1 PREFACE
Management of risk due to industrial operations is one of the most complex issues facing the society today. In recent times accidents are becoming the focus of greater attention because of their increasing frequency and their huge impact on organization as well as the society. The risk from the industrial operation not only remain confirmed to the boundaries of the industrial premises, but have potential for impact on the areas well outside their perimeter. Transportation of hazardous material from the industry to various destinations by road, rail and pipelines poses yet another hazard enroute or in transit. In the light of accidents at Bhopal, Vizag, Mexico, Flixborough etc considerable public and governmental concern has been aroused for evolving appropriate strategy for identifying, assessing, controlling industrial risk and action plan for handling emergencies when it strikes.
A sincere effort has been made in this document for addressing the issues mentioned above. This valuable compilation would help government agencies and other concerned who are entrusted with handling of emergencies. The plan gives clear organizational structure for all agencies and elaborates the duties to be performed by each when situation demands, so as to reduce the probability / severity of community suffering and property damage. The activities among other things include providing help in arranging for food, shelter, clothing, medical attention and other life sustaining requirements.
2 TABLE OF CONTENTS
CHAPTER 1: INTRODUCTION ...... 4 CHAPTER 2 : OBJECTIVE, PURPOSE AND SCOPE ...... 5 CHAPTER 3 : ABBREVIATIONS AND DEFINITIONS ...... 6 CHAPTER 4: USER GUIDE ...... 10 CHAPTER 5: INITIAL NOTIFICATION AND EMERGENCY CONTROL CENTRES ...... 12 CHAPTER 6: RISK POTENTIAL AND GEOGRAPHICAL FEATURES OF DISTRICT ...... 15 CHAPTER 7 ORGANISATION FOR DISASTER MANAGEMENT ...... 23 CHAPTER 8: ROLES & RESPONSIBILITIES OF EMERGENCY COORDINATORS ...... 40 CHAPTER 9 : WARNING SYSTEM ...... 50 CHAPTER 10: PERSONAL PROTECTION OF CITIZENS ...... 51 CHAPTER 11: EVACUATION PLAN ...... 52 CHAPTER 12 : CONTAINMENT AND CLEANUP ...... 54 CHAPTER 13 : TRANSPORT EMERGENCY ...... 55 CHAPTER 14 : TESTING AND UPDATING PLAN ...... 58 CHAPTER 15 : GENERAL GUIDELINES IN DISASTER ...... 61 CHAPTER 16 : SAFETY PRECAUTIONS (RESPONSE PERSONNEL SAFETY) ...... 62 CHAPTER 17 : GUIDE ON ANTIDOTES ...... 63
Annexure : 1 : Chemical Fact Sheets (MAH Industries) AEGIES CHEMICALS INDIA LTD ...... 67 BHARAT PETROLEUM CORP. LTD. – REFINERY DIVISION ...... 71 BHANDUP COMPLEX WATER TREATMENT PLANT ...... 76 CHEMICAL TERMINAL TROMBAY LTD ...... 80 HINDUSTAN PETROLEUM CORP. LTD. REFINERY ...... 84 HINDUSTAN PETROLEUM CORPORATION LTD. MAHUL TERMINAL ...... 88 HPCL MAHUL LPG FILLING PLANT ...... 92 MAHINDRA & MAHINDRA (TRACTOR DIVISION) ...... 96 MAHINDRA & MAHINDRA LTD. (JEEP DIVISION) ...... 100 PARLE PRODUCTS LIMITED...... 104 RASHTRIYA CHEMICALS AND FERTILIZERS LTD, TROMBAY UNIT ...... 109 SANUJ STEELS PVT LTD ...... 114 HINDUSTAN PETROLEUM CORP LTD : AVIATION FUEL STATION ...... 116 INDIAN OIL CORP LTD : AVIATION FUEL STATION ...... 118 SEA LORD CONTAINERS LIMITED ...... 120
Annexure : II : Chemical Fact Sheets (Hazardous pipelines) AEGIS CHEMICAL INDUSTRIES LTD ...... 125 AEGIS CHEMICAL INDUSTRIES LTD– LPG/PROPANE...... 127 BHARAT PETROLEUM CORPORATION LTD- HSD / MS /KERO ...... 130 GAS AUTHORITY OF INDIA (GAIL) : NATURAL GAS ...... 132 HINDUSTAN PETROLEUM CORPORATION (ATF) ...... 134 HINDUSTAN PETROLEUM CORPORATION LTD : MS/HSD/KERO ...... 135 HINDUSTAN PETROLEUM CORPORATION LTD : FO / LDO ...... 136 INDIAN PETROCHEMICALS CORP. LTD : PROPANE (LIQUID) ...... 137 MAHANAGAR GAS LTD.: NATURAL GAS ...... 138 RASHTRIYA CHEMICALS & FERTILIZERS LTD.: NATURAL GAS ...... 140 RELIANCE INDUSTRIAL INFRA LTD: NAPHTHA / KERO ...... 141 TATA POWER COMPANY LIMITED : NATURAL GAS ...... 143
Annexure - III : Information on Chemicals at MAH Factories
Annexure - IV : Contact Information - Emergency Services
