Silicones for Paints & Coatings
Surface Modifiers Silicone based Resins for Coating
Surface Modifiers for Resin Hybridization Agents Pigments & Fillers Take your products to the next level with Shin-Etsu Silicones. In our quest to serve the complex needs of users in diverse industries, Shin-Etsu Silicone has developed in excess of 5,000 different products. We brought our technical expertise to bear in the field of coating agents and paints to develop a wide array of products. Our Silicone based Resins, Resin Hybridization Agents, Surface Modifiers for Coating, and Surface Modifiers for Pigments & Fillers are used extensively to make your products meet the demanding needs of your customers.
Features of Silicones 3 Product Map - 4 Types of Silicone Usage - 4-5 Silicone based Resins 6-11 Silicone Resins 6-9 Silicone Oligomers 10-11 Resin Hybridization Agents 12-21 Acrylic Resins 12-15 Polyester & Alkyd Resins 16-17 Epoxy Resins 18-19 CONTENTS Urethane Resins 20-21 Surface Modifiers for Coating 22-29 Silicone Powders 22-23 KP Series 24-27 Other Highly Functional Products 28-29
Surface Modifiers for Pigments & Fillers 30-31 Alkoxy Silanes & Silane Coupling Agents 30
Spherical Silica Fine Particles 31
*For information on handling precautions and packaging, see the catalog for the relevant product. Please read the Safety Data Sheet (SDS) before use. SDS can be obtained from our Sales Departments.
2 Take your products to the next level with Shin-Etsu Silicones. Features of Silicones Silicones are a type of hybrid material which has properties of both organic and inorganic materials.
Structures of Silicones All silicone products are composed of the four basic units shown at MUnits DUnits TUnits QUnits Mono-functional Di-functional Tri-functional Tetra-functional right. How they are combined will determine the category in which the R 3SiO1/2 R 2SiO2/2 RSiO3/2 SiO4/2 product falls. R R R
Features of materials with siloxane bonds R ●High bonding energy (106 kcal/mol): R R Resists breakdown from heat and light. Around 25% higher bonding energy than C-C bonds. R Organic group (including methyl group, phenyl group and reactive functional group) Features of materials with siloxane chain ●Helical molecule & low intermolecular force: Structure of Fluid Excellent water repellency, defoaming, and ●Dimethyl polysiloxane composed primarily of D Units. release properties (interfacial characteristics); ●Low surface tension, with excellent water repellency gas permeable. Physical properties are and release properties. not strongly temperature dependent. Used for resin modification and to make release agents, defoamers, etc. ●Constituent Units : M Units, D Units Structure of Resin ●Three-dimensional network structure composed primarily of T Units. ●Owing to their dense structures, silicone resins outperform other silicones in weatherability and heat resistance. Used for resin modification and to make heat- and weather- resistant paints. ●Constituent Units : D Units, T Units, (Q Units)
Characteristics imparted by organic groups ●Primary Organic Groups Methyl groups: hydrophobicity Phenyl groups: compatibility with resins, heat resistance Polyether groups: hydrophilicity Alkoxy groups: adhesiveness, moisture-cure properties Amino groups: reactive with epoxies and other resins (Meth)acryl groups: radical polymerization
Structure of Silane ●Each molecule contains two functional groups with different reactivity. ●Constituent Units : M Units, D Units, T Units, Q Units 3 Product Map - 4 Types of Silicone Usage -
SiliconeSilicone basedbased ResinsResins
Silicone Resins Silicone Oligomers (Type A)
Dehydration condensation Dealcoholization reaction condensation reaction
：Alkoxy Groups ：Methyl or Methyl / Phenyl Groups ：Methyl or Methyl / Phenyl Groups Structure:Resin having a high molecular weight and 3D siloxane Structure:Resin having a relatively low molecular weight and 3D network structure. siloxane network structure. Molecules contain alkoxy groups and Features:With excellent film-forming abilities, coatings can range from non-reactive functional groups. very hard to flexible. Features:Can be used as coating materials, or to modify organic resins.
Heat Resistance
Electrical Insulation Weatherability
Water Repellency
P 6-11 Base Resins Components of Paints & Coatings ResinResin HybridizationHybridization AgentsAgents
Silane Coupling Agents Silicone Oligomers (Type AR) Silicone Resins
Modified Silicone Fluids
：Alkoxy Groups Me Me Me Me ：Reactive Functional Groups ：Alkoxy Groups ：Reactive Functional Groups ：Methyl / Phenyl Groups
Resin having relatively a Structure:Monomers whose molecules Structure: Structure:Resin having a high Me Me Me Me contain alkoxy groups and reactive low molecular weight and 3D siloxane molecular weight and 3D siloxane functional groups. network structure. Molecules contain network structure. ：Reactive Functiopnal Groups Me：Methyl Groups Features:While alkoxy groups improve alkoxy groups and reactive Features:With excellent Structure:2D siloxane main chain with adhesion to inorganic materials, reactive functional groups. film-forming abilities, coatings can reactive or non-reactive functional groups functional groups improve adhesion to Features:Can be used as an organic range from very hard to flexible. in the side chains and on the ends. organic materials. resin modifier or reactive diluents. Features:Silicone fluids having reactive functional groups can be used for the modification of organic resins.
Acrylic Resins Polyester & Alkyd Resins Epoxy Resins Urethane Resins
Heat Heat Resistance Resistance Weatherability Flexibility Adhesion Weatherability Adhesion Weatherability
Wear Wear Heat Resistance Water Flexibility Resistance Water Flexibility Adhesion Adhesion Slip Resistance Resistance Resistance
P 12-15 P 16-17 P 18-19 P 20-21
4 Product Map
SurfaceSurface ModifiersModifiers forfor CoatingCoating
Silicone Powders KP Series Hybrid Type Coating Solution
Resin Part Silicone
Rubber Part
Silicone migrates to the surface Structure (3 types): Resin, rubber & resin coated rubber Features:Available in a variety of particle sizes to meet a Features: Surface Modifiers designed to use as leveling range of requirements. agents, defoamers, slip agents, and in paints and coatings.
Leveling Heat Deforming Resistance Hydrophilic Weatherability Slip Anti-staining Light Antistatic Diffusion Matting Additives P 22-29 Components of Paints & Coatings SurfaceSurface ModifiersModifiers forfor PigmentsPigments && FillersFillers Pigments Silane Coupling Agents Spherical Silica Fine Particles & Fillers Me Me Me：Methyl Groups Me Me Me
Me
10-300nm Me
：Alkoxy Groups Me ：Reactive Functional Groups Me
Structure:Monomers whose molecules Structure:Structure: Very small particle size contain alkoxy groups and reactive functional with narrow particle size distribution. Particle Alkoxy Silanes groups. surfaces are treated to give them extra water Features:While alkoxy groups improve repellency. adhesion to inorganic materials, reactive Features:Monodisperse, less aggregation. functional groups improve adhesion to organic Highly adhesive to various powders. Improves materials. flowability.
：Alkoxy Groups ：Non-reactive Functional Groups
Structure:Monomers whose molecules contain alkoxy groups. Features:Alkoxy groups act to improve Adhesion adhesion to inorganic materials and modify the surface energy of the substrate.
Dispersibility Flowability
P 30-31
5 Silicone based Resins Silicone Resins
Silicone resins are composed primarily of T Units ●Model of Cured Silicone Resins and have a 3D structure. Silicone resins form coatings with excellent heat resistance and weatherability. Unmodified silicones include methyl and methyl phenyl resins, while the organic resin-modified types include epoxy-modified, polyester-modified, and alkyd-modified resins. Silicone based Resins
Features • Heat Resistance • Weatherability • Flexibility • High Hardness • Anti-corrosion Properties • Electrical Insulation
Product List
Compatibility ProductProduct Non-volatile CureCure Compatibility MainMain CureCure ApplicableApplicable TypeType content Solvent HardnessHardness withwith Features TSCAT* namename 105℃×3h speedspeed organicorganic resins resins applicationsapplicationsconditionsconditions typetype % White flake, excellent heat Heat resistant and KR-220L 100*1 None Rapid High Low Baking Powder, solvent resistance and flame retardance, Listed flame retardant binders very little smoking upon heating Heat resistant and 100*1 None Rapid High Low Baking Powder, solvent Powder type of KR-220L Listed KR-220LP Methyl flame retardant binders Toluene, Heat resistant and Excellent heat resistance 50 Rapid High Low Baking Solvent Not KR-242A isopropyl alcohol flame retardant binders and flame retardance Listed Water proofing Baking, room Toluene Solvent Thin hard coating KR-251 20 Rapid Medium Low and insulating coatings temperature Listed Water proofing Baking, room Toluene, xylene Solvent Glossy hard coating Listed KR-255 50 Medium Medium Medium and insulating coatings temperature Excellent flexibility and 50 Xylene Slow Low Medium Heat resistant paints Baking Solvent Listed KR-282 Methyl / anti-cracking properties Excellent heat resistance Phenyl Xylene Heat resistant paints Solvent Not KR-300 50 Medium High Medium Baking high hardness coating Listed Excellent heat resistance and Xylene Heat resistant paints Solvent Listed KR-311 60 Medium Medium High Baking compatibility with organic resins
Xylene, Excellent anti-corrosion property, Heat resistant paints Solvent ES-1001N 45 diacetone alcohol, - - - Baking heat resistance and weatherability Listed n-butanol Epoxy Room Excellent anti-corrosion property Toluene Heat resistant paints Solvent Listed ES-1002T modified 60 - - - temperature*4 and chemical resistance resin Xylene, Heat resistant paints Solvent Excellent anti-corrosion properties Not ES-1023 45 diacetone alcohol - - - Baking Listed
Room Not Alkyd 50 Xylene - - - Heat resistant paints Solvent Excellent flexibility and adhesion Listed KR-5206 modified resin temperature Excellent flexural resistance, PGMAC*2 - Heat resistant paints Solvent Listed KR-5230 60 - - Baking heat resistance and weatherability 2 PGMAC* , Retains glossy appearance 3, Not KR-5234 Polyester 60 MMBAC* - - - Heat resistant paints Baking Solvent under high temperature Listed modified resin isobutyl alcohol PGMAC*2, 3 Excellent releasability Not KR-5235 60 MMBAC* , - - - Heat resistant paints Baking Solvent Listed isobutyl alcohol and non-stick properties *1 Active ingredient (Not specified values) *2 PGMAC : Propylene glycol monomethylether acetate *3 MMBAC : 3-Methyl-3- methoxybutyl acetate *4 ES-1002T must be used with KP-390 (cross-linker).
