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7 zones, arcs and active continental margins

ubduction zones are created when two litho- Th e third type of convergent plate boundary spheric plates move against each other and represent the active continental margins where S one of the two plates descends under the other oceanic litho sphere is subducted beneath conti- through the process of subduction. However, only nental litho sphere without a marine basin behind oceanic litho sphere is able to sink deeply into the the ; rather, the arc is built directly on ’s to become reincorporated there. the adjacent . Th e is Continental crustal material is generally too light connected directly to the hinterland, although a to be subducted to great depth. Th e interaction of shallow marine basin may exist behind the volcanic the subduction zone and the of the arc. Examples for active continental margins are mantle generates the melts that rise to feed the the , SE , and the western and central typical of island arcs and active conti- that includes and . nental margins. Th e forth type of convergent margin occurs Subduction zones are critical to the dynamics of along zones of continent-continent collision. If the Earth because they represent the essential driv- two continental masses collide during continuous ing force behind the movement of plates. Moreover, subduction, they eventually merge. Telescoping of initiated by subduction is responsible the two plates and the buoyancy of the subducting for the creation of continental through a se- continent eventually leads to a standstill of subduc- ries of complex processes. Th e continental crustal tion within the collision zone. Th e oceanic part material generated in this fashion has a low specifi c of the subducting plate tears off and continues to weight and remains at the outer rind of the Earth drop down, a process referred to as " breakoff ". and is not reintegrated into the mantle. Without this Continent-continent collisions ultimately result in light-weight , which forms high the formation of ranges like the Hima- topographic features on the Earth, our planet would layas or the Alps. Fig. 7.1 Convergent have a completely diff erent face. Th e total length plate margins of the Earth of global subduction zones sums to more than Structure of plate margin systems with characterized by ensimatic 55,000 km, a length only slightly shorter than the subduction zones island arcs (underlain by total length of the mid- ridges (60,000 km). Systems of convergent plate boundaries are char- ), ensialic island arcs (underlain by Four types types of convergent plate boundaries acterized by a distinct topographic and geologic continental crust), and ac- are recognized (Figs. 7.1, 7.2): subdivision. Although the plate boundary itself is tive continental margins. Th e fi rst type occurs when ocean is subducted below other ocean litho sphere ("intra- oceanic subduction zone") to create a volcanic Kamchatka Alaska system built on oceanic crust ("ensi- Nankai Alëutian Kuril Cascade matic island arc"; sima – artifi cal word fi rst used Ryukyu by Wegener made from silicon and magnesium Izu-Bonin Lesser to characterize ocean fl oor and Earth’s mantle). Mariana Examples for intra-oceanic, ensimatic island arc Philippine systems include the Mariana in the Pacifi c Solomon and the in the Atlantic. Sunda Banda Peru Th e second type occurs where oceanic litho- Chile sphere is subducted beneath continental litho sphere Kermadec South and an island arc underlain by continental crust - forms (" ensialic island arc"; sial – silicon and alu- wich minum for continental crust). Th e island arc of this system is separated from the continent by a marine basin underlain by oceanic crust. Examples for is- active continental margin ensimatic island arc (deep <8 km) land arc systems underlain by continental crust are ensialic island arc ensimatic island arc ( trench >8 km) the Japanese Islands and the eastern Sunda Arc.

W. Frisch et al., Plate , DOI 10.1007/978-3-540-76504-2_7, © Springer-Verlag Berlin Heidelberg 2011

Licensed to jason patton 792 Subduction zones, island arcs and active continental margins

Ensimatic island arc: only represented by a line at the surface, commonly volcanic arc within a deep sea trench, a zone several hundreds Philippine backarc basin Sea Plate of kilometers wide is formed by processes which are related to subduction. Th e volcanic zone above the subduction zone, in many cases expressed as an

lithospheric mantle island arc, is the dominating element of this plate boundary system. We use arc as shorthand for the spreading zone terms volcanic arc or magmatic zone. Th e arc is the asthenosphere oceanic crust point of reference for the that is usually divided into three parallel zones: from the trench to the arc is the zone, the arc zone Ensialic island arc: Japan comprises the magmatic belt, and the region behind Japan the arc is the backarc zone (Fig. 7.3). Th is generally Eurasian Pacific Plate Plate (backarc basin) Mt. agreed upon subdivision of three parts turned out to Fuji be practical in order to describe the complex struc- tures of convergent plate boundary systems. Deep-sea form the major topographic

continental crust expression at convergent plate boundaries. Th ese deep, narrow furrows surround most of the Pacifi c Rim and small portions of the rims that surround the Indian and Atlantic . Oceanic litho sphere is bent downward under the margin of the "upper Active continental margin: Andes Andes high active volcanoes plate" and dives into the asthenosphere. Th e result is an elongated deep trench that is located between South American retroarc the abyssal plains and the border of the upper plate. Peru-Chile Plate Trench Th e deepest trenches, with depths of about 11,000 m, are known from the Challenger and the Vitiaz deep (named aft er an English research vessel and a Russian researcher) in the southern Mariana trench. Water depths of more than 10,000 m are also known from the Kurile, Izu-Bonin, Philippine and Tonga- Kermadec trenches (Fig. 7.1). Convergent plate boundaries are responsible for the greatest diff erences of relief on the Earth’s Continent-continent collision: surface. Diff erences in altitude of 10 km between the deep sea trench and volcanoes of the magmatic Indo- arc are not unusual. A relief of 14,300 m across a distance of less than 300 km can be observed Himalayas between Richards Deep (–7636 m) and Llullaillaca Tibetan Plateau (+6723 m) in the Chilean Andes, the highest active

continental crust on Earth. In a transect from the trench onto the upper lithospheric mantle plate, the following morphological features gener- ally occur (Fig. 7.3). Th e landward side of the deep

asthenosphere sea trench is part of the upper plate and consists of a slope with an average steepness of several degrees. slab breakoff In front of the Philippine Islands the angle exceeds 8° where a rise from –10,500 m to –200 m occurs over a distance of 70 km. Th e outer ridge follows Fig. 7.2 Examples of diff erent types of plate margins behind the slope. In most cases, the ridge remains with subduction zones. The island arc of the Marianas substantially below ; however, in several developed on oceanic crust, that of Japan on continental cases, islands emerge above sea level ( Sunda Arc: crust. The volcanic zone of the Andes is built on the South American continent ( active continental margin). The Mentawai; Lesser Antilles: ). Th e outer collision of two produces a ridge is not always distinctive. Next in the transect, like the Himalayas – subduction wanes, leading to slab directly in front of the volcanic arc, lies the forearc breakoff . basin, another prominent morphological element.

Licensed to jason patton Spontaneous and forced subduction: Mariana- and Chile-type subduction 937

forearc region magmatic backarc region arc outer forearc ocean volcanic arc backarc basin continent ridge basin volcanic front Abukuma-type deep sea trench accretionary wedge 0

oceanic crust

50 lithospheric mantle subducted

high-pressure metamorphism 100 asthenosphere

[km]

+100 free-air gravity [mGal]

-100

200 heat flow [mW/m2]

100

0

Collectively, the deep sea trench, outer ridge, Fig. 7.3 Structure of a plate margin system with sub- and forearc basin comprise the forearc region. Th e duction zone and ensialic island arc. Gravity and heat fl ow distance between the plate boundary and magmatic data show typical pair of negative and positive anomaly. 1 Gal (galilei) = 1 cm/s2(unit of acceleration). zone has a width of between 100 and 250 km. Th is 1 mGal = 10-3 Gal. mW/m2 = milliwatt per square meter. region is also called the arc-trench-gap, a magmatic gap that with very few exceptions is void of magmat- ic activity. Low temperatures in the crust are caused Spontaneous and forced subduction: by the coolness of the subducting plate underneath Mariana- and Chile-type subduction and prevent the formation of by melting or Subduction zones can be subdivided into two the rise of magma from deeper sources. types, based on characteristics of the subducted The volcanic arc, with an average width of plate (Uyeda and Kanamori, 1979). Th e fi rst type 100 km, is the central part of the island arc or the is referred to as a Mariana-type subduction zone active continental margin and is characterized and is characterized by old and dense litho sphere by signifi cant magmatic activity. Approximately that is subducted and sinks into the sublithospheric 90 % of all active volcanoes above the sea level, mantle by its own weight. Th erefore, it is generally most of which are in or around the Pacifi c Ocean, the steepest-dipping of the two. Th e second type are subduction-related volcanoes. The zone of is referred to as a Chile-type subduction zone volcanism has a sharp boundary on the forearc and is characterized by younger, hotter and less- margin and a gradual one on the backarc margin dense lithosphere that dips at a shallower angle (Fig. 7.3). (Fig. 7.5). Island arcs are separated from adjacent conti- Because oceanic lithosphere becomes denser nents by a marine basin underlain by ocean crust, with increasing age, it can achieve a density greater the backarc basin (Figs. 7.2, 7.3). Active continental that that of the underlying asthenosphere and thus margins, synonomous with continental arcs, have a be more easily subducted; this is spontaneous sub- backarc region that may have thinned continental duction (Nicolas, 1995) or free subduction (Frisch crust and/or a zone of compressional structures. and Loeschke, 1986), meaning that it arises from

Licensed to jason patton 794 Subduction zones, island arcs and active continental margins

What is the reason for the arcuate shape of island arcs? angle of 45° and 3335 km with an angle of 60°. However, most island arcs have radii that do not match these calculations. For In principle the arcuate shape of island arcs is easy to explain. example, below a depth of 100 km, the subduction zone of A thumb pushed against a rubber ball causes the normal con- the Mariana Arc dips nearly vertical (Fig. 7.2). However, The vex bulge of the ball to become a concave dent and the line of radius of bending is less than 1500 km; its southern margin is bending marks a circular line on the surface of the ball. Before even more stronger bent (Fig. 7.1). There are several possible a plate enters a subduction zone it possesses a curvature ac- explanations for this discrepancy. One may be attributed to cording to the curvature of the Earth. When it dives into the a delay factor as the angle of inclination varies over certain subduction zone, this curvature inverts and convex becomes periods of time and the geometry of the upper plate does concave. Adjacent arcs commonly display a catenary-like not respond in immediate fashion. A second reason may be pattern as observed in the related to inhomogeneous structure and stiff components Western Pacifi c where one in the upper plate. In the case of the Mariana Arc, it appears R island arc drapes next to the that some other tectonic feature has also bent the arc. The subduction zone other (Fig. 7.1). The radius of strong curvature in its southern part is related to drag along r an arc, r, can be calculated a transform . α using the formula In the case of active continental margins, the infl uence of the subduction zone upon the shape of the upper plate and R that of the overall plate boundary becomes minimal. The α subducted plate is not able to substantially cut or deform the plate Earth´s radius where R is the radius of the thick and stiff edge of the continental litho sphere. The long, (6370 km) Earth (6370 km) and α the linear convex and concave shape of the plate boundary to the inclination angle of the sub- west of the Andes is determined by the shape of the South duction zone (Fig. 7.4). American continent and the various older plates that make it Subduction zones have up. Subduction zones commonly occur along old passive con- angles of inclination be- tinental margins at the zone of weakness where the oceanic tween 30° and 90° and aver- litho sphere has been welded to continental litho sphere and Fig. 7.4 Geometric relation age approximately 45°. The fractures formed due to their diff erent buoyancies, especially between the angle of a subduction zone (α) and the curvature radius radius of an island arc (r) is where the old oceanic litho sphere is cold and dense. This (r) of a deep sea trench– island arc 2500 km using the formula scenario appears to have occurred along the western margin system (Bott, 1982). above with a subduction of .

internal cause. Th eoretically this inversion of den- eastern margin of the Pacifi c, mostly less than sity occurs when the oceanic litho sphere reaches 50 Ma (Fig. 2.12), as well as that of the Philippine an age of ca. 30 million years. In order to create Sea Plate and the western Sunda Arc is too buoy- new subduction, the aging process must proceed ant to subduct spontaneously, but rather is forced further because an excess of density is necessary to underneath the upper plate by compressional forces. create the vertical forces that are capable of tearing Such conditions promote shallow subduction and a off the litho sphere and initiating subduction. As strong coupling to the upper plate. In other words, mentioned above, oceanic litho sphere may reach the horizontal compressional force is transferred ages of up to 200 millions of years (oldest oceanic from the subducting plate to the upper plate and crust today: ca. 185 Ma, in front of the Marianas compressional structures such as folding and - and ca. 175 Ma, at both margins of the Central ing of crustal units evolve far into the upper plate ). Th erefore, old ocean crust can (Fig. 7.5). In contrast, spontaneous subduction undergo spontaneous subduction. Old ocean crust with steeply dipping subduction zones generates has a litho spheric mantle that is approximately 2 % extensive decoupling so less deformation of the denser than the asthenosphere directly beneath it. upper plate occurs and extensional structures form. However, if the age of the oceanic litho sphere is Forced subduction may evolve from spontaneous young, subduction can only be initiated by com- subduction as increasingly younger portions of the pressional forces; this is forced subduction. downgoing plate are subducted thus changing the Th e western rim of the Pacifi c Plate is charac- vertical component at a plate boundary to a more terized by litho sphere with ages greater than strongly coupled horizontal force. 100 Ma. Th erefore, spontaneous subduction domi- Steeply dipping subduction zones such as the nates. However, younger litho sphere typical of the Mariana-type subduction produce significant

Licensed to jason patton Spontaneous and forced subduction: Mariana- and Chile-type subduction 957

WE Fig. 7.5 Mariana-type consequences. A strong of the subducting margin of upper plate litho sphere forces the subduction zone to roll-back under extension volcanism (above) and Chile-type (be- oceanward – i. e., towards the subducting plate or low) subduction zones. At the Marianas, subduction easterly into the edge of the Pacifi c Plate in the old, dense occurs easily and the sub- lithosphere case of the Marianas. Th e locus of the hinge zone, duction zone rolls back to where the ocean fl oor is bent down into the sub- the east (insert). At Chile, duction zone and which marks the plate boundary, young and specifi cally migrates backwards, away from the locus of the arc. light litho sphere pushes subduction upwards; subduction is Th is process is termed subduction or slab roll-back 12 rollback forced. (Fig. 7.5, insert). Th e roll-back causes extensional forces to develop at the plate boundary and the edge of the upper plate is extended. Th e roll-back causes margin of upper plate under compression the island arc to migrate towards the outside of the WE arc system which in turn results in a strong exten- sion of the backarc region (Fig. 7.5). If the arc was originally built on a continent, this process leads plutonism to the separation of the island arc from the upper plate continent. Th e resulting separation behind the island arc generates a backarc basin and with young, less dense suffi cient extension, new oceanic crust may form lithosphere (example: Sea of Japan). Th e western Pacifi c is char- subduction zone acterized by numerous island arc–backarc systems with buoyancy (Fig. 7.1). Th e garland- or drape-like alignment of the island arcs results from their separation from the continent and the formation of backarc basins. Typically, the garlands have lengths from 2000 to structures are restricted essentially to the tip of 2500 km. Because the Mariana Arc comprises an the upper plate. intra-oceanic subduction zone, the formation of The subduction zones and convergent plate the backarc basin occurred solely within oceanic boundaries of Chile-type subduction are funda- crust (Fig. 7.2). mentally diff erent in many ways. Th e subducting Subduction roll-back that forms during Mariana- plate is intermittently coupled to the upper plate type subduction has an eff ect on the topography of because of the buoyancy of the former; this causes the plate boundary system. Th e mean topographic compression and thickening of the upper plate elevation on the edge of the upper plate is low (Fig. 7.5). Th ickening of continental crust leads to because of the eff ect of suction and extension. On orogenesis and the generation of a high mountain the other hand, the depth of the deep sea trenches range. Deep sea trenches are shallower and volca- is signifi cantly deeper on average because the sub- nic zones are characterized by signifi cantly higher ducting plate bends downward very steeply and elevations than volcanoes associated with Mariana- the island arcs do not deliver enough sedimentary type subduction. Th e highly elevated hinterland is material to even partially fi ll the trench. Th e world’s more likely to deliver sedimentary material into deepest trenches, all with depths greater than the trenches, and the supply is gerenally 8000 m, occur along westward-directed subduc- not hampered by intervening ridges. Even more tion zones (including those of the Atlantic Ocean) consequential than the topographic height is the that involve old oceanic litho sphere (Fig. 7.1). Th e structural height, the total amount of uplift within roll-back of the westward directed subduction the volcanic zone, which may exceed 20 km. Crustal zones may be enhanced by an eastward directed structures originally formed at depth are subse- asthenospheric as calculated from global quently uncovered by . In fact, metamorphic plate drift compared to fl ow of the sublithospheric and intrusive magmatic rocks at the surface in the mantle (LePichon, 1968; Doglioni et al., 1999). Andes can be used to estimate the amount of uplift A curious situation at subduction zones with and subsequent amount of erosion. backarc basins (Mariana-type subduction) is the Along Chile-type subduction zones the com- juxtaposition of strong convergence and divergence. pressional forces are transferred far into the Although relative plate movement velocities at upper plate. Th erefore, in this area convergent plate boundaries in the western Pacifi c are particularly strong and frequent. Regionally, approach 9 cm/yr, a wide area at the edge of the up- compressional structures with overthrusts evolve per plate is under extensional stress. Compressive that are oceanward-directed in the forearc and

