2018 Annual Report Cloyne Waste Disposal Site
Environmental Compliance Approval No. A371108
Cambium Reference No.: 7215-007
March 20, 2019
Prepared for: The Corporation of the Township of North Frontenac
Cambium Inc. P.O. Box 325 52 Hunter Street East, Peterborough Ontario, K9H 1G5 Telephone: (866) 217.7900 Facsimile: (705) 742.7907 cambium-inc.com
2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Executive Summary The Cloyne waste disposal site operates under Ministry of the Environment, Conservation and Parks Environmental Compliance Approval No. A371108. The site is on Lot 20, Range A, in the geographic Township of Anglesea, in the Township of Addington Highlands. The site is at 202 Skootamatta Lake Road just north of the Village of Cloyne and is jointly owned by the Township of North Frontenac and the Township of Addington Highlands and is operated by the Township of North Frontenac. The site consists of an approved fill area of 4.0 ha within a total site area of 8.09 ha and ceased landfilling operations in 2008 with a total of 10,100 m³ of waste in place. The site now operates as a transfer station for solid, non-hazardous domestic and commercial waste.
Consistent with previous years, the water level measurements from 2018 indicated that groundwater flows in May and November were to the west-northwest and north, respectively.
The groundwater quality down-gradient of the waste disposal area at drive-point DP4 was observed to have a number of parameter concentrations elevated greater than background water quality at the Site. The parameter concentrations were observed to meet the Reasonable Use Concept criteria and Provincial Water Quality Objectives in most cases; therefore, adverse impacts to groundwater and receiving surface waters were not expected.
Marginal impacts were evident at downstream surface water stations SW2 and SW4 from site operations, and at station SW3 from de-icing activities on adjacent Skootamatta Lake Road. Where elevated concentrations were observed, regardless of the source, parameter concentrations observed were within the range characteristic of natural surface waters and were not interpreted to be causing any adverse biological impacts to the receiving stream.
Several parameters were observed to exceed the surface water trigger values on two or more consecutive occasions in 2018 at the downstream trigger location surface water station SW3. Elevated concentrations were attributed at least in part to road de-icing activities on Skootamata Lake Road, and natural sources. Parameter concentrations observed were within the range characteristic of natural surface waters and were not interpreted to be causing adverse biological impacts to the receiving stream; therefore, a detailed surface
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2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Table of Contents 1.0 Introduction ...... 1 1.1 Scope of Work ...... 1 1.2 Site Location ...... 1 1.3 Site Description ...... 2
2.0 Methodology ...... 3 2.1 Groundwater Monitoring Program ...... 4 2.2 Surface Water Monitoring Program ...... 5 2.4 Site Inspection and Operations Overview ...... 7
3.0 Geological and Hydrogeological Context ...... 8 3.1 Topography and Drainage ...... 8 3.2 Hydrogeological Setting ...... 10 3.2.1 Groundwater Flow Direction ...... 11
4.0 Results and Discussion ...... 13 4.1 Groundwater Quality ...... 13 4.1.1 Background Groundwater Quality ...... 14 4.1.2 Leachate Characteristics ...... 15 4.1.3 Down-gradient Groundwater Quality ...... 15 4.1.4 Groundwater Trigger Mechanism ...... 17 4.1.4.1 Compliance Assessment ...... 21 4.2 Surface Water Quality ...... 22 4.2.1 Background Surface Water Quality ...... 23 4.2.2 Downstream Surface Water Quality ...... 24 4.2.3 Surface Water Trigger Mechanism ...... 26 4.2.3.1 Contingency Plan ...... 27 4.2.3.2 Compliance Assessment ...... 28 4.3 Landfill Gas ...... 29 4.4 Adequacy of Monitoring Program ...... 29
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5.0 Site Operations ...... 32 5.1 Site Access and Security ...... 32 5.2 Training ...... 33 5.3 Drainage ...... 34 5.4 Roads ...... 34 5.5 Aesthetics ...... 34 5.6 Complaints and Incidents ...... 35 5.7 Monitoring Well Security ...... 35 5.8 Materials Summary ...... 36 5.8.1 Site Usage ...... 36 5.8.2 Material Diversion ...... 36 5.9 Compliance with Environmental Compliance Approval ...... 37
6.0 Conclusions and Recommendations ...... 38
References
Glossary of Terms
List of Embedded Tables Embedded Table 1 Site Details ...... 2 Embedded Table 2 Surface Water Sampling Observations and Locations ...... 9 Embedded Table 3 Historical and 2018 Precipitation Data ...... 10 Embedded Table 4 Groundwater QA/QC Evaluation ...... 14 Embedded Table 5 Leachate Indicator Parameters ...... 15 Embedded Table 6 Surface Water QA/QC Evaluation ...... 22 Embedded Table 7 Summary of PWQO Criteria Exceedances in Surface Waters ...... 25 Embedded Table 8 Summary of Site Usage ...... 36 Embedded Table 9 Summary of Diverted Materials ...... 37
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List of Appended Figures Figure 1 Regional Location Plan Figure 2 Local Topography Plan Figure 3 Existing Conditions Figure 4 Groundwater Elevations Figure 5 Groundwater Configuration
List of Appended Tables Table 1 Environmental Monitoring Programs Table 2 Groundwater Elevation Data Table 3 Summary of Groundwater Quality Table 4 Summary of Groundwater Quality - PWQO Table 5 Summary of Surface Water Quality
List of Appendices Appendix A Environmental Compliance Approval A371108 Appendix B Field Data Sheets Appendix C Laboratory Certificates of Analysis Appendix D Site Photographs Appendix E Borehole Log
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1.0 Introduction
Cambium Inc. (Cambium) was retained by The Corporation of the Township of North Frontenac (Township) to complete the 2018 monitoring program at the Cloyne waste disposal site (Site).
This report summarizes the results of the 2018 monitoring program and provides recommendations to the Township regarding environmental compliance and operation of the Site. The Site is governed under Ministry of the Environment, Conservation and Parks (Ministry) Environmental Compliance Approval (ECA) No. A371108 (Appendix A), most recently amended on September 10, 2013.
1.1 Scope of Work
The scope of the 2018 work program was based on the results of the 2017 monitoring program (Cambium, 2018), the requirements of the Site ECA, and included the following:
Groundwater monitoring in the spring and autumn
Surface water monitoring in the spring and autumn
Landfill gas monitoring in the spring and autumn
Preparation of the annual report
This report presents the results of the 2018 work program and includes a summary of the operational activities at the Site.
1.2 Site Location
The Cloyne Waste Disposal Site is located on Lot 20, Range A, in the geographic Township of Anglesea, in the Township of Addington Highlands. The Site is accessed from 202 Skootamatta Lake Road, approximately 1.0 km north of the Village of Cloyne (Figure 1). The Universal Transverse Mercator (UTM) coordinates for the Site entrance are Zone 18T, 326826m east, 4966821m north.
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1.3 Site Description
The Site is a natural attenuation landfill and is owned jointly by the Township of Addington Highlands and the Township of North Frontenac. The Site is closed to landfilling and currently operates as a transfer station for solid, non-hazardous domestic and commercial waste, in accordance with ECA No. A371108. The service area for the Site is the Township of North Frontenac and the Township of Addington Highlands. There was reportedly 10,100 m³ of waste in place when landfilling ceased at the Site in 2008.
Site details are provided in Embedded Table 1, a Local Topography Plan is attached as Figure 2, and an Existing Conditions plan is attached as Figure 3.
Embedded Table 1 Site Details Total Site Area 8.09 ha Approved Area of Refuse Placement 4.0 ha Total Site Capacity, not including Final Cover 10,100 m³ Existing Refuse 10,100 m³
To aid in the understanding of the Site history and development, the following report is included digitally in the report package:
Cloyne Waste Disposal Site, Site Closure Plan (TSH, 2008).
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2.0 Methodology
This section provides a brief description of the methodology followed to complete the 2018 monitoring program.
The work program was completed in 2018 to maintain compliance with the Site ECA and Ministry guidelines and regulations. As such, the environmental monitoring work program was completed in accordance with the reports entitled Guidance Manual for Landfill Sites Receiving Municipal Waste (MOEE, 1993) and Monitoring and Reporting for Waste Disposal Sites, Groundwater and Surface Water, Technical Guidance Document (MOE, 2010).
Field tasks were completed following Cambium’s Standard Operating Procedures developed from recognized standard procedures such as those listed above and the Ministry document Guidance on Sampling and Analytical Methods for use at Contaminated Sites in Ontario (MOEE, 1996). A health and safety program was developed for Site specific conditions and all Cambium personnel working on the project were familiarized and required to follow the identified protocol.
Groundwater and surface water samples were collected at the locations and frequencies shown in Table 1. All collected surface water and groundwater samples were stored in coolers with freezer packs and maintained at less than 10°C after collection and during transport to Caduceon Environmental Laboratories in Kingston, Ontario (Caduceon). Caduceon is accredited by the Canadian Associations for Laboratory Accreditation Inc. (CALA) for specific environmental tests listed in the scope of accreditation approved by the CALA.
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2.1 Groundwater Monitoring Program
The 2018 groundwater monitoring program included sample collection on May 22 and November 1, 2018 at five (5) groundwater monitoring wells in the established groundwater monitoring network (Figure 3). The groundwater wells included in the monitoring program are as follows:
MW1 DP2 DP3 DP4 MW5 The following exceptions to sampling were noted:
Drive-point piezometers DP2 and DP3 were inaccessible in May due to flooding from an adjacent beaver dam and could not be sampled.
Drive-point piezometers DP2 and DP3 were accessible during the November sampling event; however, were observed to be damaged and could not be sampled.
There were no other deviations from the approved groundwater monitoring program outlined in Table 1.
The following tasks were completed as part of the monitoring program:
Prior to sampling, water levels were measured at each monitoring well using an electronic water level tape.
Each groundwater monitoring well to be sampled was purged of approximately three well bore volumes. Where wells were observed to go dry, only one well volume was purged. The volume of groundwater to be purged was calculated on-site during each monitoring event using the measured water level and the well diameter. Purged water was disposed of on-site, down-gradient of each respective monitor. Samples were collected using dedicated polyethylene tubing equipped with inertial-lift footvalves, with the exception of monitor DP4 where a low flow sampling technique was executed due to its historic low volumes of water.
Where required (i.e., groundwater for metals analysis), samples were field filtered.
Field measurements were collected including: pH, conductivity, temperature, dissolved oxygen (DO), and oxygen reduction potential (ORP).
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Groundwater elevations are summarized on Table 2. The results of the groundwater monitoring program are presented in Sections 3.2.1 and 4.1 and analytical results are included in Table 3 and Table 4.
Locations of all groundwater monitoring locations are included on Figure 3. The groundwater field data sheets completed during the 2018 monitoring program are included as Appendix B, laboratory Certificates of Analysis provided by Caduceon have been attached as Appendix C, and photographs of each location are included in Appendix D.
Blind duplicate groundwater samples were collected from drive-point piezometer DP4 in May and monitoring well MW1 in November as part of the Quality Assurance/Quality Control (QA/QC) program. In addition to these samples, the laboratory completes internal QA/QC. As this represents 10 percent of the samples taken, this program is considered sufficient. The results of the QA/QC program are presented in Section 4.1.
2.2 Surface Water Monitoring Program
Cambium staff were on-site May 22 and November 1, 2018 to collect samples from the following surface water sampling stations:
SW1 SW2 SW3 SW4
There were no deviations from the approved surface water monitoring program, outlined in Table 1.
The following tasks were completed as part of the monitoring program:
Surface water samples were collected by immersing the sample container into the water body.
Where sample bottles were prefilled with preservatives, a clean bottle was used to collect and decant the water directly into the sample bottle.
Field measurements including pH, conductivity, temperature, DO, and ORP were collected.
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Where possible, the following measurements were collected at each surface water location: depth, width, and flow velocity.
Weather conditions prior to and during the field events were recorded at the time of sampling.
The results of the surface water sampling program are presented in Section 4.2 and summarized on Table 5.
Surface water locations are shown on Figure 3. Surface water field data sheets summarizing field observations and measurements are provided in Appendix B, the laboratory Certificates of Analysis provided by Caduceon are included as Appendix C, and photographs of the surface water sampling stations are included in Appendix D.
Blind duplicate surface water samples were collected from station SW3 during the May and November sampling events as part of the QA/QC program. In addition to these samples, the laboratory completes internal QA/QC. As this represents 10 percent of the samples taken, this program is considered sufficient. The results of the QA/QC program are presented in Section 4.2.
2.3 LANDFILL GAS MONITORING PROGRAM
Landfill gas (LFG) is not currently actively managed at the Site. The large, open site area and isolated location from the public supports passive landfill gas management, which allows generated landfill gas to naturally disperse through the waste and naturally-permeable cover to the atmosphere.
At the request of the Ministry, a dedicated gas probe (GP1) was installed at the Site in 2014 (AECOM, 2015). Landfill gas monitoring was conducted at gas probe GP1 in 2018 in conjunction with the spring and autumn monitoring events. Total combustible gas concentrations were measured at the gas probe, prior to collecting groundwater levels, using a portable gas meter calibrated to methane. The landfill gas monitoring results for the 2018 monitoring program are discussed in Section 4.3.
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2.4 Site Inspection and Operations Overview
Site operations were observed during the visits conducted by Cambium staff in May and November 2018. During these visits the following items were inspected on accessed areas of the Site and observations noted in the field file:
litter control cover material condition
condition and layout of status of monitoring well condition and layout of access roads, access gates security recycling bins
In February 2019, the Township provided additional 2018 Site maintenance information. The results of the Site inspections conducted are presented in Section 5.0.
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3.0 Geological and Hydrogeological Context
3.1 Topography and Drainage
The Site is in the Salmon River watershed. The Salmon River watershed is in southeastern Ontario and is composed of a complex network of rivers, streams, and lakes. The Salmon River has a drainage area of 921 km² from Mazinaw Lake near the Village of Cloyne to the Bay of Quinte in Lake Ontario near the community of Shannonville.
The Site is situated roughly 1.0 km north of the Village of Cloyne. The surrounding landscape is a mixture of bush, wetland, and marshes. Surface drainage on the property is mainly to the southwest from the landfill into a wetland; however, it is ultimately directed to the northeast via a shallow intermittent watercourse located on-site that runs north of the waste footprint (AECOM, 2015). This watercourse flows south after leaving the Site and discharges to a series of lakes and ultimately into Beaver Creek. Beaver Creek flows through Kennebec Lake and into the Salmon River. There are no provincially significant wetlands within 500 m of the Site.
There are currently four (4) surface water locations, as follows (Figure 3):
Surface water monitoring station SW1 is 55 m northwest of the waste mound, upstream of the Site and represents background water quality at the Site.
Surface water station SW2 is immediately adjacent the northwest extent of the waste pile.
Surface water station SW3 is 175 m northeast, down-gradient, and downstream of the waste mound. This location represents water quality that is leaving the Site.
Surface water station SW4 was established in October 2016 to monitor the quality of the ponded water resulting from the beaver dam. This location was established at the request of the Ministry in comments dated May 6, 2016 and is a temporary location (Cambium, 2017). This station was established to determine if any impacts were occurring in the ponded water to aid in developing an appropriate water management strategy for the beaver dam and ponded area.
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A beaver dam was constructed near surface water station SW2, which has caused extensive flooding west of the waste disposal area. This flooding has caused monitors DP2 and DP3 to be underwater semi-regularly and inaccessible for sampling or repairs. As discussed in Ministry comments and the 2016 Annual Report (Cambium, 2017), the Township should consider implementing a water management strategy which may include 1) installation of engineered drainage and stormwater management system; 2) construction of a berm to exclude water from the waste pile area and transfer station; and/or, 3) management of water levels behind the beaver dam.
The Township completed efforts in 2018 to lower the flooded area. Although there was still flooding observed during the November sampling event, there was significantly less water than had been observed in recent years. It is understood that efforts will continue into 2019 to lower the water and complete a clean-up of this area.
Water at the surface water locations is described as ponded with limited or no observable flows. Embedded Table 2 summarizes surface water flow measurements and sampling conditions observed during the 2018 sampling events; additional information is included in the field sheets in Appendix B.
Embedded Table 2 Surface Water Sampling Observations and Locations Station Station UTM 1 May November SW1 326562 4966873 Area flooded Ponded – no observable flow SW2 326682 4966775 Ponded – no observable flow Ponded – no observable flow SW3 326819 4966906 Observable, non-measurable flow Ponded – no observable flow SW4 326713 4966805 Ponded – no observable flow Ponded – no observable flow Notes: 1. Zone 18.
A review of the 2018 precipitation data, as obtained from Environment Canada (Government of Canada, 2018) in comparison to the average precipitation (Government of Canada, 2015) for the Drummond Centre station (1981 to 2010 climate normals) indicated that precipitation was generally consistent with the climate normals (1981-2010); precipitation depths in 2018 were only 12% greater than normal. That being said, it was noted that April received significantly more precipitation than normal (110% more) and May received significantly less (57% less).
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Embedded Table 3 includes the amount of precipitation during and in the three days prior to the sampling events. Refer to Appendix B for field sheets and climate data.
Embedded Table 3 Historical and 2018 Precipitation Data Average Monthly Precipitation During and Sampling Date Precipitation (mm) 2018 Precipitation (mm) Prior to Sampling (mm) (1981 – 2010) May 24, 2018 77 33 15.8 78.5 (October) 86.6 (October) November 1, 2018 34.4 83.6 (November) 108.2 (November)
3.2 Hydrogeological Setting
The bedrock is mainly comprised of metamorphic clastic and carbonate sediments of the Grenville Province. These units generally have little weathering and low porosity. The Precambrian bedrock is thinly veneered with glacial sediments in the region. Thick organic deposits are common in valleys and swamps. Coarse-textured deltaic deposits and ice-contact stratified deposits are also common. (AECOM, 2015)
The local topography and geology have a strong influence on the groundwater system. The bedrock is poorly fractured and provides few opportunities for groundwater flow. As such, the vast majority of groundwater is assumed to travel through the shallow and relatively coarse overburden (AECOM, 2015). It has been reported that leachate impacted groundwater will flow from the waste mound to the northwest and will discharge to the watercourse along the northern edge of the wetland and ultimately to the wetland east of the Site and Skootamatta Lake Road, towards Highway 41.
There is one domestic supply well located approximately 350 m down-gradient from the waste mound. The well was initially installed to 60 m below ground surface (bgs) and was subsequently deepened to 90.0 mbgs; this suggests that the water bearing unit at 60 mbgs was not sufficient for a supply well. Refer to Appendix E for the water well records for this well.
Leachate generated from the Site is inferred to discharge to surface and is not expected to infiltrate the bedrock aquifer; therefore, the down-gradient well is not considered to be at risk of contamination derived from landfill leachate.
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There are two monitoring wells and three drive-point piezometers installed at the Site. Monitoring well MW1 was installed in the waste mound in 2009; monitoring well MW5 was installed in the autumn of 2013 to monitor the background water quality at the Site and is reportedly installed in the bedrock to a similar depth of the leachate monitor (MW1). The three drive-point piezometers were installed in the shallow overburden along the west (DP2), northwest (DP3), and north (DP4) perimeter of the waste mound in 2009. The piezometers DP2, DP3, and DP4 were installed to the inferred bedrock contact (auger refusal) and were constructed of galvanized steel pipe. Refer to Appendix E for the available borehole log for monitor MW1 and to Table 2 for UTM coordinates for each monitor. Access to drive-point piezometers DP2 and DP3 has been intermittent related to the construction of a beaver dam causing flooding in this area.
3.2.1 Groundwater Flow Direction
Historically, the general direction of groundwater flow was to the north and northwest from the waste disposal area. This suggested that some component of flow was directed to the watercourse along the northern area of the waste disposal site, as well as into the low-lying area to the west, immediately adjacent to the waste disposal footprint. As drive-point piezometers DP2, DP3, and DP4 were reportedly installed at the bedrock contact and the shallow groundwater is expected to follow the bedrock contact, elevations observed at these drive-points confirm the observed flow path (i.e., assumed bedrock elevations at DP2 (west) and DP4 (northeast) were observed to be 90.5 and 91.8 m above sea level (asl), respectively).
In recent years as flooding has been present west of the waste mound, groundwater flow has been observed to have a more predominant west-northwest flow towards the flooded area.
The water level data collected in 2018 are presented in Table 2 and Figure 4. Groundwater elevations in 2018 were observed to be relatively consistent with their historical trends, including significant fluctuation observed at well MW5.
The groundwater elevation contours and groundwater flow directions are depicted on Figure 5. Although using bedrock well MW5 in combination with the overburden elevations to define the
Cambium Inc. Page 11 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019 overburden flow directions is not appropriate, groundwater flow directions across the Site can still be generalized.
The water level measurements from 2018 in the overburden wells on-site indicated that groundwater flows in May were to the west-northwest (consistent with recent years); however, as the water levels were observed to recede in the flooded area west of the waste mound, groundwater flows were observed to be to the north. Due to the limited water elevations available, hydraulic gradients could not be estimated.
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4.0 Results and Discussion
Water quality analytical results from the monitoring program are used to assess the existence, extent, and level of impacts to the groundwater environment related to waste disposal site activities. To ensure appropriate actions are in place to respond to any potential degradation in groundwater quality beyond an acceptable level, Site specific trigger levels and contingency plans need to be adhered to for the Site. This aids in the assessment of impacts from leachate contamination and helps to prevent adverse impacts to the environments surrounding the waste disposal site.
This section presents the results of the 2018 monitoring program completed at the Site as compared to available historical data and discusses observed trends in the groundwater quality.
4.1 Groundwater Quality
The groundwater chemistry data obtained from the analysis of groundwater samples collected from the monitoring wells at the Site from 2009 to 2018 are presented in Table 3. The groundwater quality data for samples collected in 2018 have been compared with historic results, background water quality data, and the Ministry Guideline B-7 Reasonable Use Concept (MOEE, 1994). Given that groundwater is interpreted to discharge to surface, the groundwater quality data have been compared with to the Provincial Water Quality Objective (PWQO) (MOEE, 1994) and where appropriate and required by the ECA, the Canadian Water Quality Guidelines (CWQG) for the Protection of Aquatic Life (CCME, 2007).
In 2018, duplicate groundwater samples were collected from piezometer DP4 in May and monitoring well MW1 in November. Results from the analyses completed on the blind duplicate samples as part of the QA/QC program were evaluated. The duplicate analysis indicated that, while in general, the data between duplicate samples showed good correlation, the parameters in Embedded Table 4 reported notable differences. Parameter concentrations were considered to be significantly different if the relative percent difference (RPD) between the duplicate and
Cambium Inc. Page 13 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019 the original samples was greater than 30RPD when both analytical results were greater than five times the reportable detection limit (RDL).
Embedded Table 4 Groundwater QA/QC Evaluation May – DP4 November - MW1 Colour – 44% Total Phosphorus – 35% Total phenolics – 36%
It is noted, the RPD is calculated only when both the parent and duplicate samples concentrations are greater than five times the RDL. Parent/duplicate samples with only one measurable concentration were assessed qualitatively. If the measurable concentration was close to the detection limit, the sample results were considered valid and the measurable concentration was accepted. Evaluation of these parent/duplicate samples did not identify significant data quality issues.
Based on the above, the groundwater data was considered suitable for its intended use, which was to identify changes in water quality and analyzed parameters present at concentrations greater than the applicable standards. The groundwater analytical results were interpreted with confidence while caution was used in interpreting the results of the above listed parameters.
4.1.1 Background Groundwater Quality
When evaluating the impact of any waste disposal site on a groundwater resource, a reference point or value must be established to assist in determining the magnitude of the impact. In this respect, the quality of the groundwater that is not-impacted by the waste disposal site operation (background water quality) should be used for comparison purposes. Given the location of monitoring well MW5 (Figure 3), this well represents background water quality at the Site. It is however noted, this well is installed in the bedrock inferred to be competent with limited flow, whereas the down-gradient wells/piezometers are installed in the overburden; therefore, some water quality variations are expected related to bedrock versus overburden water quality.
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To date, the background monitor MW5 has been reported to have low concentrations of most parameter concentrations with the exception of manganese and total suspended solids. In 2018, parameter concentrations were generally similar to historical results.
4.1.2 Leachate Characteristics
Monitoring well MW1 is completed within the waste mound and is used to determine the leachate characteristics of the Site. Although the water quality at monitoring well MW1 has been observed to exceed background water quality concentrations for most parameters, key leachate indicator parameters (LIPs) have been determined which best assess the Site-related impacts (AECOM, 2015); refer to Embedded Table 5. Following comments received from the Ministry groundwater reviewer dated August 3, 2017 (Cambium, 2018), ammonia, total dissolved solids (TDS), and boron were added.
Embedded Table 5 Leachate Indicator Parameters alkalinity chloride sodium potassium magnesium chemical oxygen demand (COD) conductivity total Kjeldahl nitrogen (TKN) ammonia TDS boron
The above listed parameters are considered to be characteristic of leachate at the Site; therefore, will be examined closely when assessing waste related impacts at the down- gradient monitoring wells.
The 2018 water quality results indicated that the majority of parameter concentrations at monitor MW1 were generally within historical ranges, with the exception of a few slightly elevated metals in May (e.g., tungsten, vanadium, etc.).
Decreasing trends were evident for all LIPs, in some cases significant trends. This is attributed to time since closure in 2008 and covering of the Site in 2013.
4.1.3 Down-gradient Groundwater Quality
Samples could not be collected from drive-point piezometers DP2 and DP3 in May due to flooding in the area. Although the water had receded and the wells could be accessed, they
Cambium Inc. Page 15 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019 were observed to be damaged and could not be sampled, consistent with observations in October 2016.
Given that significant improvement of water quality has been observed at the Site since closure (MW1) and the conceptual Site model indicates shallow groundwater discharges to surface northwest and north of the waste mound, it was recommended that these piezometers be decommissioned and removed from the monitoring program (Cambium, 2017).
In comments dated August 3, 2017 (Cambium, 2018), the Ministry groundwater reviewer noted that the most significant leachate impacts were historically detected at drive-point piezometer DP3 and indicated that drive-point piezometer DP4 does not adequately assess groundwater quality at the toe of the waste mound. Given the issues of flooding and damage at the current locations, the reviewer suggested decommissioning the existing piezometer and establishing new piezometers in more appropriate locations. The reviewer further noted that the primary purpose of the down-gradient monitors is to provide an assessment of groundwater quality at the toe of the waste mound prior to discharging to surface water; therefore, the need for and location of monitors should ultimately be determined by the Ministry Surface Water Scientist. As of the date of this report, no comments have been received from the Surface Water Unit.
Drive-point piezometer DP4 is approximately 10 m north of the waste disposal area. To date, water quality from piezometer DP4 has exhibited elevated concentrations of the following LIP concentrations compared to background water quality at the Site: TDS, conductivity, chloride, ammonia, boron, and sodium. Leachate impacts at this monitor are not unexpected given the location adjacent the toe of the waste mound. In addition to the identified LIPs, the following parameter concentrations have also been observed to be elevated at down-gradient drive- point DP4: DOC, iron, and manganese. It is understood that these parameters are elevated in the leachate at the Site; however, are also naturally elevated in the area. As such, elevated concentrations of these parameters have at least been partially attributed to natural conditions.
Parameter concentrations at this location were observed to decrease significantly in 2013 following Site closure activities, consistent with the leachate concentrations at well MW1. Since that time concentrations have been observed to be stable with the exception of aluminum
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(slight), calcium, sulphate, and magnesium which have been observed to increase. It is noted, of these parameters, only magnesium is a key LIP for the Site. Regardless, the degree of leachate impacts at drive-point piezometer DP4 have decreased significantly since the Site closure and capping; this is expected to continue.
The 2018 water quality results indicated that the parameter concentrations at piezometer DP4 were generally within historical ranges with most LIPs continuing to decrease or stabilize (with the exception of magnesium as noted).
4.1.4 Groundwater Trigger Mechanism
To ensure appropriate recognition and response to potential degradation in groundwater quality beyond an acceptable concentration, Site specific triggers and contingency plans have been developed for the Site. These are based on the Ministry Reasonable Use Concept (RUC) values for groundwater (MOEE, 1994). The Ministry Reasonable Use Policy states that, in accordance with the appropriate criteria for particular uses, a change in quality of the groundwater on an adjacent property will be accepted only as follows:
The quality cannot be degraded by an amount in excess of 50% of the difference between background and the Ontario Drinking Water Standards (ODWQS) for non-health related parameters and in excess of 25% of the difference between background and the ODWQS for health related parameters. Background is considered to be the quality of the groundwater prior to any man made contamination.
Ministry Procedure B-7-1.
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As discussed in Section 3.0, any leachate generated at the Site will migrate laterally into the adjacent wetland and not into deeper aquifer systems. As dictated by the Ministry Reasonable Use Policy (MOEE, 1994), where groundwater provides baseflow to a surface water feature, this is the recognized reasonable use of the groundwater; therefore, the intent of Ministry Guideline B-7 is met. It is noted that the Ministry groundwater reviewer concurred with this conclusion in a memo dated August 3, 2017 (Cambium, 2018). It is recommended that management approaches should be focused on the receiving surface water feature.
Despite this, as prescribed in correspondence dated February 11, 2013 (AECOM, 2014), the groundwater trigger mechanism for the Site is based on the RUC. The trigger mechanism is as follows:
Groundwater trigger parameters should include all of the chemical constituents listed on Table 1 for which there is an ODWQS. An exceedance for any listed chemical parameter would be defined as a numerical elevation of any analytical value above the Reasonable Use Guideline (RUG) values at the down-gradient on-site monitors DP2, DP3, and DP4 related to the landfill.
Certain metals (iron and manganese) and organics (DOC and organic nitrogen) are ubiquitous constituents within a wetland setting and have naturally occurring wide ranges in concentrations. The examination of these parameters as impact indicators should be based on established trends and gradients.
If three consecutive RUG exceedances for any trigger parameter are deemed to be caused by the landfill then further investigations should be initiated to determine the significance of the exceedance. This investigation may consist of completing additional monitoring locations further downgradient and closer to the property boundary. If further exceedances are confirmed based on the additional investigations with respect to the trigger above a contingency plan should be prepared and submitted after the third exceedance to the Ministry Regional Director for approval.
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Such a contingency plan should provide recommendations for i) the acquisition of additional bufferlands; ii) the timing for the acquisition of bufferlands (if acceptable to the Ministry); and iii) the subsequent water quality monitoring program needed to confirm acceptable off-site groundwater impact.
Regardless of the RUG conformance, should any landfill perimeter monitor contain any constituent (excepting DOC, iron, manganese and zinc) having a concentration exceeding the PWQO on two consecutive occasions and is deemed to be caused by the landfill, an environmental study should be undertaken to establish that the bordering vegetation/bordering functions are not significantly affected by the leachate discharge.
In summary, the RUC values should be calculated for all parameters in the established annual monitoring program, as designated by the trigger mechanism. The trigger locations are defined as drive-points DP2, DP3, and DP4.
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The groundwater trigger mechanism is to be activated if: i) the exceedance of the RUC concentration for one or more parameters at three consecutive sampling events, at any of the trigger locations, deemed to be caused by the landfill; and/or, ii) the exceedance of the PWQO criteria for two or more consecutive sampling events for any parameter except DOC, iron, manganese, and zinc, at any of the trigger locations, deemed to be caused by the landfill.
The RUC criteria, which is the maximum concentration of a particular contaminant that is considered acceptable in the groundwater beneath an adjacent property, is calculated in accordance with the following relationship:
퐶푚 = 퐶푏 + 푥 ∙ (퐶푟 − 퐶푏)
Where: Cm = maximum concentration accepted
Cb = background concentration
Cr = Maximum concentration permitted in accordance with the Ontario Drinking Water Standards x = a constant that reduces the contamination to a level that is considered by the Ministry to have a negligible effect on water use. i.e. 0.5 for non-health related parameters 0.25 for health related parameters.
In 2018, the RUC values were calculated for all parameters that have a corresponding
ODWQS limit using the median value of the background concentration (Cb) from a minimum of the previous five sampling events. The maximum allowable concentration (Cm) of any particular parameter may be calculated using the background concentration of that parameter from a monitor up-gradient of the Site, the designated ODWQS value for that parameter, and a constant that reflects whether the parameter is health or aesthetic-related as defined by the ODWQS. Where background concentrations were less than the laboratory method detection limit, the method detection limit was used as the background value. The calculated Cm values for the site were set as the RUC values. Where a background value exceeded the ODWQS value, the Cb value was set as the RUC value.
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4.1.4.1 Compliance Assessment
In 2018, the RUC concentrations were calculated for the Site using background water quality from monitoring wells MW5 (Table 3). The RUC values were calculated for all of the parameters for the Site that have a corresponding ODWQS limit.
In 2018, the RUC assessment included drive-point piezometer DP4 only as drive-point piezometers DP2 and DP3 were not accessible (May) and damaged (November). Colour, TDS, DOC, iron, and manganese were observed to exceed the RUC criteria of three or more consecutive occasions (Table 3). Table 4 compares the groundwater quality to the PWQO and CWQG where applicable. No parameter concentrations exceeded the stipulated PWQO based trigger in 2018.