Products Types and Properties
Property Type Methyl type Methyl / Phenyl type Epoxy modified resin Alkyd modified resin Polyester modified resin Heat resistance ++ ++ + + + Hardness ++ + ± ± ± Weatherability ++ ++ - + + Flexibility - - ± + + Anti-corrosion property ± ± ++ ± ±
* ++:Excellent +: Good ±: Satisfactory -: Poor
6 Silicone based Resins
Map of Structures and Features
1 KR-220L * Silicone based Resins KR-220LP *1
1 KR-242A * KR-300 High KR-251*1 High
KR-255 2
KR-211 * KR-311 Hardness KR-282
Low Low
Compatibility with Organic Resins Units / D Ratio T Phenyl Group Content KR-212 Low * 2
High Low Slow High Cure Speed Rapid *2 T Units / D Units Ratio Low 2 High * High Phenyl Group Content Low *1 Methyl silicone resin that contains no phenyl groups. *2 T Units / D Units Ratio and phenyl content are key factors determining hardness, cure speed and compatibility with organic resins, but not all products fit this pattern.
Product Type Methyl / Phenyl Type Methyl Type
KR-242A High hardness Solution KR-282 KR-311
Powder KR-220L KR-220LP Room temperature Even drying higher hardness Ultra-high molecular weight KR-251 KR-255 KR-300
Epoxy Type Polyester Type
ES-1001N KR-5230
Improved adhesion & thermal shock Room temperature Imparts Non-stick Improved cure speed drying resistance property
ES-1023 ES-1002T KR-5235 KR-5234
7 Silicone based Resins Silicone Resins
Features of Silicone Resins Silicone resins are used in a wide range of applications. Taking advantage of 3D molecular structures, silicone resins exhibit excellent heat resistance, weatherability, and electrical insulation.
Silicone based Resins Model of Silicone Resins
●Before Curing ●After Curing
Heating Dehydration Condensation Reaction
Forms hard coating with three-dimensional network structure
Methyl groups or Phenyl groups
Weight Loss Data in air at High Temperature Heat Resistance : Comparison Data (Methyl/Phenyl Type) with Organic Resins (under 250℃)
100 100 Silicone resins
90 90
Silicone-modified alkyd resins 80 80 Weight(%) 70 70 Epoxy resins Gloss retention ratio(%) 60 Methyl thermal Phenyl Thermal 60 Condensation decomposition decomposition Alkyd resins 50 50 0 200 400 600 800 0 20 40 60 80 100 Temperature(℃) Time(h)
Weather Resistance : Sunlight Absorption : Comparison Data with Organic Resins Comparison Data with Organic Resins
2.0 *Methyl silicone is not affected by sunlight, 100 because sunlight passes through it.
Silicone resins 1.0
50 Wavelengths of sunlight Illuminance(W/m) Absorption band of organic resins
Gloss retention ratio(%) Silicone modified alkyd resins Alkyd resins Absorption band of Methyl / Phenyl silicone
0 0 100 200 300 400 500 300 450 600 750 Time(h) Wavelength(nm)
8 Silicone based Resins
Unique Silicone Resins Technology perfected over several decades created a line of silicone resins with unique performance features. Silicone based Resins Solid Silicone Resin KR-220L
Solid silicone resin consisting of 100% active content. Available in flake or powder form. Heat-cured resin, and because it is a liquid at temperatures between 80°–150°C, it can be used without a solvent. Can be used to make binders and powder coatings. And because it dissolves in toluene and isopropyl alcohol, KR-220L offers a great number of possibilities in the ways it can be used. ●Dry Blend ●Solution Blend KR-220L KR-220L
Solvent
Grinding Mix with filler Dissolve in solvent Add fillers Solvent elimination * Catalysts may also be added *Catalysts may also be added
●Melt Blend
KR-220L
Heating Melt Filler addition Cool *Catalysts may also be added ●Powdered Silicone Resin
Ultra High Molecular Weight Silicone Resin KR-251
KR-251 is a methyl silicone resin with a very high molecular weight. Due to its excellent film-forming ability, KR-251 forms coatings with just a simple drying process. In addition, because it contains D units, KR-251 forms coatings that resists cracking even after heat-curing. ●Model of Coating Structure Common Grade Silicone Resin KR-251 High molecular weight Low molecular weight
Heat cure Heat cure or or Catalyst Catalyst
Easy to crack due to Forms a high quality film Forms a harder coating film. Poor film forming The collection of large molecules properties when dried high crosslinking density by air drying alone translates to excellent crack resistance, film-forming ability, and toughness.
Highly Durable Heat Resistant Paint Resins ES-1023/KR-311
The combination of the epoxy-modified silicone resin ES-1023 (with its outstanding corrosion resistance and adhesiveness) and the unmodified silicone resin KR-311(with its high heat resistance), a highly durable and heat resistant coating is formed.
●Application Examples Base coat : ES-1023 1. Applying the base coat Blending example of base coating Blending example of top coating Substrate : Steel plate Baking : 150℃-180℃×20 to 30 min. ES-1023 • • • • • • 30wt% KR-311 • • • • • • • •40wt% Zinc powder ••••••40wt% Ceramic black ••••••20wt% Top coat : KR-311 Talc •••••••••••••••••10wt% Talc •••••••••••••••••••20wt% Base coat : ES-1023 2. Applying the top coat Xylene •••••••••••••20wt% Xylene •••••••••••••••20wt% Substrate : Steel plate Baking : 150℃-200℃×20 to 30 min.
9 Silicone based Resins Silicone Oligomers
2-Part Room Temperature Moisture Cure Coatings Type A silicone oligomers (please refer P.4) are used with a curing agent to produce coatings that cure at ambient temperatures and humidities. In recent years, these oligomers have been widely used for exterior automotive coatings and interior floor coatings. Silicone based Resins ●Exterior Automotive Coatings ●Interior Floor Coatings ●Model of Molecular Structure of a Coating
Dealcoholization condensation reaction
: Alkoxy Groups : Methyl or Methyl / Phenyl Groups
Cross linking system Product Lineup With a range of silicone oligomers and curing agents to choose from, the user has a great degree of control over the cure speed, hardness, or flexibility of the cured coating. With silicone oligomers, the degree of polymerization and ratio of 3D crosslinking (T Units) to 2D crosslinking (D Units) will influence such properties as curing speed and the hardness and/or flexibility of the coating. For example, by combining a methyl silicone oligomer with a lesser proportion of a phenyl oligomer, a coating with enhanced flexibility and glossiness is produced . Methyl Type Methyl / Phenyl Type Features : Excellent water repellency, cure speed Features : Excellent water repellency, cure speed Product name Features TSCA KR-401N Excellent curability, Gloss Listed
High X-40-9250
Low Imparts flexibility Slow X-40-9227 Listed KR-510 Forms high hardness coating Listed X-40-9246 KR-9218 Forms medium hardness coating Listed
X-40-9225 Catalysts Lineup Adding
Hardness Product name Type amount Features TSCA KR-500 Cure speed wt% Polymerization
degree (Viscosity) D-220 Phosphoric acid 5-10 Very high activity Listed KR-515 X-40-2309A Phosphoric acid 10-50 High activity, can accelerate curing Listed D-25 Titanium 0.5-3 Higher activity than D-20 Listed
Rapid KC-89S High D-20 Titanium 2-5 Slow reactivity Listed Low Solvent diluted type Low T/D Ratio High DX-175 Titanium 3-5 Listed (Easy to use) Slow Cure speed Rapid DX-9740 Aluminum 0.5-5 Forms high hardness coatings Listed High Flexibility Low Solvent diluted type CAT-AC Aluminum 0.5-10 Listed (Easy to use)
Blending Examples and Film Properties
Parameter Catalyst (adding amount) Film thickness Tack free Flexural resistance / Pencil hardness Product name % μm 25℃ min Impact resistance
KR-500*1 D-20(2) 25 40 H ± KR-500 D-20(4) 25 25 2H ±-- KR-500 DX-9740(5) 25 100 5H - 1 X-40-9225* D-20(3) 30 60 H + KR-500/ 1 X-40-9250* D-20(2) 80 75 F + (=80/20)
+ : Excellent ± : Satisfactory - : Poor (Not specified values) *Substrate : Polished steel sheet, Cure conditions : 25℃ / 70% RH × 7days (Tack-free time varies depending on temperature and humidity) *1 KR-500 and X-40-9225 are listed in TSCA. X-40-9250 is not listed in TSCA. 10 Silicone based Resins
1-Part Room Temperature Moisture Cure Coatings These coating agents come pre-mixed with a curing agent. These one-component products cure at room temperature with exposure to moisture in the air. KR-400 is designed to produce high hardness coatings. X-40-2327 is fast curing, while KR-401 produces coatings with high flex resistance and impact resistance. Silicone based Resins
Parameter Viscosity at Refractive Tack free at Pencil hardness / Reactive groups 2 Features TSCA Product name 25℃ mm /s index at 25℃ 25℃ min curing days
KR-400 Methyl 1.2 1.390 30-60 5H/2days 8H/7days Forms high hardness coatings Listed X-40-2327 Methyl 0.9 1.382 5-10 5H/1day Rapid cure, Finished coating can be recoated. Listed KR-401 Methyl / Phenyl 20 1.435 30-60 3H/7days Excellent flexural strength and impact resistance Listed *Substrate : Polished steel sheet, Cure conditions : 25℃ / 70% RH × 7days (Tack-free time varies depending on temperature and humidity) (Not specified values) New Products Our product offerings include coating agents with special features such as enhanced water repellency, antistatic properties and UV shielding abilities. Fluorine-containing type KR-400F Features: Fluorine is incorporated for enhanced slip property, Water Contact Angle on a KR-400F Film water repellency and antifouling properties. 110°
Glass treated Glass treated Untreated glass with KR-400F Untreated glass with KR-400F
Substrate
Parameter Viscosity at Tack free at Pencil hardness TSCA Product name 25℃ mm2/s 25℃ min after 7 days
Not Before Cleaning After Cleaning KR-400F 1.2 30-60 8H Listed
(Not specified values) Ultraviolet-shielding type X-40-9309A Features: The silicone coating resists breakdown from UV rays, and also helps prevent degradation of the underlying substrate.