Licensed to jason patton 796 Subduction zones, island arcs and active continental margins Fig. 7.6 Stress accu- completely fi lled with sediments and some trenches mulated during coupling coupling at plate boundary bulge have surprisingly little sediment due to restricted at the boundary between sediment supply; and in most trenches, the sedi- Juan de Fuca and followed ments are continuously subducted and thus tec- by rapid decoupling tonically removed. (Hyndman, 1996). A similar stress Th e sedimentary input into the deep sea trenches decoupling combined accumulation varies considerably. Th e subducting oceanic plate with an abrupt movement carries sediments on its surface (pelagic sediments of the edge of the upper plate towards the trench decoupling extension and subsidence from the abyssal plain; pelagos, Greek sea, ocean) was responsible for the and this material can be carried tectonically into in the subduc- trenches. Pelagic deposits can also settle directly tion zone of Sumatra that into trenches from the thick above. caused the devastating Other sediments come from the adjacent island arc, on 26 December, fracture 2004. forearc region, and continental margin as suspen- sion deposits, turbidity current deposits, and vari- ous slump and landslide deposits. Th ese terrigenous sediments (terrigenous, Latin-Greek of the ) are continentward-directed in the backarc region carried into the trench across the continental slope (Fig. 7.5). Cosequently, the backarc area is also and typically transported over large distances along under compressional stress. Crustal shortening the trench axis by trench-parallel currents. Th ere- occurs across the entire magmatic zone, which in fore, most trenches consist of mixtures of pelagic turn has an eff ect on the magmatism itself. Crustal and terrigenous deposits as well as sediments and melts typically become trapped in the crust and sedimentary rocks transported into the trench on crystallize as intrusions or melt adjacent crustal the subducting lower plate. rocks and feed highly explosive acidic volcanoes Th e amount of sediment in a trench, regardless (see below). Th e collective processes of tectonic of origin, is related to the balance between the sedi- stacking and magmatic have formed a ment supply and the slow tectonic removal of trench crustal thickness of 70 km in the Andes, one of the fi l l . Th ick trench deposits are generally favored areas of thickest continental crust on Earth. by a low subduction rate and accompanying slow Th e transfer of forces at convergent plate bound- tectonic removal of trench-fi ll material. If trench aries varies. Stress analyses in the forearc region of fi ll is rapid under these conditions, the trench fi lls the upper plate along and Central America and trench morphology is and the surface revealed changing states of stress through time grades into the adjacent abyssal plains. Such a (Meschede et al., 1997). Phases of compression that condition exists today in the trench off Oregon and refl ect coupling of forces between both plates may Washington, USA. In contrast, trenches are deep be followed by extensional phases during which and more irregular if the sedimentary supply is low decoupling occurs. During the extensional phases or if swells adjacent to it such as the forearc outer the crustal stack at the edge of the upper plate be- ridge intercept and block sediment entry. Th e lack comes unstable, and thus collapses. Reverse and of sediment in the deep trenches of the Marianas, thrust faults that evolved during the compressional the Tonga and , and the Kuril phases can be reactivated as normal faults. Subse- Islands can be explained by these conditions. quent phases of coupling and decoupling are also A comprehensive example of the factors that observed at the plate boundary between the Juan are relevant to sedimentation in deep sea trenches de Fuca Plate and North American Plate. During is found in the Northern Pacifi c Trench system periods of plate coupling, the edge of the upper plate (Fig. 7.7). Comparing the Washington-Oregon is vaulted until there is a spontaneous decoupling Trench, the Alëutian Trench, and the Kurile- because of the high accumulation of energy. As Kamchatka Trench, a systematic change of the sedi- a result, the upper plate abruptly steps forward mentary balance can be observed. Th e sedimentary towards the subducting plate and its margin is ac- cover tectonically transported into the trench by companied by subsidence (Fig. 7.6). the ocean fl oor ( pelagic sediments) increases sig- nifi cantly in thickness from east to west. One of the Deep sea trenches as sediment traps oldest parts of Pacifi c oceanic crust occurs in the Deep sea trenches, the greatest depressions on northwestern Pacifi c. Accordingly, the sediments Earth and deepest zones in the oceans, are places formed on the abyssal plains are thicker here than where sediment is trapped both tectonically and further to the east and these deposits are carried sedimentologically. However, few trenches are into the trench by the subduction process.

Licensed to jason patton Accretionary wedge and outer ridge 977

150°E 160°E 170°E 180° 170°W 160°W 150°W 140°W 130°W

60°N Alaska Canada

Sea of Okhotsk

Kamchatka

A 7680m 50°N 7220m s d 8530m n la B Washington- Is Alëutian Trench ril Oregon Ku Kuril- Kamchatka Trench 9000m Trench C 10540m

Kamchatka Trench[km] Alëutian Trench[km] Washington-Oregon Trench [km] A B C hemipelagic 6 sediments 2 terrigenous 6 pelagic sediments sediments (turbidites) 7 3 7 8 4 8 oceanic 9 crust 5

Fig. 7.7 The deep sea trench system of the northern angle of 0.2° is suffi cient to transport the fi nest Pacifi c (Scholl, 1974). A systematic change of sediment fraction of sediments along the trench axis. Trench- balance takes place between the Kurile-Kamchatka parallel transportation has been documented over Trench (A), Alëutian Trench (B), and Washington-Oregon Trench (C). a distance of 1400 km. In this manner, sediments brought into the trench at local points are spread longitudinally over long distances. Th ick turbidite sequences have been deposited in Th e Kurile-Kamchatka Trench generally lacks the Washington-Oregon Trench during the Pleis- trench turbidites (sediment input at one location tocene ice age. Sea level was lowered by more than is diverted into the Alëutian Trench). Th e depth 100 m during glacial maximums, and a lack of - of the trench with respect to the adjacent abyssal riers enabled free transport of sediments from the plain refl ects the diff erent sedimentation regimes of land to the shelf margin where turbidites directed these three areas: Th e Kurile-Kamchatka Trench is the sediment into the deep sea. Th e trench was com- approximately 3–4 km deeper; the Alëutian Trench pletely fi lled with turbidites and consequently no is 1–2 km deeper, and the Washington-Oregon longer morphologically evident. Th erefore, turbidity Trench does not show notable trench morphology currents could reach the open ocean and the pelagic or diff erence in depth. sedimentary layer was thickened considerably by distal turbidites (hemipelagic sediments: Fig. 7.7). Accretionary wedge and outer ridge Turbidites are described as distal (as opposed to Th e morphology of the outer ridge forms as sedi- proximal) when they are far away from their origin ments are scraped off of the subducting plate dur- and contain only fi ne-grained, silty to clayey mate- ing subduction. As the subducting plate transports rial. Presently, the huge continues its sedimentary fi ll from the trench towards the to direct sediment into the trench. arc, some portion of the sediment is subducted Th e Alëutian Trench is not directly infl uenced by and transported down to great depths where it terrigenous sediments because the outer basin and becomes an important factor in the feeding of outer ridge intercept the sediment supply. However, subduction-related . Th e remaining por- canyon-like gaps in the outer ridge exist adjacent tion, or in some cases the entire sedimentary layer to Alaska and in the westernmost part near Kam- and parts of the oceanic crustal , can be chatka. Th ere sediments are transported as turbid- scraped off at the frontal tip or the bottom of the ity currents into the trench where they are diverted upper plate and added to a so-called accretionary parallel to the trench axis. At some locations a slope wedge on the upper plate (Fig. 7.8).

Licensed to jason patton 798 Subduction zones, island arcs and active continental margins An accretionary wedge grows from below. Th e stacking. In contrast, south of Japan, where the scraped-off sedimentary layers are stacked and Plate subducts beneath the Eurasian continuously uplift ed by renewed underplating Plate, a thick sedimentary layer greater than 1000 m from below, a process that results in morphological is entering the Nankai subduction zone. Here, the elevation of the outer ridge. Th e more material that decollement zone remains in the sedimentary layer is scraped off , the higher the elevation of the outer and does not cut through the underlying oceanic ridge. Th e process of accretion has been modeled crust as is the case in Vanuatu. Approximately in sandbox experiments so the evolution of the ac- the lower third of the sedimentary layer is being cretionary wedge is well understood (Fig. 7.8). Th e subducted and does not contribute to the growth underplating process resembles large-scale of the accretionary wedge. thrusts in mountain ranges. Previously juxtaposed Increased pressure and temperature occurs in layers of sediment are stacked during the shorten- the deeper parts of accretionary wedges. Th e rocks ing process and at each overthrust, older sediments are metamorphosed and deformed by dynamic are placed over younger ones. Th e process and processes acting within the wedge. Deformation sequence of events can also be viewed from the structures like scaly fabric in shear zones form at opposite perspective – younger units are forced shallow depths shortly aft er entering the subduc- below older ones by underthrusting. tion zone (Fig. 7.10). Such a fabric is characterized Eight overthrust planes that display repetitions by a large number of polished fault planes (slick- of the sedimentary layers have been drilled at the ensides) on small, cm-sized rhombohedra-shaped Vanuatu accretionary wedge in the SW Pacific blocks of claystone. With continuing deformation (Fig. 7.8). Because the sedimentary layer at the penetrative narrow cleavage planes develop (“slaty subducting plate has a thickness of slightly more cleavage”) and with increasing pressure and tem- than 100 m, the much greater thickness of the perature, metamorphism begins. accretionary wedge is a result of intense tectonic Large submarine slides may occur along the steep slope of deep sea trenches. Such large-scale deep sea trench 1000 m slides have been studied by bathymetric investiga- outer accretionary wedge ridge tions along the Pacifi c of Costa Rica and along 500 m the Kermadec deep sea trench north-northeast of Site 829 Site 828 . It is hypothesized that the slides are triggered by larger earthquakes that are frequent in oceanic crust a subduction zone. Competent layers such as sand- stones are torn and then embedded as fragments basal decollement into soft er -rich layers to produce a mixed layer of and claystone with a “block-in-matrix”

ODP Leg 134 Site 828 Site 829 structure. Such rocks are called mélanges (mixture drill sites Pacific Plate of rocks), and more specifi cally sedimentary mé- 15°S langes because they formed primarily by sediment- Fig. 7.11 828 Vanuatu gravity gliding processes ( ). 829 Th e slide masses, including some isolated large pieces of rocks (olistolites, Greek sliding rocks), Indo- clastic sediments may eventually reach the deep sea trench and then Australian Pliocene/Pleistocene Plate enter the subduction zone (Fig. 7.11). Th erefore, Eocene- off -scraped rocks of the oceanic crust () 20°S

thrust planes Fig. 7.8 Upper: structure of the accretionary wedge in front of Vanuatu, southwest Pacifi c (Meschede and Pelletier, 1994). Each thrust plane is characterized by 165°E 170°E younger rocks that underlie older rocks. Oceanic crust has been scraped-off from the subducting plate and added into the accretionary wedge. Limestones and basalts 10 cm were strongly sheared at the thrust planes and tectonic breccias were formed. Middle: map of subduction zone and stratigraphic columns obtained from Deep-Sea Drill- ing Project. Lower: tectonic stacking of the sedimentary sequences has been modeled in a sandbox experiment sandbox experiment basal decollement (construction of the experiment and photo: Nina Ku- kowski, GFZ Potsdam, ).

Licensed to jason patton Accretionary wedge and outer ridge 997 and various rocks transported into the deep sea indurated sedimentary rocks within a soft matrix trench are juxtaposed within the tectonic zone of of clay or slate comprise a tectonic mélange. Parts friction between the two plates where all compo- of this mélange may have been mixed initially nents are mixed by the strong tectonic movement. by sedimentary and later by tectonic processes Pieces of all magnitudes (up to kilometers in size) (sedimentary-tectonic mélange; Fig. 7.11) although of disrupted competent rocks like and the processes can be diffi cult to distinguish. If

The accretionary wedge of the Sunda Arc as the Andaman and Nicobar Islands and the Mentawai Ridge in front of Sumatra. Farther SW away from the infl uence of the The Sunda Arc provides an instructive example demonstrat- and adjacent to Java, the trench is distinctive with ing how the shape of the accretionary wedge depends on the depths of almost 7500 m. Accordingly, the outer ridge is not well amount of sediments transported into the subduction zone expressed and lies mostly below a water depth of 2000 m. (Fig. 7.9). Fueled by an enormous monsoon-controlled supply Along Sumatra, the slope of the accretionary wedge falling of sedimentary material, the and Brahmaputra rivers from the outer ridge to the deep sea trench typically displays constructed the huge several-kilometer-thick submarine Ben- distinctive subdivisions. Here active thrusts produce elongate gal fan (Fig. 4.16) that extends to the southernmost point of fl at areas and depressions that are called slope basins (Fig. 7.9, Sumatra. The sedimentary fan lies on the Indo-Australian Plate insert). They are common along Mentawai Ridge where some and is transported towards the NNE where it is being subducted are exposed above sea level. During their complex history, they in the Sunda Arc. Therefore, the deep sea trench along the acted as sediment traps that recorded the uplift history of the northwestern part of this island-arc system is mostly masked outer ridge. Analyses of the microfauna indicate uplift from by the high sedimentation rate while the outer ridge, built by deep water to shallow water conditions. The youngest sedimen- the tectonic stacking of fan-supplied sediments, is emergent tary rocks include the formation of reefs in very shallow water, several hundred meters above sea level. It forms islands such followed by uplift above sea level (Moore et al., 1980).