Colour was noted to exceed RUC on three or more occasions at DP4. Colour exceedances frequently occur at all groundwater monitoring locations on-site, including background location MW5.
Total dissolved solids concentrations have been observed to periodically exceed the RUC criteria at drive-point DP4 since installation in 2009; the concentrations observed in 2018 were within historical ranges observed at this location. As stated in previous reports, the most common chemical constituents of TDS are calcium, phosphates, nitrates, sodium, potassium, and chloride, which are found in nutrient run-off among other sources (Cambium, 2018). A review of these constituents indicated that most parameter concentrations were observed to be low and stable with the exception of calcium which was observed to be increasing at this piezometer since 2013. The concentrations of TDS and calcium were reviewed in the leachate water quality at the Site; both parameter concentrations were observed to be stable (calcium) or decreasing (TDS) over time. Furthermore, the ODWQS criteria used to derive the RUC criteria is not a health-related parameter. Based on the above, the elevated concentrations of TDS at drive-point piezometer DP4 are not expected to cause adverse impacts down-gradient of the waste mound.
Although DOC, iron, and manganese are elevated in the leachate at the Site, comparing these parameter concentrations to the background water quality is not suitable. As the background
Cambium Inc. Page 21 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019 well is installed in the bedrock, it is not unexpected that this well would not be influenced by elevated parameter concentrations such as DOC, iron, and manganese, often observed to be elevated in organic soils similar to those surrounding the waste mound at the Site (Bendell- Young, 2003). Furthermore, the trigger states: Certain metals (iron and manganese) and organics (DOC and organic nitrogen) are ubiquitous constituents within a wetland setting and have naturally occurring wide ranges in concentrations. The examination of these parameters as impact indicators should be based on established trends and gradients… should any landfill perimeter monitor contain any constituent (excepting DOC, iron, manganese and zinc) having a concentration exceeding the PWQO. The concentrations of DOC, iron, and manganese at drive-point piezometer DP4 were observed to be decreasing over time.
Based on the above, the Site is not interpreted to be causing adverse impacts on the down-gradient groundwater regime and the groundwater trigger was not activated in 2018.
4.2 Surface Water Quality
The 2009 to 2018 surface water quality data are presented in Table 5. The surface water data have been compared with background water quality data, historic results, and the PWQO and CWQG criteria, where applicable.
In 2018, duplicate groundwater samples were collected from surface water sampling location SW3 in May and November. Results from the analyses completed on the blind duplicate samples as part of the QA/QC program were evaluated. The duplicate analysis indicated that, while in general, the data between duplicate samples showed good correlation, the following parameters reported notable differences for the sampling events shown in Embedded Table 6. Parameter concentrations were considered to be significantly different if the RPD between the duplicate and the original samples was greater than 30RPD when both analytical results were greater than five times the RDL.
Embedded Table 6 Surface Water QA/QC Evaluation May- SW3 November – SW3 None Iron – 36%
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Parent/duplicate samples with only one measurable concentration were assessed qualitatively. If the measurable concentration was close to the detection limit, the sample results were considered valid and the measurable concentration was accepted. Evaluation of these parent/duplicate samples did not identify significant data quality issues.
Based on the above, the surface water data was considered suitable for its intended use, which was to identify changes in water quality and analyzed parameters present at concentrations greater than the applicable standards. The surface water analytical results were interpreted with confidence.
4.2.1 Background Surface Water Quality
The water quality at location SW1 is considered representative of background conditions. Surface water quality at this location has historically been typified by low concentrations of major irons such as chloride and sodium and elevated concentrations of iron and total phosphorus. Seasonal fluctuations have been evident, observed to be significant in some cases.
The following general recommendations were noted:
The 2018 water quality results indicated that the parameter concentrations at surface water station SW1 were generally within their respective historical range.
The concentration of total phenolics was noted to be elevated in November 2018. Surface water location SW1 is located within an area that experiences intermittent flooding. Elevated concentrations of phenolics are typical in stagnant water environments.
Total aluminum concentrations exceeded the PWQO criteria in November; however, the observed concentration was within its historical range.
Surface water station SW1 continued to represent background surface water quality at the Site in 2018.
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4.2.2 Downstream Surface Water Quality
In 2018, three downstream surface water locations were monitored at the Site in May and November: SW2, SW3, and SW4:
Surface water station SW2 is immediately adjacent to the waste disposal area in the ponded area, between drive-point piezometers DP3 and DP4. As previously discussed, the presence of the beaver dam has caused extensive flooding in this area. Surface water quality at this location has historically been reported to be similar to background surface water quality at station SW1 including significant seasonal fluctuations.
Surface water station SW3 is approximately 175 m northeast and downstream of the waste disposal area. This sampling station is at the upstream end of a culvert underneath Skootamata Road. Surface water quality at this location has historically been reported to have a number of parameter concentrations which were slightly elevated greater than at background station SW1 (LIPs); these include alkalinity, conductivity, TDS, chloride, boron, magnesium, and sodium. Given that station SW3 is located in close proximity to Skootamata Lake Road, elevated concentrations of parameters such as sodium, chloride, magnesium, and conductivity, were attributed to impacts from road salt. Furthermore, the sporadically elevated metals concentrations at this location may be related to salt use on the adjacent road as well. Salt influences the chemistry of the soil in which it infiltrates and can release metals (e.g., aluminum, boron, zinc, copper, cobalt, mercury, cadmium) and base cations (calcium, magnesium, potassium) (Health Canada, 2001).
Surface water sampling location SW4 was established and sampled for the first time in October 2016. This location is downstream of station SW2, and upstream of station SW3. Parameter concentrations at this location have also been noted to fluctuate sporadically, and are often comparable to the maximum concentrations observed at background station SW1; however, it is noted that water quality data is still limited at this location.
Due to the fact that surface water quality is noted to fluctuate regularly at the Site, average concentrations were compared across stations. In general, average parameter concentrations at downstream locations are comparable to those observed at background station SW1. It is
Cambium Inc. Page 24 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019 noted that average concentrations of a number of parameters are elevated at SW3, compared to the other surface water stations, including LIPs alkalinity, conductivity, TDS, chloride, magnesium, and sodium. This was attributed to road salt impacts discussed previously.
In 2018, the concentrations of the majority of parameters measured at downstream locations were within their respective historical ranges. The following provides a summary of notable observations following the 2018 surface water sampling campaign:
Concentrations of the majority of parameters measured at SW2 and SW4 were comparable or slightly elevated when compared to those at background location SW1 in both May and November.
In May and November 2018, a number of parameters, including some LIPs, were noted to be elevated at SW3 compared to upstream Sites (SW1, SW2, and SW4) including alkalinity, conductivity, chloride, hardness, boron, calcium, magnesium, manganese, potassium, and sodium. This can be attributable to impacts from road salt, as discussed above.
The concentrations of total phenolics were noted to be elevated in November at all surface water locations, including background station SW1. This was not attributed to the landfill.
Exceedances of PWQO criteria observed at downstream surface water stations in 2018 are provided in Embedded Table 7. Background surface water station SW1 is included for comparison. All PWQO and CWQG exceedances at the downstream surface water monitoring stations were within their respective historical ranges and/or consistent with concentrations observed at background station SW1.
Embedded Table 7 Summary of PWQO Criteria Exceedances in Surface Waters SW Sample Station May November SW1 Iron, Total Phosphorus (TP) Aluminum, Iron SW2 Iron, TP Copper, TP SW3 Iron, TP, DO (low) Copper, Iron, Zinc SW4 Iron, TP, Zinc Iron, TP, Zinc
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Overall, marginal impacts were evident at downstream surface water station SW2 and SW4 from Site operations and at station SW3 from de-icing activities on the adjacent road. Where elevated concentrations were observed, regardless of the source, parameter concentrations observed were within the range characteristic of natural surface waters and were not interpreted to be causing any adverse biological impacts to the receiving stream.
4.2.3 Surface Water Trigger Mechanism
The surface water trigger mechanism approved by the ECA (Condition 4.1.2) is described in correspondence dated February 11, 2013 (AECOM, 2014) and is outlined below.
Surface water trigger points are generally located at any point where surface water impacts due to landfilling operation are likely to occur. The water quality at the surface water station SW3 has been identified as the trigger sampling point to monitor potential impacts to the surface water migrating downstream of the landfill (Figure 3). The water quality at this location is therefore be compared to the trigger parameter concentrations for all parameters listed in Table 1.
The trigger parameter concentrations for the Site are defined as the numerical elevation of any trigger parameter at surface water station SW3:
1. greater than PWQO or the CWQG criteria where a PWQO does not exist, or greater than the background concentration (75th percentile) at station SW1 if higher than the PWQO/CWQG criteria; or,
2. if a PWQO/CWQG does not exist for the specified parameter, greater than the background concentration (75th percentile) at station SW1.
Two exceedances of any sampled trigger parameter at station SW3 considered to be caused by the Site triggers the conductance of a detailed surface water/biological study to determine if the trigger exceedance causes acceptable or unacceptable quality/biological impacts on the receiving watercourse. If the quality impacts are determined to be unacceptable by the detailed surface water/biological study, a contingency plan would be prepared and submitted to the Ministry Regional Director for approval prior to implementation.
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The plan should provide recommendations for any remedial measures that would address the potential impacts and the subsequent quality monitoring to confirm acceptable surface water conditions. If acceptable impact should be demonstrated by the surface water/biological study, the Ministry would be requested to support the continuance of routine sampling without mitigation regarding the specific trigger exceedance.
4.2.3.1 Contingency Plan
The contingency plan involves a tiered approach where: Tier I is a confirmatory phase, Tier II is an assessment phase, and Tier III is a remediation or mitigation phase.
Tier I involves a detailed analysis of historical monitoring results by a qualified professional. The objective of this analysis is to determine if the observed impact can be attributed to the landfill. Possible outcomes of Tier I include:
A determination that the observed exceedances are not due to landfill impacts or are not significant. In this instance, the professional might recommend changes to the trigger mechanism to avoid repeating the triggering event.
Detailed recommendations for further study to determine the impact of the exceedance. This might include a recommendation for more frequent or more extensive sampling or for a detailed surface water/biological study to determine if the exceedance is having an unacceptable quality/biological impact on the receiving watercourse.
A recommendation to proceed with Tier III remedial action.
Recommendations for further study should include time frames for initiation and completion. The Tier I report should be completed and submitted to Ministry’s District Manager within 120 days of submission of the Annual Report in which the Tier I trigger is deemed to be occurring.
Tier II would involve implementation of the study recommended by the Tier I report. Possible outcomes of Tier II include:
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A determination that the observed exceedances are not having an adverse impact on the receiving watercourse. In this instance the professional might recommend changes to the trigger mechanism to avoid repeating the triggering event.
A recommendation to proceed with Tier III remedial action.
Tier III is remedial action. Further study may be required to determine the most appropriate action(s). Follow up monitoring will be required to confirm the adequacy of the action. Remedial actions that may be considered include:
Drainage improvements
Installation of additional low permeability soil or geotextile capping
Installation of a leachate collection and treatment system
Closure of the Waste Disposal Site
Any recommendation for remedial action should include a time frame for completion of studies and implementation as well as recommended changes to the monitoring program to confirm the effectiveness of the action taken.
4.2.3.2 Compliance Assessment
In 2018, for several parameters, the 75th percentile background concentration at station SW1 could not be calculated given there was less than eight (8) data sets. Using available data, the following parameters were observed to exceed the trigger values on two or more consecutive occasions at surface water station SW3 (Table 5): alkalinity, conductivity, TDS, COD, hardness, calcium, magnesium, potassium, sodium, and DO (low).
For comparison purposes, the following parameters were observed to exceed the trigger values on two or more consecutive occasions at background surface water station SW1 in 2018: alkalinity, COD, hardness, calcium, magnesium, and conductivity (field).
As discussed in Section 4.2.2, elevated concentrations for the majority of the above listed parameters at station SW3 have been attributed at least in part to road salt impacts as this station is in close proximity to Skootamata Lake Road. Furthermore, all parameter
Cambium Inc. Page 28 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019 concentrations observed in 2018 the exceeded the trigger concentrations on two or more consecutive occasions other than sodium, were within the concentration ranges observed at station SW1.
As mentioned previously, parameter concentrations observed were within the range characteristic of natural surface waters and were not interpreted to be causing any adverse biological impacts to the receiving stream. Based on the above, a detailed surface water/biological study was not considered warranted and the trigger mechanism was not activated in 2018.
4.3 Landfill Gas
Landfill gas, specifically methane and carbon dioxide, is derived from the decomposition of organic wastes. Production of LFG from landfilled wastes normally reaches a maximum rate approximately two (2) years after placement and may continue at this rate for many years. The biological decomposition process results in the generation of LFG until some period, likely decades, after the landfilling of that waste ceases. Methane is explosive at volumes of 5 to 15 % methane by volume (50,000 ppm to 150,000 ppm) in air.
LFG was monitored at gas probe GP1 on-site in conjunction with the 2018 groundwater monitoring events (Appendix B). Methane was not observed at gas probe GP1 greater than 0.05 % methane by volume in 2018.
4.4 Adequacy of Monitoring Program
In an effort to have a refined and concise monitoring program at the Site, the existing monitoring program is reviewed annually to determine if it sufficiently monitors impacts at the Site. Following the 2018 assessment, the monitoring program continues to effectively characterize Site conditions, groundwater and any groundwater discharges from the Site, and surface water conditions and includes data that relates to upstream/background and downstream receiving water conditions. At the Site, in whole or in part:
All monitoring wells are confirmed to be in good condition and secure.
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All fieldwork for groundwater investigations was done in accordance with the established SOPs (including internal/external QA/QC).
The Site has an adequate buffer, contaminant attenuation zone (CAZ), and contingency plans in place.
Design and operational measures, including size and configuration of any CAZ, are adequate to prevent potential human health impacts and impairments of the environment.
The Site meets compliance and assessment criteria.
All surface water sampling for the monitoring period was successfully completed in accordance with the ECA.
All field work for the surface water investigations was done in accordance with SOPs including internal/external QA/QC requirements.
It is noted, following an assessment of the monitoring program in 2016 and discussed in Section 4.1.3, drive-point piezometers DP2 and DP3 are damaged. It was recommended that these drive-points be decommissioned and removed from the monitoring program (Cambium, 2017). In comments dated August 3, 2017 (Cambium, 2018), the Ministry groundwater reviewer suggested that decommissioning the existing monitors and establishing new drive points in more appropriate locations may be advisable. The reviewer indicated that the need for and location of these monitors should ultimately be determined by the Ministry Surface Water Scientist. As of the date of this report, no comments have been received from the Surface Water Unit.
As discussed in Section 4.1.4, groundwater is interpreted to discharge to surface at the Site; therefore, the intent of Ministry Guideline B-7 is met. It is noted that the Ministry groundwater reviewer concurred with this conclusion in a memo dated August 3, 2017 (Cambium, 2018). As such, it is recommended that management approaches be focused on the receiving surface water feature and the groundwater trigger be removed from the annual assessment. The surface water trigger mechanism outlined in Section 4.2.3 will continue to be used. As required
Cambium Inc. Page 30 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019 by Condition 4.3 of the ECA, the trigger mechanism will not be changed until written permission is granted by the District Manager.
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5.0 Site Operations
This section presents a summary of the operations in 2018 for the Cloyne waste disposal site. The Site is closed to landfilling and operates as a transfer station for solid, non-hazardous domestic and commercial waste.
The Site is jointly owned by the Township of North Frontenac and the Township of Addington Highlands. Residents from both Townships are permitted to bring their waste and recyclable material to the Site where materials are stored in bear-proof bins.
5.1 Site Access and Security
The Site is well screened by the surrounding forest, and thick vegetation. Site access is controlled from Skootamatta Lake Road by a lockable gate which was observed to be in good repair in 2018. Access is only permitted during operational hours, with the presence of a Site attendant.
Signage is posted at the gate, which lists the Site ECA number, emergency contact information, acceptable wastes, hours of operation, Site rules, and a bear advisory. In 2017, the Township upgraded existing signage and installed new signage at the recycling depot informing users what materials are acceptable and directing users to appropriate storage or disposal areas. Furthermore, signs stating that “dogs must stay in vehicles” were installed in 2017 (Cambium, 2018). In 2018, the Township implemented a visual management system through the use of signs to direct residents on how to sort and place divertible materials.
As of March 2017, the Site received new hours to better serve the residents of Township and for the safety of the site attendants.
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The hours of operation are as follows:
Winter (October 1 to May 14)
Sunday ...... 9:00 AM to 4:00 PM Wednesday ...... 1:00 PM to 4:00 PM Friday ...... 9:00 AM to 12:00 PM
Summer (May 15 to September 30) Sunday, Monday (includes Holidays) ... 9:00 AM to 4:30 PM Wednesday, Friday ...... 9:00 AM to 1:00 PM Saturday ...... 9:00 AM to 2:00 PM
On Sunday, and Monday the Site is closed from 1:00PM to 1:30PM. All Township sites are closed on Christmas and New Year’s Day.
According to the Township, a log book is kept at the Site in which the Site attendant records on each day of operation, the results of daily inspections, any incidents, materials received, and other items, as required by the ECA. Additionally in 2018, an annual and a general monthly inspection was completed by the Joint Health and Safety Committee and the Waste and Recycling Lead Hand. Details of the inspections included personal protective equipment, daily operational logs, condition of the signage, gates and fences, and other operational features of the Site.
5.2 Training
Waste Site Attendant Operator training detailing the Litter Control Plan, acceptable waste types, daily operations, etc. was provided to all site attendants and other waste/recycling staff in May 2018 for all current and new employees as per the requirements of Condition 12 of the ECA (Appendix A). Previous years training included:
Invasive Plant Awareness, and Bear Wise training was provided to all Site attendants and other waste/recycling staff in 2016.
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Commercial Vehicle Operator’s Registration training and Waste Management Systems Driver training was provided to all waste and recycling haulers in 2016.
Propane in Construction training and Standard First Aid and Cardiopulmonary Resuscitation (CPR) trailing is provided to all waste site attendances and the waste/recycling hauler on a 3-year renewal basis.
5.3 Drainage
The waste mound was observed to be adequately covered and there was minimal evidence of erosion observed during Site visits in 2018.
As discussed in Section 3.1, a beaver dam was constructed near surface water station SW2, which has caused extensive flooding west of the waste disposal area. The Township is currently in the process of gradually deconstructing the beaver dam, lowering the water levels slowly to prevent any flooding across Skootamatta Lake Road and/or Highway 41. The Township hopes to have this problem resolved by spring 2019.
5.4 Roads
The access road was observed to have sufficient width at the entrance and within the Site to allow unimpeded winter travel and access for emergency and snow removal equipment. The site access roads were observed to be well maintained and graded and were regularly cleared of snow with a sand mixture applied by the Township during the winter months.
5.5 Aesthetics
The Township conducted regular litter collection programs as necessary throughout the 2018 operating year at the Site. The landfill attendant is responsible for the clean-up of blown litter on a daily basis. Additional help is provided in the summer months when two staff members are designated towards litter clean up and maintenance of all Township sites.
In 2018, Cambium noted that the immediate area of the Site was observed to be clean, with minimal waste reported around the perimeter. As reported in 2017, considerable amounts of blown litter were noted in the vicinity of the beaver dam by surface water monitoring station
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SW2 (Cambium, 2018). The Township is currently working on cleaning up this area in conjunction with the deconstruction of the beaver dam and lowering the water levels.
5.6 Complaints and Incidents
The Township reported that there were no formal complaints or incidents at the Site in 2018.
5.7 Monitoring Well Security
As a part of the 2018 work program, Cambium inspected all monitoring wells as listed in Table 1 for compliance with Ontario Regulation (O. Reg.) 903 (Wells).
The following repairs were recommended in the 2016 Annual Monitoring Report (Cambium, 2017); however, due to inaccessibility, this work was unable to be completed in the subsequent years. The Township is currently in the process of lowering the water levels in the area of these drive points with the goals of having them accessible in 2019.
Drive-point DP2 and DP3 were reported to be unsecured, as the inside galvanized steel piping broke through the cap of the drive-point. This was observed for the first time in the autumn of 2016 as these drive-points had previously been inaccessible due to being underwater as a result of the nearby beaver dam. As discussed in Section 4.1.3, these drive-points should be decommissioned as they are being filled by surface water and should be removed from the monitoring program. It is noted that the Site is considered out of compliance with Condition 3.9 of the ECA until these drive-points are addressed.
Photographs of the monitoring wells are included in Appendix D.
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5.8 Materials Summary
The following waste types are approved to be accepted at the Site; refer to Figure 3 for the collection locations of each material.
Domestic and commercial solid, non-hazardous waste Blue Box Recyclables
5.8.1 Site Usage
Site usage, as documented by the Township, is summarized in Embedded Table 8.
Embedded Table 8 Summary of Site Usage 2018 2017 2016 Vehicles – Private 7,029 6,037 - Bags of Garbage 4,848 4,764 8,896
Using the number of garbage bags, it is possible to determine the tonnage of residential waste deposited at the Site. Assuming each bag weighs 14 kg, 68 tonnes of residential waste was deposited at the Site in 2018 by Township of North Frontenac residents.
Waste collected at Site is kept in 30 m³ bins and transferred periodically to the Township’s 506 Waste Disposal Site or the Kaladar Waste Disposal Site located in the Township of Addington Highlands. In 2018, 11 – 30 m³ bins were transferred to the 506 Waste Disposal Site.
5.8.2 Material Diversion
Embedded Table 9 provides a summary of the materials diverted from the all Township sites in 2018.
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Embedded Table 9 Summary of Diverted Materials Material Blue Box Plastic Containers 60.97 tonnes Glass 58.42 tonnes Paper 42.63 tonnes Cardboard 16.52 tonnes Other 0.14 tonnes
Scrap Metal1 30.61 tonnes Sub total 209.29 tonnes Notes: 1. Scrap metal is only accepted at 506, Mississippi, and Plevna.
5.9 Compliance with Environmental Compliance Approval
The Township is managed the Site in compliance with the ECA in 2018 with the exception of Condition 3.9. Once drive-points DP2 and DP3 are decommissioned, the Site will be in compliance with the ECA.
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6.0 Conclusions and Recommendations
Based on the 2018 monitoring program, Cambium provides the following conclusions regarding the Cloyne waste disposal site.
Consistent with historical results, the water level measurements from 2018 indicated that groundwater flows in May and November were to the west-northwest and north, respectively.
The groundwater quality down-gradient of the waste disposal area at monitor DP4 was observed to have a number of parameter concentrations elevated greater than background water quality at the Site. The parameter concentrations were observed to meet the RUC and PWQO criteria in most cases; therefore, adverse impacts to groundwater and receiving surface waters were not expected.
The groundwater trigger mechanism was not activated in 2018. Furthermore, it has been interpreted that any leachate generated at the Site will migrate laterally into the adjacent wetland and not into deeper aquifer systems. As contaminated groundwater is interpreted to be discharging to surface water on-site, the intent of Ministry Guideline B-7 is met.
Marginal impacts, if any were evident at downstream surface water stations SW2 and SW4 from Site operations, and at station SW3 from de-icing activities on the adjacent road. Where elevated concentrations were observed, regardless of the source, parameter concentrations observed were within the range characteristic of natural surface waters and were not interpreted to be causing any adverse biological impacts to the receiving stream.
Several parameter concentrations were observed to exceed the surface water trigger values on two (2) or more consecutive occasions in 2018 at surface water station SW3. Elevated concentrations were attributed at least in part to road salt impacts as this location is in close proximity to Skootamata Lake Road, and to natural sources. Parameter concentrations observed were within the range characteristic of natural surface waters and were not interpreted to be causing any adverse biological impacts to
Cambium Inc. Page 38 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
the receiving stream. As such, a detailed surface water/biological study was not considered warranted and the trigger mechanism was not activated.
Methane was not observed at gas probe GP1 greater than 0.05 % methane by volume in 2018.
According to Township records, a total of 4,848 bags of waste were received at the Site in 2018 and transferred to the Township’s 506 Waste Disposal Site.
The Township diverted a total of approximately 209.29 tonnes of blue box recyclables and scrap metal from all operational sites in 2018.
The Township is currently in the process of slowly lowering the water levels in the flooded area west of the waste mound. The beaver dam located near surface water station SW2 is being gradually deconstructed to prevent any flooding on Skootamatta Lake Road and/or Highway 41.
The Township is currently managing the Site in compliance with the Site ECA with the exception of Condition 3.9. Once drive-points DP2 and DP3 are decommissioned, the Site will be in compliance with the ECA.
Based on the 2018 monitoring program, Cambium provides the following recommendations regarding the Cloyne waste disposal site.
Drive-points DP2 and DP3 are damaged and require decommissioning. Given that significant improvement of water quality has been observed at the Site since closure and the conceptual Site model indicates shallow groundwater discharges to surface northwest and north of the waste mound, it is recommended that drive-points be decommissioned and removed from the monitoring program. As required by Condition 3.8, until written approval from the District Manager is received, the groundwater, surface water, and LFG monitoring program should be completed as detailed in Table 1.
As discussed in Section 4.1.4, groundwater is interpreted to discharge to surface at the site; therefore, the intent of Ministry Guideline B-7 is met. It is recommended that the groundwater trigger assessment be removed from the annual assessment. Site
Cambium Inc. Page 39 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
compliance will continue to be assessed using the surface water trigger mechanism. As required by Condition 4.3 of the ECA, the trigger mechanism will not be changed until written permission is granted by the District Manager.
Cambium Inc. Page 40 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
References AECOM. (2014). Cloyne Waste Disposal Site, 2013 Annual Report.
AECOM. (2015). Cloyne Waste Disposal Site, 2014 Annual Report.
Bendell-Young, L. (2003). Peatland Interstitial Water Chemistry in Relation to That of Surface Pools along a peatlnad mineral gradient. Water, Air, and Soil Pollution, 143, 363-375.
Cambium. (2017). 2016 Annual Report, Cloyne Waste Disposal Site. Cambium.
Cambium. (2018). 2017 Annual Report, Cloyne Waste Disposal Site. Peterborough, Ontario: Cambium Inc.
CCME. (2007). Canadian Environmental Quality Guidelines. Canadian Council of Ministers of the Environment.
Government of Canada. (2015). Canadian Climate Normals & Averages 1981-2010. Retrieved December 1, 2015, from Canadian Climate Normals: http://climate.weather.gc.ca/climate_normals/index_e.html
Government of Canada. (2018). Historical Data. Retrieved January 30, 2019, from Past weather and climate: http://climate.weather.gc.ca/historical_data/search_historic_data_e.html
Health Canada. (2001). Priority Substances List Assessment Report for Road Salts. Retrieved November 2, 2015, from http://www.hc-sc.gc.ca/ewh-semt/pubs/contaminants/psl2- lsp2/road_salt_sels_voirie/index-eng.php
MOE. (2010). Monitoring and Reporting for Waste Disposal Sites, Groundwater and Surface Water, Technical Guidance Document. Ministry of the Environment.
MOEE. (1993). Guidance Manual for Landfill Sites Receiving Municipal Waste (PIBS 2741). Ministry of the Environment and Energy.
MOEE. (1994). Guideline B-7: Incorporation of the Reasonable Use Concept into MOEE Groundwater Management Activities. Ministry of the Environment and Energy.
Cambium Inc. Page 41 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
MOEE. (1994). Water Management: Policies, Guidelines, Provincial Water Quality Objectives. Ministry of the Environment and Energy.
MOEE. (1996). Guidance on Sampling and Analytical Methods for Use at Contaminated Sites in Ontario (1.1 ed.). Ministry of the Environment and Energy.
TSH. (2008). Cloyne Waste Disposal Site, Site Closure Plan. Totten Sims Hubicki Associates.
Cambium Inc. Page 42 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Glossary of Terms Active Face/Area The portion of the landfill facility where waste is currently being deposited, spread and/or compacted prior to the placement of cover material. Adverse Environmental Impact Any direct or indirect undesirable effect on the environment resulting from an emission or discharge which is caused or likely to be caused by human activity. Annual Report Report documenting the results of water quality, environmental quality, and operations monitoring for the year, or for a period as prescribed in the Certificate of Approval. Approved Design and Operations Plan The design of a landfill site and it's facilities which have been submitted along with the application documents for which formal Ministry approval has been issued through the Certificate of Approval. Approved Site or Facility A landfill site/facility for which there is an existing and current Certificate of Approval. Aquifer A geologic unit (soil or rock) that contains sufficient saturated permeable material to yield measurable quantities of water to wells and springs. Attenuation Natural process through which the concentrations of landfill generated contaminants are reduced to safe levels. Borehole Is a hole drilled for soil sampling purposes. Buffer Area An area of land situated within the peripheral area surrounding an active filling area, but limited in extent to the property boundary, assigned to provide space for remedial measures, contaminant control measures, and for the reduction or elimination of adverse environmental impact caused by migrating contaminants. Certificate of Approval The license or permit issued by the Ministry for the operation of a landfill site. Issued to the owner of the site with conditions of compliance stated therein. Contaminant A compound, element or physical parameter, usually resulting from human activity, or found at elevated concentrations that have or may have a harmful effect on public health or the environment. Contaminant Migration Path Route by which a contaminant will move from the site into adjacent properties or the natural environment. Usually a route that offers the least resistance to movement. Contamination Attenuation Zone The zone beneath the surface, located beyond the landfill site boundary, where contaminants will be naturally attenuated to predetermined levels. Also, see Reasonable Use Policy. Contingency Plan A documented plan detailing a co-ordinated course of action to be followed to control and remediate occurrences such as a fire, explosion, or release of contaminants in an uncontrolled manner that could threaten the environment and public health. Cover Material Material approved by the Ministry that is used to cover compacted solid waste. Usually, a soil with suitable characteristics for specific end- use. Site Development Plan and Operations Report Development and Operations Plan or Report is a document detailing the planned sequence of activities through the landfill site's active life, the control systems, site facilities and monitoring systems, that are necessary. This document is required for obtaining a Certificate of Approval. Design Capacity The maximum amount of waste that is planned to be disposed of at a landfill site. Detection Limit Concentration under which a parameter cannot be quantitatively measured.
Cambium Inc. Page 43 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
EAA or EA Act Environmental Assessment Act, Revised Statutes of Ontario, 1990. One of the primary acts of legislation intended to protect, conserve and wisely manage Ontario's environment through regulating planning and development. EPA Environmental Protection Act, Revised Status of Ontario, 1990. EPA is another of the primary pieces of Provincial legislation governing the protection of the natural environment of the Province. Evapotranspiration The evaporation of all water from soil, snow, ice, vegetation and other surfaces, including the water absorbed by plants, that is released to the atmosphere as vapour. Fill Area The area of a landfill site designed and designated for the disposal of waste. Final Cover Soil material or soil in combination with synthetic membranes, overlain by vegetation in a planned landscape, placed over a waste cell that has reached the end of its active life. Groundwater Subsurface water that occurs beneath the water table in soils and rocks that are fully saturated. Hydraulic Conductivity The rate of flow of water through a cross-section under a specific hydraulic gradient. It is a property of the geologic formation and the fluid, in hydrogeologic applications where the fluid is water. (Units of m/day or cm/s). Hydraulic Gradient The head drop per unit distance in the direction of flow, the driving force for groundwater flow. Hydrogeology The study of subsurface waters and related geologic aspects of surface waters. Impermeable Fill Soil material that is placed as filling material that is sufficiently cohesive and fine grained to impede and restrict the flow of water through it. In situ Testing Testing done on-site, in the field, of material or naturally occurring substances in their original state. Landfill Gas Combustible gas (primarily methane and carbon dioxide) generated by the decomposition of organic waste materials. Landfill Site A parcel of land where solid waste is disposed of in or on land for the purposes of waste management. Leachate Water or other liquid that has been contaminated by dissolved or suspended particles due to contact with solid waste. Leachate Breakout Location where leachate comes to the ground surfaces; a seep of spring. Limit of Filling The outermost limit at which waste has been disposed of, or approved or proposed for disposal at a landfill. Ministry Ontario Ministry of the Environment, Conservation, and Parks. Monitoring Regular or spontaneous procedures used to methodically inspect and collect data on the performance of a landfill site relating to environmental quality (i.e. air, leachate, gas, ground or surface water, unsaturated soils, etc.). Monitoring Well Is the constructed unit of casing and screen installed in a borehole. Multi-Level Monitoring Well More than one monitoring well installed at a given test well location. Native Soil Soil material occurring naturally in the ground at a location. Natural Attenuation Where contaminants are reduced to acceptable concentration levels by natural mechanisms (dilution, absorption onto the soil matrix, etc.), biological action, and chemical interaction.
