*828SERBSF10,644*
*828SERBSF10,644*
Site Name (Subject): WINSTON CONTAINER COMPANY
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Site ID (Document ID): NCD024477556
Document Name (DocType): Preliminary Assessment/Site Inspection (PA/SI)
Report Segment: 1 Description: Screening Site Investigation Report
Date of Document: 10/10/1991
Date Received:
Box: Enter SF and II with na spaces SF10,644
Access Level: PUBLIC
Division: WASTE MANAGEMENT
Section: SUPERFUND
Program (Document Group): SERB (SERB)
Document Category: FACILITY
Print Report for Go to New Go to New Record - Delete Record I Record Blank Record (default to last record values) I .. I
I SCREENING SITE INVESTIGATION REPORT I Winston Container Company I NCD 024 477 556 Charlotte, North Carolina I 10 October 1991 I I Prepared for: North Carolina Superfund Section Solid Waste Management Division • NC Department of Environment, Health, and Natural Resources I Prepared by:
HDR Engineering, Inc. of North Carolina I 128 South Tryon Street I Charlotte, N. C. I I Volume I SSI Report List of References I Appendix A: Maps and Photographs Appendix B: Preliminary Assessment Form Site Inspection Form I Latitude/Longitude Calculation Form f I
--- I .. TABLE OF CONTENTS I EXECUTIVE SUMMARY SECTION
I 1.0 INTRODUCTION 1.1 Study Objectives 1.2 · HDR Participation I 1.3 Limitations I 2.0 BACKGROUND 2.1 Location 2.2 Site Layout I 2.3 Ownership History 2.4 Site Use History 2.5 Process and Waste Disposal History I 2.6 Permit and Regulatory History 2.7 Remedial Actions to Date 2.8 Description of Earlier Reports I 2.9 Summary Trip Report
3.0 ENVIRONMENTAL SETTING 3.1 Topography • 3.2 Surface Water 3.3 Geology, Soils, and Groundwater I 3.4 Climate and Meteorology 3.5 Land Use 3.6 Population Distribution I 3.7 Water Supply 3.8 Critical and Sensitive Environments
I 4.0 TARGET ANALYSIS 4.1 Groundwater 4.2 Surface Water I 4.3 Air I 4.4 On-site Exposure 5.0 WASTE TYPES AND QUANTITIES 5.1 Waste Types and Disposal Methods I 5.2 Waste Quantities ~. I I I .. TABLE OF CONTENTS (continued) 6.0 FIELD INVESTIGATION I 6.1 Description of Samples and Sample Location 6.2 Quality Control Samples 6.3 Field Measurements I 6.4 Analytical Support 6.5 Analytical Results
I 7.0 TOXICOLOGICAL AND CHEMICAL CHARACTERISTICS I APPENDICES A Maps and Photographs B. Preliminary Assessment Report I Site Inspection Form Latitude/Longitude Calculation Form I c. References D. Analytical Results E. Sampling Plan I F. Excerpts from Site Safety Plan
•I I I I I I I f I I •• EXECUTIVE SUMl\.fARY I The Winston Container Co. site is located on Morris Field Road in Charlotte, North Carolina, about 0.3 miles east of the intersection of Airport Drive and Morris Field Road.
I Prior to 1953, the site was pasture land. Following its purchase by Winston Container, the existing facilities were constructed. Since 1953, the only modifications to the facility were an addition to the parking area in 1982, and the relocations of the office and front entrance I from Morris Creek Road to Airport Drive around the same time.
The Winston Container Co. facility is used for the refinishing and refurbishing of steel I drums. The entire facility is bordered by Taggart Creek to the north, south, and east, and by a chain link fence to the west. At the northern end of the facility is a garage used for I truck repair. Wastes are generated as follows: Waste ash and dust from the paint removal processes I (0008), waste paint solids from paint overspray (0008), and waste solvents from cleanup operations (F003/F005). Methyl ethyl ketone (MEK) is used on site, and VM&P Naphtha I (Petroleum Spirits, Stoddard Solvent) was previously used. · There are two UST's currently in use at the facility: (1) a 10,000 gallon diesel fuel tank, and (2) an MEK storage tank of unknown age and estimated size of 2,000 to 5,000 gallons. The facility map shows two additional underground storage tanks for MEK and for VM&P ••• Naphtha that are no longer in use. I Environmental samples collected at the site indicate releases of di-n-butylphthalate, butylbenzyl phthalate, bis (2-ethylhexyl) phthalate, di-n-octyl phthalate, 1 ,2-dichlorobenzene, acetone, antimony, arsenic, barium, cadmium, calcium, chromium, copper, cyanide, lead, I mercury, selenium, silver, sodium, and zinc. I I I I
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1.0 INTRODUCTION .. 1.1 Study Objectives I A list of potential hazardous waste sites, known as the Comprehensive Environmental Response, Compensation, and Liability Information System I (CERCLIS), has been established by the United States Environmental Protection Agency (USEPA), in cooperation with the State of North Carolina (State). After a site is placed on this list, it must undergo one or more investigations to I determine its priority status for remedial action by the USEPA.
The North Carolina Department of Environment, Health, and Natural Resources I (NCDEHNR) has entered into a cooperative agreement under Section 104 of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980, Pub. L. 96-510, 94 Stat. 2767, 42 U.S.C. 9601 et seq. (CERCLA) as I amended by the Superfund Amendments and Reauthorization Act of 1986, Pub. L. No. 99-499, 100 Stat. 1613 (SARA), to conduct Screening Site Investigations on 45 sites in North Carolina. The objectives of each Screening Site I Investigation are to
1. develop a hazard ranking score (HRS) for the site, as described in the I HRS Users Manual (Ref. 19), and
2. collect other data which may be useful in conducting any future investigations which may be required, particularly the Listing Site • Investigation Evaluation (LSIE), which is essentially a preliminary I scoring of the site using the revised HRS (RHRS). This investigation is conducted as a part of the Hazard Ranking System, which I serves as an objective screening device to evaluate the relative potential of uncontrolled hazardous substances to cause human health or safety problems, or ecological or environmental damage. The HRS score represents an estimate of I the relative probability and magnitude of harm to human population or sensitive environment from exposure to hazardous substances as a result of the I contamination of groundwater, surface water, or air. 1.2 IIDR Participation
I HDR Engineering, Inc. of North Carolina (HDR) has been retained by the NCDEHNR, Superfund Section, to conduct Screening Site Investigations for 20 I sites in Western North Carolina, including the site described in this report.
I~. 1 I I 1.3 Limitations on Use of Document
This investigation was conducted for the sole purpose of assisting the .. NCDEHNR and the USEPA in screening sites for further regulatory action under CERCLA, as amended by SARA. Any other use of this document is I prohibited without the expressed written consent of HDR. Furthermore, any use of this document by any party other than the NCDEHNR or the USEPA is prohibited without the expressed written consent of HDR. This document is not I to be used, except by NCDEHNR or the USEPA, as evidence that (1) contamination does or does not exist on the property, (2) that the facility is or is I not in compliance with applicable laws and regulations, or (3) that further regulatory action will or will not be required. I I I I
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2.0 BACKGROUND .. 2.1 Location I The Winston Container Co. Site is located on Morris Field Road in Charlotte, North Carolina, about 0.3 miles east of the intersection of Airport Drive and I Morris Field Road. The coordinates of the site are: latitude 35° 13' 00", longitude 80° 55' 29" (Ref. 1, 2; Fig. 1). I 2.2 Site Layout
The Winston Container Co. facility is used for the refinishing and refurbishing I of steel drums. The entire facility is bordered by Taggart Creek to the north, south, and east, and by a chain link fence to the west. At the northern end of the facility is a garage used for truck repair. This garage has a 10,000-gallon I underground storage tank used for storage of diesel fuel. The facility office and factory areas are in the middle of the site. Drum segregation, receiving, and incineration take place outdoors south of the factory. A building housing the I drum opening equipment is located at the southern end of the facility (Ref. 3).
In front of the facility are two above-ground storage tanks for well water I storage. An underground storage tank containing methyl ethyl ketone (MEK) is located southwest of the water tanks. The age and size of the tank are unknown, with the estimated size ranging from 2,000 to 5,000 gallons (Ref. 3). • The facility has a slight (approximately 1%) slope to the southwest, with the access/evacuation road forming a slight berm between the site and the creek. I Taggart Creek is located approximately 10 feet below the ground elevation of I Winston Container Co. (Ref. 3). 2.3 Ownership History I Winston Container Co. has operated on the present site since 1953. Prior to 1953, the site was pasture land. The owner since Winston Container has been I on this site is Mr. Robert Winston, Sr. (Ref. 3). 2.4 Site Use History
I Before 1953, the site was undeveloped. Following its purchase by Mr. Winston, the existing facilities were constructed. The only modifications to the facility were an addition to the parking area in 1982, and the relocation of the I office and front entrance from Morris Creek Road to Airport Drive around the same time (Ref. 1, 3).
I~. 3 I I 2.5 Process and Waste Disposal History
Drums are received and segregated into groups, essentially open-topped and .. closed-top containers. Closed-top drums are cut open and then fed into an I incinerator to loosen the drum coating. Open topped drums are fed directly to the incinerator. The next step is to remove the paint by scouring with lead shot in a "wheelabrator" unit. Ash from the incinerator and dust from the I wheelabrator are collected and stored in drums for disposal as hazardous waste (D008) (Ref. 3).
I After all paint is removed from the drums, the drums are sized, leak tested, and painted using spray epoxy coatings. Two coats of drum lining epoxy are applied automatically, with each coating oven baked after application. The I outer coating is applied in a paint spray booth. Paint overspray is collected in the paint spray booth. To prevent buildup of overspray solids in the paint spray booth, Winston Container uses a closed-loop water wash system. Overspray I solids impinge on the surface of the water, and are collected in a tank, where they are skimmed into drums and disposed of as hazardous waste (D008). MEK is used as the solvent for all coatings presently used. All waste MEK generated I from spraying operations and cleaning operations is collected in drums and disposed of as hazardous waste (F003/F005). Several years ago, a second solvent, VM&P Naphtha (Petroleum Spirits), was also used for some coatings. I The use of these coatings and the VM&P solvent have since been discontinued. Once the drums have been coated, gaskets and lids are added and the drums are stored in tractor trailers for shipment (Ref. 3). • Wastewaters are generated from the incinerator both from the contact cooling water used to cool the incinerator production-line chain, and from washdown of I the incinerator pad area. These wastewaters are discharged into two settling tanks, and then to the sewer, system. The waterbath used to leak test drums is I batch-discharged to the sewer as necessary. The water wash used to capture paint overspray is continuously recycled, with additional make-up water added I to replace evaporate losses (Ref. 3). There are two underground storage tanks (USTs) currently in use of the facility: (1) a 10,000 gallon diesel fuel ~k, and (2) an MEK storage tank of unknown I age and an estimated size of 2,000 to 5,000 gallons. The facility map shows two additional USTs for MEK and VM&P Naphtha that are no longer in use I (Ref. 3). Prior to RCRA, the incinerator ash was disposed of in one or more of the City of Charlotte landfills that were operating at the time. The date of the sewer I connection or other disposal practices of paint waste was not known (Ref. 3).
~. 4 I I I 2.6 Pennit and Regulatory History .. In 1980, the Winston Container Co. applied for interim status under RCRA as a TSD facility. In 1985, the facility was deleted as a TSD but remained a I generator. Winston Container has air quality permits to construct/operate for the paint spraying line, dip tank, shot blasting operation, spray painting booth, and incinerator. These permits date from 1973 to present. The air quality I regulatory history includes reformulating the paints used to meet volatile organic compound (VOC) standards and continual monitoring and modification of the incinerator to meet visible emission regulations. One inspection report in 1980 I noted two unpermitted discharges into Taggart Creek. (Ref. 1, 4). I 2. 7 Remedial Actions to Date There have been no remedial actions at this site (Ref. 3).
I 2.8 Description of Earlier Reports I No other reports have been made for this facility (Ref. 3). I 2.9 Summary Trip Report On June 22, 1990, the Winston Container Co. facility was visited by Grover Nicholson of the NCDEHNR, Superfund Section; George Tyrian of HDR Engineering, Inc.; and Jarrell Wootan of the Mecklenburg County Department of Environmental Protection Agency. In addition to visiting the site itself, - Jarrell Wootan and George Tyrian performed a windshield inspection of the I surrounding area. At 1:00 pm the inspection team visited the site and spoke to Mr. Fred Ross and I Mr. Bob Winston, Jr. of Winston Container Co. The results of the trip are summarized in a Summary Trip Report (Ref. 3).
I On October 23, 1990, the site was visited by Grover Nicholson, Jarrell Wootan, Fletcher Armstrong (HDR), and LeRoy Meyer (HDR). The group met with Mr. Fred Ross and briefed him on the activities planned for the day. The field I investigation included the collection of environmental samples for subsequent analysis, as described in Section 6.0. I I ~ 5 I I
3.0 ENVIRONMENTAL SETTING .. 3.1 Topography I The site is located in an area of mostly undeveloped land adjacent to the Douglas International Airport. The elevation of the site is approximately 635 I feet above mean sea level. The slope at the facility is estimated at approximately 1% to the southwest (Ref. 3). I 3.2 Surface Water Stormwater runoff from the site drains southwest across the site, toward Taggart I Creek, which borders this facility on three sides. The facility area is flat, with Taggart Creek approximately 10 feet below the facility. Taggart Creek discharges to Sugar Creek about 2 miles downstream (Ref. 2; Fig. 1). Sugar I Creek discharges to the Catawba River approximately 20 miles away. I 3.3 Geology, Soils, and Groundwater The site lies within the Charlotte Belt hydrogeologic unit of the Piedmont Province. The Charlotte Belt Granite belongs to the diorite-granite complex or I is believed to be associated with it.
Gabbro-diorite is widely exposed along N.C. Route 49 south of Shopton in the southwest part of the county. It is a massive medium-to coarse-grained dark • colored igneous rock composed .mostly of pyroxene or hornblende and plagioclase feldspars. It is exposed in a few road cuts and as isolated boulders I above the generally flat land surface.
The diorite-granite complex proper covers a large area around Charlotte. I Bodies of diorite are locally separate from bodies of granite, but as a whole the two rocks are too closely intermixed to map separately. Outcrops are not I common enough to ascertain the predominance of one type over the other except in a general way. (Ref. 5). I Bedrock is covered by unconsolidated material, known as saprolite, which is derived from weathering of the parent rock. The hydraulic conductivity of the saprolite in the unsaturated zone is estimated to be 1. 77 x 10"3 em/sec. Due to I heterogeneity of the bedrock, the thickness of the covering saprolite varies locally (Ref. 7). I
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In the North Carolina Piedmont, groundwater typically behaves as a single aquifer from the top of the saturated zone into the fractured bedrock (Ref. 7). .. Although there is one drinking water well at the site, the groundwater elevation I is not available. However, since the site is about 10 feet above the level of Taggart Creek, the depth to groundwater at this site is estimated at I approximately 10 feet (Ref. 3). I 3.4 Climate and Meteorology In the Charlotte area, the mean annual precipitation is 44 inches and the mean annual evaporation is 41 inches (Ref. 8). Assuming uninhibited evaporation, the I net precipitation would be 3 inches. The one-year, 24-hour rainfall is 3.0 inches (Ref. 9).
I 3.5 Land Use
The immediate area surrounding the Winston Container facility is undeveloped. I Within 1/4 mile are industrial, commercial, and residential land uses (Ref. 3). I 3.6 Population Distribution The Site lies within the boundaries of Charlotte, NC, a city of 314,447 people (Ref. 10). The area surrounding the site can be characterized as mixed • industrial, commercial, and non-farm residential. (Ref. 3). The schools and day care facilities (not including day care homes) within four I miles of the subject site are estimated as follows (Ref. 20): I 1-mile radius 0 schools, 0 day care centers 2-mile radius 3 schools, 14 day care centers 3-mile radius 8 schools, 17 day care centers I 4-mile radius 7 schools, 14 day care centers I 3.7 Water Supply Within the city limits of Charlotte, residents obtain water from the Charlotte water system. This system obtains water from intakes located on the Catawba I River, none of which are downstream of the subject site (Ref. 12). No other water intakes are located within 15 miles downstream from the subject site (Ref. 14). The only source of water for residents outside the Charlotte Water System I are private wells or very small public systems which supply limited service. All of these small public systems are supplied by groundwater (Ref. 13).
I~. 7 I I 3.8 Critical and Sensitive Environments
There are neither wetlands of 5 acres or more nor critical habitats of federally .. listed endangered species within 4 miles of the site or within 15 miles along I Taggart Creek and Sugar Creek downstream of the site (Ref. 11). I I I I I I
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4.0 TARGET ANALYSIS ~ 4.1 surface Water I Within 15 miles of the site, Sugar creek is not now used for irrigation, but its use by a nursery located downstream of the site is being considered (Ref. 16). The only fishing that may be done on Sugar Creek is by local residents (Ref. 15) • There I are no downstream surface water intakes for drinking water purposes on Taggart creek or on Sugar Creek within 15 miles of I the Winston Container co. 4.2 Groundwater I This area is located within the Charlotte Mecklenburg Utility District (CMUD), so groundwater is ·not used extensively. Many of the houses in the area predate the Charlotte city water system, so it is expected that wells are still used. The I Winston Container Co. site itself uses well water on site.
The total population using groundwater within four miles of I the subject site is estimated as follows (Ref .22):
I DISTANCE # HOUSES # HOUSES # PEOPLE # PEOPLE FROM SITE SERVED BY USING USING USING (MILES) CMUD AREA PRIVATE COMMUNITY GROUNDWATER WELLS WELLS (SEE NOTE) • (A) (B) (C) 2.5(0.6A+B)+C I 0 - \ 14 0 0 21 I \ - ~ 73 0 0 110 :, 2 - 1 333 0 0 500 I 1 - 2 967 15 190 1678 2 - 3 1418 208 585 3232 I 3 - 4 1240 424 920 3840 TOTAL 4045 647 1695 9381 I Note: An estimated 60% of the households in the CMUD are private wells. According to the 1990 census, the Mecklenburg County I population density is 2.5 persons per household. I {' I I
These numbers were obtained by: ~ 1. excluding all densely populated areas (i.e., the portion shaded on the USGS maps) within the boundaries of City of I Charlotte Water system, since these people are served by the Charlotte Water system, I 2. counting the number of residents serviced by small rural water systems, since these are all serviced by wells (Ref. 13), I 3. counting the number of houses outside the CMUD on the USGS maps (Ref. 2; Fig. 1), and multiplying the number of houses by 2.5 peoplejhouse, since all of these houses all I assumed to be served by domestic wells, and 4. counting the number of houses inside the CMUD on the USGS I maps, and multiplying 60% of the number of houses by 2.5 people/house to assume the 60% of the residences inside I the CMUD are served by domestic wells (Ref. 12). I
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Winston Container Co. is served by an on-site well. The distance to the nearest .. house possibly served by an on-site well is about 300 ft. (Ref. 3, Fig 1.) I 4.3 Air The population within 4 miles of the site is estimated as follows (Ref. 22):
I 1-mile radius 2,000 people 2-mile radius 8,100 people 3-mile radius 19,100 people I 4-mile radius 45,000 people I These numbers were obtained by 1. assuming that the population density within the densely populated I portion of Charlotte (i.e., the portion shaded on the USGS maps) could be estimated using the population density of Charlotte, or 2,251 I people/house (Ref. 10), 2. counting the number of houses on the USGS maps (Ref. 2, Fig 1), I multiplying the number of houses by 3.8 people/house, and 3. counting the number of residents known to be served by small rural water systems but not otherwise identified (Ref. 13). • 4.4 On-Site Exposure I The population within one mile of the site is estimated at 2,000 people, as described in Section 4.3.
I There are no wetlands or sensitive environments within 4 miles of the site (Ref. 21). I I I I
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5.0 WASTE TYPES AND QUANTITIES .. 5.1 Waste Types and Disposal Methods I The type of waste generated at the site is classified as waste ash and dust from the incinerator operations. Prior to RCRA regulations, the waste ash and dust was disposed of in one or more of the City of Charlotte landfills that were I operating at the time. A 1985 laboratory analysis for metals showed the I following detectable concentrations in soil on site (Ref. 4): Barium 520 ppm Cadmium 5.7 ppm I Chromium 220 ppm Mercury 1.3 ppm Lead 690 ppm I Arsenic 3.8 ppm I 5.2 Waste Quantities Winston Container generates approximately 400 to 500 drums/year of waste ash and dust (Ref. 1). Typical quantities of wastes stored on-site prior to disposal I are as follows (Ref. 17):
Ash, "Wheelabrator" Dust, Paint Sludge (D008): 60 drums Waste Solvent (MEK) (F003/F005): 6 drums •I I I I I I
~. 11 I I I le 6.0 FIELD INVFSTIGATION 6.1 Description of Samples and Sample Locations
I Environmental samples were jointly collected by HDR and the NC Superfund Section at the Winston Container Site on October 23, 1990, for subsequent I laboratory analysis. Of significant concern at this site is the possibility of soil, groundwater, and surface water contamination. I A background surface soil sample (SS-32) was collected on the east side of the property, near the parking lot (Fig. 3). This sample was analyzed for target compound list (TCL) volatile organic compounds (VOCs), TCL semivolatile I organic compounds (SVOCs), and target analyte list (TAL) metals/cyanide. Surface soil samples from three locations (SS-31A, SS-31B, and SS-31C) were I collected in the drum washing area and were composited into one soil sample (SS-31). The composited sample SS-31 was analyzed for TCL SVOCs and TAL metals/cyanide. A second sample was taken at location SS-31A and was I analyzed for TCL VOCs. Surface soil samples were collected at SS-33A, SS- 33B, and SS-33C in and around the drum storage area and were composited. This composite soil sample was tested for TCL SVOCs and TAL I metals/cyanide. A second sample was taken from SS-33A (adjacent to a yellow sludge material) and was analyzed for TCL VOCs.
An attempt to reach ground water was made at the location of AB-31. If •• groundwater had been reached, a sample would have been collected to be used as a background water sample. However, since there was auger refusal at 11.5 I feet, soil collected from the 7.0 to 11.5-foot interval was analyzed for TCL SVOCs and TAL metals/cyanide. Soil at 11.5 feet was sampled for VOC I analysis. A groundwater sample (DW-31) was collected from the on-site drinking water I well and was analyzed for TCL VOCs, TCL SVOCs, and TAL metals/cyanide. Taggert Creek, which runs along the north, west, and south sides of the site, I was sampled at two locations. The creek sediment was sampled upstream of the plant (SED-32) and downstream of the plant (SED-31).
I Sample collection methods are described in the Sampling Plan (Appendix E). I
••I 12 I I le 6.2 Quality Control Samples Two quality assurance (QA) samples were collected for the combined sampling I event covering Hoover Repair Shop Site, the Winston Container Site, and the Basco Hand Tools Site. I A trip blank was provided by the laboratory and was transported with the sampling team throughout the three days during which the above sites were I sampled. The trip blank was analyzed for TCL VOCs and TCL SVOCs. An equipment rinsate blank was poured at the Hoover Repair Shop Site and was I analyzed for TAL metals/cyanide. A third QA sample, an equipment rinsate blank, was collected for equipment used at the Winston Container Site and the Easco Hand Tools Site. For this I sample, the equipment was rinsed with isopropanol, such that the blank contained a certain amount of that solvent. This sample was analyzed for TCL I VOCs and TCL SVOCs. 6.3 Field Measurements
I No field measurements were recorded .
6.4 Analytical Support
•• Laboratory analyses of the equipment rinsate blank for organic compounds and I the background groundwater sample for organics and metals were conducted by the NCDEHNR. All other samples were transported to CompuChem Laboratories, Inc. of Research Triangle Park, North Carolina. CompuChem I subcontracted the analysis of TAL metals to Skinner & Sherman, Inc. of Waltham, Massachusetts. Both laboratories are in the USEPA Contract Laboratory Program (CLP), and all analyses conducted by either of them were I in accordance with the applicable USEPA CLP Statement of Work. I 6.5 Analytical Results Laboratory results for environmental samples are presented in Table 6-1. Excerpts from the original data packages are presented in Appendix D. I Complete laboratory reports are to be submitted to the NC Superfund Section under separate cover. I
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In the composite surface soil samples taken from the drum storage area (samples le SS-31 and SS-33), significant levels of antimony, arsenic, barium, cadmium, calcium, copper, iron, lead, mercury, selenium, silver, sodium, zinc, di-n butylphthalate, butylbenzyl phthalate, bis (2-ethylhexyl) phthalate, acetone, and I cyanide were detected. When these samples were diluted and reanalyzed, 1,2- dichlorobenzene and di-n-octyl phthalate were also detected. In one of the composite surface soil samples (SS-31), chromium was detected at 5.5 times the I background sample. I I I I I •• I I I I I I
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Analytical Results for Envirorunental Samples I e Winston Container Site
I Sample Analyte Grou~ (Units} Signi- Number Description Analyte Detection Level Result ficance MCL Remarks I BL-1 Equpment rinsate blank TAL Metals/Cyanide (l!g/1} Barium 2.0 9.4 5000 Chromium 5.0 13.7 100 I Lead 1.0 5.4 * Aluminum 23.0 34.4 Calcium 13.0 52.1 I Copper 3.0 10.1 Iron 10.0 117 Manganese 1.0 5.80 Nickel 6.0 7.10 100 I Sodium 48.0 929 Zinc 9.0 32.0
I BL-1 Trip blank TCL VOCs (l!g/1} Methylene Chloride 5 3 5 B,J I TCL SVOCs e none detected I NCSFS Equipment rinsate blank TCL VOCs (l!g/1} (Equipment rinsed with Chloroform 5 4 J I Isopropanol) Acetone 10 304 TCL SVOCs I none detected AB-31 Deep soil sample TAL Metals/Cyanide (mglkg} (Background for Aluminum 6.1 25,900 I groundwater) Arsenic 5.1 2.30 Barium 0.5 69.6 Beryllim 0.2 0.25 I Calcium 2.4 4230 Chromium 1.4 401 Cobalt 0.9 45.8 I Copper 0.7 21.0 Iron 4.7 48,900 Lead 0.5 1.60 N Magnesium 7.1 26,800 I Manganese 0.5 545 Nickel 1.4 127 Potassium 17.0 195 Sodium 11.8 64.6 Vanadium 0.7 92.9 ••I Zinc 1.2 100 15 I I Table 6-1 (continued) I Analytical Results for Environmental Samples e Winston Container Site
I Sample Anal~te GrOUQ (Units) Signi- Number Description Analyte Detection Level Result ficance MCL Remarks I AB-31 (Continued) TCL VOCs (&!g/kg} Methylene Chloride 6 29 B I Acetone 12 31 TCL SVOCs (&!glkg) Bis (2-Ethylhexyl) I Phthalate 390 40 J 2 Semivolatile TICs J I DW-31 Groundwater sample from TAL Metals/C~anide (&!gill on site drinking water Barium 2.0 31.2 5000 well Calcium 10.0 23,400 I Copper 3.0 6.30 Iron 20.0 36.0 Lead 2.0 5.40 I Magnesium 30.0 13,100 Manganese 2.0 4.50 e Potassium 72.0 2190 I Sodium 50.0 11,200 Vanadium 3.0 4.00 Zinc 5.0 198
I TCL VOCs {l!g/1) Methylene Chloride 5 3 B,J 1, 1-Dichloroethene 5 2 J I Trichloroethene 5 3 J
TCL SVOCs I none detected
SS-32 Background surface TAL Metals/C~anide (mg/kg} I soil sample Aluminum 6.4 20,000 Arsenic 0.5 0.68 N,W Barium 0.5 78.3 I Beryllium 0.2 0.45 Calcium 2.5 1580 Chromium 1.5 57.1 Cobalt 1.0 20.7 I Copper 0.7 44.6 Iron 5.0 33,800 Lead 0.5 6.80 N Magnesium 7.4 7940 ••I 16 I I Table 6-1 (continued)
Analytical Results for Environmental Samples I e Winston Container Site
I Sample Analyte Groun (Units) Signi- Number Description Analyte Detection Level Result ficance MCL Remarks
I SS-32 (Continued) Manganese 0.5 447 Nickel 1.5 22.6 Potassium 17.8 2000 I Sodium 12.4 39.8 Vanadium 0.7 106 Zinc 1.2 37.5 I Cyanide 0.62 0.87 TCL VOCs (l!g/k:g} I Methylene Chloride 6 41 B TCL SVOCs (l!g/k:g) I 3 Semivolatile TICs J
SS-31 Composite surface soil TAL Metals/Cyanide (mg/k:g) I sample taken from drum Aluminum 6.0 12,900 ns storage area Antimony 5.5 71.2 1 N e Arsenic 0.5 4.40 ns N Barium 0.5 2030 3 I Cadmium 0.7 24.0 1 Calcium 2.3 22,300 3 Chromium 1.4 487 ns I Cobalt 0.9 78.9 ns Copper 0.7 7160 3 Iron 4.6 49,500 ns Lead 0.5 5740 3 N I Magnesium 6.9 5050 ns Manganese 0.5 564 ns Mercury 0.1 3.30 1 I Nickel 1.4 74.1 ns Potassium 16.6 2720 ns Selenium 0.7 7.60 1 N I Silver 1.2 26.1 1 Sodium 11.5 1960 3 Vanadium 0.7 38.1 ns Zinc 1.2 4650 3 I Cyanide 0.59 3.2 2
TCL SVOCs (l!g/k:g) I 1,2-Dichlorobenzene 3900 6300 ns 7900 8400 1 D,J Benzoic Acid 20,000 530 ns J 39,000 4700 ns D,J Phenanthrene 3900 430 ns J ••I 17 I I Table 6-1 (continued)
Analytical Results for Environmental Samples I e Winston Container Site
I Sample Analyte GroUQ (Units) Signi- Number Description Analyte Detection Level Result ficance MCL Remarks I SS-31 (Continued) Di-n-Butyl Phthalate 3900 25,000 1 7900 27,000 1 D Fluoranthene 3900 450 ns J I 7900 1000 ns D,J Butylbenzyl phthalate 3900 94,000 E 7900 100,000 1 F I Bis {2-Ethylhexyl) Phthalate 3900 47,000 1 7900 46,000 1 D Di-n-Octyl Phthalate 3900 4000 ns I 7900 1600 1 D,J 20 Semivolatile TICs J
I SS-31A TCL VOCs (l!g/kg) Methylene Chloride 6 14 ns B Acetone 12 57 1 I Toluene 6 9 ns Ethylbenzene 6 1 ns J Styrene 6 2 ns J e Total Xylenes 6 9 ns I 4 Volatile TICs J
I SS-33 Composite surface soil TAL Metals/Cyanide (mg/kg} sample from drum storage Aluminum 6.6 6450 ns area Antimony 6.1 68.3 1 N I Arsenic 0.5 5.50 1 N Barium 0.5 1100 3 Cadmium 0.8 10.4 1 Calcium 2.5 10,600 ns I Chromium 1.5 205 ns Cobalt 1.0 35.0 ns Copper 0.8 622 3 I Iron 5.0 72,200 ns Lead 0.5 1140 3 N,S Magnesium 7.6 3890 ns I Manganese 0.5 462 ns Mercury 0.1 2.90 1 Nickel 1.5 47.6 ns Potassium 18.2 1800 ns I Selenium 0.7 26.3 1 N,S Silver 1.3 21.6 1 Sodium 12.6 231 ns Vanadium 0.8 33.6 ns ••I 18 I I Table 6-1 (continued)
Analytical Results for Environmental Samples le Winston Container Site
I Sample Analyte Grou[! (Units) Signi- Number Description Analyte Detection Level Result ficance MCL Remarks I SS-33 (Continued) Zinc 1.3 931 3 I Cyanide 0.63 7.5 2 TCL SVOCs (l!g/kg) Phenol 4700 1400 OS ] I 4-Methylphenol 4700 730 OS ] Isophorone 4700 490 OS ] 2,4-Dimethylphenol 4700 570 OS ] I Benzoic Acid 24,000 2600 OS ] 94,000 2700 OS D,J Dimethyl Phthalate 4700 4700 OS 19,000 3700 OS D,J I Pentachlorophenol 24,000 1000 OS ] Di-n-Butyl Phthalate 4700 34,000 1 Fluorantbene 4700 640 ns ] I Butylbenzylpbthalate 4700 3700 OS ] 19,000 3300 OS D,J e Benzo (a) Anthracene 4700 610 ns ] Bis (2-Ethylbexyl) 4700 100,000 E I Phthalate 19,000 68,000 1 F Di-n-Octyl Phthalate 4700 1200 OS ] I 20 Semivolatile TICs J
SS-33A TCL VOCs (l!glkg) I Methylene Chloride 6 54 OS B Acetone 13 10 OS B,J
I SED-32 Background stream TAL Metals/Cyanide (mg/kg) sediment soil taken Aluminum 6.1 4010 from upstream in the Arsenic 0.5 1.00 N,W I creek Barium 0.5 63.2 Calcium 2.4 1440 Chromium 1.4 26.2 I Cobalt 0.9 8.20 Copper 0.7 13.3 Iron 4.7 8450 Lead 0.5 2.70 N I Magnesium 7.1 3160 Manganese 0.5 299 Nickel 1.4 11.1 Potassium 16.9 479 ••I 19 I I Table 6-1 (continued)
Analytical Results for Environmental Samples le Winston Container Site
I Sample Analyte Grou~ (Units} Signi- Number Description Analyte Detection Level Result ficance MCL Remarks I SED-32 (Continued) Sodium 11.8 22.90 Vanadium 0.7 22.60 I Zinc 1.2 15.5 TCL VOCs (ug/1} Methylene Chloride 7 43 B I Acetone 12 4 B,J
TCL SVOCs (j!gll} I 7 Semivolatile TICs J SED-31 Downstream sediment TAL Metals/C~anide (mg/kg} I sample from the creek Aluminum 6.4 4810 ns Arsenic 0.5 0.65 ns Barium 0.5 47.9 ns N I Calcium 2.4 1260 ns Chromium 1.5 25.1 ns Cobalt 1.0 14.7 ns Copper 0.7 16.7 ns Iron 4.9 10,800 ns •• Lead 0.5 4.70 ns N Magnesium 7.3 2660 ns I Manganese 0.5 319 ns Nickel 1.5 10.0 ns Potassium 17.6 909 ns I Sodium 12.2 28.7 ns Vanadium 0.7 26.5 ns Zinc 1.2 19.6 ns
I TCL VOCs (l!g/1} Methylene Chloride 6 32 ns B I Acetone 13 16 ns B TCL SVOCs (l!g/1} Benzoic Acid 2200 68 ns J I 4-Nitrophenol 2200 48 ns J Pyrene 430 53 ns J Benzo (a) Antracene 430 47 ns J Chrysene 430 48 ns J I Bis {2-Ethylhexyl) Phthalate 430 500 ns 11 Semivolatile TICs J ••I 20 I I Table 6-1 (continued)
Analytical Results for Enviromnental Samples le Winston Container Site I Significance (Ref. 23): I 1 - Analyte was not detected in the background sample. Concentration in subject sample was C::3 times (organics and cyanide) or C:: 10 times (inorganics) the detection limit of the background sample.
