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Project details

 Synthetic Organic Chemicals 5(f)

 For Terms of Reference [ToR]

 New Project

1. Basic Information of the Project: i Name & Address of the Project site M/s. Delta Finochem Pvt. Ltd. (Complete details with plot no./Survey no., Plot No. C-192, Saykha Industrial Landmark etc. ) Estate, Survey No. 276/P,277/P, Village Saykha, Tal- Vagra, Dist Bharuch. ii Name of the Applicant Sandeep Deshmukh (Director)

iii Address for correspondence Plot No. 121, MIDC Satpur, Behind Sakal Press Nashik -422007, Maharastra iv Contact no. and e-mail ID of the Applicant Mo. no.: +91 9823079831

e-Mail: [email protected]

v Aerial distance of nearest Habitat (KM) Saykha Village: 2.70 km in NW Name of village direction

vi Longitude & Latitude of the Project Site: (4 corners of the site) 21°46'2.81"N 72°49'39.95"E 21°46'3.70"N 72°49'39.89"E 21°46'3.73"N 72°49'39.38"E 21°46'11.53"N 72°49'39.46"E 21°46'11.56"N 72°49'43.24"E 21°46'4.01"N 72°49'43.17"E 21°46'3.96"N 72°49'42.39"E 21°46'2.82"N 72°49'42.38"E

vii Category as per the Schedule to the EIA 5 (f) Synthetic Organic Chemicals Notification 2006 i.e. 1(d), 2(b), 5(f) etc.

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Sub-Category: B1 viii Applicability of General Conditions of EIA Notification 2006: i.e. Ensure that (1) Protected areas notified under the (1) No Wildlife (Protection) Act, 1972; (2) CEPI areas (2) No (3) Eco-sensitive areas and (3) No (4) Inter-state boundaries and (4) No international boundaries; are not located within 5 km or 10 km (as the case may be) area from the boundary of the proposed site. Note: If located in Vapi-Sarigam region, kindly give exact aerial distance from the interstate boundary i.e. Boundary with Maharashtra state & U.T. of Daman, Diu and Dadra Nagar Haveli. viii In case of unit located outside the Notified Not Applicable area: Complying the three conditions as per the amendment to EIA Notification, 2006 vide SO 1599 (E) dated 25/06/2014.

[i.e. water consumption less than 25 M3/day; Fuel consumption less than 25 TPD; and not covered in the category of MAH units as per the Management, Storage, Import of Hazardous Chemical Rules (MSIHC Rules), 1989] (Storage details of all the hazardous chemicals shall be submitted in tabular form for justification.)

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2. Online application & PH reg. : a) Online application proposal no.: SIA/GJ/IND2/XXXXX/XXXX

b) Date of online acceptance for ToR by - SEAC: c) Date of presentation for ToR: -

3. Product profile: Sr. CAS no. / Quantity Name Of Product End-Use of Products No. CI no. (MT/Month) Group A Quaternary Compound Tetra Butyl Ammonium 1. 1643-19-2 (pharma, dyes, Bromide chemical industries) Quaternary Compound Tetra Butyl Ammonium 2. 32503-27-8 (pharma, dyes, Hydrogen Sulphate chemical industries) Quaternary Compound Tetra Butyl Ammonium 3. 311-28-4 (pharma, dyes, Iodide chemical industries) Quaternary Compound Ethyl Triphenyl 4. 1530-32-1 (pharma, dyes, Phosphonium Iodide chemical industries) Quaternary Compound Tetra Ethyl Ammonium 5. 71-91-0 (pharma, dyes, Bromide chemical industries) Quaternary Compound Tetrabutyl Ammonium 6. 3109-63-5 (pharma, dyes, Hexafluoro Phosphate chemical industries) 1250 Quaternary Compound Tetrapropyl Ammonium 7. 1941-30-6 (pharma, dyes, Bromide chemical industries) Tetra Butyl Ammonium Quaternary Compound 8. Bromide Solution In Water 1643-19-2 (pharma, dyes, 50% chemical industries) Quaternary Compound Ethyl Triphenyl 9. 1530-32-1 (pharma, dyes, Phosphonium Bromide chemical industries) Quaternary Compound Tetraphenyl Phosphonium 10. 2751-90-8 (pharma, dyes, Bromide chemical industries) Quaternary Compound Methyl Triphenyl 11. 1779-49-3 (pharma, dyes, Phosphonium Bromide chemical industries) Quaternary Compound Phenyl Trimethyl 12. 16056-11-4 (pharma, dyes, Ammonium Bromide chemical industries) 13. Phenyl Trimethyl 4207-56-1 Quaternary Compound

