Publication No. 73-e57 SIJI( ‘( )t iii ~§~~1(N WA-07--1 100 Memo to: BiN But-well ~ ) Hi I 1 ol Ii( •( From: Ron Devitt

Subject: Weyerhaeuser Company — Snoqualmie Re: Bill i3urwell’s Request Memo Dated April 11, 1973

Date: June 21, 1973

OBJECTIVES

i. To characterize the various process discharges

2. To ~etervinethe degree of treatment occurring in the se~:li •q ditch

3. 7~ evaluate tr~e water quality of the log 4. To characterize the effluent from the log pond

I NTRODUCTI ON

On May 7, 1973, Jim Armstrong and I met Weyerhaeuser (Weyco) rep~ ntatives Roy Reinersten and Bruce Martinell at their Snoqualmie mill to di~.ss the proposed survey. On nay 8 tine survey was conducted as requested, but it was imposs~ ~e ~ determine flow at several locations and the depth of sludge build-~ i~ the pond was ~c,tdetermined. STATION LOCATION2 AND OBSERVATIONS

#1 Effluent from long pond. A composite sample wc.s oota~ frD: the oischarge over and through the weir at the outfall. Th~ .ei ias ft king badly; the traditonal method of measurino the

#2 S~tt~ing ditch effluent from 5-foot culvert beloa syvacs di~ .a~”c>~. #3 Syvacel discharge 10 yards upstream from confluence w~ ~et~ ~ ditch. Oil was observed on the surface. #4k Cajbined storm water and truck wash. Oil was observec surface. The flow increased tremendously while truc[ v~a ~er v~as in use.

Gov,rnor John A~ B~gqs, Director Olympic. No ~‘‘~:on h8504 Vo~phii 0 .0> Page two Memo to Bill Burwell June 21, 1973

#5 Storm water upstream of confluence with 4A. No flow was determined. The culvert was partially obstructed with debris and water was backed up to the north.

#6 Plywood lay-up glue waste.

#7 Discharge from log soaking vats. #8 Discharge from phenolic glue cooking. #9 Barker effluent. Samples were obtained from the ditch in the boil from the discharge. #10 Discharoe from powerhouse. This station was not sampled; there was no discharge during the survey period. #10k Log pond near powerhouse. Coliform samples were taken from catwalk at midchannel. #11 Combined discharge southwest of “mill” area.-

#12 Sewage treatment plant discharge. This station was not sampled because arrangements are being made to connect to the city lagoons.

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TABLE I

FIELD DATA

Teiiip MI Settleable Solids (mg/l) Flow (estii~iated cfsl 1 14.4 5.4 .15 2 21.4 5.6 .3 2.02 3 14.9 5.9 .07 4A .12 +200% 5 .06 6 11.2 5.5 07 7 34. 8 5.9 .02 9 6.0 4.5 1 .74 10 11 20.8 .05 12 13 13.7 6.1

Discussion of Field Data There is a discrepency between reported field settleable solids and laboratory data. This difference is explained by the fact that on stations 1 , 2, and 9, the lab solids were run on the composite and the field solids were determined on grab samples. Station 11 settleable solids are different, but tests were run on two different grab samples. The ph values obtained in the field were consistently lower than lab values. This is possibly explained by biological and chemical changes which occurred during storage and transport even though the samples were iced. The flow values were computed by measuring the dimensions of a channel and multiplying by the velocity. Although they are rough estimates, flows are reported to two places to give better comparisons. Inter- mittent rain fell on the day of the survey. Page four Memo to Bill Burwell June 21, 1973

TABLE III Coliform Colonies/100m1 s Sampling Point and Time Total Fecal Fecal Strep

Log pond effluent 945 hrs 55,000 3,000 <400 Log Pond at effluent weir-surface 1510 hrs 50,000 1 ,900 <400 Log pond at effluent weir-bottom 1510 hrs 60,000 3,500 <400

From catwalk south of powerhouse - mid channel-surface 1450 hrs 80,000 6,000 1300 From catwalk south of powerhouse - mid channel - bottom (4 meters) 1450 hrs 70,000 6,000 1200 Discussion of Lab Data The values reported characterize the individual discharges. The treatment ditch appears to reduce settleable solids, 800, and COD. The effluent from the log pond is characterized by the data for Station #1.