2 - Background concentration was C::the detection limit, but <2 times the detection limit. Concentration in subject I sample was C::3 times (organics and cyanide) or 10 times (inorganics) the background concentration or C::4 times (organics and cyanide) or C:: 10 times (inorganic) sample the detection limit of the background, whichever is less.
I 3 - Background concentration was C::2 times the detection limit. Concentration in subject sample was C::2 times (organics and cyanide) or C:: 10 times (inorganics) the background concentration. I ns - Not significant, according to conditions necessary to document an observed release. I Remarks: B - Analyte is found in associated blank as well as in sample. Indicates possible/probable blank contamination. E - Compound whose concentration exceeds the calibration range of the instrument for that analysis. The sample was I diluted and re-analyzed according to specification. F - Concentration at the secondary dilution factor . J - Estimated value. N - Spiked sample recovery not within control limits. S - The reported valve was determined by the Method of Standard Additions (MSA). •• W - Post digestion spike for Furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance. I X - Coeluting compounds. * - Duplicate analysis not within control limits. I I I I I
••I 21 I I le 7.0 TOXICOLOGICAL AND CHEMICAL CHARACTERISTICS The toxicological and chemical characteristics of acetone, antimony, arsenic, barium, cadmium, calcium, chromium, copper, butylbenzyl phthalate, bis (2-ethylhexyl) phthalate, I Di-n-butylphthalate, lead, mercury, selenium, silver, sodium, zinc, and cyanide are I presented on the following pages (Ref. 18). I I I I I •• I I I I I I
••I 22 I I 25 ACETONE ABC750
SYNS: SYNS: ACETIC ACID-2,6-DIME11lYL-m- 2,6-DIMETIIYL-m-DIOXAN-4-0L ACETON (GERMAN, D\TTCH, POL- ME11lYL KETONE ~ DIOXAN-4-YL ESTER ACETATE ISll) PROPANONE ACETOMETIIOXAN 2,6-DIME11lYL-m-DIOXAN-4-YL DIMETIIYLFORMALDEHYDE 2-PROPANONE 6-ACETOXY -2,4-DIMETIIYL-m-DI· ACETATE DIMETIIYLKETAL PYROACETIC ACID I OXANE DIOXIN (BACTERICIDE) (OBS.) DIMIITHYL. KIITONE PYROACETIC liTHER DOOA GIV GARD DXN KETONE PROPANE RCRA WASTE NUMBER U002
DIMETHOXANB NCI-CS6213 ~-KETOPROPANE TOXICITY DATA: CODEN: TOXICITY DATA: CODEN: I mma-sat 5500 JLg/plate ENMUDM 8(Suppl skn-rbt 500 mg/24H MLD 28ZPAK -,42,72 7),1,86 eye-rbt 100 mg/24H MOD 28ZPAK -,42,72 sln-dmg-par I pph ENMUDM 7,677,85 cyt-smc 200 mmolltube HEREAY 33,457,47 orl-rat TDLo:948 g/kg/88W-I: JNCIAM 53,791,74 sln-smc 47600 ppm ANYAA9 407,186,83 I CAR cyt-ham:fbr 40 g/L FCTOD7 22,623,84 3 orl-rat LD50: 1930 mg/kg GCTB** 3125171 ihl-mam TCLo:31500 JLg/m / GTPZAB 26(6),24,82 24H (1-130 prcg):REP IARC Cancer Review: Animal Limited Evidence IMEMDT orl-man TDLo: 2857 mg/kg 34ZJAG -,64,69 I 15,177,77 orl-man TDLo:2857 mg/kg DIAEAZ 15,810,66 ivn-rat LD50:5500 mg/kg NPIRI* 1,1,74 THR: An experimental carcinogen. Moderately toxic by ihl-man TDLo:440 JLg/m 3/6M GISAAA 42(8)42, 77 ingestion. See also ESTERS. When heated to decomposi ihl-man TDLo: 10 mg/m3/6H GISAAA 42(8)42, 77 I tion it emits acrid smoke and fumes. orl-mus LD50: 3000 mg/kg PCJOAU 14,162,80 eye-hmn 500 ppm JIHTAB 25,282,43 skn-rbt 395 mg open MLD UCDS** 517170 cyc-rbt 3950 JLg SEV AJOPAA 29,1363,46 I ihl-hmn TCLo:500 ppm:EYE JIHTAB 25,282,43 ABCSOO HR:2 ihl-man TCLo: 12000 ppm/4H: AOHYA3 16,73,73 2'-ACETONAPHTHONE CNS I CAS: 93-08-3 NIOSH: AL 2988000 unk-man LDLo: 1159 mg/kg 85DCA1 2,73,70 mf: Ca2H100 mw: 170.22 ihl-rat LCLo: 16000 ppmi4H AIHAAP 23,95,62 ipr-rat LDLo:500 mg/kg JPPMAB 11,150,59 3 SYNS: ihl-mus LCLo: 110000 mg/m / AGGHAR 5,1 ,33 , ORANGE CRYSTALS METIIYL-JJ-NAPIITHYL KETONE 62M ~-ACETONAPimiALBNB METIIYL-2-NAPIITHYL KETONE ipr-mus LDSO: 1297 mg/kg SCCUR* -,1,61 ~-ACETYLNAPimtALBNE ~-METIIYL NAPIITIIYL KETONE orl-dog LDLo:24 g/kg AEXPBL 18,218,1884 2-ACETYLNAPJmiALENE 1-(2-NAPimiALENYL)ETIIANONE ipr-dog LDLo:8 g/kg AEXPBL 18,218,1884 I ACETONAPlfiTIONE ~-NAPIITHYL METHYL KETONE scu-dog LDLo:5 g/kg AEXPBL 18,218,1884 ~-ACETONAPIITHONE 2-NAPlmiYL METHYL KETONE skn-rbt LD50: 20 g/kg UCDS** 517170 2-ACETONAPimiONE scu-gpg LDLo: 5000 mg/kg AGGHAR 5,1,33 TOXICITY DATA: CODEN: On Community Right To Know List. Reported in EPA I skn-hmn 500 mg/24H FCTXAV 13,681,75 TSCA Inventory. orl-mus LD50:599 mg/kg MDZEAK 8,244,67 OSHA PEL: TWA 1000 ppm I Reported in EPA TSCA Inventory. ACGIH TLV: TWA 750 ppm; STEL 1000 ppm THR: Moderately toxic by ingestion. A human skin irritant. DFG MAK: 1000 ppm (2400 mgtm3) When heated to decomposition it emits acrid smoke and NIOSH REL: TWA 590 mg!m3 I fumes. DOT Classification: Flammable Liquid, Label: Flammable Liquid
THR: Moderately toxic by various routes. A skin and severe I ABC750 HR: 2 eye irritant. Human systemic effects by inhalation: changes ACETONE in EEG, changes in carbohydrate metabolism, nasal effects, CAS: 67-64-1 NIOSH: AL 3150000 conjunctiva irritation, respiratory system effects, nausea and I DOT: 1090 vomiting, and muscle weakness. Human systemic effects mf: C3H60 mw: 58.09 by ingestion: coma, kidney damage, and metabolic changes. PROP: Colorless liquid, fragrant mint-like odor. Mp: Narcotic in high concentration. In industry, no injurious I -94.6°, bp: 56.48°, ulc: 90, flash p: 0°F (CC), lei: 2.6%, effects have been reported other than skin irritation resulting ue1: 12.8%, d: 0.7972@ 15°, autoign temp: (color) 869°F, from its defatting action, or headache from prolonged inha vap press: 400 mm@ 39S, vap d: 2.00. Mise in water, lation. A common air contaminant. Dangerous disaster haz I- ale, and ether. ard due to fire and explosion hazard; can react vigorously I I ABDOOO ACETONE CHLOROFORM 26
with oxidizing materials. Potentially explosive reaction with TOXICITY DATA: CODEN: nitric acid + sulfuric acid; bromine trifluoride; nitrosyl chlo ipr-mus LD50: 125 mglkg NTIS** AD277-689 ride + platinum; nitrosyl perchlorate; chromyl chloride; Reported in EPA TSCA Inventory. thiotrithiazyl perchlorate; and 2,4,6-trichloro-1 ,3,5-triazine '- THR: Poison by intraperitoneal route. When heated to de 1 + water. Reacts to form explosive peroxide products with 2-methyl-1 ,3-butadiene; hydrogen peroxide; and peroxomo composition it emits acrid smoke. nosulfuric acid. Ignites on contact with activated carbon; chromium trioxide; dioxygen difluoride + carbon dioxide; I ABDSOO HR:3 and potassium-tert-butoxide. Reacts violently with bromo ACETONE DIETHYLSULFONE form; chloroform + alkalies; bromine; and sulfur dichlo CAS: 115-24-2 NIOSH: TX 3850000 ride. Incompatible with CrO; (nitric + acetic acid); NOCI; mf: C7H160 4S2 mw: 228.35 I nitryl perchlorate; permonosulfuric acid; NaOBr; (sulfuric acid + potassium dichromate); (thio-diglycol + hydrogen PROP: D: l.l83, mp: 12r-t28°, bp: 300° (sl decomp), peroxide); trichloromelamine; air; HN03; chloroform; and Sol in water, ale, and ether. H S0 • To fight fire, use C0 , dry chemical, alcohol foam. I 2 4 2 SYNS: For further information see Vol. 4, No. 3 of DPIM Report. ACETONE BIS(ETHYL SULFONE) PROPANE DIETJIYL SULFONE 2.2-DIS(ETIIYLSULFONYL)PRO- SULFONAL PANE SULFONMETHANE I ABDOOO JJR:J I>UmJYISlJLI'ONDIMETIIYL ACETONE CHLOROFORM MIITIIANE CAS: 57-15-8 NIOSH: UC 0175000 TOXICITY OATA: CODEN: I mw: 177.46 unk-man LDLo: 147 mg/kg 85DCAI 2,73,70 or1-dog LDLo:800 mglkg 12VXA5 8,1003,68 PROP: Crystals, camphor odor. Mp: 97°, bp: 167°. orl-rbt LDLo:3000 mg/kg HBAMAK 4,1404,35 HBAMAK 4,1404,35 SYNS: orl-gpg LDLo: 8500 mglkg I CJIL.ORETONE CHLORBUTANOL THR: A human poison by unspecified route. Moderately Cl..ORTRAN CIILORBUTOL toxic by ingestion. Mutagenic data. When heated to decom METJIAFORM CHLOROBUTANOL position it emits toxic fumes of SO.r. , SEOAFORM TRICIILORO-ten-BUTYL ALCOIIOL p,f3,f3-TRICIILORO-tert-BUTYL AL- tert-TRJCHL.OROBUTYL ALCOHOL COIIOL 1.1.1-TRJCIILOR0-2-METHYL-2- HCP PROPANOL ABD750 HR:J ANHYDROUS CHLOROBUTANOL ACETONE OIL I NIOSH: AL 6700000 TOXICITY DATA: CODEN: DOT: 1091 mmo-sat 20 ~mollplate MUREAV 90,91,81 cyt-smc 10 mmolltube HEREA Y 33,457,47 PROP: (a) Standard: light, lemon-yellow. (b) Refined: al I skn-rbt 850 ~g MLD XEURAQ MDDC-1715 most water white. (c) Heavy: dark, orange-yellow. Bp: eye-rbt 9180 ~g/30S MLD XEURAQ MDDC-1715 orl-dog LDLo:238 mg/kg AIPTAK 8,77,01 (a) 75-160°, (c) 80-225°. D: (a) 0.826-0.830, (b) 0.812, orl-rbt LDLo:213 mglkg AIPTAK 8,77,01 (c) 0.885-0.865. I par-frg LDLo:800 mglkg AIPTAK 8,77,01 DOT Classification: Aammable Liquid, Label: Aammable Reported in EPA TSCA Inventory. Liquid I THR: Poison by ingestion. Moderately toxic by parenteral THR: Dangerous fire and explosion hazard when exposed route. A narcotic. A skin and eye irritant. Mutagenic data. to heat or flame. Can react vigorously with oxidizing materi See also CHLORAL HYDRATE, which acts similarly. als. Some carcinogenic activity. To fight fire, use C02, Dangerous; can react with oxidizing materials. Combustible dry chemical. I when exposed to heat or flame. When heated to decomposi tion it emits toxic fumes of Cl-. See also PHOSGENE. ABEOOO HR:J I ACETONE PEROXIDE ABD250 HR:J PROP: Liquid. The trimeric form is crystalline. Mp: 97°. ACETONE DIETHYL KETAL THR: No toxicity data. See PEROXIDES, ORGANIC. ·I CAS: 126-84-1 NIOSH: AL 4900000 Aammable by spontaneous chemical reaction; can react mf: C,H,602 mw: 132.23 vigorously with reducing materials. The trimeric form is SYNS: shock-sensitive and static-electricity-sensitive and may de I' 2,2-0IETI IOXYPROPANE USAF 00-44 tonate. I I 277 ANTIMONY AMMONIA TRIACETIC ACID AOCOOO
L SYNS: Antimony and its compounds are on the Community Right w ANTIBIOTICUM PA147 cGERMANI 3-CARBOXY-2.4-PENT AOIENAL· To Know List. LACTOL THR: Mutagenic data. See also ANTIMONY COM TOXICITY DATA: CODEN: POUNDS. When heated to decomposition it emits toxic I ivn-mus LDLo:250 mg/kg ARZNAD 17,693,67 fumes of Sb and Na 0. unk-mus LD50:20 mg/kg ARZNAD 17,693,67 2 THR: Poison by intravenous and other unspecified routes. I When heated to decomposition it emits acrid smoke and AQB750 HR:J irritating fumes. ANTIMONY CAS: 7440-36-0 NJOSH: CC 4025000 DOT: 2871 I APYSOO HR:3 mf: Sb mw: 121.75 ANTIBIOTIC 6640 SULFATE CAS: 53776-71-9 NIOSH: WK 1940000 PROP: Silvery or gray, lustrqus metal. Mp: 630°, bp: 1635°, ,I mf: C,9H3,Ns0,•512H204S mw: 545.69 d: 6.684 @ 25°, vap press: I mm@ 886°. Insol in water, sol in hot concentrated H2S04 • t SYNS: EXTRAMYCIN RICKAMICIN SULFATE SYNS: MENSISO SISOMICIN SULFATE ANTIMONY BLACK C.l. 71050 !II PATHOMYCIN SISOMIN ANTIMONY REGULUS STIBIUM I ANTYMON ti'OJ.ISIIt TOXICITY DATA: CODEN: .... scu-rat LD50:500 mg/kg NIIRDN 6,320.82 TOXICITY DATA: CODEN: I ivn-rat LD50:49 mg/kg NIIRDN 6,320,82 unk-man LDLo: 15 mg/kg 85DCAI 2,73,70 IMS-RAT LD50:404 mgtkg NIIRDN 6,320,82 ipr-rat LDLo: 100 mg/kg INMEAF 10(2),15.41 .... ipr-mus LD50:221 mg/kg 12VXA5 9,1105,76 ipr-gpg LDLo: 150 mg/kg INMEAF 10(2),15.41 scu-mus LD50:272 mgtkg NIIRDN 6.320,82 I ivn-mus LD50:37 mg/kg KZKEDZ 4,107,78 Antimony and its compounds are on the Community Right ims-mus LD50:280 mg/kg NIJRDN 6,320,82 To Know List. Reported in EPA TSCA Inventory. ..THR: Poison by intravenous, intramuscular, intraperitoneal OSHA PEL: TWA 500 f.l.g(Sb)tm 3 rand subcutaneous routes. See also SULFATES. When ACGIH TLV: TWA 0.5 mg(Sb)tm3 heated to decomposition it emits very toxic fumes of SO, DFG MAK: 0.5 mg(Sb)/m3 and NOx. NIOSH REL: TWA 0.5 mg(Sb)/m3 I DOT Classification: Poison B •• AQBOOO HR: 3 THR: A human poison lly an unspecified route. An experi ANTIIIELMYCIN mental poison lly intraperitoneal and possibly other routes. CAS: 31282-04-9 NIOSH: WK 2130000 I Sec also ANTIMONY COMPOUNDS. Moderate fire and mf: C:wH ,N3013 mw: 527.60 3 explosion hazard in the forms of dust and vapor, when SYNS: exposed to heat or flame. See also POWDERED METALS. I HYGROMIX-8 HYGROMYCIN B For further information, see Vol. 2, No. I of DPIM Report. TOXICITY DATA: CODEN: When heated or on contact with acid, emits toxic fumes ipr-rat LD50:63 mgtkg GISAAA 38,11,73 of SbH3, electrolysis of acid sulfides and stirred Sb halide I ipr-gpg LD50: 13 mg/kg GISAAA 38,11,73 yields explosive Sll. It can react violently with NH 4N03; halogens; BrN ; BrF ; HCI0 ; CIO; CIF ; HN0 ; KN0 ; THR: Poison by intraperitoneal route. When heated to de 3 3 3 3 3 3 KMn0 ; K:!0 ; NaN0 ; oxidants. I composition it emits toxic fumes of NO,. 4 1 3 AQB250 HR: D AQCOOO HR: 3 ANTIMONIC ACID, SODIUM SALT ANTIMONY AMMONIA TRIACETIC ACID I CAS: Ill 12-10-0 NIOSH: CC 3065000 CAS: 72017-60-8 NIOSH: AF 5810000 mf: C 1:!H 14N10 11Sb•2H10 mw: 536.07 SYNS: SODIUM ANTIMONATE SODIUM POLY ANTIMONATE SYN: AT,\·S~ SODIUM ANTIMONY I TOXICITY DATA: CODEN: .OXICITY DATA: CODEN: ivn-hmn TDLo:9 mg/kg/150-1: XPHPAW 411,158,74 cyt-hmn:tbr I nmoi/L AEMBAP 91,117.78 SYS I cyt-hmn:leu I nmol/L AEMBAP 91,117.78 ipr-mus LD50:62 mg/kg XPHPAW 441.131,74 I I ARA750 ARSENIC 298 ARA750 HR:J fumes; can react vigorously on contact with oxidizing mate ARSENIC rials. Incompatible with bromine azide; dirubidium acety CAS: 7440-38-2 NIOSH: CG 0525000 lide; halogens; palladiuqt; zinc; platinum; NCI 3; AgN03; Cr0 ; Na 0 ; hexafluoro isopropylideneamino lithium. For ~ DOT: 1558 3 2 2 af: As aw: 74.92 further information, see Vol. 4, No. 1 of DPIM Report. I PROP: Silvery to black, brittle, crystalline and amorphous ARBOOO HR:J metalloid. Mp: 814°@ 36 atm, bp: subl@ 612°, d: black m-ARSENIC ACID crystals 5.724@ 14°; black amorphous 4.7, vap press: I CAS: 10102-53-1 NIOSH: CG 0760000 I mm @ 372° (sublimes). Insol in water; sol in HN03• See mf: AsH0 mw: 123.93 also ARSENIC VAPOR. 3 SYN: METAARSENIC ACtO SYNS: I ARSEN (GERMAN, POUSH) COLLOIDAL ARSENIC Reported in EPA TSCA Inventory. Arsenic and its com ARSENICALS GREY ARSENIC ARSENIC-?$ METALLIC ARSENIC pounds are on the Community Right To Know List. ARSENIC BLACK OSHA PEL: TWA 0.01 mg(As)/m3 I 3 TOXICITY DATA: CODEN: ACGIH TLV: TWA 0.2 mg(As)/m 3 cyt-mus-ipr 4 mg!kg/48H-I EXPEAM 37,129,81 NIOSH REL: CL 2 J.Lg(As)/m /15M orl-rat TOLo:605 J.Lg/kg (35 W GISAAA (8)30,77 I preg):REP THR: See ARSENIC COMPOUNDS. When heated to de orl-mus TOLo: 120 mg/kg TJAOAB 15,3JA,77 composition it emits toxic fumes of As. (preg):TER ipr-mus TDLo:40 mg/kg (preg): TJAOAB 15,3JA,77 ARB250 HR:J I TER o·ARSENIC ACID imp-rbt TDLo:75 mglkg:ETA ZEKBAI 52,425,42 orl-man TOLo: 7857 mg/kg/55Y: CMAJAX 120,168,79 CAS: 7778-39--4 NIOSH: CG 0700000 SKN DOT: 1553/1554 I orl-man TOLo:7857 mglkg/55Y: CMAJAX 120,168,79 mf: AsH30 4 mw: 141.95 GIT ims-rat LDLo: 20 mg/kg NCIUS* PH 43-64- SYNS: 886,SEPT,70 ACIDE ARSENIQUE UQUIDE HI-YIELD DESSICA!In' H-10 scu-rbt LOLo:300 mglkg ASBIAL 24,442,38 DOT Classification: Poison B, Label: Poison THR: A poison. See also ARSENIC COMPOUNDS and BROMIDES. When heated to decomposition it emits very NIOSH REL: CL 2 J.Lg(As)/m3/15M \ toxic fumes of As and Br-. For further infonnation, see I THR: A poison. See also ARSENIC COMPOUNDS. Arsenic Tribromide, Vol. 2, No. 3. of DPIM Report. ARE750 HR:J ARFSOO HR:J ARSENICAL FLUE DUST (DOT) ARSENIC CHLORIDE NIOSH: CG 1340000 CAS: 7784-34-1 NIOSH: CG 1750000 I DOT: 1560 Arsenic and its compounds are on the Community Right mf: AsCI mw: 181.28 To Know List. 3 PROP: Colorless, oily liquid. D: 2.15 @ 25°, mp: -16°, I OSHA PEL: TWA 0.01 mg(As)/m3 bp: 130°. Decomp in water and by UV light~ mise in chloro ACGIH TLV: TWA 0.5 mg(As)/m3 fonn, CCI , ether, iodine, P, S, alkali iodides, oils and 3 4 NIOSH REL: CL 2 J.Lg(As)/m /l5M fats. Vap d: 6.25, vap press: 10 mm @ 23S. I DOT ClaSsification: Poison B, Label: Poison SYNS: THR: Poison by inhalation and ingestion. See also AR ARSENOUS TRICHLORIDE (9CI) CHLORURE ARSENIEUX TRICHLOROARSINE (FRENCH> SENIC COMPOUNDS. I ARSENIC BUTI'ER CHLORURE D" ARSENIC (FRENCH) ARSENIC(III) CHLORIDE FUMING LIQUID ARSENIC ARFOOO HR:J ARSENIOUS CIILORIDE TRICHLORURE D"ARSENIC ARSENIC BISULFIDE ARSENOUS CIILORIDE (FRENCH> I mf: As2S2 mw: 214 TOXICITY DATA: CODEN: PROP: Red-brown crystals. Bp: 565°, mp: p = 307°, d: cyt-hmn: leu 600 nmol!L MUREAV 88,73,81 a = 3.506 @ 19°, J3 = 3.254 @ 19°. mrc-bcs 30 11-Udisc MUREAV 77,109,80 otr-ham:emb 3 IJ.rnol/L CNREAS 39,193,79 I ihl-mus LCLo:338 ppm!IOM HBTXAC 1,324,56 SYNS: 3 ARSENIC SULFIDE REALOAR ihl-cat LCLo: 100 mglm /IH ZGEMAZ 13,523,21 Arsenic and its compounds are on the Community Right Reported in EPA TSCA Inventory. Arsenic and its com To Know List. pounds are on the Community Right To Know List. EPA Extremely Hazardous Substances List. • THR: A poison. See also ~RSENIC COMPOUNDS and 3 SULFIDES. Flammable in the fonn of dust when exposed OSHA PEL: TWA 0.01 mg(As)tm I 3 to heat or flame. Explosion hazard when intimately mixed ACGIH TLV: TWA 0.2 mg(As)/m NIOSH REL: CL 2 J.Lg(As)/m3/l5M with powerful oxidizers such as Cl2; KN03; chlorates. It will react with water or steam to produce toxic and flamma DOT Classification: Poison B, Label: Poison I ble vapors. THR: A poison via inhalation. See also ARSENIC COM ARF250 HR:J POUNDS and CHLORIDES. Very poisonous; fumes in I ARSENIC(III) BROMIDE air. Mutagenic test data. When heated to decomposition it CAS: 7784-33-0 NIOSH: CG 1375000 emits very toxic fumes of As and Cl-. Highly reactive. DOT: 1555 Explodes with Na; K; AI on impact. mf: AsBr mw: 314.65 I 3 ARF750 HR:J PROP: Colorless, rhombic crystals. Mp:32.8°, bp: 220.0°, ARSENIC COMPOUNDS • · vap press: l mm@ 41.8°, d: 3.3972@ 25°, (liq), 3.3282. SYN: ARSENICALS I SYNS: ARSENOUS TRIBROMIDB ARSENIC TRIBROMIDB Arsenic and its compounds are on the Community Right 11UBROMOARSINB ARSENOUS BROMIDE To Know List. I Reported in EPA TSCA Inventory. Arsenic and its com Used as insecticides, herbicides, silvicides, defoliants, de pounds are on the Community Right To Know List. siccants and rodenticides. Poisoning from arsenic com pounds may be acute or chronic. Acute poisoning usually OSHA PEL: TWA 0.01 mg(As)tm3 results from swallowing arsenic compounds; chronic poi ACGIH TLV: TWA 0.2 mg(As)/m3 soning from either swallowing or inhalaling. Acute allergic NIOSH REL: CL 2 J.L&(As)/m3/15M reactions to arsenic compounds used in medical therapy DOT Classification: Poison B, Label: Poison have been fairly common. The type and severity of reaction I I 303 ARSENIC IODIDE MIXED WITH MERCURIC IODIDE ARHOOO depending upon the compound of arsenic. Inorganic arseni Arsenic and its compounds are on the Community Right cals are more toxic than organics. Trivalent is more toxic To Know List. than pentavalent. Acute arsenic poisoning (from ingestion) THR: Poison by inhalation and ingestion. See also AR results in marked irritation of the stomach and intestines SENIC COMPOUNDS. Flammable. Evolves dangerous with nausea, vomiting, and diarrhea. In severe cases, the fumes of As when heated. I vomitus and stools are bloody and the patient goes into collapse and shock with weak, rapid pulse, cold sweats, ARGSOO coma, and death. Chronic arsenic poisoning, whether HR:J I through ingestion or inhalation, may manifest itself in many ARSENIC HEMISELENIDE different ways. There may be disturbances of the digestive mw: 228.78 system such as loss of appetite, cramps, nausea, constipa Arsenic compounds and its compounds as well as selenium I tion, or diarrhea. Liver damage may occur, resulting in and its compounds are on the Community Right To Know jaundice. Disturbances of the blood, kidneys, and nervous List. system are not infrequent. Arsenic can cause a variety of skin abnormalities including itching, pigmentation, and THR: See ARSENIC COMPOUNDS and SELENIUM COMPOUNDS. When heated to decomposition it emits I even cancerous changes. A characteristic of arsenic poison fumes of As and Se. Incompatible with oxidizing materials. ing is the great variety of symptoms that can be produced. When heated to decomposition it emits highly toxic fumes A recognized carcinogen of the skin, lungs, liver. An ex of Se and As. I perimental carcinogen of the mouth, esophagus, larynx, bladder and para nasal sinus. Dangerous; when heated to decomposition, or when metallic arsenic contacts acids ARG750 HR:J or acid fumes, or when water solutions of arsenicals are in ARSENIC IODIDE I CAS: 7784-45-4 contact with active metals such as Fe; AI; Zn; they emits NIOSH: CG 1950000 highly toxic fumes of arsenic. For further information, see DOT: 1557 Vol. 1, No. 3 of DPIM Report. mf: Asi3 mw: 455.62 I In treating acute poisoning from ingestion BAL (dimer PROP: Red hexagonal crystals. Mp: 141.8°; bp: 403°; d: captol) is of questionable effectiveness for acute and chronic 4.38@ 13°. Solubility: in water= 6/100@ 25°, in CS 2 poisoning with trivalent arsenicals, such as As trioxide, = 5.2/100. arsine and arsenites. It is of no value for pentavalent arseni cals, such as cacodylic acid, methanearsonic acid, sodium, SYNS: ARSENIC TRIIODIDE ARSENOUS TRIIODIDE (9CI) cacodylate, MSMA, DSMA, arsanilic acid, arsenic acid, ARSENOUS IODIDE TRIIODOARSINE and arsenates. Vomiting and gastric lavage are the preferred I emergency treatments for acute arsenical poisoning. Mod Reported in EPA TSCA Inventory. Arsenic and its com em medical treatment of arsenical poisoning uses exchange pounds are on the Community Right To Know List. . transfusion and dialysis (A. E. De Palma, J. Occup Med., OSHA PEL: TWA 0.01 mg(As)/m3 I Vol. 11,582-587 (1969). Note: Arsenic compounds are ACGIH TLV: TWA 0.2 mg(As)/m3 common air contaminants. NIOSH REL: CL 2 J.Lg(As)/m3/15M ARGOOO HR:J DOT Classification: Poison B, Label: Poison I ARSENIC DIETHYL mf: [As(C2Hsh mw: 266.2 THR: A poison. See also ARSENIC COMPOUNDS and IODIDES. Can form a shock sensitive compound with so I PROP: Liquid or oil. Bp: 185°-190°, d: about I. dium or potassium. When heated to decomposition it emits Arsenic and its compounds are on the Community Right very toxic fumes of 1- and As. To Know List. ARHOOO HR:J I THR: A poison. A dangerous fire hazard by spontaneous ARSENIC IODIDE MIXED WITH MERCURIC chemical reaction. Dangerous when heated. Incompatible IODIDE with oxidizing materials. See also ARSENIC COM CAS: 8012-54-2 NIOSH: CG 1955000 I POUNDS. PROP: A 100 mL solution contains 0.9 to 1.0 g arsenic ARG250 HR:J iodide and 1.05 g mercuric iodide (27ZTAP 3,62,69). ARSENIC DIMETHYL mf: lA:s(CH3h mw: 210.0 SYN: DONOVAN"S SOLU110N PROP: Colorless to yellow oily liquid. Mp: -6°; bp: 186°; Arsenic and its compounds, as ·well as mercury and its d: 1.15. compounds, are on the Community Right To Know List. I I BAG500 BARBITURATES 340 BAGSOO HR:3 BAHSOO HR:3 BARBITURATES BARIUM ACETATE CAS: 543-80-6 NIOSH: AF 4550000 SYNS: I \. mw: 255.44 BARBITAL DERIVATIVES OF BARBITURIC I BARBITAL SODIUM ACID, I.E. PROP: White crystals. Water-sol. BARBITONE SYNS: are THR: Salts or derivatives of barbituric acid. They cen ACE11C ACID, BARIUM SALT OCfAN BARNATY (CZECH) tral nervous system depressants and are used as hypnotics, BARIUM DIACETATE I sedatives and anesthetics. Usually administered orally. They are strongly habit forming. Several compounds includ TOXICITY DATA: CODEN: ing amo-, seco-, and pentabarbital are restricted chemicals. orl-rat LDS0:921 mglkg MarJV# 29MAR77 ivn-mus LDSO: 11 mg/kg TXAPA9 22,150,72 I Their use can cause a reaction called barbiturism which is orl-rbt LDLo:236 mglkg EQSSDX 1,1,75 marked by chills, headache, fever, and cutaneous eruptions. scu-rbt LDLo:96 mglkg EQSSDX 1,1,75 See BARBITAL SODIUM. ivn-rbt LDLo: 12 mglkg EQSSDX 1,1,75 I Reported in EPA TSCA Inventory. Barium and its com I BAG750 HR: 1 pounds are on the Community Right To Know List. BARBITURIC ACID mf: C4H403N2 mw: 128.1 OSHA PEL: TWA 500 ppm I ACGIH TLV: TWA 0.5 mg(Ba)/m3 PROP: Crystals or white to yellow-white powder, mp: 245°, bp: 260° (decomp). THR: Poison via ingestion, intravenous and subcutaneous I. THR: Mildly toxic. Irritating to skin, eyes and mucous routes. When heated to decomposition it emits acrid smoke membranes. An allergen. Has no hypnotic properties. Com and fumes. See also BARIUM COMPOUNDS. bustible. I BAH250 HR:3 BAH750 HR:3 BARIUM BARIUM ACETYLIDE CAS: 7440-39-3 NIOSH: CA 8370000 CAS: 12070-27-8 DOT: 1399/140011854 mf: C2Ba mw: 161.35 af: Ba aw: 137.36 Barium and its compounds are on the Community Right -- PROP: Silver-white, sltly lustrous, somewhat malleable To Know List. metal. Mp: 725°, bp: 1640°, d: 3.5 @ 20°, vap press: 10 1 Ignites on contact with vapors of water or ethanol in air. mm@ 1049°. Incandescent reaction when heated with: hydrogen @ Reported in EPA TSCA Inventory. Community Right To 150°C; chlorine @ I40°C; bromine @ 130°C; iodine @ Know List. 12rc; and selenium@ 150°C. See also BARIUM COM I ACGIH TLV: TWA 0.5 mglm3 POUNDS and ACETYLIDES. DFG MAK: 0.5 mg/m3 ·' ' I DOT Classification: Some barium compounds are flamma- BA/000 HR:3 ble or explosive BARIUM AZIDE CAS: 18810-58-7 NIOSH: CQ 8500000 THR: See BARIUM COMPOUNDS. Water and stomach DOT: 0224 I acids solubilize barium salts and can cause poisoning. mw: 221.40 Symptoms are vomiting, colic, diarrhea, slow irregular pulse, transient hypertension, and convulsive tremors and PROP: Monoclinic prisms. Mp: -N2 @ about 120°, bp: I muscular paralysis. Death may occur from a few hours to explodes, d: 2.936. a few days. Half-life of barium in bone has been estimated SYN: BARIUM AZIDE, dry or containinsless than 50'Io w11er <000 at 50 days. Dust is dangerous and explosive when exposed I to heat, flame, or chemical reaction. Violent or explosive Reported in EPA TSCA Inventory. Barium and its com reaction with water; CC14; ftuorotrichloromethane; trichlo pounds are on the Community Right To Know List. roethylene; and C Cl • Incompatible with acids; C2Cl F ; 2 4 3 3 OSHA PEL: TWA 0.5 mg(Ba)/m3 C H FC1 ; C HC1 and water; 1,1 ,2-trichloro triftuoro eth 2 2 3 2 3 ACGIH TLV: TWA 0.5 mg/(Ba)m3 ane; and ftuorotrichloroethane. The powder may ignite or explode in air or other oxidizing gases. For further informa DOT Classification: Class A Explosive; Label: Explosive ~ tion, see Vol. 3, No. 4 of DPIM Report. A and Poison I 1343 BARIUM FERRITE BAL625 I!