Cambium Inc. Page 44 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Occupational Health and Safety Act The primary act of legislation enacted by Ontario Ministry of Labour to regulate and control the safety in the workplace, also Occupational Health and Safety Act, Revised Statutes of Ontario, 1990. Odour Control Minimizing or eliminating the nuisance and undesirable impact of objectionable or unpleasant odours arising from waste disposal operations. Open Burning Burning any matter whereby the resultant combustion products are emitted directly to the atmosphere without passing through an adequate stack, duct, or chimney. Operations Plan A document detailing the waste disposal operations in a planned, and if necessary, a staged manner, that ensure compliance with regulatory provisions concerning the operations of a landfill site. Operator (Site Operator)/Attendant The individual or organization who, through ownership or under contract, manages and operates a landfill site for the purpose of waste disposal. Owner A person, persons, organization or municipal authority who own a landfill facility or part of a landfill facility, and in whose name the Certificate of Approval for the site is issued. Percolation The movement of infiltrating water through soil. Permeability Often used interchangeable with hydraulic conductivity, but not strictly correct. Permeability is a property of the porous media only. Dependent upon media properties that affect flow, diameter, sphericity, roundness and packing of the grains. Piezometer A well that intersects a confined aquifer. Provisional Certificate of Approval (Provisional C of A) Same as Certificate of Approval. Reasonable Use Policy A policy developed by the Ministry to stipulate limits to the level of groundwater quality impairment that may be permitted to occur at site property boundaries, to allow the reasonable use of adjacent properties or land without adversely affecting public health and the environment. Recharge Zone An area where precipitation or surface run-off infiltrates into the ground and then, through natural percolation enters an aquifer. Recycling Sorting, collecting or processing waste materials that can be used as a substitute for the raw materials in a process or activity for the production of (the same or other) goods. For example, the "Blue Box" system, in-plant scrap handling, or raw material recovery systems. Recycling is also the marketing of products made from recycled or recycled materials. Reduction (of waste or component of 3Rs program) Those actions, practices or processes which result in the production or generation of less waste. Remedial Action Corrective action taken to clean-up or remedy a spill, an uncontrolled discharge of a contaminant, or a breach in a facility or its operations, in order to minimize the consequent threat to public health and the environment. Representative Sample A small portion of soil, water, etc. which can be subjected to testing and analysis, that is expected to yield results that will reliably represent the identical characteristics of the source of the material or of a larger body of material. Reuse (component of 3Rs program) The use of an item again in its original form, for a similar purpose as originally intended, or to fulfil a different function. Run-off The part of precipitation (rain water, snow melt) that flows overland and does not infiltrate the surface material (soil or rock). Saturated Zone The zone of a subsurface soil where all voids are filled with water. Sedimentation The deposition of fine grained soil in an undesirable location, caused by the scouring, erosion and transportation of earth materials by surface run-off.
Cambium Inc. Page 45 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Sensitive Land Use A land use where humans or the natural environment may experience an adverse environmental impact. Settlement The subsidence of the top surface and underlying waste of a landfill or waste cell as a result of densification under its own weight. Site Capacity The maximum amount of waste that is planned to be disposed (design capacity) or that has been disposed of at a landfill site. Site Closure The planned and approved cessation or termination of landfilling activities at a landfill site upon reaching its site capacity. Site Life The period of time from its inception through active period of waste disposal, to the time when a landfill site reaches its' site capacity, when it ceases to receive any further waste, including and up to closure. Solid Waste Any waste matter that cannot be characterized by its physical properties as a liquid waste product. Solid Waste Disposal Site or Facility A site or facility such as a landfill site where solid waste is disposed of. Source Separation The separation of various wastes at their point of generation for the purposes of recycling or further processing. Standpipe A monitoring well which intersects the water table aquifer. Stormwater Run-off that occurs as a direct result of a storm event or thaw. Stormwater Detention Control of stormwater by the construction of impoundments of structures for the purpose of regulating stormwater flows during high intensity rainfall events, that would otherwise transport excessive amounts of sediment, cause soil erosion or cause flooding. Stratigraphy The geologic sub-structuring, usually layered with different distribution, deposition and age. Surface Run-off (Drainage) See Run-off. Surface Water Water that occurs at the earth's surface (ponds, streams, rivers, lakes, oceans). Sub-Soil Soil horizons below the topsoil. Test hole Is a hole drilled for soil sampling purposes. Topsoil The uppermost layer of the soil containing appreciable organic materials in mineral soils. Adequate fertility to support plant growth. Unsaturated Zone (also vadose zone) - The zone in a porous sub-soil, where the voids are not completely water-filled, but contain some air-filled voids. Limited above by the land surface and below by the water-table. Vector A disease carrier and transmitter; usually an insect or rodent. V.O.C. Volatile organic compounds are those compounds which will readily volatilize (convert from liquid to gas phase) at conditions normally found in the environment. Waste Ashes, garbage, refuse, domestic waste, industrial waste, or municipal refuse and other used products as are designated or interpreted by the provisions of the Environmental Protection Act. Waste Disposal Site (Facility) Any land or land covered by water upon, into, in or through which, or building or structure in which, waste is deposited or processed and any machinery or equipment or operation required for the treatment or disposal of waste.
Cambium Inc. Page 46 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Waste Management System All facilities, equipment and operations for the complete management of waste, including the collection, handling, transportation, storage, processing and disposal thereof, and may include one or more waste disposal sites. Water Table The water level attained in a monitoring well which screens the surficial unconfined aquifer. Water Balance Amounts of water to various components in a system so that water entering the system equals the amount of water contained within and discharged out of a system. Water Level The level of water in a well. Well Casing The pipe that is used to construct a well. Well Screen A filtering device used to keep sediment from entering a well. Wetlands Areas where water is at, near or above the land surface long enough to be capable of supporting aquatic or hydrolytic vegetation, and which have soils indicative of wet conditions.
Cambium Inc. Page 47 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Appended Figures
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A B E Water Area D R S L IL Provincial Park
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0 A 5 not constitute an endorsement by the Ministry of Natural Resources or the 2 /E'dKE T 2 3 5 30 T Ontario Government). 3 0 3 8 A 29 9 - Distances on this plan are in metres and can be converted to feet by 2 0 2 dividing by 0.3048. ZKZE' L A - Cambium Inc. makes every effort to ensure this map is free from errors but K cannot be held responsible for any damages due to error or omissions. This
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2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Figure4:GroundwaterElevations 102
101
100
99 (m) 98 MW1 Elevation 97 DP2 DP3 96 DP4
Groundwater MW5 95
94
93
92
Date
2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Appended Tables
Cambium Inc. Cloyne Waste Disposal Site The Township of North Frontenac Cambium Reference No.: 7215-007
Table 1 - Environmental Monitoring Programs
Location Task Frequency Parameters
Groundwater Bicarbonate, calcium, sodium, chloride, sulphate, potassium, Groundwater Elevations magnesium, alkalinity, ammonia, MW1, DP2, DP3, Field measurements (pH, Twice annually colour, conductivity, pH, DOC, TDS, DP4, MW5 TSS, nitrite, nitrate, TKN, BOD, COD, temperature, conductivity, dissolved oxygen, and total phenols. (spring and autumn) oxygen reduction potential All metals and trace metals with a 1 QA/QC (ORP)) PWQO including mercury, boron, iron, manganese, phosphorus Anion sum, cation sum, ion balance Groundwater Elevations Field measurements (pH, Once every 5 years; MW1 next in 2019 temperature, conductivity, EPA 624 VOCs
dissolved oxygen, and oxygen reduction potential (spring) (ORP)) Surface Water Bicarbonate, calcium, sodium, Surface water sampling chloride, sulphate, potassium, SW1, SW2, SW3 Flow estimates magnesium, alkalinity, ammonia, Staff gauge elevations Twice annually colour, conductivity, pH, DOC, TDS, SW4 (temporary TSS, nitrite, nitrate, TKN, BOD, COD, Field measurements (pH, location) total phenols. temperature, conductivity, (spring and autumn) All metals and trace metals with a dissolved oxygen, and PWQO including mercury, boron, oxygen reduction potential 1 QA/QC iron, manganese, phosphorus (ORP)) Anion sum, cation sum, ion balance Landfill Gas
Measure combustible gas Twice annually GP1 % by volume in all monitors Methane Groundwater Elevations (spring and autumn)
2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 2: Groundwater Elevation Data
Monitor MW1 DP2 DP3 DP4 MW5
Northing 4966748 4966736 4966766 4966795 4966718 Easting 2 326697 326673 326677 326711 326751 Original Ground 102.18 94.74 - 94.05 104.13 Elevation (m)
Stick Up (m) 0.92 0.45 - 0.65 0.83
Depth (m) 11.45 4.70 - 2.91 13.27
Measuring Point 103.10 95.19 95.09 94.70 104.96 (m)
Screend Layer Overburden/Waste Overburden Overburden Overburden Bedrock
8-Dec-09 94.36 94.19 94.30 94.05 - 13-Apr-10 94.30 94.16 94.22 93.90 - 5-Oct-10 94.38 94.12 94.21 94.29 - 1-Jun-11 94.37 93.94 94.09 93.68 - 3-Nov-11 94.27 93.95 94.02 93.85 - 30-Apr-12 94.43 94.19 94.22 94.18 - 28-Nov-12 94.25 94.14 94.22 94.12 - 16-May-13 94.44 94.14 94.28 93.90 - 30-Oct-13 94.53 - - 94.07 97.36 23-Jun-14 94.69 94.66 94.77 93.97 97.26 18-Nov-14 94.86 - - - 96.00 25-May-15 94.60 94.71 - 93.91 97.94 9-Nov-15 94.74 - - 93.89 97.03 19-Apr-16 94.89 - - 94.63 98.92 5-Oct-16 94.38 - - 92.80 94.73 3-May-17 94.71 - - 94.02 101.41 18-Sep-17 94.89 - - 94.06 96.40 22-May-18 94.71 - - 94.12 98.93 11-Nov-18 94.52 - - 93.85 95.37 Notes: 1. Elevations are relative to a local datum. 2. Zone 18, accurate to +/- 5.0 metres "-" Water Level data unavailable for sampling event 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 3: Summary of Groundwater Quality
DP2 DP2 DP2 DP2 DP2 DP2 DP2 DP2 DP2 DP2 Parameter ODWQS 2 RUC 3 8-Dec-09 13-Apr-10 8-Oct-10 1-Jun-11 3-Nov-11 30-Apr-12 28-Nov-12 16-May-13 23-Jun-14 25-May-15
Alkalinity (CaCO3) 500 332 204 224 187 176 180 179 - 179 177 178
Bicarbonate (CaCO3) NVNV------Colour (TCU) 53.5------5 Conductivity (µs/cm) NV NV 479 459 401 359 374 353 377 352 353 353 pH (units) 6.5 - 8.5 NV 7.08 7.52 7.68 7.88 7.76 7.99 7.67 7.82 7.86 8.02 Solids Total Dissolved (TDS) 500 344 264 252 221 197 206 194 207 194 194 194 Solids Total Suspended (TSS) NV NV 77900 2020 400 432 364 82 236 64 76 88 Carbon Dissolved Organic (DOC) 5 3.7 7.4 2.9 4.6 3.6 1.8 1.6 10.5 1.8 17.9 2 Oxygen Demand Biological (BOD) NV NV 20 14 6386< 2< 2< 2- Oxygen Demand Chemical (COD) NV NV 24 49 31 12 164 9 < 5 < 5 39 - Total Phenolics NV NV < 0.001 - < 0.001 - < 0.001 - < 0.001 - - < 0.001 Chloride 250 126 24 8.4 5 < 1 5.1 1.7 1.9 1.4 15.4 3.2 Nitrogen Ammonia (NH3) & Ammonium (NH4) NV NV 1.01 1.15 0.61 0.57 1.18 0.749 0.38 0.478 0.62 0.45 Sulphate 500 257 5 < 1 < 1 1 < 1 < 1 < 1 < 1 1 1 Nitrogen Nitrite (NO2) 1 0.3 < 0.1 - < 0.1 - < 0.1 - < 0.1 - - - Nitrogen Nitrate (NO3) 10 2.5 < 0.1 0.1 < 0.1 0.1 < 0.1 < 0.1 < 0.1 0.1 < 0.1 - Nitrogen Total Kjeldahl (TKN) NV NV 4 - 0.7 - 0.72 - 1.2 - - - Mercury 0.001 0.0003 < 0.00002 - < 0.00002 - 0.00003 - < 0.00002 - - -
Hardness (as CaCO3 ) 500 339 200 183 203 174 180 175 148 174 169 190 Aluminum 0.10.06------0.02 Antimony 0.006 0.0016 ------Arsenic 0.025 0.0064 < 0.0001 - 0.0001 - 0.0002 - 0.0001 - - < 0.0001 Beryllium NV NV ------Boron 5.0 1.25 0.016 0.027 0.171 0.029 < 0.005 0.01 0.019 0.01 0.037 < 0.005 Cadmium 0.005 0.0013 < 0.00002 - < 0.00002 - 0.00004 - < 0.00002 - - < 0.00002 Calcium NV NV 62.5 57.3 62.1 54.7 57 55.4 46.5 54.5 52.1 59.7 Chromium 0.05 0.014 < 0.002 - < 0.002 - < 0.002 - < 0.002 - - < 0.002 Cobalt NV NV ------Copper 1.0 0.5 < 0.002 - < 0.002 - < 0.002 - < 0.002 - - 0.0007 Iron 0.30 0.155 0.998 2.57 2.65 1.33 0.975 0.631 0.758 0.748 14.9 1.36 Lead 0.01 0.0025 < 0.00002 - 0.00007 - 0.00011 - 0.00015 - - < 0.00002 Magnesium NV NV 10.6 9.73 11.6 9.08 9.16 8.93 7.71 9.08 9.46 9.86 Manganese 0.05 0.071 0.164 1.13 0.654 0.676 0.257 0.17 0.147 0.149 2.23 0.334 Molybdenum NV NV ------Nickel NVNV------< 0.01 Phosphorus Total NV NV 8.55 - 0.34 - < 0.01 - 0.08 - - < 0.1 Potassium NV NV 4.9 2.9 9 2.6 2.8 2.7 2.3 2.5 4.4 2.8 Selenium 0.010 0.0033 ------Silver NVNV------Sodium 200 102 13.6 3.6 13.2 2.7 3.4 2.8 2.5 3.1 11.6 4.4 Thallium NV NV ------Tungsten NV NV ------Uranium 0.020.005------Vanadium NV NV ------Zinc 5 2.5 0.009 - 0.035 - 0.043 - < 0.005 - - 0.006 Zirconium NVNV------Conductivity (µs/cm)4 NV NV 380 330 - 364 378 306 350 297 280 400 pH (units)4 6.5 - 8.5 NV 7.91 7.23 - 7.14 7.19 6.83 7.55 7.45 7.83 7.42 Temperature (°C)4 NV NV 8.4 12 - 17.8 9.5 9 7.5 4.6 11.5 13.4 Oxidation Reduction Potential (mV)4 NVNV------38 Dissolved Oxygen4 NVNV------2.39 Notes: 1. Results expressed in mg/L unless otherwise stated 2. ODWQS means Ontario Drinking Water Quality Standards 3. RUC means Reasonable Use Concept 4. Results from field analysis Bold text and shading indicates values exceeding ODWQS Bold text indicates values exceeding the RUC NV indicates No Value "" denotes parameter not analysed 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 3: Summary of Groundwater Quality
DP3 DP3 DP3 DP3 DP3 DP3 DP3 DP3 Parameter ODWQS 2 RUC 3 8-Dec-09 13-Apr-10 8-Oct-10 1-Jun-11 3-Nov-11 30-Apr-12 16-May-13 23-Jun-14
Alkalinity (CaCO3) 500 332 502 594 372 215 486 475 390 51
Bicarbonate (CaCO3) NV NV ------Colour (TCU) 5 3.5 ------Conductivity (µs/cm) NV NV 1560 1750 1510 615 1260 1200 928 129 pH (units) 6.5 - 8.5 NV 7.37 7.84 7.97 7.69 7.78 7.69 7.39 7.57 Solids Total Dissolved (TDS) 500 344 855 964 828 338 692 660 510 71 Solids Total Suspended (TSS) NV NV 3250 2500 70 644 216 26 190 420 Carbon Dissolved Organic (DOC) 5 3.7 63.3 23.2 23.9 29 56.2 - 45.5 18.3 Oxygen Demand Biological (BOD) NV NV 12- 7 5 2323266 Oxygen Demand Chemical (COD) NV NV 846 275 124 143 324 - 270 160 Total Phenolics NV NV ------Chloride 250 126 162 183 93 45 86.6 - 48 3.7 Nitrogen Ammonia (NH3) & Ammonium (NH4) NV NV 13.4 12.8 9.2 5.3 < 0.05 7.78 11.6 1.95 Sulphate 500 257 1< 1311-< 1< 1 Nitrogen Nitrite (NO2) 10.3< 0.1 - 0.7 -0.1--- Nitrogen Nitrate (NO3) 10 2.5 0.1 0.1 0.2 0.3 1.9 - < 0.1 0.1 Nitrogen Total Kjeldahl (TKN) NV NV 30 - 13.6 - 20.8 - - - Mercury 0.001 0.0003 < 0.00002 - 0.00107 -----
Hardness (as CaCO3 ) 500 339 145 160 96 56 104 - - 11 Aluminum 0.1 0.06 ------Antimony 0.006 0.0016 ------Arsenic 0.025 0.0064 0.0041 - 0.0015 - 0.0027 - - - Beryllium NV NV ------Boron 5.0 1.25 1.03 1.14 0.829 0.454 1.62 - - 0.117 Cadmium 0.005 0.0013 0.00035 - 0.00002 - 0.00003 - - - Calcium NV NV 45.9 51.3 30.4 17.6 33.2 - - 3.39 Chromium 0.05 0.014 0.013 - 0.01 - 0.009 - - - Cobalt NV NV ------Copper 1.0 0.5 0.013 - 0.004 - 0.006 - - - Iron 0.30 0.155 1.95 1.5 5.54 1.35 1.95 --2.54 Lead 0.01 0.0025 0.0191 - 0.00179 - 0.00207 - - - Magnesium NV NV 7.35 7.76 4.84 2.83 4.97 - - 0.65 Manganese 0.05 0.071 0.434 0.409 0.284 0.204 0.321 --0.26 Molybdenum NV NV ------Nickel NV NV ------Phosphorus Total NV NV 4.8 - 0.08 - 0.81 - - - Potassium NV NV 108 123 82.3 44.1 103 - - 8.9 Selenium 0.010 0.0033 ------Silver NV NV ------Sodium 200 102 218 230 146 72.3 172 --6.8 Thallium NV NV ------Tungsten NV NV ------Uranium 0.02 0.005 ------Vanadium NV NV ------Zinc 5 2.5 0.058 - 0.037 - 0.087 - - - Zirconium NV NV ------Conductivity (µs/cm)4 NV NV 1490 1706 - 564 1092 1029 630 120 pH (units)4 6.5 - 8.5 NV 7.20 6.43 - 7.36 7.32 6.57 6.85 7.78 Temperature (°C)4 NV NV 6.1 10.3 - 18.6 8.9 9.8 6.48 17.7 Oxidation Reduction Potential (mV)4 NV NV ------Dissolved Oxygen4 NV NV ------Notes: 1. Results expressed in mg/L unless otherwise stated 2. ODWQS means Ontario Drinking Water Quality Standards 3. RUC means Reasonable Use Concept 4. Results from field analysis Bold text and shading indicates values exceeding ODWQS Bold text indicates values exceeding the RUC NV indicates No Value "" denotes parameter not analysed 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 3: Summary of Groundwater Quality
DP4 DP4 DP4 DP4 DP4 DP4 DP4 DP4 DP4 Parameter ODWQS 2 RUC 3 8-Dec-09 13-Apr-10 8-Oct-10 1-Jun-11 3-Nov-11 30-Apr-12 16-May-13 30-Oct-13 23-Jun-14
Alkalinity (CaCO3) 500 332 108 83 97 291 292 295 143 149 180
Bicarbonate (CaCO3) NV NV ------Colour (TCU) 5 3.5 ------Conductivity (µs/cm) NV NV 265 189 215 894 892 917 363 380 537 pH (units) 6.5 - 8.5 NV 6.63 7.42 7.36 7.15 7.07 7.14 7.15 7.20 7.26 Solids Total Dissolved (TDS) 500 344 146 104 118 492 491 504 200 209 295 Solids Total Suspended (TSS) NV NV 3780 2800 80 335 175 24 52 52 24 Carbon Dissolved Organic (DOC) 5 3.7 13.1 9.5 10.9 18.3 29.1 28.5 17.7 15.6 6.9 Oxygen Demand Biological (BOD) NV NV 11882747< 22 Oxygen Demand Chemical (COD) NV NV 59 21 39 128 90 81 33 37 49 Total Phenolics NV NV < 0.001 - < 0.001 - < 0.001 - - < 0.001 - Chloride 250 126 11 5.3 7 104 109 116 23.9 23.7 54.8 Nitrogen Ammonia (NH3) & Ammonium (NH4) NV NV 1.78 1.01 1.2 1.59 1.73 1.69 1.63 1.46 1.54 Sulphate 500 257 16< 1< 1< 12 < 1< 1< 113 Nitrogen Nitrite (NO2) 10.3< 0.1 - < 0.1 - < 0.1 - - < 0.1 - Nitrogen Nitrate (NO3) 10 2.5 < 0.1 0.1 < 0.1 < 0.1 0.5 < 0.1 0.1 < 0.1 < 0.1 Nitrogen Total Kjeldahl (TKN) NV NV 6 - 1.6 - 4.23 - - 2.2 - Mercury 0.001 0.0003 < 0.00002 - < 0.00002 - 0.00003 - - < 0.00002 -
Hardness (as CaCO3 ) 500 339 61 60 37 207 217 211 86 62 168 Aluminum 0.1 0.06 ------Antimony 0.006 0.0016 ------Arsenic 0.025 0.0064 < 0.0001 - 0.0002 - 0.001 - - 0.0003 - Beryllium NV NV ------Boron 5.0 1.25 0.108 0.051 0.216 0.638 0.572 0.436 0.226 0.316 0.213 Cadmium 0.005 0.0013 < 0.00002 - 0.00003 - 0.00004 - - < 0.00002 - Calcium NV NV 19 18.9 11 64.8 68.9 66.8 27.2 19 52.7 Chromium 0.05 0.014 0.003 - 0.002 - 0.005 - - 0.003 - Cobalt NV NV ------Copper 1.0 0.5 < 0.002 - 0.002 - < 0.002 - - < 0.002 - Iron 0.30 0.155 7 6.31 8.74 18.7 23.3 21.7 8.79 9.62 17.4 Lead 0.01 0.0025 < 0.00002 - 0.00019 - 0.00013 - - 0.0001 - Magnesium NV NV 3.3 3.19 2.27 10.9 10.9 10.8 4.31 3.59 8.72 Manganese 0.05 0.071 0.147 0.135 0.197 0.487 0.487 0.457 0.188 0.209 0.361 Molybdenum NV NV ------Nickel NV NV ------Phosphorus Total NV NV 4.6 - 0.1 - < 0.01 - - < 0.01 - Potassium NV NV 2.8 2.1 1.5 2.8 3.3 3 2.8 3.2 - Selenium 0.010 0.0033 ------Silver NV NV ------Sodium 200 102 25.1 13.8 12.1 102 121 121 47.4 46.6 47.8 Thallium NV NV ------Tungsten NV NV ------Uranium 0.02 0.005 ------Vanadium NV NV ------Zinc 5 2.5 0.009 - 0.011 - 0.033 - - 0.035 - Zirconium NV NV ------Conductivity (µs/cm)4 NV NV 252 210 - 873 826 831 258 280 456 pH (units)4 6.5 - 8.5 NV 7.10 6.92 - 6.41 6.81 5.81 6.80 6.21 6.98 Temperature (°C)4 NV NV 8.3 10.3 - 16.5 10.1 9.4 3.7 9.4 12.9 Oxidation Reduction Potential (mV)4 NV NV ------Dissolved Oxygen4 NV NV ------Notes: 1. Results expressed in mg/L unless otherwise stated 2. ODWQS means Ontario Drinking Water Quality Standards 3. RUC means Reasonable Use Concept 4. Results from field analysis Bold text and shading indicates values exceeding ODWQS Bold text indicates values exceeding the RUC NV indicates No Value "" denotes parameter not analysed 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 3: Summary of Groundwater Quality
DP4 DP4 DP4 DP4 DP4 DP4 DP4 DP4 Parameter ODWQS 2 RUC 3 25-May-15 9-Nov-15 19-Apr-16 5-Oct-16 3-May-17 18-Sep-17 22-May-18 1-Nov-18
Alkalinity (CaCO3) 500 332 177 179 192 180 200 193 195 225
Bicarbonate (CaCO3) NV NV - 179 192 180 200 193 195 225 Colour (TCU) 5 3.5 4 3 44166127 Conductivity (µs/cm) NV NV 575 635 623 658 674 671 671 747 pH (units) 6.5 - 8.5 NV 7.47 7.46 7.40 7.79 7.87 7.78 7.94 8.00 Solids Total Dissolved (TDS) 500 344 316 349 343 362 371 369 348 390 Solids Total Suspended (TSS) NV NV 60 60 10 14 16 50 40 14 Carbon Dissolved Organic (DOC) 5 3.7 2.3 2 3 3.2 5.7 5.9 10.6 7.4 Oxygen Demand Biological (BOD) NV NV ----2< 2< 2< 3 Oxygen Demand Chemical (COD) NV NV ----91887 Total Phenolics NV NV < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 0.004 Chloride 250 126 47.9 49.7 42.4 41.1 34.9 34.8 41.4 41.7 Nitrogen Ammonia (NH3) & Ammonium (NH4) NV NV 0.76 0.78 0.82 0.92 0.71 0.66 0.61 0.65 Sulphate 500 257 40 66 70 93 69 75 94 100 Nitrogen Nitrite (NO2) 10.3 ----< 0.05< 0.05< 0.05< 0.05 Nitrogen Nitrate (NO3) 10 2.5 ----< 0.05< 0.05< 0.05< 0.05 Nitrogen Total Kjeldahl (TKN) NV NV ----0.90.70.80.9 Mercury 0.001 0.0003 ----< 0.00002 < 0.00002 < 0.00002 < 0.00002
Hardness (as CaCO3 ) 500 339 289 254 298 - 291 335 317 330 Aluminum 0.1 0.06 0.03 0.03 0.05 0.03 0.02 0.08 0.05 0.07 Antimony 0.006 0.0016 - < 0.0001 < 0.0001 < 0.0001 < 0.0001 0.0002 < 0.0001 < 0.0001 Arsenic 0.025 0.0064 0.0002 0.0002 < 0.0001 0.0002 0.0002 0.0002 < 0.0001 < 0.0001 Beryllium NV NV - < 0.002 < 0.0001 < 0.002 < 0.0001 < 0.0001 < 0.002 < 0.002 Boron 5.0 1.25 0.011 0.034 0.028 0.052 0.037 0.065 0.044 0.056 Cadmium 0.005 0.0013 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.000014 < 0.000014 < 0.000015 < 0.000015 Calcium NV NV 90.9 78.8 92.2 91.9 89.6 102 98.4 100 Chromium 0.05 0.014 < 0.002 < 0.002 < 0.002 < 0.002 < 0.001 < 0.001 0.003 < 0.001 Cobalt NV NV - < 0.005 < 0.0001 < 0.0001 < 0.0001 < 0.0001 < 0.0001 < 0.0001 Copper 1.0 0.5 < 0.0001 - < 0.0001 0.0003 < 0.0001 0.0003 0.0004 < 0.0001 Iron 0.30 0.155 18.913.711.18.216.775.044.193.51 Lead 0.01 0.0025 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 0.00003 < 0.00002 Magnesium NV NV 15 13.8 16.4 15.6 16.2 19.4 17.3 19.5 Manganese 0.05 0.071 0.493 0.4 < 0.0001 0.373 0.237 0.358 0.318 0.338 Molybdenum NV NV - < 0.01 0.404 0.0004 0.0004 0.0005 0.0005 0.0005 Nickel NV NV < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 Phosphorus Total NV NV < 0.1 < 0.1 < 0.1 < 0.01 < 0.1 < 0.1 0.07 0.03 Potassium NV NV 2.3 1.6 1.4 1.6 1.5 3.6 2.7 3.3 Selenium 0.010 0.0033 - < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 Silver NV NV - < 0.00002 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium 200 102 11.4 15.3 21.4 22.7 19.0 24.7 21.2 24.2 Thallium NV NV - - < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten NV NV - - < 0.01 - - < 0.01 0.06 < 0.01 Uranium 0.02 0.005 - < 0.00005 < 0.00005 < 0.00005 0.00007 0.00009 0.00014 0.00012 Vanadium NV NV - < 0.005 < 0.005 0.008 < 0.005 < 0.005 0.005 < 0.005 Zinc 5 2.5 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 0.005 < 0.005 < 0.005 Zirconium NV NV - - < 0.003 - - < 0.003 < 0.003 < 0.003 Conductivity (µs/cm)4 NV NV 600 690 640 650 640 670 700 790 pH (units)4 6.5 - 8.5 NV 6.45 6.94 6.81 7.23 7.38 7.22 - 7.50 Temperature (°C)4 NV NV 13.8 8.2 11.8 15.4 9.7 17.2 10.8 11.1 Oxidation Reduction Potential (mV)4 NV NV 58 28 78 88 154 146 78 177 Dissolved Oxygen4 NV NV 1.61 5.03 6.18 2.90 3.64 6.90 7.07 1.57 Notes: 1. Results expressed in mg/L unless otherwise stated 2. ODWQS means Ontario Drinking Water Quality Standards 3. RUC means Reasonable Use Concept 4. Results from field analysis Bold text and shading indicates values exceeding ODWQS Bold text indicates values exceeding the RUC NV indicates No Value "" denotes parameter not analysed 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 3: Summary of Groundwater Quality
MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 Parameter ODWQS 2 RUC 3 8-Dec-09 13-Apr-10 8-Oct-10 1-Jun-11 3-Nov-11 30-Apr-12 28-Nov-12 16-May-13 30-Oct-13 23-Jun-14 18-Nov-14
Alkalinity (CaCO3) 500 332 838 951 886 902 952 825 978 896 554 557 438
Bicarbonate (CaCO3) NV NV ------Colour (TCU) 5 3.5 ------14 Conductivity (µs/cm) NV NV 2530 2770 2610 2610 2690 2490 2630 2250 1470 1230 923 pH (units) 6.5 - 8.5 NV 6.98 7.86 7.86 7.62 7.93 7.62 8.05 7.60 7.48 7.46 7.39 Solids Total Dissolved (TDS) 500 344 1390 1520 1440 1440 1480 1370 1450 1240 810 674 508 Solids Total Suspended (TSS) NV NV 37000 19500 5730 3760 2450 2480 2660 2070 1270 3400 570 Carbon Dissolved Organic (DOC) 5 3.7 22 16.6 22.7 41.6 56.6 48.5 58.3 20.9 17.4 16 26.4 Oxygen Demand Biological (BOD) NV NV 3728> 247111127438 Oxygen Demand Chemical (COD) NV NV 769 1220 536 521 747 336 165 308 191 165 78 Total Phenolics NV NV 0.006 - < 0.001 - 0.009 - 0.005 - < 0.001 - 0.003 Chloride 250 126 267 290 278 144 252 268 227 165 67.8 50.1 25.5 Nitrogen Ammonia (NH3) & Ammonium (NH4) NV NV 59.5 60 108 77 84 69.4 81.7 48.5 27.4 21.5 12.8 Sulphate 500 257 12655< 1535476< 1 Nitrogen Nitrite (NO2) 10.3< 0.1 - < 0.5 - < 0.1 - < 0.1 - < 0.1 - < 0.1 Nitrogen Nitrate (NO3) 10 2.5 < 0.1 < 0.1 < 0.1 0.1 < 0.1 < 0.1 < 0.1 < 0.1 0.2 < 0.1 < 0.1 Nitrogen Total Kjeldahl (TKN) NV NV 150 - 108 - 102 - 82 - 34.5 - 13.5 Mercury 0.001 0.0003 < 0.00002 - < 0.00002 - 0.00006 - < 0.00002 - < 0.00002 - < 0.00002
Hardness (as CaCO3 ) 500 339 385 332 380 404 301 518 264 430 310 322 - Aluminum 0.1 0.06 ------Antimony 0.006 0.0016 ------Arsenic 0.025 0.0064 0.0078 - 0.0047 - 0.0057 - 0.0061 - 0.0049 - - Beryllium NV NV ------Boron 5.0 1.25 1.08 1.37 1.15 0.952 1.25 0.639 1.06 1.4 0.82 0.757 0.589 Cadmium 0.005 0.0013 < 0.00002 - < 0.00002 - 0.00004 - 0.00003 - < 0.00002 - - Calcium NV NV 98.2 70.7 87.7 97.6 60.9 130 50.7 95.3 78.7 81.9 91.5 Chromium 0.05 0.014 0.004 - 0.002 - 0.003 - 0.003 - 0.002 - - Cobalt NV NV ------Copper 1.0 0.5 < 0.002 - < 0.002 - 0.002 - < 0.002 - < 0.002 - - Iron 0.30 0.155 18.5 0.11 14.7 19.4 9.12 23.1 7.05 23.2 42.7 47.4 53.6 Lead 0.01 0.0025 < 0.00002 - 0.00014 - 0.00013 - 0.00005 - 0.00009 - - Magnesium NV NV 33.9 37.8 39.1 38.8 36.3 47.1 33.5 46.6 27.6 28.4 19.6 Manganese 0.05 0.071 0.971 0.49 0.986 1.29 0.429 2.12 0.368 0.713 1.1 1.16 1.43 Molybdenum NV NV ------Nickel NV NV ------Phosphorus Total NV NV 7.5 - 3.5 - 0.1 - 0.9 - 1.86 - 0.45 Potassium NV NV 136 167 144 139 152 119 160 124 56.4 48.5 25.9 Selenium 0.010 0.0033 ------Silver NV NV ------Sodium 200 102 270 284 225 203 257 167 271 216 90.7 75.1 38 Thallium NV NV ------Tungsten NV NV ------Uranium 0.02 0.005 ------Vanadium NV NV ------Zinc 5 2.5 0.01 - 0.007 - 0.012 - < 0.005 - 0.011 - - Zirconium NV NV ------Conductivity (µs/cm)4 NV NV 2309 2632 - 2295 2103 2155 2490 1505 1656 1122 631 pH (units)4 6.5 - 8.5 NV 8.59 8.56 - 7.26 7.07 6.41 7.40 7.45 5.89 7.39 6.53 Temperature (°C)4 NV NV 13 15.2 - 17.9 10.5 13.3 7.9 6.3 11.6 14.6 7.3 Oxidation Reduction Potential (mV)4 NV NV ------Dissolved Oxygen4 NV NV ------Notes: 1. Results expressed in mg/L unless otherwise stated 2. ODWQS means Ontario Drinking Water Quality Standards 3. RUC means Reasonable Use Concept 4. Results from field analysis Bold text and shading indicates values exceeding ODWQS Bold text indicates values exceeding the RUC NV indicates No Value "" denotes parameter not analysed 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 3: Summary of Groundwater Quality
MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 Parameter ODWQS 2 RUC 3 25-May-15 9-Nov-15 19-Apr-16 5-Oct-16 3-May-17 18-Sep-17 22-May-18 1-Nov-18
Alkalinity (CaCO3) 500 332 409 423 377 330 451 403 323 396
Bicarbonate (CaCO3) NV NV - 423 377 330 451 403 323 396 Colour (TCU) 5 3.5 12 12 15 11 14 22 16 33 Conductivity (µs/cm) NV NV 932 909 913 762 1080 899 725 950 pH (units) 6.5 - 8.5 NV 7.41 7.28 7.20 7.54 7.48 7.37 7.61 7.70 Solids Total Dissolved (TDS) 500 344 513 500 502 419 594 494 378 505 Solids Total Suspended (TSS) NV NV 8700 2000 5350 3300 3150 1700 1500 840 Carbon Dissolved Organic (DOC) 5 3.7 16.9 1 16.2 13.1 7.3 15.1 21.9 18.4 Oxygen Demand Biological (BOD) NV NV 30 150 8 15 22 11 >16.5 15 Oxygen Demand Chemical (COD) NV NV 215 181 659 322 295 273 121 230 Total Phenolics NV NV < 0.001 < 0.001 < 0.001 0.003 0.004 0.001 < 0.001 0.016 Chloride 250 126 32.9 26.8 93.4 28.3 53.3 37.1 33.6 55.2 Nitrogen Ammonia (NH3) & Ammonium (NH4) NV NV 14.3 13.8 17.3 15.3 17.6 12.6 12.6 16.9 Sulphate 500 257 1316651< 1< 1 Nitrogen Nitrite (NO2) 10.3< 0.1 < 0.1 < 0.1 < 0.1 < 0.05 < 0.05 < 0.05 < 0.05 Nitrogen Nitrate (NO3) 10 2.5 < 0.1 < 0.1 < 0.1 0.1 < 0.05 < 0.05 < 0.05 < 0.05 Nitrogen Total Kjeldahl (TKN) NV NV 19.2 16.9 32.7 21 19.3 24.9 14.8 22.3 Mercury 0.001 0.0003 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002
Hardness (as CaCO3 ) 500 339 232 295 270 - 325 335 248 271 Aluminum 0.1 0.06 0.03 0.04 0.03 0.03 0.03 0.08 0.05 0.06 Antimony 0.006 0.0016 - 0.0002 < 0.0001 0.0002 0.0002 0.0002 0.0001 0.0001 Arsenic 0.025 0.0064 0.0013 0.0011 0.0134 0.0012 0.0035 0.0009 0.0016 0.0009 Beryllium NV NV - < 0.002 < 0.0001 < 0.002 < 0.0001 < 0.0001 < 0.002 < 0.002 Boron 5.0 1.25 0.466 0.514 0.422 0.453 0.527 0.625 0.36 0.538 Cadmium 0.005 0.0013 0.00002 0.00002 0.00003 < 0.00002 < 0.000014 < 0.000014 < 0.000015 < 0.000015 Calcium NV NV 65 88.3 81.1 73.6 97.7 102 76 81.6 Chromium 0.05 0.014 < 0.002 < 0.002 < 0.002 < 0.002 < 0.001 < 0.001 0.007 0.002 Cobalt NV NV - < 0.005 0.0077 0.0002 0.0004 0.0003 0.0003 0.0004 Copper 1.0 0.5 < 0.002 - 0.0027 0.0001 0.0006 0.0004 0.0004 < 0.0001 Iron 0.30 0.155 0.263 56.2 42.8 37.7 - 42.5 32.9 26.9 Lead 0.01 0.0025 0.00006 0.00009 < 0.00002 < 0.00002 < 0.00002 0.00003 0.00003 < 0.00002 Magnesium NV NV 17 18 16.3 16.1 19.6 19.5 14 16.3 Manganese 0.05 0.071 0.704 1.62 0.0004 0.982 0.72 1.3 1.01 0.799 Molybdenum NV NV - < 0.01 1.47 0.0002 0.0003 0.0002 0.0002 0.0001 Nickel NV NV < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 Phosphorus Total NV NV < 0.1 0.1 < 0.1 1.69 < 0.1 0.1 0.81 0.9 Potassium NV NV 32.3 21.5 29.5 24.1 44.3 34.3 26.6 43.6 Selenium 0.010 0.0033 - < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.0001 < 0.001 Silver NV NV - < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.001 < 0.0001 Sodium 200 102 49.5 32.3 55.6 39.2 94.3 56.4 43.8 80.6 Thallium NV NV - - < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten NV NV - - 0.04 - - < 0.01 0.12 0.02 Uranium 0.02 0.005 - < 0.00005 0.00073 < 0.00005 0.00009 0.00012 < 0.00005 < 0.00005 Vanadium NV NV - 0.006 < 0.005 < 0.005 < 0.005 < 0.005 0.011 < 0.005 Zinc 5 2.5 < 0.003 0.017 0.011 0.007 < 0.005 < 0.005 < 0.005 < 0.005 Zirconium NV NV - - < 0.003 - - < 0.003 < 0.003 < 0.003 Conductivity (µs/cm)4 NV NV 990 1040 910 870 1200 1040 870 1030 pH (units)4 6.5 - 8.5 NV 7.37 6.88 6.82 7.35 7.14 7.00 - 6.97 Temperature (°C)4 NV NV 12 9.7 13.3 14.0 12.2 14.2 11.6 10.3 Oxidation Reduction Potential (mV)4 NV NV 134 70 95 135 189 138 -3 211 Dissolved Oxygen4 NV NV 2.01 4.11 5.29 2.20 6.47 3.00 1.08 0.85 Notes: 1. Results expressed in mg/L unless otherwise stated 2. ODWQS means Ontario Drinking Water Quality Standards 3. RUC means Reasonable Use Concept 4. Results from field analysis Bold text and shading indicates values exceeding ODWQS Bold text indicates values exceeding the RUC NV indicates No Value "" denotes parameter not analysed 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 3: Summary of Groundwater Quality
MW5 MW5 MW5 MW5 MW5 MW5 MW5 MW5 MW5 MW5 MW5 Parameter ODWQS 2 RUC 3 30-Oct-13 23-Jun-14 18-Nov-14 25-May-15 09-Nov-15 19-Apr-16 05-Oct-16 03-May-17 18-Sep-17 22-May-18 01-Nov-18
Alkalinity (CaCO3) 500 332 168 154 171 161 175 160 177 141 164 153 196
Bicarbonate (CaCO3) NV NV ----175160177141164153196 Colour (TCU) 5 3.5 --< 2< 24 < 2 < 2 4 < 2 7 < 2 Conductivity (µs/cm) NV NV 455 338 369 355 384 337 384 296 342 323 355 pH (units) 6.5 - 8.5 NV 8.07 7.97 7.99 7.95 7.96 7.75 8.05 7.84 7.98 8.01 8.01 Solids Total Dissolved (TDS) 500 344 250 186 203 195 211 185 211 163 188 166 183 Solids Total Suspended (TSS) NV NV 8000 2080 9150 7300 5400 9900 32500 128 720 2800 1120 Carbon Dissolved Organic (DOC) 5 3.7 4.4 2.1 2.4 1.1 < 0.2 0.9 0.7 2.4 4.3 4.2 2.3 Oxygen Demand Biological (BOD) NV NV < 2< 2-----3< 2< 2< 3 Oxygen Demand Chemical (COD) NV NV 34889-----444822< 5 Total Phenolics NV NV < 0.001 - < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 0.002 Chloride 250 126 5 1.6 1.4 2.5 2.4 3.3 2.8 1.7 1.3 1.9 1.5 Nitrogen Ammonia (NH3) & Ammonium (NH4) NV NV 0.295 0.08 0.01 0.1 0.04 0.06 0.07 < 0.01 0.13 0.05 0.04 Sulphate 500 257 68 14 19 24 18 14 18 11 11 12 14 Nitrogen Nitrite (NO2) 10.3< 0.1------< 0.05< 0.05< 0.05< 0.05 Nitrogen Nitrate (NO3) 10 2.5 < 0.1< 0.1-----< 0.05< 0.05< 0.05< 0.05 Nitrogen Total Kjeldahl (TKN) NV NV 0.2------0.30.20.30.1 Mercury 0.001 0.0003 < 0.00002 ------< 0.00002 < 0.00002 < 0.00002 < 0.00002
Hardness (as CaCO3 ) 500 339 248 176 - 204 169 178 - 139 187 160 178 Aluminum 0.1 0.06 - - - 0.02 0.02 0.02 0.02 0.01 0.04 0.04 0.03 Antimony 0.006 0.0016 ----0.0001 < 0.0001 0.0003 < 0.0001 < 0.0001 < 0.0001 < 0.0001 Arsenic 0.025 0.0064 0.0002 - - 0.0015 0.0002 < 0.0001 0.0007 0.0001 < 0.0001 < 0.0001 0.0002 Beryllium NV NV ----< 0.002< 0.0001 < 0.002 < 0.0001 < 0.0001 < 0.002 < 0.002 Boron 5.0 1.25 0.041 0.011 0.01 < 0.005 0.005 < 0.005 0.011 < 0.005 0.007 < 0.005 < 0.005 Cadmium 0.005 0.0013 0.00003 - - < 0.00002 0.00002 < 0.00002 < 0.00002 < 0.000014 < 0.000014 < 0.000015 < 0.000015 Calcium NV NV 65.1 50.1 49.5 55.1 48.8 52.1 56.4 40.8 54.9 47.2 50.8 Chromium 0.05 0.014 < 0.002 - - < 0.002 < 0.002 < 0.002 < 0.002 < 0.001 < 0.001 0.002 < 0.001 Cobalt NV NV ----< 0.005< 0.0001 0.0002 < 0.0001 < 0.0001 < 0.0001 < 0.0001 Copper 1.0 0.5 < 0.002 - - < 0.002 - < 0.0001 0.0002 0.0013 0.0007 0.0011 0.0006 Iron 0.30 0.155 0.014 < 0.005 0.032 0.259 0.009 0.01 0.025 < 0.005 < 0.005 0.008 0.009 Lead 0.01 0.0025 < 0.00002 - - < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 Magnesium NV NV 20.7 12.3 12.8 16.2 11.4 11.7 14.2 8.95 12.2 10.3 12.5 Manganese 0.05 0.071 0.504 0.117 0.105 0.288 0.043 < 0.0001 0.216 0.0306 0.006 0.05 0.071 Molybdenum NV NV ----< 0.010.0230.0039 0.0004 0.0009 0.0007 0.0013 Nickel NV NV - - - < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 Phosphorus Total NV NV 11.9 - 2.65 < 0.1 < 0.1 < 0.1 1.84 < 0.1 < 0.1 0.98 0.36 Potassium NV NV 1.4 - 1.4 1.7 1.2 1.3 1.4 1.1 1.4 1.1 1.2 Selenium 0.010 0.0033 ----< 0.001< 0.001< 0.001< 0.001< 0.001< 0.001< 0.001 Silver NV NV ----< 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium 200 102 6.7 4 5.4 5.5 3.2 6.0 5.0 2.8 4.0 3.2 3.0 Thallium NV NV -----< 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten NV NV -----< 0.01--< 0.01< 0.01< 0.01 Uranium 0.02 0.005 ----0.00012 < 0.00005 0.00028 0.00006 0.0001 0.00013 0.00016 Vanadium NV NV ----< 0.005< 0.005< 0.005< 0.005< 0.005< 0.005< 0.005 Zinc 5 2.5 < 0.005 - - < 0.003 0.013 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Zirconium NV NV -----< 0.003--< 0.003< 0.003< 0.003 Conductivity (µs/cm)4 NV NV 279 259 224 370 380 370 400 290 340 310 370 pH (units)4 6.5 - 8.5 NV 6.93 8.80 7.00 7.42 7.22 7.67 7.54 7.57 7.74 - 7.58 Temperature (°C)4 NV NV 7.3 9.3 5.6 8.7 8 9.4 10.6 10.1 12.3 8.5 8.0 Oxidation Reduction Potential (mV)4 NV NV - - - 88 55 34 120 136 44 26 159 Dissolved Oxygen4 NV NV - - - 4.46 8.17 5.66 6.19 6.69 9.29 4.39 7.71 Notes: 1. Results expressed in mg/L unless otherwise stated 2. ODWQS means Ontario Drinking Water Quality Standards 3. RUC means Reasonable Use Concept 4. Results from field analysis Bold text and shading indicates values exceeding ODWQS Bold text indicates values exceeding the RUC NV indicates No Value "" denotes parameter not analysed 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.:7215-007
Table 4: Summary of Groundwater Quality - PWQO
DP2 DP2 DP2 DP2 DP2 DP2 DP2 DP2 DP2 DP2 Parameter PWQO 2 CWQG 8-Dec-09 13-Apr-10 8-Oct-10 1-Jun-11 3-Nov-11 30-Apr-12 28-Nov-12 16-May-13 23-Jun-14 25-May-15
Alkalinity (CaCO3) decrease >25% NV 204 224 187 176 180 179 - 179 177 178
Bicarbonate (CaCO3) NVNV------Colour (TCU) NV NV ------5 Conductivity (µs/cm) NV NV 479 459 401 359 374 353 377 352 353 353 pH (units) 6.5-8.5 NV 7.08 7.52 7.68 7.88 7.76 7.99 7.67 7.82 7.86 8.02 Solids - Total Dissolved (TDS) NV NV 264 252 221 197 206 194 207 194 194 194 Solids - Total Suspended (TSS) NV NV 77900 2020 400 432 364 82 236 64 76 88 Carbon - Dissolved Organic (DOC) NV NV 7.4 2.9 4.6 3.6 1.8 1.6 10.5 1.8 17.9 2 Oxygen Demand - Biological (BOD) NV NV 20 14 6386< 2< 2< 2- Oxygen Demand - Chemical (COD) NV NV 24 49 31 12 164 9 < 5 < 5 39 - Total - Phenolics NV NV < 0.001 - < 0.001 - < 0.001 - < 0.001 - - < 0.001 Chloride NV 120 24 8.4 5 < 1 5.1 1.7 1.9 1.4 15.4 3.2
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 1.01 1.15 0.61 0.57 1.18 0.749 0.38 0.478 0.62 0.45 Sulphate NV NV 5 < 1 < 1 1 < 1 < 1 < 1 < 1 1 1
Nitrogen - Nitrite (NO2) NV 0.06 < 0.1 - < 0.1 - < 0.1 - < 0.1 - - -
Nitrogen - Nitrate (NO3) NV 13 < 0.1 0.1 < 0.1 0.1 < 0.1 < 0.1 < 0.1 0.1 < 0.1 - Nitrogen - Total Kjeldahl (TKN) NV NV 4 - 0.7 - 0.72 - 1.2 - - - Mercury 0.0002 NV < 0.00002 - < 0.00002 - 0.00003 - < 0.00002 - - - Aluminum 0.075 NV ------0.02 Antimony 0.02 NV ------Arsenic 0.005 NV < 0.0001 - 0.0001 - 0.0002 - 0.0001 - - < 0.0001 Beryllium 0.011 NV ------Boron 0.2 NV 0.016 0.027 0.171 0.029 < 0.005 0.01 0.019 0.01 0.037 < 0.005 Cadmium 0.0001 NV < 0.00002 - < 0.00002 - 0.00004 - < 0.00002 - - < 0.00002 Calcium NV NV 62.5 57.3 62.1 54.7 57 55.4 46.5 54.5 52.1 59.7 Chromium 0.001 NV < 0.002 - < 0.002 - < 0.002 - < 0.002 - - < 0.002 Cobalt 0.0009 NV ------Copper 0.005 NV < 0.002 - < 0.002 - < 0.002 - < 0.002 - - 0.0007 Iron 0.30 NV 0.998 2.57 2.65 1.33 0.975 0.631 0.758 0.748 14.9 1.36 Lead 0.003 NV < 0.00002 - 0.00007 - 0.00011 - 0.00015 - - < 0.00002 Magnesium NV NV 10.6 9.73 11.6 9.08 9.16 8.93 7.71 9.08 9.46 9.86 Manganese NV NV 0.164 1.13 0.654 0.676 0.257 0.17 0.147 0.149 2.23 0.334 Molybdenum 0.04 NV ------Nickel 0.025 NV ------< 0.01 Phosphorus - Total 0.03 NV 8.55 - 0.34 - < 0.01 - 0.08 - - < 0.1 Potassium NV NV 4.9 2.9 9 2.6 2.8 2.7 2.3 2.5 4.4 2.8 Selenium 0.1 NV ------Silver 0.0001 NV ------Sodium NV NV 13.6 3.6 13.2 2.7 3.4 2.8 2.5 3.1 11.6 4.4 Thallium 0.0003 NV ------Tungsten 0.03 NV ------Uranium 0.005 NV ------Vanadium 0.006 NV ------Zinc 0.02 NV 0.009 - 0.035 - 0.043 - < 0.005 - - 0.006 Zirconium 0.004 NV ------Conductivity (µs/cm)4 NV NV 380 330 - 364 378 306 350 297 280 400 pH (units)4 6.5 - 8.5 NV 7.91 7.23 - 7.14 7.19 6.83 7.55 7.45 7.83 7.42 Temperature (°C)4 NV NV 8.4 12 - 17.8 9.5 9 7.5 4.6 11.5 13.4 Oxidation Reduction Potential (mV)4 NVNV------38 Dissolved Oxygen4 5.0NV------2.39 Notes: 1. Results expressed in mg/L unless otherwise stated 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines. 4. Results from field analysis 5. Bold text and shading indicates values exceeding PWQO or CWQG. 6. "-" parameter not analyzed. 7. NV indicates No Value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.:7215-007
Table 4: Summary of Groundwater Quality - PWQO
DP3 DP3 DP3 DP3 DP3 DP3 DP3 DP3 Parameter PWQO 2 CWQG 8-Dec-09 13-Apr-10 8-Oct-10 1-Jun-11 3-Nov-11 30-Apr-12 16-May-13 23-Jun-14
Alkalinity (CaCO3) decrease >25% NV 502 594 372 215 486 475 390 51
Bicarbonate (CaCO3) NV NV ------Colour (TCU) NV NV ------Conductivity (µs/cm) NV NV 1560 1750 1510 615 1260 1200 928 129 pH (units) 6.5-8.5 NV 7.37 7.84 7.97 7.69 7.78 7.69 7.39 7.57 Solids - Total Dissolved (TDS) NV NV 855 964 828 338 692 660 510 71 Solids - Total Suspended (TSS) NV NV 3250 2500 70 644 216 26 190 420 Carbon - Dissolved Organic (DOC) NV NV 63.3 23.2 23.9 29 56.2 - 45.5 18.3 Oxygen Demand - Biological (BOD) NV NV 12- 7 5 2323266 Oxygen Demand - Chemical (COD) NV NV 846 275 124 143 324 - 270 160 Total - Phenolics NV NV ------Chloride NV 120 162 183 93 45 86.6 - 48 3.7
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 13.4 12.8 9.2 5.3 < 0.05 7.78 11.6 1.95 Sulphate NV NV 1 < 1 3 1 1 - < 1 < 1
Nitrogen - Nitrite (NO2) NV 0.06 < 0.1 - 0.7 - 0.1 ---
Nitrogen - Nitrate (NO3) NV 13 0.1 0.1 0.2 0.3 1.9 - < 0.1 0.1 Nitrogen - Total Kjeldahl (TKN) NV NV 30 - 13.6 - 20.8 - - - Mercury 0.0002 NV < 0.00002 - 0.00107 ----- Aluminum 0.075 NV ------Antimony 0.02 NV ------Arsenic 0.005 NV 0.0041 - 0.0015 - 0.0027 - - - Beryllium 0.011 NV ------Boron 0.2 NV 1.03 1.14 0.829 0.454 1.62 - - 0.117 Cadmium 0.0001 NV 0.00035 - 0.00002 - 0.00003 - - - Calcium NV NV 45.9 51.3 30.4 17.6 33.2 - - 3.39 Chromium 0.001 NV 0.013 - 0.01 - 0.009 --- Cobalt 0.0009 NV ------Copper 0.005 NV 0.013 - 0.004 - 0.006 --- Iron 0.30 NV 1.95 1.5 5.54 1.35 1.95 --2.54 Lead 0.003 NV 0.0191 - 0.00179 - 0.00207 - - - Magnesium NV NV 7.35 7.76 4.84 2.83 4.97 - - 0.65 Manganese NV NV 0.434 0.409 0.284 0.204 0.321 - - 0.26 Molybdenum 0.04 NV ------Nickel 0.025 NV ------Phosphorus - Total 0.03 NV 4.8 - 0.08 - 0.81 --- Potassium NV NV 108 123 82.3 44.1 103 - - 8.9 Selenium 0.1 NV ------Silver 0.0001 NV ------Sodium NV NV 218 230 146 72.3 172 - - 6.8 Thallium 0.0003 NV ------Tungsten 0.03 NV ------Uranium 0.005 NV ------Vanadium 0.006 NV ------Zinc 0.02 NV 0.058 - 0.037 - 0.087 --- Zirconium 0.004 NV ------Conductivity (µs/cm)4 NV NV 1490 1706 - 564 1092 1029 630 120 pH (units)4 6.5 - 8.5 NV 7.20 6.43 - 7.36 7.32 6.57 6.85 7.78 Temperature (°C)4 NV NV 6.1 10.3 - 18.6 8.9 9.8 6.48 17.7 Oxidation Reduction Potential (mV)4 NV NV ------Dissolved Oxygen4 5.0 NV ------Notes: 1. Results expressed in mg/L unless otherwise stated 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines. 4. Results from field analysis 5. Bold text and shading indicates values exceeding PWQO or CWQG. 6. "-" parameter not analyzed. 7. NV indicates No Value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.:7215-007
Table 4: Summary of Groundwater Quality - PWQO
DP4 DP4 DP4 DP4 DP4 DP4 DP4 DP4 DP4 Parameter PWQO 2 CWQG 8-Dec-09 13-Apr-10 8-Oct-10 1-Jun-11 3-Nov-11 30-Apr-12 16-May-13 30-Oct-13 23-Jun-14
Alkalinity (CaCO3) decrease >25% NV 108 83 97 291 292 295 143 149 180
Bicarbonate (CaCO3) NV NV ------Colour (TCU) NV NV ------Conductivity (µs/cm) NV NV 265 189 215 894 892 917 363 380 537 pH (units) 6.5-8.5 NV 6.63 7.42 7.36 7.15 7.07 7.14 7.15 7.20 7.26 Solids - Total Dissolved (TDS) NV NV 146 104 118 492 491 504 200 209 295 Solids - Total Suspended (TSS) NV NV 3780 2800 80 335 175 24 52 52 24 Carbon - Dissolved Organic (DOC) NV NV 13.1 9.5 10.9 18.3 29.1 28.5 17.7 15.6 6.9 Oxygen Demand - Biological (BOD) NV NV 11882747< 22 Oxygen Demand - Chemical (COD) NV NV 59 21 39 128 90 81 33 37 49 Total - Phenolics NV NV < 0.001 - < 0.001 - < 0.001 - - < 0.001 - Chloride NV 120 11 5.3 7 104 109 116 23.9 23.7 54.8
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 1.78 1.01 1.2 1.59 1.73 1.69 1.63 1.46 1.54 Sulphate NV NV 16 < 1 < 1 < 1 2 < 1 < 1 < 1 13
Nitrogen - Nitrite (NO2) NV 0.06 < 0.1 - < 0.1 - < 0.1 - - < 0.1 -
Nitrogen - Nitrate (NO3) NV 13 < 0.1 0.1 < 0.1 < 0.1 0.5 < 0.1 0.1 < 0.1 < 0.1 Nitrogen - Total Kjeldahl (TKN) NV NV 6 - 1.6 - 4.23 - - 2.2 - Mercury 0.0002 NV < 0.00002 - < 0.00002 - 0.00003 - - < 0.00002 - Aluminum 0.075 NV ------Antimony 0.02 NV ------Arsenic 0.005 NV < 0.0001 - 0.0002 - 0.001 - - 0.0003 - Beryllium 0.011 NV ------Boron 0.2 NV 0.108 0.051 0.216 0.638 0.572 0.436 0.226 0.316 0.213 Cadmium 0.0001 NV < 0.00002 - 0.00003 - 0.00004 - - < 0.00002 - Calcium NV NV 19 18.9 11 64.8 68.9 66.8 27.2 19 52.7 Chromium 0.001 NV 0.003 - 0.002 - 0.005 --0.003 - Cobalt 0.0009 NV ------Copper 0.005 NV < 0.002 - 0.002 - < 0.002 - - < 0.002 - Iron 0.30 NV 7 6.31 8.74 18.7 23.3 21.7 8.79 9.62 17.4 Lead 0.003 NV < 0.00002 - 0.00019 - 0.00013 - - 0.0001 - Magnesium NV NV 3.3 3.19 2.27 10.9 10.9 10.8 4.31 3.59 8.72 Manganese NV NV 0.147 0.135 0.197 0.487 0.487 0.457 0.188 0.209 0.361 Molybdenum 0.04 NV ------Nickel 0.025 NV ------Phosphorus - Total 0.03 NV 4.6 - 0.1 - < 0.01 - - < 0.01 - Potassium NV NV 2.8 2.1 1.5 2.8 3.3 3 2.8 3.2 - Selenium 0.1 NV ------Silver 0.0001 NV ------Sodium NV NV 25.1 13.8 12.1 102 121 121 47.4 46.6 47.8 Thallium 0.0003 NV ------Tungsten 0.03 NV ------Uranium 0.005 NV ------Vanadium 0.006 NV ------Zinc 0.02 NV 0.009 - 0.011 - 0.033 --0.035 - Zirconium 0.004 NV ------Conductivity (µs/cm)4 NV NV 252 210 - 873 826 831 258 280 456 pH (units)4 6.5 - 8.5 NV 7.10 6.92 - 6.41 6.81 5.81 6.80 6.21 6.98 Temperature (°C)4 NV NV 8.3 10.3 - 16.5 10.1 9.4 3.7 9.4 12.9 Oxidation Reduction Potential (mV)4 NV NV ------Dissolved Oxygen4 5.0 NV ------Notes: 1. Results expressed in mg/L unless otherwise stated 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines. 4. Results from field analysis 5. Bold text and shading indicates values exceeding PWQO or CWQG. 6. "-" parameter not analyzed. 7. NV indicates No Value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.:7215-007
Table 4: Summary of Groundwater Quality - PWQO
DP4 DP4 DP4 DP4 DP4 DP4 DP4 DP4 Parameter PWQO 2 CWQG 25-May-15 9-Nov-15 19-Apr-16 5-Oct-16 3-May-17 18-Sep-17 22-May-18 1-Nov-18
Alkalinity (CaCO3) decrease >25% NV 177 179 192 180 200 193 195 225
Bicarbonate (CaCO3) NV NV - 179 192 180 200 193 195 225 Colour (TCU) NV NV 4344166127 Conductivity (µs/cm) NV NV 575 635 623 658 674 671 671 747 pH (units) 6.5-8.5 NV 7.47 7.46 7.40 7.79 7.87 7.78 7.94 8.00 Solids - Total Dissolved (TDS) NV NV 316 349 343 362 371 369 348 390 Solids - Total Suspended (TSS) NV NV 60 60 10 14 16 50 40 14 Carbon - Dissolved Organic (DOC) NV NV 2.3 2 3 3.2 5.7 5.9 10.6 7.4 Oxygen Demand - Biological (BOD) NV NV ----2< 2< 2< 3 Oxygen Demand - Chemical (COD) NV NV ----91887 Total - Phenolics NV NV < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 0.004 Chloride NV 120 47.9 49.7 42.4 41.1 34.9 34.8 41.4 41.7
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.76 0.78 0.82 0.92 0.71 0.66 0.61 0.65 Sulphate NV NV 40 66 70 93 69 75 94 100
Nitrogen - Nitrite (NO2) NV 0.06 ----< 0.05 < 0.05 < 0.05 < 0.05
Nitrogen - Nitrate (NO3) NV 13 ----< 0.05 < 0.05 < 0.05 < 0.05 Nitrogen - Total Kjeldahl (TKN) NV NV ----0.90.70.80.9 Mercury 0.0002 NV ----< 0.00002 < 0.00002 < 0.00002 < 0.00002 Aluminum 0.075 NV 0.03 0.03 0.05 0.03 0.02 0.08 0.05 0.07 Antimony 0.02 NV - < 0.0001 < 0.0001 < 0.0001 < 0.0001 0.0002 < 0.0001 < 0.0001 Arsenic 0.005 NV 0.0002 0.0002 < 0.0001 0.0002 0.0002 0.0002 < 0.0001 < 0.0001 Beryllium 0.011 NV - < 0.002 < 0.0001 < 0.002 < 0.0001 < 0.0001 < 0.002 < 0.002 Boron 0.2 NV 0.011 0.034 0.028 0.052 0.037 0.065 0.044 0.056 Cadmium 0.0001 NV < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.000014 < 0.000014 < 0.000015 < 0.000015 Calcium NV NV 90.9 78.8 92.2 91.9 89.6 102 98.4 100 Chromium 0.001 NV < 0.002 < 0.002 < 0.002 < 0.002 < 0.001 < 0.001 0.003 < 0.001 Cobalt 0.0009 NV - < 0.005 < 0.0001 < 0.0001 < 0.0001 < 0.0001 < 0.0001 < 0.0001 Copper 0.005 NV < 0.0001 - < 0.0001 0.0003 < 0.0001 0.0003 0.0004 < 0.0001 Iron 0.30 NV 18.9 13.7 11.1 8.21 6.77 5.04 4.19 3.51 Lead 0.003 NV < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 0.00003 < 0.00002 Magnesium NV NV 15 13.8 16.4 15.6 16.2 19.4 17.3 19.5 Manganese NV NV 0.493 0.4 < 0.0001 0.373 0.237 0.358 0.318 0.338 Molybdenum 0.04 NV - < 0.01 0.404 0.0004 0.0004 0.0005 0.0005 0.0005 Nickel 0.025 NV < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 Phosphorus - Total 0.03 NV < 0.1 < 0.1 < 0.1 < 0.01 < 0.1 < 0.1 0.07 0.03 Potassium NV NV 2.3 1.6 1.4 1.6 1.5 3.6 2.7 3.3 Selenium 0.1 NV - < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 Silver 0.0001 NV - < 0.00002 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium NV NV 11.4 15.3 21.4 22.7 19 24.7 21.2 24.2 Thallium 0.0003 NV - - < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten 0.03 NV - - < 0.01 - - < 0.01 0.06 < 0.01 Uranium 0.005 NV - < 0.00005 < 0.00005 < 0.00005 0.00007 0.00009 0.00014 0.00012 Vanadium 0.006 NV - < 0.005 < 0.005 0.008 < 0.005 < 0.005 0.005 < 0.005 Zinc 0.02 NV < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 0.005 < 0.005 < 0.005 Zirconium 0.004 NV - - < 0.003 - - < 0.003 < 0.003 < 0.003 Conductivity (µs/cm)4 NV NV 600 690 640 650 640 670 700 790 pH (units)4 6.5 - 8.5 NV 6.45 6.94 6.81 7.23 7.38 7.22 - 7.50 Temperature (°C)4 NV NV 13.8 8.2 11.8 15.4 9.7 17.2 10.8 11.1 Oxidation Reduction Potential (mV)4 NV NV -58 -28 -78 -88 154 146 78 177 Dissolved Oxygen4 5.0 NV 1.61 5.03 6.18 2.90 3.64 6.90 7.07 1.57 Notes: 1. Results expressed in mg/L unless otherwise stated 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines. 4. Results from field analysis 5. Bold text and shading indicates values exceeding PWQO or CWQG. 6. "-" parameter not analyzed. 7. NV indicates No Value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.:7215-007