●Model of Ultraviolet-shielding ●Data of Light Transmissivity
100 90 80 70 60 50 40 30
Transmissivity (%) Transmissivity KR-400 Parameter Viscosity at Tack free at Pencil hardness Conventional grade X-40-9309A 20 TSCA 10 X-40-9309A Product name 25℃ mm2/s 25℃ min after 7 days Damage 0 Substrate Substrate 200 300 400 500 600 700 800 Not Wavelength (nm) X-40-9309A 1.4 120 5H Listed
(Not specified values) Antistatic type X-40-2450X Features: Forms an antistatic layer on surfaces, thus making them less likely to attract dirt and dust.
Dust, Yellow sand, Exhaust gas etc. Substrate Parameter Viscosity at Tack free at Pencil hardness TSCA Product name 25℃ mm2/s 25℃ min after 7 days Treated Untreated Not X-40-2450X 1.0 90 6H Listed Antistatic layer (Not specified values) 11 Resin Hybridization Agents Acrylic Resins
We have products designed for use with water-based, solvent-based, and UV-cure acrylic resins.
Resulting Properties Properties that can be Imparted to Acrylic Resins • Better heat resistance Heat Resistance 5 • Higher weatherability • Improved water repellency 4 Weatherability Water • Increased flexibility 3 Resistance • Enhanced wear resistance 2 No Additive • Better water resistance 1 Silane Coupling Agents • Improved adhesion
Resin Hybridization Agents Silicone Oligomers • Higher hardness 0 • Room-temperature curability Silicone Resins Modified Silicone Fluids Flexibility Adhesion
Wear Resistance
Product List Water type, Solvent type Active Recommended Product category Product name Type Solvent Applicable type Features TSCA ingredient % adding amount % KBM-1003 Vinyl 100 None Water or solvent 0.5-2.0 Methoxy tri-functional Listed
Silane coupling agents KBM-503 Methacrylic 100 None Water or solvent 0.5-2.0 Methoxy tri-functional Listed (Radical reaction type) KBE-503 Methacrylic 100 None Water or solvent 0.5-2.0 Ethoxy tri-functional Listed Not KBM-502 Methacrylic 100 None Water or solvent 0.5-2.0 Methoxy di-functional Listed Not KBE-502 Methacrylic 100 None Water or solvent 0.5-2.0 Ethoxy di-functional Listed KBM-303 Epoxy 100 None Water or solvent 0.5-2.0 Alicyclic epoxy Listed Silane coupling agents KBM-403 Epoxy 100 None Water or solvent 0.5-2.0 Glycidyl Listed (Room temperature KBM-603 Amino 100 None Water or solvent 0.5-2.0 Diamine Listed cure type) KBE-903 Amino 100 None Water or solvent 0.5-2.0 Primary amine Listed KC-89S Methyl 100 None Water or solvent 10-20 Low DP (degree of polymerization) Listed KR-515 Methyl 100 None Water or solvent 10-20 Medium DP Listed Silicone oligomers KR-500 Methyl 100 None Water or solvent 10-20 Medium DP Listed KR-510 Methyl / Phenyl 100 None Solvent 10-20 Excellent compatibility Listed KR-211 Methyl / Phenyl 70 Xylene Solvent 10-50 Excellent compatibility Listed Silicone resins KR-212 Methyl / Phenyl 70 Xylene Solvent 10-50 Excellent flexibility and compatibility Listed KR-216 Propyl / Phenyl 100 None Solvent 10-50 Solid type Listed X-22-174ASX Single-end Methacrylic 100 None Solvent 0.5-20 Short chain length Listed Modified silicone fluids X-22-174BX Single-end Methacrylic 100 None Solvent 0.5-20 Medium chain length Listed KF-2012 Single-end Methacrylic 100 None Solvent 0.5-20 Long chain length Listed (Not specified values)
Application Examples • Construction exterior parts • Heavy-duty anticorrosion, exterior building (Chemical plant) • Automotive paint (Car, Train) • Automotive parts • Display, electrical equipment
●Exterior construction parts ●Hard coating ●Heavy-duty anticorrosion paint
12 Resin Hybridization Agents
Process of silicone hybridization Water, Solvent type
Radical Polymerization Properties Imparted
Silane Coupling Agents Weatherability, Adhesion, Radical Reaction Type Room Temperature Cure, Water Resistance Acrylic Monomer Single-end Modified Water Repellency, Silicone Fluids Flexibility Heat Reaction Dehydration or Dealcoholization Condensation Resin Hybridization Agents
Acrylic Polymer Silicone Weatherability Oligomers
Dehydration-condensation
Acrylic Polymer Heat Resistance, Silicone Resins Weatherability Silicone Modified Acrylic Resin
Reaction with Organic Functional Groups
Acrylic Polymer Silane Coupling Agents Adhesion, Room Temperature Cure Type Water Resistance Room Temperature Reaction
Product Type
●Silicone Oligomers ●Modified Silicone Fluids Longer chain, Higher molecular weight Higher molecular weight single-end termination (Improves weatherability) (Improves weatherability) Short chain type (Improves water repellency, (Excellent radical Longer chain film-forming ability and copolymerizability) (Improves KC-89S KR-515 KR-500 water repellency, copolymerization ability) releasability) Imparts phenyl groups X-22-174ASX X-22-174BX KF-2012 (Improves compatibility)
KR-510 ●Silane Coupling Agents Radical Reaction Type
Methacrylic Type ●Silicone Resins KBM-503 Methoxy / KBM-502 Tri-functional (Standard) Di-functionalization Higher molecular weight and phenyl groups KR-212 (Improves storage stability, water (Improves flexibility and compatibility) repellency, lower VOC content)
KR-211 Di-functionalization (Improves storage stability, water repellency, lower VOC content) Solidification (Solvent less) KR-216 KBE-503 KBE-502
13 Resin Hybridization Agents Acrylic Resins
Synthesis Examples of Heat Reaction Type
●Modification via Radical Polymerization using KBM-503 Results in improved adhesion to substrates and improved moisture resistance. ●Model of Resin Modification
Water Type Solvent Type Acrylic Resins 1 MMA* , Polymerization MMA*1, Polymerization 2 KBM-503 Water initiator 2 KBM-503 Solvent BMA* etc. Surfactant BMA* etc. initiator Total about Total about C O C O 50 wt. part 0.5-2 wt. part 50-100 wt. part 1-5 wt. part 50 wt. part 0.5-2 wt. part 50-100 wt. part 1-2 wt. part O KBM-503 O KBM-503
C3H6 C3H6 Si O R Si O R Reaction Reaction Resin Hybridization Agents OO OO
Substrate Silicone Modified Silicone Modified Acrylic Emulsion Acrylic Resin (Non-volatile content : about 50%) (Non-volatile content : about 50 %) Improving Adhesion
*1 MMA=Methyl methacrylate *2 BMA=Butyl methacrylate
●Modification via Dehydration-condencsation or ●Model of Resin Modification Dealcoholization-condensation using KR-500. Results in improved adhesion to substrates and enhanced weatherability. Acrylic Resins
Polymerization MMAetc. KR-500 KBM-503 Water initiator C O C O Surfactant 40 wt. parts 5-10 wt. parts 1-2 wt. parts 50-100 wt. parts a few parts O KBM-503 O KBM-503 C3H6 C3H6 Si O R Si O R Improving Improving OO Weatherability OO Weatherability KR-500 KR-500 Stirring (Emulsifying)
Copolymerization (Heating)
Cooling
pH Adjustment (pH around 8)
OOOOOO
Silicone Modified Acrylic Emulsion Substrate (Non-volatile content : about 30-50 %) Improving Adhesion Improving Adhesion
●Modification via Radical Polymerization using KF-2012. Silicone chains are grafted onto the acrylic resin, thereby improving the surface characteristics and water repellency.
Polymerization MMAetc. KF-2012 Solvent Imparting Water Repellency initiator ●Model of Resin Modification Total about 50 wt. parts 5-10 wt. parts 50-100 wt. parts 1-2 wt. parts Silicone Silicone
Reaction KF-2012 Si KF-2012 Si
C3H6 C3H6 O O CO CO Silicone Modified Acrylic Resin Acrylic Resins (Non-volatile content : about 50 %)
14 Resin Hybridization Agents
Product List UV type Active Applicable Recommended Product category Product name Type Solvent Features TSCA ingredient % type adding amount % KBM-5103 Acrylic 100 None UV 1-50 Standard product Listed Not Silane coupling agents X-12-1048 Acrylic 100 None UV 1-50 Acrylic group / Si ratio = 1 Listed Not X-12-1050 Acrylic 100 None UV 1-50 Polymer type, Acrylic group / Si ratio = 5 Listed Not KR-513 Acrylic / Methyl 100 None UV 10-50 Condensation cure type of KBM-5103 Listed Silicone oligomers Not X-40-9308 Acrylic 100 None UV 10-50 High hydrolyzability Listed X-22-164A/B Dual-end Methacrylic 100 None UV 10-50 Slip property Listed Modified silicone fluids X-22-2445 Dual-end acrylic 100 None UV 10-50 Leveling property Listed (Not specified values)
Process of Silicone Hyblidization : UV Type
Properties Improved Resin Hybridization Agents
Acrylic Silane Adhesion Coupling Agents
Oligomer Containing Acrylic Polymer Acrylic Groups High Hardness, Adhesion UV Cure
Single-end (metha) Water Repellency, Acrylic Modified Fluid Wear Resistance Silicone Modified Acrylic Resin
Hard Coating Application Silicone oligomers containing acrylic groups can be used with acrylic coating resins to produce coatings with higher hardnesses. In addition to the products described above, Shin-Etsu has other with unique molecular structures like those shown below.