The coliform data presented in Table III reflect the water “quality” of the log pond. Page five Memo to Bill Burwell June 21, 1973

PERSONAL COMMENTS

Background June 6, 197 Pat Lee and I did a survey on the sewage treatment plant and composited the log pond effluent at the weir. Additional stations were established in the log pond and grab samples were taken. The results of this survey indicated that the efficiency of the STP was marginal and that disinfection was inadequate. The following field data were reported on the log pond effluent from 1100 hours to 1900 hours. Max Mm Mean Median Temp (C0) 19.8 19.1 19.6 19.8 pH 7.1 6.2 6.7 Conductivity (iimhos/cm) 140 125 130 130 Settleable Solids (rnl/l) .3 .1 .1 .1

Laboratory data on the effluent composite from 1300 hours to 1900 hours were:

BOO - 13 ppm Sp. Conductivity — ll2~mhos/cm

COD - 100 ppm Turbidity — 36JTU

TS - 183 ppm pH — 7.1 TNVS — 97 ppm

TSS - 36 ppm NVSS - 40 ppm Total coliform samples taken from the outfall were run in the motel using the Millipore Field Kit. Values are reported in colonies/lOOmls.

TIME TI ME

1130 — <20,000 1430 - 22,000 1230 - 26,000 1730 - <20,000 1330 — 31 ,000 1830 - <20,000

The overall quality of the log pond effluent was better during this previous survey. The BOO, COD, Solids, Turbidity, and coliform were all lower. The pH was also within the acceptable range for discharge, contrary to field data obtained in 1973. Page six Memo to Bill Burwell June 21, 1973

Flow Estimation Flow estimates are rough. The area of water was measured with a tape measure and/or yardstick. The velocity was computed by timing a float- ing object (cigarette filter) dropped in midstream, and measuring the length of travel. Time was doubled in each case, because the velocity of the general waterway was obviously slower than at the surface midstream. Although the method was crude, the estimates are somewhat relative and better than an eyeball guess. The use of a 900 “V” notch weir pipe inserts was not possible because the culverts all had flows exceeding the capacity of the weirs. The use of a gurley meter was impossible in shallow depth flows. Also in the settling ditch, the amount of sludge build-up made wading difficult and would have also biased gurley meter readings.

Methods use in calculation are attached.

Col iform The exceeding high numbers of coliform present a potential health hazard to the employees working in and around the log, pond. Comparing these numbers to the effluent from the White operation, the values are gross; this is due to the discharge of inadequately disinfected domestic sewage. A ratio of fecal to fecal streptococci of greater than 4.4 indicates that the source of bacterial contamination is of human origin. The ratios obtained from Station lOA surface and bottom are 4.6 and 5.0 respectively. Considering that fecal streptococci do not multiply in water, the values obtained near the powerhouse are very high. An apparent die-off is observed before discharge from the log pond, but the numbers of total coliform (55,000; 50,000; 60,000 colonies/l00 mls) are still gross. The proposal of connecting the domestic sewerage to the city treatment system will improve the bacterial quality of the pond considerably; but, in the interim, the chlorine addition rate on the STP should be increased. There is little danger of damaging any biota of the pond by adding excess- ive chlorine.

An effort should be made to encourage the industry to inform their employees who have potential contact with the long pond waters of the health hazard which exists. 2

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/ 7’ .4 U) MEMORANDUM Check Department of Ecology Information For Action Permit

Other ______

TO: Ron Pine & Pete Hildebrandt DATE: ~ R I,.,. FROM: H. W. BurWe11 / “‘s—’ /“ ,.., ½’.’ 7~ - ~ I’’ -‘p2 / A~

4 “ ~) gnoqua1rn~ej)C (0 41) 3/4 ~ SUBJECT: ~ 1)’ ‘~~‘ C ~ -‘4 SCOP ING /,

(44’ ‘74 OBJECTIVE 4’) 1. To characterize the wastes being discharges at the unit process level.