3500 m 90°E 100°E 110°E volcanic arc outer forearc deep sea Andaman Islands ridge basin 10°N trench 4200m Bengal Fan (with depth Nicobar Islands Siberut Sumatra contours) Eurasian Andaman Plate Mentawai Sea M slope 4000 m e basins n t a w a i

5210m 1790m Sunda Shelf 0° Sumatra 4500 m R i d g e location of 7 cm/yr cross section Ninetyeast Ridge 6070m 7360m

Java Indo-Australian Plate J a Java va 3560m

R i d g e 5270m 10°S c h strike-slip fault Ridgee n 7450m Trench Tr r active volcano o T i m outer ridge Sahul Shelf subduction zone 8 cm/yr

Fig. 7.9 Map showing contrasting plate-tectonic conditions along ridge are signifi cantly deeper. In front of Australia, the continental the Sunda Arc. In front of Sumatra, sediment of the thick Bengal fan are crust of the Sahul shelf is being subducted beneath the Sunda Arc; this scraped-off and incorporated into the accretionary wedge. This causes causes a particularly strong uplift of the outer ridge (Timor Ridge) and the outer ridge to emerge from the sea at this location ( Mentawai marks the initial stage of orogenesis. Ridge – see insert). In front of Java, the deep sea trench and the outer

Licensed to jason patton 7100 Subduction zones, island arcs and active continental margins Fig. 7.10 Development of scaly fabric and slaty cleav- formation of scaly fabric slaty cleavage age along thrust planes in an accretionary wedge. incipient advanced ~5 cm

ophiolitic material forms the dominant component, it is called an ophiolitic mélange. Such ophiolitic mélanges are commonly alined along the zone between plates aft er a collision. 1 km accretionary wedge instead of accretion Sedimentary accretionary wedges occur in many subduction zones including large portions of the of Oman (Makran subduction zone, Fig. 5.16), Sumatra, SW Japan, and in smaller areas of western decollement and the Lesser Antilles (Fig. 7.13). oceanic crust Many other subduction zones are characterized by the opposite process, subduction erosion. During subduction erosion, rock material is scraped off sedimentary-tectonic from the bottom of the upper plate and transported mélange sedimentary mélange downward with the subducting plate. Such basal erosion of the upper plate is known from the Mari- anas, the Tonga Islands, Costa Rica and Chile. In these cases, an accretionary wedge has not evolved. It is assumed that many modern convergent plate

outer boundaries have accretion at the tip of the upper slope ridge forearc plate and erosion farther down the subduction sediments basin zone. Subduction erosion transfers a considerable

slope basin amount of sediment from the surface to greater depths. In places where subduction erosion occurs, oceanic crust the outer ridge is not a signifi cant feature because

tectonic mélange sedimentary material does not accumulate in an accretionary wedge. Th e forearc basin commonly grades directly into the trench with little or no topographic rise between the two. Subduction erosion is particularly eff ective when the lower plate has a roughly textured surface and is only covered by a thin sedimentary layer (Fig. 7.14). As the lower plate enters the subduction zone and tectonic mélange e.g., e.g., is bent, the upper part of the plate is extended; a fragments fragments fragments series of trench-parallel horst and graben structures of sand- (basalt, serpentinite) of radiol- stone arite are subsequently formed. Th e roughness caused by these structures acts like a grater on the basal part of the upper plate (basal erosion, Fig. 7.14), much like a cheese grater removes cheese from the base basalt of the cheese block. Material that is scraped off the upper plate enters the subduction zone where it is transported downward into deeper parts of the sub-

10 cm duction zone. Th is process is currently happening in the Mariana Arc. on the subducting sedimentary-tectonic mélange from plate create a somewhat diff erent kind of subduc- clayey, sheared matrix the ophiolite of Osa, Costa Rica ~ 1 m to 1 km tion erosion. Single seamounts scrape material from the frontal tip of the accretionary wedge along the Fig. 7.11 Formation of mélange in an accretionary wedge and subduction zone upper plate and carry it into the subduction zone (Cowan, 1985). Inserts show variations across diff erent portions of the mélange. The outcrop photo shows a typical mélange structure. Mélange is characterized by a block- (frontal erosion). A superb example of this setting in-matrix structure. Mud-volcanoes develop by explosive dewatering of sediments occurs off the Pacifi c coast of Costa Rica where under high pressure. seamounts currently buried by the tip of the upper

Licensed to jason patton Subduction erosion instead of accretion 1017

Mud volcanoes Fig. 7.12 Mud-volcano at the foot of the Apen- nine at Maranello, south of Modena, (photo kindly provided by Achim Kopf, Uni- Mud volcanoes are widespread features versity of Bremen, Germany). The steep tip of the that occur on the top of accretionary cone is approximately 1 m high. wedges. They are volcano-like features which are not fed by molten rocks but or 360 km/h (Kopf, 2003). Gas-charged rather by mud rich in water and clay. eruptions of mud volcanoes produce an The mud originates at the shallow plate explosion. Mud volcanoes without gas boundary and forces its way through the produce cones that rapidly form hard margin wedge (Fig. 7.11). Water originates slopes with angles steeper than 5°. Erup- from porous sediment along the decolle- tions with gas as a component form fl at, ment zone between the upper and lower dough-like structures that can reach plate where it becomes overpressured diameters of tens of kilometers. because of lateral pressure in the sub- In the Mediterranean region, the Afri- duction zone. Additionally, the pore fl uid can Plate subducts south of Crete beneath pressure increases due to additional water the . Adjacent to Crete, mud contained in opal that is released from volcano fi elds occur on the sea fl oor with siliceous organisms, and in clay minerals (primarily smectite). some cones more than 500 m high and 40 km wide. They occur Methane and other volatile hydrocarbons are generated from as much as 150 km away from the plate boundary. The dewa- decomposing organic material and add to the increase in pore tering of minerals, a chemical conversion of water-containing fl uid pressure (Kopf, 2003). Overpressure occurs when the (hydrated) minerals into water-free minerals, plays an impor- internal pressure of a rock exceeds that of the surrounding tant role. The water, which originally occurred as pore fl uids confi ning pressure, a value determined by the weight of the and in hydrated minerals, is forced out of the highly strained overlying rocks. Overpressure generates cracks that are used subduction zone upward through the accretionary . by low-density, water-rich masses of mud to rise in a . If Mud volcanoes can also occur in collision zones following the mud extrudes at the surface it may form fountains and the subduction that led to . The principle mud-volcanoes either on subaerial or submarine surfaces. of evolution is the same as discussed above. Mud volcanoes The rise of a mud diapir happens quickly. For example, salt in collision zones are known from the Caucasus, Trinidad and and mantle diapirs have rising velocities of millimeters Pakistan, and locally in the (Fig. 7.12) and to centimeters per year whereas mud diapirs that lack gas, . Eruptions of these mud volcanoes occur in intervals have velocities of about 2 mm/s or more than 60 km/yr. At of years to decades. these velocities, they can cut through an entire accretionary A special situation is present in the forearc area of the wedge of several kilometers thickness within a couple of Marianas in the western Pacifi c where serpentinite mud- weeks. If methane gas is present, velocities can reach 100 m/s diapirs occur. These mud-volcanoes are up to 2000 m high and 30 km wide and contain abundant fragments of serpentinite (mantle transformed into serpentinite by water absorption), gabbro,

Asia North America and basalt. The imbedded rock fragments are probably scraped off from the upper oceanic plate by the rising mud masses that are gener- ated in the decollement zone between the two plates. However, , i. e., high-pressure Pacific metamorphosed basalt rock fragments are Plate East South also present among the components; such Pacific America rocks can only be derived from the subducting Rise Nazca plate after it is buried to a depth of more than Plate Australia 15 km. Serpentinite mud-volcanoes are only known from the intra-oceanic subduction zone Indo- Australian Plate of the Marianas; this suggests that they only form where oceanic litho sphere is present in the outer part of the upper plate. Plate Antarctic Fig. 7.13 Map of Circum-Pacifi c showing location of subduction zones with and without accretionary wedges convergent plate margins: with accretionary wedge without accretionary wedge (von Huene and Scholl, 1991).

Licensed to jason patton 7102 Subduction zones, island arcs and active continental margins and where the subduction angle is high and subduc- Fig. 7.14 Subduction tion roll-back occurs (Mariana type). Examples for erosion upper: at the base upper plate the fi rst case include Central America (see below) of the upper plate caused and parts of South America, and for the second case by subducted horsts and oc eanic cru grabens; lower: at the st basal the Marianas, Tonga, and NE Japan. In Chile-type erosion front of the upper plate subduction, subduction erosion occurs because of caused by subducted the strong contact pressure caused by strong plate seamounts. coupling. In Mariana-type subduction, erosion is caused by the rough, saw-tooth-like morphology on the subducting plate.

seamounts Pore fluids have important consequences in upper plate subduction zones and on subduction erosion. Recall from above that pore fl uids originate both from de- oc frontal eanic cru st erosion watering of hydrous minerals and from expulsion of water from sediments. Pore fl uids in the high-stress zone along the plate boundary decollement actually increase mobility and slippage in this zone by acting as a lubricant. During explosive expulsions of fl uids, framework grains break and loose their connective- plate leave obvious bulges followed by indenta- ness, and the rocks become ground by shearing. tions in the slope of the upper plate. Subsequently, Such rocks are called cataclasites. Cataclasis (Greek sediment gravity slides may fi ll up or obscure these strong fracturing) is a common process associated indentations (Fig. 7.14 lower, Fig. 7.15). with subduction erosion. Fluids that escape upwards Basal erosion on the upper plate causes the plate through the upper plate may generate mud volca- boundary to migrate towards the arc, which itself noes (see box; Fig. 7.11). Fig. 7.15 Subduction is moving backward in response to the migrating Subduction erosion can be proven only indirectly of seamounts at the plate subduction zone. Th is process occurred along Costa as the process occurs at depth and the eroded rocks margin off Costa Rica Rica and in parts of the Andes between the Miocene become subducted to even greater depth. In contrast, (von Huene et al., 2000). and present (Fig. 7.16). A tectonic mélange, con- accretionary wedges can be directly studied. An ac- The indentation of the into the sub- sisting of parts of the scraped off upper plate, has tive plate margin that may be the site of subduction duction zone leaves deep evolved along the decollement zone. Th e mélange is erosion is the Central American subduction zone furrows in the upper plate transported into the depths of the subduction zone adjacent to Costa Rica. Here, the is (fi gure after bathymetric along with the plate being subducted. being subducted beneath the Plate with data of the research vessel Sonne, made by Wilhelm Subduction erosion can occur both where the a velocity of about 9 cm/yr. Th e volcanic front has Weinrebe, IfM-Geomar subduction zone angle is relatively low and there is a shift ed 40 km backwards (towards the Caribbean) Kiel, Germany). strong coupling between the two plates ( Chile type) during the last 15 million years. Th is shift probably corresponds to the amount of shortening formed by subduction erosion (Fig. 7.16).

traces of As subduction erosion thins the upper plate, subducting the outer part subsides. Sediments deposited in seamounts the forearc area can be used to document this subsidence. For instance, benthic foraminifera, single-celled organisms which live within the sediment, indicate the approximate sedimentation depth based on their shell shape and design. If fora minifera and other sedimentological features in layers of decreasing age at a convergent margin indicate increasing water depth, subduction ero- sion is a likely explanation. At a drill site of the Ocean Drilling Program off Costa Rica, shal- [m] Quepos low water sediments occur at the deepest part of Plateau -2000 a hole whereas near the top of the well core, deep seamounts 8 cm/yr -4000 water sediments occur (Meschede et al., 2002). Ac- cretionary sequences produce the opposite pattern because the gradual buildup of the accretionary wedge causes a shallowing-upward sedimentation

Cocos Plate

Licensed to jason patton Earthquakes and Benioff zones 1037 pattern over the wedge. Th is pattern is present at the Mentawai Ridge in the Sunda Arc (see box SW zone of subduction erosion NE and mélange formation above). Miocene (15 Ma) active volcanic arc The forearc basin extensional structures coastline Forearc basins are zones of crustal subsidence that plate boundary lie between the outer ridge and the mountain range of the volcanic arc. Th ey are generally dominated by great thicknesses of and sedi- mentary rock that form in depths that range from abyssal to shallow. Present examples of foreaerc basins include the Sandino Basin of off shore Nica- subduction mélange ragua and the basin that lies between the Mentawai eroded until present Ridge and Sumatra. Th e former contains deposits by subduction erosion approximately 10 km thick and the latter consists of sediment 4–5 km thick that displays a general shallowing-upward sequence (Fig. 7.9). Although ~ 40 km ~ 40 km backward shift backward shift the deposits in the Sumatra example are domi- of plate boundary of volcanic arc nated by sediment derived from the adjacent arc, Present they also contain appreciable amounts of marine subsidence present coastline biogenic carbonate, especially within the younger, plate boundary shallower deposits. Forearc basins are underlain by either thinned continental or normal oceanic crust. Th e distri- oceanic crust bution of the two is related to the origin of the Miocene subduction zone. Typically new subduction zones coast line evolve at the juncture between continental and lithospheric oceanic crust, along a passive continental margin, mantle because this zone is generally structurally weak. Continental margins typically show irregular asthenosphere shapes with alternating salients and embayments; subduction zones tend to form smooth, arcuate plate boundaries. Th erefore, the margin of the up- per plate along the new plate boundary is likely to for 95 % of all earthquakes on Earth and are re- Fig. 7.16 Subduction contain embayments of oceanic crust (Fig. 7.17). ferred to as Benioff zones aft er the geophysicist, erosion at the plate mar- Hence, the type of crust in the forearc region may Hugo Benioff , who recognized and systematically gin of Costa Rica where the Cocos Plate subducts be continental, oceanic, or both in a given section. investigated such zones in the Pacifi c Ocean and beneath the Caribbean Such oceanic entrapments are called remnant or below the Sunda Arc (Benioff , 1954), or Wadati- Plate (Meschede et al., residual ocean basins. Benioff zones (in 1935 Kiyoo Wadati documented 1999). Backward shift Forearc basins on oceanic crust may feature earthquake epicenters along a down plunging (towards the backarc) of great water depth. Th e oceanic crust merges into the volcanic arc is caused by subduction erosion of thinned continental crust towards the volcanic arc. the upper plate since the If an accretionary wedge and an outer ridge develop continental crust Miocene. vo lcan at the convergent margin, the basin will be topo- ic chain cross graphically constricted and fi ll rapidly with sedi- section ment (see box). During collision, ophiolites from uction the basement of forearc basins may be accreted oceanic crust subd onto the adjacent continental crust. As opposed to continental oceanic crust subducted ophiolites from the lower plate, they do crust not experience high-pressure metamorphism un- pelagic sediments less they are scraped off and dragged down. Fig. 7.17 Development oce of a residual forearc basin Earthquakes and Benioff zones anic c rust caused by the formation Subduction zones are easy to detect because they of a subduction zone at form long, linear belts with intense earthquake ac- accretionary wedge residual basin volcanic arc an irregular continental tivity. Th ese seismically active zones are responsible margin.