_!OP: Heavy, yellow, crystalline powder. D: 4.498 @ Reported in EPA TSCA Inventory. Cyanide and its com pounds, as well as barium and its compounds, are on the ~s- Community Right To Know List. BARIU~ CHROMATE (I: I) C.l. PIOMEI'IT YELLOW 31 OSHA PEL: TWA 0.5 mg(Ba)/m3 1BARIUM CHROMATE OXIDE LEMON CHROME ACGIH TLV: TWA 0.5 mg(Ba)/m3 BARYTA YELLOW LEMON YELLOW CHROMIC ACID, BARIUM SALT PERMANEI'IT YELLOW DOT Classification: Poison B, Label: Poison (1:) STEINBUHL YELLOW I C.l. 77103 . ULTRAMARINE YELLOW THR: A deadly poison. See also CYANIDE and BARIUM COMPOUNDS (SOLUBLE). When heated to decomposi TOXICITY DATA: CODEN: tion it emits toxic fumes of CN-. For further information, sce-ham:ovr 100 j.Lg/L MUREAV 156,219,85 I see Vol. 3, No. 4 of DP/M Reports. IARC Cancer Review: Animal Inadequate Evidence IMEMDT 2,100,73; Human Sufficient Evidence IMEMDT BALOOO HR:3 23,205,80. Reported in EPA TSCA Inventory. Barium and BARIUM CY ANOPLATINITE its compounds are on the Community Right To Know List. 1 mf: BaPt(CN)4•4H20 mw: 508.6 3 3 OSHA PEL: TWA 0.1 mg (C30 3)m ; 0.5 mg(Ba)/m PROP: (a) Monoclinic, yellow crystals; (b) rhombic crys ACGIH TLV: TWA 0.5 mg(Ba)/m3; 0.05 mg(Cr)/m3; Hu tals. Mp: loses 2H20 @ 100°; d: (a) 2.076, (b) 2.085. I man Carcinogen NIOSH REL: TWA 0.001 mg(Cr(VI))/m3 Cyanide and its compounds, as well as barium and its com pounds, are on the Community Right To Know List...... _ I THR: A poison. A human carcinogen. Mutagenic data. For fire hazard, see CHROMATES. It reacts vigorously THR: A poison. See also BARIUM COMPOUNDS (SOL with reducing materials. See also BARIUM COMPOUNDS UBLE); CYANIDE; and PLATINUM COMPOUNDS...... (SOLUBLE) and CHROMIUM COMPOUNDS. Used in When heated to decomposition it emits highly toxic fumes I pyrotechnics and as an explosive initiator . of CN- and NOx. ..J:!SOO HR: 3 BAL250 HR:3 ~RIUM COMPOUNDS (SOLUBLE) BARIUM DIAZIDE Barium and its compounds are on the Community Right mf: BaN6 mw: 221.38 To Know List. Barium and its compounds are on the Community Right I THR: The soluble barium salts, such as the chloride and To Know List. sulfide, are poisonous when ingested. The insoluble sulfate THR: A poison. Impact-sensitive when dry; avoid contact used in radiography is not acutely toxic. See also BARIUM with Pb; acids. See also BARIUM COMPOUNDS and SULFATE. The chromate is a human carcinogen. Few AZIDES. I cases of industrial systemic poisoning have been reported, but one investigator describes a fatal case of poisoning BALSOO HR:3 attributed to barium oxide, the symptoms being severe ab BARIUM DICHROMATE I dominal pain with vomiting, dyspnoea, rapid pulse, paraly mw: 353.38 sis of the arm and leg, and eventually cyanosis and death. The same investigator produced paralysis in animals with PROP: Brownish-red, crystalline masses. barium oxide and carbonate. The usual result of exposure SYN: BARIUM BICHROMATE I to the sulfide, oxide, and carbonate is irritation of the eyes, nose, and throat, and of the skin, producing dermatitis. Barium and its compounds, as well as chromium and its I The salts mentioned are somewhat caustic. compounds, are on the Community Right To Know List. BAK750 HR:3 THR: A poison. See also BARIUM COMPOUNDS BARIUM CYANIDE (SOLUBLE) and CHROMIUM COMPOUNDS. Some CAS: 542-62-1 NIOSH: CQ 8785000 chromates are carcinogenic. A moderate fire hazard by I DOT: 1565 chemical reaction with easily oxidized materials. A power mw: 189.38 ful oxidizer. Incompatible with reducing materials. BAL625 HR:D I . BARIUM FERRITE CYANIDE., SOUD (000 RCRA WASTE NUMBER 1'013 CAS: 12047-11-9 NIC?SH: CQ 9520800 mw: I I II.54 I ...... I 411 BENZYL BUTYL PHTHALATE BECSOO ipr-mus LD50:837 mglkg FRPSAX 33,516,78 TOXICITY DATA: CODEN: scu-mus LDLo: 504 mg/kg PCJOAU 13,829,79 orl-mus LD50:200 mglkg JMCMAR 13,1215,70 JMCMAR 13,1215,70 THR: Moderately toxic by several routes. Experimental ipr-mus LD50:300 mglkg reproductive effects. When heated to decomposition it emits THR: Poison by ingestion and intraperitoneal routes. See toxic fumes of NOx. also FLUORIDES. When heated to decomposition it emits I very toxic fumes of F- and NO_.. BEA850 HR: 3 N·BENZYLBIGUANIDE HYDROCHLORIDE BECOOO HR:2 I CAS: 1421-23-4 NIOSH: DU I 106000 BENZYL BROMIDE mf: C9H13Ns•CJH mw: 227.73 CAS: 100-39-0 NIOSH: XS 7965000 DOT: 1737 SYNS: mf: C H Br mw: 171.05 I 1-BENZILBIGUANIDE CLORI 1-BENZYLBIGUANIDE IIYDRO 7 7 DRATO liTALlAN) CIILORIDE PROP: Clear, refractive liquid; pleasant odor, lachrymator, BENZYLBIGUANIDE HYDRO- insol in water. Mp: -4.0°, bp: 198°, d: 1.438 @ 22°/0°, CHLORIDE vap d: 5.8. I TOXICITY DATA: CODEN: orl-rat LD50: 48 I mg/kg FRPSAX 15,521.60 SYNS: tORill\.fO~IETIIYI.lllENZENE IIROMOI'IIENYI.MIITIIANE ipr-rat LD50: 108 mg/kg FRPSAX 15.521.60 ipr-mus LD50: 195 mg/kg JAJAAA 18,196,65 r-1 IIRI II\. II 11\.fl·:n IYI.)NITRI 1- op-IIRI IMI HI li.UHNil I IIFNZLNF n IIROMOTOl.liENI! (1>01") THR: Poison by intraperitoneal route. Moderately toxic CODEN: by ingestion. When heated to decomposition it emits toxic TOXICITY DATA: dns-csc 1300 Jlnlol/L ZKKOBW 92,177,78 fumes of NO_. and HCI. Reported in EPA TSCA Inventory. BEBOOO HR:3 BENZYL BIS(2·CHLOROETHYL)AMINOMETIIYL DOT Classification: Corrosive Material, Label: Corrosive CARBAMATE THR: Intensely irritating and corrosive to skin, eyes, and CAS: 58050-46-7 NIOSH: EY 8870000 mucous membranes. Large doses cause central nervous sys mw: 305.23 tem depression. Mutagenic data. Reaction with molecular sieve produces toxic hydrogen bromide gas. See also SYN: N- PROP: Clear, oily liquid. Mp: <-35°, bp: 370°, flash p: TOXICITY DATA: CODEN: 390°F, d: 1.116 @ 25°/25°, vap d: 10.8. orl-mus LDLo:500 mg/kg JPETAB 43,413,31 ivn-mus LDLo:50 mg!kg JPETAB 43,413,31 SYNS: '- BBP NCI·C54375 THR: Poison by intravenous route. Moderately toxic by 1 1.2-BENZENEDICARBOXYLIC PALATINOL DB ingestion. Sec also ESTERS and CARBAMATES. When ACID. BUTYL PIIENYLMETIIYL SANTICIZER 160 heated to decomposition it emits very toxic fumes of N01 ESTER SICOL 160 and HCI. BUTYL BENZYL PIITIIALATE UNIMOLL BB n-BUTYL BENZYL PlmiALATE I BEDSOO IIR: 3 TOXICITY DATA: CODEN: BENZYLCARBAMIC ESTER OF 3-0XYPHENYL orl-rat TDLo:21 gfkg (140 TOXlD9 4,136,84 TRIMETHYLAMMONIUM METHYLSULFATE I male):REP CAS: 64051-16-7 NIOSH: BR 463()()()() orl-rat TDLo:433 glkgt2Y-C: NTPTR* NTP-TR- mw: 396.50 CAR 213,82 mf: C 17 H21 N202•CH304S orl-rat LD50:2330 mg/kg IARC** 29,193,82 SYNS: orl-mus LD50:4170 mg/kg IARC** 29,193,82 I AMMONIUM 13-N·BENZYLCARBA- (m-IIYDROXYPIIENYLJTRI- ipr-mus LD50:3160 mg/kg EVHPAZ 4,3,73 MOYLOXY)PHENYL)TRIMETIIYL METIIYLAMMONIUM METIIYl· orl-gpg LD50: 13750 mglkg GTPZAB 24(3),25,80 METIIYLSULFATE SULFATE BENZYLCARBA- IARC Cancer Review: Animal Inadequate Evidence AR-23 MATE N-BENZYL-CARBAMIC ACID-3- I IMEMDT 29, 193,82; NTP Carcinogenesis Bioassay (feed); (TRII'-IETIIYLAMMONIOl No Evidence: mouse NTPTR* NTP-TR-213,82; Clear Evi PIIENYL ESTER. METIIYLSUL ., dence: rat NTPTR* NTP-TR-213,82. Reported in EPA FATE TSCA Inventory. Community Right To Know List. TOXICITY OATA: CODEN: ••• THR: Moderately toxic by ingestion and intraperitoneal orl-mus LDLo: 33 mg/kg JPETAB 43,413,31 routes. An experimental carcinogen. Experimental repro ivn-mus LDLo: 100 JLg!kg NTIS** PBI58- I ductive effects. See also ESTERS. Combustible when ex 508JPETAB 43,413,31 posed to heat or flame; can react with oxidizers. To fight THR: Poison by ingestion and intravenous routes. See also p fire, use spray or mist, C02, dry chemical. When heated CARBAMATES; ESTERS; and SULFATES. When heated to decomposition it emits acrid smoke and irritating fumes. to decomposition it emits very toxic fumes of SO.x, NH3 For further information, see Butyl Benzyl Phthalate, Vol. and NO... 2, No. 2 of DPIM Report. BED750 HR:J BEDOOO HR:2 3-BENZYL-4-CARBAMOYLMETHYLSYDNONE BENZYL-n-BUTYRATE CAS: 14504-15-S NIOSH: WU 7675000 I CAS: 103-37-7 NIOSH: ES 7350000 mw: 233.25 mf: C H 0 . mw: 178.25 1111 11 14 2 SYN: J.BENZYl.SYDNONE-4-ACETAMIDE SYN: BENZYL-N-BUTANOATE TOXICITY OATA: CODEN: I TOXICITY OATA: CODEN: orl-rat TDLo:23 mg/kg/13W-I: GANNA2 65,273,74 orl-rat LD50:2330 mglkg FCTXA V 2,327,64 NEO orl-rat LD50: 4450 mg/kg GANNA2 65,273,74 Reported in EPA TSCA Inventory. THR: An experimental neoplastigen. Mildly toxic by inges I THR: Moderately toxic by ingestion. See also ESTERS. tion. When heated to decomposition it emits toxic fumes When heated to decomposition it emits acrid smoke and ofNO.x. irritating fumes. I BE£250 HR: 1 BED250 HR:3 BENZYLCARBINYL CINNAMATE BENZYLCARBAMIC ESTER OF 3-0XYPHENYL CAS: 103-53-7 NIOSH: GE 0405000 I DIMETHYLAMINE HYDROCHLORIDE mw: 252.33 CAS: 63884-81-1 NIOSH: EY 8740000 SYNS: mf: c,6H1sN202•CIH mw: 306.82 PIIENETIIYL CINNAMATE PIIENYLETIIYL CINNAMATE 13-PIIENETIIYL CINNAI\IATE 13-PIIENYLETIIYL CINNAMATE I SYNS: AR-22 3-(N' ·BENZYlCARBAMdYlOXY) TOXICITY DATA: CODEN: N.N·DIMETIIYL-ANJLINE HY skn-rbt 500 mg/24H MLD FCTXAV 16,637,78 f DROCHLORIDE orl-rat LD50: 5 g/kg FCTXAV 16,637,78 I I i 505 BIS(ETHYLMERCURI)PHOSPHATE BJT250 BJSOOO JIR:3 IMEMDT 29,269 ,82. NTP Carcinogenesis Bioassay (feed); BIS(2-ETHYLHEXYL)PHTHALATE Clear Evidence: mouse, rat NTPTR* NTP-TR-217,82. EPA CAS: 117-81-7 NIOSH: TI 0350000 Genetic Toxicology Program. Reported in EPA TSCA In ~ mf: C24H s04 mw: 390.62 ventory. Community Right to Know List. 3 SYNS: OSHA PEL: TWA 5 mg!m3 I 3 3 BEIIP IIATCOL OOP ACGIH TLV: TWA 5 mg/m ; STEL 10 mg!m BIS(2-ETIIYUIEXYLH .2-BEN- JIERCOFLEX 260 NIOSH REL: (DEHP) Reduce to lowest feasible level ZENEDICARBOXYLATE KODAR.EX DOl' I BISOFLEX Rl MOLLANO THR: Poison by intravenous route. Suspected human car BISOR.EX DOP NCI-CS2733 cinogen and an experimental teratogen. Affects the human COMPOUND 889 NUOPLAZDOP gastrointestinal tract. A mild skin and eye irritant. When DAF68 OCTOIL heated to decomposition it emits acrid smoke. For further OEIIP OCTYL PIITIIALATE I 01(2-IITIIYLIIEXYL)ORTJIO- information, see Di-(2-Ethylhexyl)Phthalate, Vol. 2, No. PALATINOL All PiffiiALATE PHTHALIC ACID DIOCTYL ESTER 2 of DPIM Report. 01(2-ETIIYLHEXYL)PimJALATE PllTSBURGJI PX-138 I DIOCTYL PIITIIALATE PLATINOL All 01-sec-OCTYL PlffiiALATE PLATINOL DOP BJS250 HR: 2 (ACGIH) RC PLASTICIZER DOP BIS(2-ETHYLHEXYL)SEBACATE DOP RCRA WASTE Nl!MRER U02R CAS: 122-62-3 NIOSH: VS 1000000 I EIITYLIIEXYL PIITIIALATE REOI\fOL OOP ERGOPLAST FDO REOMOLD 79P mf: C26H500 4 mw: 426.76 2-ETIIYLIIEXYL PlffiiALATE SICOL ISO PROP: Light, clear liquid; mild odor. Bp: 248° @ 9 mm, EVIPLAST 80 STAR.EX OOP fp: -55°, flash p: 410°F, d: 0.913@ 25°/25°, vap d: 14.7. I EVIPLAST81 TRUR.EX DOP R.EXIMEL VESTINOL All SYNS: R.EXOLDOP VINICIZER 80 DISOFLEX DOS MONOPLEX DOS FLEXOL PLASTICIZER DOP WITCIZER 312 DECANEDIOIC ACID. BIS(2· OCTOILS GOOD-RITE GP 264 I ETHYUIEXYL) ESTER OCTYLSEBACATE TOXICITY DATA: CODEN: 01(2-IITUYLHEXYLlSEBACATE PX438 DIOCTYL SEBACATE STALR.EX DOS skn-rbt 500 mg/24H MLD 28ZPAK -,48,72 DOS UNIR.EX DOS eye-rbt 500 mg AJOPAA 29,1363,46 2-IITHYUIEXYL SEBACATE eye-rbt 500 mg/24H MLD 28ZPAK -,48,72 dns-rat: Jvr 500 JLmoi/L PMRSDJ 5,371,85 TOXICITY DATA: CODEN: sln-ham:Jvr 50 mg/L PMRSDJ 5,397,85 orl-rat LD50:12800 mg/kg 14CYAT 2,1883,63 I orl-rat TDLo:35 mg/kg (140 FCTXAV 15,389,77 ivn-rat LD50:900 mg/kg MRLR*"' No.256,54 pre):REP ivn-rbt LD50:540 mglkg MRLR** No.256,54 orl-mus TDLo: 50 mg/kg (70 EVHPAZ 45,71,82 preg):REP Reported in EPA TSCA Inventory. orl-rat TDLo:216 g/kg/2Y-C: NTPTR"' NTP-TR- I THR: Moderately toxic by ingestion and intravenous routes. CAR 217,82 orl-mus TDLo:260 g/kg/2Y-C: NTPTR* NTP-TR- See also ESTERS. Combustible when exposed to heat or CAR 217,82 flame; can react with oxidizing materials. To fight fire, orl-rat TD :433 glkg/2Y-C:CAR NTPTR* NTP-TR- I use foam, C02, dry chemical. When heated to decomposi 217,82 tion it emits acrid and irritating fumes. orl-mus TD :519 g/kg/2Y-C: NTPTR * NTP-TR- CAR 217,82 orl-mus TD :120 g!kg124W-C: CRNGDP 4,1021,83 I ETA B]T250 JIR: 3 orl-man TDLo: 143 mg/kg:GIT JIHTAB 27,130,45 BIS(ETHYLMERCURI)PHOSPHATE orl-rat LD50: 30600 mglkg EVHPAZ 3,131,73 CAS: 2440-45-1 NIOSH: OW 4375000 I ipr-rat LD50:30700 mg/kg JIHTAB 27,130,45 mf: C H Hg 04P mw: 555.30 ivn-rat LD50: 250 mg/kg TXAPA9 45,230,78 4 11 2 orl-mus LD50: 30 g/kg TJADAB 14.259,76 PROP: Solid ipr-mus LD50: 14 g/kg JPMSAE 55.158,66 I ivn-mus LD50: 1060 mg/kg NTIS** PU250-10l SYNS: orl-rbt LD50:34 g/kg EVHPAZ 4,3, 73 ETIIYLI\.IERCURIC PHOSPHATE LIGNASAN-X skn-rbt LD50: 25 gtkg JIHTAB 27,130,45 IITIIYLMERCURY PHOSPIIATE NEW IMPROVED CERESAN skn-gpg LD50: 10 g/kg EVHPAZ 4,3,73 LIGNASAN FUNGICIDE NEW IMPROVED GRANOSAN skn-gpg LD50: 10 g/kg EVHPAZ 4,3,73 TOXICITY DATA: CODEN: IARC Cancer Review: Human Inadequate Evidence scu-mus TDLo:40 mg/kg (IOD NISFAY 20,1479,68 IMEMDT 29.269,82; Animal Sufficient Evidence preg):REP I I CAC500 CADIA DEL PERRO 664 Arsenic and its compounds are on the Community Right orl-rat LD50: 225 mglkg TXAPA9 41.667.77 To Know List. ipr-ral LD50:4 mglkg TXAPA9 41,667.77 scu-rat LD50: 9 mg/kg TXAPA9 41,667.77 THR: Poison by most routes. See also ARSENIC COM ivn-rat LD50: IRllO JLglkg JJATIJK 1.264.81 POUNDS and SULFIDES. Dangerous lire hazard when unr-rat LD50: 1140 mglkg GTPZAB 2215).6,78 orl·lllll' LD50: HlJO mg/kg 4HITAH -.14.7H '- exposed to heat or by spontaneous chemical reaction. i.e .. ihl-mus LCLo: 170 mgtm' NTIS** PBI58-508 1 in air. Vigorous reaction with oxidizing materials. When unr-mus LD50:890 mgtkg GTPZAB 22(5).6.78 heated to decomposition it emits toxic fumes of As. orl-rbt LDLo:70 mgtkg AMPMAR 34.127.73 scu-rbt LlJLo:6 mgikg PROTA* -.-.55 ivn-rbt LDLo: 5 mg/kg JOGBAS 35.693.28 I CACSOO HR:J ims-ham LDLo: 25 mglkg NCIUS* PH-43-64-886 CADIA DEL PERRO NIOSH: EU 9500000 lARC Cancer Review: Animal Sufficient Evidence IMEMDT 11.39.76: IMEMDT 2.74.73. Cadmium and its I PROP: Aqueous extract from the dried leaves of the plant compounds are on the Community Right To Know List. (JNCIAM 46,1131,71). Reported in EPA TSCA Inventory. EPA Genetic Toxicol SYNS: ogy Program. L K. IXINA KRAMERIA IXINA 3 3 OSHA PEL: TWA 0.1 mg(Cd)tm ; CL 0.6 mg!Cd)tm TOXICITY DATA: CODEN: (fume) scu-rat TDLo:300 mg/kg/1 Y-1: JNCIAM 46.1131.71 ACGIH TLV: TWA 0.01 mg(Cd)/m3 (dust), Human car- I NEO cinogen ..... ims-rat TDLo:45 gtkg!IY-l:ETA JNCIAM 46.1131.71 lWG BAT: Blood 1.5 1-lgldL: Urine IS 1-1g/dL skn-ham TDLo:53950 mgtkg/ JNCIAM 53.1259.74 65W-I:CAR NIOSH REL: (Cadmium) Reduce to lowest feasible level 1... scu-rat TD :990 mg/kg/55W-I: JNCIAM 52.1579.74 THR: A human poison by inhalation and possibly other NEO routes. Poison experimentally by ingestion, inhalation, in THR: An experimental carcinogen, turnorigen and neoplas traperitoneal. subcutaneous. intramuscular. and intravenous I tigen. When heated to decomposition it emits acrid smoke routes. In humans inhalation causes an excess of protein and fumes. in the urine. An experimental carcinogen. tumorigen, neo p plastigen. and teratogen. Experimental reproductive effects. CADOOO HR:J Mutagenic data. The dust ignites spontaneously in air and CADMIUM is nammable and explosive when exposed to heat. name, CAS: 7440-43-9 NIOSH: EU 9800000 or by chemical reaction with oxidizing agents: metals: HN 3: mf: Cd mw: 112.40 Zn: Se: and Te. Explodes on contact with hydrazoic acid. Violent or explosive reaction when heated with ammonium PROP: Hexagonal crystals, silver-white. malleable metal. nitrate. Vigorous reaction when heated with nitryl fluoride. Mp: 320.9°, bp: 767 ± 2°, d: 8.642. vap press: I mm {[t When heated strongly it emits toxic fumes of Cd. See also 394°. CADMIUM COMPOUNDS. For further information, see SYNS: Vol. 3. No. 5 of DPIM Report. C.l. 77180 KADMIUM cGERMANI I COLLOIDAL CADMIUM TOXICITY OAT A: CODEN: CAD250 HR:J cyt-ham:ovr I JLmoi!L CGCGBR 26.251.80 CADMIUI\1(11) ACETATE orl-rat TDLo:220 mg/kg (1-220 TOLED5 11.:!33.82 CAS: 543-90-8 NIOSH: EU 9810000 I prcg):REP,TER DOT: 2570 orl-rat TDLo: 23 mg/kg ( 1-220 PSEBAA 158.614,78 mf: C H~0 •112Cd mw: 116.25 pre g): REP, TER 2 2 ivn-rat TDLo: 1250 JLglkg (140 JJATDK 1.264,81 PROP: Monoclinic, colorless crystals; odor of acetic acid. I preg): REP,TER Mp: 256°, bp: decomp, d: 2.341. ims-rat TDLo:40 mg/kg/4W-1: JEPTDQ 1Cil.51,77 CAR SYNS: ims-rat TD :70 mgtkg: ETA BJCAAI 18.124.64 ACETIC ,\CIO. CADMIUM SALT CADMIUM DIACETATE I ims-rat TD :63 mg/kg: ETA NATUAS 193.592.62 HIScACETOXYICAilMIUl\.1 ims-rat TD :45 mg/kg/4W-1: NCIUS* PH-43-64- CADMIUM ACETATE tDOTl NEO 886.SEPT. 71 ihl-man TCLo:88 J.lg!m3/8.6Y: AEHLAU 28.147,74 TOXICITY DATA: CODEN: I KID cyt-hmn:lym 10 nmoi/L MUREAV 85.236.81 ihl-hmn LCLo:39 mg/m 3/20M AIHAAP 31.180,70 orr-ham:cmb I J.Lmoi/L CNREA8 39.193.79 r unk-man LDLo: 15 mglkg 85DCAI 2.7~.70 dnd-ham: emb I J.lmol/L CNREA8 39,193.79 I I 667 CADMIUM DICYANIDE CAF500 . TOXICITY OATA: CODEN: Cadmium and its compounds are on the Community Right orl-mus TDLo: 15 mg/kg (50 AXVMAW 34,399,80 To Know List. male):REP itt-mam TDLo:29 JLg/kg (ID BECfA6 26,233,81 OSHA PEL: TWA 0.2 mg(Cd)/m3; CL 0.6 JT!g(Cd)/m3 male):REP (dust) I scu-rat TDLo:6580 JLg/kg:ETA ARGEAR 36,119,70 ACGIH TLV: 0.01 mg(Cd)/m3 (dust), Human carcinogen Cadmium and its compounds are on the Community Right NIOSH REL: (Cadmium) Reduce to lowest feasible level To Know List. THR: An experimental tumorigen. Cadmium compounds I OSHA PEL: TWA 0.2 mg(Cd)/m3; CL 0.6 mg(Cd)/m3 are considered to be carcinogens. See also CADMIUM (dust) CHLORIDE; CADMIUM COMPOUNDS; and CHLO ACGIH TLV: TWA 0.01 mg(Cd)/m3 (dust), Human car- RIDES. When heated to decomposition it emits very toxic I cinogen fumes of Cd and Cl-. NIOSH REL: (Cadium) Reduce to lowest feasible level THR: Cadmium compounds are considered to be carcino CAE750 HR:3 I gens. An experimental tumorigen. Experimental reproduc _CADMIUM COMPOUNDS tive effects. When heated to decomposition it emits toxic NIOSH: EV 0260000 • fumes of Cl- and Cd. See also CADMIUM CHLORIDE; TOXICITY DATA: CODEN: CADMIUM COMPOUNDS; and CHLORIDES. I ihl-hmn TCLo: 1500 JLg!m3/14Y ANYAA9 271,273,76 I:CAR,PUL CAE425 HR:3 Cadmium and its compounds are on the Community Right • I CADMIUM CHLORIDE, HYDRATE (2:5) To Know List. CAS: 7790-78-5 NIOSH: EV 0178000 OSHA PEL: TWA 0.2 mg(Cd)/m3; CL 0.6 mg(Cd)/m3 mf: CdCI •5/2H 0 mw: 228.35 • 2 2 (dust) I TOXICITY DATA: CODEN: ACGIH TLV: 0.01 mg(Cd)/m3 (dust), Human carcinogen dni-hmn:lym 28 iJ.rnoUL IAAAAM 79,83,86 NIOSH REL: (Cadmium) Reduce to lowest feasible level scu-rat TDLo:7 mg/kg (ID JOENAK 34,329,66 male):REP THR: Inhalation causes lung cancer in humans. Poison by scu-rat TDLo: 2 mg/kg ( 1D CCPfA Y 27,521,83 ingestion, however, the irritating and emetic action is so male):REP · violent that little of the cadmium has time to be absorbed ipr-mus LDSO: 7 mg/kg ACLSCP 11,476,81 and fatal poisoning rarely ensues. Experimental carcinogens I Cadmium and its compounds are on the Community Right and teratogens. Cases of human poisoning have been re To Know List. ported from ingestion of food or beverages prepared or stored in cadmium-plated containers. Inhalation of fumes OSHA PEL: TWA 0.2 mg(Cd)/m3; CL 0.6 mg(Cd)/m3 or dusts affects the respiratory tract and the kidneys. Brief (dust) I exposure to high concentrations may result in pulmonary ACGIH TLV: TWA 0.01 mg(Cd)/m3 (dust), Human car- edema and death. Fatal concentrations may be breathed cinogen without sufficient discomfort to warn a workman to leave NIOSH REL: (Cadium) Reduce to lowest feasible level I the exposure. Cadmium oxide fumes can cause metal fume THR: Poison by intraperitoneal route. Cadmium com fever resembling that caused by zinc oxide fumes. When pounds are considered to be carcinogens. Experimental re heated to decomposition they emit toxic fumes of Cd. I productive effects. Human mutagenic data. When heated to decomposition it emits toxic fumes of Cl- and Cd. See also CADMIUM CHLORIDE; CADMIUM COM CAFSOO HR:3 POUNDS; and CHLORIDES. . ;· CADMIUM DICYANIDE I mf: C2CdN2 mw: 164.44 CAESOO HR:3 Cadmium and its compounds and Cyanide and its com CADMIUM CHLORIDE, MONOHYDRATE pounds are on the Community Right To Know List. I 3 3 CAS: 35658-65-2 NIOSH: EV 0190000 OSHA PEL: TWA 0.2 mg(Cd)/m ; CL 0.6 mg(Cd)/m mf: CdC12•H20 mw: 201.32 (dust) 3 TOXICITY DATA: CODEN: ACGIH TLV: TWA 0.01 mg(Cd)/m (dust), Human car orl-rat TDLo:65 mglkgi2Y-C: cAtEDQ 9,191,80 cinogen ETA NIOSH REL: (Cadium) Reduce to lowest feasible level I 675 CALCIUM ACETATE CAL750 THR: Poison by subcutaneous and intramuscular routes. SYNS: Moderately toxic by ingestion. An experimental carcinogen. CALCIC AT CALCIUM. METAL. CRYSTALLINE Experimental reproductive effects. When heated to decom CALCIUM. non-pyruphoric !DOT I IDOTI CALCIUM. p)·rophun.: IDOTl CALCIUM. METAL CDOTI position it emits acrid smoke and fumes. See also LIMO NENE. Reported in EPA TSCA Inventory. DOT Classification: Flammable Solid, Label: Flammable CAL075 HR:J Solid and Dangerous When Wet; IMO: Flammable Solid; CALACIDOL Label: Spontaneously Combustible CAS: 60996-85-2 NIOSH: TN 4884000 THR: See CALCIUM COMPOUNDS. Flammable when mf: C2oH39N2•Cl mw: 343.06 heated or in intimate contact with moisture or acids. Moder SYNS: ate explosion hazard in intimate contact with very powerful 1-(2-IDICYCLOHEXYLAMINOJ I.U. 7 oxidizing agents. Reacts with moisture or acids to liberate ETHYL)·I-METHYL·PIPERI· large quantities of hydrogen; can develop explosive pressure DINIUM CHLORIDE in containers. To fight fire, use special mixtures of dry TOXICITY DATA: CODEN: chemical. Violent reaction with water may evolve explosive orl-mus LD50:892 mg/kg FRPSAX 16,773,61 hydrogen gas. Potentially explosive reaction with alkali ... ipr-mus LD50: 125 mgikg FRPSAX 16,773,61 metal hydroxides or carbonates; dinitrogen tetraoxide; lead scu-mus LD50: 151 mg/kg FRPSAX 16,773.61 chloride + heat; phosphorus(V) oxide + heat; sulfur + THR: Poison by subcutaneous and intraperitoneal routes. heat. Molten calcium reacts explosively with asbestos ce Moderately toxic by ingestion. When heated to decomposi ment. Hypergolic reaction with chlorine fluorides (e.g., .. tion it emits toxic fumes of NOx and Cl-. chlorine trifluoride; chlorine pentafluoride). Ignition on con tact with halogens (e.g., fluorine; chlorine); sulfur + vana dium( VI oxide. Violent reaction with mercury (at 390°C); .. CAL125 HR:2 silicon (above 1050°C); sodium + mixed oxides + heat. CALADIUM Incompatible with air. PROP: The various species of this genus have variegated, heart-shaped leaves. The leaf coloration may be green with CALSOO HR:3 white, orange or red. They are popular house plants and CALCIUM ACETARSONE • may be cultivated all year in subtropical gardens and in CAS: 64046-96-4 NIOSH: CF 8575000 the summer in temperate zones. mw: 555.67 SYNS: SYN: N-ACETYI.