3 CHAPTER 1: INTRODUCTION
No Industrial plant, office, commercial, or mercantile organization is immune from catastrophe. Therefore, emergency action planning is not a luxury, it is good insurance. Today, the need for emergency action planning is intensified by the trend to build in the suburbs where professionally trained help may not be available.
Emergencies can arise at any time and do not have to be caused by a spectacular occurrences, such as nuclear attacks or tornadoes, in fact, serious personnel injuries and property losses can result from broken water and gas lines, exploding boilers and- explosion in neighboring plants. Injuries and property damage result form basic six causes : work accidents, fire & explosions, flood , earthquakes, hurricanes, tornadoes warfare or civil strife. Often when disaster strikes, all personnel are affected, their lives are in jeopardy and their jobs ate threatened. Major considerations in planning for disaster control must include 'provisions for protecting personnel, evacuating both injured and uninjured, and care of the incapacitated.
Regardless of the size and type of organization, management is responsible for developing and operating an emergency action Programme, which is designed to meet all eventualities. An effective emergency action plan requires the same good organization and administration as any business undertaking. There is no one emergency plan that will do all things for all organizations. Each company must therefore decide on a plan that fits its needs and can be afforded.
Emergency action plans include the organizing and training of small groups of people to perform specialized services, such as fire fighting or first aid, and to restore the organization to a productive unit. Small, well trained groups can. serve as a nucleus to be expanded to any size needed to meet ant kind of emergency. Even with outside help available, a self help plan is the best assurance that losses will be kept to a minimum. This precaution is particularly true in the case of warfare or civil strife because outside help may not be immediately available an the survival of the company will depend on its own ability to cope with its problem.
Ministry of Environment & Forest (MOEF) Government of India as the nodal ministry for management of chemical disasters, have as part of a programme avoid major accidents like Bhopal and restrict the loss of human beings, have decided to prepare a district disaster management plan, as per their guidelines. This plan is only a district management action plan for the Mumbai suburban district.
4 CHAPTER 2 : OBJECTIVE, PURPOSE AND SCOPE
OBJECTIVE & PURPOSE The emergency Response Plan means a detailed programme of action to control and minimize the effect of an emergency, requiring prompt corrective measures beyond normal procedures to protect human life, minimize injuries, optimise loss control & reduce the exposure to physical assets & environment . in other words the emergency response plan is a process by which the response to an extra ordinary event is galvanised urgently through activation of functional components and assignment of responsibility for each component to an appropriate agencies. The action plan functions optimally only if undertaken and an institutional set-up responsible for the mitigation and response is understood clearly.
The purpose of this plan is to outline the procedures for immediate action, if major emergencies occur involving Major Hazard Units in the district.
Every Major Accident Hazard Unit has its Onsite Emergency Plan to deal with an emergency inside the premises of the factory. I fan emergency arises beyond the resources of the factory, they have an obligation to seek assistance from the Government. This plan comes into operation as soon as a responsible person of the Major Hazard Unit covered under this plan triggers the initial alert action regarding the Offsite emergency Plan as specified under this plan.