Licensed to jason patton 7104 Subduction zones, island arcs and active continental margins

The Shigatse Flysch in Tibet hinterland uplift caused by episodes of enhanced magmatic activity led to coarsening-upwards trends. Tectonic quiescence A well exposed, extraordinary example of a fossil forearc or decreased rates of basin subsidence lowered the relief and basin is the Shigatse Basin in Tibet, which prior to the colli- led to fi ner-grained deposits and fi ning-upwards cycles. sion of India and Central , was fi lled with fl ysch (Einsele In areas where large rivers entered the flysch basin, et al., 1994). Flysch (Swiss-German to fl ow, derived from the coarse-grained gravels extend far into it. Conglomerate lay- tendency of weathered sandy-clayey layers to fl ow downhill) ers are concentrated throughout given measured sections sequences comprise thick units of turbidite deposits that suggesting that river courses remained constant through typically evolve pre- to synorogenically in subduction zones. time. Rivers transported abundant volcanic material that Turbidites are frequently deposited in deep sea trenches was derived from the active arc as well as plutonic detritus and subsequently scraped-off and deformed in accretionary derived from more deeply dissected parts of the arc. Addi- wedges. Turbidites are also common in deep-water forearc tional non-arc-derived material was supplied by the distant basins fl anked by steep submarine slopes along the volcanic hinterland, the present of the Tibetan Plateau, arc, especially if water-saturated sediments are periodically indicating that some rivers headed north of the arc and shed of the arc over long spans of time. Proximal turbidity subsequently dissected through it in their journey to the currents and distal suspension currents carry sediment far forearc fl ysch basin. into the basin; the periodic events are triggered by earth- The southern, more distal portions of the basin are charac- quakes, a common phenomenon in forearc basins such as terized by fi ner-grained and thinner deposits. Farther seaward, the Shigatse Basin. sediments were scraped off the subducting plate along the From the mid- to Early Tertiary, oceanic crust plate boundary and contributed to an accretionary wedge. of the rapidly northward-drifting was subducted Although the edge of the upper plate was bent to form an beneath the Tibetan Block. The Gangdese Belt, which today outer ridge, it remained below the sea level (Fig. 7.18). forms mountains 7000 m high in the Transhimalaya, evolved Collision of the Indian continent with Central Asia occurred over the subduction zone as a volcanic arc. In the forearc in the Early Tertiary ca. 55 Ma. During the collision, the charac- area, the Shigatse Basin developed as a residual ocean ba- ter of the Shigatse forearc basin was completely transformed sin (Fig. 7.17); it transitioned into thinned continental crust as it was underplated by the Indian continent that was par- towards the Gangdese Belt (Fig. 7.18). tially subducted below Central Asia (Fig. 7.18). The new basin Along the northern edge of the became entirely emergent above basin, sedimentation commenced S N the sea level. It was surrounded Gangdese with shallow-water carbonate Late Cretaceous by complex tectonic elements in- deposits in coastal areas, whereas accretionary outer older sediments cluding the now inactive volcanic wedge ridge farther south, the sedimentary flysch sequence chain to the north and the stacked rocks refl ect deep-water environ- of the Himalayan thrust o cea ments. The increased sedimentary nic belt to the south. As sedimenta- cru oceanic st load generated rapid subsidence crust tion continued, the basin evolved continental and thick fl ysch sediments, derived crust into a non-marine molasse basin from the north, that steadily fi lled or successor basin. Rivers supplied the basin (Fig. 7.18). The turbid- coarse-grained gravels and Early Tertiary ite rocks are mostly arc-derived erosion Shigatse Flysch and fi ne red muds were deposited volcanic-rich clastics that were de- Qiuwu Molasse in lakes. These deposits comprise posited in water depths between the Qiuwu Molasse. The shorten- shelf 1000 and 3000 m during several sediments ing during and after the collision cycles of sedimentation. Each cycle reduced the Shigatse Basin to one

reflects early rapid subsidence continental crust third of its original width of 70 km accompanied by deep-water de- of the Indian Plate or more. The collision between the position followed by shallowing- plates is marked by the Yarlung-

upwards deposits that mark basin Yarlung-Tsangpo Qiuwu Present mélange suture zone Molasse filling. Smaller-scale cycles are (ophiolites) defined by individual fining- or accretionary Yarlung Fig. 7.18 Development of the Shi- wedge coarsening-up sequences within Shigatse Flysch River gatse Flysch in Tibet. Subduction of the the larger cycles. They reflect Indian Plate beneath the Eurasian Plate nappe stack created a forearc basin that evolved as (Himalayas) the complex subduction-related a residual basin partly on oceanic crust. dynamics of the basin. Increased Subsequent continental collision has basin subsidence rates and/or deformed the basin as shown.

Licensed to jason patton Earthquakes and Benioff zones 1057

Tsangpo suture line, which farther west is called the Indus Kailash Molasse further to the west that is named after the suture line; Yarlung Tsangpo derives its name from the upper 6700 m-high holy mountain of the buddhists and hindus. course of the Brahmaputra river in Tibet. Continued tectonic shortening folded both the Shigatse Foredeep basins in the foreland adjacent to an emerging Flysch and the Qiuwu Molasse. Presently, the eroded layers mountain range following continental collision are called of folded mudstone, sandstone, and conglomerate form an foreland, molasse, or successor basins (see Ch. 11). Molasse attractive along a 20 km-wide strike valley with deposits consist of thick, shallow water, marine to non-marine, characteristic low, parallel ridges. The rocks are exceptionally sedimentary deposits of sandstone, conglomerate, and mud- well exposed because of the dry conditions in the Tibetan stone that typically form syn- to post-orogenically in foreland/ highlands; the mountainous area ranges from 4200 to 5000 m foredeep basins. The term molasse apparently is derived from in height. In more humid , mud-dominated, thin- the use of harder as millstones (Latin mola). The bedded fl ysch sequences tend to be mostly concealed by soils Qiuwu Molasse of the Shigatse Basin is equivalent to the and vegetation. surface below Japan). Th e earthquakes associated In contrast, shallow earthquakes along the sub- with Benioff zones reach a maximum depth of duction zone are generated by horizontal compres- almost 700 km (Fig. 7.19). sion and the friction between the two converging Subduction zones are characterized by earth- plates. Th ey are released directly along the plate quakes with three diff erent depth ranges: (1) shal- boundary or along accompanying fractures parallel low earthquakes, earthquakes with epicenters from to the down-plunging plate boundary (Fig. 7.20). near the surface to depths of 70–100 km, the nor- They can reach a depth corresponding to the mal thickness of the litho sphere; (2) intermediate thickness of the upper-plate lithosphere, typically earthquakes with depths between 70 and 400 km; 70–100 km, although there is a clear decrease in fre- and (3) deep earthquakes with depths between quency below 50 km. Th e largest earthquakes, like 350 and 700 km (Figs. 1.8, 7.20). Th is pattern of of the ones that struck Japan in 1923, Kamchatka in earthquake depth occurs only in subduction zones; 1952, Chile in 1960, Alaska in 1964, and Sumatra in in fact earthquakes with epicenters deeper than 2004, originate within this zone. Th ese earthquakes Fig. 7.19 Distribution of earthquake epicen- 100 km are not known outside of subduction zones all (except Japan) had moment magnitudes between ters in various modern because hot asthenospheric mantle fl ows plastically 9.0 and 9.5 and they represent the strongest ever subduction zones. Such when subjected to stress. In most regions outside registered. In each of these cases, the downgoing features are known as of subduction zones, earthquakes with epicenters plates subduct with relatively high velocities and at Benioff zones. These zones penetrate to the boundary deeper than 20 km are rare because at this depth, a shallow angle beneath the overlying continental between upper and lower continental crust behaves ductilely with stress. crust. Th ese large, shallow earthquakes are respon- mantle to approximately Subduction zones suff er such deep earthquakes be- sible for approximately 90 % of the total earthquake 660 km depth. cause cool, rigid oceanic lithosphere is transported to great depths relatively rapidly. Th ese conditions Marianas Java Kuril infl uence these rocks and allow large stresses to 0 accumulate that are spontaneously released into earthquake energy. Stresses also develop due to 200 mineral phase transitions accompanied by changes of mineral properties in the subducting plate. Th is mechanism is hypothesized to be responsible for 400 deep earthquakes. Fault-plane-solutions of earthquakes (Fig. 2.14) 600 are indicative of their origin. Th e bending zone km 660 km of the subducting plate is characterized by low- Tonga (North) Tonga (South) Japan 0 magnitude earthquakes caused by horizontal tensional stress in accordance with the formation of graben structures (Figs. 7.14, 7.20). Epicenters 200 of these earthquakes can be up to 25 km deep. Th e accompanying fractures allow sea water to pen- 400 etrate deep into the litho spheric mantle and cause it to change partly to serpentinite. Th e serpentinite 600 may rise to the surface in serpentinite diapirs as km 660 km discussed previously.

Licensed to jason patton 7106 Subduction zones, island arcs and active continental margins

compressional Fig. 7.20 Cross section through a subduction zone extensional earthquakes showing the diff erent types of earthquake mechanisms earthquakes (Green, 1994). The uppermost area is dominated by shal- low earthquakes caused by horizontal compression along thrust planes. Serpentine dewatering causes intermedi- ate earthquakes to depths of 400 km. Deep earthquakes are probably created by the mineral from to spinel and occur in depths between 350 and 700 km.

100 km lithospheric mantle oceanic crust asthenosphere above 6000 m deep ocean fl oor) waves. However,

intermediate their behavior in shallow water and along coastlines earthquakes is drastically diff erent and extremely dangerous. Here, their velocity of propagation is dramatically olivine reduced in the shallow water because of increased friction caused by contact of the wave with the sea fl oor. Concurrently, the wave length drastically 400 km

shortens and the wave amplitude increases until it may rear up to more than 30 m high along the coast. Th is wall of water rushes across low landscapes creating widespread havoc. Earthquakes that occur at greater depths are spinel deep consequences of internal stress within the subduct- earthquakes 660 km ing plate. Th e zone of intermediate earthquakes is generally separated from the zone of deep earth- quakes by a gap of low seismic activity. Intermedi- ate earthquakes are mostly tensional whereas deep perovskite + magnesio-wuestite earthquakes are compressional, relative to the direction of the plate movement (Fig. 7.21a,b). Th is condition results from the medium into which the subducting plate sinks. Outside of the subduction zone, the Earth’s mantle has its lowest density and energy worldwide. The periodic occurrence of viscosity in the asthenosphere, the zone between the large earthquakes in intervals of several decades base of the litho sphere down to 250–300 km. Cooled to centuries demonstrates that the movement in and dense litho sphere of the subducting plate will the zone of friction between the two plates occurs sink down into the asthenosphere relatively rap- in an irregular way. idly, without substantial resistance, because of its Shallow earthquakes in subduction zones can higher density. Th is leads to downward-directed cause two types of devastation, (1) destruction tensional stress within the plate and -caused directly from the physical shaking and vibration earthquakes (Fig. 7.20). Th e higher density of the and (2) the generation of (Japanese subducting plate relative to its surrounding material harbor wave). Th e subduction-generated massive has been described above as an essential factor in earthquake of the 26th December 2004, adjacent the driving force of plate motion. to the northern tip of Sumatra demonstrated At approximately 400 km in depth, the surround- this to the entire world. Th e subduction of the ing mantle material becomes denser because of a Indo-Australian Plate beneath the Eurasian Plate pressure-caused mineral phase transition; this leads moves with a velocity of 7 cm/yr at this location. to a higher resistance towards the subducting plate. Relative displacement of blocks at the focus of the Th erefore, compressive stresses develop parallel to earthquake at a depth of 20 km was approximately the direction of downward movement (Figs. 7.20, 20–30 m. Th is instantaneous physical movement is 7.21b). At a depth of approximately 660 km, the equal to the amount of movement that would occur boundary with the lower mantle, another mineral during an average subduction creep over an interval phase transition occurs in the mantle and strength- of 300–400 years. ens it. Subsequently the subducting plate as a whole Tsunamis are diffi cult to detect in the deep, open becomes less dense than the lower mantle. Ad- ocean where they form long (more than 500 km), ditional compressive stress within the subducting low (ca. 1 m), rapidly moving (more than 800 km/h plate is generated by the resistance of the stronger

Licensed to jason patton The secret of deep earthquakes 1077 and denser lower mantle and is transferred upwards a bcd to shallower depths (Fig. 7.21c). If slab-breakoff 0 occurred, such stress transfer is impossible and 100 the subduction zone throughout the asthenosphere astheno- sphere remains in a state of tensional stress (Fig. 7.21d). 400 The secret of deep earthquakes

All rock material at depth incurs a lithostatic pres- resistance increasing sure (the equivalent to the hydrostatic pressure 660 [km] lower mantle in water) that is determined by the weight of the overlying pile of rock. Tectonic movements add an in direction of subduction: extension compression additional, directed pressure that leads to an overall deviatoric stress where the pressure on a single particle of rock is greater in one direction than sphere and reaches a minimum at 300–400 km Fig. 7.21 Intermediate in all other directions. Earthquakes are the result depth. Deep earthquakes are most common across and deep earthquakes of directed tectonic pressure. If a certain limiting a depth range of 550–600 km (Fig. 7.23). indicate extension or compression in direction value, which depends on the strength properties Th e zone in which deep earthquakes occur cor- of the downward plate of the rocks is exceeded, the rocks react with shear responds to the stability range of spinel within the movement (Isacks and fracturing where frictional gliding occurs between subducting plate. Outside of the subduction zone, Molnar, 1969). This results the two separated blocks. In cases of large earth- olivine, the main component of the mantle rock from the resistance of the quakes, the movement between the blocks in the peridotite, compacts at a depth of 400 km and upper mantle into which the plate plunges. If the area of the focus may be greater than 10 m. changes into the more densely packed mineral plate reaches the bound- Shear fractures in a rock have been investigated structure of spinel with the same mineral formula ary of the lower mantle, compressive stress can experimentally. When subjected to compression, as olivine (Mg2SiO4). Th e structure of spinel is numerous microcracks, thin, short hairline stable to a depth of about 660 km; below this be traced upwards into the upper parts of the fractures, develop that are oriented parallel to boundary it again changes into a denser-structured subducting plate the direction of maximum compressional stress; mineral, perovskite (MgSiO3) plus magnesio- there is little extension of the rock parallel to the wuestite (MgO). Within the subducting plate, the direction of minimum compressional stress. Th e stability range for spinel exists between 350 and result is a decrease in the strength of the rock. If 700 km, the depth at which deep earthquakes oc- tectonic stress continues in the same direction, cur. Consequently, it seems likely that the mineral failure occurs and shear planes oblique to the main phase transition of olivine to spinel is responsible direction of pressure develop that join the existing for the deep earthquakes. microfractures (Fig. 7.22a). However, at greater depths, where lithostatic pressure is increased, such displacements along a) compression fractures would not be possible because rocks under these conditions react plastically by ductile deformation when subjected to tectonic stress. Moreover, the high lithostatic pressure does not allow the formation of microfractures because they are coupled with extension. Nonetheless, 20 % of earthquakes in subduction zones occur at interme- diate depths and approximately 8 % occur as deep μm μm μm earthquakes. Within the subducting plate, they formation of microcracks weakening of rock continuous fault plane are concentrated along a belt in the internal part b) compression of the plate (Fig. 7.20). Frequency of earthquakes decreases from a maximum in the upper litho-

Fig. 7.22 a) Microcracks form in response to tectonic pressures that weaken the rock; shear fractures follow. b) Below a depth of approximately 350 km, so-called olivine spinel anticracks form in the subducting plate due to mineral lens μ μ μ phase transition from olivine to spinel. Connected spinel m m m lenses create continuous bands of weak material that formation of anticracksformation of weak zone continuous favor abrupt movement (Green, 1994).