-4-IIYDROXY-m-ARSANIUC ACID. CALCIUM SALT ANGEL WINGS COUER SAIGNANT IIIAITII CALADIO (PUERTO RICO) ELEPHANT'S EAR TOXICITY DATA: CODEN: CANANGA IIEART·Ili'-JESllS or l-eal LI>Lo: IJ5 mg/kg PSEUAA 27,267,30 CAPOTILLO I MEXICO) LAGRIMAS d.: MARIA C. BICOLOR MOTIIER-IN·LAW PLANT Arsenic and its compounds are on the Community Right CORAZON de CABRITO (CUBA) PALETA de PINTOR I PUERTO To Know List. RICO) OSHA PEL: TWA 0.5 mg(As)/m3 THR: The whole plant contains toxic calcium oxalate ACGIH TLV: TWA 0.2 mg(As)/m3 raphides. Chewing any part of the plant results in burning pain in the lips, mouth and throat, possibly followed by THR: Poison by ingestion. See also ARSENIC COM inflammation and blistering. Systemic effects are usually POUNDS and CALCIUM COMPOUNDS. When heated not seen because of the insolubility of calcium oxalate, to decomposition it emits very toxic fumes of As and NOx. however, ingestion may cause inflammation of the stomach and intestines. See also OXALATES. CAL750 HR:J CALCIUM ACETATE CAL250 HR:2 CAS: 62-54-4 NIOSH: AF 7525000 CALCIUM mf: C4H60 4 •Ca mw: 158.18 CAS: 7440-70-2 NIOSH: EV 8040000 SYNS: DOT: 1401/1855 BROWN ACETATE SORBO-CALCIAN mf: Ca mw: 40.08 CALCIUM OIACETATE SORBO·CALCION GRAY ACETATE TELTOZAN PROP: Silver-white, soft metal. Mp: 84r, bp: 1484°, d: LIME ACETATE VINEGAR SALTS 1.54@ 20°, vap press: 10 mm@ 983°. LIME PYROLIGNITE I 911 CHROMIUM CHLORIDE CMJ250 I !HR: An experimental carcinogen and neoplastigen. Very COMPOUNDS. For further information, see Vol. 3, No. ~werful oxidizer. See also CHROMIUM COMPOUNDS. 3 of DPIM Report. CMISOO HR: 3 CMJOOO HR:3 CHROMITE (MINERAL) CHROMIUM ACETATE HYDRATE I CAS: 1308-31-2 NIOSH: GB 4000000 CAS: 628-52-4 NIOSH: AG 3000000 mf: Cr2Fe04 mw: 223.85 mf: C4H60 4•Cr•H20 mw: 188.12 I SYNS: PROP: Red crystals. CHROME ORE CHROMITE ORE CHROMITE IRON CHROMITE SYNS: TOXICITY DATA: CODEN: ACETIC ACID, CHROMIUM (2+) CHROMIUM DIACETATE I SALT (SCI, 9Cil CHROMOUS ACETATE mma-sat 2 mglplate CRNGDP 3,1331,82 CHROMIUM(Hl ACETATE CHROMOUS ACETATE MONO. cyt-hmn:oth 500 mg/L BJCAAI44,219,8l CHROMIUM(II) ACETATE HYDRATE dni-ham:kdy 500 mg/L BJCAAI44,2l9,81 oms-ham:kdy 500 mg/L BJCAAI44,219,81 TOXICITY DATA: CODEN: I cyt-ham:ovr 5 mg/L BJCAAI44,219,81 orl-rat L050: 11260 mg/kg AIHAAP 30,470,69 sce-ham:ovr 10 mg!L CRNGDP 3,1331,82 Reported in EPA TSCA Inventory. Chromium and its com IARC Cancer Review: Animal Inadequate Evidence pounds are on the Community Right To Know List. I IMEMDT 23,205,80. Chromium and its compounds are on the Community Right To Know List. OSHA PEL: CL 0.5 mg(Cr)/m3 ACGIH TLV: TWA 0.5 mg(Cr)/m3 OSHA PEL: CL 0.5 mg{Cr}/m3 I ACGIH TLV: TWA 0.05 mg/m3 {ore processing}; Human THR: Mildly toxic by ingestion. The anhydrous acetate ·- Carcinogen (ore processing) ignites spontaneously in air. See also CHROMIUM COM POUNDS. When heated to decomposition it emits acrid THR: A human carcinogen. Human mutagenic data. See smoke and irritating fumes. I also CHROMIUM COMPOUNDS and IRON. ~1750 HR:3 CMJ250 HR:3 CHROMIUM CHROMIUM CHLORIDE CAS: 7440-47-3 NIOSH: GB 4200000 CAS: 10025-73-7 NIOSH: GB 5425000 I mf: Cr mw: 52.00 mf: CI3Cr mw: 158.35 SYN: CHROME PROP: Bp: 1300° (subl). TOXICITY DATA: CODEN: SYNS: ivn-rat TOLo:2160 J.l.g/kg16W-1: JNCIAM 16,447,55 CHROMIC CHLORIDE C.l. 77295 I ETA CHROMIUM( Ill) CHLORIDE (I: 3) PURATRONIC CHROMIUM CHLQ. imp-rat TOLo: 1200 J.1.g/kg/6W-I: JNCIAM 16,447,55 CHROMIUM CIILORIDE. ANHY- RIDE ETA DROUS TRICHLOROCHROMIUM I imp-rbt TDLo:75 mglkg:ETA ZEKBAI 52,425,42 CHROMIUM TRICHLORIDE orl-hmn LOLo:71 mglkg:GIT 34ZIAG -,176,69 TOXICITY DATA: CODEN: IARC Cancer Review: Animal Inadequate Evidence pic-esc 500 J.l.moi/L ENMOUM 6,59,84 cyt-hmn:oth 500 mg/L BJCAAI44,219,81 , CIMhroEM~T 23,d2~5,80. Repodrted in EPthA CTSCA I~vent?ry. I mJUm an 1ts compoun s are on e ommumty R1ght dnd-rat-ipr 80 mglkg CNREAB 45,1146,85 dni-mus:fbr 300 J.l.moi/L JTEH06 15,237,85 To Know List. see-ham: lng 39 mg/L CRNGDP 4,605,83 3 ipr-mus TOLo:44600 J.l.g/kg (80 JTSCOR 1,1,76 I OSHA PEL: TWA 1 mglm preg):TER 3 ACGIH TLV: TWA 0.5 mglm ipr-mus TDLo:59500 J.l.g/kg (90 JTSCOR 1,1,76 preg):REP THR: Human poison by ingestion with gastrointestinal ef scu-mus TOLo:450 mglkg TJAOAB 12,198,75 I fects. An experimental tumorigen and suspected carcino (l-170 preg):TER gen. Powder will explode spontaneously in air .. Ignites and· skn-rat LOLo:2 glkg 85GMAT -,39,82 is potentially explosive in atmospheres of carbon dioxide. ihl-mus LC50:31500 J.l.g/m3/2H 85GMAT -,39,82 Violent or explosive reaction when heated with ammonium ipr-mus LOS0:434 mglkg COREAF 256,1043,63 I Arate. May ignite or react violently witli bromine penta- scu-mus LOLo:800 mg/kg AQMOAC #70-15,70 ivn-mus LOLo:400 mglkg AQMOAC #70-15,70 lllllll!foride. Incandescent reaction with nitrogen oxide; sulfur ivn-mus L050: 40 mglkg 85GMAT -,39,82 l dioxide. Incompatible with oxidants. See also CHROMIUM skn-rbt LDLo: I glkg 85GMAT -,39,82 I I CMJSOO CHROMIUM COMPOUNDS 912 ivn-rbt LOLo:288 mg/kg . EQSSOX 1,1,75 CMKOOO HR:J skn-gpg LOLo: 202 mg/kg AEHLAU 11,201,65* CHROMIUM(VI) OXIDE (1:3) AEHLAU 11,201,65 ipr-gpg LOLo:200 mg/kg CAS: 1333-82-0 NIOSH: GB 6650000 Reported in EPA TSCA Inventory. EPA Genetic Toxicol DOT: 1463/1755 ' .. ogy Program. Chromium and its compounds are on the mf: Cr0 mw: 100.00 3 Community Right To Know List. EPA Extremely Hazard I PROP: Red, rhombic, deliquescent crystals. D: 2. 70, mp: ous Substances List. 196°, bp: decomp, sol: 61.7 g/100 cc @ 0°, 67.45 g/100 OSHA PEL: CL 0.5 mg(Cr)/m3 cc@ 100°. ACGIH TLV: TWA 0.5 mg(Cr)/m3 I SYNS: THR: Poison by skin contact, inhalation, intramuscular, ANHYDRIDE CHROMIQUE CHROMIUM TRIOXIDE. ANHY- intravenous, and intraperitoneal routes. Moderately toxic (FRENCH) DROUS (DOT) ANIDRIDE CROMICA (ITALIAN> CHROMO (TRIOSSIDO Dl) (ITAL· I by subcutaneous route. An experimental teratogen. Experi CHROME (TRIOXYDE DE> IAN) mental reproductive effects. Human mutagenic data. Reacts CMY840 HR:3 TOXICITY DATA: CODEN: COAL TAR DYE, LIQUID (DOT) ims-rat TDLo: 126 mg/kg:NEO NATUAS 173,822,54 NIOSH: GF 8620000 imp-rbt TDLo:75 mg/kg:ETA ZEKBAI 52,425,42 ims-rat TD :126 mgtkg:NEO BJCAAI 10,668,56 DOT Classification: Corrosive Material, Label: Corrosive or1-rat LDLo: 1500 mg/kg 15CYAT 2,1026,63 ipr-rat LDLo:250 mg/kg EQSSDX 1,1,75 THR: A corrosive material. Many of the coal tar dyes are ivn-rat LDLo:lOO mg/kg EQSSDX 1,1,75 quite harmless and are permitted for foods, drugs, and cos itr-rat LDLo:25 mg/kg NTIS** AEC-TR-6710 metics. Some of them may be allergens or carcinogens. ipr-mus LDLo: 100 mg/kg EQSSDX 1,1,75 orl-rbt LDLo: 750 mg/kg AIPT AK 62,347,39 When heated to decomposition they emit acrid smoke and ivn-rbt LDLo: 100 mg/kg EQSSDX 1,1,75 fumes. Reported in EPA TSCA Inventory. EPA Extremely Hazard ous Substances List. Cobalt and its compounds are on the CMZIOO HR:3 Community Right To Know List. COAL-TAR PITCH 3 CAS: 65996-93-2 NIOSH: GF 8655000 OSHA PEL: TWA 0.1 mglm ACGIH TLV: (metal, dust, and fume) TWA 0.05 mg(Co)/ SYNS: m3 COAL TAR PITCH VOLATILES PITCH DFG TRK: 0.5 mg/m3 calculated as cobalt in that portion CACOIHl PITCH. COAL TAR of dust that can possibly be inhaled in the production TOXICITY DATA: CODEN: of cobalt powder and catalysts; hard metal (tungsten car skn-mus TDLo:36 g/kg/ISW-1: AJIMDS 2,59,81 bide) and magnet production (processing of powder, ma ... CAR chine pressing, and mechanical processing of unsintered skn-mus TD :4200 mg/kg/ TXAPA9 18.41,71 articles); others 0.1 mg/m3 calculated as cobalt in that 31W-I:NEO skn-mus TD :82 gtkg/52W-I: HYSAAV 33(5),180.68 portion of dust that can possibly be inhaled. I CAR THR: Poison by intravenous, intratracheal, and intraperito· Reported in EPA TSCA Inventory. neal routes. Moderately toxic by ingestion. An experimental neoplastigen and tumorigen. Inhalation of the dust may OSHA PEL: TWA 0.2 mg/m3 cause pulmonary damage. The powder may cause dermati· p ACGIH TLV: TWA 0.2 mg!m3 (volatile), Human Carcino- tis. Ingestion of soluble salts produces nausea and vomiting gen by local irritation. Powdered cobalt ignites spontaneously NIOSH REL: TWA 0.1 mg/m3 in air. Flammable when exposed to heat or llame. Explosive THR: An experimental carcinogen and neoplastigen by skin reaction with hydrazinium nitrate; ammonium nitrate + I contact. When heated to decomposition it emits acrid smoke heat; and 1,3,4,7-tetramethylisoindole (at 390°C). Ignites '• and fumes. on contact with bromine pentafluoride. Incandescent reac II tion with acetylene; nitryl fluoride. See also COBALT COMPOUNDS. For further information, see Vol. I, No. CNA250 HR:3 3 of DPJM Report. COBALT CAS: 7440-48-4 NIOSH: GF 8750000 I• af: Co aw: 58.93 HR: 2 CNASOO PROP: Gray, hard, magnetic, ductile, somewhat malleable COBALT ACETATE TETRAHYDRATE metal. Exists in two allotropic forms. At room temperature, CAS: 6147-53-1 NIOSH: AG 3325000 I the hexagonal form is more stable than the cubic form; mf: C4Hc,04 •Cu•4H20 mw: 249.11 '• both forms can exist at room temperature. Stable in air or SYNS: II toward water at ordinary temperatures. D 8.92, mp 1493°, ACETIC ACID. C0HALTf2-t I SALT, COBALTOUS ACETATE TETRA- bp about 3100°, Brinell hardness: 125, latent heat of fusion TETRAIIYDRATE JIYDRATF. 62 cal/g, latent heat of vaporization 1500 cal/g, specific COilAI.T !)(ACETATE TloTRAIIY· OCT AN KOIIAI.TNATY ICZECIII DR ATE heat (15-100°): 0.1056 cal/gfC. Readily sol in dil HN03; i• very slowly attacked by HCI or cold H2S04• The hydrated TOXICITY DATA: CODEN: salts of cobalt are red, and the sol salts form red solns skn-rbl 500 mg/24H MOD 28ZPAK -.21.72 which become blue on adding coned HCI. eye-rbt 500 mg/24H MLD 28ZPAK -,21.72 cyt-hmn: 1ym 600 ~giL CYGEDX 12(3),46,78 SYNS: orl-rat LD50: 708 mg/kg FCfOD7 20,311,82 AQUA CAT KOBALT (GERMAN, POLISH I •. C.l. 77320 NCI-C60Jll Cobalt and its compounds are on the Community Right I COBALT-59 SUPER COBALT To Know List. ·I I CNH785 CONVALLATOXOL 950 CNH785 HR:J PROP: A metal with a distinct reddish color. Mp: 1083°. CONVALLATOXOL bp: 2324°, d: 8.92, vap press: 1 mm@ 1628°. CAS: 3253-62-1 NIOSH: FH 4900000 SYNS: mf: C29H440w mw: 552.73 ALI.BRI NATURAL COPPER COPPER BRONZE SYNS: ANAC I Ill COPPER.MILLED ARWOOD ('O\'PER COPPER SLAG-AIRBORNE '- CONVALLOTOXOL COVALLATO:' PROP: Oily liquid, mild odor. Bp: 340°, fp: -35°, flash SYNS: p: 315°F (CC). d: 1.047-1.049 (ci 20°/20°, autoign temp: IIISfn-llliTYLJSEBACATE MONOPLEX DllS 757°F. vap d: 9.5X. lli'CANI'IliOIC ACIIJ. IJIIllffYI. POLYC'JZER DIIS ~ UiTI'R J'X 4114 SYNS: 1>1-n-llliTYL SEIIACATE SEilACJC ACID. I>IIIIITYI. I \II ~ KOIMI'I.I'X IIIIS STAI'LEX J>IIS I n-III'N/.1 :NI'I li<"AIWOX Yl.l<" Al"lll. I >IIIII rYI. 1'1 HIIAI.ATI' t AC!illl 1 llllll!TYI. I'STI'R I'I.AOI. CODEN: llENZENI'·n-I>IC,\RilOXYt.IC ACID IIEXAI'LAS M II TOXICITY DATA: lll-n-llltTYI. ESTER PAI.ATI:-;lll. C orl-mt TDLo:418 glkg (lOW AMIHBC 7,3111.5.' J n-IIIITYI. I'IITIIAI.ATE t()OTl I'OI.YCI/.I'.R 1>111' malc/100 prc):REP I orl-rat LD50: 16 g/kg NPIRI* 2.22.75 CEI.I.llf'IJ'X IJI'II I'X lnt Dill' RCRA WASH: NIIMIIER l'M'I Reported in EPA TSCA Inventory. DIOLITYL-1.~-Ili'NZENI'DICAR- STAI'I.I'X Dill' I IIOXYI.AIT. \\TICIZER ·"MI THR: Mildly toxic by ingestion. Experimental rcpmdu(ti\C TOXICITY DATA: CODEN: effects. Combustible when exposed to heat or flame; r;m mmo-sat I 00 flg/platc JTEHD6 16.61.85 react with oxidizing materials. To fight fire, usc CO!. d~ cyt-ham: fbr :m m)!IL/2411 1\ILJREAV 4R.337.77 chemical. When heated to decomposition it cmils arr~ I IGJOOO HR:3 IGHOOO HR: 2 IRIDIUM IPROPRAN CAS: 7439-88-5 CAS: 14885-29-1 NIOSH: NI 6450000 af: lr aw: 192.2 mf: C7H11N30 2 mw: 169.21 ~I PROP: Silver-white very hard metallic element. Mp: 2450°, SYNS: IPRONIDAZOLE 1-METIIYL-2-c 1-METHYLETHYLl-5- bp: approx 4500°, d: 22.65@ 20°/4°. Highest specific grav I 2-ISOPROPYI.·I·METIIYL-~-NI NTTR0-111-IMIIJI\ZOLE ity of all elements. TROIMIDAZULE R07-1~54 The pure metal is clinically inert and no toxicity data is available. Most of its compounds are poorly soluble in TOXICITY OAT A: CODEN: water and thus are not absorbed efficiently by the body. mmo-sat I ~mol/L TCMUD8 3.429.83 mmo-csc 50 ~moi!L MUREAV 48,155,77 The chlorides are poison or moderately toxic by ingestion mmo-klp 20 ~moi/U20H MUREA V 66.207.79 and are eye and skin irritants. There are no reports of acute nimo-omi 20 ~moi!L MUREAV 4R,I55,77 of chronic health effects to workers handling iridium and mmo-smc 5 ppm MUREA V 86,243,81 its compounds. The IIJUlr and 192Ir radioisotopes are used orl-trk LD50:640 mg/kg POSCAL 49,92,70 in clinical radiography and most references to the toxicity THR: Moderately toxic by ingestion. Mutagenic data. Used of iridium relate to these isotopes. as an antiprotozoal and antimicrobial agent. When heated A catalytic metal. The powdered metal may ignite sponta to decomposition it emits toxic fumes of NO,. neously in air. Violent reaction or ignition on contact with interhalogens (e.g., bromine pentafluoride; chlorine tri fluoride). Alloys with zinc, after extraction with acids, leave IGH700 HR:D heat-sensitive explosive residues. Is attacked by F2, Cl 2 at IREHDIAMINE A red heat: by potassium sulfate or a mixture of potassium CAS: 3614-57-1 NIOSH: TU 4812000 hydroxide and nitrate: on fusion: lead; zinc; tin. mw: 316.59 SYNS: PREGN-S-ENE-3-J3,20-a-DIAMINE IG)499 HR: 3 IRIDIUM TETRACHLORIDE TOXICITY OAT A: CODEN: CAS: 10025-97-5 NIOSH: NO 3610000 mmo-omi 200 ~g/plate PNASA6 58,256,67 mw: 334.00 ·~ dni-omi 60 ~moi!L PNASA6 58,256,67 I THR: Mutagenic data. When heated to decomposition it SYN: IRIDIUM(IV) CHLORIDE emits toxic fumes of NOx. TOXICITY OAT A: CODEN: orl-rat LD50:8115 ~g/kg GTPZAB 21(7),55,77 I /G/000 HR: 3 EPA Extremely Hazardous Substances List. Reported in IRGAPYRIN EPA TSCA Inventory. CAS: 8064-79-7 NIOSH: UQ 8290000 THR: Poison by ingestion. When heated to decomposition mf: C,9HtnN20 •C H11N 0 mw: 539.74 I 2 13 3 il cmils !oxic fumes of Cl-. See also IRIDIUM. SYNS: 4-RUTYL-1·1,2-DIPIIENYL-3.!1-PY • IRGAPYRINE IGK800 HR:3 RAZOUDINEDIONE Wmf 4-(01- PABIALGIN IRON I METIIYLAMINOI-1.2-DIHYDRO- RHEOPYRINE 1,5-DIMETIIYL-2-PIIENYL-311- CAS: 7439-89-6 NIOSH: NO 4565500 PYRAZOL-3-0NE af: Fe aw: 55.85 I' I 2009 IRON(JII)·o-ARSENITE PENTAHYDRATE IGOOOO SYNS: Arsenic and its compounds are on the Community Right ANCOR EN 80/ISO CARBONYL IRON To Know List. ARMCO IRON OSHA PEL: TWA 0.01 mg(As)/m3 TOXICITY DATA: CODEN: 3 ACGIH TLV: TWA 0.2 mg(As)/m ; TWA I mg/(Fe)/m3 ipr-rbt LDLo: 20 mg/kg NTIS** PB 158-501! NIOSH REL: (Inorganic Arsenic) CL 0.002 mg(As)/rn3/ '- Reported in EPA TSCA Inventory. ISM 1 THR: Poison by intraperitoneal route. Iron is potentially DOT Classification: Poison B; Label: Poison ' toxic in all forms and by all routes of exposure. The inhala tion of large amounts of iron dust results in iron pneumoco THR: A deadly poison by various routes. A pesticide. When I niosis (arc welders lung). Chronic exposure to excess levels heated to decomposition it emits toxic fumes of As. See of iron (> 50-100 mg Fe/day) can result in pathological also ARSENIC COMPOUNDS and IRON COMPOUNDS. deposition of iron in the body tissues. the symptoms of I which are fibrosis of the pancreas, diabetes mellitus. and liver cirrhosis. /GNOOO HR:J As with other metals, it becomes more reactive as it is IRON(Ill) ARSENATE (1: 1) more finely divided. Ultrafine iron powder is pyrophoric CAS: 10102-49-5 NIOSH: NO 4585000 I and potentially explosive. Explosive or violent reaction with DOT: 1606 ammonium nitrate + heat; ammonium peroxodisulfate: mw: 194.77 chloric acid; chlorine trinuoride; chloroformamidinium ni SYNS: I trate; bromine pcnrafluoride + heat (with iron powder): ARSEN<\.IT. 01' IRON. I'ERRI(" air + oil (with iron dust); sodium acetylide. Ignites on Arsenic and its compounds are on the Community Right contact with chlorine; dinitrogcn tetraoxide; liquid nuorine; To Know List. hydrogen peroxide (with iron powder); nitryl lluoride + heat; peroxyformic acid; potassium perchlorate; potassium OSHA PEL: TWA 0.01 mg(As)/m3 dichromate; sodium peroxide (at 240°C): polystyrene + ACGIH TLV: TWA 0.2 mg(As)/m3: TWA I mg/(Fe)/m3 3 friction or spark (iron powder). Mixtures of iron dust with NIOSH REL: (Inorganic Arsenic) CL 0.002 mg(As)/m / I;. air + water may ignite on drying. Reduced iron reacts 15M with water to produce explosive hydrogen gas. Catalyzes DOT Classification: Poison B; Label: Poison the exothermic polymerization of acetaldehyde. See also IRON COMPOUNDS; IRON DUST; and FERROUS ION. THR: A deadly poison. A pesticide. When heated to decom ~ position it emits toxic fumes of As. See also ARSENIC IGLOOO /IR: J COMPOUNDS and IRON COMPOUNDS. IRON ACETYLACETONATE CAS: 14024-18-1 NIOSH: NO 8960000 IGOOOO HR:J I mf: C 15 H21 Fe06 mw: 353.21 IRON(IU)·o-ARSENITE PENTAHYDRATE SYNS: CAS: 63989-69-5 NIOSH: NO 4600000 I FERRIC ACETYLACETONATE TRIS12 .4-PENT ANEDION ATO 1IRON I'ERRIC TRIACETYLACETONATE DOT: 1607 mf: As2Fe20 •Fe203•5H20 mw: 607.34 TOXICITY DATA: CODEN: 6 I ivn-mus LD50: 100 mgtkg CSLNX* NX#02372 PROP: Brown-yellow powder. I Reported in EPA TSCA Inventory. SYNS: THR: Poison by intravenous route. When heated to decom FERRIC ARSENITE. BASIC FERRIC ARSENITE. SOLID (DOT) I position it emits acrid smoke and fumes. See also IRON Arsenic and its compounds are on the Community Right COMPOUNDS. To Know List. 3 I IGMOOO JIR: J OSHA PEL: TWA 0.0 I mg(As)/m IRON(Il) ARSENATE (3:2) ACGIH TLV: TWA 0.2 mg(As)/m3; TWA I mg/(Fe)/m3 CAS: 10102-50-8 NIOSH: NO 4580000 NIOSH REL: (Inorganic Arsenic) CL 0.002 mg(As)/m3/ DOT: 1608 15M I mf: As 0 •3Fe mw: 445.39 2 8 DOT Classification: Poison B. Label: Poison SYNS: ARSENATE OF IRON. FERROUS FERROUS ARSENATE. SOI.ID THR: A deadly poison. When heated to decomposition it I ll:RROUS ARSENATE !DOT) tDOTJ emits toxic fumes of As. See also ARSENIC COM· IRON ARSENATE IDOTl POUNDS and IRON COMPOUNDS. I I LCCOOO LA VENDER ABSOLUTE 2096 OSHA PEL: TWA 0.2 mg!m3 THR: An experimental carcinogen. When heated to decom 3 NIOSH REL: (To Coal Tar Products) TWA 0.1 mg!m position it emits toxic fumes of NO,~. See also AROMATIC AMINES. ~ DOT Classification: Aammable or Combustible; Label Flammable Liquid LCFOOO HR:J I THR: An experimental carcinogen and tumorigen. Muta LEAD genic data. A human and experimental skin irritant. When CAS: 7439-92-1 NIOSH: OF 7525000 heated to decomposition it emits acrid smoke and irritating af: Pb aw: 207.19 I fumes. PROP: Bluish-gray, soft metal. Mp: 327.43°, bp: 1740°, d: 11.34 @ 20°/4~. vap press: I mm @ 973°. LCCOOO HR: 1 SYNS: I LAVENDER ABSOLUTE C.l. 7"7~ OLOW (POLISH) CAS: 8000-28-0 NIOSH: OF 6100000 C. I. PIGMENT METAL 4 OMAHA GLOVER OMAHA & GRANT PROP: Found in the flowers of Lavandula officina/is chaix. LEAD FLAKE Sl I The main constituent is Iinalyl acetate. A dark green liquid LEADS2 so ~ prepared from alcoholic extract of a residue which is ex TOXICITY DATA: CODEN: tracted from plant material using an organic solvent. cyt-hmn-unr 50 J.Lg/rn3 MUREAV 147,301,85 cyt-rat·ihl 23 J.Lg/m3/16W GTPZAB 26(10),38,82 I TOXICITY DATA: CODEN: cyt-mky-orl 42 mg/kg/30W TOLE05 8,165,81 skn-rbt 500 mg/24H MLD FCfXAV 14,449,76 orl-rat TDLo:790 mglkg AEHLAU 23,102,71 orl-rat LD50:4250 mg/kg FCfXAV 14,449,76 (MGN):REP THR: Mildly toxic by ingestion. A skin irritant. When orl-rat TOLo: 1140 mglkg (140 PHMCAA 20,201,78 I pre-210 post): REP heated to decomposition it emits acrid smoke and irritating orl-rat TOLo: 1100 mg/kg (1-220 FEPRA7 37,895,78 fumes. See also 3,7-DIMETHYL-1,6-0CTAD1EN-3-0L preg):TER ACETATE. ihl-rat TCLo: 10 mglm3124H ZHPMAT 165,294,77 (1-210 preg):TER orl-wmn TDLo:450 mg/kg/6Y: JAMAAP 237,2627,71 LCDOOO PNS:CNS HR:l 3 LAVENDER OIL ihl-hmn TCLo: 10 J.Lg/m :GIT: VROEA5 (5),107,81 ' LIV ,. CAS: 8000-28-0 NIOSH: OF 6110000 ipr-rat LOLo: 1000 mg/kg EQSSOX 1,1,75 PROP: Main constituent is linalyl acetate. Found in the orl-pgn LOLo: 160 mglkg HBAMAK 4,1289,35 I plant Lavandulaofficinalif choix (Fam. Labiate). Prepared IARC Cancer Review: Animal Inadequate Evidence by steam distillation of the flowering stalks of the plant. IMEMDT 23,325,80. Lead and its compounds are on the Community Right To Know List. Reported in EPA TSCA SYNS: LA VENDEL OEL (GERMAN) OIL OF LA VENDER Inventory. EPA Genetic Toxicology Program. 3 TOXICITY DATA: OSHA PEL: TWA 0.05 mg(Pb)/m CODEN: 3 skn-rbt 500 mg/24H MLD FCfXAV 14,451,76 ACGIH TLV: TWA 0.15 mg(Pb)/m 3 ' orl-rat LD50:9040 mg/kg PHARAT 14,435,59 NIOSH REL: TWA (Inorganic Lead) 0.10 mg(Pb)/m Reported in EPA TSCA Inventory. THR: Poison by ingestion. Moderately toxic by intraperito - neal route. It is a suspected carcinogen of the lungs and THR: Mildly toxic by ingestion. A skin irritant. When I kidneys. Human systemic effects by ingestion and inhala· heated to decomposition it emits acrid smoke and irritating tion: loss of appetite, anemia, malaise, insomnia, headache, fumes. See also 3,7-DIMETHYL-1,6-0CTADIEN-3-0L irritability, muscle and joint pains, tremors, flaccid paralysis ACETATE. I without anesthesia, hallucinations and distorted percep tions, muscle weakness, gastritis and liver changes. The LCEOOO HR:J major organ systems affected are the nervous system, blood I LD-813 system, and kidneys. Lead encephalopathy is accompanied CAS: 64083-05-2 NIOSH: OF 6730000 by severe cerebral edema, increase in cerebral spinal fluid pressure, proliferation and swelling of endothelial cells in PROP: Commercial mixture of aromatic amines containing capillaries and arterioles, proliferation of glial cells, neu approx 40% MOCA. ronal degeneration and areas of focal cortical necrosis in TOXICITY DATA: CODEN: fatal cases. Experimental evidence now suggests that blood orl-rat TDLo: 37 g/kg/2Y -C: CAR TXAPA9 31,159,75 levels of lead below 10 J.Lg/dl can have the effect of dimin· I 1 2097 LEAD ACETATE lCGOOO ishing the IQ scores of children. Low levels of lead impair or flame. Moderately explosive in the form of dust when neurotransmission and immune system function and may exposed to heat or flame. Mixtures of hydrogen peroxide ncrease systolic blood pressure. Reversible kidney damage + trioxane explode on contact with lead. Rubber gloves an occur from acute exposure. Chronic exposure can lead containing lead may ignite in nitric acid. Violent reaction to irreversible vascular schlerosis, tubular cell atrophy, in on ignition with chlorine trifluoride; concentrated hydrogen I terstitial fibrosis, and glomerular sclerosis. Severe toxicity peroxide; ammonium nitrate (below 200°C with powdered can cause sterility, abortion and neonatal mortality and mor lead); sodium acetylide (with powdered lead). Incompatible bidity. An experimental teratogen. Experimental reproduc with NaN3; Zr; disodium acetylide; oxidants. Can react tive effects. Human mutagenic data. Very heavy intoxica vigorously with oxidizing materials. A common air contam I tion can sometimes be detected by formation of a dark inant. When heated to decomposition it emits highly toxic line on the gum margins, the so-called ''lead line." fumes of Pb. See also LEAD COMPOUNDS. For further When lead is ingested, much of it passes through the information, see Vol. 1, No. 1 of DPIM Report. I body unabsorbed, and is eliminated in the feces. The greater portion of the lead that is absorbed is caught by the liver LCGOOO HR:J and excreted, in part, in the bile. For this reason, larger LEAD ACETATE I amounts of lead are necessary to cause toxic effects by CAS: 301-04-2 NIOSH: AI 5250000 this route, and a longer period of exposure is usually neces DOT: 1616 sary to produce symptoms. On the other hand, upon inhala mf: C4H60 4•Pb mw: 325.29 tion, absorption takes place easily from the respiratory tract I and symptoms tend to develop more quickly. For industry, PROP: Trihydrate: colorless crystals or white granules or inhalation is much more important than is ingestion. For powder. Sltly acetic odor, slowly effloresces. D: 2.55, mp: the general population, exposure to lead occurs from inhaled 75° (when rapidly heated), decomp above 200°. Very sol I air, dust of various types, and food and water with an in glycerol. approximate 50!50 division between inhalation and inges SYNS: tion routes. Lead occurs in water in either dissolved or ACETATE de PLOMB (FRENCH) LEAD DIBASIC ACETATE I particulate form. At tow pH, lead is more easily dissolved. ACETIC ACID LEAD (2+) SALT NORMAL LEAD ACETATE Chemical treatment to soften water increases the solubility BLEIACETAT (GERMAN) PLUMBOUS ACETATE -..rf lead. Adults absorb about 5-15% of ingested lead and DIBASIC LEAD ACETATE RCRA WASTE NUMBER UJ44 LEAD (2+) ACETATE SALT OF SATURN ...