Chemical Structures
X−12−2475 X−12−2430C
O O O O O O O O F O O
Si SiO O Si O Si SiO O Si O
O O O O O O O
O F F
F =Fluoroalkyl X-12-2475 and X-12-2430C are not listed in TSCA.
Acrylic Coating Material Blend Ratio ●Durability Testing Dipentaerythritol triacrylate : 80 wt. part Product name Pencil hardness Taber abrasion test Hexanediol diacrylate : 20 wt. part ∆Haze(500g load, 100 rotations) 2-Hydroxy-2-methyl-1 phenyl-plopane-1-one : 10 wt. part KR-513 2H 3.0
The above acrylic coating / Si material = 100 / 50 wt. part X-12-1050 2H 3.0
X-40-9308 2H 3.0 Application / Cure Method X-12-2475 3H 2.5 Film thickness : about 20μm Substrate : POLYCASE made by Sumitomo Bakelite Co., Ltd. X-12-2430C 2H 3.0 ECK100 clear 2mm thickness Blank H 4.0 UV curing condition : High-pressure mercury vaper lump (Not specified values) 600mJ/cm2 Nitrogen substitution 15 Resin Hybridization Agents Polyester & Alkyd Resins
Polyester and alkyd resins are inherently flexible and chemically resistant. By giving these the heat resistance and weatherability of a silicone, we create a much more durable resin.
Resulting Properties Properties that can be Imparted to Polyester & Alkyd Resins • Better heat resistance Heat Resistance 5 • Higher weatherability • Increased flexibility 4 Weatherability Water • Enhanced wear resistance 3 Resistance • Better water resistance 2 No Additive • Better cold resistance 1 Silane Coupling Agents • Improved adhesion
Resin Hybridization Agents 0 Silicone Oligomers Silicone Resins Modified Silicone Fluids Flexibility Adhesion
Wear Resistance
Product List Active Recommended Product category Product name Type Solvent Applicable type Features TSCA ingredient % loading % KBM-503 Methacrylic 100 None Solvent 0.5-2.0 Methoxy tri-functional Listed KBE-503 Methacrylic 100 None Solvent 0.5-2.0 Ethoxy tri-functional Listed Not Silane Coupling Agents KBM-502 Methacrylic 100 None Solvent 0.5-2.0 Methoxy di-functional Listed Not KBE-502 Methacrylic 100 None Solvent 0.5-2.0 Ethoxy di-functional Listed KBM-5103 Acrylic 100 None Solvent 0.5-2.0 Excellent reactivity Listed KC-89S Methyl 100 None Solvent 10-20 Low DP (degree of polymerization) Listed KR-515 Methyl 100 None Solvent 10-20 Medium DP Listed Silicone Oligomers KR-500 Methyl 100 None Solvent 10-20 Medium DP Listed KR-510 Methyl / Phenyl 100 None Solvent 10-20 Compatibility Listed KR-211 Methyl / Phenyl 70 Xylene Solvent 10-50 Excellent compatibility Listed Silicone Resins KR-212 Methyl / Phenyl 70 Xylene Solvent 10-50 Excellent flexibility, compatibility Listed KR-216 Propyl / Phenyl 100 None Solvent 10-50 Solid type Listed KF-2201 Phenol modified 100 None Solvent 0.5-10 Heat resistance, Excellent flexibility Listed Modified Silicone Fluids X-22-3701E Carboxylic acid modified 100 None Solvent 0.5-10 Release property Listed (Not specified values)
Application Examples • Building exterior parts (Rolled Steel) • Consumer electronics parts (Facility, Equipment) • Construction parts • Automotive paints(Car, Train)
●Painted Steel ●Tanks
16 Resin Hybridization Agents
Synthesis Examples
Weatherability is improved by inserting KR-510 into the polyester resin.
●Reaction Mechanisms Dealcoholization Polyester Resin -C-OH + RO-Si≡ Polyester Resin -C-O-Si≡ + R-OH condensation reaction
Dehydration -C-OH + HO-Si≡ -C-O-Si≡ + H2O condensation Polyester Resin Polyester Resin
●Polyester Resin Modification with Silicone Oligomers ●General Properties ●Film Properties Product name Cure condition Tetraisopropyl KR-510 285℃×1min 285℃×10min Polyester Resin KR-510 Parameter Parameter titanate Colorless to pale yellow Appearance slightly clowdy liquid Pencil hardness 2H 4H
70 wt. parts 30 wt. parts 0.5-2 wt. parts Resin Hybridization Agents Viscosity at 25℃ mm2/s 100 Adhesion (cross cut adhesion test) 100/100 100/100
Specific gravity at 25℃ 1.16 Impact resistance Dupont test cm Min.50 Min.50
Refractive index at 25℃ 1.509 MEK* rubbing times 100 Min.100
Reaction(110℃-125℃×30min) Active ingredient % 100 Xylene rubbing times 10 Min.100 (Not specified values) *MEK : Methyl ethyl ketone (Not specified values) PGM-AC*
Stop reaction ●Weatherability Test Result of Silicone Modified Polyester Resin
100 Filtration, Adjusting Non-volatile Content Silicone content 50%
80 Silicone content 30%
Silicone content 0% 60
Silicone Modified 40 Polyester Resins
(Non-volatile content : about 50%) 20 Gloss retention ratio (%) ratio retention Gloss Test method: 0 Sunshine weatherometer 0 200 400 600 800 1,000 Time (h) *PGM-AC:Propylene glycol monomethylether acetate
Heat resistance is improved by inserting a high-molecular-weight silicone resin into the alkyd resin.
●Reaction Mechanisms
Dehydration Alkyd Resins -C-OH + HO-Si≡ Alkyd Resins -C-O-Si≡ + H2O condensation
●Alkyd Resin Modification with Silicone Oligomer ●Heat Resistance Comparison Data at 250℃ Room Temperature Reaction Heat Reaction
KR-211 100 Alkyd Resins or Alkyd Resins KR-216 KR-212 Silicone resins 50-70 wt. parts 30-50 wt. parts 50-70 wt. parts 30-50 wt. parts 90
Silicone modified alkyd resins 80 Reaction (100℃-130℃×2-5h) 70 Epoxy resins Gloss retention ratio (%) 60 Silicone Modified Alkyd Resins Alkyd resins 50 0 20 40 60 80 100
●Product Type Time (h)
Higher molecular weight, higher phenyl content Solidification (Improved flexibility, compatibility) (Solventless) KR-211 KR-212 KR-216
17 Resin Hybridization Agents Epoxy Resins
Shin-Etsu produces a line of silane coupling agents and silicone oligomers that help improve adhesion to substrates, and silicone oligomers and silicone resins that help improve the heat resistance and weatherability of epoxy resins. Resulting Properties Properties that can be Imparted to Epoxy Resins •Better heat resistance Heat Resistance 5 •Higher weatherability •Improved adhesion 4 Water •Better water resistance 3 Resistance Weatherability 2 No Additive 1
Resin Hybridization Agents Silane Coupling Agents 0 Silicone Oligomers
Silicone Resins
Flexibility Adhesion
Wear Resistance
Product List Active Applicable Recommended Product category Product name Type ingredient % Solvent type adding amount % Features TSCA KBM-403 Epoxy 100 None Solvent 0.5-2.0 Standard product Listed Not X-12-981S Epoxy 100 None Solvent 0.5-2.0 Multi-functional type Listed Not X-12-984S Epoxy 100 None Solvent 0.5-2.0 Multi-functional type Listed Silane Coupling Agents KBE-903 Amino 100 None Solvent 0.5-2.0 Standard product Listed KBE-9103P Amino 100 None Solvent 0.5-2.0 Protected functional group type Listed Not X-12-972F Amino 15 Ethanol Solvent 0.5-2.0 Ethanol solution, Multi functional type Listed Not KR-516 Epoxy / Methyl 100 None Solvent 0.5-2.0 Epoxy equivalent 280g/mol Listed Not KR-517 Epoxy 100 None Solvent 0.5-2.0 Epoxy equivalent 830g/mol Listed Silicone Oligomers KR-500 Methyl 100 None Solvent 10-20 Standard product Listed KR-510 Phenyl 100 None Solvent 10-20 Standard product Listed KR-211 Methyl / Phenyl 70 Xylene Solvent 10-50 Standard product Listed Silicone Resins KR-212 Methyl / Phenyl 70 Xylene Solvent 10-50 Excellent flexibility, compatibility Listed KR-216 Propyl / Phenyl 100 None Solvent 10-50 Solid type Listed (Not specified values)
Application Examples • Heavy-duty (Bridges, Tanks, Steel structures) • Marine paint
●Bridge ●Pipes
●Marine Paint
18 Resin Hybridization Agents
Protected Functional Group Silane Coupling Agent KBE-9103P The functional group is protected in KBE-9103P, which means the silane can be mixed with materials that are chemically incompatible. The user can also expect improved adhesion. ●Resulting Properties ●General Properties ●Adhesion Tests with Epoxy Internal-addition Adhesives • More stable compositions [Blend] JER827 made by Mitsubishi Chemical Corporation 100 wt. part Parameter Product name KBE-9103P (epoxy resins) Silane Coupling Agents 5 wt. part Triethylenetetramine 5 wt. part • Improved adhesion Purity at 25℃ GC% min. 95 Viscosity at 25℃ mm2/s 3.0 Substrate : Aluminum ●Chemical Structure of KBE-9103P Product name No (Not specified values) Condition additive KBE-9103P KBE-903 ●Storage Stability in Epoxy Resins Initial strength MPa 3.9 7.6 6.1 Reactive site Me [Blend] JER827 made by Mitsubishi Chemical Corporation 50 wt. part After water resistance test (95℃×10h) MPa 3.4 6.4 5.2 Toluene 50 wt. part Silane Coupling Agents 5 wt. part (Not specified values) Viscosity Substrate : Steel (EtO)3Si N i-Bu Product name No Resin Hybridization Agents Product name No Condition additive KBE-9103P KBE-903 Days additive KBE-9103P KBE-903 2 MPa 12.4 17.8 15.7 After 3 days mm /s 4.2 4.4 7.8 Initial strength
2 MPa 9.3 14.1 13.5 After 14 days mm /s 4.3 4.7 8.6 After water resistance test (95℃×10h) (Not specified values) (Not specified values)
Multi Functional Silane Coupling Agent These silane coupling agents contain an organic polymer chain with alkoxy groups and several organic functional groups. Their large number of reaction sites helps guarantee better adhesion. Because their main components are low in volatility and they have good film-forming ability, these silane coupling agents can also be used as primers.