Table 4: Summary of Groundwater Quality - PWQO
MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 Parameter PWQO 2 CWQG 8-Dec-09 13-Apr-10 8-Oct-10 1-Jun-11 3-Nov-11 30-Apr-12 28-Nov-12 16-May-13 30-Oct-13 23-Jun-14 18-Nov-14
Alkalinity (CaCO3) decrease >25% NV 838 951 886 902 952 825 978 896 554 557 438
Bicarbonate (CaCO3) NV NV ------Colour (TCU) NV NV ------14 Conductivity (µs/cm) NV NV 2530 2770 2610 2610 2690 2490 2630 2250 1470 1230 923 pH (units) 6.5-8.5 NV 6.98 7.86 7.86 7.62 7.93 7.62 8.05 7.60 7.48 7.46 7.39 Solids - Total Dissolved (TDS) NV NV 1390 1520 1440 1440 1480 1370 1450 1240 810 674 508 Solids - Total Suspended (TSS) NV NV 37000 19500 5730 3760 2450 2480 2660 2070 1270 3400 570 Carbon - Dissolved Organic (DOC) NV NV 22 16.6 22.7 41.6 56.6 48.5 58.3 20.9 17.4 16 26.4 Oxygen Demand - Biological (BOD) NV NV 3728> 247111127438 Oxygen Demand - Chemical (COD) NV NV 769 1220 536 521 747 336 165 308 191 165 78 Total - Phenolics NV NV 0.006 - < 0.001 - 0.009 - 0.005 - < 0.001 - 0.003 Chloride NV 120 267 290 278 144 252 268 227 165 67.8 50.1 25.5
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 59.5 60 108 77 84 69.4 81.7 48.5 27.4 21.5 12.8 Sulphate NV NV 12 6 5 5 < 1 5 3 54 7 6 < 1
Nitrogen - Nitrite (NO2) NV 0.06 < 0.1 - < 0.5 - < 0.1 - < 0.1 - < 0.1 - < 0.1
Nitrogen - Nitrate (NO3) NV 13 < 0.1 < 0.1 < 0.1 0.1 < 0.1 < 0.1 < 0.1 < 0.1 0.2 < 0.1 < 0.1 Nitrogen - Total Kjeldahl (TKN) NV NV 150 - 108 - 102 - 82 - 34.5 - 13.5 Mercury 0.0002 NV < 0.00002 - < 0.00002 - 0.00006 - < 0.00002 - < 0.00002 - < 0.00002 Aluminum 0.075 NV ------Antimony 0.02 NV ------Arsenic 0.005 NV 0.0078 - 0.0047 - 0.0057 - 0.0061 - 0.0049 - - Beryllium 0.011 NV ------Boron 0.2 NV 1.08 1.37 1.15 0.952 1.25 0.639 1.06 1.4 0.82 0.757 0.589 Cadmium 0.0001 NV < 0.00002 - < 0.00002 - 0.00004 - 0.00003 - < 0.00002 - - Calcium NV NV 98.2 70.7 87.7 97.6 60.9 130 50.7 95.3 78.7 81.9 91.5 Chromium 0.001 NV 0.004 - 0.002 - 0.003 - 0.003 - 0.002 -- Cobalt 0.0009 NV ------Copper 0.005 NV < 0.002 - < 0.002 - 0.002 - < 0.002 - < 0.002 - - Iron 0.30 NV 18.5 0.11 14.7 19.4 9.12 23.1 7.05 23.2 42.7 47.4 53.6 Lead 0.003 NV < 0.00002 - 0.00014 - 0.00013 - 0.00005 - 0.00009 - - Magnesium NV NV 33.9 37.8 39.1 38.8 36.3 47.1 33.5 46.6 27.6 28.4 19.6 Manganese NV NV 0.971 0.49 0.986 1.29 0.429 2.12 0.368 0.713 1.1 1.16 1.43 Molybdenum 0.04 NV ------Nickel 0.025 NV ------Phosphorus - Total 0.03 NV 7.5 - 3.5 - 0.1 - 0.9 - 1.86 - 0.45 Potassium NV NV 136 167 144 139 152 119 160 124 56.4 48.5 25.9 Selenium 0.1 NV ------Silver 0.0001 NV ------Sodium NV NV 270 284 225 203 257 167 271 216 90.7 75.1 38 Thallium 0.0003 NV ------Tungsten 0.03 NV ------Uranium 0.005 NV ------Vanadium 0.006 NV ------Zinc 0.02 NV 0.01 - 0.007 - 0.012 - < 0.005 - 0.011 - - Zirconium 0.004 NV ------Conductivity (µs/cm)4 NV NV 2309 2632 - 2295 2103 2155 2490 1505 1656 1122 631 pH (units)4 6.5 - 8.5 NV 8.59 8.56 - 7.26 7.07 6.41 7.40 7.45 5.89 7.39 6.53 Temperature (°C)4 NV NV 13 15.2 - 17.9 10.5 13.3 7.9 6.3 11.6 14.6 7.3 Oxidation Reduction Potential (mV)4 NV NV ------Dissolved Oxygen4 5.0 NV ------Notes: 1. Results expressed in mg/L unless otherwise stated 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines. 4. Results from field analysis 5. Bold text and shading indicates values exceeding PWQO or CWQG. 6. "-" parameter not analyzed. 7. NV indicates No Value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.:7215-007
Table 4: Summary of Groundwater Quality - PWQO
MW1 MW1 MW1 MW1 MW1 MW1 MW1 MW1 Parameter PWQO 2 CWQG 25-May-15 9-Nov-15 19-Apr-16 5-Oct-16 3-May-17 18-Sep-17 22-May-18 1-Nov-18
Alkalinity (CaCO3) decrease >25% NV 409 423 377 330 451 403 323 396
Bicarbonate (CaCO3) NV NV - 423 377 330 451 403 323 396 Colour (TCU) NV NV 12 12 15 11 127 22 16 33 Conductivity (µs/cm) NV NV 932 909 913 762 1080 899 725 950 pH (units) 6.5-8.5 NV 7.41 7.28 7.20 7.54 7.48 7.37 7.61 7.70 Solids - Total Dissolved (TDS) NV NV 513 500 502 419 594 494 378 505 Solids - Total Suspended (TSS) NV NV 8700 2000 5350 3300 3150 1700 1500 840 Carbon - Dissolved Organic (DOC) NV NV 16.9 1 16.2 13.1 7.3 15.1 21.9 18.4 Oxygen Demand - Biological (BOD) NV NV 30 150 8 15 22 11 >16.5 15 Oxygen Demand - Chemical (COD) NV NV 215 181 659 322 295 273 121 230 Total - Phenolics NV NV < 0.001 < 0.001 < 0.001 0.003 0.004 0.001 < 0.001 0.016 Chloride NV 120 32.9 26.8 93.4 28.3 53.3 37.1 33.6 55.2
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 14.3 13.8 17.3 15.3 17.6 12.6 12.6 16.9 Sulphate NV NV 1316651< 1< 1
Nitrogen - Nitrite (NO2) NV 0.06 < 0.1 < 0.1 < 0.1 < 0.1 < 0.05 < 0.05 < 0.05 < 0.05
Nitrogen - Nitrate (NO3) NV 13 < 0.1 < 0.1 < 0.1 0.1 < 0.05 < 0.05 < 0.05 < 0.05 Nitrogen - Total Kjeldahl (TKN) NV NV 19.2 16.9 32.7 21 19.3 24.9 14.8 22.3 Mercury 0.0002 NV < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 Aluminum 0.075 NV 0.03 0.04 0.03 0.03 0.03 0.08 0.05 0.06 Antimony 0.02 NV - 0.0002 < 0.0001 0.0002 0.0002 0.0002 0.0001 0.0001 Arsenic 0.005 NV 0.0013 0.0011 0.0134 0.0012 0.0035 0.0009 0.0016 0.0009 Beryllium 0.011 NV - < 0.002 < 0.0001 < 0.002 < 0.0001 < 0.0001 < 0.002 < 0.002 Boron 0.2 NV 0.466 0.514 0.422 0.453 0.527 0.625 0.36 0.538 Cadmium 0.0001 NV 0.00002 0.00002 0.00003 < 0.00002 < 0.000014 < 0.000014 < 0.000015 < 0.000015 Calcium NV NV 65 88.3 81.1 73.6 97.7 102 76 81.6 Chromium 0.001 NV < 0.002 < 0.002 < 0.002 < 0.002 < 0.001 < 0.001 0.007 0.002 Cobalt 0.0009 NV - < 0.005 0.0077 0.0002 0.0004 0.0003 0.0003 0.0004 Copper 0.005 NV < 0.002 - 0.0027 0.0001 0.0006 0.0004 0.0004 < 0.0001 Iron 0.30 NV 0.263 56.2 42.8 37.7 - 42.5 32.9 26.9 Lead 0.003 NV 0.00006 0.00009 < 0.00002 < 0.00002 < 0.00002 0.00003 0.00003 < 0.00002 Magnesium NV NV 17 18 16.3 16.1 19.6 19.5 14 16.3 Manganese NV NV 0.704 1.62 0.0004 0.982 0.72 1.3 1.01 0.799 Molybdenum 0.04 NV - < 0.01 1.47 0.0002 0.0003 0.0002 0.0002 0.0001 Nickel 0.025 NV < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 Phosphorus - Total 0.03 NV < 0.1 0.1 < 0.1 1.69 < 0.1 0.1 0.81 0.9 Potassium NV NV 32.3 21.5 29.5 24.1 44.3 34.3 26.6 43.6 Selenium 0.1 NV - < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 Silver 0.0001 NV - < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium NV NV 49.5 32.3 55.6 39.2 94.3 56.4 43.8 80.6 Thallium 0.0003 NV - - < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten 0.03 NV --0.04 - - < 0.01 0.12 0.02 Uranium 0.005 NV - < 0.00005 0.00073 < 0.00005 0.00009 0.00012 < 0.00005 < 0.00005 Vanadium 0.006 NV - 0.006 < 0.005 < 0.005 < 0.005 < 0.005 0.011 < 0.005 Zinc 0.02 NV < 0.003 0.017 0.011 0.007 < 0.005 < 0.005 < 0.005 < 0.005 Zirconium 0.004 NV - - < 0.003 - - < 0.003 < 0.003 < 0.003 Conductivity (µs/cm)4 NV NV 990 1040 910 870 1200 1040 870 1030 pH (units)4 6.5 - 8.5 NV 7.37 6.88 6.82 7.35 7.14 7.00 - 6.97 Temperature (°C)4 NV NV 12 9.7 13.3 14.0 12.2 14.2 11.6 10.3 Oxidation Reduction Potential (mV)4 NV NV -134 -70 -95 -135 189 138 -3 211 Dissolved Oxygen4 5.0 NV 2.01 4.11 5.29 2.20 6.47 3.00 1.08 0.85 Notes: 1. Results expressed in mg/L unless otherwise stated 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines. 4. Results from field analysis 5. Bold text and shading indicates values exceeding PWQO or CWQG. 6. "-" parameter not analyzed. 7. NV indicates No Value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.:7215-007
Table 4: Summary of Groundwater Quality - PWQO
MW5 MW5 MW5 MW5 MW5 MW5 MW5 MW5 MW5 MW5 MW5 Parameter PWQO 2 CWQG 30-Oct-13 23-Jun-14 18-Nov-14 25-May-15 09-Nov-15 19-Apr-16 05-Oct-16 03-May-17 18-Sep-17 22-May-18 01-Nov-18
Alkalinity (CaCO3) decrease >25% NV 168 154 171 161 175 160 177 141 164 153 196
Bicarbonate (CaCO3) NV NV ----175160177141164153196 Colour (TCU) NV NV - - < 2 < 2 4 < 2 < 2 4 < 2 7 < 2 Conductivity (µs/cm) NV NV 455 338 369 355 384 337 384 296 342 323 355 pH (units) 6.5-8.5 NV 8.07 7.97 7.99 7.95 7.96 7.75 8.05 7.84 7.98 8.01 8.01 Solids - Total Dissolved (TDS) NV NV 250 186 203 195 211 185 211 163 188 166 183 Solids - Total Suspended (TSS) NV NV 8000 2080 9150 7300 5400 9900 32500 128 720 2800 1120 Carbon - Dissolved Organic (DOC) NV NV 4.4 2.1 2.4 1.1 < 0.2 0.9 0.7 2.4 4.3 4.2 2.3 Oxygen Demand - Biological (BOD) NV NV < 2< 2-----3< 2< 2< 3 Oxygen Demand - Chemical (COD) NV NV 34889-----444822< 5 Total - Phenolics NV NV < 0.001 - < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 0.002 Chloride NV 120 5 1.6 1.4 2.5 2.4 3.3 2.8 1.7 1.3 1.9 1.5
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.295 0.08 0.01 0.1 0.04 0.06 0.07 < 0.01 0.13 0.05 0.04 Sulphate NV NV 68 14 19 24 18 14 18 11 11 12 14
Nitrogen - Nitrite (NO2) NV 0.06 < 0.1------< 0.05 < 0.05 < 0.05 < 0.05
Nitrogen - Nitrate (NO3) NV 13 < 0.1< 0.1-----< 0.05 < 0.05 < 0.05 < 0.05 Nitrogen - Total Kjeldahl (TKN) NV NV 0.2------0.30.20.30.1 Mercury 0.0002 NV < 0.00002 ------< 0.00002 < 0.00002 < 0.00002 < 0.00002 Aluminum 0.075 NV - - - 0.02 0.02 0.02 0.02 0.01 0.04 0.04 0.03 Antimony 0.02 NV ----0.0001 < 0.0001 0.0003 < 0.0001 < 0.0001 < 0.0001 < 0.0001 Arsenic 0.005 NV 0.0002 - - 0.0015 0.0002 < 0.0001 0.0007 0.0001 < 0.0001 < 0.0001 0.0002 Beryllium 0.011 NV ----< 0.002 < 0.0001 < 0.002 < 0.0001 < 0.0001 < 0.002 < 0.002 Boron 0.2 NV 0.041 0.011 0.01 < 0.005 0.005 < 0.005 0.011 < 0.005 0.007 < 0.005 < 0.005 Cadmium 0.0001 NV 0.00003 - - < 0.00002 0.00002 < 0.00002 < 0.00002 < 0.000014 < 0.000014 < 0.000015 < 0.000015 Calcium NV NV 65.1 50.1 49.5 55.1 48.8 52.1 56.4 40.8 54.9 47.2 50.8 Chromium 0.001 NV < 0.002 - - < 0.002 < 0.002 < 0.002 < 0.002 < 0.001 < 0.001 0.002 < 0.001 Cobalt 0.0009 NV ----< 0.005 < 0.0001 0.0002 < 0.0001 < 0.0001 < 0.0001 < 0.0001 Copper 0.005 NV < 0.002 - - < 0.002 - < 0.0001 0.0002 0.0013 0.0007 0.0011 0.0006 Iron 0.30 NV 0.014 < 0.005 0.032 0.259 0.009 0.01 0.025 < 0.005 < 0.005 0.008 0.009 Lead 0.003 NV < 0.00002 - - < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 Magnesium NV NV 20.7 12.3 12.8 16.2 11.4 11.7 14.2 8.95 12.2 10.3 12.5 Manganese NV NV 0.504 0.117 0.105 0.288 0.043 < 0.0001 0.216 0.0306 0.006 0.05 0.071 Molybdenum 0.04 NV ----< 0.01 0.023 0.0039 0.0004 0.0009 0.0007 0.0013 Nickel 0.025 NV - - - < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 Phosphorus - Total 0.03 NV 11.9 - 2.65 < 0.1 < 0.1 < 0.1 1.84 < 0.1 < 0.1 0.98 0.36 Potassium NV NV 1.4 - 1.4 1.7 1.2 1.3 1.4 1.1 1.4 1.1 1.2 Selenium 0.1 NV ----< 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 Silver 0.0001 NV ----< 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium NV NV 6.7 4 5.4 5.5 3.2 6.0 5.0 2.8 4 3.2 3 Thallium 0.0003 NV -----< 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten 0.03 NV -----< 0.01 - - < 0.01 < 0.01 < 0.01 Uranium 0.005 NV ----0.00012 < 0.00005 0.00028 0.00006 0.0001 0.00013 0.00016 Vanadium 0.006 NV ----< 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Zinc 0.02 NV < 0.005 - - < 0.003 0.013 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Zirconium 0.004 NV -----< 0.003 - - < 0.003 < 0.003 < 0.003 Conductivity (µs/cm)4 NV NV 279 259 224 370 380 370 400 290 340 310 370 pH (units)4 6.5 - 8.5 NV 6.93 8.80 7.00 7.42 7.22 7.67 7.54 7.57 7.74 - 7.58 Temperature (°C)4 NV NV 7.3 9.3 5.6 8.7 8.0 9.4 10.6 10.1 12.3 8.5 8.0 Oxidation Reduction Potential (mV)4 NV NV - - - -88 55 34 120 136 44 -26 159 Dissolved Oxygen4 5.0 NV ---4.46 8.17 5.66 6.19 6.69 9.29 4.39 7.71 Notes: 1. Results expressed in mg/L unless otherwise stated 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines. 4. Results from field analysis 5. Bold text and shading indicates values exceeding PWQO or CWQG. 6. "-" parameter not analyzed. 7. NV indicates No Value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 5: Summary of Surface Water Quality
SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 Parameter PWQO 2 CWQG3 75th Percentile 5 Trigger 3-Jun-09 19-Aug-09 8-Dec-09 5-Apr-10 20-Aug-10 8-Oct-10 1-Jun-11 30-Apr-12 20-Nov-12 9-May-13 21-Aug-13 30-Oct-13
Alkalinity (CaCO3) decrease >25% NV 36 36 18 36 25 25 35 29 27 24 31 31 34 30
Bicarbonates (CaCO3) NVNVNVNV------Colour (TCU) NVNVNVNV------Conductivity (µs/cm) NVNV9191618066648174737499 86 86 82 pH (units) 6.5-8.5 6.5-9.0 7.29 6.5-8.5 6.7 6.74 7.25 7.23 6.97 7.25 7.36 7.37 7.08 6.99 7.16 7.19 Solids - Total Dissolved (TDS) NVNV50.050344436354440404155 47 47 45 Solids - Total Suspended (TSS) NV NV 41.0 41 72 26612130 140 8 52 154 4122 Carbon - Dissolved Organic (DOC) NVNVNVNV--8.1------Oxygen Demand - Biological (BOD) NV NV 4.0 4.0 < 2 < 2 < 2 < 2 3 4 < 2 4 5 33< 2 Oxygen Demand - Chemical (COD) NV NV 28 28.0 25 28 21 23 64 19 21 15 40 23 11 26 Total - Phenolics NV NV 0.001 0.001 < 0.001 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 0.002 Chloride NV1204 12023333434.66.54.244.2
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.05 0.05 < 0.05 < 0.05 < 0.05 < 0.05 0.15 0.05 < 0.05 0.048 0.047 0.027 0.194 0.014 Ammonia (N)-unionized 0.02 0.02 0.003 0.02 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 - < 0.005 < 0.005 Sulphate NV NV 3 3 3 5 221< 12333< 11
Nitrogen - Nitrite (NO2) NV 0.06 0.1 0.1 0.8 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
Nitrogen - Nitrate (NO3) NV 3 0.1 3 < 0.1 0.6 < 0.1 0.1 0.2 0.1 < 0.1 < 0.1 0.2 < 0.1 < 0.1 < 0.1 Nitrogen - Total Kjeldahl (TKN) NV NV 0.8 0.8 0.6 0.6 0.4 0.3 2.5 0.6 0.4 0.7 0.6 1 0.8 0.4 Mercury 0.0002 0.00003 NV 0.0002 - - < 0.00002 - - < 0.00002 - - < 0.00002 - - < 0.00002
Hardness (as CaCO3 ) NV NV 42 42 30 35 26 23 43 36 30 30 43 35 39 34 Aluminum (total) 0.075NVNV0.075------Antimony 0.02NVNV0.02------Arsenic 0.005 0.005 0.0006 0.005 - - < 0.0005 - - 0.0011 - - 0.0005 - - 0.0004 Beryllium 0.011 NV NV 0.011 ------Boron 0.2 1.5 0.006 0.2 - - < 0.005 - - < 0.005 - - < 0.005 - - < 0.005 Cadmium 0.0001 0.00009 0.00006 0.0001 - - < 0.0001 - - < 0.0001 - - 0.00002 - - < 0.00002 Calcium NV NV 14 14 9.67 11.6 8.38 7.37 14.2 11.7 9.58 9.44 13.8 11.2 12.7 10.7 Chromium 0.001 0.001 0.002 0.002 - - < 0.002 - - < 0.002 - - 0.014 - - < 0.002 Cobalt 0.0009 NV NV 0.0009 ------Copper 0.005 NV 0.002 0.005 - - < 0.002 - - < 0.002 - - < 0.002 - - < 0.002 Iron 0.3 0.3 1.8 1.8 1.23 1.33 0.225 0.279 9.28 5.71 0.686 0.466 2.56 0.414 2.17 0.461 Lead 0.003 NV 0.0005 0.003 - - < 0.0001 - - 0.0015 - - 0.00059 - - 0.0001 Magnesium NV NV 1.95 1.95 1.3 1.46 1.33 1.04 1.78 1.51 1.36 1.45 1.99 1.63 1.65 1.65 Manganese NV NV 0.337 0.337 0.4 0.22 0.02 0.066 0.657 0.683 0.086 0.049 0.364 0.077 0.277 0.081 Molybdenum 0.040.073NV0.04------Nickel 0.025NVNV0.025------Phosphorus - Total 0.03 NV 0.09 0.09 0.04 0.05 0.02 0.01 0.32 0.04 < 0.01 0.02 0.05 0.09 0.04 < 0.01 Potassium NV NV 0.7 0.7 0.1 0.2 0.5 0.4 0.2 0.2 0.2 0.3 0.5 0.9 0.3 0.6 Selenium 0.10.001NV0.1------Silver 0.0001 0.00025 NV 0.0001 ------Sodium NV NV 2.7 2.7 1.4 1.2 2.2 1.6 1.3 2.3 2 33.82.7 2.3 2.8 Thallium 0.0003 0.0008 NV 0.0003 ------Tungsten 0.03NVNV0.03------Uranium 0.0050.015NV0.005------Vanadium 0.006NVNV0.006------Zinc 0.02 0.03 0.01 0.02 - - < 0.005 - - 0.025 - - 0.007 - - < 0.005 Zirconium 0.004NVNV0.004------Conductivity (µs/cm)7 NV NV 86 86 58 78 72 66 86 69 66 62 85 84 80 74 pH (units)7 6.5 - 8.5 NA 7.56 6.5 - 8.5 8.17 6.28 8.26 7.03 6.71 6.76 7.21 7.02 7.22 - 6.65 7.05 Temperature (°C)7 NV NV 18.9 18.9 14.9 20.4 2.1 13.2 19 10.9 21.7 10.2 5.1 18.6 18.7 4.5 Oxidation Reduction Potential (mV)7 NVNVNVNV------Dissolved Oxygen7 5.0 NV 8.0 5.0 8.03 5.17 11 7 3 5794 6 3.6 10 Notes: 1. All results are expressed in mg/L unless otherwise stated. 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines for the Protection of Aquatic Life. 4. Bold text indicate values exceeding PWQO or CWQG criteria 4. Bold text and shading indicate values exceeding the trigger value. 5. 75th percentile as calculated from a minimum of six (1) events, not including the current year, at station SW1. 6. "-" parameter not analyzed. 7. Results from field analysis. 8. Calculated from Total Ammonia and field data. 9. NV means no value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 5: Summary of Surface Water Quality
SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 SW1 Parameter PWQO 2 CWQG3 75th Percentile 5 Trigger 10-Jun-14 25-Aug-14 18-Nov-14 25-May-15 9-Nov-15 19-Apr-16 5-Oct-16 3-May-17 18-Sep-17 22-May-18 1-Nov-18
Alkalinity (CaCO3) decrease >25% NV 36 36 36 33 25 139 54 33 95 28 49 40 71
Bicarbonates (CaCO3) NV NV NV NV ----543395-494071 Colour (TCU) NV NV NV NV - 68632930243140364556 Conductivity (µs/cm) NV NV 91 91 91 83 70 286 125 77 201 73 108 89 151 pH (units) 6.5-8.5 6.5-9.0 7.29 6.5-8.5 7.17 7.21 6.61 7.68 7.06 7.03 7.61 7.48 7.29 7.58 7.66 Solids - Total Dissolved (TDS) NV NV 50.0 50 50 46 39 157 69 42 111 40 59 45 77 Solids - Total Suspended (TSS) NV NV 41.0 41 411036108685447 Carbon - Dissolved Organic (DOC) NV NV NV NV - - - 9.3 5.3 5.6 8.6 5.9 11.1 8.6 11 Oxygen Demand - Biological (BOD) NV NV 4.0 4.0 11 -----25 3 5 < 3 Oxygen Demand - Chemical (COD) NV NV 28 28.0 42 -----27202838 32 Total - Phenolics NV NV 0.001 0.001 < 0.001-----< 0.001< 0.001< 0.001< 0.0010.006 Chloride NV 120 4 120 3.5 3.6 4.1 1.7 2.3 3.1 2.2 1.8 2.2 2.7 1.3
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.05 0.05 0.05 0.08 < 0.01 0.04 < 0.01 0.02 0.02 < 0.01 0.04 0.05 0.03 Ammonia (N)-unionized 0.02 0.02 0.003 0.02 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Sulphate NV NV 3 3 < 1< 1133322< 1< 13
Nitrogen - Nitrite (NO2) NV 0.06 0.1 0.1 < 0.1-----< 0.1< 0.05< 0.05< 0.05< 0.05
Nitrogen - Nitrate (NO3) NV 3 0.1 3 < 0.1-----< 0.1< 0.05< 0.05< 0.05< 0.05 Nitrogen - Total Kjeldahl (TKN) NV NV 0.8 0.8 1.3 -----0.80.60.40.50.6 Mercury 0.0002 0.00003 NV 0.0002 ------< 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002
Hardness (as CaCO3 ) NV NV 42 42 38 - - 153 64 36 - 31 49 56 94 Aluminum (total) 0.075 NV NV 0.075 - - - 0.04 0.12 0.05 0.07 0.05 0.03 0.04 0.08 Antimony 0.02 NV NV 0.02 ----< 0.0001 < 0.0001 < 0.0001 0.0001 < 0.0001 0.0003 0.0002 Arsenic 0.005 0.005 0.0006 0.005 - - - 0.0006 0.0003 0.0002 0.0006 0.0003 0.0008 0.0005 0.0003 Beryllium 0.011 NV NV 0.011 ----< 0.002< 0.002< 0.002< 0.002< 0.002< 0.002< 0.002 Boron 0.2 1.5 0.006 0.2 - < 0.005 0.006 < 0.005 0.021 < 0.005 0.008 < 0.005 0.015 0.009 0.009 Cadmium 0.0001 0.00009 0.00006 0.0001 - - - 0.00005 0.00006 < 0.00002 < 0.00002 0.000015 0.000045 < 0.000015 < 0.000015 Calcium NV NV 14 14 12.5 13.8 7.07 49.4 19.6 11.3 30.8 9.68 15.3 17.1 27.9 Chromium 0.001 0.001 0.002 0.002 - - - < 0.002 < 0.002 < 0.002 < 0.002 < 0.001 < 0.001 < 0.001 < 0.001 Cobalt 0.0009 NV NV 0.0009 ----0.0002 0.0001 0.0002 0.0001 0.0002 0.0001 0.0002 Copper 0.005 NV 0.002 0.005 - - - 0.0013 0.0022 0.0003 0.0002 0.0009 0.0062 0.0003 0.0007 Iron 0.3 0.3 1.8 1.8 2.93 1.83 0.972 0.589 0.379 0.281 1.11 0.357 0.37 0.46 0.452 Lead 0.003 NV 0.0005 0.003 - - - 0.0005 0.00032 0.0001 < 0.00002 0.00017 0.00043 0.00008 0.0001 Magnesium NV NV 1.95 1.95 1.61 1.83 1.32 7.22 3.79 1.95 4.78 1.71 2.52 3.17 5.8 Manganese NV NV 0.337 0.337 0.959 0.327 0.075 0.337 0.124 0.064 0.305 0.059 0.103 0.051 0.054 Molybdenum 0.04 0.073 NV 0.04 ----< 0.01< 0.01< 0.01< 0.01< 0.01< 0.01< 0.01 Nickel 0.025 NV NV 0.025 ----0.0013 0.0003 0.0006 0.0005 0.0018 0.0004 0.0004 Phosphorus - Total 0.03 NV 0.09 0.09 0.13 0.06 0.12 0.05 < 0.1 0.03 0.09 0.07 - 0.04 0.03 Potassium NV NV 0.7 0.7 0.7 0.5 0.7 2.8 1.2 0.6 0.9 0.5 0.7 0.5 1.7 Selenium 0.1 0.001 NV 0.1 ----< 0.001< 0.001< 0.001< 0.001< 0.001< 0.001< 0.001 Silver 0.0001 0.00025 NV 0.0001 ----< 0.00002 < 0.00002 0.00016 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium NV NV 2.7 2.7 2.5 2.7 3.0 1.4 2.6 2.7 2.0 1.7 1.4 3.2 2.7 Thallium 0.0003 0.0008 NV 0.0003 ----< 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten 0.03 NV NV 0.03 -----< 0.01-< 0.01< 0.01< 0.01< 0.01 Uranium 0.005 0.015 NV 0.005 ----0.00074 < 0.00005 < 0.00005 < 0.00005 0.00022 < 0.00005 < 0.00005 Vanadium 0.006 NV NV 0.006 ----< 0.005< 0.005< 0.005< 0.005< 0.005< 0.005< 0.005 Zinc 0.02 0.03 0.01 0.02 - - - < 0.005 0.039 < 0.005 0.005 0.008 0.006 0.02 0.018 Zirconium 0.004 NV NV 0.004 -----< 0.003-< 0.003< 0.003< 0.003< 0.003 Conductivity (µs/cm)7 NV NV 86 86 80 76 39 300 130 110 220 70 120 100 170 pH (units)7 6.5 - 8.5 NA 7.56 6.5 - 8.5 7.57 6.68 5.83 7.34 7.45 7.65 7.55 7.66 7.38 - 7.74 Temperature (°C)7 NV NV 18.9 18.9 21.3 20.7 -0.1 15.8 6 16 17.3 15.1 18.9 17.8 8.0 Oxidation Reduction Potential (mV)7 NV NV NV NV - - - -48 -45 -108 31 120 141 -38 151 Dissolved Oxygen7 5.0 NV 8.0 5.0 2.7 5.13 5.07 3.41 8.31 6.77 7.41 9.1 5.08 7.69 7.84 Notes: 1. All results are expressed in mg/L unless otherwise stated. 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines for the Protection of Aquatic Life. 4. Bold text indicate values exceeding PWQO or CWQG criteria 4. Bold text and shading indicate values exceeding the trigger value. 5. 75th percentile as calculated from a minimum of six (1) events, not including the current year, at station SW1. 6. "-" parameter not analyzed. 7. Results from field analysis. 8. Calculated from Total Ammonia and field data. 9. NV means no value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 5: Summary of Surface Water Quality
SW2 SW2 SW2 SW2 SW2 SW2 SW2 SW2 SW2 SW2 SW2 Parameter PWQO 2 CWQG3 75th Percentile 5 Trigger 3-Jun-09 8-Dec-09 5-Apr-10 20-Aug-10 8-Oct-10 1-Jun-11 30-Apr-12 20-Nov-12 9-May-13 21-Aug-13 30-Oct-13
Alkalinity (CaCO3) decrease >25% NV 36 36 46 35 57 88 49 49 39 45 44 61 43
Bicarbonates (CaCO3) NV NV NV NV ------Colour (TCU) NV NV NV NV ------Conductivity (µs/cm) NV NV 91 91 132 89 136 192 112 115 100 125 111 134 105 pH (units) 6.5-8.5 6.5-9.0 7.29 6.5-8.5 6.33 7.04 7.39 7.23 7.07 7.02 7.31 6.96 7.03 7.2 7.18 Solids - Total Dissolved (TDS) NV NV 50.0 50 73 49 75 106 61 63 55 69 61 74 58 Solids - Total Suspended (TSS) NV NV 41.0 41 118 102 126 8 74 106306143 Carbon - Dissolved Organic (DOC) NV NV NV NV -7.8------Oxygen Demand - Biological (BOD) NV NV 4.0 4.0 10 5 5 < 2 10 22356< 2 Oxygen Demand - Chemical (COD) NV NV 28 28.0 62 63 37 42 24 107 18 40 28 28 33 Total - Phenolics NV NV 0.001 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 0.002 < 0.001 Chloride NV 120 4 120 5 4 55433.753.82.84.3
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.05 0.05 0.18 < 0.05 < 0.05 0.06 0.08 0.32 0.042 0.029 0.033 0.02 0.01 Ammonia (N)-unionized 0.02 0.02 0.003 0.02 < 0.005 < 0.005 < 0.005 - < 0.005 < 0.005 < 0.005 < 0.005 - < 0.005 < 0.005 Sulphate NV NV 3 3 3 3 2< 111 3 4 2< 1< 1
Nitrogen - Nitrite (NO2) NV 0.06 0.1 0.1 0.8 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
Nitrogen - Nitrate (NO3) NV 3 0.1 3 < 0.1 0.2 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 0.1 0.1 < 0.1 < 0.1 Nitrogen - Total Kjeldahl (TKN) NV NV 0.8 0.8 2.1 1.8 1.5 0.7 1.6 5.8 0.6 0.6 0.9 0.9 0.5 Mercury 0.0002 0.00003 NV 0.0002 - 0.00003 - - < 0.00002 - - < 0.00002 - - < 0.00002