2. To determine the degree of treatment, if any, is being achieved by the current settling ditch.

3. To characterize the effluent from the Snoqualmie Log Pond. 4. To evaluate the water quality in the Log Pond.

BACKGROUND

In terms of industrial waste water disposal, the Weyerhaeuser Mill at Sno— qualmie, until now, has been all but ignored by this Department. The process effluents have not been adequately an&l~zed nor has the treatment ~iystembeen evaluated. The operation consists of a mill and power house, a plywood mill, a hydraulic barker and a wood fiber processing operation. The power house has a thermal discharge at times, a blow down discharge and small quantities of bear- ing water. The saw mill discharges saw guide water and cooling water. The ply- wood operation has phenolitic glue wastes associated with it along with dryer condensate, log conditioning discharges, and small amounts of cooling water. The most significant discharge is associated with the hydraulic barker, the dis- charge being treated by means of a settling ditch. The “sylvacel” or wood fiber plant produces small quantities of cooling water. In addition to these effluents, a discharge occurs from the log washer and oil problems are associated with a number of the processes.

Station Location Analysis

1 Along Road, (Composit Sample: Effluent . 7B0D5, ‘COD, suspended solids,

• ~ ,•-‘ solids, “he~aDe_extraction

1’ ~‘/§ ½’ Grab Sample: PH, temp.,(’.~jLow1—’ -C- 4.,C~” _____..,,~9rthophosphate, - ~ .nitrate - .~-total phosphate, turbidity, total and fecal coliform 2 Settling Ditch Effluent Composit, Sample:

BOD5*, COD, suspended solids, settleable solids, vo~~~e *BOD5 for ditch effluent should be run after phenol analysis. Toxic conditions may be present (Freeze Sample). : : Page 2 April 17, 1973

Location Analysis Station solids-, ‘hexane extraction,

½henols ~ - Grab Samples: pH, temp,’.flow,-

turbidity, ~ammonia, 76rthophos-

3 Drainage from Hyster Shop Grab: pH, temp( hexane extrac- and “Syvacel” tion, estimate (flow> -- 7 4 Log Washer Grab: BOD5, ‘

5 Storm Water ditch Estimate flow

6 Condensate from drier from Grab:

Hydraulic Barking ‘ BOp5,. COD, turbidity, 9 flow,) pH, ,‘~.mmonia, ‘-=ojal phosphates, ~iane extraction

Power House Discharge Grab: Plow, temp, pH

Guide water & cooling Grab: ~Settleable solids, ‘Ssuspended 11 solids, -BQD5, -CODs’ flow 1, pH

13 Intake Grab: ‘Suspended solids,-’

Sample Log Pond bottom and at the surface for total coliform, fecal coliform, and 1’-~’S depth of sludge build up.

A ~ Ut ENTITY TO CONTACT ‘ ~ ~~{\~C ~

1. Bob Hammerly, Weyerhaeuser, .‘g~—25I1 —‘ -, 2. Northwest Regional Office, Attn: H. W. Burwell

EXPECTED RESULTS

The most important parameters involve charterization of discharges from the various operations and characterizing the effluent from the log pond. The results should be in two formats. The first should include all the data and observations taken at the time of sampling. The second should be any comments, statements as to corrective action and reflective observations. Such a division Page 3 April 17, 1973

in the report allows for the data portion only to be transmitted to the industry.

STUDY COMPLETION DATE

By May 15, 1973, so as to insure pond overflow. Due not sample on a Monday or a day following a holiday.