●Chemical Structure of Multi Functional Silane Coupling Agents ●Interface Adhesion Test of Glass / Epoxy Resin
130 Si(OR)3 R = Me, Et 128 Organic Organic 126 Functional Group Functional Group 124 122 120 118 Organic Group 116 114 112 110 Organic Organic 108 106 Functional Group Si(OR)3 Functional Group 104 102
Interfacial shear strength (Relative value) 100 89 ●Features and Resulting Properties Untreated 1%KBE-903 1%X-12-972F 1%KBM-403 1%X-12-984S Many sites for reaction with resins Improved coupling performance Test method Treatment method Low volatility Less silane required (1) 1% aqueous solution applied to glass substrate. (2) Cured material [EPIKOTE 828 (epoxy resin made by Film-forming ability Can be used as primer Mitsubishi Chemical Corp.) / triethylenetetramine] is prepared, adhesive strength is tested. Contain trialkoxysilyl groups Improved adhesion *Calculated against baseline value of 100 for adhesion to untreated substrate.
Product List Number of Organic reactive groups 2 Reactive group functional group Product name Alkoxy group per Si Viscosity mm /s equivalent g/mol Note Amino X-12-972F EtO 5 8.6 600 15% Ethanol solution X-12-981S EtO 3 1,000 290 - Epoxy X-12-984S EtO 3 2,000 270 - (Not specified values) Synthesis Example
Heat resistance is improved by inserting KR-212 into the epoxy resin. ●Modification Example with Silicone Resins
●Reaction Mechanism Epoxy Resin KR-212 Metalic Catalyst Dehydration 50-70 wt. parts 30-50 wt. parts 0.2-1 wt. parts Epoxy Resin -C-OH + HO-Si≡ Epoxy Resin -C-O-Si≡ + H2O condensation ●General Properties Reaction Viscosity Viscosity Specific Product (140℃×5-10h) Type Appearance at at 25℃ gravity at Solvent name 25℃ mPa•s mm2/s 25℃ Methyl / Colorless 28 8.6 1.07 Xylene KR-212 Phenyl type transparent liquid Silicone Modified Epoxy Resin (Not specified values)
19 Resin Hybridization Agents Urethane Resins
Many types of polyurethane (e.g. thermoplastic polyurethane and synthetic leathers) can be modified with silicones to improve adhesion, flexibility, wear resistance and slip property.
Resulting Properties Properties that can be Imparted to Urethane Resins • Better heat resistance Heat Resistance 5 • Higher weatherability • Increased flexibility 4 • Enhanced wear resistance Weatherability 3 Water Resistance • Improved adhesion 2 • Better water resistance 1 No Additive • Improved slip property
Resin Hybridization Agents 0 Silane Coupling Agents
Modified Silicone Fluids
Flexibility Adhesion
Wear Resistance
Product List Active Applicable Recommended Product category Product name Type Solvent Features TSCA ingredient % type adding amount % KBE-9103P Amino 100 None Water or solvent 0.5-2.0 Protected functional group Listed KBM-9659 Isocyanurate 100 None Water or solvent 0.5-2.0 Multi-functional Listed X-12-5263HP Amino 100 None Water or solvent 0.5-2.0 Bis amine Listed Silane Coupling Agents Not X-12-1056ES Mercapto group protected 100 None Water or solvent 0.5-2.0 Protected functional group, low odor Listed KBE-9007 Isocyanate 100 None Water or solvent 0.5-2.0 Ethoxy tri-functional Listed KBM-403 Epoxy 100 None Water or solvent 0.5-2.0 Methoxy tri-functional Listed KF-6000 Dual-end carbinol 100 None Water or solvent 0.5-20 Excellent compatibility Listed KF-6001 Dual-end carbinol 100 None Water or solvent 0.5-20 Flexibility, wear resistance Listed Modified Silicone Fluids KF-6002 Dual-end carbinol 100 None Water or solvent 0.5-20 Flexibility, wear resistance Listed Not X-22-170BX Single-end carbinol 100 None Water or solvent 0.5-10 Excellent compatibility Listed Not X-22-176DX Single-end diol 100 None Water or solvent 0.5-10 Surface slick property Listed (Not specified values)
Application Examples • Construction parts • Consumer electronics parts • Automotive interior parts
●Synthetic Leathers for Automotive ●Interior Sealant
20 Resin Hybridization Agents
Protected Functional Group Silane Coupling Agent X-12-1056ES The organic functional group in X-12-1056ES is protected. This means the user may be able to use a one-component formulation where a two-component formulation was once required, or that the Silane Coupling Agent can be added at the same time as reactive materials because unwanted reactions are prevented. It also means a greatly increased shelf life.
●Application Example of Protected Mercapto Group Silane Coupling Agent X-12-1056ES 1 part moisuture cure OCN NCO Deprotection of S-Si + H2O Reaction of SH and NCO Improved adhesion Si(OEt)3 to substrate Hydrolyzable groups react with substrate (MeO)3Si S Two-component polyol cure Isocyanate crosslinking X-12-1056ES HO R OH
●Stability with Isocyanate Compounds Resin Hybridization Agents
30,000 KBM-803 2,000 KBM-803
25,000 X-12-1056ES X-12-1056ES 1,500 2,000
15,000 1,000
10,000
Viscosity (mPa•s) Viscosity (mPa•s) Viscosity 500 5,000
0 0 0 5 10 15 20 25 30 0 10 20 30 40 50 60 Time (Days) Time (Days) Change in viscosity when mixed with aromatic isocyanate (M-200) Change in viscosity when mixed with aromatic isocyanate (TLA-100) Condition : Silane 5 wt% added, storage at 50℃ Condition : Silane 5 wt% added, storage at 50℃
Synthesis Examples
●Modification Example with Single-end Diol Fluids ●Model of Graft Copolymer
Urethane Resins X-22-176DX Structure of X-22-176DX O H
90-99 wt. parts 1-10 wt. parts Silicone R
O H ●Resulting Properties 1. Slip property Reaction Graft Copolymer
2. Wear resistance (80℃×2h) Silicone Silicone
R R O O O O Silicone Modified CO C OO C C O Urethane Resins Urethane Urethane Urethane Resins NNHH Resins NNHH Resins
●Modification Example with Dual-end Carbinol Fluids ●Model of Block Copolymer
KF-6001 Urethane Resins Structure of KF-6001
80-99 wt. parts 1-20 wt. parts OH R Silicone R O H
●Resulting Properties 1. Flexibility Reaction 2. Wear resistance (80℃×2h) Block Copolymer H H H Urethane N C O R Silicone R O C N Urethane N C O R Silicone Silicone Modified Resins Resins Urethane Resins O O O
21 Surface Modifiers for Coating Silicone Powders
●Model of Hybrid Resin Part Shin-Etsu has developed a unique line of silicone powders which Silicone Powder fall into three categories: Hybrid Silicone Powder, Silicone Rubber Powder and Silicone Resin Powder. These products impart a variety of Rubber Part properties (i.e. lubricity, wear resistance and light diffusion) into coating agents and paints.