-~tain less than 5%. Children absorb about 50% and retain LEAD(IJ) ACETATE SUGAR OF LEAD about 30%. LEAD DIACETATE Lead produces a brittleness of the red blood cells so that they hemolyze with but slight trauma; the hemoglobin TOXICITY DATA: CODEN: I is not affected. Due to their increased fragility, the red sln-smc 250 jLmol/L MUTAEX 1,21,86 cyt-hmn: lym I mmoUU24H TXCYAC 10,67,78 cells are destroyed more rapidly in the body than is normal, mnt-rat-ipr 51800 jLg/kg AEHLAU 40,144,85 producing an anemia which is rarely severe. The loss of otr-rat:emb 200 mg/L JJIND8 67,1303,81 I circulating red cells stimulates the production of new young oms-rat-ipr 10400 jLg/kg AEHLAU 40,144,85 cells which, on entering the blood stream, are acted upon cyt-rat-unr 9 mg/kg/26W-C GISAAA 49(3),15,84 by the circulating lead, with resultant coagulation of their cyt-rat·ipr 51800 jLg/kg AEHLAU 40,144,85 orl-rat TOLo:600 jLg/kg (300 AJOGAH 115,1058,73 I basophilic material. These cells after suitable staining, are male):REP recognized as "stippled cells." There is no uniformity of orl-rat TOLo: 1413 mg/kg (1-180 ENVRAL 30,152,83 (J opinion regarding the effect of lead on the white blood preg):TER cells. orl-mus TOLo:236 mglkg ARTOON 41,125,78 I In addition to its effect on the red blood cells, lead pro (7-160 preg):TER orl-rat TOLo:900 mglkg/600-C: ENVRAL 24,391,81 duces a damaging effect on the organs or tissues with which NEO it comes in contact. No specific or characteristic lesion is orl-rat TO :250 g/kg/47W-C: BJCAAI 16,283,62 I produced. Autopsies in deaths attributed to lead poisoning ETA and experimental work on animals have shown pathological orl-rat TO :2430 mg/kg/23W-C: ENVRAL 24,391,81 lesions of the kidneys, liver, male gonads, nervous system, ETA orl-rat TO :4605 mglkg/44W-C: ENVRAL 24,391,81 blood vessels and other tissues. None of these changes, ETA I however, has been found consistently. In cases of severe orl-rat TO :7560 mglkgi72W-C: ENVRAL 24,391,81 lead poisoning, the amount of lead found in the blood is NEO frequently in excess of 0.07 mg per 100 cc of whole blood. orl-rat TO :9150 mg/kg/44W-C: AJPAA4 50,571,67 NEO The urinary lead excretion generally e~ceeds 0.1 mg per orl-rat TO :218 glkg/IY-C:ETA BECfA6 23,464,79 of urine. orl-rat TO : 138 g!kg176W-C: TOPAOO 13,50,85 Flammable in the form of dust when exposed to heat ETA I ------I LCTOOO LEAD COMPOUNDS 2102 IMEMDT 23,205,80. Lead and its compounds, as well as rapidly absorbed by the respiratory and gastrointestinal sys chromium and its compounds are on the Community Right tems and through the skin. Tetraethyl lead is converted in To Know List. Reported in EPA TSCA Inventory. the body to triethyl l~ad which is a more severe neurotoxin than inorganic lead. Diagnostic mobilization of lead with \ OSHA PEL: TWA 0.05 mg(Pb)/m3; CL 0.1 mg(Cr03)/m3 calcium EDT A may be useful in questionable cases. When ACGIH TLV: TWA 0.05 mg(Cr)/m3; TWA 0.15 mg(Pb)/m3 heated to decomposition they emit toxic fumes of Pb. See I NIOSH REL: (Chromium(VI)) TWA 0.001 mg(Cr(Vl))/ also LEAD and specific compounds. m3; (Inorganic Lead) TWA 0.10 mg(Pb)/m3 THR: A human carcinogen. An experimental carcinogen, I neoplastigen and tumorigen. Human mutagenic data. When LCUOOO HR:3 heated to decomposition it emits very toxic fumes of Pb. LEAD(II) CYANIDE See also LEAD COMPOUNDS and CHROMIUM COM CAS: 592-05-2 NIOSH: OG 0175000 I POUNDS. DOT: 1620 mf: C2N2Pb mw: 259.23 LCTOOO HR:3 PROP: White powder. LEAD COMPOUNDS SYNS: Lead and its compounds are on the Community Right To C.l. 77610 CYANURE de PLOMB (FRENCH) • Know List. C. I. PIGMEI'IT YELLOW 48 LEAD CYANIOE (DOT) I THR: Lead poisoning is one of the commonest of occupa TOXICITY DATA: CODEN: tional diseases. The presence of lead-bearing materials or ipr-rat LDLo: 100 mglkg NCNSA6 5,27,53 lead compounds in an industrial plant does not necessarily Lead and its compounds, as well as cyanide and its com I result in exposure on the part of the worker. The lead pounds, are on the Community Right To Know List. must be in such fonn, and so distributed, as to gain entrance into the body or tissues of the worker in measurable quan OSHA PEL: TWA 0.05 mg(Pb)/m3 tity, otherwise no exposure can be said to exist. Some ACGIH TLV: TWA 0.15 mg(Pb)/m3 I 3 lead compounds are carcinogens of the lungs and kidneys. NIOSH REL: (Inorganic Lead) TWA 0.10 mg(Pb)/m Others are experimental neoplastigens and tumorigens. DOT Classification: Poison B, Label: Poison Mode of entry into body: 1. By inhalation of the dust, II' fumes, mists or vapors. (Common air contaminants). 2. By THR: Poison by intraperitoneal route. Violent reaction with ingestion of lead compounds trapped in the upper respira Mg. A fire hazard and a powerful oxidizer. When heated tory tract or introduced into the mouth on food, tobacco, to decomposition it emits very toxic fumes of Pb, eN fingers or other objects. 3. Through the skin; this route is and NO.r. See also LEAD COMPOUNDS and CYANIDES. of special importance in the case of organic compounds of lead, as lead tetraethyl. In the case of the inorganic fonns of lead, this route is of no practical importance. LCVOOO HR:3 Significant quantities of lead can be ingested from water LEAD DICHLORITE that has been sitting in pipes with lead solder. Some water mf: Cl20 4Pb mw: 477.00 I coolers may also have this type of solder. Lead and its compounds are on the Community Right To Lead is a cumulative poison. Increasing amounts build Know List. up in the body and eventually reach a point where symptoms and disability occur. See LEAD for symptoms of overexpo SYN: LEAD(Il) CHLORITE sure. I THR: Explodes when heated to l00°C or on contact with The toxicity of the various lead compounds appears to antimony sulfide or sulfur. Violent reaction with carbon; depend upon several factors: (1) the solubility of the com red phosphorus; or sulfur. When heated to decomposition pound in the body fluids; (2) the fineness of the particles it emits very toxic fumes of Pb and Cl-. See also LEAD I of the compound; solubility is greater in proportion to the COMPOUNDS and CHLORITES. fineness of the particles; (3) conditions under which the compound is being used. Where a lead compound is used I as a powder, contamination of the atmosphere will be much LCWOOO HR:2 less if the powder is kept damp. Of the various lead com LEAD DIMETHYLDITHOCARBAMATE pounds, the carbonate, the monoxide, and the sulfate are CAS: 19010-66-3 NIOSH: OF 8850000 considered to be more toxic than metallic lead or other mf: C6H N S •Pb mw: 447.63 lead compounds. Lead arsenate is very toxic due to the 12 2 4 presence of the arsenic radical. Organolead compounds are PROP: Solid. Mp: 258°, d: 2.5. I I 2193 MERCURY MCW250 Mercury and its compounds are on the Community Right skn-rat LD50: 1500 mglkg GTPZAB 25(7),27 ,81 o Know List. orl-mus LD50: 180 mglkg GTPZAB 25(7),27 ,81 ipr-mus LD50: 10 mg/kg GTPZAB 25(7),27,81 IOSH REL: (To Inorganic Mercury) TWA 0.05 Mercury and its compounds are on the Community Right mg(Hg)/m3 To Know List. EPA Genetic Toxicology Program. Reported I THR: Poison by intravenous and intramuscular routes. in EPA TSCA Inventory. When heated to decomposition it emits very toxic fumes ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin) of NO.x, Na 0 and Hg vapors. See also MERCURY COM 2 NIOSH REL: (To Inorganic Mercury) TWA 0.05 POUNDS. I mg(Hg)/m3 MCV750 HR:3 THR: Poison by ingestion and intraperitoneal routes. Mod MERCUROPHYLLINE erately toxic by skin contact. Mutagenic data. A fungicide. I CAS: 8012-34-8 NIOSH: OV 8650000 An FDA over-the-counter drug. Incompatible with bro SYNS: mides; iodides; alkali chlorides; sulfates; sulfites; carbon MERCUPURIN MERCUZANTHIN ates; hydroxides; lime water; ammonia; golden antimony I sulfide; cyanides; copper salts; hydrogen peroxide; iodine; TOXICITY DATA: CODEN: iodoform; lead salts; silver salts; sulfides. When heated to JAMAAP 117,1806,41 ivn-hmn IDLo:28 mg!kg:CVS Cl- ipr-rat LD50: 121 mg/kg THERAP 10,936,55 decomposition it emits very toxic fumes of and Hg. I scu-mus LD50: 163 mg(Hg)/kg JPETAB 105,336,52 See also MERCURY COMPOUNDS. ivn-mus LD50; 1410 mglkg JPETAB 99,149,50 ivn-cat LDLo:250 mg/kg JPETAB 99,149,50 MCW250 HR:3 ivn-rbt LDLo: 177 mg/kg JPETAB 99,149,50 MERCURY CAS: 7439-97-6 NIOSH: OV 4550000 I Mercury and its compounds are on the Community Right DOT: 2809 To Know List. af: Hg aw: 200.59 ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin) I NIOSH REL: (To Inorganic Mercury) TWA 0.05 PROP: Silvery, heavy, mobile liquid. A liquid metallic element. Mp: -38.89°, bp: 356.9°, d: 13.534@ 25°, vap .... mg(Hg)/m3 press: 2 x w-3 mm@ 25°. Solid: tin-white, ductile, mal ...-r'HR: Poison by subcutaneous, intraperitoneal and intrave leable mass which can be cut with a knife. nous routes. Human systemic effects by intravenous route: 1 cardiac arrythmias. When heated to decomposition it emits SYNS: q COLLOIDAl. MERCURY NCI-C60399 toxic fumes of Hg. See also MERCURY COMPOUNDS. KWIK (DUTCH) QUECKSil.BER (GERMAN) I MERCURE (FRENCH) QUICK Sll.VER MCWOOO HR:3 MERCURIO (ITALIAN) RCRA WASTE NUMBER UUl MERCUROUS CHLORIDE MERCURY, METALLIC (DOT) RTEC (POLISH) CAS: 7546-30-7 NIOSH: OV 8750000 I TOXICITY DATA: CODEN: mw: 472.09 cyt-man-unr 150 JJ.g/m3 AEHLAU 34,461,79 3 PROP: White, odorless, tasteless, heavy powder or crystals. ihl-rat TCLo:890 nglm /24H GISAAA 45(3),72,80 Sublimes@ 400°, d: 7.150. Insol in H 0, ale and ether. (16W male): REP I 2 ihl-rat TCLo:7440 nglm3/24H GISAAA 45(3),72,80 Protect from light. Sunlight causes it to decamp into mercu (16W male):REP ric chloride and metallic Hg. ipr-rat TDLo:400 mglkg/140-1: ZEKBAI 61,511,57 ETA I SYNS: ihl-man TDLo:44300 JJ.glm3/8H: JOCMA7 20,532,78 CALOOREEN MERCUROCHLORIDE !DUTCH) CNS,LIV ,MET CALOMEL MERCURY(I) CHLORIDE ihl-wmn TCLo: 150 JJ.g/m3/46D: AEHLAU 33,186,78 CALOMELANO (ITALIAN) MERCURY MONOCHLORIDE CNS,GIT I CALOSAN MERCURY PROTOCHLORIDE skn-man TDLo: 129 mg/kg/5H DERAAC 172,48,86 CHLORURE MERCUREUX MILD MERCURY CHLORIDE C:EAR,CNS,SKN (FRENCH) PRECTPITE BLANC ihl-rbt LCLo: 29 mglm3/30H AMIHBC 7,19,53 C.l. 77764 QUECKSILBER(I)-CHLORID (GER· I CLORURO MERCUROSO (ITAL MAN) Mercury and its compounds are on the Community Right IAN) QUECKSILBER CHLORUER (GER" To Know List. CYCLOSAN MAN) 3 KALOMEL (GERMAN) SUBCHLORIDE OF MERCURY OSHA PEL: CL 0.1 mg!m 3 I ACGIH TLV: TWA 0.05 mg(Hg)/m (vapor, skin) CODEN: 3 DFG MAK: 0.01 ppm (0.1 mglm ) MUREAV 77,109,80 ENMUDM 7,381,85 NIOSH REL: (To Inorganic Mercury) TWA 0.05 3 GTPZAB 25(7),27 ,81 mg(Hg)/m I I MCW350 MERCURY(IJ) ACETYLIDE 2194 DOT Classification: Corrosive Material; Label: Corrosive SYNS: AMINOMERCURIC CHLORIDE MERCURY AMINE CHLORIDE THR: Poison by inhalation. An experimental tumorigen. AMMONIATED MERCURY MERCURY AMMONIATED Corrosive to skin, eyes and mucous membranes. Human MERCURIC AMMONIUM CHLO- WHITE MERCURY PRECIPrrATED systemic effects by inhalation: wakefulness, muscle weak RIDE. SOLID WHITE PRECIPrrATE ness, anorexia, headache, tinnitus, hypermotility, diarrhea, MERCURIC CIII.ORIDE, AMMONI ATED I liver changes, dermatitis, fever. An experimental teratogen. " Experimental reproductive effects. Human mutagenic data. Mercury and its compounds are on the Community Right Used in dental applications, electronics, and chemical syn To Know List. Reported in EPA TSCA Inventory. thesis. I ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin) May explode on contact with 3-bromopropyne; alkynes NIOSH REL: (To Inorganic Mercury) TWA 0.05 + silver perchlorate; ethylene oxide; lithium; methylsilane mg(Hg)/m3 + oxygen (explodes when shaken); peroxyformic acid; I chlorine dioxide; tetracarbonylnickel + oxygen. May react DOT Classification: Poison B, Label: Poison with ammonia to form an explosive product. Mixtures with THR: A poison. Explosive reaction with halogens or amine methyl azide are shock- and spark-sensitive explosives. The metal salts. When heated to decomposition it emits very vapor ignites on contact with boron diiodophosphide. Re II toxic fumes of Cl-, NO.x, and Hg. See also MERCURY acts violently with acetylenic compounds (e.g., acetylene, COMPOUNDS. sodium acetylide, 2-butyne-1,4-diol + acid); metals (e.g., I aluminum; calcium; potassium; sodium; rubidium; exo thermic formation of amalgams); Cl2; CI02; CH3N3; Na2C2; MCWS09 HR:3 nitromethane. Incompatible with methyl azide; oxidants. MERCURY(II) ORTHOARSENATE When heated to decomposition it emits toxic fumes of Hg. CAS: 7784-37-4 NIOSH: OV 7040000 I See also MERCURY COMPOUNDS. For further informa mf: AsH04•Hg mw: 340.52 tion, see Vol. 1, No. 3 of DPIM Report. DOT: 1623 SYN: MERCURIC ARSENATE (DOT) I MCW350 HR:3 MERCURY(II) ACETYLIDE Arsenic and its compounds, as well as mercury and its CAS:· 37297-87-3 compounds, are on the Community Right To Know List. mf: C Hg mw: 224.61 ,, 2 OSHA PEL: TWA 0.01 mg(As)/m3 Mercury and its compounds are on the Community Right ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin) To Know List. NIOSH REL: (To Inorganic Mercury) TWA 0.05 mg(Hg)/ 3 m3; (To Inorganic Arsenic) CL 0.002 mg(As)/m /15M I THR: A shock- and heat-sensitive explosive. Upon decom position it emits toxic fumes of Hg. See also MERCURY DOT Classification: Poison B; Label: Poison COMPOUNDS and ACETYLIDES. THR: Poison. When heated to decomposition it emits toxic ~ fumes of Hg and As. See also MERCURY COMPOUNDS MCW400 HR:3 and ARSENIC COMPOUNDS. MERCURY(II) aci-DINITROMETHANIDE I inf: C2H2HgN408 mw: 410.65 MCXOOO HR:3 Mercury and its compounds are on the Community Right MERCURY(I) AZIDE To Know List. CAS: 38232-63-2 NIOSH: OV 7045000 I THR: An explosive detonator. Upon decomposition it emits mf: Hg2N6 mw: 485.22 toxic fumes of Hg and NOr See also MERCURY COM SYNS: I POUNDS. MERCUROUS AZIDE (DOT) MERCURY AZIDE Mercury and its compounds are on the Community Right MCWSOO HR:3 To Know List. MERCURY AMIDE CHLORIDE I CAS: 10124-48-8 NIOSH: OV 7020000 ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin) DOT: 1630 DOT Classification: Forbidden mf: CIH2HgN mw: 252.07 THR: Poison. Explodes on heating in air. When heated to H NHgCI 2 decomposition it emits very toxic fumes of NO.x and Hg. PROP: White, pulverized lumps or powder. See also AZIDES• and MERCURY COMPOUNDS. I I 2197 MERCURY(II) CYANIDE MDA250 MCY755 HR:3 THR: The customary grouping of all organic mercurials MERCURY(II) CHLORITE in a single category is not fully justified by the toxicity of CAS: 7616-83-3 the compounds. Alkyl rnercurials have very high toxicity; \ mf: Cl2Hg04 mw: 335.49 aryl compounds, particularly the phenyls, are much less toxic, and the organornercurials used in therapeutics are SYN: MERCURY DICltLORITE I less toxic. The alkyls and aryls commonly cause skin bums Mercury and its compounds are on the Community Right and other forms of irritation, and both can be absorbed To Know List. through the skin. Fatal poisoning has occurred due to expo sure to alkyl rnercurials and permanent damage to the brain I THR: A poison. The dry chlorite is spontaneously explo has been reported. Phenyl rnercurials appear to be no more sive. Upon decomposition it emits toxic fumes of CJ- and toxic than metallic mercury. Organic mercury compounds, Hg. See also MERCURY COMPOUNDS and CHLO like organic lead compounds, seem to have an affinity for I RITES. lipoid-containing organs, resulting in central nervous sys MCZOOO HR:3 tem disturbances such as from tetraethyl lead. These are MERCURY COMPOUNDS, INORGANIC common air contaminants. Many mercury compounds are I explosively unstable or undergo hazardous reactions. When Mercury and its compounds are on the Community Right heated to decomposition they emit highly toxic fumes of To Know List. Hg. I THR: Mercury is a general protoplasmic poison; after ab sorption it circulates in the blood and is stored in the liver, MDAJOO HR:3 kidneys, spleen and bone. In industrial poisoning, the prin MERCURY(I) CYAN AMIDE cipal effect is upon the central nervous system, the mouth CAS: 72044-13-4 I and gums. The cardinal symptoms of industrial mercury rnf: CHg N rnw: 240.61 poisoning are stomatitis, tremors, and psychic disturbances. 2 2 Usually the first complaints are of excessive salivation and Mercury and its compounds are on the Community Right I painful chewing. In severe cases there may be gingivitis To Know List. with loosening of the teeth, and a dark line on the gum THR: A poison. Explodes when heated rapidly to 325°C .. margins resembling the "lead line." The psychic distur or when exposed to intense light while in a sealed container. .... bance (so called "erethism") includes loss of memory, When heated to decomposition it emits toxic fumes ofNOx, insomnia, lack of confidence, irritability, vague fears and CN- and Hg. See also MERCURY COMPOUNDS. depression. The dermatitis produced by fulminate of mer cury takes the form of small, discrete ulcers on the exposed I parts, and is usually accompanied by conjunctivitis and MDA150 HR:3 inflammation of the mucous membranes of the nose and MERCURY(II) CYANATE throat. In humans, it is readily absorbed by the respiratory CAS: 3021-39-4 I tract (elemental mercury vapor, dusts of mercury corn mw: 284.62 pounds), intact skin, and the gastrointestinal tract. Occa sional incidental swallowing of metallic mercury man be Mercury and its compounds, as well as cyanide and its I without harm. Spilled and heated elemental mercury is par compounds, are on the Community Right To Know List. ticularly hazardous. A number of mercury compounds, in THR: A poison. A pressure-sensitive explosive. When addition to the fulminate, can cause skin irritation and be heated to decomposition it emits toxic fumes of NOX, eN II absorbed through the skin. They are strong allergens and and Hg. See also MERCURY COMPOUNDS, CYANIDE, common air contaminants. Acute Toxicity: Soluble salts and CYANATES. have violent corrosive effects on skin and mucous mem- branes, cause severe nausea, vomiting, abdominal pain, il bloody diarrhea, kidney damage, and death usually within MDA250 HR:3 10 days. Many mercury compounds are explosively unsta MERCURY(II) CYANIDE ble or undergo hazardous reactions. When heated to decom CAS: 592-04-1 NIOSH: OW 1515000 position they emit toxic fumes of Hg. DOT: 1636 II rnf: C HgN rnw: 252.63 MDAOOO HR: D 2 2 II MERCURY COMPOUNDS, ORGANIC PROP: Colorless, odorless, transparent prisms; darkened by light. Decornp @ 320°, d: 3.996. Sltly sol in ether. I Mercury and its compounds are on the Community Right r To Know List. SYNS: I CYANURE de MERCURE (FRENCH) MERCURJC CYANIDE. SOUD DFG MAK: 0.01 rng!m3 (DOT) I 2477 NICKEL NCWSOO I TOXICITY DATA: CODEN: TOXICITY DATA: CODEN: skn-rbt 500 mg open MLD UCDS** 4/29/69 orl-rat TDLo:42 g/kg (350 pre): OYYAA2 14,755,77 orl-rat LD50:20 g/kg UCDS** 4129/69 REP orl-rat TDLo:45500 mg/kg (910 OYYAA2 14,853,77 Reported in EPA TSCA Inventory. malc):REP orl-rat LDSO: 20 g/kg NIIRDN 6,546,82 THR: Mildly toxic by ingestion. A skin irritant. ipr-rat LD50:5000 mg/kg NIIRDN 6.546,82 I scu-rat LD50: 5000 mg/kg NIIRDN 6,546,82 NCVSOO HR:I orl-mus LD50:20 g/kg NIIRDN 6,546,82 NIAX TRIOL 6000 ipr-mus LD50: 5000 mg/kg NIIRDN 6.546,82 CAS: 102395-10-8 NIOSH: QR 4600000 scu-m us LD50: 5000 mg/kg NIIRDN 6,546,82 orl-dog LD50:5000 mg/kg NIIRDN 6.546,82 I TOXICITY DATA: CODEN: orl-rht LDSO: 10 gtkg NIIRDN 6,546,82 skn-rbt 500 mg open MLD UCDS** 6115171 ipr-rbt LD50: 5000 mg/kg NIIRDN 6.546,82 orl-rat LD50:57 gtkg UCDS** 6115171 THR: Mildly toxic by ingestion. Experimental reproductive I THR: Mildly toxic by ingestion. A skin irritant. effects. When heated to decomposition it emits toxic fumes of NOt. See also ESTERS. NCWOOO HR:J I NIAZOL NCWSOO HR:3 CAS: 550-99-2 NIOSH: NJ 4375000 NICKEL mw: 246.76 mf: C 14H 14N2•CIH CAS: 7440-02-0 NIOSH: QR 5950000 I SYNS: af: Ni aw: 58.71 ALBALON LIQUIFJI.l\.1 2-f 1-NAPIITIIYl.METIIYI.I-!-IM Clf:RA IJ)AZOI.INE IIYiliHX "III.ORIIJE PROP: A silvery-white, hard, malleable and ductile metal. COLD AN PRIVINE HYDROCIILORIDE D: 8.90 (c1· 25°, vap press: I mm @; 1810°. Crystallizes I 4.5-DIIIYDR0-2-1 1-NAPIITHALE- PRJZOLE JIYDROCIILORIDE as metallic cubes. Mp: 1455°, bp: 2730°. Stable in air at NYLMETHYL)-IH-IMJDAZOLE RIIJNANTIN room temp. MONOHYDROCIILORIDE RIIINOPERD NAPIIAZOLINE IIYDROCIILORJDE SANORIN-SPOFA SYNS: I NAPHCON STRICYLON C.l. 77775 NICKEL SPONGE NAPIICON FORTE VASOCON Ni !7fl Ni 0901·5 2-( 1-NAPHTIIYLMETI IYLHMID NICKEL !70 Ni 4JOJT AZOLINE IIYDROCIILORIDE NICKEL (f)l1STl NP 2 NICKEL 1 ITM.f,\N l RANEY ALLOY TOXICITY DATA: CODEN: NICKEL PARTICLES RANEY NICKEL ipr-rat LDSO: 50 mg/kg JPETAB 86.284.46 seu-rat LD50:325 mg/kg JPETAB 86.284.46 TOXICITY DATA: CODEN: I ivn-rat LD50:6 mg/kg JPETAB 113,341.55 otr-ham: kdy 400 mg/L JAPUDO 53,193,84 seu-mus LDSO: 170 mg/kg JPETAB 86.2811.-lfi otr-ham :cmh 5 JllliOI/L TOXID I I NCXOOO NICKEL(III ACETATE (1 :21 2478 ims-rat TO :90 mg/kg/18W-J: NCIUS* PH 43-64- otr-ham: kdy 2:!5 mg/L IAPUOO 53.193.84 ETA 886.AUG.69 ivn-ham TDLo: 10 mg/kg (8D AD TEAS 5.5 I , 72 ims-rat TO : 889 J.Lg!kg: ETA JPTLAS 97.375.69 prcg):REP ipl-rat TO :1250 mg/kg/17W-I: TRBMAV 10.167.52 ims-rat TDLo:420 mg/kgi47W-I: NCIUS* PH 43-64- ETA NEO 8!!6.JUL.6!l ipl-rat TO :125 mg/kg/21W-I: PWPSAX 16.150.73 imp-rat TDLn:95 mg/kg17!!W-C: PAACA3 5,50,64 '- ETA ETA 1 ims-rat TO :200 mg/kg/21W-I: PWPSA8 14.68,71 ipr-rnus TDLo:360 mgikg/8W-l: CNREA8 36.1744.76 NEO NEO ims-rat TO: I g/kgii7W-I:CAR PAACAJ 9.28.68 ims-rat TD : :!25 mg/kg/46\V-I: NCIUS* PH 43-64- itr-rat LOLo: 12 mg/kg NTIS** AEC-TR-6710 ETA XS6.AUG,69 I ivn-mus L0Lo:50 mg/kg FATOAO 23.549.60 orl-rat L050:350 mglkg PWPSA8 11,39,68 ivn-dog LOLo: 10 mg/kg 14CYAT 2.1120.63 ipr-rat LOSO: 23 mgtkg PWPSA8 11.39.68 scu-rat LOLo: 12500 J.Lgikg NTIS** PD 158-508 orl-rnus LD50:-HO mg/kg PWPSA8 11.39.68 ipr-rbt LOLo: 7 mg/kg NTIS** PB I 58-50S ipr-rnus L050:32 mglkg PWPSA8 11.39.68 I scu-rbt LOLo: 7500 J.Lglkg NTIS** PBI5S-508 scu-gpg LOLo: 20 mgikg JOHY A Y 8.565.08 orl-gpg LOLo: 5 mg/kg AMPMAR 25.247.64 Nickel and ils compounds are on the Community Right IARC Cancer Review: Animal Inadequate Evidence To Know List. Reported in EPA TSCA Inventory. IMEMDT 2,126,73; Animal Sufficient Evidence I. IMEMDT 11.75.76. Reported in EPA TSCA Inventory. OSHA PEL: TWA I mg(Ni)tm·' Community Right To Know List. EPA Extremely Hazard ACGIII TLV: TWA 0.1 mg(Ni)/nr' I ous Substances List. NIOSH REL: (Inorganic Nickell TWA 0.015 mg(Ni)/nr' OSHA PEL: TWA I mg(Ni)/nr' TllR: Poison hy ingestion. intraperitoneal and subcutaneous ACGIH TLV: TWA I mg/m3 routes. An experimental neoplastigen and !umorigen. Ex NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/nr1 perimental reproductive effects. Mutagenic data. When heated to decomposition it emits irritating fumes. See also THR: Poison by ingestion. intratracheal. intraperitoneal. NICKEL COMPOUNDS . • subcutaneous and intravenous routes. An experimental car cinogen, neoplastigen, tumorigen, and teratogen. Experi mental reproductive effects. Ingestion of soluble salts causes NCXSOO HR:J • nausea, vomiting, diarrhea. Mutagenic data. Hypersensitiv NICKEL ACETATE TETRAHYDRATE p ity to nickel is common and can cause allergic contact CAS: 6018-89-9 NIOSH: QR 6126000 dermatitis, pulmonary asthma, conjunctivitis. and inflam mf: Co~Hli04 •Ni•4H 2 0 mw: 248.89 matory reactions around nickel-containing medical implants TOXICITY DATA: CODEN: and prostheses. Powders may ignite spontaneously in air. cyt-mus:mmr 100 J.LIDOI/L MUREAV 68,337.79 Reacts violently with F ; NH N0 : hydrazine: NH : (H r 2 4 3 3 2 ipr-mus L050:45700 J.Lglkg RCOCBS 30.133,80 + dioxane); performic acid; P; Se; S; (Ti + KCJOJ). Incom Nickel and its compounds are on the Commu.nity Right patible with oxidants (e.g .