Hardness (as CaCO3 ) NV NV 42 42 64 35 46 87 54 57 44 56 48 70 48 Aluminum (total) 0.075 NV NV 0.075 ------Antimony 0.02 NV NV 0.02 ------Arsenic 0.005 0.005 0.0006 0.005 - < 0.0005 - - < 0.0005 - - 0.0004 - - 0.0005 Beryllium 0.011 NV NV 0.011 ------Boron 0.2 1.5 0.006 0.2 - 0.03 - - 0.023 - - < 0.005 - - < 0.005 Cadmium 0.0001 0.00009 0.00006 0.0001 - < 0.0001 - - < 0.0001 - - 0.0001 - - < 0.00002 Calcium NV NV 14 14 13.8 11.2 14.3 27.6 17.7 18.6 14.2 17.8 15.5 23 15.2 Chromium 0.001 0.001 0.002 0.002 - < 0.002 - - 0.007 --0.003 - - < 0.002 Cobalt 0.0009 NV NV 0.0009 ------Copper 0.005 NV 0.002 0.005 - 0.008 - - 0.002 - - 0.002 - - < 0.002 Iron 0.3 0.3 1.8 1.8 8.39 18.2 2.79 2.36 1.78 5.06 0.33 1.79 0.794 2.1 0.88 Lead 0.003 NV 0.0005 0.003 - 0.003 - - 0.001 - - 0.00078 - - 0.00008 Magnesium NV NV 1.95 1.95 2.26 1.78 2.43 4.41 2.45 2.46 2.18 2.82 2.35 3.11 2.35 Manganese NV NV 0.337 0.337 0.279 2.48 0.258 0.213 0.2 0.996 0.043 0.274 0.236 0.597 0.234 Molybdenum 0.04 0.073 NV 0.04 ------Nickel 0.025 NV NV 0.025 ------Phosphorus - Total 0.03 NV 0.09 0.09 0.38 0.31 0.21 0.03 0.27 0.82 0.02 0.08 0.06 0.07 < 0.01 Potassium NV NV 0.7 0.7 1.7 0.9 2.9 2.4 2.5 1 0.6 1.5 1.2 0.7 1.2 Selenium 0.1 0.001 NV 0.1 ------Silver 0.0001 0.00025 NV 0.0001 ------Sodium NV NV 2.7 2.7 14.4 2.5 5.3 4.3 3.8 2.8 3 3 2.6 2.3 2.1 Thallium 0.0003 0.0008 NV 0.0003 ------Tungsten 0.03 NV NV 0.03 ------Uranium 0.005 0.015 NV 0.005 ------Vanadium 0.006 NV NV 0.006 ------Zinc 0.02 0.03 0.01 0.02 - 0.027 - - 0.008 - - 0.008 - - < 0.005 Zirconium 0.004 NV NV 0.004 ------Conductivity (µs/cm)7 NV NV 86 86 127 79 132 - 144 133 105 116 136 107 49 pH (units)7 6.5 - 8.5 NA 7.56 6.5 - 8.5 7.53 8.79 6.53 - 6.4 7.05 6.84 7.05 - 6.56 6.41 Temperature (°C)7 NV NV 18.9 18.9 17.7 2.3 17.7 - 10.6 22.7 9.8 2.6 20.5 22.6 3.4 Oxidation Reduction Potential (mV)7 NV NV NV NV ------Dissolved Oxygen7 5.0 NV 8.0 5.0 3.75 67-1 5943410 Notes: 1. All results are expressed in mg/L unless otherwise stated. 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines for the Protection of Aquatic Life. 4. Bold text indicate values exceeding PWQO or CWQG criteria 4. Bold text and shading indicate values exceeding the trigger value. 5. 75th percentile as calculated from a minimum of six (1) events, not including the current year, at station SW1. 6. "-" parameter not analyzed. 7. Results from field analysis. 8. Calculated from Total Ammonia and field data. 9. NV means no value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 5: Summary of Surface Water Quality
SW2 SW2 SW2 SW2 SW2 SW2 SW2 SW2 SW2 SW2 SW2 Parameter PWQO 2 CWQG3 75th Percentile 5 Trigger 10-Jun-14 25-Aug-14 18-Nov-14 25-May-15 09-Nov-15 19-Apr-16 05-Oct-16 03-May-17 18-Sep-17 22-May-18 01-Nov-18
Alkalinity (CaCO3) decrease >25% NV 36 36 48 54 33 52 37 28 56 26 39 33 49
Bicarbonates (CaCO3) NV NV NV NV ----372856-393349 Colour (TCU) NV NV NV NV - 46327635202932364527 Conductivity (µs/cm) NV NV 91 91 113 119 84 119 92 68 122 67 87 76 109 pH (units) 6.5-8.5 6.5-9.0 7.29 6.5-8.5 7.3 7.34 6.93 7.14 7.31 7.05 7.63 7.34 7.3 7.63 7.61 Solids - Total Dissolved (TDS) NV NV 50.0 50 62 65 46 66 51 37 67 37 48 38 55 Solids - Total Suspended (TSS) NV NV 41.0 41 511191251445 6 4< 3 Carbon - Dissolved Organic (DOC) NV NV NV NV - - - 9.8 8.2 4.8 10 5.1 10.4 8.4 8.8 Oxygen Demand - Biological (BOD) NV NV 4.0 4.0 8 -----2335 < 3 Oxygen Demand - Chemical (COD) NV NV 28 28.0 39 -----30 12 28 35 20 Total - Phenolics NV NV 0.001 0.001 < 0.001 - - 0.001 - - < 0.001 < 0.001 < 0.001 < 0.001 0.005 Chloride NV 120 4 120 2.8 2.6 4.2 3.2 3.7 3.6 2.1 2 2.2 2.9 1.8
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.05 0.05 0.03 0.13 < 0.01 0.47 < 0.01 0.03 0.03 0.01 0.03 0.05 0.03 Ammonia (N)-unionized 0.02 0.02 0.003 0.02 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Sulphate NV NV 3 3 < 1< 1< 1< 1< 13 < 12 < 1< 12
Nitrogen - Nitrite (NO2) NV 0.06 0.1 0.1 < 0.1-----< 0.1< 0.05< 0.05< 0.05< 0.05
Nitrogen - Nitrate (NO3) NV 3 0.1 3 < 0.1-----< 0.1< 0.05< 0.05< 0.05< 0.05 Nitrogen - Total Kjeldahl (TKN) NV NV 0.8 0.8 1.3 -----0.60.50.50.70.7 Mercury 0.0002 0.00003 NV 0.0002 ------< 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002
Hardness (as CaCO3 ) NV NV 42 42 52 --54 56 29 - 28 41 51 69 Aluminum (total) 0.075 NV NV 0.075 - - - 0.06 0.08 0.05 0.01 0.04 0.03 0.04 0.03 Antimony 0.02 NV NV 0.02 ----< 0.0001 < 0.0001 0.0002 0.0002 0.0001 0.0003 < 0.0001 Arsenic 0.005 0.005 0.0006 0.005 - - - 0.0006 0.0004 0.0002 0.0004 0.0003 0.0006 0.0004 0.0003 Beryllium 0.011 NV NV 0.011 ----< 0.002< 0.002< 0.002< 0.002< 0.002< 0.002< 0.002 Boron 0.2 1.5 0.006 0.2 - < 0.005 < 0.005 < 0.005 0.006 < 0.005 0.007 0.007 0.009 0.008 < 0.005 Cadmium 0.0001 0.00009 0.00006 0.0001 - - - 0.00003 0.00003 < 0.00002 < 0.00002 < 0.000014 < 0.000014 < 0.000015 0.000028 Calcium NV NV 14 14 16.9 19.3 8.47 17.4 17.6 9.3 18 8.68 13 15.7 20.9 Chromium 0.001 0.001 0.002 0.002 - - - < 0.002 0.003 < 0.002 < 0.002 < 0.001 < 0.001 < 0.001 < 0.001 Cobalt 0.0009 NV NV 0.0009 ----< 0.0001 < 0.0001 < 0.0001 < 0.0001 0.0001 < 0.0001 0.0001 Copper 0.005 NV 0.002 0.005 - - - 0.0007 0.0013 0.0002 < 0.0001 0.0004 0.0017 0.0003 0.0058 Iron 0.3 0.3 1.8 1.8 1.2 0.861 0.344 5.54 0.503 0.323 0.316 0.268 0.401 0.383 0.184 Lead 0.003 NV 0.0005 0.003 - - - 0.00054 0.00022 0.00023 < 0.00002 0.00007 0.00024 0.00008 0.00022 Magnesium NV NV 1.95 1.95 2.33 2.55 1.36 2.46 2.96 1.5 2.85 1.49 2.00 2.97 4.17 Manganese NV NV 0.337 0.337 0.383 0.169 0.035 0.414 0.053 0.024 0.055 0.024 0.051 0.036 0.018 Molybdenum 0.04 0.073 NV 0.04 ----< 0.01< 0.01< 0.01< 0.01< 0.010.02< 0.01 Nickel 0.025 NV NV 0.025 ----0.0008 0.0002 0.0002 0.0003 0.001 0.0004 0.0008 Phosphorus - Total 0.03 NV 0.09 0.09 0.15 0.05 0.05 0.1 0.1 0.02 0.01 0.03 - 0.06 0.04 Potassium NV NV 0.7 0.7 0.9 0.8 0.7 1.4 1.3 0.5 0.4 0.4 0.4 0.4 0.7 Selenium 0.1 0.001 NV 0.1 ----< 0.001< 0.001< 0.001< 0.001< 0.001< 0.001< 0.001 Silver 0.0001 0.00025 NV 0.0001 ----< 0.00002 < 0.00002 0.00013 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium NV NV 2.7 2.7 2.2 2.1 2.2 2.7 3.2 2.8 2.1 1.8 1.5 3.4 2.5 Thallium 0.0003 0.0008 NV 0.0003 ----< 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten 0.03 NV NV 0.03 -----< 0.01-0.01< 0.01< 0.01< 0.01 Uranium 0.005 0.015 NV 0.005 ----0.00038 < 0.00005 < 0.00005 < 0.00005 0.00007 < 0.00005 0.00043 Vanadium 0.006 NV NV 0.006 ----< 0.005< 0.005< 0.005< 0.005< 0.005< 0.005< 0.005 Zinc 0.02 0.03 0.01 0.02 - - - < 0.005 0.111 < 0.005 < 0.005 < 0.005 0.005 0.019 0.012 Zirconium 0.004 NV NV 0.004 -----< 0.003-< 0.003< 0.003< 0.003< 0.003 Conductivity (µs/cm)7 NV NV 86 86 100 110 62 160 100 70 130 70 100 80 130 pH (units)7 6.5 - 8.5 NA 7.56 6.5 - 8.5 7.27 6.92 7.25 6.76 7.96 7.2 7.07 7.8 7.18 - 7.94 Temperature (°C)7 NV NV 18.9 18.9 21.1 22.7 1.3 14.8 7.2 15.3 16.7 13.7 18.7 17.9 7.6 Oxidation Reduction Potential (mV)7 NV NV NV NV - - - 97 -60 -112 8 116 136 -48 153 Dissolved Oxygen7 5.0 NV 8.0 5.0 3.5 4.13 4.11 1.56 8.94 8.38 4.32 7.81 6.05 8.88 9.75 Notes: 1. All results are expressed in mg/L unless otherwise stated. 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines for the Protection of Aquatic Life. 4. Bold text indicate values exceeding PWQO or CWQG criteria 4. Bold text and shading indicate values exceeding the trigger value. 5. 75th percentile as calculated from a minimum of six (1) events, not including the current year, at station SW1. 6. "-" parameter not analyzed. 7. Results from field analysis. 8. Calculated from Total Ammonia and field data. 9. NV means no value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 5: Summary of Surface Water Quality
SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 Parameter PWQO 2 CWQG3 75th Percentile 5 Trigger 3-Jun-09 19-Aug-09 8-Dec-09 5-Apr-10 8-Oct-10 1-Jun-11 16-Aug-11 3-Nov-11 30-Apr-12 20-Aug-12 20-Nov-12 9-May-13 21-Aug-13 30-Oct-13
Alkalinity (CaCO3) decrease >25% NV 36 36 60 82 42 52 74 74 83 69 52 116 53 75 84 64
Bicarbonates (CaCO3) NV NV NV NV ------Colour (TCU) NV NV NV NV ------Conductivity (µs/cm) NV NV 91 91 139 195 110 131 163 183 188 165 138 261 148 195 193 172 pH (units) 6.5-8.5 6.5-9.0 7.29 6.5-8.5 6.59 6.72 7.31 7.47 7.39 7.28 7.49 7.24 7.67 7.47 7.02 7.13 7.17 7.36 Solids - Total Dissolved (TDS) NV NV 50.0 50 77 107 60 72 89 100 104 91 76 144 81 107 106 94 Solids - Total Suspended (TSS) NV NV 41.0 41 61038 81690 18236244162 Carbon - Dissolved Organic (DOC) NV NV NV NV --6.2------Oxygen Demand - Biological (BOD) NV NV 4.0 4.0 < 2< 2< 2< 2 5 4 10 6 2 6 324< 2 Oxygen Demand - Chemical (COD) NV NV 28 28.0 19 32 16 32 27 40 55 20 20 59 43 22 30 18 Total - Phenolics NV NV 0.001 0.001 < 0.001 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 Chloride NV 120 4 120 45554765.66.77.96.810.77.79.8
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.05 0.05 < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 0.05 < 0.05 < 0.05 0.034 0.599 0.023 0.137 0.022 0.061 Ammonia (N)-unionized 0.02 0.02 0.003 0.02 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 0.0168 < 0.005 - < 0.005 < 0.005 Sulphate NV NV 3 3 2134 < 11< 113 1 5 1< 11
Nitrogen - Nitrite (NO2) NV 0.06 0.1 0.1 0.2 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1
Nitrogen - Nitrate (NO3) NV 3 0.1 3 < 0.1 1 0.1 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 Nitrogen - Total Kjeldahl (TKN) NV NV 0.8 0.8 0.5 0.8 0.3 0.6 0.5 1.4 1.5 0.7 0.7 3.9 0.8 1 0.7 0.4 Mercury 0.0002 0.00003 NV 0.0002 - - < 0.00002 - < 0.00002 - - 0.00003 - - < 0.00002 - - < 0.00002
Hardness (as CaCO3 ) NV NV 42 42 60 87 46 48 80 73 84 60 64 139 66 82 88 66 Aluminum (total) 0.075 NV NV 0.075 ------Antimony 0.02 NV NV 0.02 ------Arsenic 0.005 0.005 0.0006 0.005 - - < 0.0005 - < 0.0005 - - 0.0002 - - 0.0003 - - 0.0002 Beryllium 0.011 NV NV 0.011 ------Boron 0.2 1.5 0.006 0.2 - - 0.007 - 0.041 - - 0.016 - - 0.015 - - 0.033 Cadmium 0.0001 0.00009 0.00006 0.0001 - - < 0.0001 - < 0.0001 - - < 0.00002 - - 0.00011 - - < 0.00002 Calcium NV NV 14 14 18.6 26.4 14.2 14.6 25.4 22.9 26.8 18.7 20 44.1 20 25.6 28 20.2 Chromium 0.001 0.001 0.002 0.002 --0.009 - < 0.002 - - 0.012 --0.055 - - < 0.002 Cobalt 0.0009 NV NV 0.0009 ------Copper 0.005 NV 0.002 0.005 - - < 0.002 - < 0.002 - - < 0.002 - - 0.004 - - < 0.002 Iron 0.3 0.3 1.8 1.8 0.888 2.17 0.197 0.279 1.95 3.68 3.33 1.6 0.21 13.1 1.2 0.891 1.68 0.238 Lead 0.003 NV 0.0005 0.003 - - < 0.0001 - 0.0004 - - 0.00014 - - 0.00099 - - < 0.00002 Magnesium NV NV 1.95 1.95 3.35 5.01 2.54 2.72 4.1 3.81 4.16 3.23 3.49 7.03 3.86 4.33 4.3 3.76 Manganese NV NV 0.337 0.337 0.139 0.384 0.01 0.024 0.27 0.374 0.499 0.183 0.012 0.38 0.048 0.122 0.35 0.026 Molybdenum 0.04 0.073 NV 0.04 ------Nickel 0.025 NV NV 0.025 ------Phosphorus - Total 0.03 NV 0.09 0.09 0.01 0.06 < 0.01 0.02 0.03 0.16 0.12 0.08 0.03 1.03 0.11 0.04 0.04 < 0.01 Potassium NV NV 0.7 0.7 0.6 1.6 0.9 1.5 2.7 1.7 1.6 2.2 1.5 3.1 2 2.3 0.3 2.6 Selenium 0.1 0.001 NV 0.1 ------Silver 0.0001 0.00025 NV 0.0001 ------Sodium NV NV 2.7 2.7 3.4 4.8 2.8 3 3.3 4.2 6.1 3.5 4.5 6.9 3.8 6.9 5.7 6.1 Thallium 0.0003 0.0008 NV 0.0003 ------Tungsten 0.03 NV NV 0.03 ------Uranium 0.005 0.015 NV 0.005 ------Vanadium 0.006 NV NV 0.006 ------Zinc 0.02 0.03 0.01 0.02 - - < 0.005 - 0.037 - - 0.009 - - 0.028 - - < 0.005 Zirconium 0.004 NV NV 0.004 ------Conductivity (µs/cm)7 NV NV 86 86 140 195 95 132 177 175 179 209 126 240 81 187 169 112 pH (units)7 6.5 - 8.5 NA 7.56 6.5 - 8.5 6.91 5.88 7.32 6.15 6.51 6.91 5.93 7.3 6.75 7.96 6.83 - 6.5 6.25 Temperature (°C)7 NV NV 18.9 18.9 16.5 18.7 0.8 15.8 11.4 23.2 25.7 7.8 13 17 2.1 19 18.4 3.3 Oxidation Reduction Potential (mV)7 NV NV NV NV ------Dissolved Oxygen7 5.0 NV 8.0 5.0 2.88 2.52 662 78792441.69 Notes: 1. All results are expressed in mg/L unless otherwise stated. 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines for the Protection of Aquatic Life. 4. Bold text indicate values exceeding PWQO or CWQG criteria 4. Bold text and shading indicate values exceeding the trigger value. 5. 75th percentile as calculated from a minimum of six (1) events, not including the current year, at station SW1. 6. "-" parameter not analyzed. 7. Results from field analysis. 8. Calculated from Total Ammonia and field data. 9. NV means no value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 5: Summary of Surface Water Quality
SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 SW3 Parameter PWQO 2 CWQG3 75th Percentile 5 Trigger 10-Jun-14 25-Aug-14 18-Nov-14 25-May-15 09-Nov-15 19-Apr-16 05-Oct-16 03-May-17 18-Sep-17 22-May-18 01-Nov-18
Alkalinity (CaCO3) decrease >25% NV 36 36 78 77 54 81 56 45 95 41 91 85 60
Bicarbonates (CaCO3) NV NV NV NV ----564595-918560 Colour (TCU) NV NV NV NV - 49204622235839275230 Conductivity (µs/cm) NV NV 91 91 197 184 139 197 153 124 285 118 225 221 164 pH (units) 6.5-8.5 6.5-9.0 7.29 6.5-8.5 7.16 7.2 7.09 7.38 7.37 7.38 7.78 7.68 7.3 7.68 7.36 Solids - Total Dissolved (TDS) NV NV 50.0 50 109 101 76 108 84 68 157 65 124 113 83 Solids - Total Suspended (TSS) NV NV 41.0 41 3141083663188 4 Carbon - Dissolved Organic (DOC) NV NV NV NV - 15.3 8 11 6.8 5.3 12.3 6.2 11.5 12.1 8.3 Oxygen Demand - Biological (BOD) NV NV 4.0 4.0 2-----< 233 5 3 Oxygen Demand - Chemical (COD) NV NV 28 28.0 27-----32 16 39 32 21 Total - Phenolics NV NV 0.001 0.001 < 0.001-----< 0.001< 0.001< 0.001< 0.0010.004 Chloride NV 120 4 120 9.4 6.3 6.3 8.1 8.8 7.1 19.6 8 10.7 16.9 12.4
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.05 0.05 0.09 0.19 < 0.01 0.17 0.04 0.02 0.06 < 0.01 0.06 0.05 0.08 Ammonia (N)-unionized 0.02 0.02 0.003 0.02 < 0.005 0.1900 - < 0.005 < 0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 Sulphate NV NV 3 3 1< 12< 12 493< 1< 12
Nitrogen - Nitrite (NO2) NV 0.06 0.1 0.1 < 0.1-----< 0.1< 0.05< 0.05< 0.05< 0.05
Nitrogen - Nitrate (NO3) NV 3 0.1 3 < 0.1-----< 0.1< 0.05< 0.05< 0.05< 0.05 Nitrogen - Total Kjeldahl (TKN) NV NV 0.8 0.8 0.6-----0.60.50.70.80.5 Mercury 0.0002 0.00003 NV 0.0002 ------< 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002
Hardness (as CaCO3 ) NV NV 42 42 87 --90 69 53 - 53 113 110 89 Aluminum (total) 0.075 NV NV 0.075 - - - 0.02 0.08 0.02 0.02 0.03 0.07 0.04 0.05 Antimony 0.02 NV NV 0.02 ----0.0001 < 0.0001 0.0001 0.0001 0.0004 0.0002 < 0.0001 Arsenic 0.005 0.005 0.0006 0.005 - - - 0.0003 0.0002 0.0001 0.0004 0.0004 0.0005 0.0003 0.0003 Beryllium 0.011 NV NV 0.011 ----< 0.002< 0.002< 0.002< 0.002< 0.002< 0.002< 0.002 Boron 0.2 1.5 0.006 0.2 - 0.064 0.026 0.038 0.034 0.011 0.065 0.015 0.076 0.034 0.037 Cadmium 0.0001 0.00009 0.00006 0.0001 - - - < 0.00002 0.00004 < 0.00002 < 0.00002 < 0.000014 0.000031 < 0.000015 0.000027 Calcium NV NV 14 14 27 28 13.6 28 20.9 16.6 35.7 16.1 34.8 34 26.4 Chromium 0.001 0.001 0.002 0.002 - - - < 0.002 < 0.002 < 0.002 < 0.002 < 0.001 < 0.001 < 0.001 < 0.001 Cobalt 0.0009 NV NV 0.0009 ----< 0.0001 < 0.0001 0.0002 < 0.0001 0.0005 0.0002 0.0004 Copper 0.005 NV 0.002 0.005 - - - < 0.0001 0.0021 0.0002 0.0004 0.0005 0.0052 0.0002 0.0067 Iron 0.3 0.3 1.8 1.8 2.42 1.6 0.255 2.75 0.65 0.291 1.53 0.572 4.23 1.74 1.95 Lead 0.003 NV 0.0005 0.003 - - - < 0.00002 0.00048 0.00006 < 0.00002 0.00006 0.00098 0.00006 0.00031 Magnesium NV NV 1.95 1.95 4.61 4.58 2.71 4.86 4.15 2.91 6.57 2.99 6.43 6.13 5.68 Manganese NV NV 0.337 0.337 0.255 0.281 0.014 0.567 0.034 0.03 0.195 0.023 0.495 0.281 0.224 Molybdenum 0.04 0.073 NV 0.04 ----< 0.01< 0.01< 0.01< 0.01< 0.01< 0.01< 0.01 Nickel 0.025 NV NV 0.025 ----0.0014 0.0004 0.0011 0.0007 0.0023 0.001 0.0011 Phosphorus - Total 0.03 NV 0.09 0.09 0.11 0.05 0.04 0.03 0.1 0.01 0.01 0.03 - 0.06 0.02 Potassium NV NV 0.7 0.7 1.4 1.7 2 1.7 2.2 1.3 2 0.9 3.3 1.8 2.1 Selenium 0.1 0.001 NV 0.1 ----< 0.001< 0.001< 0.001< 0.001< 0.001< 0.001< 0.001 Silver 0.0001 0.00025 NV 0.0001 ----< 0.00002 < 0.00002 0.00014 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium NV NV 2.7 2.7 6 6.3 3.6 6.3 5.2 4.7 11.7 4.6 8.4 9.3 7.2 Thallium 0.0003 0.0008 NV 0.0003 ----< 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten 0.03 NV NV 0.03 -----< 0.01-< 0.01< 0.01< 0.01< 0.01 Uranium 0.005 0.015 NV 0.005 ----0.00088 < 0.00005 < 0.00005 < 0.00005 0.00017 < 0.00005 0.00049 Vanadium 0.006 NV NV 0.006 ----< 0.005< 0.005< 0.005< 0.005< 0.005< 0.005< 0.005 Zinc 0.02 0.03 0.01 0.02 - - - < 0.005 0.046 < 0.005 0.013 < 0.005 0.075 0.019 0.023 Zirconium 0.004 NV NV 0.004 -----< 0.003-< 0.003< 0.003< 0.003< 0.003 Conductivity (µs/cm)7 NV NV 86 86 211 224 78 210 160 190 290 180 250 240 190 pH (units)7 6.5 - 8.5 NA 7.56 6.5 - 8.5 7.04 15.1 - 6.53 7.38 7.92 7.72 7.52 7.46 - 7.93 Temperature (°C)7 NV NV 18.9 18.9 25.2 19.3 -0.6 15.1 5.6 16.4 16.0 16.0 16.7 16.3 6.9 Oxidation Reduction Potential (mV)7 NV NV NV NV - - - -40 -30 -66 36 136 127 56 167 Dissolved Oxygen7 5.0 NV 8.0 5.0 6.18 4.95 5.3 2.33 7.16 8.4 6.44 7.33 1.77 4.41 5.71 Notes: 1. All results are expressed in mg/L unless otherwise stated. 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines for the Protection of Aquatic Life. 4. Bold text indicate values exceeding PWQO or CWQG criteria 4. Bold text and shading indicate values exceeding the trigger value. 5. 75th percentile as calculated from a minimum of six (1) events, not including the current year, at station SW1. 6. "-" parameter not analyzed. 7. Results from field analysis. 8. Calculated from Total Ammonia and field data. 9. NV means no value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site Cambium Ref.: 7215-007
Table 5: Summary of Surface Water Quality
SW4 SW4 SW4 SW4 SW4 Parameter PWQO 2 CWQG3 75th Percentile 5 Trigger 05-Oct-16 03-May-17 18-Sep-17 22-May-18 01-Nov-18
Alkalinity (CaCO3) decrease >25% NV 36 36 98 33 56 42 68
Bicarbonates (CaCO3) NV NV NV NV 98 - 56 42 68 Colour (TCU) NV NV NV NV 20 36 35 48 54 Conductivity (µs/cm) NV NV 91 91 229 92 127 100 153 pH (units) 6.5-8.5 6.5-9.0 7.29 6.5-8.5 7.88 7.56 7.18 7.64 7.56 Solids - Total Dissolved (TDS) NV NV 50.0 50 126 51 70 51 78 Solids - Total Suspended (TSS) NV NV 41.0 41 852463 Carbon - Dissolved Organic (DOC) NV NV NV NV 8.4 5.4 10.5 8.4 8.5 Oxygen Demand - Biological (BOD) NV NV 4.0 4.0 2235 < 3 Oxygen Demand - Chemical (COD) NV NV 28 28.0 22 15 32 34 20 Total - Phenolics NV NV 0.001 0.001 < 0.001 < 0.001 < 0.001 < 0.001 0.005 Chloride NV 120 4 120 7.1 4.2 3.9 4.6 4.7
Nitrogen - Ammonia (NH3) & Ammonium (NH4) NV NV 0.05 0.05 0.49 0.05 0.32 0.08 0.52 Ammonia (N)-unionized 0.02 0.02 0.003 0.02 <0.005 <0.005 <0.005 <0.005 <0.005 Sulphate NV NV 3 3 33< 1< 11
Nitrogen - Nitrite (NO2) NV 0.06 0.1 0.1 < 0.1 < 0.05 < 0.05 < 0.05 < 0.05
Nitrogen - Nitrate (NO3) NV 3 0.1 3 0.1 < 0.05 < 0.05 < 0.05 < 0.05 Nitrogen - Total Kjeldahl (TKN) NV NV 0.8 0.8 0.9 0.5 0.8 0.8 1.1 Mercury 0.0002 0.00003 NV 0.0002 < 0.00002 < 0.00002 < 0.00002 < 0.00002 < 0.00002
Hardness (as CaCO3 ) NV NV 42 42 -3474 58 86 Aluminum (total) 0.075 NV NV 0.075 0.02 0.04 0.08 0.04 0.03 Antimony 0.02 NV NV 0.02 < 0.0001 0.0002 < 0.0001 0.0004 0.0003 Arsenic 0.005 0.005 0.0006 0.005 0.0004 0.0003 0.0009 0.0003 0.0004 Beryllium 0.011 NV NV 0.011 < 0.002 < 0.002 < 0.002 < 0.002 < 0.002 Boron 0.2 1.5 0.006 0.2 0.104 0.018 0.043 0.017 0.042 Cadmium 0.0001 0.00009 0.00006 0.0001 < 0.00002 < 0.000014 0.000057 < 0.000015 < 0.000015 Calcium NV NV 14 14 29.8 10.3 23.1 17.8 26.3 Chromium 0.001 0.001 0.002 0.002 < 0.002 < 0.001 < 0.001 < 0.001 < 0.001 Cobalt 0.0009 NV NV 0.0009 0.0002 < 0.0001 0.0012 0.0002 0.0003 Copper 0.005 NV 0.002 0.005 < 0.0001 0.0005 0.005 0.0003 0.0003 Iron 0.3 0.3 1.8 1.8 3.47 0.429 5.91 1.28 4.05 Lead 0.003 NV 0.0005 0.003 < 0.00002 0.0001 0.00062 0.00015 0.00008 Magnesium NV NV 1.95 1.95 5.15 1.92 3.86 3.19 4.98 Manganese NV NV 0.337 0.337 0.289 0.033 0.683 0.108 0.226 Molybdenum 0.04 0.073 NV 0.04 < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 Nickel 0.025 NV NV 0.025 0.0014 0.0005 0.0032 0.001 0.0009 Phosphorus - Total 0.03 NV 0.09 0.09 0.03 0.04 - 0.06 0.05 Potassium NV NV 0.7 0.7 3.2 0.9 1.9 0.8 2 Selenium 0.1 0.001 NV 0.1 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 Silver 0.0001 0.00025 NV 0.0001 0.00012 < 0.00002 < 0.00002 < 0.0001 < 0.0001 Sodium NV NV 2.7 2.7 7.2 2.8 4 4.1 5.3 Thallium 0.0003 0.0008 NV 0.0003 < 0.00005 < 0.00005 < 0.00005 < 0.00005 < 0.00005 Tungsten 0.03 NV NV 0.03 - < 0.01 < 0.01 < 0.01 0.02 Uranium 0.005 0.015 NV 0.005 < 0.00005 < 0.00005 0.00017 < 0.00005 < 0.00005 Vanadium 0.006 NV NV 0.006 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Zinc 0.02 0.03 0.01 0.02 < 0.005 < 0.005 0.068 0.024 0.023 Zirconium 0.004 NV NV 0.004 - < 0.003 < 0.003 < 0.003 < 0.003 Conductivity (µs/cm)7 NV NV 86 86 240 110 150 100 180 pH (units)7 6.5 - 8.5 NA 7.56 6.5 - 8.5 7.35 7.45 7.48 - 7.75 Temperature (°C)7 NV NV 18.9 18.9 16.9 13.9 17.8 17.6 7.4 Oxidation Reduction Potential (mV)7 NV NV NV NV 33 115 151 -55 172 Dissolved Oxygen7 5.0 NV 8.0 5.0 5.78 8.79 2.67 7.00 5.78 Notes: 1. All results are expressed in mg/L unless otherwise stated. 2. PWQO means Provincial Water Quality Objectives. 3. CWQG means Canadian Water Quality Guidelines for the Protection of Aquatic Life. 4. Bold text indicate values exceeding PWQO or CWQG criteria 4. Bold text and shading indicate values exceeding the trigger value. 5. 75th percentile as calculated from a minimum of six (1) events, not including the current year, at station SW1. 6. "-" parameter not analyzed. 7. Results from field analysis. 8. Calculated from Total Ammonia and field data. 9. NV means no value or not applicable. 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Appendix A Environmental Compliance Approval A371108
Cambium Inc. CONTENT COPY OF ORIGINAL
Ministry of the Environment Ministère de l’Environnement
AMENDMENT TO ENVIRONMENTAL COMPLIANCE APPROVAL NUMBER A371108 Notice No. 1 Issue Date: September 10, 2013
The Corporation of the Township of North Frontenac 6648 Road 506 Plevna, Ontario K0H 2M0
AND
The Corporation of the Township of Addington Highlands 72 Edward Street Flinton, Ontario K0H 1P0
Site Location: Cloyne Waste Disposal Site 202 Skootamatta Lake Rd, Part of Lot 20, Range A, Geographic Township of Anglesea, Township of Addington Highlands, County of Lennox and Addington
You are hereby notified that I have amended Approval No. A371108 issued on February 7, 2008 forthe establishment and operation of 4.0 hectares Waste Disposal Site within a total Site area of 8.09 hectares, as follows:
1. ERRATA - SITE OWNERSHIP/OPERATOR, TOTAL AREA AND SITE LOCATION
Pursuant to Condition 6.0 in Amended Provisional Certificate of Approval, Waste Disposal Site, No. A371108, dated February 7, 2008, approval is hereby granted for the correction of errors as appeared in the Certificate, for Ownership/Operator, location and total area of the Cloyne Waste Disposal Site, as follows:
A. The name and address of the Owner/Operator of the Site are corrected:
FROM: The Corporation of the Township of North Frontenac Post Office Box, No. 97 Plevna, Ontario K0H 2M0
TO: The Corporation of the Township of North Frontenac 6648 Road 506 Plevna, Ontario K0H 2M0
AND
The Corporation of the Township of Addington Highlands 72 Edward Street Flinton, Ontario K0H 1P0
B. Legal description of the Site Location is corrected: CONTENT COPY OF ORIGINAL
FROM: Cloyne Waste Disposal Site Lot 19, Concession Range A, Anglesea, Township of Addington Highlands, County of Lennox and Addington
TO: Cloyne Waste Disposal Site Part of Lot 20, Range A, Geographic Township of Anglesea, Township of Addington Highlands, County of Lennox and Addington;
C. The Total Site Area, including Waste Fill Area and Buffer is corrected:
FROM: 4.0 hectares Waste Disposal Site
TO: 4.0 hectares Waste Fill Area within a Total Site Area of 8.09 hectares, designated on Plan 29R-6964, received and deposited on November 21, 1995, as Part 1, Lot 20, Range A, Geographic Township of Anglesea, Township of Addington Highlands; and
2. SITE CLOSURE PLAN
Pursuant to Condition 21 in Approval, dated February 7, 2008, approval is hereby granted for the closure of the Cloyne Waste Disposal Site, in accordance with a report entitled "Site Closure Plan, Cloyne Waste Disposal Site, Certificate of Approval, A371108, Township of North Frontenac, dated August 2008", and the documentation listed below, and subject to the terms and conditions listed herein:
Documentation
The following documentation is hereby added to Schedule "A" and forms part of the Environmental Compliance Approval No. A371108:
1. Letter dated September 24, 2008 from Guy Laporte, Totten Sims Hubicki Associates to Tesfaye Gebrezghi, Director, Section 39, Environmental Protection Act, Ministry of the Environment, Re: Submission of closure plan to comply with Condition 21 of Approval No. A371108.