Licensed to jason patton 7108 Subduction zones, island arcs and active continental margins Fig. 7.23 Frequency of of serpentine and thus belongs to the category of number of earthquakes per year earthquakes in a subduc- depth intermediate earthquakes. tion zone (Green, 1994). 1 10 100 0 Between the depths of 350 and 700 km, a Deep earthquakes are shallow [km] diff erentiated through earthquakes completely diff erent mechanism for earthquake their diff erent mechanism 100 generation must operate that overlaps with the of formation. intermediate zone of intermediate earthquakes between 350 and earthquakes 400 km. Once again, a mineral phase transition is shear fracture 200 thought to be a critical in explaining the processes serpentine

dehydration of dehydration involved. Th e mineral phase transition from oliv- 300 ine to spinel occurs according to the temperature structure of the downgoing plate and is distributed 400 over the whole range of depths within the plate (Fig. 7.20). At these depths, the remaining olivine is “metastable”. Initially, small lenses of spinel form 500 anticrack shear within the peridotite of the subducting plate; they deep are aligned vertical to the maximum compressional anticracks earthquakes formation of formation 600 stress (Fig. 7.22b). Because spinel has a denser min- eral structure than olivine and thus needs less space,

700 this change corresponds to a reduction of volume. Th e spinel lenses can be interpreted as “anticracks” because they are rotated 90° compared with normal Intermediate and deep earthquakes also are microcracks. If enough anticracks are formed, the released by spontaneous displacements within rock becomes weakened. Finally the anticracks are rocks; however, the mechanisms diff er from those joined and an instantaneous shear movement of of shallow earthquakes (Green, 1994). Intermediate the rock develops. However, the shear movement earthquakes are related to dewatering processes does not occur at a fracture plane where blocks of with increasing depth of the mineral serpentine. rocks break off , but rather through a process called Serpentine is a magnesium silicate mineral with a superplasticity. high water-content (Mg6[Si4O10(OH)8]; the water- Superplasticity occurs at high temperatures and content is 13 weight-%). Serpentine develops from is favored where rock-forming minerals are very olivine and precursors and frequently oc- fi ne grained. Th e mineral grains slip past each curs in of the litho spheric mantle below other along their boundaries. Although this may the oceanic crust as well as in serpentinite bodies seem to be an apparently trivial process, it leads to within the oceanic crust. With increasing tem- fast plastic deformation and is apparently unique perature and increasing pressure, the crystal lattice to the conditions outlined above. Th e amalgam- becomes instable and releases the bound water; this ated spinel lenses are extremely fi ne-grained and enables the re-formation of olivine and pyroxene. with appropriately oriented tectonic stress, result Th e spontaneous dewatering, which is accompa- in rapid grain reorientations along narrow shear nied by a substantial decrease of volume, causes zones in the rocks. And this process may generate microfracturing and weakens the rock, eventually earthquakes. Th e characteristic of such “anticrack leading to the formation of shear fractures; they can earthquakes” is not discernible from normal frac- occur, despite the high lithostatic pressure, if the ture earthquakes because in both cases, blocks of rock is under directed stress. Because the amount rocks are displaced against each other. Th e ther- of serpentine decreases with depth, the number of mal structure of the subducting plate, with a cold intermediate earthquakes also decreases; this trend downward plunging fi nger in its interior, indicates continues to a maximum depth of 400 km where that mineral phase transitions from olivine to serpentine is no longer available (Fig. 7.23). spinel gradually occur between 350 and 700 km Two seismically active belts, mostly in the (Fig. 7.20). Th e maximum earthquake occurrence, subduction zones of the western Pacific, were at depths of 550–600 km (Fig. 7.23), is related to discovered at depths near 100 km. One belt is at frequent phase transitions within in this zone. the surface of the subducting plate, and the other The above-mentioned mechanisms for inter- 20–40 km deeper, within the plate. Th e upper belt mediate and deep earthquakes give a satisfactory of earthquakes is caused by shear movements along explanation for earthquakes in subduction zones. the plate boundary and thus belongs in the cat- However, the theory of deep earthquakes also raises egory of shallow earthquakes. However, the lower contradiction because the metastability of olivine belt is considered to be related to the dewatering and its gradual change over a large depth range is

Licensed to jason patton High-pressure or subduction metamorphism 1097 controversial. A contrasting explanation for deep 0 100 200 300 400 500 600 700 T [°C] earthquakes suggests that thermal instabilitiy 0 0 within the plate may lead to high stress that spon- diagenesis contact metamorphism taneously produces fi lms of melted rocks at fault 0.2 planes (Wiens, 2001). facies 10 ) Abukuma-type s facies i x e t 0.4 amphibolite facies a High-pressure or subduction n a granulite facies (

e

t metamorphism i

n

a 20

r

Rocks in subduction zones are metamorphosed g 0.6

f

blueschist facies metamorphism in magmatic belts above subduction zones belts above

o

under conditions of high pressure at relatively low Barrow-type g n

i

t

l temperature, hence the terms high-pressure (prop- e 0.8

m erly high-pressure/low-temperature) metamor- 30 phism or subduction metamorphism; Fig. 7.24). Such metamorphism results because cool rock 1.0 high-pressure metamorphism material is rapdly subducted to great depths. Nor- metamorphism regional 40 mally, at a depth of 50 km that corresponds to a 1.2 pressure of 1.5 gigapascal (1 GPa = 10 kilobar), the

c metamorphism in collision zones in collision temperature is approximately 800–900 °C. In con- o 1.4 n trast, oceanic crust that reaches the same depth in change 50 1.5 in y-axis d i a subduction zone reaches temperatures between t i facies 200 to more than 500 °C. Th e lower value is valid o 60 2.0 n s for old, cool, rapidly subducting litho sphere and the n 70 higher value is for young, and warm, more slowly o t subducting litho sphere; the NE and SW margins 2.5 r e 80 of Japan, respectively provide examples of each a l ultrahigh-pressure (Stern, 2002). i 3.0 z metamorphism 90 fractures e Th e contrast in temperature within and outside d of subduction zones becomes even more notice- garnet 100 able at depth. Th is is indicated by the patterns of 3.5 isotherms (lines of equal temperature) within sub- 110 subduction zones ducting plates. Th e isotherms are strongly declined 4.0 metamorphism in 120 downward and under the upper plate because rocks are poor heat conductors and they need millions of 130 years to adjust to the higher temperatures normally pressure [gigapascal] depth [km] seen at depth (Fig. 7.25). However, the pressure within the subducted plate increases immediately, Fig. 7.24 Pressure-temperature (PT) diagram showing diff erent types of metamor- without delay, based on the given depth because it phism and . High-pressure metamorphism is typical for subduc- is dependent on the burden of the overlying rock tion zones and Barrovian-type regional metamorphism typifi es continent-continent collisions. Abukuma-type regional metamorphism and contact metamorphism occur pile. Th erefore, the rocks and minerals within the in the magmatic belts above subduction zones. Diagenesis occurs in the realm of rock subducted plate experience the extreme conditions consolidation and is considered a non-metamorphic process. The insert shows a coësite of subduction metamorphism – rapid deep burial crystal, formed at the conditions of ultrahigh-pressure metamorphism, enclosed in causes high pressure with relatively low tempera- a garnet. Because of pressure reduction during the uplift of the rock, the coësite was tures (Fig. 7.24). Rocks that have been buried more partly changed into quartz. This caused a volume increase in the quartz and produced the cracks in the garnet crystal. than 100 km within subduction zones and subse- quently exhumed during orogenic processes can be observed directly on outcrop. 35 km burial depth) and its stability fi eld is open Metamorphic conditions in a subduction zone towards higher pressure and temperature. Eclogite transform basalts, dolerites and gabbros of the is mainly composed of (Na-Al pyroxene) oceanic crust into glaucophane-schists (blue- and pyrope-rich garnet (Mg-Al garnet). schists) and (Fig. 7.24). Glaucophane is a (Na-Ca feldspar), one of the major components of blue-violet Na- that forms at a pressure oceanic crust, is no longer stable under these condi- of about 0.6 GPa (corresponding to about 20 km tions. Denser mineral phases generally form under burial depth). It remains stable over a large pressure high pressure and thus high-pressure metamorphic range as long as the temperature remains below rocks have higher specifi c weights (eclogite: about 500 °C. Eclogite, on the other hand, forms at a 3.5 g/cm3) compared to their non-metamorphic pressure of about 1 GPa (corresponding to about equivalents (about 3.0 g/cm3).

Licensed to jason patton 7110 Subduction zones, island arcs and active continental margins

volcanic arc In addition to basalt, dolerite and gabbro, sedi- depth backarc basin mentary rocks and splinters of continental crust [km] ocean deep sea trench continent carried with the subducted material experience 0 200 200 400 600 400 high-pressure metamorphism. However, the 600 800 mineral composition in these rocks is not easy to 800 identify as having formed under high-pressure

1000 1000 conditions. Many groups of minerals (garnets, 200 1200 , micas, chloritoids, etc.) have special subducting members formed under high-pressure conditions plate 1400 which are chemically diff erent from their relatives 1400 formed under diff erent pressure-temperature con- 800 ditions. Only a detailed microchemical analysis of 400 1600 the minerals using an electron-microprobe can 1000 detect whether they were formed under high- pressure or normal conditions of metamorphism. Under conditions of high-pressure metamorphism, 1200 600 iron-magnesium silicates mostly have compositions similar to those of the Mg end-members because the small ion radius of magnesium supports denser

200 0 200 400 600 800 packing of atoms. distance from trench [km] Sediments contribute signifi cantly to the de- watering in a subduction zone although following depth deep sea trench volcanic arc [km] continental high-pressure metamorphism they continue to in- magmatic gap oceanic crust crust clude water-containing minerals such as phengite (a 0 type of mica), karpholite, chloritoid and . 300 Water released in the subduction zone causes in- 20 Abukuma-type 300 metamorphism tense changes in the mantle above and, from a cer-

40 600 tain depth, melting processes which are responsible 600 for magmatism above a subduction zone. 60 lithospheric It is diffi cult to explain how rocks that have mantle been metamorphosed at great depths in subduc- 80 incipient tion zones are exhumed at the surface. Such high- formation of eclogite pressure metamorphic rocks occur in mountain 100 1100 ranges in lenses or in larger bodies within ophi- 1100 120 olite sequences and their adjacent rocks. Typically they occur within long narrow zones that contain 140 asthenosphere ophiolites and mark the suture zone of collisions between two continental masses. 160 50 km Commonly, high-pressure mineral associations are only preserved as relics. Th is is because high- pressure minerals adapt to decreasing pressure Fig. 7.25 Diagrammatic Oceanic crust is dewatered during subduction. and temperature conditions that accompany slow cross sections through Basaltic rocks contain abundant water because isostatic ascent. Only rapid uplift accompanied by subduction zones. Upper: interaction with near the mid-ocean ridge relatively low temperatures or rapid cooling main- computer-modeled temperature distribution, forms water-containing minerals (zeolite, chlorite, tains high-pressure minerals in rocks. Investiga- in °C, of a subduction epidote, amphibole; Ch. 5). Under conditions of tions of textures in eclogites suggest that regions system and, lower: cross subduction metamorphism, the water-containing of extreme crustal extension above high-pressure section through an active minerals become unstable and are replaced. Water metamorphic rocks generate the conditions in continental margin show- set free by metamorphism of these minerals is which high-pressure minerals can be preserved; ing an estimation of the isograds (lines of the same partly bound in other water-containing but high- such conditions permit rocks from deep-seated temperature) (Schubert pressure resistant minerals (e. g., lawsonite, zoisite, subduction zones to rapidly reach the surface and Turcotte, 1975). glaucophane); however, the major portion is emit- (Platt, 1986). Processes associated with erosion by ted into the mantle above the subduction zone. water and ice occur much too slowly to remove the Subducting rocks are thus gradually dewatered and overlying rocks rapidly enough. that is the reason why eclogite, to a large extent, is Th e geologic setting of the Western Alps clearly a “dry” rock. illustrates this last point. Th e mineral assemblage

Licensed to jason patton High-pressure or subduction metamorphism 1117

Ultrahigh-pressure metamorphic rocks fractures around quartz inclusions document the conversion of coësite ( density 2.93 g/cm3) Eclogites and glaucophane-schists are important into quartz (2.65 g/cm3); the volume increase indicators of extinct subduction zones that are during the conversion forced the garnet to break. exhumed at the surface by orogenic processes Commonly small relics of coësite are preserved (Ch. 11). In some mountain ranges, the rocks adjacent to the quartz (Fig. 7.24, insert). were buried to a depth of more than 100 km form from carbon in organic and pressures of 3–4 GPa. Coësite and , material that was preserved in sediments that which have been detected at various locations were later subjected to high pressures. At ap- mostly as very small crystals less than 0.1 mm proximately 300 °C, organic material is trans- in diameter, are indicators of such deep burial. formed into graphite ( density ca. 2.2 g/cm3) and Metamorphism within the range of stability of subsequently, at a pressure of about 3.5 GPa coësite and diamond is also called ultrahigh- (corresponding to a depth of nearly 110 km), into pressure metamorphism (Fig. 7.24). diamond (3.5 g/cm3). Both, graphite and diamond Coësite is a high-pressure modifi cation of are composed of carbon, but the atomic structure quartz that occurs at pressures greater than 2.5 of the latter is much more compact. GPa (at 500 °C), which corresponds to a depth of Diamonds have yet to be discovered in the 80 km. Before its discovery in metamorphic rocks Dora-Maira massif. Apparently, the maximum of the Dora-Maira massif in the Italian Western pressure of 3.5 GPa, the stability field of dia- Alps (Chopin, 1984), coësite was only known mond, was not attained. Both diamond- and naturally in deposits related to meteorite impacts coësite-bearing metamorphic rocks are present such as Nördlinger Ries, Germany. The coësite of in ancient subduction zones in the Caledonian the Western Alps was preserved as an armored Mountains of , the Dabië Shan of East- relic in pure pyrope crystals up to 10 cm across. ern China, the Kokchetav massif in , The pyrope shield prevented the conversion of the Erzgebirge in Germany, and other mountain the denser coësite into the less dense quartz ranges. Because metamorphic diamonds have because it prevented the related increase of vol- diameters in the range of micrometers, they are ume. High-pressure garnets with radial tension diffi cult to detect.

with pyrope and coësite there (see box) suggests that orogenic collapse (Ch. 11). If subduction, which 100 km of rock had to have been removed above produces compression at depth, continues during the ancient subduction zone rocks. Yet regional extension in the upper plate, the subduction zone relations show that only 20–25 km of rock were transports relatively cold rock material below removed by erosion (England, 1981). What hap- the high-pressure metamorphic rocks that have pened to the other 80 km of rock? Large detachment previously been sheared off . Th is condition uplift s faults have been mapped in the Dora-Maira massif. the and prevents it from be- Th ese faults document considerable extension in ing heated. It is also thought that high-pressure the region. In fact, mapping shows that a 50 km- sequences can be pressed in reverse upwards along thick package of rock and another 10 km-thick subduction zones even during continuous subduc- package of rock are missing from the top of the tion and compression. Th is mechanism has been coësite-bearing metamorphic rocks. Th ese rocks proposed for high-pressure units in the Swiss Alps must have been removed by tectonic, not erosional (Fig. 7.26b; Schmid et al., 1996). processes. Th e missing rocks were removed by rapid Corner fl ow is another mechanism that can horizontal displacement during orogenic collapse rapidly uplift high-pressure metamorphic rocks. of the orogen (Fig. 7.26a). Such features were fi rst Rocks of the blueschist facies within the accretion- described from the North American Basin and ary wedge are forced upwards because the wedge Range Province in structures called metamorphic consists of scraped-off sediments that becomes core complexes or metamorphic domes (Ch. 3). narrower at depth. Th e subducted and metamor- Here, deeply buried rocks are rapidly brought to phosed rocks from the lower part of the wedge are the surface by tectonic processes. returned towards the surface along the frontal part Crust that is thickened by underplating during of the upper plate (Fig. 7.26c). the subduction process is gravitationally unstable, High-pressure minerals are destroyed, espe- a condition that initiates crustal extension by an cially if uplift of the rocks occurs slowly or the