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Ammonium Tribromide (pharma, dyes, chemical industries) Quaternary Compound Tetrabutyl Ammonium 14. 38932-80-8 (pharma, dyes, Tribromide chemical industries) Tetra Butyl Ammonium Quaternary Compound 15. Hydrogen Sulphate 55% 32503-27-8 (pharma, dyes, Solution I Water chemical industries) Quaternary Compound Methyl Triphenyl 16. 2065-66-9 (pharma, dyes, Phosphonium Iodide chemical industries) Quaternary Compound Butyl Triphenyl 17. 13371-17-0 (pharma, dyes, Phosphonium Chloride chemical industries) Quaternary Compound Benzyl Triphenyl 18. 1100-88-5 (pharma, dyes, Phosphonium Chloride chemical industries) Quaternary Compound Tetra Methyl Ammonium 19. 75-57-0 (pharma, dyes, Chloride chemical industries) Quaternary Compound Tetra Ethyl Ammonium 20. 56-34-8 (pharma, dyes, Chloride chemical industries) Quaternary Compound Tetraethylammonium 21. 429-06-1 (pharma, dyes, Tetrafluoroborate chemical industries) Quaternary Compound Methyl Trioctyl Ammonium 22. 63393-96-4 (pharma, dyes, Chloride chemical industries) Quaternary Compound Methyl Tributyl Ammonium 23. 56375-79-2 (pharma, dyes, Chloride chemical industries) Group B Bromide ( pharma, 24. N-Hexyl Bromide 111-25-1 dyes Industries) Alpha Bromo 2 Bromide ( pharma, 25. 29270-30-2 Chlorophenyl Acetic Acid dyes Industries) Methyl Alpha-Bromo-2- Bromide ( pharma, 26. 85259-19-4 Chlorophenyl Acetate dyes Industries) Bromide ( pharma, 27. 4 Bromo Anisole 104-92-7 dyes Industries) Bromide ( pharma, 28. Decyl Bromide 112-29-8 dyes Industries) 1000 Bromide ( pharma, 29. 1 4 Dibromobutane 110-52-1 dyes Industries) Bromo Acetaldehyde Bromide ( pharma, 30. 7252-83-7 Dimethyl Acetal (Badima) dyes Industries) Bromoacetaldehyde Diethyl Bromide ( pharma, 31. 2032-35-1 Acetal dyes Industries) Bromide ( pharma, 32. 3 Bromo Acetophenone 2142-63-4 dyes Industries) Bromide ( pharma, 33. Bromo Trichloro Benzene 21928-51-8 dyes Industries) 34. Chloroacetaldehyde 97-97-2 Bromide ( pharma,

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Dimethyl Acetal dyes Industries) 2-Chloromethyl-1,3- Bromide ( pharma, 35. 2568-30-1 Dioxolane dyes Industries) Bromide ( pharma, 36. 4 Bromo Benzaldehyde 1122-91-4 dyes Industries) Bromide ( pharma, 37. N-Propyl Bromide 106-94-5 dyes Industries) Bromide ( pharma, 38. N-Butyl Bromide 109-65-9 dyes Industries) Bromide ( pharma, 39. Cyclopentyl Bromide 137-43-9 dyes Industries) Bromide ( pharma, 40. N- Pentyl Bromide 110-53-2 dyes Industries) Bromide ( pharma, 41. N- Cetyl Bromide 57-09-0 dyes Industries) Bromide ( pharma, 42. Isobutyl Bromide 78-77-3 dyes Industries) Bromide ( pharma, 43. 1 Bromo 5 Chloro Pentane 54512-75-3 dyes Industries) Group C Intermediate ( pharma 44. 2 Amino Diphenyl Sulfide 1134-94-7 industries) Intermediate ( pharma 45. Keta Stage 4 03159-07-7 industries) Intermediate ( pharma 46. Amino Propanediol 61278-21-5 industries) Tri Ethyl Phosphono Intermediate ( pharma 47. 867-13-0 Acetate industries) Tri Methyl Phosphono Intermediate ( pharma 48. 5927-18-4 Acetate industries) Dimethyl Amino Isopropyl Intermediate ( pharma 49. 4584-49-0 Chloride Hydrochloride industries) Intermediate ( pharma 50. Thioanisole 100-68-5 industries) Intermediate ( pharma 51. Phenetole 103-73-1 industries) Intermediate ( pharma 52. Net Acid 42017-89-0 550 industries) Intermediate ( pharma 53. Flavone Acid 525-82-6 industries) LSP Amine (S)-2- Intermediate ( pharma 54. (Aminomethyl)-1- 22795-99-9 industries) ethylpyrrolidine Intermediate ( pharma 55. Anisole 100-66-3 industries) Dimethylamine Ethyline Intermediate ( pharma 56. 42751-79-1 Diamine industries) Intermediate ( pharma 57. Methoxy Hydroxylamine Hcl 593-56-6 industries) 2-(Furan-2-Yl)-2-(Syn- Intermediate ( pharma 58. 39684-61-2 Methoxyimino) Acetic Acid industries) Intermediate ( pharma 59. Dihydroxy Dithiane 40018-26-6 industries) 60. Orotic Acid 50887-69-9 Intermediate ( pharma

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industries) Intermediate ( pharma 61. 2 Amino Benzyl Alcohol 5344-90-1 industries) 1 Amino 4 Cyclopentyl Intermediate ( pharma 62. 61379-64-4 Piperazine industries) Total 2800 Note:  Unit will manufacture any of the products from Group A on either/or basis and total production capacity of Group A shall not exceed 1250 MT/Month.  Unit will manufacture any of the products from Group B on either/or basis and total production capacity of Group B shall not exceed 1000 MT / Month.  Unit will manufacture any of the products from Group C on either/or basis and total production capacity of Group C shall not exceed 550 MT / Month.  Products from Group A, B and C will be manufacture at same time, Therefore, total production capacity shall not exceed 2800 MT /month

The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006.