SCOPE The Major Accident Hazard Units in Mumbai Suburban district are covered under this plan. The plan will apply only to the following emergency scenario :
• Release of toxic / flammable material, both liquid & gases • Explosion / Fire
5 CHAPTER 3 : ABBREVIATIONS AND DEFINITIONS
THE EMERGENCY RESPONSE PLAN The emergency Response Plan means a detailed programme of action to control and minimize the effect of an emergency, requiring prompt corrective measures beyond normal' procedures to protect human life, minimize injuries, optimize loss control & reduce the exposure to physical assets & environment.
In other words the emergency response plan is a process by which response to plan an extra ordinary event is galvanized urgently through activation of functional component and assignment of responsibility for each component to a appropriate agencies.
The object of an emergency plan is to intercept a developing disaster as quickly as possible so as to minimise its scale and consequences in terms of loss of life and property. It is oriented towards containment and extermination of the hazard. A Disaster Plan is pressed into service after the terminal event has occurred arid is oriented towards Salvage and Rescue Operations.
DISASTER An event, natural or manmade, sudden or progressive which impacts with such severity that the affected community must respond by taking exceptional measures It is a sudden or progressive occurrence of such magnitude as to affect normal pattern of life in an industry and/or vicinity causing extensive damage to life and/or property.
TYPES AND LIKELY CAUSES OF DISASTER
TYPES OF DISASTER The types of disaster considered for this plan are limited to the following:
• Fire and explosion • Vapour cloud • Toxic Gas release • Large Oil Spills
These disaster may arise form an industrial activity with the industry or during transportation of hazardous material by pipeline, road or rail en route its destinations or in transit.
The other types of disaster mentioned below are not considered within the scope of this plan
• Hurricane, Flood, Cyclone
6 • Strike and sabotage • Nuclear disaster
CAUSES OF DISASTER Various causes that can lead to the above referred types of disasters are as follows a) In-plant emergencies due to
• deficiencies in system/ • malfunctioning/improper handling in operations or maintenance • Design or Equipment failure b) Emergency during transportation of hazardous material by road, rail or by pipeline
The other causes of disaster mentioned below are not considered within the scope of this plan.
• Natural calamities like Cyclone/storm/gale/flood/Lightning/Earthquake • Deliberate acts of man like Sabotage, Riot, War Debris from a falling air craft/rockets
PHASES OF DISASTER
WARNING PHASE Many disasters are preceded by some sort of warning. For example with the aid of satellites and network of weather stations, many meteorological disasters like cyclones and hurricanes can be predicted and actions can be taken to eliminate/reduce their effect.
In an industrial unit the detection and alarm system can be used for timely detection of emergencies and alerting required personnel
PERIOD OF IMPACT PHASE This is the period when the disaster actually strikes and very little can be done to lessen the effects of disaster. The period of impact may last for a few seconds (like fire, explosion, gas leak) or may prolong for days (fire, leak, water pollution etc.)
RESCUE PHASE The rescue starts immediately after the impact phase and continues until necessary measures are taken to rush help and combat with the situation. The responsibilities assigned to each of the co-ordinators in organisation structure will be performed by them. Needless to emphasise that prompt and well organised rescue operations can save valuable lives.
7 RELIEF PHASE In this phase, apart from organising relief measures internally, depending on severity of the disaster, external help should also be summoned to provide relief i measures (like evacuations to a safe place and providing medical help, food, clothing etc.). This phase will continue till normalcy is restored.
REHABILITATION PHASE This is the final and longest phase. It includes rebuilding damaged property, estimating the damages, payment of compensation, etc. Help from revenue/insurance authorities need to be obtained to assess the damage, quantum of compensation to be paid etc.
DISASTER MANAGEMENT An applied science consisting of a continuing process of systematic observation, analysis and dissemination that allows for the conscious structuring of a series of events or conditions, by the timely and informed application of resources.
PHASES OF DISASTER MANAGEMENT: Before the emergency : Preparatory action which include identification of specific hazards and area of vulnerability, adoption of mitigatory steps, setting up of response facilities education of communities, conducting of simulated training exercise etc.
During the emergency : It is the implementation of the operational plan to reduce casualties and damage to property.
After emergency: It is phase that involve restoring normalcy and assessing the damage. It is also necessary to carry out investigation of the causes of the accident to avoid repetition of similar occurrences.