Licensed to jason patton 7112 Subduction zones, island arcs and active continental margins Fig. 7.26 Conceptual a) rapid uplift of high-pressure models of rapid uplift of metamorphic rocks Rapid burial, rapid uplift high-pressure metamor- suture zone with ophiolites phic rocks by a) lateral Subduction rates calculated today mostly migration of crustal 20 wedges, b) push-up along range between 3 and 9 cm/yr indicating that a sub duc tion zone, c) cor- 40 continental crust of the lower plate rocks in subduction zones rapidly reach great ner fl ow in a subduction 60 depths. Depending on the inclination angle zone. [km] of the subduction zone (most are between 30 push-up of subducted and 60°), the depth of burial of a given mass material along b) subduction zone of rock increases 15 to 80 km per million years and reaches a depth of 100 km in 1 to 7 million years. Temperatures rise in subduction zones at 20 5-10 °C/km, compared to normal geothermal gradients in continental crust of 30 °C/km. 40 The eclogites of the Dora-Maira massif in the Western Alps were subducted to approxi- 60 mately 100 km depth during the Early Tertiary. [km] It is uncertain how long this process lasted, but c) corner flow with slow subduction rates of 2 cm/yr as is as- sumed for the Alpine orogenesis, this process Fig. 7.27 Schematic sketch of pillow near required less than 10 m. y. According to age 20 Zermatt, . The determinations on the critical minerals, exhu- mineral composition was mation from 100 km to 20 km depth was in the 40 partly adjusted to lower range of 5–8 m. y. (Gebauer et al., 1997); this pressure conditions during [km] corresponds to an average rate of uplift from the subduc- tion zone. Therefore, the 10–16 km/m. y. During the same time interval, central parts in the core of temperatures decreased from approximately the pillows, which are pro- water content increases during the uplift process 800 to 300 °C, a rate of 60–100 °C/m. y. The tected against circulating (e. g. thrusting interleaved with water-bearing high rates of exhumation occurred because fl uids, remain as eclogite, sedimentary rocks). Water may also be released by of extensional processes in the overlying rock the edges as glaucophane- schist, and the pinches the collapse of water-containing minerals. Water pile, but the rapid cooling rate is unclear. The where fl uids could corrode is an important reagent for mineral reactions. If low heat conductivity of rocks suggests that easily, as greenschist. the amount of available water is low, adaptation rapid uplift of rocks should occur without an to the changed pressure and tem- accompanying large loss of heat. perature conditions is only partial Pressure and temperature conditions are and eclogite may still be present as documented in the mineral parageneses. Para- a relict mineral assemblage. geneses are assemblages of minerals in equilib- An example of re-metamorphosed rium within a rock that formed during defi ned eclogites occurs in the area around pressure, temperature and fluid conditions. Zermatt, Switzerland (Fig. 7.27; Conditions of parageneses are well known from Bearth, 1959). Pillow lavas, former experiments and calculations on the thermody- ocean-floor remnants from the namic equilibrium. Because mineral suites are zone of Zermatt–Saas Fee, were confi ned to specifi c conditions during burial subjected to high-pressure eclogite or uplift of a rock, the pressure-temperature metamorphism, yet the pillows path (P-T path) can be reconstructed when the t is h remained amazingly well preserved. older parageneses have not completely been sc n e re This indicates that despite high destroyed. If some minerals in a paragenetic g lithostatic pressure, directed stress sequence are suited to radiometric age dating,

t was rather low during subduction of it is possible to extend the P-T path with the age s i eclogite h c the rocks. Lithostatic pressure alone datings to construct a pressure-temperature- s e

u l

b does not cause deformation of rocks; time path (P-T-t path). However, P-T-t calcula- deformation only occurs when di- tions are marked with certain errors. rected stress is applied. When the metamorphosed sequence bearing the pillow lavas was uplift ed, water 1 m pinch pillow ~ appeared; initially while the rocks

Licensed to jason patton Subduction-related magmatism – a paradox 1137 were under less extreme pressure and slightly de- in a simple way: Sediments and ocean crust, along creasing temperatures, glaucophane was formed. with serpentinites within it, release water upwards. Th e water did not penetrate the inner protected Th e water-bearing fl uids rise into the hot astheno- core of the pillows where the eclogitic mineral sphere wedge between the lower and upper plate assemblage was preserved. However, the edges of and cause melting. Melting is initiated because the the pillows were changed into blueschist. At shal- solidus temperature, slightly greater than 1000 °C lower depth, the blue glaucophane of the spandrels for “wet” mantle, is exceeded at this location below between the pillows was changed into green am- the volcanic belt. When the solidus temperature is phibole; blueschist was converted into greenschist. exceeded, the melting process begins – rocks are Th erefore, these petrographically complex rocks solid below this temperature. Without the fl uids, contain mineral assemblages from three diff erent “dry” conditions prevail and the solidus would be metamorphic pressure-temperature fields that at approximately 1400 °C. Water depresses the document decreasing pressure and uplift of the melting point of rocks. rock assemblage (Fig. 7.24). Th e critical role of water in the evolution of sub- Because of its low density, continental crust can- duction-related magmatic rocks is mirrored in their not be subducted and incorporated in signifi cant water content, generally comprising several percent amounts into the upper mantle. However, coësite- by weight (up to 6 % H2O). For comparison, basalts and diamond-bearing rocks indicate that they can at mid-ocean ridges have typical water values below be dragged rather deep into a subduction zone. 0.4 % and basalts at hot spots below 1.0 %. Eventually, they will move upwards even though they increase in density during their high-pressure modifi cation; their buoyancy is less than that of surrounding mantle material. It is unclear if crustal partly volcanic arc material can move deeper into subduction zones serpentinized depth pressure more than 200 km, perhaps to eventually disappear 0 0 into the Earth’s mantle. If this process occurs, the amount transferred is certainly minor. partly chlorite lithospheric 50 molten mantle 2 Subduction-related magmatism serpentine – a paradox? 1100°C 100 At fi rst glace, it would seem paradoxical that 1400°C 4 subduction zones, some of the coldest tectonic zones at given depths produce prolifi c amounts 150 of magmatism. How can locations where cold asthenosphere corner flow 6 litho sphere is rapidly subducted, in turn, cause 200 magma to rise and feed intense plutonism and volcanism? About a quarter of the magmatic rocks dehydration 8 on Earth, nearly 9 km3/yr, are formed above sub- 250 duction zones. Th is compared to 21 km3/yr, more than 60 % of all magmatism, at mid-ocean ridges 300 10 (Schmincke, 2004). Th e rising melts in the area of the magmatic zone cause a high geothermal gradi- [km] [GPa] ent with heat fl ow values of 100 milliwatt per m2 or more (Fig. 7.3). temperature profile below melting curve Volcanism commences abruptly at the volcanic the active volcanic arc for "wet" mantle or magmatic front. Magmas develop above sub- 0 duction zones when the downgoing slab plunges into the asthenosphere and reaches a depth of 80– depth 100 km (Fig. 7.28). Melting above the subduction zone is a complicated process but can be described 100 formation of melt Fig. 7.28 Processes of melting below volcanic arcs (Stern, 2000). Dewatering from the subduction zone [km] causes formation of serpentine in the lithopheric mantle 0[°C]300 600 900 1200 1500 of the upper plate and melts in the hot asthenospheric temperature wedge at greater depths.

Licensed to jason patton 7114 Subduction zones, island arcs and active continental margins Th e most violent volcanism occurs directly be- serpentine become unstable at increasing depth and hind the magmatic front where the large amount temperature and are transformed back to water-free of water derived from the subduction zone enters pyroxene and olivine. Th e additional water released into the asthenospheric wedge. With increasing by the mineral transformation rises and enriches depth of the subduction zone, the magma sources the water content of the subduction zone and thus become deeper (Fig. 7.29). As distance increases enhances to the melting process. Merging magma from the magmatic front towards the backarc, less blobs eventually become large enough to form water is released from the subduction zone and diapirs that rise against the downward-directed magmatic activity decreases. Most magmatism mantle currents. fades when the subduction zone reaches a depth of Subduction zones have extreme contrasts in 200–250 km. In SW Japan, volcanoes most distant crustal temperature in very close proximity. Con- from the volcanic front are located in the backarc sequently, metamorphic processes contrast across basin area, where the subduction zone reaches a fairly tight zones. For example, rising magmas gen- depth of more than 300 km. Th e downward mo- erate dramatically diff ernt types of metamorphism tion of the subduction zone induces a downward within the upper plate as compared to processes in current in the asthenospheric wedge above. As a the subducted plate immediately below. result, hot asthenosphere is drawn in from behind. In this manner, the asthenospheric wedge is con- Rocks of the magmatic zone tinuously supplied with new, hot mantle material. Melted rock material rising in the magmatic belt Th e result is a corner fl ow between the two plates above the subduction zone forms huge intrusive (Fig. 7.28). bodies, called (Greek deep bodies of Water released from the subduction zone is rocks); melts that reach the surface form volcanoes. already generated before the top of the subduction compositions include , volu- zone reaches the asthenosphere, and thus, coin- metrically most important and named aft er the cides with the zone where the subducting plate Andes, basalt, and (names of rocks glides along the upper plate. A conversion occurs are presented on the inner jacket at the back of the Fig. 7.29 Cross section of the Japanese Islands within the litho spheric mantle of the upper plate book). Collectively, these rocks are referred to as showing the change in above the subduction zone in which large amounts calc- alkaline rocks because of their high concen- melting depth (Schmincke, of water-containing minerals like amphibole and tration of calcium as well as the importance of al- 2004). The lower dia- serpentine are formed (Fig. 7.28). Th e serpentiniza- kali elements. Calc- alkaline rocks have distinctive gram shows the volume of magma produced at tion weakens the mantle in the upper plate causing chemical characteristics and typically occur above various zones across the the plate boundary to deform and be drawn down- subduction zones. Th oleiitic magmatic rocks can subduction zone. wards along the subduction zone. Amphibole and occur in minor amounts near the magmatic front and certain alkaline rocks can be important in the backarc basin area. Recall that most tholeiites are Mt. Fuji Yatsuga Take Hakone produced at mid-ocean ridges and above large hot Oki-Dogo Ontake O-Shima spots whereas alkaline rocks occur dominantly in intra-plate domains, especially hot spots and Sea of Japan continental graben structures. Pacific Ocean [km] continental crust Much of the magma produced above a subduc- lithospheric mantle tion zone does not reach the Earth’s surface but 100 rather gets trapped in the crust below the volcanoes oceanic crust 200 as plutons (intrusive bodies). , the intrusive asthenosphere equivalent of andesite is the most important plu- 300 tonic rock. Other important rock types include, tonalite, granodiorite and (the equivalents 400 of dacite and rhyolite); gabbro, the equivalent of high-alumina tholeiitic basalt basalt, is rare. magma basalt magma magma are almost exclusively the product of subduction zones and thus are strong indicators of previous subduction activity in old mountain 2625 total delivery volume of km3 active volcanoes in the ranges. Presently, 339 of 342 (99 %) active an- 436 Japanese volcanic belt 126 km3 desitic volcanoes are located above subduction 37 9 km3 km3 0 km3 zones. Generally, the chemical composition of magmas produced above subduction zones refl ects volcanic front their complex mechanism of formation. Their

Licensed to jason patton Rocks of the magmatic zone 1157 composition includes elements from the subducted spider diagrams (Fig. 7.30). Th is kind of diagram plate that are transported by the released aque- off ers a clear view because any number of elements ous fl uids and give a characteristic imprint to the can be used and the normalization allows a direct magmatic rock. Th e source of most of the melted comparison. Trace elements are generally useful substance is the process of of as- in characterizing magmatic rocks because their thenospheric material in the above strictly defi ned concentrations commonly indicate the subduction zone. Additional control of magma specifi c conditions of formation. Th e most impor- composition comes from the crust of the upper tant character of the subduction-related magmatic plate through which the magmas penetrate. Th is rocks are their high concentrations in potassium crustal infl uence varies depending on what crustal and rubidium relative to MORB and their negative type is present within the upper plate. Continental tantalum and niobium anomalies (Fig. 7.30). crust and thick island arc crust especially infl u- Th e evolution of subduction magmas is not yet ence magmatic composition. Contribution from fully understood in detail but agreement exists that the diff erent sources is refl ected by a number of the following processes are crucial: characteristic elements. Melts generated in the asthenospheric wedge • Some elements originate from the subducted above the subduction zone show the composition metamorphosed sediments and basalts. Th e of basalts or basaltic andesites. Th ey are enriched subduction component is considered to be de- in mobile elements that are easily transported by rived mostly from the sediments, in particular aqueous fl uids and include potassium, rubidium, water, the cosmogenic beryllium-10 (see box strontium, barium, thorium and uranium, all of below), and lithophile elements. them “lithophile ” (Greek “liking rocks”, tending to • Primarily, the melts are formed within the concentrate in continental crust). Th ese elements, asthenospheric wedge between the subduction which are concurrently mantle-incompatible be- zone and the upper plate. Th ey rise through the cause of their large ionic radii, are mainly derived crust because of their lower density. from subducted metamorphosed sediments, accord- • If the crust of the upper plate in the area of ing to their concentration pattern (Stern, 2000). the magmatic arc is oceanic, the Marianas, for Other elements with high ion potential, a high example, the magmas are not altered substan- relation of charge to ionic radius, are diffi cult to tially and remain mainly basaltic to andesitic mobilize and remain in the metamorphic rocks in composition (Fig. 7.31). Island arc tholeiites of the subduction zone. Th ey also preferentially and (andesites rich in Mg, named remain in the residual mantle peridodite during aft er the north of the Marianas) partial melting of the asthenospheric wedge; only are formed. limited amounts transfer into the basaltic melt. • Magmas that penetrate continental crust are Th erefore, subduction-generated melts are poor altered by two factors: assimilation of crustal in these “immobile” elements such as the heavy material and gravitational diff erentiation, both rare earth elements, niobium, tantalum, hafnium, of which produce compositions enriched in zirconium, yttrium, phosphorus or titanium. SiO2 and K2O. Calc-alkaline suites are gener- Compared to mid-ocean ridge basalt ( MORB) the ated that include aluminum-rich basalt (see Fig. 7.30 Spider- subduction-generated melts are partly depleted below), andesite, dacite and rhyolite; andesite diagrams for calc- alkaline in these elements, for instance in niobium and is clearly more common than basalt. basalts produced above tantalum. Th e depletion in Nb and Ta can be at- subduction zones (Pearce, tributed to early crystallization and stay back of 1983). The x-axis shows magnetite which incorporates these elements in elements with decreasing 100 mantle incompatibility: its crystal lattice. enrichment ensialic the initial fi ve elements From the diff erent behavior of lithophile and island arc are strongly incompat- immobile elements subduction-related magmatites ible or lithophile, the last active continental can be detected. Compared to MORB, the litho- 10 margin two are compatible, and compared to those in between are phile elements are strongly enriched in subduction- 5 MORB the partially compatible 2 related magmatites, the immobile elements show / MORB rock elements. Concentra- similar or lower concentrations as in MORB. To 1 tion of every element in ensimatic visualize the distribution pattern in the rocks the island arc the rock is divided by an average value for MORB concentrations of the elements are normalized depletion ( mid-ocean ridge basalt – against MORB. Th ey are calculated in relation 0.1 SrK Rb BaTh Ta Nb Ce P ZrHf Sm Ti Y Yb Sc Cr MORB-normalized values). to an average composition of MORB and the en- The scale of the y-axis is richment or depletion is depicted in the so-called logarithmic.

