 20 10 08 0 11 0 30 30 82 01 0 30 22 0 25 11 No. 60, Vol. 2019, , Yb 1 76 1 0 75 1 0 61 30 86 0 66 0 87 2 31 84 92 13 65 1 91 43 1 86 Lu 0 25 0 20 11 0 20 10 30 15 0 12 0 14 0 40 30 82 33 0 30 23 0 27 Ni 243 637 1680 1167 1652 675 366 684 802 145 313 87 2 268 120 154 Cr 810 2020 2710 2002 1945 2881 884 3170 2670 317 853 120 10 820 260 190 V 282 249 115 190 122 189 126 131 117 220 210 248 bdl 219 150 115 Co 61 74 161 74 108 69 61 80 76 44 57 34 bdl 48 31 13 Cu 14 101 10 20 8 9 bdl 4 bdl 148 10 55 3 78 1 6 Sc 40 35 24 23 15 31 35 31 30 32 34 32 3 24 19 15 Zn 70 96 94 57 93 63 35 50 45 64 84 74 53 80 58 18
(continued) Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021 September 27 on guest by https://academic.oup.com/petrology/article/60/11/2131/5700738 from Downloaded Table 1: Continued ora fPetrology of Journal Geological unit: Polelle Group, Meekatharra Polelle Group, Meekatharra Formation, Polelle Group, Meekatharra Formation, Lordy Basalt Member Bassetts Volcanic Member Formation, Stockyard Basalt Member
Lithology: basalt to basaltic andesite Ol basalt to basaltic andesite Ol-Px Opx Tholeiitic basalt Tholeiitic basalt to (siliceous high-Mg basalt) ortho-cumulate (siliceous high-Mg basalt) ortho-cumulate ortho-cumulate to basaltic andesite basaltic andesite (population 1) (population 2)
Sample ID 217712 217771 221627 217714 221693 209130 217798 209176 209198 217755 217757 217788 217791
% 11 No. 60, Vol. 2019, , (anhydrous) Al2O3 10 81 13 36 9 54 6 28 13 96 12 27 11 49 6 09 8 53 14 44 14 78 13 97 14 83 CaO 8 20 6 55 7 85 4 95 10 52 9 76 8 25 5 01 6 34 11 93 11 70 10 00 10 35 Fe2O3 (Total Fe) 12 73 10 94 12 39 12 88 9 56 10 19 10 28 10 91 9 93 10 11 10 71 14 34 11 25 K2O0 06 0 12 0 04 0 15 0 07 0 08 0 12 0 05 0 37 0 11 0 15 0 38 0 35 MgO 16 43 9 81 19 34 27 44 9 55 12 00 14 35 29 70 19 37 7 56 6 16 6 29 5 49 MnO 0 17 0 13 0 18 0 17 0 16 0 18 0 17 0 17 0 18 0 18 0 20 0 20 0 23 Na2O1 15 3 63 0 38 0 52 1 40 1 15 1 25 0 14 0 69 2 08 1 87 2 05 2 51 P2O5 0 06 0 07 0 05 0 03 0 06 0 05 0 04 0 02 0 04 0 06 0 07 0 13 0 14 SiO2 49 54 54 56 49 32 46 78 54 12 53 69 53 41 47 20 53 94 52 74 53 48 51 25 53 50 TiO2 0 63 0 76 0 58 0 35 0 55 0 46 0 46 0 23 0 35 0 75 0 85 1 39 1 34 LOI 4 42 2 79 4 95 6 97 1 98 3 13 2 63 6 01 3 37 0 93 0 899 93 99 06 ppm Cs 0 10 10 12 0 78 0 18 1 30 25 0 53 4 0 06 0 06 0 09 0 1 Rb 1 43 6251 72 53 63 724 31 42 21211 4 Ba 32 49 828 12930 622 3 194 522 427 749 697 179 977 2 Th 0 82 1 38 0 80 43 0 68 0 69 0 65 0 24 0 50 22 0 28 0 46 0 44 U0 22 0 36 0 28 0 08 0 22 0 19 0 17 0 05 0 1 bdl 0 07 0 12 0 09 Nb 1 82 21 60 91 1 10 60 30 51 71 93 3 2 Sr 57 146 79 61732 137 532 95 826 389 7 131 5 126 101 5 Pb bdl bdl bdl bdl 5 4 bdl 4 0 5 bdl bdl bdl bdl Hf 1 31 71 20 71 21 0 90 40 81 11 62 32 4 Zr 44 65 45 23 44 38 36 15 21 44 57 89 88 Y15 517 613 77 814 815 213 56 9 516 819 429 527 Ta bdl 0 10 1 bdl 0 1 bdl bdl bdl bdl bdl 0 10 10 1 La 3 94 93 21 92 72 72 41 11 42 32 84 34 3 Ce 8 511 27 84 15 65 54 92 13 36 27 912 111 8 Pr 1 09 1 48 1 01 0 58 0 73 0 70 61 0 30 41 01 1 31 91 