• bromine pentafluoride; peroxy To Know List. formic acid; potassium perchlorate; chlorine: nitryl fluoride; ammonium nitrate). Raney-nickel catalysts may initiate OSHA PEL: TWA I mg(Ni)/m3 hazardous reactions with ethylene + aluminum chloride; ACGIH TLV: TWA 0.1 mg(Ni)tm3 p-dioxane; hydrogen; hydrogen + oxygen; magnesium sili NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m3 cate; methanol; organic solvents + heat; sulfur compounds. Nickel catalysts have caused many industrial accidents. For THR: Poison by intraperitoneal route. Mutagenic data. further information, see Vol. 3. No. 3 of DPIM Report. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL(ll) ACETATE and I NICKEL COMPOUNDS. NCXOOO HR:J NICKEL(II) ACETATE (1:2) I CAS: 373-02-4 NIOSH: QR 6125000 NCYOOO HR:D mw: 176.81 NICKEL ALLOY, Ni,Be CAS: 37227-61-5 NIOSH: QR 6126300 PROP: Green prisms. Mp: decomp. d: 1.798. I SYN: UERYLLIUM·NICKEL ALLOY SYNS: ACETIC ACID. NICKEL!2+l SALT NICKELOUS ACEl"ATE IARC Cancer Review: Animal Inadequate Evidence I TOXICITY OAT A: CODEN: IMEMDT 23,143,80. Nickel and its compounds as well pic-esc I 60 J.Lmoi!L ENl\lllDM 6.59.84 as beryllium and its compounds are on lhe Community r dns-rat-ipr 129 11mollkgiSD-I CRNGDP 6.1819.85 Right To Know List. I I 3011 SELENIUM 580500 SeO[N(CHJhh SBOSOO HR:J SELENIUM Selenium and its compounds are on the Community Right CAS: 7782-49-2 NIOSH: VS 7700000 To Know List. DOT: 2658 '- OSHA PEL: TWA 0.2 mg(Se)/m3 af: Se aw: 78.96 1 ACGIH TLV: TWA 0.2 mg(Se)tm3 PROP: Steel gray, non-metallic clement. Mp: 170-217°, THR: Selenium compounds are poisons. May decompose bp: 690°, d: 4.81-4.26, vap press: I mm @ 356°. Jnsol explosively when heated above 50°C. When heated to de in H20 and ale; very sltly sol in ether. I composition it emits toxic fumes of NO.. and Se. See also SYNS: SELENIUM COMPOUNDS. C.J. 7780~ SELENIUM DUST COLLOIDAL SELENIUM SELENIUM ELEMENTAl. I EI.EMENTI\1. SEI.ENIIIM SI'.I.ENIIJM IIOMOPOI.YMER SELEN IPOLISII) SEI.ENIUJ\.1 MJ,.'fAL I'OWI>ER. SBN550 HR:3 SELENIUM ALLOY NON-PYROPIIORJC fDOT) SELENINYL BROMIDE SELENIUM BASE VANDEX CAS: 7789-51-7 mw: 254.77 TOXICITY DATA: CODEN: orl-mus TDLo: 134 mg/kg AEHLAU 23,102,71 Selenium and its compounds are on The Community Right (MGN):TER I To Know List. orl-mus TDLo:480 mg/kg/600· YMBUA7 11,368,60 C:ETA OSHA PEL: TWA 0.2 mg(Seltm3 orl-rat LD50:6700 mg/kg TXAPA9 20,89,71 ACGIH TLV: TWA 0.2 mg(Se)/m3 ihl-rat LDLo:33 mg/kg/!!H AMIHBC 4,458,51 I ivn-rat LD50:6 mg/kg AMIHBC 4,458,51 THR: Selenium compounds are poisons. Explosive reaction ivn-rbt LDLo:2500 IJ.g!kg JOGBAS 35,693,28 with white phosphorous. Violent reaction with sodium; po unr-frg LDLo:3 mg/kg PHREA7 23,305,43 I; tassium; zinc; red phosphorous. When heated to decomposi Selenium and its compounds are on the Community Right tion it emits toxic fumes of Br- and Se. See also SELE To Know List. Reported in EPA TSCA Inventory. NIUM COMPOUNDS. OSHA PEL: TWA 0.2 mg(Se)tm3 p ACGIH TLV: TWA 0.2 mg/m3 DFG MAK: 0.1 mgtm3 SBOOOO HR:J SELENIOUS ACID DOT Classification: Poison B, Label: St. Andrews Cross I CAS: 7783-00-8 NIOSH: VS 7175000 THR: Poison by inhalation, intravenous and possibly other mw: 128.98 routes. An experimental tumorigen and teratogen. Experi PROP: Transparent, colorless crystals. Mp: dccomp, d: mental reproductive effects. Occupational exposure has I 3.004 @ 15°/4°, vap press: 2 mm @ 15°. Very sol in caused pallor, nl!rvousness, depression, garlic odor of ale; insol in ammonia. breath and sweat, gastrointestinal disturbances and dermati tis. Liver damage in experimental animals. Chronic inges SYNS: tion of 5 mg of selenium per day resulted in 49% morbidity I RCRA WASTE NUMBER U204 SELENIUM DIOXIDE in 5 Chinese villages. The main symptoms were brittle I TOXICITY OATA: CODEN: hair with intact follicles, new hair with no pigment, brittle cyt-hmn:lym 10 J,Lmoi!L ESKGA2 26,99,80 nails with spots and streaks, skin lesions, peripheral an I orl-rat LDLo:25 mg/kg NCNSA6 5,28,53 esthesia, acroparaesthesia, pain, and hyperreflexia. Similar ipr-rat LDLo: 10 mg/kg NCNSA6 5,28,53 effects have been seen in populations with selenium blood I. ivn-mus LD50: II mglkg CSLNX* NX#05656 levels of 800 tJ.g!L. In cattle, "alkali disease" is associated EPA Extremely Hazardous Substances List. Selenium and with consumption of grain or plants containing 5-25 mgl its compounds are on the Community Right To Know List. kg of selenium. The symptoms are lack of vitality, loss Reported in EPA TSCA Inventory. of appetite, emaciation, deformation and shedding of hoofs, loss of hair, and erosion of joints. Consumption of plants OSHA PEL: TWA 0.2 mg(Se)/m3 I grown in seleniferous areas can cause effects in humans ACGIH TLV: TWA 0.2 mg(Se)/m3 and animals. Selenosis in humans has occurred from inges THR: Poison by ingestion, intraperitoneal and intravenous tion of 3.2 mg selenium per day. Selenium is an essential routes. Human mutagenic data. Used as an oxidizing agent. trace element for many species. When heated to decomposition it emits toxic fumes of Se. Reacts to form explosive products with metal amides. ~ See also SELENIUM COMPOUNDS. Can react violently with barium carbide; bromine penta- I I SBPOOO SELENIUM (COLLOIDAL) 3012 fluoride; calcium carbide; chlorates; chlorine trifluoride; SBQOOO HR: J chromic oxide (Cr03); fluorine; lithium carbide; lithium SELENlUM DIMETHYLDITHIOCARBAMATE silicon (Li 6 Si 2); metals; nickel; nitric acid: sodium; nitrogen CAS: 144-34-3 NIOSH: VT 0780000 trichloride; oxygen; potassium: potassium bromate: ru mw: 559.84 bidium carbide; zinc: silver bromate: strontium carbide; PROP: Yellow powder, crystals. D: 1.58, melting range: '- thorium carbide; uranium. When heated to decomposition 140-172°. 1 it emits toxic fumes of Se. See also SELENIUM COM POUNDS. For further information, see Vol. I, No. 3 of SYNS: DPIM Report. METHYL SELENAC TETRAKISIDIMETIIYLCAR· I BAMODITIIIOATO-S .S' I SELENIUM SBPOOO HR:J IARC Cancer Review: Animal Inadequate Evidence IM I SELENIUM (COLLOIDAL) EMDT 12.161. 76. Selenium and its compounds are on CAS: 7782-49-2 NIOSH: VS 8310000 the Community Right To Know List. Reported in EPA af: Se aw: 78.96 TSCA Inventory. 3 TOXICITY OAT A: CODEN: OSHA PEL: TWA 0.2 mg(Se)/m 3 ivn-rat LDLo: 6 mgtkg JPETAB 33.270.28 ACGIH TLV: TWA 0.2 mg(Se)/m Selenium and its compounds are on the Community Right THR: Selenium compounds are poisons. May be a carcino To Know List. Reported in EPA TSCA Inventory. gen. When heated to decomposition it emits very toxic fumes of Se. SOr. and NO_,. See also SELENIUM COM OSHA PEL: TWA 0.2 mg(Se)/m~ POUNDS and CARBAMATES. ACGlll TLV: TWA 0.2 rng(Sc)lm' THR: Poison by intravenous route. When heated to decom . position it emits toxic fumes of Se. See also SELENIUM SBQSOO HR: 3 and SELENIUM COMPOUNDS. SELENIUM(IV) DIOXIDE (1: 2) II CAS: 7446-08-4 NIOSH: VS 8575000 mw: 110.96 p SBPSOO HR:J PROP: White to sltly reddish, lustrous. crystalline powder SELENIUM COMPOUNDS or needles. Mp: 340-350° (sublimes), d: 3.95 @ I5°/l5°, vap press: I mm@ 157.0°. Selenium and its compounds are on the Community Right To Know List. · SYNS: RCRA WASTE NUMBER U2().1 SELENIUM DIOXIDE 3 OSHA PEL: TWA 0.2 mg(Se)/m SELENIOUS ANHYDRIDE SELENIUM OXIDE c ACGIH TLV: TWA 0.2 mg(Se)/m3 TOXICITY DATA: CODEN: I THR: Poison by inhalation and intravenous routes. Consid mrc-bcs 10 mmoi!L MUREAV 77.109,80 ered to be experimental carcinogens. Selenium in small ipr-rat TDLo: 2160 JLg/kg (900 IJPPAZ 27,237.83 amounts is essential for normal growth of some animals. male):REP scu-grb TDLo:5600 JLglkg (ID JRMSAS 85,297,65 Deficiency or excess is associated with serious disease in male):REP livestock. Long-term exposure may be a cause of amyo ihl-rbt LCLo:5890 mg/m3t20M NTIS** PB 158-508 trophic lateral sclerosis in humans, just as it may cause scu-rbt LD50:4 mg/kg CTOXAO 17.171,80 "blind staggers" in cattle. Elemental selenium has low scu-grb LDLo: 7500 JLglkg JRMSAS 85,297.65 3 I acute systemic toxicity, but dust or fumes can cause serious ihl-dom LCLo:6590 mglm /IOM NTIS** PB158-508 irritation of the respiratory tract. Hydrogen selenide resem Selenium and its compounds are on the Community Right bles other hydrides in being highly toxic. and selenium To Know List. Reported in EPA TSCA Inventory. EPA I oxychloride is a vesicant. Some organoselenium compounds Genetic Toxicology Program. have the high toxicity of other organometals. Inorganic OSHA PEL: TWA 0.2 mg(Se)/m3 selenium compounds can cause dermatitis. Garlic odor of ACGIH TLV: TWA 0.2 mg(Se)lm3 I breath is a common symptom. Pallor. nervousness. depres sion, digestive disturbances and death have been reported THR: Poison by subcutaneous route. Mildly toxic by inhala in cases of chronic exposure. Selenium compounds are com tion. Mutagenic data. Experimental reproductive effects. mon air contaminants. When heated to decomposition it Incompatible with PCI3• Used as an oxidizing agent. When emits toxic fumes of Se. See also SELENIUM and specific heated to decomposition it emits toxic fumes of Se. See compounds. also SELENIUM COMPOUNDS. I ------··· - --- I SDHOOO SILICON OXIDE 3026 SYNS: THR: An experimental tumorigen by implant. In the form SILICON TETRAR..UORIDE ([)OTI TETRAFI.UOR!JSII.ANE of dust it is an allergen and a nuisance dust. Flammable Reported in EPA TSCA Inventory. when exposed to heat or flame. A moderate explosion haz ard. When heated to decomposition it emits acrid smoke OSHA PEL: TWA 2.5 mg(F)/m 3 and irritating fumes. See also POLYMERS, INSOLUBLE. 1'- ACGIH TLY: TWA 2.5 mg(F)/nr' NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg!F)/m~ S/J/500 IIR: 2 DOT Classification: Nonflammable Gas: Lahcl: Nonllam- SILVER I mable Gas; Poison A: Label: Poison Gas. Corrosive CAS: 7440-22-4 NIOSH: VW 3500000 THR: A poison. A corrosive irritant to skin. eyes. and af: Ag aw: 107.868 mucous membranes. When heated to decomposition it emirs PROP: Sort. ductile, malleable, lustrous. white metal. Mp: I toxic fumes of F-. See also FLUORIDES and HYDRO 961.93°. bp: 2212°, d: 10.50@ 20°. FLUORIC ACID. SYNS: ARc;unuM SILBER !GERMANI SDHOOO fiR: 3 Cl. 77X~Il SILVER ATOM I SILICON OXIDE SIIELL SIL \'ER CAS: 10097-28-6 TOXICITY DATA: CODEN: I mf: OSi mw: 44.09 mul-rat TDLo:330 mg/kg/43\V- ZEKBAI 63,586,60 THR: Ignites spontaneously in air. J:ET/\ imp-rat TOLo: 2400 mg/kg: ETA CNREA8 16,439,56 imp-mus TDLo: II g/kg: ETA NATWAY 42,75,55 SDHSOO HR:J imp-rat TO :2570 mgtkg: ETA NATWAY 42.75,55 I SILICON TETRAAZIDE ihl-hmn TCLo: I mg/m 3 :SKN DTLVS* 3,231,71 CAS: 27890-58-0 Silver and its compounds are on the Community Right To I mw: 196.17 Know List. Reported in EPA TSCA Inventory. THR: Has exploded spontaneously. When heated to decom OSHA PEL: TWA 10 J.Lglm3 position it emits toxic fumes of NOx· See also AZIDES. ACGIH TLV: TWA (metal) 0.1 mglm\ (soluble com- pounds as Ag) 0.01 mg/m 3 II 3 SD/1670 IIR: 2 DFG MAK: 0.01 mg/m SILICON TRIETHANOLA.l\IIN THR: An experimental tumorigen. Human systemic effects CAS: 42959-18-2 NIOSII: JG 6716000 by inhalation: skin effects. Inhalation of dusts can cause I mf: CxH 1qNO.,Si mw: 205.37 argyrosis. Flammable in the fom1 of dust when exposed to SYNS: name or by chemical reaction with C2H2: NH 3; bromoazide: 2.2-DIMETIIYL-I.J.IliOXA-f>-t\ZA· T.E.A.S. CIF,: ethylene imine: H20 2; oxalic acid; H2S04; tartaric I 2-SILACYCLOOCTANE-6-ETIIA· TRIETIJ,\NOI.A!\IINE SIUCIEE acid. Incompatible with acetylene: acetylene compounds; NOL 1FRENCII1 aziridine: bromine azide; 3-bromopropyne; carboxylic ac DIMETHYL· I. I -DIOXA-2.8-IIY • DROXYETIIYL-5 SILA·I AZA-5 ids: copper + ethylene glycol; electrolytes + zinc; ethanol I CYCLOOCTANE I FRENCH I + nitric acid: ethylen oxide: ethyl hydroperoxide; ethylene imine: iodoform; nitric acid; ozonides; peroxomonosulfuric TOXICITY DATA: CODEN: acid: peroxyformic acid. For further information, see Vol. orl-rat LD50:3400 mg/kg THERAP 32.517.77 I ipr-rat LD50: 1920 mg/kg THERAP 32.517,77 I. No. I of DPIM Report. See also POWDERED METALS orl-mus LD50:3900 mg/kg EJMCA5 16.425.81 and SILVER COMPOUNDS. ipr-mus LD50:2230 mgikg EJMCA5 16.425.81 I THR: Moderately toxic by ingestion and intraperitoneal SDJOOO HR:J routes. When heated to decomposition it emits toxic fumes SILVER ACETYLIDE of NOr CAS: 7659-31-6 mf: C2Ag 2 mw: 239.76 I SDIOOO HR:2 Ag~Ag SILK NIOSH: YW 2700000 Silver and its compounds are on the Community Right To Know List. TOXICITY OAT A: CODEN: imp-rat TDLo: 36 mg/kg: ETA CNREA8 15.333 ..55 DOT Classification: Forbidden I I 3039 SODIUM ACETARSONE SEGOOO SEESOO HR:J als. To fight fire, use soda ash, dry sodium chloride or SODIUM graphite, in order of preference. When heated to decomposi CAS: 7440-23-5 NIOSH: VY 0686000 tion it emits toxic fumes of Na20. See also SODIUM HY DOT: 1428/1429 DROXIDE and HYDROGEN. For further information, see mf: Na mw: 22.9898 Vol. I, No. 8 of I>P//H Report. PROP: Light, sofl, ductile, malleable, silver-white metal. SEFOfJfJ IJR: 3 Mp: 97.81°, bp: 881.4°, d: 0.9710 (iv 20°, autoign temp: SODIUM (liquid alloy) > 115° in dry air, vap press: 1.2 mm iodine monochloride; iodine pentafluoride; lead oxide; maleic anhydride; manga DOT Classification: Label: Flammable solid and Dangerous nous chloride; mercuric bromide; mercuric chloride; men:u When Wet ric fluoride; mercuric iodide; mercurous chloride; mercurous THR: A very dangerous fire hazard when exposed to heat I oxide; methyl chloride; molybdenum trioxide; monoammo I or flame or by chemical reaction. These are very reactive nium phosphate; nitric acid; nitrogen peroxide; nitrosyl forms of sodium which, if carelessly handled, may catch fluoride; nitrous oxide; phosgene; phosphorus; phosphorous fire. After sodium has been extinguished, the burning or pentafluoride; phosphorus pentoxide; phosphorus tribro I ganic vapor can be dealt with by very cautious use of a mide; phosphorus trichloride; phosphoryl chloride; potas carbon dioxide extinguisher. To extinguish, see SODIUM. sium oxides; potassium ozonide; potassium superoxidc; se Do not use carbon tetrachloride. Moderate explosion hazard lenium; silicon tetrachloride; silver bromide; silver chloride: by chemical reaction; will react with water or steam to I silver fluoride; silver iodide; sodium peroxide; stannic chlo produce heat and hydrogen; on contact with oxidizing mate ride; stannic iodide with sulfur; stannic oxide; stannous rials it can react vigorously, and on contact with acid or chloride; sulfur; sulfur dibromide; sulfur dichloride; sulfur acid fumes it can emit toxic fumes. When heated it loses dioxide; sulfuric acid; tellurium; tetrachloroethane; thallous I the solvent and emits highly toxic fumes of Na 0. See bromide; thiophosphoryl bromide; trichlorethylene; vana 2 also SODIUM and individual dispersant. dium pentachloride; vanadyl chloride; zinc bromide; any oxidizing material. Decomposes moisture to evolve hydro I SEGOOO HR:J gen and heat. Reacts exothermally with halogens, acids SODIUM ACETARSONE and halogenated hydrocarbons. CAS: 5892-48-8 NIOSH: CF 8750000 Heated sodium is spontaneously flammable in air. Can mf: C H AsN0 •Na mw: 297.09 I be safely stored under liquid hydrocarbons. Dangerous ex 8 9 5 plosion hazard when exposed to moisture in any fonn! SYN: N-ACETYL-4-IIYDROXY·m·ARSANILIC ACID SODIUM SALT Keep away from water at all times! When heated in air it TOXICITY OATA: CODEN: emits toxic fumes of sodium oxide. Reacts with water or ivn-rat LDLo:750 mg/kg ADSYAF 25,799,32 steam to produce heat, hydrogen, and flammable vapors. orl-cat LDLo: 125 mg/kg PSEBAA 27,267,30 Can react vigorously to explosively with oxidizing materi- orl-rbt LDLo: 150 mg/kg PSEBAA 27,267,30 I I 3511 ZINC ZBJOOO THR: Mutagenic data. When heated to decomposition it emits toxic fumes of Br-, NOr and HCI. See also ZIMELIDINE. ZBJOOO HR:3 ZBASOO HR: 3 ZINC ZIMELIDINE '- CAS: 7440-66-6 NIOSH: ZG 8600000 1 CAS: 56775-88-3 NIOSH: UC 6555000 DOT: 1383/1436 mf: C .6H 7BrN mw: 317.26 1 1 2 af: Zn aw: 65.37 SYNS: PROP: Bluish-white, lustrous, metallic element. Mp: I CZI-3·(4'·BROMOPHENYLI-3-(3''. 3+1-BROMOPIIENYLI-N .N-DI PYRIDYLIDIMETIIYL METHYL-3-(3-PYRIDINYLI-2- 419.8°, bp: 908°, d: 7.14 @ 25°, vap press: I mm @ ALLYLAMINE PROPEN-1-AMINE 487°. Stable in dry air. 3-(p-BROMOPHENYLI-N .N -DI cis-H 102.09 I I'o1ETIIYL-3-(3·PYRIDYI.I cis-ZIMELIDINE SYNS: ALLYLAMINE. IZI·ZIMELIDINE llt.UE POWDER PASCO C.l. 77945 ZINC OUST TOXICITY DATA: CODEN: C.l. PIGMENT BLACK 16 ZINC POWDER I orl-wmn T0Lo:56 mg/kg/140: BMJOAE 285,1009,82 C.l. PIGMENT METAL 6 ZINC. POWDER OR DUST. NON GIT.CNS EM ANA Y ZINC DUST PYROPIIORIC COOTI orl-rat LD50:900 mg/kg ORUGAY 24,169,82 GRANULAR ZINC ZINC, POWDER OR DUST, PYRO· ivn-rat LD50:50 mg/kg DRUGAY 24,169,82 JASAD PIIORIC COOT) I orl-mus LD50:800 mg/kg ORUGAY 24,169,82 MERRILLITE ivn-mus LD50:60 mg/kg ORUGAY 24,169,82 TOXICITY DATA: CODEN: THR: Poison by intravenous route. Moderately toxic by skn-hmn 300 JLg/30-1: MLO 85DKA8 -.127,77 I ingestion. Human systemic effects by ingestion: muscle ihl-hmn TCLo: 124 mg/m3/50M: AIIYGAJ 72,358,10 weakness, headache and nausea. When heated to decompo PUL.SKN sition it emits toxic fumes of Br- and NOr. Zinc and its compounds are on the Community Right To Know List. Reported in EPA TSCA Inventory. EPA Ge I netic Toxicology Program. ZBA525 HR: 3 DOT Classification: Flammable Solid; Label: Dangerous p ZIMELIDINE DIHYDROCHLORIDE When Wet, non-pyrophoric; Flammable Solid; Label: CAS: 60525-15-7 NIOSH: UC 6555200 Spontaneously Combustible, pyrophoric mf: C16H17 BrN2 •2CIH mw: 356.70 THR: Human systemic effects by ingestion: cough, dyspnea SYNS: and sweating. A human skin irritant. Pure zinc powder, I IZI-3·(4-BROMOPIIENYL)-N.N-DI 11102109 HYDROCHLORIDE METIIYI.-3-13-PYRIOINYI.I-2· ZIMEI.IOINE IIYOROCIII.ORH>E dust, fume is relatively non-toxic to humans by inhalation. I'Rfii'EN·I·AMINE lllliYimf>· The difficulty :~rises from oxidation of zinc fumes immedi Clli.ORIIIE ately prior to inhal:~tion or presence of impurities such as I Cd, Sh, As, Ph. Inhalation may cause sweet taste, throat TOXICITY DATA: CODEN: dryness, cough, weakness, generalized aches, chills, fever, orl-rat TOLo: 120 mg/kg (6-170 KSRNAM 17.1833.1!3 preg):REP nausea, vomiting. I orl-rat TDLo: 12 mg/kg (6-170 KSRNAM 17,1833,83 Flammable in the form of dust when exposed to heat preg):REP or Harne. May ignite spontaneously in air when dry. Explo orl-rat LD50:844 mg/kg APSXAS 20,295,83 sive in the form of dust when reacted with acids. Incompati ipr-rat LD50: 99800 JLg!kg APSXAS 20,295,83 ble with NH~N0 ; Ba0 ; Ba(N0 )z; Cd; CS ; ehlorates; I scu-rat LD50:227 mg/kg APSXAS 20,295,83 3 2 3 2 ivn-rat L050:45800 JLg/kg KSRNAM 17,1833,83 Cl 2; CIF3; Cr03; (ethyl acetoacetate + tribromoneopentyl orl-mus LD50:341 mg/kg KSRNAM 17,1833,83 alcohol); F2; hydrazine mononitrate; hydroxylamine; ipr-mus LD50: 84400 JLglkg APSXAS 20,295,83 Pb(N 3h; (Mg + Ba(N03)z + Ba02); MnCI2; HN03; per I scu-mus LD50: 154 mg/kg KSRNAM 17,1833,83 formic acid; KCI03; KN03; K20 2; Se; NaCI03; Na202; ivn-mus LD50:27700 KSRNAM 17,1833,83 S; Te; H20; (NH hS; As 0 ; CS2; CaCI ; NaOH; chlori JLg/kg 4 2 3 2 orl-dog LD50:271 mg/kg KSRNAM 17,1833,83 nated rubber; catalytic metals; halocarbons; o-nitroanisole; I ivn-dog LD50: 57 mg/kg KSRNAM 17,1833,83 nitrobenzene; non-metals; oxidants; paint primer base; pen orl-cat LDLo:80 mg/kg APSXAS 20,295,83 tacarbonyliron; transition metal halides; seleninyl bromide. orl-rbt LD50:300 mg/kg KSRNAM 17,1833,83 To fight fire, use special mixtures of dry chemical. When ivn-rbt LD50:50800 JLglkg KSRNAM 17,1833,83 heated to decomposition it emits toxic fumes of ZnO. See THR: Poison by ingestion, subcutaneous, intravenous and also ZINC COMPOUNDS. For further information, see intraperitoneal routes. Experimental reproductive effects. Vol. 1, No. 7 of DPIM Report. I PA-Score 1.0 scoresheets Page: 1 WINSTON CONTAINER COMPANY - 10/11/91 REFERENCE LIST Preliminary Assessment, Winston Container Company, NCD 024 477 556, 20 Dec 85, NC Solid and Hazardous Waste Management Branch, Raleigh, NC USGS 7.5' Quadrangle Maps: Charlotte West, 1968, (photorevised 1980), Derita, 1972; Charlotte East, 1967, (photorevised 1988); Mountain Island Lake, 1969, (photoinspected 1983). summary Trip Report: Site Investigation, 22 June 90, Winston Container Company, NCO 024 477 556, George Tyrian, HDR Engr. Inc. of NC, letter to Grover Nicholson, NC Superfund Section. RCRA Notification, 19 Nov 80; RCRA Status Change Notification, 20 June 85; Winston Container Company; Lab Report, 22 July 85, NC Div. of Public Health; Air Quality Permit, 22 Aug 88, Mecklenburg County. 5. Geology and Groundwater Resources in the Charlotte Area, NC, Bull. No. 63, NC Dept. of Conservation and Development, Div. of Mineral I Resources, USGS, Dept. of the Interior, 1952. 6. Surface Water Intake Inventory and Map for Mecklenburg County, NCDEHNR Div. of Health Services, Environmental Health Section, Water Supply Branch, May 1990. Basic Elements of Ground-water Hydrology with Reference to Conditions in North carolina, Heath, R.C., USGS Water Resources Investigation Open File Report 80-44. Climatic Atlas of the United States, US Dept. of Commerce, National Climatic Center, Asheville, NC, 1979. Rainfall Frequency Atlas of the UNited States, Tech. Paper No. 40, us Dept. of Commerce, US Government Printing Office, Washington, DC, 1963 North Carolina state Government Statistical Abstract, 5th Ed., Office of State Budget and Management, Raleigh, NC, 1984. Memo and maps to Superfund Branch staff from Pat DeRosa, NC Superfund Branch, 18 May 89, Telecon with J. Fridell and D. Mignigno, us Fish and Wildlife Service, Asheville and Raleigh, NC. Memo to file from Fred Wu, HDR Engr. Inc., 5 July 90, meeting with F. Armstrong, HDR Engr. Inc. and D. Gwaltney, Public Services Supervisor, Charlotte-Mecklenburg Utility District. Public Water Supply Data Sheets for Mecklenburg County, NCDEHNR, Div. of Health Services, Environmental Health Section, Water Supply Branch, 20 April 90. Memo to file from George Tyrian, HDR Engr. Inc., 22 June 90, telecon with Eric Robinson, City of Lancaster, SC. I I 15. Memo to file from George Tyrian, HDR Engr. Inc., 21 June 90, telecon with Tony Roux , Mecklenburg county Dept. of Environmental Protection . Memo to file from George Tyrian, HDR Engr. Inc., 12 July 90, telecon ... with Jan Hoffman, Soil Conservation Service, Mecklenburg County. Memo to file from George Tyrian, HDR Engr. Inc., 29 June 90, Telecon with Fred Ross, Winston Container Company. Dangerous Properties of Industrial Materials, 7th Ed., edited by N.I. Sax and R.J. Lewis, Sr., Van Nostrand Reinhold Company, New York, 1984 Uncontrolled Hazardous Waste Site Ranking System, A Users Manual, HW-10, USEPA, 1984. List of day care facilities in Mecklenburg County, NCDEHNR, Div. of Facility Services, Child Care Section, May 1990. Hydric Soils of North Carolina, USDA, scs, Raleigh, NC, October 1989. Population Estimate: Winston Container Company, prepared by George Tyrian, HDR Engr. Inc., 31 July 90. Memo to file from Lisa Chisholm, HDR Engr. Inc., 22 Feb 91, telecon with Harvey Allen, NCDEHNR, Superfund Section, and "Conditions Necess I ary to Document an Observed Release,"from "The Proposed Revised HRS". 