2. Report entitled "Site Closure Plan, Cloyne Waste Disposal Site, Certificate of Approval, A371108, Township of North Frontenac, dated August 2008", prepared by Totten Sims Hubicki Associates.
3. Letter dated October 5, 2012 from Guy Laporte, AECOM Canada Ltd. to Dickson Odame-Osafo, Environmental Approvals Branch, Ministry of the Environment, re: response to MOE's comment dated September 20, 2011, with respect to the Closure Plan for the Cloyne Waste Disposal Site.
4. Letter dated February 11, 2013 from Guy Laporte and Terry La Chapelle, AECOM Canada Ltd. to Dickson Odame- Osafo, Environmental Approvals Branch, Ministry of the Environment, re: Monitoring Programs, Trigger Mechanisms and Contingency Plan, closed Cloyne Waste Disposal Site.
5. Letter dated July 17, 2013 from Guy Laporte and Terry La Chapelle, AECOM Canada Ltd. to Dickson Odame-Osafo, Environmental Approvals Branch, Ministry of the Environment, re: Final cap with a 3 horizontal to 1 vertical slope, closed Cloyne Waste Disposal Site.
For the purposes of the Environmental Compliance Approval, and the terms and conditions specified, the following definitions apply:
Definitions
Definition for Owner in Approval dated February 7, 2008, is hereby revoked and replaced with a new definition for Owner as follows:
"Owner" means any person that is responsible for the establishment or operation of the Site that is approved by this Approval, and includes the Corporation of the Township of North Frontenac and the Corporation of the Township of CONTENT COPY OF ORIGINAL
Addington Highlands, and their successors and assigns.
"Site" means the entire 8.09 hectares property, located on Part of Lot 20, Range A, Geographic Township of Anglesea, Township of Addington Highlands, County of Lennox and Addington, and operations approved by the Environmental Compliance Approval, No. A371108.
You are hereby notified that this approval is issued to you subject to the terms and conditions outlined below:
TERMS AND CONDITIONS
Conditions 8.2 and 17.1(c) in the Approval dated February 7, 2008, are hereby amended by deleting the words "on Site" and replacing with "at the municipal office", such that the new Conditions read as follows:
8.2 All records referred to in the Approval shall be retained at the municipal office for a minimum of three (3) years: - copy of Approvals be immediately available on Site; - waste dumping and Recycling Depot records be available on Site for the operating day.
17.1 (c) The Owner shall complete and retain at the municipal office a complaint report written within one (1) week of complaint date, listing the actions taken to resolve the complaint and any recommendations for remedial measures, and managerial or operational changes to reasonably avoid the recurrence of similar incidents.
1.0 Site Closure
1.1 The Site shall be closed for deposition of waste into the waste fill area for final disposal, and closure works, including final capping, post-closure care and monitoring of the Site, shall be completed in accordance with the Closure Plan, (Sections 3.0, 4.0 and 5.0), Item 2 of Schedule "A", as amended by letters dated October 5, 2012 and February 11, 2013, respectively listed as Items 3 and 4, in Schedule "A", attached to this Approval. Updates to the Closure Plan as appropriate, may be carried out and implemented, subject to a prior written concurrence in advance, by the District Manager.
1.2 The Owner shall carry out closure processes, including but not limited to removal of unwanted landfilling-related structures/buildings, waste fill area regrading to achieve the final contours ready to receive the final cover, improving site security/fencing and access gate to good working state, and shall prepare and follow complaints response protocol.
Final Cover
1.3 The waste fill area shall be completely capped with a final cover uncontaminated soil, consisting of a base layer of 600 mm minimum thickness of low permeability clay/silty clay soil, compacted in 200 mm thick lifts, overlain by 150 mm thickness of top soil, as described in Sections 3.2 to 3.4, Item 2 in Schedule "A", attached to this Approval. As soon as practicable, the completed final cover shall be seeded to provide vegetative cover against erosion.
1.4 The Owner shall ensure that appropriate slopes on the sides, and on the top flat areas of the final cover, are maintained, to keep the slopes stable against failure and to help prevent erosion, and to avoid ponding of water on the landfill mound, respectively.
2.0 Post-Closure Inspection/Maintenance
2.1 The Owner shall ensure that the Site, including the integrity of the final cover against subsidence, erosion and slope failure, access roads and general site features, are inspected and maintained, as described in Item 2 (Sections 3.6 to 3.9 and 3.12) of Schedule "A", and also committed in Item 5 of Schedule "A", attached to this Approval.
2.2 Where deficiencies exist or the integrity of the final cover, access gate, posted signs, fence, groundwater, surface water and landfill gas monitoring facilities, is impaired, the Owner shall carry out repairs promptly within a reasonable time period of first identification of the problem, and the results reported in the Annual Post-Closure Monitoring Report.
3.0 Post-Closure Monitoring Programs
3.1 Except as noted otherwise in Conditions 3.3 and 3.6 below, the Owner shall carry out monitoring programs for CONTENT COPY OF ORIGINAL groundwater/leachate, surface water and landfill gas, as described and summarized in Table 1 in Item 4 of Schedule "A", attached to this Approval, and in accordance with this Approval and any applicable legislation.
Groundwater Monitoring Wells and/or Drive Points
3.2 As soon as reasonably practical, the Owner shall install, at least, one (1) groundwater monitoring well nests in addition to the existing four (4) wells, as described in Item 4 of Schedule "A", attached to this Approval. The proposed location(s) and the number of well nests shall be confirmed with the District Manager in consultation with the Ministry's Regional Technical Support Group.
3.3 Groundwater/leachate shall be sampled and analysed twice per year (spring and fall), as described and summarised in Table 1 in Item 4 of Schedule "A", attached to this Approval, for a minimum of four years, subject to change, based on test results and concurrence of the District Manager. The method detection limits for all parameters shall not exceed 1/5 of the PWQO values, where this detection limits can be achieved.
3.4 The Owner shall ensure that water monitoring program at the Site shall be in compliance with the Ministry's Reasonable Use Guideline (Guideline B-7) for groundwater, and shall comply with the Provincial Water Quality Objectives for surface water.
3.5 Where groundwater discharges to surface water or wetland, the groundwater quality shall comply with the Provincial Water Quality Objectives. If test results confirm non-compliance of groundwater quality with the Provincial Water Quality Objectives, or any other monitored parameter found to be present at concentrations deemed to be unacceptable, due to landfill leachate, an assessment of the potential impact of the discharging groundwater quality on the receiving wetland and/or surface water, along with mitigation action, as necessary, shall be carried out.
Surface Water Monitoring Stations
3.6 Surface water shall be sampled and analysed twice per year (spring and fall), as described and summarised in Table 1 in Item 4 of Schedule "A", attached to this Approval, subject to the inclusion in the list in Table 1, in Item 4 of Schedule "A", of Mercury, Nitrogen species (Nitrate, Nitrite, TKN), BOD5 COD and Phenols. The method detection limits for all parameters shall not exceed 1/5 of the PWQO values, where this detection limits can be achieved.
Landfill gas Monitoring
3.7 Landfill gas (methane concentration and pressure) shall be monitored from appropriate gas monitoring probes at the Site, as described in Item 4 of Schedule "A", attached to this Approval.
Changes to Monitoring Program
3.8 A recommendation for proposed changes to the monitoring programs under this Approval may be made in the Annual Post-closure Monitoring Report, based on the results to date, and may only be implemented subject to the prior written concurrence of the District Manager.
3.9 Any groundwater/leachate monitoring wells, or surface water monitoring points, or landfill gas monitoring probes, included in the monitoring program that gets damaged or in any way made inoperable for sampling, shall be assessed, repaired, replaced or decommissioned, by the Owner/Operator, as the case may be.
4.0 Trigger Mechanisms and Contingency Plans
4.1 Monitoring programs to determine compliance of Trigger concentrations with respect to Provincial Water Quality Objectives, as well as comparison with background water quality, or any other monitored parameter found to be present at concentrations deemed to be unacceptable, shall be based on groundwater in the vicinity of the wetlands and Surface Water, as outlined in Item 4 of Schedule "A", attached to this Certificate. The results of this monitoring shall be assessed promptly when received and remedial actions, including contingency plans, as described in Item 4 of Schedule "A", attached to this Approval, or appropriate alternative method, as approved by the District Manager, shall be initiated/implemented, as necessary. A summary of the results of this monitoring shall be reported in the Annual Post- Closure Monitoring Report. CONTENT COPY OF ORIGINAL
The following trigger mechanisms for monitoring shall apply:
4.1.1 Groundwater/leachate Trigger Mechanisms:
(a) Trigger Locations - Trigger and compliance monitoring locations shall be monitors DP2, DP3, and DP4, which shall be in the vicinity of the wetlands and/or Surface Water, as described in Item 4 of Schedule "A", and/or additional trigger monitoring wells as may be required.
(b) Trigger Parameters and Compliance Criteria – Trigger parameters shall include all analytical parameters listed in Table 1 in Item 4 of Schedule "A", for which there is Provincial Water Quality Objectives (PWQO). The trigger parameters shall comply with the Provincial Water Quality Objectives.
4.1.2 Surface Water Trigger Mechanisms:
(a) Trigger Locations - Trigger and compliance monitoring locations shall be stations SW1 and SW3, as described in Item 4 of Schedule "A", and/or additional trigger monitoring stations as may be required.
(b) Trigger Parameters and Compliance Criteria – Trigger Parameters shall be all chemical parameters listed in Table 1 in Item 4 of Schedule "A", attached to this Approval. The trigger parameters shall comply with the Provincial Water Quality Objectives (PWQO)/CWQG or background. The background concentration to determine compliance, shall be calculated as 75th percentile of background concentration, based on a minimum of six (6) data points.
4.2 In the event of two (2) consecutive exceedances of a site-specific trigger criteria relating to surface water impacts due to groundwater/leachate, the Owner/Operator shall notify the District Manager, and shall follow the trigger mechanism and contingency plan, as described in Item 4 of Schedule "A", attached to this Certificate.
Changes to Trigger Mechanism
4.3 A recommendation to change the site-specific trigger mechanism and contingency plans for groundwater and surface water impacts due to leachate, may be made in the Annual Post-Closure Monitoring Report, based on the results to date, and subject to the written concurrence of the District Manager.
5.0 Annual Post-Closure Monitoring Reports
5.1 Annual Post-Closure Monitoring Report on the post-closure inspection/maintenance and monitoring of the Site, prepared by a qualified professional engineer or Geo-Scientist, and based on Items 2 and 4 in Schedule "A", attached to this Approval, and Conditions of this Approval, shall be prepared. The Annual Post-Closure Monitoring Report shall be submitted to the District Manager by May 31 each year, and shall cover the preceding calendar year. The Annual Post- Closure Monitoring Report shall include, but is not limited to the following:
(a) Executive Summary or Equivalent:
A summary of the findings, conclusions and recommendations.
(b). Environmental Quality Monitoring:
i. a site plan showing the locations of existing and changes to the monitoring network; ii a description of the conditions at each surface water and groundwater sampling location; iii. The results and interpretive analysis of the results of all groundwater/leachate, surface water and landfill gas monitoring programs, including an assessment of the need to amend the monitoring programs and trigger mechanisms or to implement contingency measures. iv. an assessment of the surface water quality in relation to Provincial Water Quality Objectives v. an assessment of the groundwater quality in relation to RUG/Provincial Water Quality Objectives and its CONTENT COPY OF ORIGINAL
impact on the receiving wetland and surface water body; vi. an assessment of the adequacy of the Contaminant Attenuation Zone, and/or the need to implement contingency action; vii. an assessment of the physical conditions of the monitoring points.
(c). Post-Closure Inspection/Maintenance:
i. a site plan showing the status of the final cover, and any changes in the final cover resulting from post closure maintenance and repairs; ii. a description of any identified site deficiencies and remedial actions implemented; iii. a description of complaints procedure and a summary of the public complaints registered against the Site, and the Owner/Operator's response and abatement action, if complaints are received; iv. a statement as to compliance with all the conditions of the Certificate of Approval; v. any changes to the closure plan that has been approved by the District Manager since the last Annual Post- Closure Monitoring Report, and any other information with respect to the Site which the District Manager may require from time to time.
(d). Recommendations:
i. Recommendations respecting any proposed changes to the monitoring program or repairs required to the monitoring network; ii. Recommendations respecting the requirement for any remedial works based on the environmental quality monitoring.
REASONS
The reason(s) for this amendment to the Approval is (are) as follows:
1. The reasons for approval of the Closure Plan and Conditions 1.0, 2.0, and 3.0 are to acknowledge that the landfill site is closed, and to ensure that appropriate closure processes, including final capping, are followed, and the closed landfill site is inspected, maintained and monitored in an environmentally acceptable manner for the protection of the natural environment and public health and safety.
2. The reason for Condition 4.0 is to provide for a mechanism which provides early warning of potential impact, to allow sufficient time to prepare and implement remedial action.
3. The reasons for Condition 5.0 are to ensure that regular review of site maintenance and monitoring data are documented and any possible improvements to site monitoring programs are identified. An annual post-closure monitoring report is an important tool used in reviewing post-closure monitoring and maintenance activities, its effect or relationship to any nuisance or environmental impacts, and for helping to ensure that the landfill site continues to perform as designed. Post-closure care will be required for as long as contaminants from the site pose a potential concern to the natural environment. Record keeping is necessary to determine compliance with this Approval, the EPA and its regulations.
This Notice shall constitute part of the approval issued under Approval No. A371108 dated February 7, 2008, as amended.
In accordance with Section 139 of the Environmental Protection Act, you may by written Notice served upon me and the Environmental Review Tribunal within 15 days after receipt of this Notice, require a hearing by the Tribunal. Section 142 of the Environmental Protection Act provides that the Notice requiring the hearing shall state:
1. The portions of the environmental compliance approval or each term or condition in the environmental compliance approval in respect of which the hearing is required, and; 2. The grounds on which you intend to rely at the hearing in relation to each portion appealed.
Pursuant to subsection 139(3) of the Environmental Protection Act, a hearing may not be required with respect to any terms and conditions in this environmental compliance approval, if the terms and conditions are substantially the same as CONTENT COPY OF ORIGINAL those contained in an approval that is amended or revoked by this environmental compliance approval.
The Notice should also include:
3. The name of the appellant; 4. The address of the appellant; 5. The environmental compliance approval number; 6. The date of the environmental compliance approval; 7. The name of the Director, and; 8. The municipality or municipalities within which the project is to be engaged in.
And the Notice should be signed and dated by the appellant.
This Notice must be served upon:
The Director appointed for the purposes of Part II.1 of The Secretary* the Environmental Protection Act Environmental Review Tribunal Ministry of the Environment 655 Bay Street, Suite 1500 AND 2 St. Clair Avenue West, Floor 12A Toronto, Ontario Toronto, Ontario M5G 1E5 M4V 1L5
* Further information on the Environmental Review Tribunal’s requirements for an appeal can be obtained directly from the Tribunal at: Tel: (416) 212-6349, Fax: (416) 314-4506 or www.ert.gov.on.ca
The above noted activity is approved under s.20.3 of Part II.1 of the Environmental Protection Act.
DATED AT TORONTO this 10th day of September, 2013 Tesfaye Gebrezghi, P.Eng. Director appointed for the purposes of Part II.1 of the Environmental Protection Act DO/ c: District Manager, MOE Kingston - District Guy Laporte, P. Eng., AECOM Canada Ltd CONTENT COPY OF ORIGINAL
Ministry Ministère AMENDED PROVISIONAL CERTIFICATE OF APPROVAL of the de WASTE DISPOSAL SITE Environment l’Environnement NUMBER A371108 Issue Date: February 7, 2008 Ontario The Corporation of the Township of North Frontenac P.O. Box 97 Plevna, Ontario K0H 2M0
Site Location: Cloyne Waste Disposal Site Lot 19, Concession Range A, Anglesea Addington Highlands Township, County of Lennox and Addington
You have applied in accordance with Section 27 of the Environmental Protection Act for approval of: the closure of the Waste Disposal Site (Landfill - see Condition 21.0) and the establishment and operation of a 4.0 hectare Waste Disposal Site (Transfer) to be used for the receipt, temporary storage and transfer of non-hazardous solid domestic and commercial waste generated within the Province of Ontario.
For the purpose of this Certificate of Approval and the terms and conditions specified below, the following definitions apply:
- “Act” means the Environmental Protection Act (EPA), R.S.O. 1990, C.E-19, as amended;
- “bulking” means the mixing of similar waste types into a single container in a secure and safe manner;
- “Certificate” means this entire provisional Certificate of Approval document, issued in accordance with section 39 of the Act, and includes any schedules to it, the application and the supporting documentation listed in Schedule "A";
- “competent” means an employee who has received training in accordance with Condition 12.2;
- “Director” means any Ministry employee appointed in writing by the Minister pursuant to section 5 of the EPA as a Director for the purposes of Part V of the EPA;
- “District Manager” means the District Manager of the local district office of the Ministry in which the Site is geographically located;
- “District Office” means the Kingston District Office, Ministry of the Environment;
- “EPA” means Environmental Protection Act, R.S.O. 1990, c. E. 19, as amended;
- “HHW” means household hazardous waste;
- “ICI” means industrial, commercial or institutional;
- “LDR” means Lands Disposal Restrictions referring to sections 74 through 85 of Ontario Regulation 347, which prohibit the disposal of listed and characteristic hazardous wastes on land until they have been treated to meet the treatment standards under Ontario Regulation 347;
- “Ministry” and “MOE” means the Ontario Ministry of the Environment;
- “Ontario Regulation 347" means Ontario Regulation 347, R.R.O. 1990, General - Waste Management, made under the Act,as amended from time to time; CONTENT COPY OF ORIGINAL
- “Operator” means any person, other than the Owner's employees, authorized by the Owner as having the charge, management or control of any aspect of the Site and includes its successors or assigns;
- “Owner” means any person that is responsible for the establishment or operation of the Site being approved by this Certificate, and includes the Corporation of the Township of North Frontenac, its successors and assigns;
- “OWRA” means the Ontario Water Resources Act, R.S.O. 1990, c. O.40, as amended;
- “PA” means the Pesticides Act, R.S.O. 1990, c. P-11, as amended from time to time;
- “Provincial Officer” means any person designated in writing by the Minister as a provincial officer pursuant to section 5 of the OWRA or section 5 of the EPA or section 17 of PA;
- “Regional Director” means the Regional Director of the local Regional Office of the Ministry in which the Site is located;
- “Regulation 347” or “Reg. 347” means Regulation 347, R.R.O. 1990, made under the EPA,as amended from time to time;
- “Site" means the 4.0 hectares property, located at Lot 19, Range A, geographic township of Anglesea Township of Addington Highlands, County of Lennox & Addington, approved by this Certificate;
- “Trained personnel” means knowledgeable in the following through instruction and/or practice: (a) relevant waste management legislation, regulations and guidelines; (b) major environmental concerns pertaining to the waste to be handled; (c) occupational health and safety concerns pertaining to the processes and wastes to be handled; (d) management procedures including the use and operation of equipment for the processes and wastes to be handled; (e) emergency response procedures; (f) specific written procedures for the control of nuisance conditions; (g) specific written procedures for refusal of unacceptable waste loads; and (h) the requirements of this Certificate.
You are hereby notified that this approval is issued to you subject to the terms and conditions outlined below:
1.0 Compliance
1.1 The Owner shall ensure compliance with all the conditions of this Certificate and shall ensure that any person authorized to carry out work on or operate any aspect of the Site is notified of this Certificate and the conditions herein and shall take all reasonable measures to ensure any such person complies with the same.
1.2 Any person authorized to carry out work on or operate any aspect of the Site shall comply with the conditions of this Certificate.
2.0 In Accordance
2.1 Except as otherwise provided for in this Certificate, the Site shall be designed, developed, built, operated and maintained in accordance with the application for this Certificate, dated January 24, 2007, and the supporting documentation listed in Schedule “A”.
3.0 Interpretation
3.1 Where there is a conflict between a provision of any document, including the application, referred to in this Certificate, and the conditions of this Certificate, the conditions in this Certificate shall take precedence.
3.2 Where there is a conflict between the application and a provision in any documents listed in Schedule "A", the CONTENT COPY OF ORIGINAL application shall take precedence, unless it is clear that the purpose of the document was to amend the application and that the Ministry approved the amendment.
3.3 Where there is a conflict between any two documents listed in Schedule "A", other than the application, the document bearing the most recent date shall take precedence.
3.4 The conditions of this Certificate are severable. If any condition of this Certificate, or the application of any condition of this Certificate to any circumstance, is held invalid or unenforceable, the application of such condition to other circumstances and the remainder of this Certificate shall not be affected thereby.
4.0 Other Legal Obligations
4.1 The issuance of, and compliance with, this Certificate does not:
(a) relieve any person of any obligation to comply with any provision of any applicable statute, regulation or other legal requirement; or (b) limit in any way the authority of the Ministry to require certain steps be taken or to require the Owner to furnish any further information related to compliance with this Certificate.
4.2 All wastes at the Site shall be managed and disposed in accordance with the Act and Ontario Regulation 347.
4.3 The Owner shall ensure that:
(a) all equipment discharging to air operating at the Site are approved under Section 9 of the Act; and (b) all effluent and stormwater runoff is discharged in accordance with OWRA.
5.0 Adverse Effect
5.1 The Owner shall take steps to minimize and ameliorate any adverse effect on the natural environment or impairment of water quality resulting from the Site, including such accelerated or additional monitoring as may be necessary to determine the nature and extent of the effect or impairment.
5.2 Despite an Owner, or any other person, fulfilling any obligations imposed by this Certificate, the person remains responsible for any contravention of any other condition of this Certificate or any applicable statute, regulation, or other legal requirement resulting from any act or omission that caused the adverse effect to the natural environment or impairment of water quality.
6.0 Change of Owner
6.1 The Owner shall notify the Director, in writing, and forward a copy of the notification to the District Manager, within 30 days of the occurrence of any changes in the following information:
(a) the ownership of the Site; (b) the appointment of, or a change in, the Operator of the Site; (c) the address of the Owner; (d) the partners, where the Owner is or at any time becomes a partnership and a copy of the most recent declaration filed under the Business Names Act, R. S. O. 1990, c. B.17, shall be included in the notification;
6.2 No portion of this Site shall be transferred or encumbered prior to or after closing of the Site unless the Director is notified in advance and sufficient financial assurance is deposited with the Ministry to ensure that these conditions will be carried out.
6.3 In the event of any change in ownership of the works, other than change to a successor municipality, the Owner shall notify the successor of and provide the successor with a copy of this Certificate, and the Owner shall provide a copy of CONTENT COPY OF ORIGINAL the notification to the District Manager and the Director.
7.0 Ministry Inspections
7.1 No person shall hinder or obstruct a Provincial Officer from carrying out any and all inspections authorized by the OWRA, the Act, or the PA, of any place to which this Certificate relates, and without limiting the foregoing:
(a) to enter upon the premises where the approved works are located, or the location where the records required by the conditions of this Certificate are kept; (b) to have access to, inspect, and copy any records required to be kept by the conditions of this Certificate; (c) to inspect the Site, related equipment and appurtenances; (d) to inspect the practices, procedures, or operations required by the conditions of this Certificate; and (e) to sample and monitor for the purposes of assessing compliance with the terms and conditions of this Certificate or the Act, the OWRA or the PA.
8.0 Information and Record Retention
8.1 Any information requested, by the Ministry, concerning the Site and its operation under this Certificate, including but not limited to any records required to be kept by this Certificate shall be provided to the Ministry, upon request, in a timely manner.
8.2 All records referred to in this Certificateshall be retained on Sitefor a minimum of three (3) years: - originals of C of A documentation kept in the Municipal Office, photocopies kept on Site - originals of Dump Site & Recycling Depot Daily Record documentation kept in the Municipal Office, photocopies kept on Site.
8.3 The receipt of any information by the Ministry or the failure of the Ministry to prosecute any person or to require any person to take any action, under this Certificate or under any statute, regulation or other legal requirement, in relation to the information, shall not be construed as:
(a) an approval, waiver, or justification by the Ministry of any act or omission of any person that contravenes any term or condition of this Certificate or any statute, regulation or other legal requirement; or (b) acceptance by the Ministry of the information’s completeness or accuracy.
8.4 Any information relating to this Certificate and contained in Ministry files may be made available to the public in accordance with the provisions of the Freedom of Information and Protection of Privacy Act, R.S.O. 1990, C. F-31.
9.0 Approved Waste Types and Processes
9.1 (a) This Site is approved to receive non-hazardous solid domestic and commercial waste.
(b) This Site is approved to receive wastes listed in Condition 9.1(a) from sources located within North Frontenac and Addington Highlands as follows:
(i) received directly from residential sources; (ii) received directly from commercial sources;
9.2 The Owner shall set operational hours which provide an adequate level of service. The hours of operation when waste/reuse material shall be accepted at the Site: (a) shall fall between the hours of 6:00 a.m and 9:00 p.m. Monday through Sunday; and (b) shall be during daylight hours; and (c) may be changed by the Owner at any time provided that Condition 9.2(b) is met, CONTENT COPY OF ORIGINAL the hours are correctly posted at the Site gate and that suitable public notice is given of any change.
10.0 Site Operations
10.1 (a) The Owner shall ensure that all incoming waste is visually inspected and reconciled with incoming documentation (where applicable) by competent personnel to ensure that only approved waste is received at this Site.
(b) Waste not approved for receipt at this Site shall be refused and either returned to the generator or re-directed to an appropriate facility.
10.2 The Owner shall ensure that the maximum amount of waste received at the Site does not exceed 16 tonnes per day.
10.3 The Owner shall ensure that the maximum amount of waste stored at the Site does not exceed 90 cubic metres at any times.
10.4 The Owner shall maintain a plan identifying the location of each storage area and/or processing equipment and the waste it contains. The Owner shall ensure the plan is a true reflection of the materials stored on-Site and make the plan available for inspection upon request by emergency response personnel and/or Provincial Officers.
10.5 The Owner shall ensure that:
(b) all containers, used to store waste, are maintained in good condition to prevent leakage. The Owner will immediately remove from service any leaking container. Leaking or failing containers shall not be stored on Site unless they are placed within leakproof overpacked drums; (c) all containers, used to store or process waste, that may discharge a contaminant into the natural environment, are closed and/or covered during storage;
11.0 Signage and Security
11.1 The Owner shall secure the Siteand shall ensure that all storage facilities, processing facilities and loading/unloading facilities are kept secure and access is restricted only to authorized personnel.
11.2 The Owner shall post a sign at the main entrance/exit to the Site displaying, in a manner that is clear and legible, the following information:
(a) the name of the Site and Owner; (b) the number of this Certificate; (c) the normal hours of operation; (d) the allowable and prohibited waste types; and (e) a twenty-four (24) hour emergency telephone number which can be used to contact the Owner in the event of an emergency or complaint.
12.0 Training
12.1 The Owner shall ensure that all staff receive basic training with respect to on-site equipment, safety and operational details.
12.2 Employees are deemed competent when they are knowledgeable, through instruction and practise, of the following:
(a) terms, conditions and operating requirements of this Certificate; (b) operation and management of the Site, or area(s) within the Site, in accordance with the specific job requirements of each individual employee, and which may include procedures for receiving, screening and identifying, refusing, handling and temporarily storing wastes; CONTENT COPY OF ORIGINAL
(c) shipping and manifesting procedures, if such functions fall within the job requirements of an individual employee; (d) an outline of the responsibilities of Site personnel including roles and responsibilities during emergencies and spills; (e) the Spill Emergency and Contingency Plan including exit locations and evacuation routing, and location of relevant equipment available for emergencies and spills; (f) environmental, and occupational health and safety concerns pertaining to the wastes to be transferred; (g) emergency first-aid information; (h) relevant waste management legislation and regulations, including the Act and Ontario Regulation 347; (i) recording procedures as required under Condition 18.0; (j) equipment and inspection procedures, as required under Condition 15.1; (k) nuisance impact control procedures, as required under Condition 13.0; and (l) procedures for recording and responding to public complaints.
13.0 Nuisance Control
13.1 The Site shall be operated and maintained such that the vermin, vectors, dust, litter, odour, noise and traffic do not create a nuisance.
13.2 If at any time dust from vehicle traffic becomes an issue, the Owner shall implement dust suppression measures up to and including the asphalt paving of vehicle routes.
14.0 Stormwater Management
14.1 The Owner shall ensure that:
(a) waste is stored in a manner which prevents contact with precipitation; and (b) all surface water runoff is directed away from unloading, loading and storage areas.