Silicone Resin Powder Silicone Rubber Powder Hybrid Silicone Powder Molecular structure: 3D network structure Molecular structure: Straight-chain crosslinked polymer Form: Rubber powders covered with resin ●KMP-706 by Scanning with ●KMP-594 by Scanning with ●KMP-600 by Scanning with Electron Microscope Electron Microscope Electron Microscope
●Model of Silicone Resin Powder ●Model of Silicone Rubber Powder ●Model of Hybrid Silicone Powder Surface Modifiers for Coating Pressure, Impact Pressure, Impact Pressure, Impact
Maintains the shape Deformed Deformed ●Features ●Features ●Features Heat resistance ++ Heat resistance + Heat resistance + Weatherability ++ Weatherability ++ Weatherability ++ Dispersibility into resins ++ Dispersibility into resins ± Dispersibility into resins ++ With organic solvents No swelling With organic solvents Swelling With organic solvents Rubber part swells Enhanced Properties ●Stress Relaxation, Impact Resistance ●Lubricity, Wear Resistance Silicone Rubber & No additive Silicone Resin Powder Hybrid Silicone Powder added Coatings & Paints Lu e bricity, Wear Resistanc Pressure,Impact Pressure,Impact
Silicone Rubber & Hybrid Silicone Paints & Coatings Powder absorb the pressure or Broken impact and relax the stress
Resin Powder - Resin Powder ++ Rubber Powder ++ Rubber Powder + Hybrid Powder ++ Hybrid Powder ++
●Soft-feel Property ●Light Diffusion Property
Silicone Rubber Powder Silicone Resin Powder Hybrid Silicone Powder Silicone Rubber Powder Soft-feel Property Hybrid Silicone Powder
Paints & Coatings Paints & Coatings
Resin Powder - Resin Powder ++ Rubber Powder ++ Rubber Powder ++ Hybrid Powder ++ Hybrid Powder ++ * ++:Excellent +: Good ±: Satisfactory -: Poor 22 Surface Modifiers for Coating
Product List Parameter Average Particle size True specific Moisture Rubber hardness Refractive index Product name Shape TSCA Type particle size μm distribution μm gravity content % Durometer A Rubber part Resin part KMP-706 Spherical 2 1-4 1.3 1 - - 1.43 Listed
Silicone resin KMP-701 Spherical 3.5 1-6 1.3 1 - - 1.43 Listed powder X-52-1621 Spherical 5 1-8 1.3 1 - - 1.43 Listed X-52-854 Spherical 0.7 0.2-5 1.3 1 - - 1.43 Listed KMP-594 Spherical 5 1-10 0.97 0.1 30 1.41 - Listed Silicone rubber KMP-597 Spherical 5 1-10 0.97 0.1 30 1.41 - Listed powder KMP-598 Spherical 13 2-30 0.97 0.1 30 1.41 - Listed KMP-600 Spherical 5 1-15 0.99 0.1 30 1.41 1.43 Listed KMP-601 Spherical 12 2-25 0.98 0.1 30 1.41 1.43 Listed Hybrid KMP-602 Spherical 30 4-60 0.98 0.1 30 1.41 1.43 Listed silicone powder KMP-605 Spherical 2 0.7-5 0.99 0.1 75 1.42 1.43 Listed X-52-7030 Spherical 0.8 0.2-2 1.01 0.1 75 1.42 1.43 Listed (Not specified values)
Product Data
Silicone Resin Powder Silicone Rubber Powder Hybrid Silicone Powder Surface Modifiers for Coating
●KMP-706 Particle Size Distribution [Hx2] ●KMP-594 Particle Size Distribution ●KMP-600 Particle Size Distribution 100 1.4 3 90 1.3 80 1.2 2.3 1.1 70 1 2 60 0.9 0.8 50 0.7 1.5 40 0.6 0.5 Volume (%) Volume (%) Volume Volume (%) Volume 1 30 0.4 20 0.3 0.5 0.2 10 0.1 0 0 0 0.5 1 2 3 4 5 10 20 0.7 1 2 3 4 5 6 7 8 10 0.7 1 2 3 4 5 6 7 10 20 30 Particle size(μm) Particle size(μm) Particle size(μm) (Not specified values) (Not specified values) (Not specified values)
●KMP-706 Heat Resistance ●KMP-594 Heat Resistance ●KMP-600 Heat Resistance (Weight changes vs. temperatures) (Weight changes vs. temperatures) (Weight changes vs. temperatures) 120 120 120 110 110 110
(%) 100 (%) 100 (%) 100 90 90 90 80 80 80 70 70 70 60 60 60 50 50 50 40 40 40 30 30 30 20 20 20 Weight changes Weight changes Weight changes 10 10 10 0 0 0 100 200 300 400 500 600 100 200 300 400 500 600 100 200 300 400 500 600 Rate of Temperature(℃) Rate of Temperature(℃) Rate of Temperature(℃) temperature increase: 10℃/min temperature increase: 10℃/min temperature increase: 10℃/min Atmosphere: Air (Not specified values) Atmosphere: Air (Not specified values) Atmosphere: Air (Not specified values)
Dispersibiilty Dispersibility in liquid epoxy resin
●Hybrid Silicone Powder KMP-601 ●Silicone Rubber Powder * *Applying a shearing force improves dispersibility of silicone rubber powders in resin.
23 Surface Modifiers for Coating KP Series
The KP Series of coating surface modifiers are highly effective in small amounts. They can be added to paints and coatings to help prevent defects and for surface modification.
Features of Polysiloxane
Structure of dimethylsiloxane 1.Low surface tension 2.Surface migration Silicone fluids have very low surface tension. They migrate easily to the surface of resins. Suface tension(25℃) Coating solution Types of liquid mN/m Silicone Dimethyl silicone KF-96 21
Toluene 28
Mineral oil 30
Glycerin 63 Migration to surface Water 72 Surface Modifiers for Coating
3.Length of siloxane chains can be controlled
Shorter chains: Better compatibility with resins, solvents, lower surface tension and improved flow properties.
Longer chains: May be incompatible with resin, solvents, and produce hammertone Length of Siloxane Main Chain effects (cissing).
Features Provided by the Organic Reactive Groups Compatibility with organic resin solutions. Surface tension can be controlled by changing the type of organic functional group.
Type Features
Organic groups consisting of chains of repeated ethylene oxide units (EO) or propylene oxide units (PO), or a combination of the two. Polyether A high proportion of EO units translates to strong hydrophilicity and water solubility, and good compatibility with acrylic and urethane resins. A high proportion of PO units translates to strong hydrophobicity.
Polyol Organic groups having a relatively compact structure with large numbers of hydroxyl groups. Silicone rich, and yet strongly hydrophilic with high polarity. Organic groups composed of acrylic polymers. Have good film-forming ability and compatibility with acrylic resins. Acrylic
Fatty acid ester Organic groups with the same basic structure as alkyd resins.Highly compatible especially with alkyd resins. Highly compatible with resins having large numbers of aromatic rings (e.g. epoxies). Phenyl Because they are hydrophobic, these groups have poor compatibility with hydrophilic resins. Organic functional Silicones dissolve very well in aromatic solvents and thus show little activity in aromatic solvent-based paints. group Fluorine Fluorine modification will produce an agent with a surface tension-reducing and defoaming effect in aromatic solvent-based paints and coatings. Poor compatibility with many resins means there can be a risk of cissing or other problems.
Alkyl Introducing alkyl or aralkyl groups will produce an additive with balanced performance and higher Aralkyl hydrophobicity. Organic groups composed of polyester polymers. Higher molecular weights than most other organic groups. Polyester Have good film-forming ability and particularly good compatibility with polyester paints and coatings.
24 Surface Modifiers for Coating
Relationship between Silicone Structure and Development Property Depending on the silicone chain length and the difference between the solubility parameters (SP) of the KP series and paint/coating, the KP series can show leveling, defoaming or slip improvement.
●Main Chain Length of Silicone Hammer tone forming property ●SP value difference
Slip property Slip property Leveling property Defoaming property Leveling property Defoaming (Releasability) (Releasability) property Low Medium High Low Medium High Silicone Film-forming Property Silicone Surface Migration Speed Low High Slow Fast
Main Applications and Functional Mechanism
●Leveling Agent (Improves Flowability) ●Defoaming Agent
Silicone moves to the surface of air bubbles. Roller coating Spray coating Paint
Paint Bubbles Substrate Paint Surface Modifiers for Coating
Moving to the surface, bubbles are broken by the following mechanism: Substrate Substrate
Silicone migrates to the surface. Bubbles
The leveling effect of the silicone helps The flow properties of the silicone helps improve produce a smoother coating surface. the wetting and spreading properties of the paint. 1.Adhesion 2.Penetration 3.Diffusion 4.Defoaming
Bubble membrane
Paint Paint Silicone Substrate Substrate
Defoaming / foam-inhibiting effect is The difference in surface tension between the silicone and the related to differences in the polarity and paint results in improved wetting and smoothness. compatibility between the paint and silicone.
●Slip Agent (Releasability Imparter) ●Anti-floating / Anti-flooding Agents ●Hammertone Agent
Silicone migrates to the surface. Silicone migrates to the surface. Paint Long-chain Silicone
Imparting water Reducing coefficient repellency of friction
Substrate Substrate Paint
Paint Convaction
Paint Substrate Substrate Paint ●Appearance of Hammertone
Silicone migrates to the surface, resulting in The silicone migrates to the coating surface • Improved slip property to form a layer that helps prevent color Long-chain silicones can encourage • Improved antiblocking properties irregularities caused by pigment separation. cissing and can thus be added to paints • Improved scratch and chip resistance This separation can be caused by convection when a hammertone finish is desired. • Improved antifouling properties currents that form in the coating as it dries.