24. Memo to Superfund Section Technical Staff from Pat DeRosa, NC Super fund Section, 28 June 1991, US Census Bureau 1990 Population Data, Persons Per Household by County. • Memo to Superfund Staff from Mary Ganley, geologist, NC Superfund Section, 20 March 1991, Well Head Protection Areas in North Carolina. National Flood Insurance Program, Flood Insurance Rate Map, City of Charlotte, North carolina, Mecklenburg county, Panel 12 lf 31, map revised 26 February 1982. Memo to file from Grover Nicholson, NC Superfund Section, 20 Sep 91, Winston Container Company, NCO 024 477 556, Fisheries and fishing on Taggart and Sugar Creeks. Analyses of samples taken on the site on 23 october 1990. I I I {' I I .. I I Appendix A I Maps and Photographs I I I I 1- I I I I I I ••I I I List of Figures Winston Container Corp. .. NCD 024 477 556 I 1. USGS 7.5' Quadrangle Maps: Charlotte West Quadrangle, 1968 I (photorevised, 1980); Derita, NC, 1972; Charlotte East, 1967 (photorevised 1988); Mountain Island Lake, 1969 (photoinspected, 1983). I. 2. Site Layout, Winston Container Corp. I 3. Sampling Locations. I I I le I I I I I I •. I I I .. Figure 1 I I I I I I I 1-. I I I I I I •. I I ITED- STATES NT OF THE INTERIOR OG ICAL SURVEY NO LAKE QUADRANGLE DERITA QUADRANGLE NORTH CAROLINA-MECKLENBURG CO. MINUTE SERIES (TOPOGRAPHIC) WATER SYS TEM KEY NUMBER §YS TEM 000 Hu ntwood MHP 153 Ki llian MHP 155 173 bakeside MHP 191 ~ arkwood MHP 192 &o urtney s;o 196 TU cker MHP §erryhill, Holiday , We stwood MHP 214 Fo rest Ridge S/0 ___ .,., 229 bawyers Stn S/D 481 ~ ou ntry Nanor Charlotte Water District SC HOOL KEY LETTER SC HOOL A Berryhill El em. 8 Amay James Elem . c Sedgefield Elem . 0 Col linswood Elem . E Ken nedy JHS F Marie Davi s El em. G Barringer Elem . H Westerly Hill s Elem . I Harding HS ~118 J 510000 Ashley Park Elem . K Herbert Spaugh Middl e Sc hool L Brun 's Ave Elem. N Thomasboro Elem. N Allenbrook Elem . 0 Paw Cree k Christian Academy p Tuckasagee Elem. Q Wilson Middle Sc hool R We st Mecklenberg HS Mapped. edited, and published by· the G~ological Survey Control by USGS, NOS/NOAA, and North Carolina Geodetic Survey ~ nooo.. E. Topography by photogrammetnc methods tram aenal photographs * ROAD CLASSIFICATION Pnmary h1ghway, all weather, taken 1965 F1eld checked 1968 "' Light-duty road, all weather, ughway, all weather, " hard surface L1ght duty road, all weather, Polycontc projeCtion improved su rfa ce ,ace Improved surface 10,000-foot grid based on North Carolma coc;r,g'ifiate system ... Secondary highway, all weather, Ummproved road , fair or dry highway, all weather, BO MI LS 0"02' CONTOUR INTERVAL 10 FEET Unimproved road fa1r or dry 1000-meter Universal Transverse Mercator gr;a Rcks , zone 17 , 1 MIL hard surface__ weather______,...... ,.,,,ace NATIONAL GEODETIC VERTICAl DATUM OF 1929 weather ~~~== == =- shown 1n blue. 1927 North Amer1can Datu m Interstate Route U S Route State Route U S Route Q Q Q Q State Route To place on the predicted Nortll Amencan DaWff/ 1983 move the 0 projectton lines 10 meters south and 17 met§§ west as UTM GRID AND 1980 MAGNETIC NORTH shown by dashed corner t1cks OECUNAnON AT CENTER OF SHE ET ~ CHARLOTTE WEST,N.C QUADRANGLE LOCATION CHARLOTTE EAST, N.C. Revisions shown m purple compiled from aerial photographs THIS COMPLIES WITH NATIONAL MAP ACCURACY STANDARDS Fine red dashed li nes md1cate se lected fence~ f1eld lines where 35080-87-TF-024 generally VISible on aer1al photographs. This iwl6fmat1 on is unchecked taken 1976 and other source data. This information not FOR BY U S GEOLOGICAL SURVEY. RESTON, VIRG INIA 22092 N3507.5-W8052 5/7.5 A bLOER TOPOGRAPHIC MAPS AND SYMBO LS IS AVAILABLE ON R£QU£ST f1eld checked . Map edited 1980 O";q~iB i ,iG 1967 Red tint 1nd 1ca tes areas 111 wh1ch only landm~ §uildmgs are shown 1%8 PHOTOREVISEO 1988 Purple tint md1cates extens1on of urban areas PHOTOREVISED 1980 DMA 4854 Ill NW- SERIES V842 DMA 4854 Jf! NE - SERI ES V842 .. -..- --~·. :;~:.~ :· •.. ~. . ,. r '-. \ _4. ! r ~- I . I lI 1-r· I ., ' I • i -...... / :~. 5/IR. .! I I r:I / -- ·; ·.·. I . I I i I ll------~~------~/ =-----ic------· ----- I ) t ,.~ I ·- \ .. ' i : \ 1 \ ' - I ! I l \ tY .' 'i-.: rQ \ !• / ..? / '\ i \ ~--- .. i ,/ f! j ! ·c- 1 u I>- ,..,- , \ I . .~ I .' ~ / / s: .....:.... / _} / -- ' I I . ' -; . ·- I I I ; --· I I ~ \ il 7 \ ( 4 . I . :,,_-.. ""'·. ' ~. ) I . .:; . I ' . ., - .·.;- ·-.!· <:_ ' ., ., ~f ·' J ~- I -:: ) I _,. I .I- J I -·• - .. .. '1 ... . .:":-- I .·.·- '""" ... _.,. ;:·· .... ·. SURVEYED BY PHiL c'oEBERRY .,. ;..· .. 'SCAL't::: ·. \ ., ~ 'SO • -. - N.C.R.L.S. NO. U' 16 . '. - I ·-· ' ,:-:: . - ~- -- .. ·• -. ~ ' _·.; VICINITY ,. __· -... _, ·.\ .- .•, ·.;; ... NTS . , ._ ·_: . . .~. . ' ,_. •• ! ; -- .. -...... ,, . . ... · i. __ - .. .•; : _:. ~ . :_, f ~ -·· I / I .. Figure 3 I I I I I I I fl I I I I I I .. I I I ~~··: ... . : . I I· I I I I I -- 1 I I .. I t\1 lu I .... f 'i) ~~ ~ .. ~ V) ~ ' -l I ~ ~ 0 lJq \I) I. ~ I I' I .. I I Appendix B I Preliminary Assessment Form Site Inspection Form I Latitude/Longitude Calculation Form I I I It I I I I I I ,.I I POTENTIAL HAZARDOUS WASTE SITE 11. 1ur:r 11r-ICA TION I 0 SITE INSPECTION REPORT . NCAT"EI rM244u77s56 &EPA PART 1 ·SITE LOCATION AND INSPECTION INFORMATION II. SITE NAME AND LOCATION I 01 SITE NAME (legel co"'mo" o, aesc:ft)t'"' ,.,. o,.,,, I 02 STREET. ROUTE NO .. OR SPECIFICt:OCAfiON 1ut:r 11•1t:r Winston Container Co. 1 Winston Container Rd. OJ CITY I~ STATE I05ZIP CODE Ioe couNTY r7~l06~G I Charlotte NC 28208 Mecklenburg 60 9 09 It:;) I I' 0 TYP21.0:. OWNERS HoP IC"•"' OftOI 9 A. PRIVATE 0 B. FEDERAL 0 C. STATE 0 0. COUNTY 0 E. MUNICIPAL 3 5 0 • 8 OL~oguD2 W ~T'fD'b N . 0 F. OTHER iJ G. UNKNOWN I _Ill. INSPt:~ IIVN_INFO~MA TION 0 1 DATE OF IN:> .. t:\. IIUN I 02 SITE STATUS i 03 YEARS OF U,.t:HA lOUr 06 l 221 90 d{ ACTIVE 1953 I Current UNKNOWN M()HTH OAY YEAA OINACTIVE :<.iYEAR ENOtNGYEAR I i 04 AGENCY -· v ~ ...... ;INSPECTION tC•oc:• .,,,., _,, 0 A. EPA 0 B. EPA CONTRACTOR 0 C. MUNICIPAL 0 0. MUNICIPAL CONTRACTOR ,,._.,." ·,mJ 0 E. STATE d{ F. STATE CONTRACTOR HDR Efl[ffle'E!ri ng 0 G. OTHER (NatfNOIIIIfft} tSt>eellyJ I I 05 CHIEF IN~rt:w 1ur I06TITL£ lOT TION I 08 T NO. 1 1 George Tyri an Environmental Engineer HDR Eng. 704 338-1800 IOi OTHER o~rt:w 1vn.:> 10 Tm.E 112 TEL£P> I ( ) ( I 13 SITE 111 :NO I """I" ·~ ·~· -~m~ Mgr. 't~ESS • 1 1 Fred Ross ;Winston 'cont. Cha~~~~~~.c~~t~~~B~ Rd. 704 394-0176 President 1 Winston Container Rd. I Robert Winston, Jr. Winston Cont. Charlotte, NC 28208 <7041394-0176 I ( I ( I I ( I I ( ) 17 ACC~~~_!~D BY Jill TIME OF .._-..,.1""" J18 ,...... ,.,~ d{ PERMISSION I 1:00 0 WARRANT Sunny, warm 1 1V.II'lrv~M~T~ON AV~ 11 aat ~ F~M 01 CONTACT [020F J03T :NO. I Fred Ross Winston Container Co. '704 )394-0176 I FOAM l06AOENCY loe ... - HON lo7T :NO. I 08 DATE .,.'"""" ~ FORsnE - 07 l16t 90 I Georqe Tyrian HDR Enq. (704) 338-180C MOOm1 DAY YII:AII EPA FORM 2070.1317·81) I I POTENTIAL HAZARDOUS WASTE SITE I.IDENriFICATION I SITE INSPECTION REPORT 1 01 ~lt' loo244u775Rs6 &EPA PART 2 ·WASTE INFORMATION II. WASTESTATES, Q~TlES, AND CHARACTERISTICS 01 PHYSICAL STATES rC~o<> •''"" •oOirl , 02 WASTE OUANiiTY AT SrTE . 03 WASTE CHARACTERISTICS rC•••• • .,•• ,ADD''' I tAI•,uw'u ot ..ur• Ov.,,,..,., musr 04' "'"•D•"a•nu }fi A TOXIC E SOLUBLE 0 I HIGHLY VOLA nLE 0 A SOLID ;X E SLURRY 0 CORROSIVE F. INFECTIOUS J EXPLOSIVE ;t!(s POWDER. FINES F LIQUID TONS IJ 8 0 0 C C RAOtOACTIVE c1 C SLUOGE 2 G G.t.S 0 G FLAMMABlE ::: >< RE.O.CT!VE 0 P!'RSISTENT H ;QNITABLE C L INCOI.AP.O. TIBLE CUBIC YAROS XJ }¢ :::J 1.1 NOT APPLICABLE I U 0. OTHER ts,,.,,.,, NO. OF DRUMS U ~ to 66 illl. WASTE TYPE I CATEGOP SUBSTANCE NAME I 01 GROSS AMOUNT lo2 UNIT OF~ASURE OJ COMMENTS SLU SLUDGE OL' OIL''WASTE I SOL SOLVENTS 330 GAl Waste MEK from oaint c Iean-up op~[s PSO Pl:::ifiCIOI:S occ OTHER~~- ... ~ r.~o~~u1r. ' ., I IOC INOqGANIC r.w~ull"41 !': ACO ACIDS BAS BASES I MES HEAVY METALS unknown Ash and dust produced is contamff[a ted IV. HAZ.AI:IDOUS SUBSTANCES rs .. f CAS Num0.111 with metals listed below I 01 CATEGORY 02 SUBSTANCE NAME 03 CAS NUMBER 0""' I. METHOD 05 I,;UN\.Ot.N RATION ~~AS.':L~f I D008 Arsenic 7440382 Drums DOOB ca-dmium 7440439 Drums DOOB Chromium 7440473 Drums I coos Lead -7439921 Drums 103/FO ~5 Methvl Ethvl Ketone -:;5~~3 ~;~ I I I I V. rccu;::, 1 vi.!KS ,...... ,_, CATEGORY I I'EEOSTOCK NAME 02CASNUMSE CITI::uur<· 01 rc:.c:.u:>JIA'I( NAME !CAS NUMBER I FOS FOS FOS FOS FOS FOS I FDS FDS I VI. SOURCES OF INFORM A TJON teto-,.,.,_..... , .. ,,, ""· ·--.•••. ""'"' I References 1, 3, 4, 17. . I ~ EPA FORM 2070·13(7-ID I I POTENTIAL HAZARDOUS WASTE SITE I. IDENTIFICATION 01 STATE! 02 S/TC >IUM&R SITE INSPECTION REPORT NC 0024477556 oEPA PART 3 ·DESCRIPTION OF HAZARDOUS CONDITIONS AND INCIDENTS •• II. HAZARDOUS CONDITIONS AND INCIDENTS I 01 r:f..A GROUNDWATER CONTAMINATION 02 0 OBSERVED (DATE. l ./t POTENnAL 0 ALLEGED 03 POPULATION POTENTIALLY AFFECTED: 72981 04 NARRATIVE DESCRIPTION Operating since 1953 - Contaminants may have leached into groundwater. It is estimatec I that 7,981 people within a 3-mile radious use groundwater as a drinking water supply. 01 eX B. SURFACE WATER CONTAMINATION 02 Ci OBSERVEO(DATE l }t POTENTIAL 0 ALLEGED I 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION I Creek is immediately adjacent to property. - 01 0 C. CONTAMINATION OF AIR 02 0 OBSERVED (DATE. l 0 POTENTIAL - -LEG ED I 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION I 01 0 D. FIRE/EXPLOSIVE CONDmONS 02 0 OBSERVED (DATE: l 0 POTENTIAL 0 ALLEGED 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION I 01 0 E. DIRECT CONTACT 02 0 OBSERVED (DATE: I 0 POTENTIAL 0 \l.LEGED le 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION I 01 d I 01 f2i G. DRINKING WATER CONTAMINATION 02 0 OBSERVED (DATE: I ffiPOTENTIAL. C \W:GED 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION I Well on site used for drinking. 0 I 0 H. WORKER EXPOSURE/INJURY 02 0 OBSERVED(DATE: ) 0 POTENTIAL. 0 ALLEGED I 03 WORKERS POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION I 01 0 I. POPULATION EXPOSURE/INJURY 02 0 OBSERVED(DATE: I 0 POTENTIAL 0 AU.EGED I 03 POPULATION POTENTIALLY AFFECTED: 04NARRATIVEDESCAPTION - •• EPA FOAM 2070·1317·11,1 I I POTENTIAL HAZARDOUS WASTE SITE .SEPA SITE INSPECTION REPORT sse. I PART 3 ·DESCRIPTION OF HAZARDOUS CONDITIONS AND INCIDENTS 0 I 0 J. DAMAGE TO FLORA 02 C OBSERVED (D.A.TE. C POTE ... TIAL 0 Al.J..EGED I 04 NARRATIVE DESCRIPTION I 01 K. DAMAGE TO FAUNA 02 C: OBSERVED (DATE: POTENTIAL 0 0 :: ALLEGED 04 NARRATIVE DESCRIPTION tt•c'"~' """'111 olspt<,.sl I 01 0 L. CONTAMINATION OF FOOD CHAIN 02 0 OBSERVED (DATE: [') POTENTIAL C ALLEGED I 04 NARRt. TIVE DESCRIPTION I 01 0 M UNSTABLECONT.A,INMENTOFWASTES 02 Cj OBSERVED (DATE: w POTENTIAL 0 ALLEGED tSo•U!Rvno,.'S:•I"d~ttgllv~o~JOJ, Le•lt~ttg Or~IJ I 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION 01 C N. DAMAGE TO OFF SITE PROPERTY 02 0 OBSERVED (DATE: 0 POTENTIAL 0 ALLEGED I 04 NARRATIVE DESCRIPTION I ;:) 0. CONTAMINATION OF SEWERS. STORM DRAINS. WWTPs 02 w OBSERVED (DATE: 0 POTENTIAL 0 ALLEGED NARRATIVE DESCRIPTION I 01 0 P ILLEGAlJUNAUTHORIZED DUMPING 02 0 OBSERVEO(OATE: CJ POTENTIAL 0 ALLEGED I 04 NARRATIVE DESCRIPTION I 05 DESCRIPTION OF ANY OTHER KNOWN, POTENTIAL. OR ALLEGED HAZARDS I I I I ,e References 1, 2, 3, 4, 6, 12, 13, 14, 16, 17, 18 1· ...... _.,:;,,.,?•:.::::1 :::-;:-·····------~ I I POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION I .SEPA PART 4 ·PERMIT AND DESCRIPTIVE INFORMATION 0 I TYPE OF PERMIT ISSUED 02 PERMIT NUMBER OJ DAr: ISSUED O• EXPIRATION DATE 05 COMMENTS I 'C"'•c• .n ,,,, IDDirJ I I I I 0 A. SURFACE IMPOUNDMENT w A. INC EN ERA TION ~ A. BUILDINGS ON SITE 0 6. PILES iJ B. UNDERGROUND INJECTION C C. DRUMS, ABOVE GROUND MAX 66 Drums o c. CHEMICAL'PHYSICAL I C D. TANK, ABOVE GROUND 0 0. BIOLOGICAL 0 E. TANK, BELOW GROUND C E. WASTE OIL PROCESSING 08AREAOF 0 F. LANDFILL 0 F. SOLVENT RECOVERY e, •• 0 G. LANDFARM 0 G. OTHER AECYCUNG/RECOVERY _a_.p._p.__r_o_x_. __8 ___ ,... 1 I 0 H. OPEN DUMP mH. OTHER None,_.,} OI.OTHER----~~---- I rSDte,,.,, I I 0 A. ADEQUATE. SECURE 0 B. MODERATE 0 C. INADEQUATE, POOR 0 D. INSECURE, UNSOUND, DANGEROUS I 02 DESCRIPTION OF DRUMS, DIKING, UNERS, BARRIERS, ETC. I Drums stacked on pallets on ground. I 0 YES ~NO I Besides fence facility is bordered I References 1, 3, 4 I :;PA FORt.l2070·13(7·8fl I I POTENTIAL HAZARDOUS WASTE SITE I.IDENTIFICA TIOH SEPA SITE INSPECTION REPORT O~~tEloil11471§Rs6 I PART 5 ·WATER, DEMOGRAPHIC, AND ENVIRONMENTAL DATA WA TEA SUPPLY 01 TYPE 0~ DRINKING SUPPLY 02 ST~TUS 03 DIST ~NCE TO SITE I tC/'I•e• u •c:>~oc•OI•J SURFACE WELL ENDANGERED AFFECTED MONITORED COMMUNITY A~ 8.0 A.O 8.C c.o A. tm:) I NON-COMMUNITY c.o o. ex D. 0 E. 0 F. C 8. tm1) Ill. GROUNDWA TEA 0 1 GAOUNOW ~TEA USE IN VICINITY IChOc> O..oJ A~ ONLy SOURCE FOR DRINKING C B. DRINKING =C COt.!MERCI~L. INDUSTRIAL, IRRIGATION 0 D NOT USED. UNUSEABLE I tOrl't•' aowc•• av&H~I (Lifftll•~ 011111 I04JI'CU IYUIOiel COMMERCIAl, INDUSTRIAL, IRRIGATION {NO Otft•r Willi IOUICII ltll'-b/1) I 02 POPULATION SERVED BY GROUND W~TER 7 1 981 03 OIST ANCE TO NEAREST DRI"'KING W ~TEA WELL on site (mi) a• DEPTH TO GROUNDWATER 05 DIRECTION OF GROUNDWATER FLOW Oe DEPTH TO AQUIFER 07 POTEN'Tl~L YIELD 08 SOLE SOURCE AQUIFER OF CONCERN OF AQUIFER ~YES 0 NO 25 < (It) I < ttt) 25 (gPd) 09 DESCRIPTION OF WEU.S (tnetvawog ••••v•. ato'", on<1 loe•t""' ,.,.,,.. ro poolllotiOII- bu"<<.,QIJ I Private wells & small community supply wells. 10 .,.,,.., • "' '" AREA II n•=•ar ru: AREA I [J:YES COMMENTS 0 YES COMMENTS 0 NO )0 NO SURFACI WATER I 1 SURFACE WATER USEtC"oc..,,oJ 0 A. RESERVOIR, RECREATION 0 B. IRRIGATION. ECONOMICALLY 0 C. COMMERCIAL, INDUSTRIAL ~ 0. NOT CURRENTLY USED I ORIN KING WATER SOURCE IMPORTANT RESOURCES 02 AFFECTEO:POTENTIALLY AFFECTED BODIES OF WATER NAME: AFFECTED DISTANCE TO SITE I Taggart Creek Adjacent to Site 0 (mi) Sutar Creel< 0 t. (mi) ca-aw6a R1ver 0 20 (ml) I V. DEMOGRAPHIC AND Pnur-cn 1 r INFORMATION 0 1 TOTAL POPULATION WITHIN 02 OIST ANCE TO NEAREST POPULATION ONE ( 1) MILE OF SITE TWO (2) MILES OF SITE THREE l3SMILES OF SITE I A.2... QOO B. 8 2 100 c. ,900 0.06 lml) NO OF PERSONS NO OF PERSONS NO OF PEIISOH5 03 NU'-4BER OF SUI~ DINGS WITHIN TWO 121 MILES OF SITE o• OISTANCE TO NEAREST OFF-SITE 8\JILOINO uri known (Urban) 0.06 I (mil 05 POPULATION WITHIN VICINITY OF SITE (PtOWdo ,.,,._ lfotc,__ o1-ol-- ,...,., ...... ,, otsto. o.g .. """'· ""'""· """"''' -~....., oi'HJ The site is located in a commercial/industrial area adjacent to Douglas I International Airport, but residential property is located approximately 1000 feet away. I . I •EPA FORM 2070·13 (7·81) · I I POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT 6 I ,SEPA PART 5 ·WATER, DEMOGRAPHIC, AND ENVIRONMENTAL DATA I 0 A. 10-e- 10-s cm:sec c:; B. 10·•- 10-e em/sec 0 C 10·•- 10·3 cmlsec d(o GREATER THAN 10·l em/sec 02 PERMEABILITY OF BEDROCK rC•oe• o•fl 0 A. IMPERMEABLE 0 B RELATIVELY IMPERMEABLE d(c. RELATIVELY PERMEABLE 0 0 VERY PERMEABLE I ILtUt11111 10-SCI'\-SKI (10- 4 - f0-1Ctn1Jt'l (f0-Z- I0- 4 c:tn~UCJ fGtUitrt"'-"'f0-lCM'IKI I OJ 05SOILPH 06NET 08 SLOPE SITEfLOPE DIRECTION OF SITE SLOPE TERRAIN AVERAGE SLOPE ______3 (in) ____ ,. I sw 50 ' 10 0 SITE IS ON BARRIER ISLAND, COASTAL HIGH HAZARD AREA, RIVERINE FLOODWA Y I 1 2 DISTANCE TO CRITICAL HABITAT toiM A. >15 (mil B. >15 (mil ENDANGERED SPECIES: I 1 3 LAND USE IN VICINITY DISTANCE TO: RESIDENTIAL AREAS; NATIONALISTATE PARKS, AGRICULTURAL LANDS I COMMERCIALJINOUSTRIAL FORESTS, OR WILOUFE RESERVES PRIME AG LAND AG LAND I __<_0_;•_;;;1;,___ (mil B. __<_0_._1 __ (ml) C. (ml) D. (mf) OF SlTE IN RELA T10N TO SURROUNCING TOPOGAAPHY The site lies within the Piedmont Provinces. The site is a flattened area which drains to Taggart Creek, approximately 10 feet below the facility elevation. The I elevation of the site is approximately 635 feet above mean sea level. The slope at the facility is estimated at 1% toward the southwest, then a steep drop to the creek. I Stormwater runoff from the site drains SW across the site. The excavation road bordering the facility forms a slight (±1') berm around the facility border. The area drains toward Taggart Creek. I Taggart Creek borders the site, (within 20') with a change in elevation of approximatel 10 feet. Therefore, the slope of the intervening terrain is estimated at 50%. Taggart Creek discharges to Sugar Creek approximately 2 miles downstream. Sugar I Creek discharges to the Catawba River. I I I I I:PA FORM 2070·13 (7•811 I I I. IUt:N 11t=ICA TION POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT '"' NcATCioa24 47r 556 I e. EPA PART 6 ·SAMPLE AND FIELD INFORMATION ...SAMPLES TAKEN NA 101 ':_IU~~.E~OF I 02 SAMPLES SEI'lT TO . I 03 ~~TII.IA~..?~ I SAMPLE TYPE GROUNDWATeR I SURFACE WATER WASTE I AIR RUNOFF I SPILL SOIL I VEGETATION OTHER Ill. FIELD Ml=4~11qEMENTS TAKEN NA I 01 TYPE 102- I I I •IV. PHOTOGA4P1-iS AND MAPS WJ~ Erl_g_jneeri nq, Inc. 01 TYPE ;(l GROUND 0 AERIAL I 02 IN CUSTOOY OF ,...... ~.. _,_ 03 MAPS oiiOCAfiON OF MAPS 0 YES I ONO V. OTHER FIELD OATA COLLE!:_TED ...... rotoliolt/ I I I I VI. SOURCES OF INFORMATION !CAt..,., •••· e.o.• atattlrlta. .tOHIII/ I . I •EPA FOAM 2070.1317·11_j I I POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT 56 PART 7· OWNER INFORMATION SICCOOE to sTREET -.oORESs ,. o &o• A SIC CODE 10 STREET AOORESS II' o. Bo•. liFO • ore 1 I STREET AOORESS 11'.0 Bor. liFO'· ••• 1 I 02 D+B NU'-IBER 08NAME STREET ADDRESS (I' 0 Bo•. liFO • ore 1 tO STREET ADDRESS (P.O. Bor. '"0 '·ore I I I SIC CODE I I I I I I D+BNUMBER 02D+ 04SICCODE (I'. O. lloa, lti'D t, ""·' I I I I ~ EPA FORM 2070-13(7·811 I I POTENTIAL HAZ/l-.RDOUS WASTE SITE SITE INSPECTION REPORT I 56 I ADDRESS IP 0 So•. i IJI, PREVIOUS OPERA TOR($) (lni-II•OCOIIIIWII; t"oo I AOORESSti'.O. llo•.lfi'OI. Ofe.l I I I I I I EPAF0fUU070-13(7·81J . I I I POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT 56 PART 9 ·GENERATOR/TRANSPORTER INFORMATION I Winston Container Co. 0J srREET AOORESS rP o 114•. RFo• ••< 1 I 1 Winston 05 CITY I Charlotte I ADDRESS (P.O. 114•. RFO •. tiC./ (P 0 So•. lf'O I. •rc J I 05CITY 01NAME 02 O+B NUMBER I OJS (P.O 114<, RFOI. IIC./ (P. 0. llo•. liFO I, OIC./ I 05CITY I I OS CITY I 01NAME 03 STREET ADDRESS (1'.0. So•. liFO •. ore./ (I'.O.Ito•.IIFOI,otc./ I OS CITY I I I I I ,, I I POTENTIAL HAZARDOUS WASTE SITE I. IDENTIFICATION 0 I SITE INSPECTION REPORT IO' NtE\ b~447~~56 ~!EPA PART 10- PAST RESPONSE ACTIVITIES fi. PAST RESPONSE AC'ttVII u::. 01 :J A. WATER SUPPLY CLOSED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 C B. TEMPORARY WATER SUPPLY PROVIDED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 :J C. PERMANENT WATER SUPPLY PROVIDED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 0 D. SPILLED MATERIAL REMOVED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 G E. CONTAMINATED SOIL REMOVED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 0 F. WASTE REPACKAGED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 0 G. WASTE DISPOSED ELSEWHERE 02 DATE OJ AGENCY I 04 DESCRIPTION 01 0 H. ON SITE BURIAL 02 DATE OJ AGENCY 04 DESCRIPTION I 01 0 I. IN SITU CHEMICAL TREATMENT 02 DATE OJ AGENCY 04 DESCRIPTION I 01 0 J. IN SITU BIOLOGICAL TREATMENT 02 D.&.TE 03AGENCY 04 DESCRIPTION 01 0 K. IN SITU PHYSICAL TREATMENT 02 DATE 03AGENCY I 04 DESCRIPTION 01 0 L. ENCAPSUL.AOON 02 DATE 03AGENCY I 04 DESCRIPTION 01 0 M. EMERGENCY W~TE TREA'TMENT 02DATE 03AGENCY I 04 OESCRIPTlON 01 0 N. CUTOFF WALLS 02 DATE 03AGENCY I 04 DESCRIPTION 01 0 0. EMERGENCY DIKING/SURFACE WATER DIVERSION 02DATE 03AGENCY I 04 DESCRIPTION 01 0 P. CUTOFF TRENCHES/SUMP 02DATE 03AGENCY 04 DESCRIPTION . . I . -01 0 0. SUBSURFACE CUTOFF WALt 02DATE 03AGENCY I 04 DESCRIPTION EPA FOAM 2070.1317 ·11 I I I POTENTIAL HAZARDOUS WASTE SITE I SITE INSPECTION REPORT PART 10 ·PAST RESPONSE ACTIVITIES 56 I 02 DATE OJ AGENCY 01 0 S CAPPINGiCOVERING 02 DATE OJ AGENCY I 04 DESCRIPTION 01 0 T BULK TANKAGE REPAIRED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 w U. GROUT CURTAIN CONSTRUCTED 02 DATE 03AGENCY I 04 DESCRIPTION 01 0 V. BOTTOM SEALED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 0 W. GAS CONTROL 02 DATE OJ AGENCY I 04 DESCRIPTION 01 0 X. FIRE CONTROL 02DATE OJ AGENCY I 04 DESCRIPTION 01 0 Y. LEACHATE TREATMENT 02 DATE 03AGENCY 04 DESCRIPTION I 01 G Z. AREA EVACUATED 02 DATE OJ AGENCY 04 DESCRIPTION I 01 0 1. ACCESS TO SITE RESTRICTED 02 DATE 03AGENCY 04 DESCRIPTlON 01 0 2. POPULATION RELOCATED 02DATE 03AGENCY I 04 DESCRIPTION 01 0 3. OTHER REMEDIAL ACTIVITIES 02DATE 03AGENCY I 04 DESCRIPTION I No remedial actions to date. I References 1~ 3 £P ... FORM 207(1-\3 (7·&1) I I POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT I PART 11 ·ENFORCEMENT INFORMATION I 01 PAST REGULATORv:ENI'ORCEMENT ACnoN :: v:s X NO 02 DESCRIPTiON OF FEDERAL STATE. LOCAL >'EGULJ.TORv•E"'I'ORCEMENT ACTIO'< I I I I I I I I I I I I I Ill. SOURCES OF INFORMATION IC•••-•c•••••MCOI.O.f.,l/otollleo.•--riC.tOI>Ofll/ References 1, 3 I ·811 I I POTENTIAL HAZARDOUS WASTE SITE I. IOENTIFICA TION SITE INSPECTION REPORT 01 STAre I02 srre NuMBER &EPA tiC DOt~tt477556 .. PART 1 ·SITE LOCATION AND INSPECTION INFORMATION II. SITE NAME AND LOCATION I 01 SITE NAME ll.tgll COI!'ti'PIO/t 0' QIJe"C)(IYI ,..,. OIJiftl 02 STREET. ROUTE NO .• OR SPECIFIC lOCATION IOENTIFIEA Winston Container Co. 1 Winston Container Road OJ CITY 04 STATE,05 ZIP CODE 06 COUNTY I 06 CO" ( ) • ( ) 13 SITE REPRESENTATIVES INTERVIEWED 14 TTTU: 1SAOORESS 1 & TELEPHONE HO I Sales Mgr. 1 Winston Container Road Fred Ross Winston Cont. Charlotte. NC 28208 t704l 394-0176 President 1 Winston Container Road I Robert Winston, Jr. Winston Cont. Charlotte, NC 28208 C704l394-0176 I ( ) ( } I ( ) I ( ) 1 7 ACCESS GAINED BY 1a TIME OF INSPECTION 1 a WEATHER CONOITIONS rco.c•-1 I C1l PERMISSION 9:00 a.m. Cloudy, mild 0 WARRANT IV.INFORMATION AVAILABLE FROM I . 01 CONTACT 02 OF ,...,_,,._....., 03 TELEPHONE NO. Fred Ross Winston Container Co. V04 1394-0176 04 PERSON RESPONSIBL.f FOR SITE INSPECTION FORM 06AGENCY De OROANIZATION 07 TELEPHONE NO. OI!DATE 01 l09L91 c. Fl etch.er Armstrong . HDR Engineerin (704)338-180C WOOffii OA Y YEAII •• EPA FORM 2070·13 (7·.11 I I IDENTIFICATION POTENTIAL HAZARDOUS WASTE SITE I. :lt STATe 102 SITE SEPA SITE INSPECTION REPORT NU~BER .. PART 2 ·WASTE INFORMATION II. WASTE STATES, QUANTITIES, AND CHARACTERISTICS I 01 PHYSICAL STATES ICho<• o•t•ll ooD'yl 02 WASTE QUANTITY AT SITE tC••<• ••r•oroooty/ 03 WASTE CHARACTERISTICS '"''"'"''u ot •Uit o"'.,.," .. ' o A sauo L.: E SLURRY muSt 04 ti'IQtDffiiiQfltU ~A TOXIC S E SOLUBLE ~ I HIGH\. Y VOLA TILE IJ 8 CORROSIVE G F. :i( 8 POWDER. FINES X; F LIQUID TONS INFECTIOUS 0 J EXPLOSIVE c: C SLUDGE .::! G GAS ::; C RADIOACTIVE C G FI..AM~ABLE :: I( REACTIVE JO 0 P!'RSISTENT )C H ;QNIT49LE :: L INCO~P,_ Ti9LE I CUBIC YAROS Ui':'1 to 66 :; ~ NOT APPLICABLE L: 0 OTHER (SDtC,yJ NO.OI'ORUMS Ill. WASTE TYPE I CATEGORY SUBSTANCE NAME 01 GROSS AMOUNT 02 UNIT OF MEASURE 03COMMENTS SLU SLUDGE OLW OILY WASTE I SOL SOLVENTS 330 GAL Waste MEK from paint clean-up opnc PSD PESTICIDES ace OTHER ORGANIC CHEMICALS I IOC INORGANIC CHEMICALS ACD ACIDS BAS BASES I MES HEAVY METALS unknown Ash and dust produced is contami n< ted IV. HAZARDOUS SUBSTANCES ($HIIDDIMJ,.Ior-ltlroouont,., c•.., CJ&$ ,.• .,.. ,., with -metals listed below. 02 SUBSTANCE NAME 03 CAS NUMBER oe MEASURE OF 01 CATEGORY 04 STORAGE/DISPOSAL METriOO 05 CONCENTRATION CONCENTRA T10N I D008 Arsenic 7440382 Drums D008 Cadmium 7440439 Drums D008 Chromium 7440473 Drums D008 Lead 7439921 Drums F003/F005 Methyl Ethyl Ketone 78933 Drums •I I I I v. FEEDSTOCKS ($11ADQIOtl/llotCA$-I I CATEGORY 0 I I'EEOSTOCK NAME 02 CAS NUMBER CATEGORY 0 I I'EEOSTOCK NAME 02 CAS NUMBER FDS FDS FDS FDS I FOS FOS FDS FDS VI. SOURCES OF INFORMATION rOI•-·.,•-••·•·'"""''-··--.-.•. ,_..11 ~. References 1,3,4,17 I I· EPA FORM 2070·1317·811 I POTENTIAL HAZARDOUS WASTE SITE I. IDENTIFICATION 01 5 EPA SITE INSPECTION REPORT Nt'El 0QM~(775s6 .. a PART 3 ·DESCRIPTION OF HAZARDOUS CONDITIONS AND INCIDENTS I II. HAZARDOUS CONDITIONS AND INCIDENTS 0 t )()(A GROUNDWA TEA CONTAMINATION 02 C OBSERVED (DATE. I ~POTENTIAL ::; ALLEGED OJ POPULATION POTENTIALLY AFFECTED: ~81 04 NARRATIVE DESCRIPTION Operating since 1953. It is estimated that 7.981 people within a 3-mile radius use I groundwater as a drinking water supply. 