4. Product wise Raw materials consumption: Sr. Name Of The Products Name of the Raw CAS / CI no. of Quantity no. Materials raw materials. MT/Month 1. Tetra Butyl Ammonium Tri-N Butyl Amine 102-82-9 781.25 Bromide N-Butyl BROMIDE 164365-88-2 586.00 Acetonitrile 75-05-8 293.00 Ethyl Acetate 141-78-6 586.00 2. Tetra Butyl Ammonium Tetra Butyl Ammonium 1643-19-2 1389.00 Hydrogen Sulphate Bromide Sulfuric Acid 7664-93-9 463.00 Methyl Isobutyl Keton 108-10-1 1389.00 3. Tetra Butyl Ammonium Tri-N Butyl Amine 102-82-9 672.25 Iodide N-Butyl Iodide 542-69-8 690.50 Acetonitrile 75-05-8 872.10 Ethyl Acetate 141-78-6 1453.50 4. Ethyl Triphenyl Triphenylphosphine 603-35-0 844.60 Phosphonium Iodide Ethyl Iodide 75-03-6 507.00 Acetonitrile 75-05-8 563.10 Methanol 67-56-1 563.10 5. Tetra Ethyl Ammonium Tri-N EthylAmine 121-44-8 658.00 Bromide Ethyl Bromide 74-96-4 781.25 Acetonitrile 75-05-8 247.00 Ethyl Acetate 141-78-6 559.25 6. Tetrabutyl Ammonium Tetra Butyl Ammonium 1643-19-2 1157.50 Hexafluoro Phosphate Bromide Caustic Soda 1310-73-2 185.20 Hexafluorophosphoric 16940-81-1 338.00

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acid 7. Tetrapropyl Ammonium Tri-N Propyl Amine 102-69-2 767.00 Bromide N-Propyl Bromide 106-94-5 724.70 Acetonitrile 75-05-8 345.00 Ethyl Acetate 141-78-6 652.00 8. Tetra Butyl Ammonium Tetra Butyl Ammonium 1643-19-2 Bromide Solution In 625.00 Bromide Water 50% 9. Ethyl Triphenyl Triphenylphosphine 603-35-0 937.50 Phosphonium Bromide Ethyl Bromide 74-96-4 393.75 Acetonitrile 75-05-8 393.75 Methanol 67-56-1 625.00 10. Tetraphenyl Triphenylphosphine 603-35-0 641.00 Phosphonium Bromide Bromobenzene 108-86-1 609.00 Acetonitrile 75-05-8 769.25 Methanol 67-56-1 769.25 11. Methyl Triphenyl Triphenylphosphine 603-35-0 987.00 Phosphonium Bromide Methyl Bromide 74-83-9 395.00 Acetonitrile 75-05-8 789.50 Methanol 67-56-1 789.50 12. Phenyl Trimethyl Di Methyl Aniline 121-69-7 760.00 Ammonium Bromide Methyl Bromide 74-83-9 615.50 Acetonitrile 75-05-8 494.00 Methanol 67-56-1 456.00 13. Phenyl Trimethyl phenyl Trimethyl 4207-56-1 757.60 Ammonium Tribromide ammonium bromide Bromine 7726-95-6 560.60 Methanol 67-56-1 454.55 Acetic Acid 64-19-7 379.00 14. Tetrabutyl Ammonium Tetrabutyl Ammonium 1643-19-2 880.30 Tribromide Bromide Bromine 7726-95-6 435.80 Methanol 67-56-1 528.20 Acetic Acid 64-19-7 528.20 15. Tetra Butyl Ammonium Tetra Butyl Ammonium 32503-27-8 687.00 Hydrogen Sulphate Hydrogen Sulphate 16. Methyl Triphenyl Triphenylphosphine 603-35-0 951.80 Phosphonium Iodide Methyl Iodide 74-88-4 539.50 Acetonitrile 75-05-8 761.50 Methanol 67-56-1 761.50 17. Butyl Triphenyl Triphenylphosphine 603-35-0 1250.00 Phosphonium Chloride Butyl Chloride 507-20-0 487.50 Acetonitrile 75-05-8 1000.00 Methanol 67-56-1 1000.00 18. Benzyl Triphenyl Triphenylphosphine 603-35-0 893.00 Phosphonium Chloride Benzyl Chloride 100-44-7 446.50