15.0 Site Inspections and Maintenance
15.1 The Owner shall ensure that:
(a) this Site has a written comprehensive inspection program which includes all aspects of this Site's operations; (b) this Site is to be inspected by competent personnel for any deterioration or discharges and for compliance with this Certificate; and (c) the following inspection schedule is adhered to as a minimum:
(i) on each operating day, an inspection of the security fencing, receiving, storage and processing areas; (ii) on a quarterly basis, spill and emergency response equipment; and (iii) on an annual basis, an inspection of containment systems for cracks and spalling.
15.2 The Owner shall ensure that any deficiencies discovered as a result of the inspection shall be remedied immediately, including temporarily ceasing operations at the Site if needed.
15.3 The Owner shall develop and implement a preventative maintenance program, in accordance with manufacturers' recommendations, for all on-site equipment associated with the processing and managing of waste. The preventative maintenance program shall be maintained on-site and shall be available for inspection by a Provincial Officer upon request.
16.0 Emergency and Contingency Planning
16.1 (a) The Owner shall have in place an emergency response plan for the operation of the Site. The plan shall include, but is not limited to:
(i) emergency response procedures to be undertaken in the event of a spill, process upset, fire, explosion or medical emergency including specific actions to take in each circumstance; CONTENT COPY OF ORIGINAL
(ii) a list of emergency response equipment available (iii) a list of names and telephone numbers of first responders available for emergency response including spill response companies; and (iv) a notification protocol with names and telephone numbers of persons to be contacted, including Owner's personnel, the Ministry's Spills Action Centre and District Office, the local Municipality and fire department.
(b) A copy of the emergency response plan shall be kept in a central location available to all staff,
(c) the Owner shall ensure that the contingency equipment and materials outlined in the emergency response plan are in a good state of repair, fully operational and immediately available;
(d) the Owner shall ensure that all operating personnel are fully trained in the contingency equipment and materials' use and in the procedures to be employed in the event of an emergency;
(e) the Owner shall review the emergency response plan on an annual basis as a minimum. Specifically the Owner shall ensure that the contact names and telephone numbers required by Condition 16.1 (a) are up to date.
16.2 The Owner shall have in place a written contingency plan to address potential operational upsets such as, but not limited to:
(a) equipment failures; (b) power failures; (c) labour disruption; (d) unavailability of waste destination facilities, border closures or other issues that may disrupt the transfer of waste from the Site.
17.0 Complaints
17.1 If at any time, the Owner receives complaints regarding negative environmental impacts from the operation of the Site, the Owner shall respond to these complaints according to the following procedure:
(a) record and number each complaint, including the following information:
(i) the nature of the complaint, (ii) if the complaint is odour or nuisance related, the weather conditions and wind direction at the time of the complaint; (iii) the name, address and the telephone number of the complainant (if provided); and (iv) the time and date of the complaint;
(b) the Owner, upon notification of the complaint, shall initiate appropriate steps to determine all possible causes of the complaint, proceed to take the necessary actions to eliminate the cause of the complaint and forward a formal reply to the complainant; and (c) the Owner shall complete and retain on-site a report (originals kept in the Municipal Office, photocopies kept on Site) written within one (1) week of the complaint date, listing the actions taken to resolve the complaint and any recommendations for remedial measures, and managerial or operational changes to reasonably avoid the recurrence of similar incidents.
18.0 Record Keeping
18.1 The Owner shall maintain a log of inspections conducted to satisfy Condition 15.1. The log shall record the following information as a minimum: CONTENT COPY OF ORIGINAL
(a) the date and time of the inspections; (b) the results of the inspection; (c) corrective action taken to address any deficiencies noted in during the inspection; and (d) the signature of the person conducting the inspection.
18.2 The Owner shall maintain a written record of all employee training required under Condition 12.0. The information recorded shall include as a minimum:
(a) date of training; (b) name and signature of person who has been trained; and (c) description of the training provided.
18.3 The Owner shall maintain a daily log in written format which includes the following information at a minimum:
(a) date of record; (b) types (class and primary characteristic where applicable), quantities and source of waste received; (c) total quantity of waste on the Site; (d) quantities and destination of each type of waste shipped from the Site; and (e) a record of any waste refusals which shall include; amounts, reasons for refusal and actions taken.
18.4 The Owner shall maintain a log of analytical results for waste materials that required testing. The analytical results shall be catalogued such that they can be referenced to waste materials received and transferred from the Site.
18.5 The Owner shall maintain a record of any spills, as defined by the Act, including but not limited to:
(a) the nature of the spill; (b) the time and date of the spill occurrence; (c) the action taken for clean up or correction of the spill, and (d) the time that the Ministry and other persons were notified of the spill in fulfilment of the reporting requirements in the Act.
19.0 Annual Report
19.1 On March 31st of each year, the Owner shall prepare and retain on Site a written report for the previous calendar year. This annual report shall include, at a minimum, the following information:
(a) a detailed monthly summary of the type and quantity of all incoming and outgoing wastes and the destination of all outgoing wastes; (b) any environmental and operational problems, that could negatively impact the environment, encountered during the operation of the Site and during the facility inspections and any mitigative actions taken; (c) any changes to the emergency response plan, the operations report or the closure plan that have been approved by the Director since the last annual report; (d) a statement as to compliance with all Conditions of this Certificate and with the inspection and reporting requirements of the Conditions herein; and, (e) any recommendations to minimize environmental impacts from the operation of the Site and to improve Site operations in this regard.
20.0 Transfer Site Closure Plan
20.1 (a) Six (6) months prior to the permanent closure of the Site, the Owner shall submit to the Director and District Manager, written notification of the decision to cease activities at this Site. The written notification shall also include, for approval by the Director, a closure plan detailing a list of activities and schedule for the implementation of those activities necessary for the decommissioning of the Site; and CONTENT COPY OF ORIGINAL
(b) Within ten (10) business days after closure of the Site, the Owner must notify the Director, in writing, that the Site is closed and that the Site closure plan has been implemented.
21.0 Landfill Closure Plan
21.1 Within one (1) year of the issuance date of this Certificate, the Owner shall submit to the Director for approval, with copies to the District Manager,a detailed site closure plan pertaining to the termination of landfilling operations,post-closure inspection, maintenance and monitoring, and end use.
21.2 The Siteshall be closed in accordance with the closure plan as approved by the Director.
21.3 The Siteshall cease accepting waste for landfilling by no later than December 31, 2008.
SCHEDULE "A"
This Schedule "A" forms part of Certificate of Approval No. 7894-72LN93.
1. Application for a Provisional Certificate of Approval for a Waste Disposal Site signed by Brenda Defosse, dated January 24, 2007.
2. Report - Proposed Solid Waste Transfer Station and Recycling Depot Design and Operations Plan, Cloyne Waste disposal Site. Jacques Whitford, Jan. 19, 2007.
3. E-mail dated January 21, 2008 from Brenda Defosse, Township of North Frontenac, to Roman Lysiak, MOE regarding submission of additional information.
The reasons for the imposition of these terms and conditions are as follows:
The reason for Conditions 1.1, 1.2, 4.1, 4.2, 4.3, 5.1, 5.2 and 8.4 is to clarify the legal rights and responsibilities of the Owner under this Certificate.
The reason for Conditions 2.1 and 19.1 is to ensure that the Site is designed, operated and maintained in accordance with the application and supporting documentation submitted by the Owner, and not in a manner which the Director has not been asked to consider.
The reason for Conditions 3.1, 3.2, 3.3 and 3.4 is to clarify how to interpret this Certificate in relation to the application and supporting documentation submitted by the Owner.
The reason for Condition 6.1 is to ensure that the Site is operated under the corporate name which appears on the application form submitted for this approval and to ensure that the Director is informed of any changes.
The reason for Condition 6.2 is to restrict potential transfer or encumbrance of the Site without the approval of the Director. Transfer or encumbrance can be made only on the basis that it will not endanger compliance with this Certificate.
The reason for Condition 6.3 is to ensure that subsequent owners of the Site are informed of the terms and conditions of this Certificate. This also applies to all supporting documentation listed in Schedule "A".
The reason for Condition 7.1 is to ensure that appropriate Ministry staff have ready access to the Site for inspection of facilities, equipment, practices and operations required by the conditions in this Certificate. This condition is supplementary to the powers of entry afforded a Provincial Officer pursuant to the Act and OWRA. CONTENT COPY OF ORIGINAL
The reason for Conditions 8.1, 8.2 and 8.3 is to ensure the availability of records and drawings for inspection and information purposes. Condition 8.2 was set at 3 years to align with Ontario Regulation 347 requirement to retain records with respect to data, analysis and other information used in preparation of LDR determination for a minimum retention period of 3 years.
The reason for Conditions 9.1, 10.1, 10.2 and 10.3 is to specify the approved areas from which waste may be accepted at the Site, the types of waste that may be accepted and the waste management activities approved for this Site, based on the Owner’s application and supporting documentation.
The reason for Condition 9.2 is to specify the hours of operation for the Site.
Conditions 10.4, and 10.5 are included to ensure that waste storage is done in a manner and duration which does not result in a nuisance or a hazard to the health and safety of the environment or people.
The reason for Condition 11.1 is to ensure that the Site is secure when unattended to prevent vandalism or theft.
The reason for Condition 11.2 is to ensure that emergency responders and the public have the necessary contact information in the event of an emergency or complaint.
The reason for Conditions 12.1 and 12.2 is to ensure that the Owner's staff are properly trained in the operation of the equipment used at the Site and in emergency response procedures.
The reason for Conditions 13.1, 13.2 and 14.1 is to ensure that the site is operated in a manner which does not result in a nuisance or a hazard to the health and safety of the environment or people.
The reason for Conditions 15.1, 15.2 and 15.3 is to ensure that all equipment and facilities are maintained in good working order.
The reason for Conditions 16.1 and 16.2 is to ensure that the Owner follows a plan with an organized set of procedures for identifying and responding to unexpected but possible problems at the Site.
The reason for Condition 17.1 is to ensure that any complaints regarding operations at this Site are responded to in a timely and efficient manner.
The reason for Conditions 18.1, 18.2, 18.3, 18.4 and 18.5 is to ensure that detailed records demonstrating compliance with the terms and conditions of this Certificate are recorded and maintained for inspection and information purposes.
The reason for Conditions 20.0 and 21.0 is to ensure that the Site is closed in accordance with MOE standards and to protect the health and safety of the environment.
This Provisional Certificate of Approval revokes and replaces Certificate(s) of Approval No. A371108 issued on March 25, 1980
In accordance with Section 139 of the Environmental Protection Act, R.S.O. 1990, Chapter E-19, as amended, you may by written notice served upon me and the Environmental Review Tribunal within 15 days after receipt of this Notice, require a hearing by the Tribunal. Section 142 of the Environmental Protection Act, provides that the Notice requiring the hearing shall state:
1. The portions of the approval or each term or condition in the approval in respect of which the hearing is required, and; 2. The grounds on which you intend to rely at the hearing in relation to each portion appealed.
The Notice should also include:
3. The name of the appellant; 4. The address of the appellant; 5. The Certificate of Approval number; CONTENT COPY OF ORIGINAL
6. The date of the Certificate of Approval; 7. The name of the Director; 8. The municipality within which the waste disposal site is located;
And the Notice should be signed and dated by the appellant.
This Notice must be served upon:
The Secretary* AND The Director Environmental Review Tribunal Section 39, Environmental Protection Act 2300 Yonge St., Suite 1700 Ministry of the Environment P.O. Box 2382 2 St. Clair Avenue West, Floor 12A Toronto, Ontario Toronto, Ontario M4P 1E4 M4V 1L5
* Further information on the Environmental Review Tribunal’s requirements for an appeal can be obtained directly from the Tribunal at: Tel: (416) 314-4600, Fax: (416) 314-4506 or www.ert.gov.on.ca
The above noted waste disposal site is approved under Section 39 of the Environmental Protection Act.
DATED AT TORONTO this 7th day of February, 2008 Tesfaye Gebrezghi, P.Eng. Director Section 39, Environmental Protection Act RL/ c: District Manager, MOE Kingston - District Brenda Defosse, The Corporation of the Township of North Frontenac 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Appendix B Field Data Sheets
Cambium Inc. FIELD SHEET - GROUND WATER DEVELOPMENT & SAMPLING
Water B.H. B.H. Stick - Purge Volumes (L) Temp pH Cond. DO ORP Observations Sample Location o CH4 (ppm) Level Depth (m) Dia. (mm) Up (m) Needed Actual ( C) (units) (mS) (mg/L) (mV) Clarity Colour Odour Sheen Other
MW1 8.39 11.45 50.0 0.92 18 18 11.6 - 870 1.08 -3 - Opaque Grey None None
DP2-4.7025.00.45------Well inaccessible
DP3------Well inaccessible
DP4 0.58 2.91 25.4 0.65 2 2 10.8 - 700 7.07 78 - Clear Slight Yellow None None QA/QC
Dry x 1 MW5 6.03 13.27 50.0 0.83 44 8.5 - 310 4.39 -26 - Opaque Grey None None 23
GP1-2.6738.01.06------<5---- Dry
LOCATION: Cloyne Waste Disposal Site DATE: 22-May-18 WEATHER (SAMPLE DAY): 8°C Overcast + Rain <1mm 16°C BAROMETRIC PRESSURE: 101.3Ļ kPa PROJECT NUMBER: 7215-007 SAMPLED BY: M. Pion + N. Morin WEATHER (PREVIOUS DAY): 20°C Sun FIELD SHEET - SURFACE WATER SAMPLING
Sample Depth Width Distance Time Velocity Discharge D.O. Temp. pH Cond. ORP Observations 3 o Station (m) (m) (m) (s) (m/s) (m /s) (mg/L) ( C) (units) (mS) (mV) Clarity Colour Odour Sheen Other
SW1 Ponded- No Observable Flow 7.69 17.8 - 100 -38 Cloudy None None None Flooded
SW2 Ponded- No Observable Flow 8.88 17.9 - 80 -48 Clear None None None Flooded
SW3 0.38 0.56 - - <0.1 <0.02 4.41 16.3 - 240 56 Cloudy None None None QA/QC. Culvert flooded.
SW4 Ponded- No Observable Flow 7.00 17.6 - 100 -55 Clear None None None
LOCATION:Cloyne Waste Disposal Site DATE:22-May-18 WEATHER (SAMPLE DAY): 8°C Overcast + Rain <1mm 16°C
PROJECT NUMBER:7215-007 SAMPLED BY:M. Pion + N. Morin WEATHER (PREVIOUS DAY): 20°C Sun
LOCATION: CloyneWDS DATE: 2018Ͳ11Ͳ01 WEATHER(SAMPLEDAY): 4°COvercast8°C
PROJECTNUMBER: 7215Ͳ007 SAMPLEDBY: M.PionandM.Francis WEATHER(PREVIOUSDAY): 13°CRain FIELDSHEET–GROUNDWATERDEVELOPMENT&SAMPLING B.H. B.H. Stick Tem Sample Water Purge Volumes (L) pH Cond. DO ORP Observations Depth Dia. – Up p LFG Location Level (units) (mS) (mg/L) (mV) (m) (mm) (m) Needed Actual (°C) Clarity Colour Odour Sheen Other
MW1 8.58 11.45 50.8 0.92 17 17 10.3 6.97 1030 0.85 211 - Opaque Black Leachate None QA/QC
DP2 - 4.70 25.4 0.45 ------Damaged
DP3 ------Damaged
DP4 0.85 2.91 25.4 0.65 3.25 3.25 11.1 7.50 790 1.57 177 - Clear None None None
Dry x 1 MW5 9.59 13.27 50.8 0.83 22 8.0 7.58 370 7.71 159 - Opaque Grey None None 8
GP1 - 2.67 38.1 1.06 ------5 - - - - Dry
LOCATION: CloyneWDS DATE: 2018Ͳ11Ͳ01 WEATHER(SAMPLEDAY): 4°COvercast8°C
PROJECTNUMBER: 7215Ͳ007 SAMPLEDBY: M.Pion&M.Francis WEATHER(PREVIOUSDAY): 13°CRain FIELDSHEET–SURFACEWATERSAMPLING Sample Depth Width Velocity Discharge Temp pH Cond. DO ORP Observations 3 Location (m) (m) (m/s) (m /s) (°C) (units) (mS) (mg/L) (mV) Clarity Colour Odour Sheen Other
SW1 Ponded - No Observable Flow 8.0 7.74 170 7.84 151 Clear None None None
SW2 Ponded - No Observable Flow 7.6 7.94 130 9.75 153 Clear None None None
Ponded- No Observable SW3 0.13 0.54 6.9 7.93 190 5.71 167 Clear None None None QA/QC Flow Ponded - No Observable SW4 - 4.0 7.4 7.75 180 5.78 172 Cloudy Brown None Yes Flow
12/12/2018 Daily Data Report for May 2018 - Climate - Environment and Climate Change Canada
Home Environment and natural resources Weather, Climate and Hazard Past weather and climate Historical Data
Daily Data Report for May 2018
DRUMMOND CENTRE ONTARIO Current Station Operator: CCN
Latitude: 45°01'56.082" N
Longitude: 76°15'10.098" W
Elevation: 145.00 m
Climate ID: 6102J13
WMO ID:
TC ID:
Max Min Mean Heat Deg Cool Deg Total Total Total Snow on Dir of Max Spd of Max Temp Temp Temp Days Days Rain Snow Precip Grnd Gust Gust °C °C °C mm cm mm cm 10's deg km/h
DAY 01 † 24.5 0.0 12.3 5.7 0.0 0.0 0.0 0.0 0 02 † 27.5 9.0 18.3 0.0 0.3 5.4 0.0 5.4 0 03 † 18.0 12.5 15.3 2.7 0.0 2.8 0.0 2.8 0 04 † 23.0 7.5 15.3 2.7 0.0 1.6 0.0 1.6 0 05 † 24.0 5.0 14.5 3.5 0.0 0.0 0.0 0.0 0 06 † 20.0 7.0 13.5 4.5 0.0 0.0 0.0 0.0 0 07 † 16.5 4.0 10.3 7.7 0.0 0.0 0.0 0.0 0 08 † 23.5 1.5 12.5 5.5 0.0 0.0 0.0 0.0 0 09 † 27.5 5.5 16.5 1.5 0.0 1.6 0.0 1.6 0 10 † 19.5 14.5 17.0 1.0 0.0 2.4 0.0 2.4 0 11 † 13.5 1.0 7.3 10.7 0.0 0.0 0.0 0.0 0 12 † 19.0 0.5 9.8 8.2 0.0 0.0 0.0 0.0 0 13 † 22.5 2.0 12.3 5.7 0.0 0.0 0.0 0.0 0 14 † 26.5 7.5 17.0 1.0 0.0 0.6 0.0 0.6 0 15 † 19.5 12.5 16.0 2.0 0.0 1.0 0.0 1.0 0 http://climate.weather.gc.ca/climate_data/daily_data_e.html?hlyRange=%7C&dlyRange=1984-06-01%7C2018-12-10&mlyRange=1984-01-01%7C200… 1/3 12/12/2018 Daily Data Report for May 2018 - Climate - Environment and Climate Change Canada
Max Min Mean Heat Deg Cool Deg Total Total Total Snow on Dir of Max Spd of Max Temp Temp Temp Days Days Rain Snow Precip Grnd Gust Gust °C °C °C mm cm mm cm 10's deg km/h
16 † 23.5 3.0 13.3 4.7 0.0 0.0 0.0 0.0 0 17 † 19.0 10.0 14.5 3.5 0.0 0.0 0.0 0.0 0 18 † 18.5 2.5 10.5 7.5 0.0 0.0 0.0 0.0 0 19 † 17.0 8.5 12.8 5.2 0.0 14.4 0.0 14.4 0 20 † 18.0 12.5 15.3 2.7 0.0 0.0 0.0 0.0 0 21 † 27.0 4.0 15.5 2.5 0.0 0.0 0.0 0.0 0 22 † 17.0 11.5 14.3 3.7 0.0 1.4 0.0 1.4 0 23 † 23.5 8.0 15.8 2.2 0.0 0.0 0.0 0.0 0 24 † 27.5 4.5 16.0 2.0 0.0 0.0 0.0 0.0 0 25 † 27.5 14.5 21.0 0.0 3.0 1.2 0.0 1.2 0 26 † 24.0 16.0 20.0 0.0 2.0 0.0 0.0 0.0 0 27 † 26.0 15.0 20.5 0.0 2.5 0.0 0.0 0.0 0 28 † 26.5 16.5 21.5 0.0 3.5 0.0 0.0 0.0 0 29 † 26.0 16.5 21.3 0.0 3.3 0.0 0.0 0.0 0 30 † 30.0 8.0 19.0 0.0 1.0 0.0 0.0 0.0 0 31 † 25.5 18.5 22.0 0.0 4.0 0.6 0.0 0.6 0 Sum 96.4 19.6 33.0 0.0 33.0 Avg 22.6 8.4 15.5
Xtrm 30.0 0.0
Summary, average and extreme values are based on the data above.
Legend
A = Accumulated C = Precipitation occurred, amount uncertain E = Estimated F = Accumulated and estimated L = Precipitation may or may not have occurred M = Missing N = Temperature missing but known to be > 0
S = More than one occurrence T = Trace Y = Temperature missing but known to be < 0 [empty] = No data available ^ = The value displayed is based on incomplete data † = Data that is not subject to review by the National Climate Archives
Date modified: 2018-07-20
http://climate.weather.gc.ca/climate_data/daily_data_e.html?hlyRange=%7C&dlyRange=1984-06-01%7C2018-12-10&mlyRange=1984-01-01%7C200… 2/3 12/12/2018 Daily Data Report for May 2018 - Climate - Environment and Climate Change Canada
http://climate.weather.gc.ca/climate_data/daily_data_e.html?hlyRange=%7C&dlyRange=1984-06-01%7C2018-12-10&mlyRange=1984-01-01%7C200… 3/3 12/12/2018 Daily Data Report for October 2018 - Climate - Environment and Climate Change Canada
Home Environment and natural resources Weather, Climate and Hazard Past weather and climate Historical Data
Daily Data Report for October 2018
DRUMMOND CENTRE ONTARIO Current Station Operator: CCN
Latitude: 45°01'56.082" N
Longitude: 76°15'10.098" W
Elevation: 145.00 m
Climate ID: 6102J13
WMO ID:
TC ID:
Max Min Mean Heat Deg Cool Deg Total Total Total Snow on Dir of Max Spd of Max Temp Temp Temp Days Days Rain Snow Precip Grnd Gust Gust °C °C °C mm cm mm cm 10's deg km/h
DAY 01 † 12.5 6.0 9.3 8.7 0.0 10.2 0.0 10.2 0 02 † 10.0 7.5 8.8 9.2 0.0 2.4 0.0 2.4 0 03 † 17.0 9.5 13.3 4.7 0.0 5.4 0.0 5.4 0 04 † 23.5 11.0 17.3 0.7 0.0 1.4 0.0 1.4 0 05 † 11.0 0.5 5.8 12.2 0.0 0.0 0.0 0.0 0 06 † 10.0 5.5 7.8 10.2 0.0 0.4 0.0 0.4 0 07 † 10.5 8.5 9.5 8.5 0.0 0.0 0.0 0.0 0 08 † 18.0 7.0 12.5 5.5 0.0 33.2 0.0 33.2 0 09 † 26.5 8.5 17.5 0.5 0.0 0.0 0.0 0.0 0 10 † 26.5 15.5 21.0 0.0 3.0 4.6 0.0 4.6 0 11 † 24.0 11.5 17.8 0.2 0.0 0.2 0.0 0.2 0 12 † 11.0 6.0 8.5 9.5 0.0 0.0 0.0 0.0 0 13 † 10.5 4.0 7.3 10.7 0.0 0.0 0.0 0.0 0 14 † 14.0 -1.5 6.3 11.7 0.0 0.0 0.0 0.0 0 15 † 12.0 3.0 7.5 10.5 0.0 1.2 0.0 1.2 0 http://climate.weather.gc.ca/climate_data/daily_data_e.html?hlyRange=%7C&dlyRange=1984-06-01%7C2018-12-10&mlyRange=1984-01-01%7C200… 1/3 12/12/2018 Daily Data Report for October 2018 - Climate - Environment and Climate Change Canada
Max Min Mean Heat Deg Cool Deg Total Total Total Snow on Dir of Max Spd of Max Temp Temp Temp Days Days Rain Snow Precip Grnd Gust Gust °C °C °C mm cm mm cm 10's deg km/h
16 † 9.5 0.5 5.0 13.0 0.0 1.0 0.0 1.0 0 17 † 8.5 3.5 6.0 12.0 0.0 0.0 0.0 0.0 0 18 † 5.5 -2.0 1.8 16.2 0.0 0.0 0.0 0.0 0 19 † 16.0 1.0 8.5 9.5 0.0 1.2 0.0 1.2 0 20 † 12.0 8.0 10.0 8.0 0.0 0.0 0.0 0.0 0 21 † 3.5 -1.0 1.3 16.7 0.0 0.0 0.0 0.0 0 22 † 8.0 -2.0 3.0 15.0 0.0 0.2 0.0 0.2 0 23 † 10.0 0.5 5.3 12.7 0.0 0.0 0.0 0.0 0 24 † 6.5 0.0 3.3 14.7 0.0 0.0 0.0 0.0 0 25 † 4.5 0.0 2.3 15.7 0.0 0.0 0.0 0.0 0 26 † 5.0 -4.0 0.5 17.5 0.0 0.0 0.0 0.0 0 27 † 4.5 -1.0 1.8 16.2 0.0 0.0 6.8 6.8 0 28 † 3.0 0.5 1.8 16.2 0.0 0.0 1.6 1.6 7 29 † 4.0 0.5 2.3 15.7 0.0 4.6 0.0 4.6 5 30 † 7.0 -2.0 2.5 15.5 0.0 2.6 0.0 2.6 T 31 † 6.0 -1.5 2.3 15.7 0.0 9.6 0.0 9.6 0 Sum 333.1 3.0 78.2 8.4 86.6 Avg 11.3 3.3 7.4
Xtrm 26.5 -4.0
Summary, average and extreme values are based on the data above.
Legend
A = Accumulated C = Precipitation occurred, amount uncertain E = Estimated F = Accumulated and estimated L = Precipitation may or may not have occurred M = Missing N = Temperature missing but known to be > 0
S = More than one occurrence T = Trace Y = Temperature missing but known to be < 0 [empty] = No data available ^ = The value displayed is based on incomplete data † = Data that is not subject to review by the National Climate Archives
Date modified: 2018-07-20
http://climate.weather.gc.ca/climate_data/daily_data_e.html?hlyRange=%7C&dlyRange=1984-06-01%7C2018-12-10&mlyRange=1984-01-01%7C200… 2/3 12/12/2018 Daily Data Report for October 2018 - Climate - Environment and Climate Change Canada
http://climate.weather.gc.ca/climate_data/daily_data_e.html?hlyRange=%7C&dlyRange=1984-06-01%7C2018-12-10&mlyRange=1984-01-01%7C200… 3/3 12/12/2018 Daily Data Report for November 2018 - Climate - Environment and Climate Change Canada
Home Environment and natural resources Weather, Climate and Hazard Past weather and climate Historical Data
Daily Data Report for November 2018
DRUMMOND CENTRE ONTARIO Current Station Operator: CCN
Latitude: 45°01'56.082" N
Longitude: 76°15'10.098" W
Elevation: 145.00 m
Climate ID: 6102J13
WMO ID:
TC ID:
Max Min Mean Heat Deg Cool Deg Total Total Total Snow on Dir of Max Spd of Max Temp Temp Temp Days Days Rain Snow Precip Grnd Gust Gust °C °C °C mm cm mm cm 10's deg km/h
DAY 01 † 8.0 3.0 5.5 12.5 0.0 17.6 0.0 17.6 0 02 † 5.0 2.0 3.5 14.5 0.0 3.6 0.0 3.6 0 03 † 4.5 3.0 3.8 14.2 0.0 1.6 0.0 1.6 0 04 † 5.5 -1.5 2.0 16.0 0.0 0.0 0.0 0.0 0 05 † 7.0 0.0 3.5 14.5 0.0 2.0 0.0 2.0 0 06 † 12.5 6.0 9.3 8.7 0.0 6.6 0.0 6.6 0 07 † 10.5 6.5 8.5 9.5 0.0 1.2 0.0 1.2 0 08 † 7.5 2.5 5.0 13.0 0.0 0.2 0.0 0.2 0 09 † 3.5 -4.0 -0.3 18.3 0.0 0.0 4.2 4.2 0 10 † 1.5 -0.5 0.5 17.5 0.0 0.0 0.0 0.0 2 11 † 1.0 -6.5 -2.8 20.8 0.0 0.0 0.4 0.4 2 12 † 6.0 -4.5 0.8 17.2 0.0 1.2 4.2 5.4 2 13 † 0.5 0.0 0.3 17.7 0.0 0.0 4.4 4.4 6 14 † -6.5 -12.5 -9.5 27.5 0.0 0.0 0.0 0.0 9 15 † -4.5 -14.5 -9.5 27.5 0.0 0.0 13.8 13.8 7 http://climate.weather.gc.ca/climate_data/daily_data_e.html?hlyRange=%7C&dlyRange=1984-06-01%7C2018-12-10&mlyRange=1984-01-01%7C200… 1/2 12/12/2018 Daily Data Report for November 2018 - Climate - Environment and Climate Change Canada
Max Min Mean Heat Deg Cool Deg Total Total Total Snow on Dir of Max Spd of Max Temp Temp Temp Days Days Rain Snow Precip Grnd Gust Gust °C °C °C mm cm mm cm 10's deg km/h
16 † 1.5 -6.5 -2.5 20.5 0.0 0.0 5.6 5.6 21 17 † 2.5 -3.5 -0.5 18.5 0.0 0.0 0.0 0.0 21 18 † -0.5 -18.0 -9.3 27.3 0.0 0.0 0.4 0.4 20 19 † 3.0 -4.0 -0.5 18.5 0.0 0.0 0.6 0.6 19 20 † -3.0 -10.0 -6.5 24.5 0.0 0.0 2.6 2.6 18 21 † -3.0 -13.0 -8.0 26.0 0.0 0.0 0.0 0.0 19 22 † -10.0 -19.5 -14.8 32.8 0.0 0.0 0.0 0.0 17 23 † -3.0 -24.5 -13.8 31.8 0.0 0.0 0.0 0.0 17 24 † 4.0 -9.0 -2.5 20.5 0.0 4.2 0.0 4.2 17 25 † 5.5 1.0 3.3 14.7 0.0 1.0 0.0 1.0 14 26 † 3.5 0.0 1.8 16.2 0.0 17.4 3.0 20.4 9 27 † 3.0 -0.5 1.3 16.7 0.0 0.0 12.4 12.4 7 28 † 1.5 0.0 0.8 17.2 0.0 0.0 0.0 0.0 18 29 † 1.0 -0.5 0.3 17.7 0.0 0.0 0.0 0.0 12 30 † 0.0 -1.5 -0.8 18.8 0.0 0.0 0.0 0.0 9 Sum 571.1 0.0 56.6 51.6 108.2 Avg 2.3 -4.4 -1.0
Xtrm 12.5 -24.5
Summary, average and extreme values are based on the data above.
Legend
A = Accumulated C = Precipitation occurred, amount uncertain E = Estimated F = Accumulated and estimated L = Precipitation may or may not have occurred M = Missing N = Temperature missing but known to be > 0
S = More than one occurrence T = Trace Y = Temperature missing but known to be < 0 [empty] = No data available ^ = The value displayed is based on incomplete data † = Data that is not subject to review by the National Climate Archives
Date modified: 2018-07-20
http://climate.weather.gc.ca/climate_data/daily_data_e.html?hlyRange=%7C&dlyRange=1984-06-01%7C2018-12-10&mlyRange=1984-01-01%7C200… 2/2 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Appendix C Laboratory Certificates of Analysis
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Appendix D Site Photographs
Cambium Inc. 2018 Annual Report, Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.:7215-007 March 2019
Photograph 1: Monitor MW1, May 2018 Photograph 2: Monitor DP2, November 2018
Photograph 3: Monitor DP3, November 2018 Photograph 4: Monitor DP4, May 2018
Cambium Inc. 2018 Annual Report, Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.:7215-007 March 2019
Photograph 5: Monitor MW5, May 2018 Photograph 6: Surface water monitoring station SW1, May 2018
Photograph 7: Surface water monitoring station SW1, Photograph 8: Surface water monitoring station SW2, November 2018 November 2018
Cambium Inc. 2018 Annual Report, Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.:7215-007 March 2019
Photograph 9: Surface water monitoring station SW2, Photograph 10: Surface water monitoring station SW3, November 2018 May 2018
Photograph 11: Surface water monitoring station SW3, Photograph 12: Surface water monitoring station SW4, November 2018 May 2018
Cambium Inc. 2018 Annual Report, Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.:7215-007 March 2019
Photograph 13: Surface water monitoring station SW4, November 2018
Cambium Inc. 2018 Annual Report Cloyne Waste Disposal Site The Corporation of the Township of North Frontenac Cambium Ref. No.: 7215-007 March 20, 2019
Appendix E Borehole Log
Cambium Inc.