25 Surface Modifiers for Coating KP Series
Product List
Molecular Water type Standard Application Type Product name Solubility weight level Active Solvent TSCA parameter (Length of siloxane Ingredient % applicability*1 adding amount main chain) wt% KP-124 8.2 Medium 100 - ± 0.005-1.0 Listed 2 Not KP-109 8.2 High 50 PGM* ± 0.01-1.0 Listed KP-110 8.3 Small 100 - ++ 0.05-5.0 Listed KP-121 8.4 Small 100 - ± 0.01-1.0 Listed KP-118 8.4 Medium 100 - ± 0.01-1.0 Listed KP-341 8.6 Medium 100 - ± 0.01-2.0 Listed Polyether modified KP-112 8.7 High 100 - + 0.01-2.0 Listed KP-125 8.7 Medium 100 - + 0.01-1.0 Listed KP-101 8.7 High 100 - + 0.01-1.0 Listed KP-106 8.9 Small 100 - ++ 0.01-2.0 Listed KP-120 10.0 High 100 - + 0.02-4.0 Listed Leveling 2 Not KP-105 10.4 Medium 30 PGM* + 0.05-10.0 Listed Polyol modified 2 Not KP-104 11.6 Medium 30 PGM* ++ 0.1-15.0 Listed Not Acrylic resin modified KP-611 9.2 High 50 Butyl acetate - 0.1-10.0 Listed Fatty acid ester modified KP-626 8.4 High 10 Butyl acetate - 0.02-2.0 Listed KP-327 7.7 Small 100 - - 0.001-0.2 Listed Phenyl modified KP-323 8.2 Small 100 - - 0.002-0.5 Listed KP-322 8.4 Medium 100 - - 0.005-1.0 Listed Surface Modifiers for Coating Fluorine modified KP-625 7.1 Small 5 DAA*3 - 0.001-2.0 Listed KP-623 8.5 High 10 Isododecane - 0.002-4.0 Listed Alkyl or KP-624 8.8 Medium 10 ECH*4 - 0.001-2.0 Listed Aralkyl modified KP-620 9.2 Medium 100 - - 0.0002-0.4 Listed KP-623 8.5 High 10 Isododecane - 0.002-4.0 Listed KP-625 7.1 Small 5 DAA*3 - 0.001-2.0 Listed Fluorine modified 5 Not Defoaming KP-651 7.2 High 8 MXHF* - 0.0003-0.5 Listed (Compound) KP-652 - - 100 - - 0.0001-0.1 Listed (Compound emulsion) KP-650 - - 55 Water ++ 0.001-0.2 Listed (Dimethyl silicone) KP-310 7.4 Ultra high 10 Toluene - 0.0005-2.0 Listed 2 Not KP-109 8.2 High 50 PGM* ++ 0.02-2.0 Listed Not Slip Polyether modified KP-306 8.3 High 10 Xylene - 0.1-10.0 Listed KP-301 8.7 Medium 10 Toluene - 0.2-20.0 Listed Polyester resin modified KP-621 9.1 High 10 Toluene / Xylene - 0.2-10.0 Listed KP-369 7.4 Small 100 - - 0.05-2.0 Listed (For solvent type) Release KP-368 7.4 Medium 100 - - 0.05-2.0 Listed (For water type) KP-126 8.6 High 100 - ++ 0.2-10.0 Listed *1 ++ = Excellent + = Good ± = Satisfactory - = Not applicable *3 DAA = Diacetone alcohol *5 MXHF = m‐xylenehexafluoride (Not specified values) *2 PGA = Propylene glycolmonomethyl ether *4 ECH = Ethylcyclohexane
Reference: SP values (solvents & polymers) *The SP values are reference values. Values may vary depending on calculation method. SP value Types of solvent SP value Boiling point ℃ Silicone Solubility Types of polymer (Theoretical value) Isooctane 7.0 99 ++ Fluorine resin (PTFE) 6.2 n-heptane 7.4 98 ++ Polyethylene 7.9 Diethyl ether 7.4 35 + Polypropylene 8.0 3-methoxy-3-methyl-butyl acetate 8.5 188 + Alkyd resin (long-oil) 7-9 Methyl isobutyl ketone 8.4 116 + SBR Rubber 8.1-8.7 Ethyl acetate-n-butyl 8.5 126 + NBR Rubber 8.8-9.5 Propylene glycol monomethylether acetate 8.7 146 + Polystyrene 8.6-9.7 Xylene 8.8 138 ++ Acrylic resin (Polystearyl methacrylate) 7.8 Toluene 8.9 111 ++ Acrylic resin (Polybutyl acrylate) 9.0 Ethyl acetate 9.1 77 + Acrylic resin (Polymethyl methacrylate) 9.5 Diacetone alcohol 9.2 168 + Acrylic resin (Polymethyl acrylate) 10.0 Methyl ethyl ketone 9.3 80 + Acrylic resin (Polymethacrylate) 10.7 Ethylcellosolve 9.9 136 - Polyvinyl acetate 9.4 Acetone 10.0 56 ± Polyvinyl chloride 9.5-9.7 Propylene glycolmonomethyl ether 10.5 120 - Polycarbonate 9.7 Tert-butanol 10.6 83 - Epoxy resin 9.7-10.9 Isobutanol 11.0 107 ± Amino resin 9.6- 10.1 n-butanol 11.1 118 ± Polyurethane resin 10.0-11.0 Isopropyl alcohol 11.5 82 + Cellulose acetate 10.0 Dimethylformamide 12.0 153 - Ethyl cellulose 10.3 Ethanol 12.8 78 - Polyester resin (PET) 10.7 Propylene carbonate 13.3 242 - Nitrocellulose 10.6-11.5 Ethylene glycol 14.2 198 - Phenol resin 11.5 Methanol 14.8 65 - Polyamide resin (Nylon-66) 13.6 Water 23.4 100 - Polyvinyl alcohol 23.4 *Dimethyl silicone fluid has an SP value of 7.2, while the SP value of a methyl phenyl silicone fluid can be 9 or higher, depending on phenyl content. 26 Surface Modifiers for Coating
KP Series Selection Guide, Arranged by Purpose *This map is offered as a guide for product selection.
For Solvent-based Paints Urethane Paints Polyester Paints Improved Leveling Ability KP-112 KP-626 3rd Option KP-104 KP-118 KP-105 KP-369 KP-625
Epoxy Paints Aromatic Solvent-based Paints KP-323 KP-623 KP-623 KP-323 KP-322 KP-327 KP-625
Improved Leveling Ability Alkyd Paints 2nd Option KP-626 Glycol Ethers KP-623 Solvent-based Paints KP-624 Improved Leveling KP-112 KP-118 Ability Surface Modifiers for Coating KP-109 Cellulose Paints KP-124 KP-104 KP-106 Alcohol-based Paints KP-105 KP-625 KP-125 Improved Leveling Ability KP-101 1st Option KP-104
All-round Product Improved Anti-cissing Property* KP-341 Improved Releasability (Completely Eliminates Fine Cissing) KP-369,KP-368 KP-611 (For Urethanes) KP-120 KP-611 (For Acrylics) KP-620 *To eliminate cissing, first try adding Improved Antiforming Property Increase Slip Property a smaller amount Reduce Slip Property of product. KP-623 KP-109 KP-624 KP-625 KP-101 KP-106 KP-620 KP-105 (Add Additional KP-651, KP-652)
For Imparting Ranking of Slip Agents Water-based Anti-cissing Property Paints KP-120
Excellent KP-341 Imparting KP-301 Antiforming Standard Products Property Improve KP-110 KP-105 Additional Releasability KP-106 KP-306 amount KP-126 KP-109 KP-650 KP-104 * KP-369 KP-368 Anti-cissing Property
Increase Slip Property KP-310 KP-109 Poor
* KP-104: Works especially well with water-soluble resins such as Polyvinyl Alcohol. Low Slick Property High
27 Surface Modifiers for Coating Other Highly Functional Products
Ionic Silicone Oligomer X-40-2450 X-40-2450 is a silicone oligomer created through the silicone modification of an ionic liquid. When added in small amounts to resins, X-40-2450 migrates easily to the coating surface, improving its heat resistance, and provides long-lasting antistatic properties.
●Resulting Properties ●General Properties ●Structural Model •Excellent antistatic agent Product name X-40-2450 Parameter ●Test Result of Antistatic Properties Form of silicone Siloxane Colorless transparent liquid Product name Appearance - + X-40-2450 Ionic liquid*4 Parameter Non-volatile content % 55 10 13 Initial 4×10 >10 Ionic Group Viscosity mm2/s 2.5 After water 11 13 wiping test*1 1×10 >10 Surface Specific gravity 25℃ 0.97 resistivity After immersion 11 13 Ω 2 3×10 >10 test in water* Solvent Methyl ethyl ketone After 11 13 3 8×10 >10 heating test* TSCA Not Listed (Not specified values) (Not specified values) ●Mix ratio : Dipentaerythritol hexaacrylate / 2-Hydroxy-2-Methyl-1-Phenyl-Propane-1-one / ●Comparison of Antistatic Properties ●Mechanism of Silicone Action Methyl ethyl ketone / X-40-2450 = 48.8 / 2.4 / 48.8 / 2.0 ●Substrate : Treated Untreated Coating solution PET (Cosmo Shine A4300) made by TOYOBO CO., LTD. 2 Silicone Surface Modifiers for Coating ●Cure conditions : 600mJ/cm under a nitrogen atmosphere ●Film thickness : 5μm *1 After rubbing the cured specimen 50 times with wet absorbent cotton, wiped off remaining water and took the measurements. *2 After submerging the cured specimen into water (25℃×5h), wiped off remaining water and took the measurements. *3 Measured after heating the cured specimen (105℃×1 day). Migration to surface *4 (n-C8H17)3(CH3)N+(CF3SO2)2N-
Photostabilizing Group Silane TMPS-E TMPS-E is a silane coupling agent that contains photostabilizing groups. TMPS-E neutralizes free radicals formed through exposure to light, thus protecting resins against degradation.
●Resulting Properties ●General Properties ●Chemical Structure of TMPS-E •Improves UV resistance Product name TMPS-E •Improves adhesion Parameter Viscosity at 25℃ mm2/s 8.0
0.95 Specific gravity at 25℃ (EtO)3Si O N-H Refractive index at 25℃ 1.44
Active ingredient % 100
TSCA Not Listed (Not specified values)
●Reaction Mechanism ●Adhesion Test Data of Glass / Epoxy Resin Interface
160 R R R R 150 140 O2 130 N UV N N 120 . 110 H O O R 100 90 . R=O+ROH ROO 80 Interfacial shear strength (Relative value) Untreated KBM-403 TMPS-E
28 Surface Modifiers for Coating
Hydrophilic Anti-stain Agents KP-912, KP-913, KP-914 KP-912, KP-913 and KP-914 are silicone oligomers that contain alkoxysilyl groups. When mixed with water, alkoxysilyl groups hydrolyze to form hydrophilic silanols groups, properties which allow these products to function as antifouling agents in paints for construction materials. KP-913 shows its hydrophilic properties earlier.
●General Properties
Parameter Viscosity at Refractive index at Alkoxy group content Alkoxy Groups TSCA Product name 25℃ mm2/s 25℃ wt% Not KP-912 Methoxy / Ethoxy 12 1.414 50 Listed Not KP-913 Methoxy 350 1.448 9.5 Listed Not KP-914 Methoxy / Ethoxy 20 1.418 50 Listed (Not specified values) ●Antifouling Mechanism ●Hydrophilicity of Coatings with Oligomers Added
100
Dirt Dirt 80
60
40 Surface Modifiers for Coating
Substrate Dirt
Coating layer 20
Water Water contact angle(degree) None added KP-912 KP-914 Test conditions: Fluoropolymer paint with 5 phr of oligomer Water contact angle measured after immersion for 16 h in 2.5% sulfuric acid solution.