1 94 Nd 5 36 64 82 53 53 32 91 31 85 16 49 810 1 Sm 1 48 2 03 1 42 0 74 1 19 1 11 0 97 0 38 0 71 56 2 14 3 29 3 24 Eu 0 55 0 57 0 54 0 27 0 47 0 42 0 46 0 16 0 30 68 0 82 1 15 1 37 Gd 1 99 2 59 1 86 1 2 17 1 89 1 65 0 75 1 42 54 2 99 4 43 4 35 Tb 0 39 0 47 0 35 0 18 0 40 36 0 36 0 14 0 20 41 0 51 0 80 75 Dy 2 56 3 27 2 51 1 28 2 57 2 52 35 0 95 1 42 86 3 38 5 55 03 Ho 0 54 0 67 0 50 26 0 55 0 58 0 55 0 21 0 30 63 0 76 1 13 1 05 Er 1 67 2 1 54 0 81 88 1 68 1 49 0 79 1 12 03 2 13 43 12 Tm 0 22 0 30 23 0 13 0 29 0 26 0 25 0 11 0 20 28 0 34 0 57 0 47 Yb 1 53 1 93 1 34 0 77 1 73 1 73 1 50 71 1 31 86 2 01 3 36 3 09 Lu 0 23 0 30 23 0 13 0 25 0 26 0 24 0 13 0 20 26 0 34 0 50 45 Ni 521 106 761 1200 175 280 360 1010 357 106 118 120 102 Cr 1310 420 2450 2640 420 1150 1340 3200 1798 250 210 110 110 V 217 263 217 86 303 235 230 120 181 285 306 368 355 Co 72 42 78 119 44 48 53 87 55 35 41 54 42 Cu 98 89 21 43 53 47 43 23 29 21 9 191 193 2139 Sc 31 40 29 20 36 33 33 19 33 38 38 39 37 Zn 79 78 94 79 65 61 68 63 58 58 67 106 109
(continued) Downloaded from https://academic.oup.com/petrology/article/60/11/2131/5700738 by guest on 27 September 2021 September 27 on guest by https://academic.oup.com/petrology/article/60/11/2131/5700738 from Downloaded Table 1: Continued 2140
Geological unit: Polelle Group, Meekatharra Formation, Polelle Group, Meekatharra Polelle Group, Bundle Volcanic Member Formation, Cue basalt (informal) Greensleeves Formation
Lithology: basalt to basaltic andesite Ol–Px ortho-cumulate Depleted tholeiitic basalt basaltic andesite to rhyolite (siliceous high-Mg basalt)
Sample ID 209114 209118 209123 217800 218803 221739 217722 227211 % (anhydrous) Al2O3 10 57 9 03 5 04 14 18 14 12 13 24 12 48 12 94 CaO 6 71 10 16 4 73 11 87 11 96 11 91 5 68 4 29 Fe2O3 (Total Fe) 10 53 11 40 11 14 12 70 13 82 9 16 6 45 3 29 K2O0 20 0 21 0 09 0 12 0 14 1 14 2 84 2 16 MgO 11 31 15 85 31 04 6 51 5 81 5 19 4 40 1 29 MnO 0 15 0 20 0 16 0 24 0 24 0 29 0 07 0 08 Na2O2 42 1 38 0 16 2 48 2 48 3 05 3 63 3 38 P2O5 0 06 0 06 0 04 0 06 0 06 0 19 0 15 0 15 SiO2 57 19 50 89 46 76 51 00 50 55 55 24 63 34 71 94 TiO2 0 66 0 62 0 34 0 80 0 80 0 55 0 93 0 45 LOI 2 56 3 26 80 55 0 44 8 11 2 11 71 ppm Cs 0 55 0 41 89 0 01 0 03 0 40 41 0 6 Rb 5 15 7 21 71 125 765 339 3 Ba 75 897 234 5 187 39 7 244 4 489 929 3 Th 1 44 1 40 80 33 0 34 42 97 10 4 U0 43 0 40 23 0 06 0 08 1 0 67 2 5 Nb 2 72 51 50 80 73 65 75 2 Sr 106 50 217 270 771 7 354 169 1 378 6 Pb 4 1 1 5 bdl bdl 5 83 10 8 Hf 1 41 30 71 41 32 72 23 1 Zr 54 50 29 47 45 101 82 115 Y14 813 77 726 826 412 213 111 3 Ta bdl 0 2 bdl bdl bdl 0 40 20 3 La673 32 51 819 11123 7 Ce 12 714 66 85 84 937 52142 2 Pr 1 62 1 80 85 0 91 0 81 4 22 65 4 3
Nd 7 57 73 94 84 315 810 216 1 Petrology of Journal Sm 2 02 1 21 1 76 1 63 2 92 68 2 8 Eu 0 64 0 60 34 0 70 55 0 80 78 0 8 Gd 2 41 2 31 19 3 03 2 84 2 32 61 2 3 Tb 0 41 0 40 21 0 61 0 55 0 40 35 0 3 Dy 2 64 2 61 34 36 4 21 2 12 18 1 6 Ho 0 55 0 50 28 0 93 0 98 0 50 45 0 4 Er 1 56 1 40 79 2 97 2 98 1 31 29 1 2 Tm 0 23 0 2012 0 5048 0 2018 0 2