Licensed to jason patton 7116 Subduction zones, island arcs and active continental margins Acidic rocks ( to ) are most Zonation of magmas in space and time abundant where the continental crust is thick and Although magmatic belts above subduction zones subduction is long lasting; the composition of the are dominated by calc- alkaline rocks, tholeiitic magmas evolves through time. Mature island arcs and alkaline magmas also occur. These three and active continental margins with thick conti- suites of magmas display a zonation in space and nental crust display an increase in acidic rocks (rich time. Th e zonation in space is related to magmatic in SiO2) compared to more primitive island arcs variation that occurs in parallel belts of increasing that are built on oceanic crust or thin continental depth across the subduction zone. At the frontal crust. For example, volcanic rocks of the Marianas part of the volcanic belt, tholeiitic magmas occur and those of the Izu and Bonin Islands to the north and are generally expressed as basaltic rocks. Th e are located on oceanic crust; they have an average broadest and central belt comprises calc- alkaline

of 53–55 % SiO2, only 2–3 % greater than levels in magmas that include the complete calc- alkaline normal oceanic crust. In contrast, volcanic rocks suite of rocks from basalt to rhyolite, but are

of the Andes are clearly more acidic, ca. 63 % SiO2, dominated by andesite. Calc- alkaline rocks are a fi gure that approaches the average composition of commonly modifi ed by crustal assimilation and the upper continental crust of the Andes, ca. 66 % diff erentiation. Potassium-rich calc- alkaline rocks SiO2. Globally, continental crust has an average increase in abundance towards the backarc region value of 57 % SiO2. Th erefore, the lower crust must and eventually pass into that are a have a basic composition. special type of alkaline rocks. Th e volume of rock Newly formed melts periodically rise upwards. produced clearly decreases into the backarc basin During their ascent, the composition of the magma (Fig. 7.29). Th e changes in character of the magmas is changed through diff erentiation. Minerals with (tholeiitic, calc- alkaline, alkaline) are controlled high melting points crystallize and are removed by the high production of partial melt beneath the from the magma through fractionated crystal- magmatic front and the decreasing magma genera- lization and gravitational diff erentiation. Crustal tion and decreasing extraction of elements from rocks can become melted and assimilated in the the subducted rocks with increasing depth of the magma; or a chemical exchange occurs with subduction zone. crustal rocks and “contaminates” the magma. A similar trend can be observed in the potassium Th rough these processes, the composition of the content that consistently increases across the arc. melt increasingly diff ers from that of the primary Island arc tholeiites, the outer belt, are depleted melt. Th e result is that subduction-related magmas in K (mostly < 0.7 weight-% K2O), calc- alkaline within continental crust are more enriched with basalts have K2O contents of about 1 % (acidic dif- lithophile elements (Fig. 7.30). Minerals with more ferentiation products are correspondingly richer in basic composition are removed from the melt and K since this element is enriched during diff erentia- remain in the lower continental crust, thus ac- tion), and shoshonites, named aft er the Shoshone counting for its basic composition compared to River in Wyoming, have K2O contents of 2 % and the more acidic composition of the upper crust. more. Th e increase in potassium with increasing On average, the upper crust is 1.5 times thicker distance from the magmatic front is most likely than the lower crust. Th e above processes explain a result of the gradual extraction of the element why magmas generated by subduction processes from the metamorphic sediments in the subduction are much more complex and variable at locations zone where K-containing minerals, especially mica, where continental crust is involved (e. g., Andes, dehydrate and yield K to aqueous fl uids. Japan) than at the locations of intra-oceanic island Because the amount of partial melt in the as- arcs like the Marianas. thenospheric wedge decreases towards the backarc If the subducting oceanic crust is very young region, potassium experiences relative enrichment and hot, the subducted basaltic crust can partially in the melts although less K is extracted from the melt in the presence of water. A distinct rock type subducted material. Moreover, the SiO2 content is formed from these magmas, known as of melts generally decreases towards the backarc aft er the Adak Island in the Alëutians. Th ese rocks region and thereby emphasizes the alkaline char- are rare and currently form in only several places. acter of the rocks, because less SiO2 is available Besides the Alëutians, where young oceanic crust to saturate the potassium in potassium feldspar is currently being subducted, adadakites are also (KAlSi3O8). Th erefore SiO2-undersaturated min- present in Costa Rica. Here, the Cocos Ridge, a erals like leucite (KAlSi2O6) are formed, typical young but inactive oceanic ridge, is being subducted of shoshonitic rocks. Shoshonites are indicative of beneath the Central American at a fl at- the rear side of subduction-related magmatic zones. tened angle of approximately 30°. In Japan they are found in the backarc basin, the

Licensed to jason patton Explosive stratovolcanoes as indicators for subduction magmatism 1177 Sea of Japan (Fig. 7.29). Th e chemistry of alkaline Subduction magmatism is the most important 100 rocks of hot spots and continental s diff ers from process in the formation of continental crust. Par- [%] primitive island arc that of shoshonites as expressed by the dominance tial melting of mantle peridotite produces basalts 80 of sodium over potassium. but no acidic rocks. Only the multiple recycling of Calc- alkaline basalts are “high-alumina ba- eroded island arc material in subduction zones and 60 salts” that are characterized by their enrichment repeated melting gradually lead to the evolution 40 in aluminum, 16–20 weight-% Al2O3 compared of acidic magmatic rocks. Repeated volcanic ero- to 12–16 % in tholeiite. Probably the aluminum sion and transport of rock particles and minerals 20 is derived from the subducted sediments. It is into sedimentary basins enriches the content of transported into the asthenospheric wedge, where quartz and clay. If these minerals are supplied to 0 melting occurs, along with the fl uids and other a subduction zone, magmatic rocks rich in silica 100 elements enriched in calc- alkaline magmas. Clay- and aluminum can develop above the subduction [%] evolved island arc rich sediments, common on ocean fl oors and in zone. If this cycle is repeated numerous times, the 80 deep-sea trenches, are rich in Al2O3. amount of acidic rocks in the continental crust A change from tholeiitic to calc- alkaline char- gradually increases. Because the crust in the mag- 60 acter of the magmatic rocks can also develop over matic arcs does not move horizontally relative to 40 time as young, intra-oceanic island arcs evolve to the magma centers as it does at mid-ocean ridges mature island arcs. Young island arcs such as the or at hot spots, substantial crustal accretion is the 20 Marianas, with underlying oceanic crust, only result. Not surprisingly, the bulk composition of produce basalts and basaltic andesites. Th e basalts continental crust is similar to andesite, the most 0 dacite have a tholeiitic composition and the andesites important rock type of the volcanic belts above basalt rhyolite are boninites. Th e composition of the boninites subduction zones. andesite indicates that they are not derived from the asthe- nospheric wedge above the subduction zone but Explosive stratovolcanoes as indicators for Fig. 7.31 Frequency rather derived from partially melted harzburgites subduction magmatism diagram showing diff erent of the litho spheric mantle of the upper plate; nor- Basaltic magmas are low in viscosity and contain volcanic compositions in primitive and evolved mally, harzburgites do not reach suffi ciently high relatively few volatiles. Th erefore, basaltic volca- intra-oceanic, ensimatic temperatures to melt (Wilson, 1989). Th rough time, noes are characterized by smooth-fl owing, low- island arcs. the intra-oceanic island arc evolves into a typical viscosity and enjoy the reputation of being calc- alkaline magmatic complex, dominated by an- non-explosive. Acidic magmas are more viscous desitic rocks, above the subduction zone (Fig. 7.31). and may contain large amounts of volatiles, es- Th e primary melts are basalts, with an SiO2 content pecially water. High-level magma chambers can ca. 48–53 weight-%, and basaltic andesites with build up enormous gas pressures that may lead 53–57 % SiO2; both tend to diff erentiate towards to spectacular explosive eruptions. Intermediate more acidic rocks. During the evolutionary pro- to acidic volcanoes above subduction zones have cess of becoming an evolved island arc, the 10- to high-risk explosive potential. 20-km thick mostly basaltic crust of the primitive Typically, explosive volcanoes above subduction island arc is thickened to greater than 20 km as it zones are andesitic to dacitic in composition and chemically evolves towards the andesitic chemical form stratovolcanoes, so named because the strati- average composition of continental crust. fi cation comprises alternating layers of lava fl ows In cases of island arcs built on continental base- and ash layers. Th e volcanoes have steep slopes, ment or arcs on active continental margins, the typically inclined to 40°, and are the prototype of rising basaltic to basaltic-andesitic magmas have the “common volcano”. Examples occur around the to penetrate the older continental crust. However, Pacifi c: (Philippines), Fujiyama the lower density continental crust forms a physi- ( Japan), Mount Saint Helens (USA), Popocatépetl cal barrier for the magma rising from the mantle. (Mexico; Fig. 7.33), Chimborazo (Ecuador). Th e Especially at Chile-type continental margins, the explosive activity produces volcanic ashes, ejected rising magma is retarded over long time periods loose material solidifying to volcanic s, whereas by the thick crust. The magmas in the crustal calmer eruptions produce lavas. Lavas are defi ned chambers diff erentiate at depth and evolve towards as extruding magma that has been degassed during more acidic compositions. Th rough this process, the ascent because pressure has been released. substantial amounts of andesitic (57–63 % SiO2), Th e eruption of Mount Saint Helens in north- dacitic (63–68 % SiO2) and rhyolitic (68–75 % SiO2) western USA in 1980 was magnifi cently document- magmas evolve. Th e melts accumulate into grano- ed. Th e volcano is a product of the subducting Juan dioritic batholiths that get stuck in the crust or rise de Fuca Plate beneath the western coast of North to the surface to form mostly explosive volcanoes. America. Surface measurements, seismic and other

Licensed to jason patton 7118 Subduction zones, island arcs and active continental margins

Isotopic signatures and the infl uence of continental crust subduction-related magmas, mostly 0.706-0.710, and refl ect a restricted crustal component. They evolved from magmas The infl uence of continental crust can be detected by iso- primarily generated from the mantle. Batholiths with I-type topic analyses. Prolonged mixing in the mantle has caused granitoids are exposed over thousands of square kilometers strontium isotopes to have a fairly consistent isotopic ratio. in the (USA) and the Andes. The batholiths The 87Sr/86Sr ratio for basalts of the upper mantle at mid- formed the roots of subduction-related volcanic belts, the ocean ridges is presently ca. 0.703 and therefore refl ects the deep crustal material later exposed by erosion. They testify isotopic composition of the mantle source (Fig. 7.32). In the to former, extensive subduction activity as the large Farallon geological past this ratio was lower because 87Sr forms by Plate was subducted under North and South America. the of 87Rb. Rubidium, an element that is S-type have a higher 87Sr/86Sr ratio (> 0.710) and incompatible in the mantle, primarily enters the acidic rocks indicate crustal melting processes, especially from metamor- of the continental crust. Cosequently, the production of 87Sr phosed sedimentary rocks. “S” stands for “sedimentary” ori- from 87Rb in the continental crust is high. Throughout Earth gin. Principally, they evolve during orogenic processes related history, this has caused acidic crustal rocks to increase their to the collision of continental crust and not as subduction- 87Sr/86Sr ratio with respect to the mantle. related magmas. Magmas directly derived from the mantle have a concurrent Some radioactive isotopes that have relatively short half- Sr isotopic ratio, ca. 0.703 for MORB and its asthenospheric can be used to identify the contribution of subducted source. However, magmas formed by melting of older conti- sediments in subduction-related magmatic rocks. The isotope nental crust have high 87Sr/86Sr ratios with values of 0.710 and beryllium-10 (10Be) is formed through cosmogenic radiation in higher. But crustal contamination of mantle-derived material the atmosphere, fl ushed by rain, and then bound into marine creates intermediate isotopic ratios. Island arc magmas typi- sediments. If these sediments are subducted, they release the cally have 87Sr/86Sr isotopic ratios between 0.704 and 0.710 beryllium to the subduction-related melts that soon erupt (Fig. 7.32) because the amount of crustal Sr is generally low. to form volcanic rocks. Because this process develops over However, it is not possible to discern whether the crustal a time period of only a few million years, some 10Be is not component was derived from the subducted sediment or the radioactively decayed (the half- of 10Be is 2.6 m. y.) when continental basement of the volcanic zone. the magmas reach the surface. In similar fashion, neodymium isotopes can be used to Volcanic rocks that contain 10Be indicate that young sedi- separate mantle and crustal ori- ments were subducted and that gin. However, 147Sm that decays 143Nd they partly fed the melts. The 143 144Nd to Nd is enriched faster in the MORB youngest sediments are always mantle than in continental crust 0.5132 in the uppermost layer of the Marianas, Alëutians, because samarium is a mantle- South Sandwich subducted sedimentary pile compatible element that re- 0.5131 and they would be the fi rst to mains in mantle rocks when Japan be scraped-off during accre- partial melts are removed. The 0.5130 tion. Therefore, the occurrence mantle origin is thus revealed of 10Be in the volcanic rocks by higher 143Nd/144Nd ratios. 0.5129 demonstrates that the young- Island arc magmatites gener- est sediments were subducted ally have 143Nd/144Nd ratios of 0.5128 rather than being scraped-off 0.5124–0.5130 (Fig. 7.32). New Zealand into an accretionary wedge. If Based on isotopic ratios 0.5127 large-scale accretion occurs, the and other chemical and miner- Earth young sediments are added to alogical characteristics, granitic 0.5126 the accretionary wedge and no rocks have been subdivided detectable 10Be will be present into I-type and S-type granites 0.5125 in the volcanic rocks above the (granite is used sensu lato or Sunda subduction zone. In older sedi- “granitoids”: granites, granodi- 0.5124 Lesser ments, most 10Be is decayed orites, tonalites). I-type granites Antilles and is no longer detectable. (“I” stands for “igneous”), are 0.5123 typically formed at island arcs Fig. 7.32 87Sr/86Sr and Earth and active continental margins 0.5122 143Nd/144Nd relations for volcanics from island arcs as compared to and generate large batholiths basalts of mid-ocean ridges ( MORB). in the magmatic zone. They 0.703 0.705 0.707 0.709 0.711 Ø Earth: average values for bulk Earth have 87Sr/86Sr ratios typical of 87Sr/86Sr composition.