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Acetonitrile 75-05-8 714.30 Methanol 67-56-1 654.80 19. Tetra Methyl Ammonium Tri Methyl Amine 75-50-3 735.30 Chloride Methyl Chloride 74-87-3 691.20 Acetonitrile 75-05-8 441.20 Ethyl Acetate 141-78-6 441.20 20. Tetra Ethyl Ammonium Tri Ethyl Amine 121-44-8 847.50 Chloride Ethyl Chloride 65039-09-0 567.80 Acetonitrile 75-05-8 508.50 Ethyl Acetate 141-78-6 508.50 21. Tetraethylammonium Tetra Ethyl Ammonium 56-34-8 1059.30 Tetrafluoroborate Chloride Potassium Hydroxide 1310-58-3 360.20 Tetrafluoroboric Acid 16872-11-0 572.10 22. Methyl Trioctyl Tri Octyl Amine 1116-76-3 1213.60 Ammonium Chloride Methyl Chloride 74-87-3 182.00 Acetonitrile 75-05-8 728.20 Ethyl Acetate 141-78-6 728.20 23. Methyl Tributyl Tri Butyl Amine 102-82-9 757.50 Ammonium Chloride Methyl Chloride 74-87-3 219.70 Acetonitrile 75-05-8 454.55 Ethyl Acetate 141-78-6 454.55 24. N-Hexyl Bromide N- Hexanol 111-27-3 686.80 Bromine 7726-95-6 549.50 Sulphur 7704-34-9 38.50 Sulfuric Acid 7664-93-9 55.00 25. Alpha Bromo 2 Ortho Chloro Phenyl 2444-36-2 759.50 Chlorophenyl Acetic Acid Acetic Acid Bromine 7726-95-6 936.75 Toluene 108-88-3 1012.70 26. Methyl Alpha-Bromo-2- Alpha Bromo 2 141109-25-3 1025.65 Chlorophenyl Acetate Chlorophenyl Acetic Acid Methanol 67-56-1 307.70 Sulfuric Acid 7664-93-9 359.00 Methylene Dichloride 75-09-2 769.25 27. 4 Bromo Anisole Phenol 108-95-2 696.30 Bromine 7726-95-6 1185.20 Dimethyl Sulphate 77-78-1 822.20 Caustic Soda 1310-73-2 259.30 28. Decyl Bromide N- Decanol 112-30-1 796.20 Bromine 7726-95-6 414.00 Red Phosphorus 7723-14-0 32.50 29. 1 4 Dibromobutane 1,4-Butanediol 110-63-4 463.00 Bromine 7726-95-6 833.40 Red Phosphorus 7723-14-0 106.50 30. Bromo Acetaldehyde Vinyl Acetate Monomer 108-05-4 701.75

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Dimethyl Acetal (Badima) Bromine 7726-95-6 1368.50 Methanol 67-56-1 877.20 Methylene Dichloride 75-09-2 1228.00 31. Bromoacetaldehyde Vinyl Acetate Monomer 108-05-4 601.50 Diethyl Acetal (Badiea) Bromine 7726-95-6 1173.00 Ethanol 64-17-5 1082.70 Methylene Dichloride 75-09-2 1052.65 32. 3 Bromo Acetophenone 3 Amino Acetophenone 99-03-6 851.00 Sodium Nitrite 7632-00-0 532.00 HBr 48% 10035-10-6 1489.40 Methanol 67-56-1 638.30 33. Bromo Trichloro Benzene 2,6 Dichloro aniline 608-31-1 1428.60 Bromine 7726-95-6 1428.60 Sodium Nitrite 7632-00-0 714.30 HCL 7647-01-0 2381.00 Methanol 67-56-1 1143.00 34. Chloroacetaldehyde Vinyl Acetate Monomer 108-05-4 952.40 Dimethyl Acetal Chlorine 7782-50-5 833.35 Methanol 67-56-1 1190.50 Methylene Dichloride 75-09-2 1666.70 35. 2-Chloromethyl-1,3- Chloroacetaldehyde 97-97-2 1142.80 Dioxolane Dimethyl Acetal Methylene Glycol 107-21-1 600.00 Cyclohexane 110-82-7 1143.00 36. 4 Bromo Benzaldehyde 4 Bromo Toluene 106-38-7 1142.00 Bromine 7726-95-6 1857.20 Hexamine 100-97-0 1428.60 HCL 7647-01-0 1857.20 Methanol 67-56-1 1000.00 37. N-Propyl Bromide N- Propanol 71-23-8 542.50 Bromine 7726-95-6 738.00 Sulphur 7704-34-9 51.70 Sulfuric Acid 7664-93-9 73.80 38. N-Butyl Bromide N- Butanol 1-36-3 593.45 Bromine 7726-95-6 655.80 Sulphur 7704-34-9 45.90 Sulfuric Acid 7664-93-9 65.60 39. Cyclopentyl Bromide Cyclopentanol 96-41-3 628.75 Bromine 7726-95-6 598.80 Sulphur 7704-34-9 42.00 Sulfuric Acid 7664-93-9 60.00 40. N- Pentyl Bromide Pentanol 634.20 Bromine 7726-95-6 590.00 Sulphur 7704-34-9 41.30 Sulfuric Acid 7664-93-9 59.00 41. N- Cetyl Bromide Cetyl alcohol 36653-82-4 593.45