Benzotriazole Group Silane X-12-1214A X-12-1214A contains a common corrosion inhibitor (benzotriazole) plus an alkoxysilyl group. By improved adhesion to metals, X-12-1214A helps ensure long-lasting protection against corrosion.
●Resulting Properties ●General Properties ●Chemical Structure of X-12-1214A
•Protects metal against corrosion Product name X-12-1214A (Especially for copper, Parameter Viscosity at 25℃ mm2/s 170 N N silver and aluminum) R 100 Active ingredient % (MeO)3Si N TSCA Not Listed
(Not specified values)
●Anti Rust Treatment on Copper plates
*BT: benzotriazole
29 Surface Modifiers for Pigments & Fillers Alkoxy Silanes & Silane Coupling Agents
Silanes and silane coupling agents can be used as surface treatments for pigments and fillers to improve their compatibility with resins and improve adhesion.
Product List
Product category Functional group Product name Chemical structure Features TSCA
KBM-1003 (MeO)3 Si Vinyl silane, standard product Listed Alkenyl KBM-1083 (MeO)3 Si Long-chain spacer type of KBM-1003 Listed O KBM-403 (MeO)3 Si O Epoxy silane, standard product Listed Epoxy O Not KBM-4803 (MeO)3 Si O Long-chain spacer type of KBM-403 Listed
(MeO) Si O Silane coupling agents KBM-503 3 Methacrylic silane, standard product Listed O Methacrylic O Not KBM-5803 (MeO)3 Si Long-chain spacer type of KBM-503 Listed O H KBM-603 (MeO)3 Si N NH2 Diamino silane Listed
Amine KBE-903 (EtO)3 Si NH2 Monoamino silane Listed
H Not KBM-6803 (MeO)3 Si N NH2 Long-chain spacer type of KBM-603 Listed
KBE-3063 (EtO)3 Si Long chain alkyl (C6), ethoxy type Listed
KBM-3063 (MeO)3 Si Long chain alkyl (C6), methoxy type Listed Alkyl Alkoxy silanes KBE-3083 (EtO)3 Si Long chain alkyl (C8), ethoxy type Listed
KBM-3103C (MeO)3 Si Long chain alkyl (C10), methoxy type Listed Pigments & Fillers Surface Modifiers for CF Fluoroalkyl KBM-7103 (MeO)3 Si 3 Fluorinated silane. Water repellency, oil repellency Listed
Fractured Composite Resin Compounded with Spherical Silica Surface Treatment of Organic Filler with Long-chain Spacer Silane Coupling Agents ●Evaluation of Inorganic Filler Dispersion KBM-503 Product name KBM-5803* (Conventional silane)
Appearance
●Silica Treated with KBM-503. ●Untreated Silica Base Resin is Unsaturated Polyester. *Left: KBM-5803 by improving dispersibility, transparency was improved. Formulation Silane treated silica 10wt% Model of Surface Hydrophobization Using Silanes Multifunctional acrylic compounds 90wt%
●Conceptual Diagram of Dropper Silica Surface Treated with KBM-3103C
Hydrophobic layer ●Enlarged Photo of Waterdrop OH C10H21 Waterdrop OH OH C10H21 C10H21 O Si O Contact angle Waterdrop Si O Si Treated SiO2 Waterdrop SiO2 MeO O O OMe Hydrophobic treatment SiO2
Glass slide
A treated silica filler is applied to a glass slide in the manner shown above, then the water contact angle is measured.
30 Surface Modifiers Surface Modifiers for for Pigments & Fillers Pigments & Fillers Spherical Silica Fine Particles
Spherical Silica Fine Particles are extremely small and have a narrow particle size distribution. Particle surfaces have been treated to be extra hydrophobic. The particles thus have excellent dispersibility, water repellency, lubricity, flow properties, and can be added to other powders, in a dry process, to improve those powder's performance. Spherical Silica Fine Particles can be used with organic pigments and fillers as well as inorganic ones.
Improved Flowability of Glass Frits
1,600 Glass frit only 1,400 QSG-100 added 1,200
1,000 QSG-30 added
800
600
Total Energy (mJ) Energy Total 400
200
0 1 2 3 4 5 6 7 8 9 10 11 Test Number 100 100 100 100 100 100 100 100 70 40 10 Tip Speed (mm/s)
Stability Test Flow Rate Test
●QSG-100
Product List Product name Parameter QSG-100 QSG-80 QSG-30 Appearance White powder White powder White powder Pigments & Fillers Surface Modifiers for Shape Spherical Spherical Spherical Average particle size nm* 110 80 30 Bulk density g/cm3 0.44 0.44 0.46 True specific gravity 1.8 1.8 1.8
Specific surface area m2/g 25 40 143 Hydrophobicity % 67 67 67 Production method Sol-Gel TSCA Listed Listed Listed * The average particle size measured by dynamic light scattering (Laser Doppler) (Not specified values)
Particle Size Distribution of QSG-100 Adhesion on various surfaces by QSG-100
35 100
28 80
21 60
Volume (%) Volume 14 40
Under Size (%) ●Metal Silicons ●Glass Frits
7 20
0 0 0.0001 0.001 0.01 0.1 1 10
Particle size (μm)
●Surface of Nylon ●Styrene Particle
31 Silicone Division 6-1, Ohtemachi 2-chome, Chiyoda-ku Tokyo, Japan
Shin-Etsu Silicones of America, Inc. Shin-Etsu Silicone Korea Co., Ltd. 1150 Damar Drive, Akron, OH 44305, U.S.A. GT Tower 15F, 411, Seocho-daero, Seocho-gu, Seoul 06615, Korea Phone : +1-330-630-9860 Fax : +1-330-630-9855 Phone : +82-(0)2-590-2500 Fax : +82-(0)2-590-2501 Shin-Etsu do Brasil Representação de Shin-Etsu Singapore Pte. Ltd. Produtos Químicos Ltda. 4 Shenton Way, #10-03/06, SGX CentreⅡ, Singapore 068807 Rua Coronel Oscar Porto, 736 11º Andar - 114/115 Phone : +65-6743-7277 Fax : +65-6743-7477 Paraíso São Paulo - SP Brasil CEP: 04003-003 Shin-Etsu Silicones India Pvt. Ltd. Phone : +55-11-3939-0690 Fax : +55-11-3052-3904 Flat No.712, 7th Floor, 24 Ashoka Estate, Barakhamba Road Shin-Etsu Silicones Europe B. V. New Delhi 110001, India Bolderweg 32, 1332 AV, Almere, The Netherlands Phone : +91-11-43623081 Fax : +91-11-43623084 Phone : +31-(0)36-5493170 Fax : +31-(0)36-5326459 Shin-Etsu Silicones (Thailand) Ltd. Products & Servises : Fluid products 7th Floor, Harindhorn Tower, 54 North Sathorn Road, Bangkok 10500, Thailand Germany Branch Phone : +66-(0)2-632-2941 Fax : +66-(0)2-632-2945 Rheingaustrasse 190-196, 65203 Wiesbaden, Germany Shin-Etsu Silicone International Trading (Shanghai) Co., Ltd. Phone : +49-(0)611-962-5366 Fax : +49-(0)611-962-9266 29F Junyao International Plaza, No.789, Zhao Jia Bang Road, Shanghai 200032, China Products & Servises : Elastomer products Phone : +86-(0)21-6443-5550 Fax : +86-(0)21-6443-5868 Shin-Etsu Silicone Taiwan Co., Ltd. Guangzhou Branch Hung Kuo Bldg. 11F-D, No. 167, Tun Hua N. Rd., B-2409, 2410, Shine Plaza, 9 Linhexi Road, Tianhe, Guangzhou, Taipei, 10549 Taiwan, R.O.C. Guangdong 510610, China Phone : +886-(0)2-2715-0055 Fax : +886-(0)2-2715-0066 Phone : +86-(0)20-3831-0212 Fax : +86-(0)20-3831-0207
●The data and information presented in this catalog may not be relied upon to represent standard values. Shin-Etsu reserves the right to change such data and information, in whole or in part, in this catalog, including product performance standards and specifications without notice. ●Users are solely responsible for making preliminary tests to determine the suitability of products for their intended use. Statements concerning possible or suggested uses made herein may not be relied upon, or be construed, as a guaranty of no patent infringement. ●The silicone products described herein have been designed, manufactured and developed solely for general industrial use only; such silicone products are not designed for, intended for use as, or suitable for, medical, surgical or other particular purposes. Users have the sole responsibility and obligation to determine the The Development and Manufacture of Shin-Etsu Silicones suitability of the silicone products described herein for any application, to make preliminary tests, and to confirm the safety of such products for their use. are based on the following registered international quality and environmental management standards. ●Users must never use the silicone products described herein for the purpose of implantation into the human body and/or injection into humans. Gunma Complex ●Users are solely responsible for exporting or importing the silicone products described ISO 9001 ISO 14001 herein, and complying with all applicable laws, regulations, and rules relating to the (JCQA-0004 JCQA-E-0002) use of such products. Shin-Etsu recommends checking each pertinent country's Naoetsu Plant ISO 9001 ISO 14001 laws, regulations, and rules in advance, when exporting or importing, and before (JCQA-0018 JCQA-E-0064) using the products. Takefu Plant ISO 9001 ISO 14001 ●Please contact Shin-Etsu before reproducing any part of this catalog Copyright (JQA-0479 JQA-EM0298) belongs to Shin-Etsu Chemical Co., Ltd.
“Shin-Etsu Silicone“ is a registerd trademark of Shin-Etsu Chemical Co., Ltd. http://www.shinetsusilicone-global.com/
This is an edited version of the product data released on Aug. 2017. Shin-Etsu 2016.3/2017.8②2.M.G.Printed in Japan