Licensed to jason patton Metamorphism in the magmatic belt 1197 geophysical investigations provided detailed infor- mation about the location of the high-level magma chamber and thus, it was possible to predict an eruption in principle but not exactly as to when it would occur. Much preparation was made to record the eruption and to avoid loss of life. Th e following events characterized the eruption of Mt. Saint Helens: (1) Rising magma caused the 3000 m-high volcano to bulge at its top; (2) the peak region started to glide, related pressure release inside the mountain generated a violent explosion that asymmetrically blasted away a huge part of the top and side of the volcano; (3) an avalanche composed of volcanic ash and gasses, mostly water as steam, raced down the valley adjacent to the ruptured fl ank, generated a shockwave, and in the upper crust at the magmatic front jumps to Fig. 7.33 Aerial view leveled trees over an area of several hundreds of 35–50 °C/km (Fig. 7.25). Consequently, rocks of of the Popocatépetl in square kilometers; (4) the explosion and ejected the crust below the volcanic belt experience a com- Mexico, a typical strato- volcano above a subduc- material lowered the elevation of the mountain pletely diff erent metamorphism than rocks in the tion zone. by about 400 m. accretionary wedge or in the subduction zone. Metamorphism in the magmatic zone is char- Metamorphism in the magmatic belt acterized as low-pressure/high-temperature; this The magmatic zones of island arcs and active means that at a given depth, the temperature is sub- continental margins are characterized by high - stantially increased compared to subduction meta- thermal gradients generated by the rising magmas. morphism. Th is temperature-dominated metamor- Whereas the temperature increases downwards in phism is named Abukuma-type metamorphism the subduction zone and in the forearc area by less aft er the Abukuma Plateau in Japan (Figs. 7.24, than 10 °C per kilometer, the 7.34) and is characterized by characteristic mineral

Paired metamorphic belts Sea of Japan As fi rst identifi ed in Japan, pairs of elongate, parallel belts with signifi cantly diff erent meta- morphic rocks are indicative of former subduc- Permian- Hida belt Abukuma tion activity. One metamorphic belt consists of pair Sangun belt Plateau

rocks formed by high-pressure metamorphism Honshu and the other consists of rocks of the Abukuma Korea facies high-temperature metamorphic rocks. These two belts of metamorphic rocks, which were formed under extremely diff erent pressure/ Pacific temperature relations, occur in direct association Ocean

and are called “paired metamorphic belts”. Ryoke belt Jurassic- Orogenic processes involve uplift that raises Kyushu Cretaceous portions of the metamorphic rocks towards Sanbagawa belt pair the surface and into the zone of erosion. From the spatial arrangement of the two contrast- Abukuma-type metamorphism high-pressure metamorphism ing belts at the surface it is possible to detect not only former subduction activity but also the polarity of the subduction zone Fig. 7.34 Paired metamorphic belts in (Fig. 7.34). The high-pressure belt (subduction metamorphism) marks the area of Japan (Miyashiro, 1973). The diff erent ages the subduction zone and the high-temperature belt (Abukuma-type metamor- of the belts indicate that subduction lasted for more than 250 million years, each with phism) marks the location of the magmatic arc. In Japan the paired metamorphic subduction directed towards N or NW. The belts indicate subduction beneath the Asian continent began in the Permian. Since subduction zone shifted stepwise outward the Permian, the subduction zone has shifted twice towards the present Pacifi c (southeastward) and is today off shore the Ocean. The presently formed metamorphic rocks are still hidden at depth. Japanese coast in the Pacifi c.

Licensed to jason patton 7120 Subduction zones, island arcs and active continental margins

Fig. 7.35 Schematic porphyry-copper type Kuroko type intrusions of granodiorites (I-type granites; see box diagram of ore deposits of above; Fig. 7.35). Th e name refers to the porphyric the porphyry- copper type volcanic arc volcano-sedimentary structure (large single crystals in a fi ne-grained and Kuroko type. Both are ore deposits related to acidic magma- matrix) of the granodiorites. Th e ore deposits are tites above subduction also called “disseminated ores” – the copper or mo- zones. lybdenum ore particles are distributed throughout granodiorite rhyolite the rock and not concentrated in veins. Large por- phyry-type deposits occur at the active continental margins of North and South America and in the disseminated network mineralization mineralization island arc systems of the western Pacifi c. Additional deposits are known from the Alpine mountain belt assemblages. Because of the high temperatures, the of southern and southern Asia. rocks are easily deformed. Porphyry-type deposits include approximately Due to the high geothermal gradient, the tem- 70 % of copper and 100 % of molybdenum mined perature in the magmatic zone increases to generate worldwide. A given ore deposit may contain the highest grades of metamorphism, 650–900 °C, 10 million to 1 billion tons of ore; commercial present at crustal depths. Rocks may experience gold deposits are commonly associated with the partial melting ( anatexis). Sedimentary rocks begin primary ores. Although concentrations of metals to melt at a temperature of approximately 650 °C, are normally low, 0.3 to 1 % Cu, they are typically if water is present (Fig. 7.24), and produce mig- distributed over large areas and lend themselves to matites, a mixed rock, formed from granitic melts relatively low-cost, open-pit mining methods. Th e that contain highly metamorphosed but not melted widely distributed ores are locally concentrated in residuals. Dry magmas and sedimentary rocks, small fractures where acid-containing fl uids leach which have already expelled their water, are not and intensely corrode the country rock. Th e most melted under these conditions; instead granulites common ore minerals are chalcopyrite and bornite develop. In general, the formation of granulites (two Cu-Fe sulfi des); pyrite is the most common occurs at the base of the continental crust. accessory mineral. Molybdenite is mined as a by- Abukuma-type metamorphism occurs below product. Intrusives delivering the ores have low 7–10 km depth and refl ects regional metamorphism. 87Sr/86Sr ratios at island arcs (about 0.704) and In contrast, intrusions that rise into shallow depths higher ratios at the active continental margin of of only a few kilometers create a zone of contact North America (up to 0.709). along their margins, the metamorphic aureole. Kuroko-type ore deposits (Fig. 7.35) comprise During this contact metamorphism (Fig. 7.24), another class of ore deposits. Th ey are present in heat of the intrusive body reacts with the cold island arcs; the type locality is in Japan. Kuroko- country rock and mobilizes aqueous fl uids that type ore deposits are characterized by polymetallic form numerous mineral changes. Th is process is sulfi dic ores with pyrite, chalcopyrite, sphalerite, mainly visible in sedimentary rocks where clay-rich and galena, as well as gold. Th ese ores are related sediments are metamorphosed to knotted schists or to rhyolitic and their feeder dikes. Ore hornfels and carbonatic rocks are metamorphosed deposits can be associated with a subvolcanic net- to skarns. Knotted schists are slaty rocks in which work of veins in rhyolites (yielding copper, zinc, newly grown metamorphic minerals form either and gold) or occur as massive copper, zinc, and specks or nodules. Hornfels is a product of higher lead ore bodies that precipitate in sea water near temperatures in which the rock is recrystallized volcanic centers. into a fi ne-grained mix of minerals that creates the horny appearance. In carbonatic rock the sup- The backarc basin ply of SiO2 from the pluton produces calc-silicate Th e island arc is continuous with the backarc basin minerals. Skarn is a Swedish word for miners of located behind the magmatic arc (Fig. 7.36). Japan, calc-silicate rock. Contact and Abukuma metamor- separated from the Asian continent by the Sea of phism are transitional in magmatic arcs. Japan, is a good example with Japan constituting the arc and the Sea of Japan constituting the back- Ore deposits in the magmatic belt arc basin. In Japan, magmatism decreases towards A number of important ore deposits, especially in the basin where shoshonitic volcanoes occur. Th e the circum-Pacifi c region, occur in the magmatic basin is underlain by oceanic crust that was formed belt above the subduction zone. Mostly these are when the Japanese Islands, containing continental porphyry-type copper and molybdenum depos- crust, drift ed away from the continent through its that are related to high-level (subvolcanic) some process of backarc spreading.

Licensed to jason patton The backarc basin 1217

Th e island-arc garlands in the western Pacifi c 60°N were mostly formed by the same process. Th e ef- Kamchatka fect of the suction caused by the roll-back of the Eurasia Basin subduction zones extended the litho sphere of the Bowers Alëutian Japan Basin Basin upper plate. Th e heat of the rising magma weak- Basin Okhotsk ened the crust and initiated the break up of the Basin area behind the magmatic belt. Consequently, new oceanic litho sphere formed in the backarc basin Shikoku Basin from the rising asthenospheric material. Formation 30°N Bonin Basin of oceanic crust in this tectonic setting is generated South China by partial melting of rising asthenosphere and is Basin related to processes that occur at a mid-ocean ridge. Parece Vela Basin

Magnetic stripes, however, are only partly evolved, Pacific Ocean probably because of irregular and closly spaced Mariana Basin

mantle currents that contribute to the formation of Sulu Sea this crust. Th e Sea of Japan is sometimes referred Western Philippine Basin to as a diff use backarc basin because the new crust Bismarck Sea Basin 0° is formed over a broad area rather than focused on Solomon Sea Basin a distinct spreading ridge. Vanuatu Basin Coral Basin Active extension and seafl oor spreading pres- Fiji Basin ently occurs in several backarc basins including the Marianas, the Tonga Islands (Fig. 7.36), and New Caledonia Lau the South Sandwich Islands (South Atlantic). In Basin Basin Australia the backarc area of the Tonga Islands, the spreading velocity reaches 16 cm/yr and thus is comparable Tasman 30°S Basin South Fiji with that of the equatorial Pacifi c. In contrast, the Basin backarc area of the Marianas has an extension rate 120°E 150°E 180°E of only 4 cm/yr. Th e processes and characteristics of fast and slow spreading mid-ocean ridge systems active inactive, high heat flow inactive, normal heat flow are comparable to spreading axes in backarc basins: smooth topography at fast spreading ridges and rough topography with a central graben at slow Sediments deposited in backarc basins consist of Fig. 7.36 Distribution of backarc basins in the west- spreading systems. Even smokers can be observed arc-derived volcaniclastics and volcanic ashes, sand ern Pacifi c (Karig, 1971). in backarc basins. Th e asthenosphere of the mantle and mud eroded from the continent, and marine In addition to the active wedge is somewhat contaminated by fl uids that carbonates. Th e thickness of foreland basin sedi- basins that generate new contain elements derived from the subduction zone. ments is highly variable and depends upon rate of oceanic crust, inactive Th erefore, basalts of the backarc basin crust have, basin subsidence and availability of eroded mate- basins exist, which accord- ing to their cooling stage, to some degree, the characteristics of subduction- rial. Both backarc and forearc basins contain large have diff ering amounts of related magmas. In most ways, they are very similar amounts of hydrocarbons. heat fl ow. to MORB. At active continental margins like the Andes, Tonga Islands large-scale compression is transferred to the up- deep-sea trench island arc Lau Ridge per plate and consequently, the backarc area is E W characterized by compressional and thrust belts. Th rusts are directed towards the backside foreland, away from the volcanic belt (Fig. 7.5). Pacific Th e weight of the stacked wedges of the thrust belt 9-16 8 cm/yr depresses the adjacent crust and generates a retro- cm/yr arc foreland basin.

lithosperic mantle Fig. 7.37 Relations of the Lau Basin, Lau Ridge, and Tonga island arc above the Tonga subduction zone. The active oceanic Lau Basin is an active backarc basin with a young spread- volcanic arc inactive crust ing axis. Spreading in the backarc basin has split the volcanic arc original volcanic arc into active and inactive components.

asthenosphere

Licensed to jason patton 7122 Subduction zones, island arcs and active continental margins plus the upper plate where it attains its full thickness Splitting of intra-oceanic island arcs including its dense litho spheric mantle (Fig. 7.3). Th e positive anomaly is most characteristic at the The intra-oceanic, ensimatic island arc of the Tonga Islands was split dur- magmatic front and decreases to normal gravity ing the late Cenozoic (Fig. 7.37). The Tonga Islands represent the present values towards the backarc basin. In the magmatic active island arc and to the west, the Lau Basin represents a backarc basin arc, the anomalously lighter asthenospheric wedge (Fig. 7.36, high heat fl ow) and the Lau Ridge represents an inactive volcanic above the subduction zone partly compensates the arc. The Lau Ridge is volcanically inactive because it is no longer located positive gravity anomaly and contributes to the above the magmatic zone. The Lau Basin is composed of newly formed emergence of the volcanic belt. oceanic crust with backarc basin characteristics along with dispersed As expected, heat fl ow abruptly changes at the remnants of the inactive island arc. It has a very thin sedimentary cover magmatic front (Fig. 7.3). Its value of ca. 50 milli- due to its young age. watt per square meter (mW/m2) in the open ocean The Lau Ridge had an interesting Late Cenozoic history (Hawkins, is only slightly below the global average. This 1974). It began as the active island arc when the Pacifi c Plate subducted value signifi cantly decreases in the forearc area beneath it. However, slab roll-back (see above) caused the subduction and increases abruptly in the magmatic arc to zone to migrate eastward. The rapid eastward migration caused the arc 80–150 mW/m2. Th ese heat-fl ow values result from to split and a backarc basin formed between the two pieces (Fig. 7.37). the downward transport of material in the forearc The split occurred because the arc consisted of hot, weak crust that was area and the rising of hot magmas in the magmatic easily pulled apart. The Tonga Islands on the eastern margin continued arc. Th is situation also results in the paired meta- to reside above active subduction and are presently the active island arc. morphic belts. With decreasing volcanic activity The Lau Ridge, now removed from above the magmatic source, is inactive; the heat fl ow in the backarc area also decreases. the backarc Lau Basin separates the two although several fragments were However, in backarc basins with active spreading, imbedded in it as the older arc became dismembered. the heat fl ow is signifi cantly higher and can reach The entirely oceanic contains an inactive, NW-SE values approaching those of the magmatic arc. trending spreading axis in its western and central part (Fig. 7.36, area with normal heat fl ow). Spreading there was active in the Middle Cenozoic. Subduction and collision Slab roll-back of the intra-oceanic Mariana subduction zone and backarc Th is chapter has presented the consequences of extension formed backarc basins along the eastern margin of the Philip- subduction activity. Only oceanic litho sphere is pine Sea Plate. The present backarc basin forms a narrow zone at the able to generate permanent subduction to great eastern margin of the plate, the Mariana Basin. The basin is characterized depths. When a crustal block with continental by young and hot ocean crust that evolved in similar fashion to the Lau material that is connected to oceanic crust reaches Basin. The Parece-Vela Basin to the west is an older backarc basin that a subduction zone, it collides with the island arc or became inactivated when the subduction zone migrated eastward and the active continental margin. During collision the the Mariana Basin formed; it is presently cooling down. continental block is partially subducted beneath the edge of the upper plate and then pushed or pulled also into deeper parts of the subduction zone. However, it is not transported to great depths Gravity and heat fl ow because of its low density. Th e colliding continen- Geophysical measurements of gravity and heat fl ow tal margins are strongly deformed, sheared and yield interesting insights into processes occurring dismembered into tectonic units (nappes) and are at convergent plate margins. Gravity and heat fl ow subjected to metamorphism characterized by an values across a plate boundary indicate typical pairs intermediate pressure gradient (Barrovian-type of negative and positive anomalies (Fig. 7.3). metamorphism; Fig. 7.24). Gravity in ocean basins in front of subduction Th e eastern Sunda Arc provides an example of zones and in backarc basins is nearly in balance; where collision has recently begun (Fig. 7.9). Th e these areas are approximately in isostatic equilib- Australian continent and its marginal Sahul shelf rium related to the sublitho spheric mantle. Th e are part of the Indo-Australian Plate that is drift ing forearc area shows a negative and adjacent posi- against the Sunda Arc. Th e collision has occurred tive gravity anomaly. Th e mass defi cit causing the adjacent to Timor and eastward. Underplating by negative anomaly is explained by the bending of the the Sahul shelf has already caused the uplift of the subducting plate that results in a trench fi lled with a outer ridge, which comprises Timor and the islands thick layer of water that is substantially lighter than directly east of it. A trench exists but it is rather rock material. Water-saturated sediments in the shallow, slightly more than 3000 m depth, because deep sea trench and in the accretionary wedge are the underplated continental crust of the Sahul shelf also less dense and add to this anomaly. Th e positive is pushing upward. Th is condition documents the anomaly results from the dense subducting plate beginning orogenesis!

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