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Bromine 7726-95-6 655.75 Sulphur 7704-34-9 45.90 Sulfuric Acid 7664-93-9 65.60 42. Isobutyl Bromide Iso Butanol 78-83-1 593.45 Bromine 7726-95-6 655.75 Sulphur 7704-34-9 45.90 Sulfuric Acid 7664-93-9 65.60 43. 1 Bromo 5 Chloro Dichloropentane 628-76-2 509.00 Pentane Dibromopentane 111-24-0 836.40 Dimethylformamide 68-12-2 109.00 44. 2 Amino Diphenyl Sulfide Ortho Nitro Chloro 88-73-3 489.00 Benzene Thiophenol 108-98-5 326.00 Caustic Soda. 1310-73-2 130.40 Methanol 67-56-1 489.00 Hydrogen 1333-74-0 19.60 Raney Nickel 7440-02-0 19.60 45. Keta Stage 4 2 amino Diphenyl Sulfide 1134-94-7 628.60 Phenyl ChloroFormate 1885-14-9 503.00 Polyphosphoric acid 8017-16-1 2750.00 Methanol 67-56-1 1257.20 Toluene 108-88-3 1571.45 Palladium 7440-05-3 314.30 46. Amino Propanediol Chloropropanediol 96-24-2 743.25 Liquid Ammonia 7664-41-7 857.00 47. Tri Ethyl Phosphono Tri Ethyl Phosphite 122-52-1 458.45 Acetate Ethyl Chloro Acetate 105-39-5 366.70 48. Tri Methyl Phosphono Tri Methyl Phosphite 594-09-2 424.00 Acetate Methyl Chloro Acetate 96-34-4 381.00 49. Dimethyl Amino Isopropyl Dimethyl Amino 108-01-0 392.80 Chloride Hydrochloride Isopropanol Thionyl Chloride 07719-09-07 499.00 Caustic Soda Solution 1310-73-2 785.70 20% 50. Thioanisole Thiophenol 108-98-5 540.20 Dimethyl Sulphate 77-78-1 687.50 Caustic Soda 1310-73-2 216.00 51. Phenetole Phenol 108-95-2 458.35 Diethyl Sulphate 64-67-5 825.00 Caustic Soda 1310-73-2 215.45 52. Net Acid Ketone 201-159-0 470.80 Acetone 67-64-1 256.80 Caustic Soda 1310-73-2 107.00 Chloroform 67-66-3 256.80 HCl 7647-01-0 256.80 53. Flavone Acid Methyl Salicylate 119-36-8 482.50

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Bromine 7726-95-6 530.70 Methylene Dichloride 75-09-2 868.45 Propionyl Chloride 79-03-8 289.50 Aluminium Chloride 7446-70-0 723.70 Hydrogen 1333-74-0 4.85 Benzyl Chloride 100-44-7 313.60 Raney Nickel 7440-02-0 106.80 54. LSP Amine N Ethyl Pyrrolidone 2687-91-4 1406.65 Dimethyl Sulphate 77-78-1 1575.45 Nitromethane 75-52-5 773.70 Caustic Soda 1310-73-2 998.75 Methanol 67-56-1 1406.65 Catalyst 35.20 L Tartaric Acid 87-69-4 1547.35 55. Anisole Phenol 108-95-2 504.60 Dimethyl Sulphate 77-78-1 742.75 Caustic Soda 1310-73-2 237.20 56. Dimethylamine Ethyline DMA Ethanol 108-01-0 670.75 Diamine Liquid Ammonia 7664-41-7 670.75 Hydrogen 1333-74-0 15.45 Palladium 7440-05-3 5.40 57. Methoxy Hydroxylamine Hydroxyl Amine 5470-11-1 589.30 HCL Hydrochloride Sodium Methoxide 124-41-4 943.00 Methyl chloride 74-87-3 432.20 Methanol 67-56-1 943.00 HCL Gas 7647-01-0 275.00 58. 2-(Furan-2-Yl)-2-(Syn- Furan 10-00-9 331.35 Methoxyimino) Acetic Acetic Anhydride 108-24-7 546.70 Acid Aluminum chloride 7446-70-0 994.00 Methylene Dichloride 75-09-2 1159.70 Sodium Nitrite 7632-00-0 447.30 HCL Aq 7647-01-0 497.00 MHA HCL 7647-01-0 258.50 Acetone 67-64-1 397.60 Caustic Solution 40% In 1310-73-2 314.80 Water 59. Dihydroxy Dithiane Vinyl Acetate Monomer 108-05-4 814.80 Chlorine 7782-50-5 672.25 Methanol 67-56-1 489.00 Sulfite Solution 12135-76-1 1751.85 60. Orotic Acid Glycolic acid 50% 79-14-1 550.00 Solution In Water Hydantoin 6440-58-0 605.00 Coustic Soda 1310-73-2 330.00 Hydrochloric Acid 30% 7647-01-0 935.00

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Solution 61. 2 Amino Benzyl Alcohol O-Nitrobenzaldehyde 552-89-6 714.30 Hydrogen 1333-74-0 43.00 Catalyst Pd 7440053 14.30 Methanol 67-56-1 2143.00 62. 1 Amino 4 Cyclopentyl cyclopentanone 96-41-3 369.20 Piperazine Piperazine 110-85-0 387.60 Hydrogen 1333-74-0 9.25 Catalyst Pd 7440053 20.40 Methanol 67-56-1 590.65 Sodium Nitrite 7632-00-0 265.80 Hydrogen 1333-74-0 24.00

5. Salient features of the project including Water, Air and Hazardous waste management: Sr. Particulars Details no. A A Total cost of Proposed Project 22.43 Crores (Rs. in Crores):

B Total Plot area ( sq. meter) 28146.66 Sq. m.