8 ABBREVIATIONS
CCG : Central Crisis Group SCG : State Crisis Group LCG : Local Crisis Group MAH : Major Accident Hazard MCL : Maximum Credible Loss MSD : Mumbai Suburban District MSDS : Material Safety Data Sheet DCG : District Crisis Group ECC : Emergency Control Center CMG : Crisis Management Group MARG : Mutual Aid Response Group BMC : Brihanmumbai Municipal Corporation MFB : Mumbai Fire Brigade MTNL : Mahanagar Telephone Nigam Ltd. MSRTC: Maharashtra State Road Trasport MSEB : Maharashtra State Electricity Board MPCB : Maharashtra Pollution Control Board DISH : Directorate Industrial Safety & Health PWD : Public Works Department NGO : Non Governmental Organisation RTO : Regional Transport Authority DCP : Deputy Commissioner of Police MECR : Main Emergency Control Room SECR : Site Emergency Control Room CEC : Chief Emergency Coordinator OEC : Onsite Emergency Coordinator
9 CHAPTER 4: USER GUIDE
This manual is a documentation of various measures to be taken in case of a offsite major emergency or a disaster. This serves as a guideline for activities to be undertaken in case of a major emergency or a disaster in the Mumbai Suburban District.
The purpose of this plan is to describe the activities to be carried out in case of a major emergency or a disaster, assist concerned agencies in planning for hazardous materials incidents and to serve as a guide & training aid . This plan is developed for the Govt. agencies and the industries to help them in understanding their roles incase of an emergency.
This Manual details the responsibilities of various agencies, mobilisation of resources and emergency handling for offsite disaster. The emergencies arising out of industrial activities and emergencies while transporting of hazardous material by pipeline, road/ rail enroute / transit in Mumbai Suburban district only are considered for the purpose of this manual .
This plan will apply to only following emergency scenario.
• Release of toxic / flammable material, both liquid & gases • Explosion / Fire
WHO SHOULD READ THIS PLAN ? This plan is developed basically for the agencies under the Govt. to make them understand their roles incase of an emergency. Also the crisis groups and the industries are expected to be clear in their roles and relationship concerning Disaster.
WHEN THIS PLAN TO BE USED ? This plan should be used for pre-incident planning and disaster. It should be used for guidance and clarification, where particular agency has a responsibility. For the catastrophic emergency this plan shall be used in conjunction with City and state crisis management plan
ACTIVATION OF THE PLAN It is generally accepted that the "WORST CASE" scenario has the remotest of occurrence. Therefore, we need to direct resource towards the control of incidents, which could realistically occur. According, Maximum Credible Loss (MCL) scenarios can effectively manage lesser hazardous incidents. A~ soon as there is fire, explosion of toxic gas release, the incident will be handled by the industrial unit concerned in accordance with the "On-Site plan. In the event of the emergency escalating into a major incident extending beyond the unit premises,
10 the offsite disaster management plan will come into effect. The plan comes into operation as soon as a responsible person of the Major Hazard Unit covered under the plan triggers the initial alert action regarding Offsite emergency plan when an emergency arises beyond the resource of the concerned unit.
DISTRIBUTION This plan shall be distributed to the concerned government agencies, members of the District Crisis Group, local Crisis Group and the concerned industries.
AMENDMENTS Any changes required to be incorporated shall be submitted in the given format. The suggested changes shall be incorporated in the manual upon approval.
11 CHAPTER 5: INITIAL NOTIFICATION AND EMERGENCY CONTROL CENTRES ______The plan will be activated upon information of incidents of following nature:
• Fire and / or explosion • Release of hazardous material and / or waste • Any emergency situation that could impact human and safety and / and or the environment.
INCIDENT DISCOVERY :
IN CASE OF EMERGENCY • Dial 100 / 101 immediately • Give you name, location, and concise description of the emergency (e.g. fire, personal injury, toxic gas release etc.) • Notify / alert the personnel in the immediate area of danger. • If personal Safety and health is not assured, do not attempt to enter the site • By this time the emergency response team will reach the site.