H~B: dw

4-16—73 dd 4-17-73 dt STATE OF WASHINGTON ORIGINAL TO: DEPARTMENT OF ECOLOGY COPIES TO: WATER QUALITY LABORATORY

DATA SUMMARY LAB FILES

Source l.AJeyco cQ SN&A&~e Collected By A-&e 1 4~ Z Date Collected______Goal, Pro./Obj.

Log Number: 92 ~ —..--—.— ~TflPI~T Oe~4s- t5~jc, S’-~” (3ort. Station: j~•• ~ j~ J .L I Ic~A iOA

pH 00403

Turbidity (JTU) q0 7o ?o 00070

CQnductivity (lImhos/cm)@2~(. 00095

COD ~L~L /(.~.3 k97 00340

BOD (5 day) i.L~i ;z~o 23 00310 ~ I ~‘~cV ~ 7c2ex~ 1 31504 TotalZ>~ctf,Coliform (Col./lOOml) ~ K 7 ~$g~ Fecai~Cd1Tforrn(Co1C/lOOml) h 5v~ .I4~Q ~ k..~ 31616 N03-N (Filtered) ±.IaL. 00620

N02-N (Filtered) 00615

NH3-N (Unfiltered) 00610

T. Kjeldahl-N (Unfiltered) 00625

O-P04-P (Filtered) Pj) 00671

Total Phos. -P (Unfiltered) 00665

Total Solids ~ 00500

Total Non Vol. Solids /(rj i~7

Total Suspended Solids ~ iLL. 00530

Total Sus. Non Vol. Solids 28 2{L

Fe~,9~ STKg~((.ci/ip,~t) =,!L~~ AA~L (300 /2CC eI-ttc,~c =~ oi Hc’&~,ve 12JV/?4cr44teS I~ )j~/: ~i)

Note: All results are in PPM unless otherwise specifi 3ed. ND is “None Detected”

Convert those marked with a * to PPB (PPM X 10 ) prior to entry into STORET &Jt~r ~c4veSre~ / Summary By . Date STATE OF WASHINGTON ORIGINAL TO: •l~Q1~tf DEPARTMENT OF ECOLOGY COPIES TO: WATER QUALITY LABORATORY

DATA SUMMARY LAB FILES

Source t.AJe ~Co & =~cu&wi.i,e (A./wi Collected By I?C0

Date Collected______PAG~’ Ioi~L Goal, Pro./Obj. •32-2~

Log Number: )J— (LVi _____ ~‘-~ 9o STORET C C~j.~-~’ £~A4 C~~4t~ C-RA~ Station: ~L~AL~fa t:ta ‘v’~ ~ I____

ph ~5 G= ~‘6 4J( 7.0 ~ 4~ 00403

Turbidity (JTU) ~o 4c 2~G j(o 3~ f{cc Z= (C) 00070

~ L)~ h -~ 00095

COD )4t4 239 jj. i?= 00340

BOD (5 day) 2A2. I~.V. 12. ~ 00310 T a~ Total~~ColifGrmti(~ol~.Jl0Onrl-) le 31504 ~3 ~•~ FecaVColif6r?n (Col./lOOml) 31616 * N03-N (Filtered) 00620 N02-N (Filtered) 00615

NH3-N (Unfiltered) A.=1..

T. Kjeldahl-N (Unfiltered) / 625 I O-P04-P (Filtered) i~.J) ~ 00671

Total Phos. -P (Unfiltered) ~j{ 00665

Total Solids 22Z 7~S 5”~ 0500

Total Non Vol. Solids lit 2?? 6e’c

Total Suspended Solids

Total Sus. Non Vol. Solids i-fl I~ h~NL= ..osi’

.~CtILr~4I1Lc ~X94DJC ,y) c9.(

I~(AA~ T~4cTrnw’s (F (

~ i ~~()OI

Note: All results are in PPM unless otnerwise specif~ed. ND is “None Detect&d” ii (

Convert those marked with a * to PPB (PPM X 10) prior to entry •nto STORET ~ *Vc~T ,~ecvesre.e Summary ~ Date &-22-~/ —I ?)