Green belt area 6320 Sq. m. ( sq. meter) C Employment generation 132

D Water i Source of Water Supply GIDC, Saykha

(GIDC Bore well, Surface water, Tanker supply etc...)

Status of permission from the concern authority.

ii Water consumption (KLD) Category Quantity Remarks KLD

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(A) Domestic 6.00 (B) Gardening 25.30 (C) Industrial

Process Considering Maximum process water consumption and waste water generation take place in product no. 2 (i.e. Tetra Butyl 263* Ammonium Hydrogen Sulphate), product no. 27 (4 Bromo Anisole) & product no. 53 (Flavone Acid)

Washing 10.0 Boiler 72 Cooling 15.0 Others 10.0

370 Industrial Total

Total (A + B + C) 401.30

1) Total water requirement for the project: 401.30 KLD 2) Quantity to be recycled: 0.0 KLD 3) Total fresh water requirement: 401.30 KLD

iii Waste water generation (KLD) Category Waste water Remarks KLD (A) Domestic 5.00 (B) Industrial

Process 308.0** Washing 10.0 Boiler 3.6 Cooling 0.80 Others 10.0

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Total Industrial 332.40 waste water

Total [A + B] 337.40 - iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc.  Primary ETP (340 KLD)  MEE ( 15 KL/Hr) Treatment scheme including segregation at source.  Not Applicable Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP.  Industrial effluent generated from proposed manufacturing process and other ancillary operation shall be allowed into in-house ETP for primary treatment. Primary treated water will be sent to CETP, Saykha for further treatment and final disposal.

Brief note on adequacy of ZLD (In case of Zero Liquid Discharge):  Not Applicable v Mode of Disposal & Final meeting point

Domestic: Domestic effluent shall be disposed in to Septic tank / Soak pit system. Industrial: Industrial effluent generated from proposed manufacturing process and other ancillary operation shall be allowed into in-house ETP for primary treatment. Primary treated water will be sent to CETP, Saykha for further treatment and final disposal. vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF  CETP, Saykha Membership of Common facility (CF) (For waste water treatment) Applied for Membership of CETP- Saykha vii Simplified water balance diagram with reuse / recycle of waste water

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viii Reuse/Recycle details (KLD) Total reuse – 0 KLD Source of waste Application Characteristics of Remarks water for reuse area with waste water to be regarding with quantity in quantity in reused (COD, BOD, feasibility KLD (From KLD (Where it TDS etc.) to reuse i.e. where it is is used) coming) ------

E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc.

- Source of Type of Air Pollution Stack Type Quantity Sr. emission emissions Control Height of of Fuel no. With i.e. Air Measures (meter) Fuel MT/Day Capacity Pollutants (APCM) Steam Boiler PM Adequate stack Natural 4800 1 (Capacity 3 12.0 m height will be Gas SCM/Day SO2 TPH) NOx provided

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Thermopack PM Adequate stack 12.0 m Natural 2900 2 (Capacity 2 height will be Gas SCM/day SO2 Lac Kcal/Hr.) NOx provided D.G Set PM Adequate stack (Stand By) 5.0 m 3600 3 HSD height will be (Capacity Lit/day SO2 provided 550 KVA) NOx D.G Set PM Adequate stack (Stand By) 5.0 m 1632 4 HSD height will be (Capacity Lit/day SO2 provided 250 KVA) NOx - ii Process gas emission details i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.)

-

Specific Source of emission Stack/Vent Air Pollution Sr. Type of Control (Name of the Product & Height no. emission Measures Process) (meter) (APCM) Process Vent – 1 Alkali Scrubber Br2, 1 (Product No. 13, 14, 24, 25, 27 8.0 m & Water to 31, 33, 36 to 42, 53 & HBR Scrubber Process – Bromination)

Process Vent – 2 Cl2, Alkali Scrubber 2 8.0 m & Water (Product No. 34, 57, 59, & HCL Scrubber Process – Chlorination) - iii Fugitive emission details with its mitigation measures: As below: - Sources of fugitive emissions will be from raw material storage area, handling of chemicals, manufacturing process and from vehicle movement on internal road. - To minimize fugitive emission, powder material will be allowed in a vessel through closed loop while liquid material will be charged through pipeline. - Transportation of raw materials & products will be carried out by trolley within premises and minimum manual material handling will be carried, so the fugitive emission due to process activity and material handling will be negligible.