01 Xl B SURFACE WATER CONTAMINATION 02 :.._, OBSERVEDIOATE ) x; POTENnAL :J ALLEGED I 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION Observed release to surface soil of acetone, antimony, arsenic, barium, bis (2-ethyl- hexyl) phthalate, butylbenzyl phthalate, cadmium, calcium, chromium, cobalt, copper, I g~aRi9~tylphthalate, lead, mercury, nickel, selenium, silver, sodium, z.inc, iron, and 01 :::::i C. CONTAMINATION OF AIR 02 w OBSERVED!OATE. I ::; POTENTIAL _LEG ED I 03 POPULATION POTENTIALLY AFFECTED: 04 NARRA nVE DESCRIPTION I 01 0 D. FIRE/EXPLOSIVE CONDITIONS 02 0 OBSERVED (DATE: I 0 POTENTIAL iJ <\LLEGEQ 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION I 01 0 E. DIRECT CONTACT 02 0 OBSERVED (DATE: ) 0 POTENTlAL 0 \l.LEGED 03 POPULATION POTENTIALLY AFFECTED: 04 NARRAnVE DESCRIPTION •I 01 Gl F. CONTAMINATION OF SOIL 02lil OBSERVED (DATE: 1lll'3/YU 1 0 POTENTIAL C \U.EGED 03 AREA POTENTIALLY AFFECTED: unknown 04 NARRATIVE DESCRIPTION I Observed release of acetone,(ACreiJ antimony, arsenic, barium, bis (2-ethylhexyl phthalate, butyl benzyl phthalate, cadium, calcium, chromium, cobalt, copper, Di-n-Butyl phthalate, lead, mercury, nickel, selenium·, silver, sodium, zinc, iron, and cyanide. I 01 DRINKING WATER CONTAMINATION 02 OBSERVED (DATE: ) ~G. 0 ().POTENTIAl,. C \U.EGEO 03 POPULATION POTENTIALLY AFFECTED: 04 NARRATIVE DESCRIPTION I Well on site used for drinking. 0 t C H. WORKER EXPOSURE/INJURY 02 0 OBSERVED (DATE: ) 0 POTENTIAL 0 ALLEGED I OJ WORKERS POTENTIALlY AFFECTED: 04 NARRATIVE DESCRIPTION I 01 0 I. POPULATION EXPOSURE/INJURY 02 0 OBSERVED (DATE: I 0 POTENTW. 0 ALLEGED 03 POPUL.ATION POTENTIALLY AFFECTED: 04 NARRATlVE DESCRIPTION ~. I EPA FORM 2070·13 (Nil) I I POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT .SEPA PART 3 ·DESCRIPTION OF HAZARDOUS CONDITIONS AND INCIDeNTS 1 :J 0. CONTAMINATION OF SEWERS. STORM DRAINS. WWTPs 02 i: OBSERVED (DATE: ------U POTENnAL C ALLEGED 04 NARRATIVE DESCRIPTION I 01 0 P ILLEGAUUNAUTHORIZED DUMPING 02 0 OBSERVED (DATE:------[J POTENTIAL 0 ALLEGEO I 04 NARRATIVE DESCRIPTION I 05 DESCRIPTION OF ANY OTHER KNOWN, POTENnAL. OR ALLEGED HAZARDS I I I References 1, 2, 3, 4,- 6, 12,· 13, 14, 16, 17, 18, Section 6.0, Appendix D ···• I I. IOENTIFICA TION POTENTIAL HAZARDOUS WASTE SITE 01 STATE I02 SITE ' I ~c AIR See reference 1973 on 5 diff~r~nt nPrmitc:; IX D. R.CRA Genera·tor 1985 ~E RCRA INTERIM STATUS NCD024477556 1980 1984 I CF SPCC PLAN 0 G. STATE,sooc.t1r IXH LOCAL tSoocd•l 0051 01/13/89 03/31/91 Discharqe non-domestic WW to I [~I OTHER tSooellrl sewer. CJ. NONE Ill. SITE DESCRIPTION I 01 STORAGE, DISPOSAL tCit•~••~,,..,.,,,.,J 02 AMOUNT 03 UNIT OF MEASURE a• TREATMENT rc.-oc• ...... """''' 050THER C: A. SURFACE IMPOUNDME~T C A.INCENERATION jiiJ A. BUILDINGS ON SITE 0 6. PILES 0 B. UNDERGROUND INJECnON DRUMS. ABOVE GROUND MAX 66 Drums I G'c. 0 C. CHEMICALIPHYSICAL C D. TANK. ABOVE GROUND 0 0. BIOLOGICAL 0 E. TANK, BELOW GROUND C E. WASTE OIL PROCESSING 011 AREA OF Silt. 0 F. LANDFILL 0 F. SOLVENT RECOVERY I 0 G. LANDFARM 0 G. OTHER RECYCUNG/RECOVERY a[H;!rOX. 8 (Acr••J 0 H. OPEN DUMP ~H. OTHER ~QDf: 0 I. OTHER (~} fSpec'''' 07COMMENTS ' •I I IV. CONTAINMENT 01 CONTAINMENT OF WASTESrC•oc•o-•1 OA.ADEOUATE,SECURE 0 B. MODERATE 0 C. IN.l.OEOUATE, POOR :0 0. INSECURE, UNSOUND. D.I.NGEROUS I 02 DESCRIPTION OF DRUMS, DIKING, UNERS, BARRIERS, ETC. I Contamination of surface soils not contained. I V. ACCESSIBILITY 01 WASTE EASILY ACCESSIBLE: 0 YES tJ NO 02COMMENTS TV contaolled gate to obtain access to factory. Besides fence faci 1 ity is bordered I by Taggart Creek with 10+ embankment. VI. SOURCES OF INFORMATION ICIIUHCrllc ,.,.,_.,_.,...... ,H •. -.....,.... ·-•1 References 1' 3, 4, Section .6.0, Appendix D ' .:PA~ FOAM 2070·1317·811 I I <)E"--TIFO::;A • :"-- POTENTIAL HAZARDOUS WASTE SITE /1 1:· :;••·;:1 ;; ; ·~ '.u~~= SITE INSPECTION REPORT NC ,0024477556 a. EPA PART 5 ·WATER, DEMOGRAPHIC, AND ENVIRONMENTAL DATA : II. DRINKING WATER SUPPLY I ; t -...o: :c :Rr'-il( .._~ S1..PC1~., I 'J2 STATUS :J ~~s~•,...:;c ·: s.-:c .. :••:• .. •.:,,'(' •.,.! I 3.JRF4CE weu. E .. 04NGEREO "'""ec-:o o.40NIT0REO i I ~ :::'-"'-"U"-I'j""Y ~ 8 .. = I .. - a= c = " - ~C'-i c:~u.,.AU'-41T"f c = :J :a :J = -- " - 3 -· I Ill. GROUNOWA TER 0 l ':;!'lCU.,OWA rep uSE :N VICINITY rC.'«">•el Iii- ON~• SOUFICE ~C~ OFIINI 7,981 OJ OtST ANCE TO NEAFIEST OFII.,I(ING WA TEFI WEU. on site I J2 "0"UL.A TICN SE~'~'<'EO 9Y ':;AOUNO WATEFI '"''I O• OEPT'H 70 GFIOUNOWATEFI 05 OfRECTION OF GROUNOW4 TEA F~OW OS O~PTio< ro AOUIFEFI 0 7 POTENT1A~ ,.1ELO oa soL.E sou~ce AOv·'!:" OF CONCERN OFAOUI~Efll 25 ~YES =NO < 25 'ttl < '"' (gOd) I Oi OESCR1PTtON OF WE U.S t'•c-...... aeOtM. '""lOCI<-,_,..,.,.._,...,-_,, Private wells & sma 11 community supply wells. I l 0 REC~o<4RQE AREA 1 l OISCHAAG£ AFIEA Q: YES COMMENTS 0 YES COMMENTS I Cj NO >0 NO IV. SURFACE WATER 01 SUFIFACE WATER USEt:••••""•l 0 A. RESERVOIR. RECREATION 0 B. IRRIGATION. ECONOMICALLY Cl C. COMMERCIAL, INDUSTRIAl. ~ 0. NOT CURRENTLY USED • ORIN KING WATER SOURCE IMPORTANT RESOURCES I 02 A~F~CTEO.POTENTI4U.Y AFFECTED BOOIES OFWATE" NAME: AFFECTED OISTANCE TO SITE Taggart Creek Adjacent to Site c: 1m1) I Su~ar Creel< 0 z (m1) ca-awoa R1ver 0 20 (mi) V. DEMOGRAPHIC AND PROPERTY INFORMATION I 01 TQTA~ POPUI..A TION WITHIN 02 OI$T ANCE TO N!AI'IEST POPULA TIOH ONE ( 1 ) MILE OF SITE TWO (21 MIL.&S OF srT! THREE wriLES OF SITE A. _2. .. QQQ •. 81100 c. .900 0.06 (11111 '00 0' I "0 o• ~f--SOHS '00 OI'I'IMClNe ,.,qc)NJ OJ NU ..!!ER OF SUI~OING$ WIT- TWO IZI Mlt.U Of' SITI 0~ orSTANCE TO ~ uri known (Urban) 0.06 (mil I 05 POPUL.ATION WITHIN VICINITY OF SIT!,,.,____ .,_.,_-_ .. ,.•. •·I·· """'· -· --~-- The site is located in a commercial/industrial area adjacent to Douglas International Airport, but residential property is located approximately I 1000 feet away. . L ~. 1!P4F~M 2070·13(7·811 · I I I POTENTIAL HAZARDOUS WASTE SITE I OE~'l';F'I;::A ~ S~ I SITE INSPECTION REPORT :· .)':'4'":!.:1 l -~ ...... '!t,.:l: I .SEPA PART 5 ·WATER. DEMOGRAPHIC, AND ENVIRONMENTAL DATA i NC I 00244 77556 VI. ENVIRONMENTAL INFORMA TIO,., J' ~E""'EAB:L.:" =F ~....,s ... :u~=u. :-::~ z:o,..E : ... (. o .... , .. ~J-4- ·o-4c-, sec: I -:A =a •a·•- •a-• '="'''otc =c •c-•- •o-1-:r'"'•c j(o ::.l'lEATER ':',..A 'I 1 Q·l -:-·sK :~ ~:.~-"'E•S•l.. ~" ':F ~E~R:Co( ~-•e•o""•• ~ A ro.APE"~'-~E.t3.E =9 REI.-" TIVELY IMPERMEABLE j( C RELA TIVEL 'f PE~'~IAEABLE ..: 0 'E"'Y PEI'lo.AEABLE ... ,s·····"'·\:..-,.tkl "0-·- ro•IC"'-UCI tro-1- ·o-•.:,.,,.C', r..c• I •C·••••' '""'-" •o '"l ~ :J :~pr,. ~v oDRQCI( ':• ;c~r .. or::CONTAMI"'ATEOSQILlO"'E ::15 SOILgH (!'!) (fit I 011 NET PRECIPITATION 07 C"E YEAR 2• HOUR RAINFALL 011 SLOPE SITerLOPE DIRECTION oF SITE sLoPE TERRAIN AVERAGE sLOPE 3 3 I I :•n) (+n) ' sw 5Q ' I :~ F~,OQO PO~ESTIAL 10 =SITE IS ON BARRIER ISL-"NO. COASTAL HIGH HAZARO AREA. RIVERINE FLOOOWA Y SITE IS JNX not in~ F'LOOOP.-41N 1' Or5TANCE TO wETLA,..OStl tc" _..,._, 1 2 OrSTANCE TO CRITICAL HABITAT,,,_.,.,,,_. tooc•fl I ESTUARINE OTHER >15 (mrl A >15 (mol 9 >15 (ml) ENOANGEREO SPECIES. I , 3 LAND use,,.. vrc1"'1TY OISTANCE TO: RESIDENTIAL AREAS; NATIONAL/STATE PARKS. AGRICUL TURAI. !.-"NOS I COMMERCIAlJINOUSTRIAL FORESTS. OR WILDUFE RESERVES "RIME AG L.ANO AGL.ANO A . <0.1 (mi) 8. <0.1 (rnt) c. (mil 0 (mil 1 • OESCFUPTIO"' OF SITE IN RELA TlON TO SURAOU,..CING TOPOGt"'APHY The site 1 ies within the Piedmont Provinces. The site is a flattened area which • drains to Taggart Creek, approximately 10 feet below the facility elevation. The elevation of the site is approximately 635 feet above mean sea level. The slope at I the facility is estimated at 1% toward the southwest, then a steep drop to the creek. Stormwater runoff from the site drains SW across the site. The excavation road I bordering the facility forms a slight (±1') berm around the facility border. The area drains toward Taggart Creek. Taggart Creek borders the site, (within 20') with a change in elevation of approximatel' I 10 feet. Therefore, the slope of the intervening terrain is estimated at 50%. Taggart Creek discharges to Sugar Creek approximately 2 miles downstream. Sugar I Creek discharges to the Catawba River. I I VII. SOURCES OF INFORMATION tCA• --... ••·· --· _ _,_ _, References 2, 3, 5, 7, 11. I ~. CPA 'a-1 2070·1~17 .. 11 I I I POTENTIAL HAZARDOUS WASTE SITE I. IDENTIFICATION SITE INSPECTION REPORT (JI sr:ttTEn)024~477 556 SEPA PART 6 ·SAMPLE AND FIELD INFORMATION .. II. SAMPLES TAKEN 01 NUMBf~ OF 02 SAMPLES SENT TO 03 ES TI>,IA TED OA TE I SAMPLE TYPE SA1.4PL.ES TAKEN ~SUL TS A V OJl.A&..E GROUNDWATeR 1 CompuChem Appendix D I Stream SP.diment 2 CompuChem WASTE I I AIR RUNOFF I SPILL SOIL 4 CompuChem Appendix D I VEGETATION Qua 1ity Contro 1 3 CompuChem/NCDEHNR Appendix D I Ill. FIELD MEASUREMENTS TAKEN 01 TYPE 02 COMMENTS I • I IV. PHOTOGRAPHS AND MAPS f-IDR .:"'.u:.-.. ,;~~~ 01 TYPE [l GROUND 0 AERIAL I 02 IN OJSTOOY OF ~ {J (NI,..OI,dtpo•tlii-01-W" 031.AA.PS 04LOCA.TION OF MAPS I 0 YES ONO I V. OTHER FIELD DATA COLLECTED rPYo...,. ..,.w. ....,,...,., I I I VI. SOURCES OF INFORMATION ICh- ,.,.,..,.,... •·P·· ••••• ,..,_ , __,.,._,_,.,, Section 6.0 ~. Appendix D . I EPA FORM 2070·13 (7·81) I, I POTENTIAL HAZARDOUS WASTE SITE - ... ·= : = '5 ·::: .. _ .... .:,:.;, SITE INSPECTION REPORT NC . 0024477556 &EPA PART 7 ·OWNER INFORMATION II. CURRENT OWNER 05 CITY loe STATE 07 ZIP CODE 12 CITY I" J s~•·: , 4 Z,:P ":~OE I i I OINAME 02 0+1 NUMIER OSHAME Oi 0•8"'. ·=" I OJSTREETAOORESSt~'O h• 10101 .,., 10 STREET AOORESS ,,. o h• 11101 otc 1 r• SICCOOE rISoCO:C:lE I 05 CITY rs STATE 07 ZIPCOOE 12CITY 113 STATE!'' ZIP COOE 01NAME 02 0 +I NUMIER 01 NAMI Oi 0+8 NUMIER I 03 STREET AOOFII!S$tl' 0 h•. 1110 1 11ct 10' SICCOOE 10 STREIT AOOAESS II' 0 le1. 1110 '· ote.t rSICCOOE 05 CITY reSTAT 07 ZIP COO£ 1:ZCITY r3 STATE •• ZIP COO£ Ill. PREVIOUS OWNER($) •~..w• _., ,.., __, IV. REALTY OWNER($),,...__,.,.._. __ ~r~u •I 01NAME 02 0+1 NUI4EII OtNAMe 02 0 +I NUMII!R 03 STREET AOOAESStl' o..... 1110 '·-1 I 04SICCOOE 03 STIIEET ~SSti'.O..... "'0'. -·1 10' SIC COOl OS CITY I OS CITY reSTATE 07ZPC0ot loe STATI! 07ZPCOOE OtNAME .o:z D+IHUWMII OtH.AMI O:Z 0+8 NUMBER I 03 STREET AOOAESS '" o le•. 1110 •. ft./ 03 STNET A00NSS 11'.0 ..... IWOI . .._, IO•SICCOOE 104SICCOOI I 05 CITY ~oeaT.\Tt or~cocc OS CITY reSTATE 07 ZI"COOI! OtNAME O:Z 0+1 NUMIIII OtNAI4 O:ZD•SHUMUII I 03 STREET AOOf'ESS ~ 0. le•. If'~'· M.l 104SICCOot 03 STNET ADOMSatii.O..... "'O '· •·I IO•SICCODE OS CITY 07ZPCOCC DICIT\' Ice sr ATE 01 ZP c:oot I IDe STAT! V. SOURCES OF INFORMATION te.t•---"· •·r.. --. --·- . I•• f I I I : POTENTIAL HAZ~.ROOUS WASTE SITE :::;'I~:~<•CATIC., : ~-a·~r :~ 5·'"'£ ,_ ... -:-:~ SITE INSPECTION REPORT 1 oEPA PART 8 • OPEFIATCR INFORMATION NC 0024477556 I I OPERATOR'S PARENT COMPANY II. CURRENT OPERA TOR ·-.. ..,·•-··•••·-•-•, I ·~~~OI'el \ .. 01 ".u.!E 02 c • e .. u ... ec:~:~ I': """'E ~-. =·~.._ ...... 3!:o:l I I Winston Container Co. I i I OJ S ~REE! AOOI:IESS :- o ""' ..0 • "' 1 r· s•c:ooe '2 S~"E:' •::"ESS • ':) ~· ~~: • elC - ...... - 1 Winston Container Rd. rJs····· 0~ CIT'Y 1' Ci;y I 108 STATE 07 ZIP COOE ~·~s~"~JHIPC::e Charlotte NC 28208 08 YEARS OF OPERATION I ~Oi NAME OF OWNEA I 1953-Presen Robert Winston, Sr. Ill. PREVIOUS OPERATOR(S)IIAI-II'KO"II~II.I>'O_M,.,IItl"'•'•"''"""••"-" PREVIOUS OPERATORS' PARENT COMPANIES ··..,--•· I 01NAME 02 0,. B NU>ABER 'tO NAME I' I :l•B .. ~. ... 8E" OJ STREET AOOI'IESS tl' 0 .... "'0 1. trc 1 12 STREET AOORESS ·• 0 .., ••o • II< r r• SICCOOE J' J s.c ::ce 05 CITY 14CLTY I rl STATE 07 ZIPCOOE r5 SU'CI 18 ZIP cooe I 08 YEAASOFOi'EAATION lOi NAME OF OWNEF! CURING THIS PERIOO 01NAIII! 02 O+B NUMBER 10NAM£ I'' O•B NUMBER I 03 STREET A.OOAESS II' 0 ..... 11'0 I. tlc.r IO~SICCOOE 12 STR!ET AOORESS ,,. o..... 1110 I. OIC.J 1'3 SICCOOE 05CITY 108STATE OTZIPCOOE I~CITV r$ STATE 18 ZlP CO OF. 1 - 08 YEARS OF OPERATION JOI NAM~ 01' OWNI!F! OUF!IHG THIS "EF!IOO I 01NAMI! 0% D+ I NUMII!F! 10NAMI 111 D•B. NUMBER 03 STREET AOOI'IESStl' o..... 11~0,, -1 I Z STREI!T AODI'I!SS 1~. 0 ..... NO I, -·1 I IC. SIC COOl r3 SICCOOi 05CITY rtSTATI! OTZ.CODI 1~CIT'!' 115 ST.-.!1!1111 ZlPCOOE I oa veAAS Ol' OPI!I'IA T10N I01 NAMI! Of' OWNI!F! DUNNO TMI 'fF!IOO I IV. SOURCES OF INFORMAnON 10e--...... -----·- I I . ~I I I POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT SEPA PART 9 ·GENERATOR/TRANSPORTER INFORMATION .. II ON-SITE GENERA TOR I Winston Container Co. 04SlCCOOE I 1 Winston Container Rd. lossuTe 07ZlPCooe Charlotte I NC 28208 I Ill. OFF·SITE OENERATORIS) 02 O+BNUM!ER OINAME OJ S'l'REcT AOOR~Ss 1' o .... ••o 1 ... 1 04 SlCCOOE 03 STFIE!T AOORESS ,, o ... ••o 1 ... 1 I / ~· S··: :oc-e OS CITY r6STATE 07ZlPCOOE OS CITY l:e sare 01 Z:PCCCE I OINAME 020•8NUM8ER OINAME I 03 S TIIIEET AOOFIESS" 0 lo1. •110 •. 01c.1 04SICCOOE 03 STREET AOORESS '' o lo•. 11101. orc.1 OS CITY rl5 STATE 07 ZIP COOf OS CITY reSUTE 07ZIPCOOI I IV. TR"NSPORTER(S) OINAMI! 02 0+8 NUMBER 01 NAMl 02 O•B NUMBER 03 STREET AOOA!SS 11' 0. lo1. •10•. oiC.I 04SICCOOE 03 STJIIEET AOOIIIESS ,,. o .... 10110 '· o1e.1 I04 SIC COO£ • I I OS CITY r· STATE 07 ZPCOOI OS CITY loeSTATE 07ZIPCOOI I 01 NAME 02 0+1 NUMIIft 01 NAMa 02 0+8 NUMIEA 03 STREET AOOAESS tl' 0 .... 1"0 • 01c 1 03 STJIIEET Aoa.ESS II' o..... 10110 '· .... 1 104 SIC COO€ I 05 CITY lotSTATI 07ZIPCOOI OS CITY IOtSTAT! 07ZIPC00f V. SOURCES OF INFORMATION tc..--•·•··----··-'' I I I ~. I I I POTENTIAL HAZARDOUS WASTE SITE I I •::lE ..-TI~·CA TIC"c SITE INSPECTION REPORT ["·5·4-cl :• ;.--::: ...... ,., .. I~EPA PART 10 ·PAST RESPONSE ACTIVITIES NC 1 D02447_Z_556 11. PAST RESPO ISE ACTIVITIES .. 0: =A NA ':"E~ SUP~''• v C~CSEO C20HE -:;jAae;cv I 04 :ESC~IPT10N ;: • _ 3 -: ... "C~A.RY w.:. ':"E::l S;,i'OJ. Y ::>RQVIOEO n:.~. ... ':3 AGENC'< - I C• OESC~ii'T10N 01 =C PEC,M.ANENT W.t.-:"ER SUPPLY PROVlDEO 02-0ArE CJ .t.GENCY I 04 DESCRIPTION 0 1 S 0 SPIU..ED MA T'ERIAL 02 DATE OJ-AGENCY 04 DESCAIPTlON I 02 O.t.T'E OJ 01 :: E CONTAMINATED SOil. REMOVED AGENCY 04 OESCAIPTlON I 01 :: F WASTE AEPACI<.4GED 02 OATE oiAGENCY 04 DESCRIPTION 01 .... G. WASTE OfSPOSEO ELSEWHERE 02 DATE 03 AGENCY I 04 OESCRIPTlON 01 :J H ON SITE BURIAL 02 DATE OJ AGENCY I 04 DESCRIF'TlON 01 C: 1. IN StT\J CHEMICAL. TREATMENT 02 DATE OJ AGENCY 04 DESCRIPTION 01 CJ J. IN StT\J BIOLOGICAL TREATMENT 02 DATE 03AGENCY I 04 DESCRIPTION C1 Cl K. IN StT\J PHYSICAL TREATMENT 02 DATE 03AGENCY I 04 OESCRIPTlON 0 1 Cl L.. ENCAPSUL.A TlON 02DATE 03-.GEHC't I 04 OESCRIPTlON 01 :J M. EMERGENCY WA:STE lMATMENT 02DATE 03AG£NCY I 04 DESCRIPTION . 01 C N CUTOFF WAU.S 02 DATE 03AGENCY 04 DESCRIPTION I 01 CJ 0 EMERGENCY DIKING/SURFACE WATER DIVERSION 020ATE 0311JSCY 04 OESCRIPTlON I 01 CJ P CUTOFF TRENCHES/SUMP 02DATE 03NJEJICY 04 DESCRIPTION . r- I 01 QQ. SUBSURFACE CUTOFF WAU. 02CATE 03NJEJICY 04 DESCRIPTION I EPA,OMI2070ol317·111 I I POTENTIAL HAZARDOUS WASTE SITE I lUI:~ ll>·tCA iiON SITE INSPECTION REPORT ro.NC''"I]o]t~El€" lsEPA PART 10 ·PAST RESPONSE ACTIVITIES 4477556 II PAST RESPONSE ACTIVITIES •c ...... _, .. ~ SAI'IArE=I h-'U.S CONSTRUCrED 02 o ... "' OJ AGENCY :; : = I C4 CESCAII''I'10N : · =s :""""''"'~c:·,e;:arNQ 02 OAT't; :J AGENCY I 04 DESCRII'TlON 01 ~ T 3ULJ< TA!';o I 0 I C X. FIRE CONTROL 02 OATE OJ AGENCY 04 DESCAIPT10N I 01 :; Y. LEACHATE T'REATMENT 02 DATE OJ AGENCY 04 DESCAIPT10N 01 :: Z AREA EVACUATED 02 DATE 03AGENCY 04 DESCRIPTION 01 0 1. ACCESS TO SITE REST'RICTED 02 DATE OJ AGENCY I 04 DESCRIPTION 01 0 2. POF'ULATION RELOCATED 02DATE OJ AGENCY I 04 DESCRIF'TION . 01 0 3. OTHER REMEDIAL ACTIVITIES 02DATC 03MEJCY - I 04 OESCRIPT10N I , No remedial actions to date. I ~ I Ill. c:nna,.~:c: OF INFORMATION tete--•·•··----·-" References 1' 3 . ••I I I POTENTIAL HAZARDOUS WASTE SITE SITE INSPECTION REPORT .. . . ~ ·. ..,._~; &EPA PART 11 ·ENFORCEMENT INFORMATION NC ··o·o244 n s55 .. II. ENFORCEMENT ;NFORMA TION I I I I I I I - I I I I I I Ill. SOURCES OF INFORMATION re•·---·•·••--·-···--·'- References 1, 3 ••I fPA 'Of'W 2070-1~ 17·111 I I PA-Score 1.0 scoresheets Page: 1 WINSTON CONTAINER COMPANY - 10/11/91 .. OMB Approval Number: 2050-0095 1------~~~=~~=~-:~=-~:=-=~=~~~~:--=~=~I I IDENTIFICATION I I POTENTIAL HAZARDOUS 1------1 I I State: I CERCLIS Number: 1 I I WASTE SITE I NC I D024477556 I I I PRELIMINARY ASSESSMENT FORM 1------1I CERCLIS Discovery Date: I I I 080179 1 I 1------l 1 1. General Site Information 1 I -;~~~~------~-~t~~~t-~~~~~;;~------1 WINSTON CONTAINER COMPANY I MORRIS FIELD ROAD PO BOX 668085 I I -~i~;~------~-~~~~~~-~-;i~-~~~~~--~-~~~~~;~----~-~~~-~~~~~~1 CHARLOTTE I NC I 28266 I MECKLENBUR jCode:jDist:j I I I I 60 I 09 I ------+------+------1 I Latitude: Longitude: IApprox. Area of Site:! Status of Site: 1 35 13 1 0.0" 80 55' 29.0" 1 14 acres 1 Active 1 I -;~-~~~~~~~~~~~~~~-~~~~~~~i~~------1 ------1 - owner: I Operator: I ~ ROBERT WINSTON, SR. I WINSTON CONTAINER COMPANY I 1------+------lI street Address: I Street Address: I I 11--~~~=~-:=~~~-~~~~------l--~~~=~-:=~~~-~~~~------: city: 1 city: 1 I I1--:~~~==~------l--:~~==~------1 state:! Zip Code: I Telephone: I State:! Zip Code: I Telephone: I I NC I 28226 I 704 394-0176 I NC I 28226 I 704 394-0176 I 1------+------l I I Type of Ownership: 1 How Initially Identified: 1 I !1 ______Private !I ______RCRA/CERCLA Notification !1 I I Ir I I PA-Score 1.0 Scoresheets Page: 2 ~ WINSTON CONTAINER COMPANY - 10/11/91 ~------1 IDENTIFICATION I POTENTIAL HAZARDOUS ~-~~;~~~-~-~;;~~~~-;~~~~~ WASTE SITE I NC I D024477556 PRELIMINARY ASSESSMENT FORM 1------1 CERCLIS Discovery Date: I I 080179 1 -;~-~i~~-;~;i~;~~;-~~;~~;~i~~------ ------Name of Evaluator: 1 Agency/Organization: I Date Prepared: I GROVER NICHOLSON I NC SUPERFUND SECTION I 5 SEP 1991 ------Street Address: I City: I State: 401 OBERLIN ROAD PO BOX 27687 I RALEIGH I NC ------+------I Name of EPA or State Agency Contact: 1 Telephone: GROVER NICHOLSON I 919 733-3801 ------+------I Street Address: I city: I State: 401 OBERLIN ROAD PO BOX 27687 I RALEIGH I NC I -~~-~i~~-~i;~~;i~i~~-<;~;-;;~-~;~-~~i;>------... Emergency I CERCLIS Signature: ~Response/Removal I Recommendation: I Assessment I Higher Priority SI I Recommendation: No I Name: I I Date: I Date: Position: I I I ~------I I I I I 'I I PA-Score 1.0 Scoresheets Page: 3 ~------:::::::_:::::::::_:::::::_~-~:~~~~:~------1 IDENTIFICATION I I POTENTIAL HAZARDOUS ~-~~~~~~-,-~;~~~~~-;~~~~~~ WASTE SITE I NC I D024477556 PRELIMINARY ASSESSMENT FORM 1------1 CERCLIS Discovery Date: I I oso119 I ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ Predominant Land Uses Within Site Setting: I Years of Operation: 1 Mile of Site: I Beginning Year: 1953 I Industrial Urban I Commercial I Ending Year: 1991 Residential I I I I ------+------Type of Site Operations: Waste Generated: I Recycling Onsite Waste Deposition Authorized I By: Present Owner Waste Accessible to the Public No .. Distance to Nearest Dwelling, School, or Workplace: I 300 Feet ------6. Waste Characteristics Information I -~~~~~~-~;~;------Q~~~~i~;------~i;~-~;~;~~i-~;~;;-~;-;~;~;~------Contaminated soil 6.00e+04 sq ft A Metals Non-drum containers 1.50e+04 gals V Organics I Inorganics I I Physical State of Waste as Deposited I Solid Liquid Tier Legend Sludge I I c = Constituent W = Wastestream 1 ~---~-=-~~:~~=------~-=-~:=~------! I I PA-Score 1.0 scoresheets Page: 4 WINSTON CONTAINER COMPANY - 10/11/91 ~------1 I IDENTIFICATION I I I POTENTIAL HAZARDOUS :-~~~~~~-,-~;;~~~~-;~~~~~~ I WASTE SITE I NC I D024477556 I I I PRELIMINARY ASSESSMENT FORM ~-~;;~~~~-~!;~~~;;;-~~~;~-! I I 080179 ------1 _::_~=~~~~-~::::_:::~~:: ______Is Ground Water Used Is There a Suspected List Secondary Target for Drinking Water Release to Ground Population Served by I Within 4 Miles: Water: Ground Water Withdrawn No No From: Type of Ground Water 0 1/4 Mile 21 I Wells Within 4 Miles: Have Primary Target Private Drinking Water Wells >1/4 - 1/2 Mile 110 Been Identified: · No I >1/2 - 1 Mile 500 Depth to >1 - 2 Miles 1678 I Shallowest Aquifer: 0 Feet ------>2 - 3 Miles 3232 ~ Nearest Designated ~Karst Terrain/Aquifer Wellhead Protection >3- 4 Miles 3840 1 Present: Area: 1 No None within 4 Miles Total 9381 ~~------I I I I I ~ I I I PA-Score 1.0 Scoresbeets Page: 5 WINSTON CONTAINER COMPANY - 10/11/91 ~------1 IDENTIFICATION I I POTENTIAL HAZARDOUS :-~~~~;~-~-~;;~~~~-;~~;~~~ WASTE SITE I NC I D024477556 1------PRELIMINARY ASSESSMENT FORM 1 CERCLIS Discovery Date: I I oao179 I -~:-~~:::::_~::::_:::~~:: ______::::_:_~:-~----- Type of Surface Water Draining 1 Shortest Overland Distance From Any site and 15 Miles Downstream: 1 Source to Surface Water: 1 Stream I I 0 Feet I o.o Miles I I I I I I I 1------+------I I 1 Is there a Suspected Release to 1 Site is Located in: l I Surface Water: No I Annual - 10 yr floodplain 1 1------~-~:-~~:::::_~::::_:::~~:: ______::::_~_~:-~----- Drinking Water Intakes Along the surface Water Migration Path: No I Have Primary Target Drinking Water Intakes Been Identified: No I Secondary Target Drinking Water Intakes: None I I I 1------ ..I I I PA-Score 1.0 scoresheets Page: 6 IL. WINSTON CONTAINER COMPANY - 10/11/91 · ~------~------I IDENTIFICATION POTENTIAL HAZARDOUS 1------1! 1 State: I CERCLIS Number: WASTE SITE I NC I D024477556 I 1------PRELIMINARY ASSESSMENT FORM 1 CERCLIS Discovery Date: III I oao179 1------l 1 a. Surface Water Pathway Part 3 of 4 1------l Fisheries Located Along the Surface Water Migration Path: Yes I Have Primary Target Fisheries Been Identified: No I I secondary Target Fisheries: I Fishery Name Water Body Type/Flow(cfs) I I Recreational fishing small-moderate stream/ 10-100 I Recreational fishing small-moderate stream/ 10-100 I I I I I I I I I ~------1a. surface Water Pathway Part 4 of 4 ------~------I Wetlands Located Along the Surface Water Migration Path? (yjn) No Have Primary Target Wetlands Been Identified? (yjn) No Secondary Target Wetlands: I None I ------Other Sensitive Environments Along the surface Water Migration Path: No I Have Primary Target Sensitive Environments Been Identified: No Secondary Target Sensitive Environments: I None I ------~ I I I PA-Score 1.0 scoresheets Page: 7 WINSTON CONTAINER COMPANY - 10/11/91 ~------~------1 IDENTIFICATION POTENTIAL HAZARDOUS 1------I 1 State: I CERCLIS Number: WASTE SITE I NC I D024477556 1------PRELIMINARY ASSESSMENT FORM 1 CERCLIS Discovery Date: I I 080179 I _::_~~~=-~~~~~::_:~=~~~: ______Are People Occupying Residences or Attending School or Daycare on or Number of Workers onsite: 1 - 100 Within 200 Feet of Areas of Known I or Suspected Contamination: No I Have Terrestrial Sensitive Environments Been Identified on or Within 200 Feet of Areas of Known or Suspected Contamination: Yes I Terrestrial Sensitive Environments: I Critical habitat for Federally designated endang/threat species ~I I 1------l 10. Air Pathway 1:-~~~~i-;~~~i~~i~~-~~-~;-;i~~i~~~-~;-~~;;;-~-~~;~;~~;~-;;i;~;;-~~-~i;~--;~-~-- 1 Onsite 50 1------l 0 - 1/4 Mile 21 I Wetlands Located 1 >1/4 - 1/2 Mile 110 I Within 4 Miles of the Site: Yes I I >1/2 - 1 Mile 1869 I 1 >1 - 2 Miles 6100 1~------>2 - 3 Miles 11100 1 Other Sensitive Environments Located l >3 - 4 Miles 25900 I Within 4 Miles of the Site: No Total 45150 I I 1 -~;~;i~i~;-;~~i;~~~;~~;-;i~~i~-~~;-;ii;-~~-~~~-~i~~~------1 I Distance Sensitive Environment Type/Wetlands Area(acres) 1 >1/4 - 1/2 Wetlands (< 1 acre) 1 I 1 I I I ~------! I I LATITUDE AND LONGITUDE.CALCULATION WORKSHEET 12 LI USING ENGINEER'S SCALE (1/60) lit SITE NAME: (}JtN~7orJ GtJT-4/NER.. Crt'! (J,t;)J'/ CERCLIS 1: iJCl:> ~Z4 4}7 ss-~ AKA: ------SSID: ------I ADDRESS: Mc;f2.i21S hE"t-D l?t:.-A-1:> f>c; Box ciTY: CHA-12.!orre- sTATE:..-.:M~C::..~-- ZIP CODE : __z.=-..;;_'Z_.Zc....;::..~....;::t;::--- __ I SITE REFERENCE POINT: 5£ eNt:> c;,:= Elli2.72..ez... /JGJI?.AJ-0/.IT Ct!.>IJI/EY0/2. usGs QUAD MAP NAME: CltA;2t.orre UJes.r TOWNSHIP: -=- N/S RANGE: -=-. E/W I SCALE: 1:24,000 MAP DATE: /Cf67{ SECTION: __1/4 - 1/4 __1/4 ~ PHO'TOe:Er.JtSE> rf'80 I MAP DATUM: ~ 1983 (CIRCLE ONE) MERIDIAN: ______COORDINATES FROM LOWER RIGHT (SOUTHEAST) CORNER OF 7.5' MAP (attach photocopy): I LONGITUDE: ~0 sz I 30 " w LATITUDE: "3G:" o o::t- • 3o ., N I COORDINATES FROM LOWER RIGHT (SOUTHEAST) CORNER OF 2.S' GRID CELL: I LONGITUDE: I Ax o.3304 = ze .11/:_" -:;4. * I .C~~E.~PRESS IN MINUTE~ fillD SECONDS (1'= 60"}: _Q_·~·~" .... I D) ADD TO STARTING LONGITUDE: ~o~• bO ._a__" + ~· 2~ .~ = I SITE LONGITUDE: ~o~·~·~" I vJ DATE: /P OC../ 91 .. I E-10 I I!!' ~ I li II I; li I I. I .. --- I I 1- I I· I '(-··-----·--·-----····--···-·------ T-oPOGRAPHic ~{AI> QUADRANGLE NAME: · &,4JZLbrrGr Wes r SCALE: 1:2.:,000- . COORDINATES OF LOWER RIGHT-HAND COR.'\ER OF 2.5-MINUTE GRID: LATITUDE: l£o JZ. '1Q_· LONGITUDE: 'S/)_oS,S_•(;!i_: E-ll I