KEY CONTACT NUMBERS • Police Control Room 100 • Mumbai Fire Brigade 101 • DCG Control Room • MCGM Control Room 1916 • Municipal Commissioner's Office 2270 4403, 2269 4725 • Mumbai Suburban District Collector’s office 2655 6808 • SCG Control Room 2202 7990
NOTIFICATION : During an emergency, the command poster the first responder at site shall notify the emergency control center severity of incident. Accordingly the ECC shall deploy resource to manage the incident. After that ECC shall issue all the internal an external notification to various agencies and shall send the call out that are contingent on the nature of the incident.
EMERGENCY CONTROL CENTRES
MAIN EMERGENCY CONTROL ROOM (MECR)
The Main Emergency Control Room (MECR) will be located at Central Control Room, Municipal Corporation Office, VT area. It is from the MECR that all operations to handle emergency will directed and coordinated. The MECR is
12 mobilized by the control room duty operator when required, by calling out the Chief Emergency Coordinator and Key Personnel
ACTION OF MECR 1. Chief Emergency Co-ordinator (CEC) to assume control. 2. Ensure that all information relating to situation is received .to ascertain • What is the status of emergency • What action the factory management has taken • Is evacuation required If Yes how will this be carried out 3. Additionally alert as necessary • Hospital authorities Transport department • Railways • Electric Supply Authorities • Revenue Department • Telephone Department • Pollution control board • Bombay Port Trust • Any Other department 4. The group of key personnel to meet and evaluate the situation plan the phases of emergency procedure ie • Phase I Immediate Response Rescue of survivors and safety of personnel is the primary' consideration. • Phase II Containment Mobilisation of resources to contain the situation is the main concern. • Phase III Control and repair Plan to regain control of the situation. 5. Provide immediate advice to SCR as to how to tackle the situation what assistance is being mobilised what are the plans for evacuation, if any.
SITE EMERGENCY CONTROL ROOM (SECR) The Site Emergency Control Room (SCR) will be set up at any suitable point close to the scene of emergency assessment of the status of emergency steps required to fight the emergency and the type of assistance required will be the areas of primary concern.
ACTION AT SCR • OEC to assume command. • Ensure that all key agencies are called in. • Ensure that al information relating to situation is received . • Assess the type of assistance required and inform MECR. • Report to MECR the status of emergency at regular intervals. • Keep a running record of events major decisions and steps taken o meet the emergency. ACTION AT SCENE
13 • Respond to emergency in accordance with the Factory's own contingency plan. • OEC Should ensure that the following are notified immediately o MECR o Police o Fire Brigade
14 CHAPTER 6: RISK POTENTIAL AND GEOGRAPHICAL FEATURES OF MUMBAI SUBURBAN DISTRICT ______
ASESSMENT OF RISK: The potential for a major emergency as a result of fire, explosion and release of chemical substances and the possible consequences at each of the Major Accident Hazard Unit has been mentioned in the Chemical Fact Sheets as part of Annexure I. Also the details of offsite pipelines with these units carrying hazardous material is covered separately as part of Annexure II. The list of major accident hazard units and details of offsite pipelines passing through Mumbai Suburban Distrct carrying hazardous material is given below
LIST OF MAJOR ACCIDENT HAZARD UNIT FACTORIES IN MUMBAI SUBURBAN DISTRICT