F Hazardous wastes (as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. i Sr. Type / Specific Category Quantity Management of HW

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No. Name of Source of & (MT/ Hazardous generation Schedule Annum) waste (Name of as per the HW Activity, Rules. Product etc.) Collection, Storage, Effluent 35.3 435 Transportation and 1. ETP Sludge Treatment (Sch. I) MT/year Disposal at TSDF site – Plant for secured landfill Collection, Storage, Used / 5.1 3.0 Transportation & sent 2. D. G Set Spent Oil (Sch. I) MT/year to registered recycler / reused for lubrication Raw Collection, Storage, Discarded material & Transportation & Containers / Finished 33.1 350 3. reused / sell to GPCB Bags / product (Sch. I) MT/year approved scraps Liners packing vendor material Collection, Storage, Transportation and Distillation Distillation 20.3 3112.30 4. Disposal for Residue Process (Sch. I) MT/year incineration OR for co- processing as per CV. Process Collection, Storage, Product Transportation and Process No. 28, 29, 28.1 1131 5. Disposal for Residue 37 to 42, MT/Year (Sch. I) incineration OR for co- 46 to 48, processing as per CV. 50, 51, 55 Process Product no. 1 to 5, 7, 9 to 14, Collection, Storage, In- 16 to 20, Spent 28.6 96615.20 house recovery / 6. 22, 23, 25, Solvent (Sch. I) MT/year Distillation & reuse in 26, 30to process 36, 43 to 45, 53, 54, 57 to 59, 61, 62 Process Collection, Storage, Product Transportation and sent Spent 28.2 422 7. no. 44, 53, to registered Catalyst (Sch I) MT/year 54, 56, 61, regenerator under 62 Rule-9 permission Sodium By Product Collection, Storage, 28.1 10000 8. Bromide of Product Transportation & MT/year Soln no. 6, (Sch. I) Disposal by sell out to

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authorized users who are having authorization with valid CCA and rule 9 permission to receive this waste Collection, Storage, Transportation & Process Disposal by sell out to Hydrogen Product authorized users who 28.1 98476 9. Bromide no. 2, 25, are having (Sch. I) MT/year Soln 27, 30, 31, authorization with valid 33, 36, 53, CCA and rule 9 permission to receive this waste Max. quantity 66 % (9864 MT/year) will be reuse & remaining Process 28.1 quantity will be sell out Product 14954 to authorized users who 10. Sulfuric Acid no. 24, 26, (Sch. I) MT/year are having 37 to 42 authorization with valid CCA and rule 9 permission to receive this waste Collection, Storage, Transportation & Disposal by sell out to Process Aqueous authorized users who Product 28.1 43421.60 11. Phosphoric are having no. 28, 29, (Sch. I) MT/year Acid authorization with valid 45, CCA and rule 9 permission to receive this waste Collection, Storage, Transportation & Disposal by sell out to Process authorized users who Methyl 28.1 5895 12. Product are having Acetate (Sch. I) MT/year no. 30 authorization with valid CCA and rule 9 permission to receive this waste Collection, Storage & Process entire quantity (100 %) Dil. HCl 28.1 36571.50 13. Product will be reuse as raw Solution (Sch. I) MT/year no. 34, material in Process within premises. Collection, Storage & Liquor Process 28.1 6198 entire quantity (100 %) 14. Ammonia (Prod. No. (Sch. I) MT/year will be reuse as raw 56) material in Process

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within premises. Collection, Storage, By product Transportation and sold Sodium 28.1 11786 15. (Prod. No. to end user having Chloride (Sch. I) MT/year 57) permission under rule- 9. Collection, Storage & Process entire quantity (100 %) 28.1 12171.50 16. Methanol Product will be reuse as raw (Sch. I) MT/year no. 35, 57 material in Process within premises. From mfg. Off Collection, Storage, Process 28.4 56 17. Specification Transportation and sent (Batch (Sch-I) MT/Year Products for co-processing. failure) - ii Membership details of TSDF, CHWIF etc. Membership of TSDF will (For HW management) be taken. iii Details of Non-Hazardous waste & its disposal (MSW and others)

Sr. Source of Category Type of Waste Disposal No. Generation of Waste Domestic Waste Employees Collected in separate 1. (Food waste, Plastic, working in the MSW bin and disposed to bin Paper etc.) premises of GIDC. Industrial Waste Steam Pipe & Sell to local scrap 2. (Glass wool ISW [Insulating Material, Vessels vendor Scrap]) From Raw Industrial Waste Material & Sell to local scrap 3. ISW (Wooden pellets) Product vender storage area

G Solvent management, VOC emissions etc. i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format)

Product Name Of The Quantity (MT/Month) % Name Of Product No. Solvent Input Recovered Recovery 1 Tetra Butyl Ammonium Acetonitrile 292.97 289.06 98.67 Bromide Ethyl Acetate 585.94 566.41 96.67 Tetra Butyl Ammonium Methyl Isobutyl 2 1388.89 1342.59 96.67 Hydrogen Sulphate Keton 3 Tetra Butyl Ammonium Acetonitrile 872.09 853.92 97.92

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Iodide Ethyl Acetate 1453.49 1431.69 98.50 Ethyl Triphenyl Acetonitrile 563.06 546.17 97.00 4 Phosphonium Iodide Methanol 563.06 554.62 98.50 Tetra Ethyl Ammonium Acetonitrile 246.71 240.13 97.33 5 Bromide Ethyl Acetate 559.21 555.92 99.41 Tetrapropyl Ammonium Acetonitrile 345.09 339.34 98.33 7 Bromide Ethyl Acetate 651.84 648.01 99.41 Ethyl Triphenyl Acetonitrile 625.00 550.00 88.00 9 Phosphonium Bromide Methanol 625.00 606.25 97.00 Tetraphenyl Acetonitrile 769.23 743.59 96.67 10 Phosphonium Bromide Methanol 769.23 753.21 97.92 Methyl Triphenyl Acetonitrile 789.47 756.58 95.83 11 Phosphonium Bromide Methanol 789.47 769.74 97.50 Phenyl Trimethyl Acetonitrile 493.92 482.52 97.69 12 Ammonium Bromide Methanol 455.93 450.23 98.75 Phenyl Trimethyl Methanol 454.55 439.39 96.67 13 Ammonium Tribromide Acetic Acid 378.79 363.64 96.00 Tetrabutyl Ammonium Methanol 528.17 519.37 98.33 14 Tribromide Acetic Acid 528.17 510.56 96.67 Methyl Triphenyl Acetonitrile 761.42 736.04 96.67 16 Phosphonium Iodide Methanol 761.42 751.90 98.75 Butyl Triphenyl Acetonitrile 1000.00 962.50 96.25 17 Phosphonium Chloride Methanol 1000.00 975.00 97.50 Benzyl Triphenyl Acetonitrile 714.29 696.43 97.50 18 Phosphonium Chloride Methanol 654.76 642.86 98.18 Tetra Methyl Acetonitrile 441.18 422.79 95.83 19 Ammonium Chloride Ethyl Acetate 441.18 426.47 96.67 Tetra Ethyl Ammonium Acetonitrile 508.47 487.29 95.83 20 Chloride Ethyl Acetate 508.47 491.53 96.67 Methyl Trioctyl Acetonitrile 728.16 701.46 96.33 22 Ammonium Chloride Ethyl Acetate 728.16 703.88 96.67 Methyl Tributyl Acetonitrile 454.55 437.88 96.33 23 Ammonium Chloride Ethyl Acetate 454.55 439.39 96.67 Alpha Bromo 2 25 Chlorophenyl Acetic Toluene 1012.66 972.15 96.00 Acid Methylene Methyl Alpha-Bromo-2- 769.23 738.46 96.00 26 Dichloride Chlorophenyl Acetate Methanol 307.69 302.56 98.33 Bromo Acetaldehyde Methylene 30 Dimethyl Acetal 1228.07 1192.98 97.14 Dichloride (Badima) Bromoacetaldehyde Methylene 31 1052.63 1010.53 96.00 Diethyl Acetal (Badiea) Dichloride 32 3 Bromo Acetophenone Methanol 638.30 612.77 96.00 Bromo Trichloro 33 Methanol 571.43 550.00 96.25 Benzene Methylene Chloroacetaldehyde 1666.67 1600.00 96.00 34 Dichloride Dimethyl Acetal Methanol 1190.48 1142.86 96.00 2-Chloromethyl-1,3- 35 Cyclohexane 1142.86 1100.00 96.25 Dioxolane 36 4 Bromo Benzaldehyde Methanol 1000.00 985.71 98.57 1 Bromo 5 Chloro Dimethyl 43 109.09 104.73 96.00 Pentane formamide 2 Amino Diphenyl 44 Methanol 488.89 472.59 96.67 Sulfide 45 Keta Stage 4 Methanol 1257.14 1225.71 97.50

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Toluene 1571.43 1532.14 97.50 Methylene 53 Flavone Acid 868.42 834.65 96.11 Dichloride 54 LSP Amine Methanol 1406.65 1378.52 98.00 Methoxy 57 Methanol 942.86 923.21 97.92 Hydroxylamine HCL 2-(Furan-2-Yl)-2-(Syn- Methylene 1159.64 1113.25 96.00 58 Methoxyimino) Acetic Dichloride Acid Acetone 397.59 390.96 98.33 59 Dihydroxy Dithiane Methanol 488.89 478.70 97.92 61 2 Amino Benzyl Alcohol Methanol 2142.86 2071.43 96.67 1 Amino 4 Cyclopentyl 62 Methanol 590.60 573.99 97.19

Piperazine ii VOC emission sources and its mitigation measures  VOCs generation will be from storage and usage of raw materials.  VOC analysers will be provided to detect any solvent leakages during storage and handling.

H  Details regarding storage of Hazardous chemicals Storage details Name of major Remarks Hazardous chemicals Storage tanks Acetone, Bromine, Methanol, Ethyl Acetate etc… Drum/Barrel storage Acetic Acid, Acetonitrile, Chloroform etc…

 Applicability of PESO : Applicable, Permission will be Taken.

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6. Details of Environmental Consultant: Sr. Particulars Details no. i Name of the Consultant Envirocare Technocrats Pvt. Ltd. ii Contact no. and e-mail ID of the Mo. no.: 9727925122 Consultant e-Mail: [email protected] iii Accreditation for the categories and 5(f), Cat-A

Validity Valid up to 15/02/2022 iv Any other details

Name & designation of the Applicant: Sandeep Deshmukh (Director)

Stamp & Signature of Applicant:

Date:

General Instructions:

 Format shall be in WORD Format (Font type- Arial, Font size- 11)  Do not change Format. Fill up your details / information in prescribed tables.  Provide authenticated (with stamp & Signature) hard copy during presentation.  Kindly send e-mail to : [email protected]  Above data shall be as per application Form-1 & PFR.  Incorporate relevant details in respective column in the Format. Do not attach Annexure except copy of Certificates etc.

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