SR. NO. NAME & ADDRESS OF FACTORY 1. Aegis Chemical Industries Ltd., Plot No. 72, Mahul Village, Trombay, Mumbai – 400 074. 2. Bharat Petroleum Corporation Ltd., (Mumbai Refinery) Mahul, Chembur, Mumbai – 400 704 3. Bhandup Complex water Treatment plant Brihan Mumbai Mahanagarpalika, Khindipada, Darag Raod, Mulund, (W), Mumbai-400082 4. Chemical Terminal Trombay Ltd. Pirpau Installation, Near MbPT Pump House Behind Tata Electric Company Trombay, Mumhai 400 074 5. Hindustan Petroleum Corporation Ltd., (Refinery) Corridor Rd., Mahul, Chembur, Mumbai - 400 074. 6. Hindustan Petroleum Corporation Ltd., Mahul Terminal Corridor road, Chembur, Mumbai - 400 074. 7. Hindustan Petroleum Corporation Ltd., Mahul LPG Filling Plant, L U Gadkari Marg, Chembur, Mumbai - 400 074 8. Mahindra & Mahindra Ltd., (Automotive division). Akurii Road, Kandivali. (E), Mumbai-400101. 9. Mahindra & Mahindra Ltd., (Tractor Division) Akurii Road, Kandivali (E),
15 Mumbai-400101. 10. Parle Products Ltd., Vile Parle (E), Mumbai - 400 057. 11. Rashtriya Chemical and Fertilizers Ltd., Trombay Unit, Chembur, Mumbai - 400 074. 12. Sanuj Steels Private Limited, D R Container Yard, Jijamata Nagar, Mahul Road, Chembur, Mumbai – 74 13 Hindustan Petroleum Corporation Ltd., Aviation Fuel Station, Chchatrapati Shivaji International Airport, Sahar, Mumbai 14 Indian Oil Copr Ltd, Aviation Fuel Station, Chchatrapati Shivaji International Airport, Sahar, Mumbai 15 Sea Lord Containers Limited Ambapada, Mahul Village, near BPCL Refinery, Chembur, Mumbai -74
LIST OF OFFSITE PIPELINES CARRYING HAZARDOUS MATERIAL IN MUMBAI SUBURBAN DISTRICT
SR. No. NAME OF FACTORY HAZARDOUS MATERIAL
1. Aegis Chemical Industries Ltd., Petrochemicals / POL Products LPG /Propane 2. Bharat Petroleum Corporation High Speed Diesel Ltd., Refinery (MMPL) Motor Spirit Superior Kerosene 3. Gas Authority of India Ltd Natural Gas
4. Hindustan Petroleum Corporation Aviation Turbine fuel Ltd., Refinery (MPPL) High Speed Diesel Motor Spirit Superior Kerosene Furnace oil / Light diesel oil 5. Indian Petrochemicals Corpn. Ltd Propane
6. Mahanagar Gas Ltd Natural GAS
8. Rashtriya Chemical and Fertilizers Natural Gas Ltd., 9. Reliance Industrial Infrastructure Naphtha / Kerosene Ltd 10. Tata Power Company Pvt. Ltd. Natural Gas
16
GEOGRAPHICAL FEATURES Mumbai Suburban District which is one of the revenue district of Greater Mumbai Metropolitan area or BrihamnMumbai Municipal Corporation (BMC).lt covers an area of 370sqkm The district consist of one administrative subdivision comprising three tahsils ie Kurla.Borivaliand AndheriThe distrcit covers 14 municipal wards of BMC and is also referred as Eastern Suburbs and western suburbs .
SALIENT PHYSICAL FEATURES AND LAND USE PATTERNS
Land Use Area in Sq km and Percentage
Inhabited area 277.5 (75%)
Agricultural area (5%)
Industrial area 41.0 (11.69%)
Forest Cover 33.0 (8.31%)
Waste Land Nil
Total 370 Sq km
CLIMATE & RAIN FALL The details about climate and rainfall in Mumbai Suburban District as recorded at Santacruz gauge station of India Meteorological Department are as under:
The climate of the Mumbai Suburban District is tropical maritime. The daily maximum temperature (mean) range from 29.1 c in August to 33.3 c in the month of April. Daily minimum temperature (mean) range from 16.3 c in January to 26.2 c in May. The average annual rainfall of this district based on last 30 years data is 2457.0 mts. The district receives an average seasonal rainfall of 2363.0 mm during June -September. The average monthly rainfall is highest in the month of July (945.4 mm) followed by August (660.4mm). The monthly rainfall in June is 647.5 mm and 309.2 mm in September.
TERRAIN AND CLIMATIC CHARACTERISTICS.: Terrain and climatic characteristic of the district are useful understand the precipitation and flood potential of the region. If the district exhibits varying oi differing terrain and collimation characteristics, the you make additional copies o1 the template and fill the requested information.
Area (in sq.Kms) 370
17 Climate Tropical Temperature in Celsius Maximum 31.7 Minimum 22.1
Rainfall 2422.1 Total Annual Rainfall (mm) 201.8 Maximum Rain fall (mm) 3784.9 (1958 AD) Months during which maximum rainfall occurs. June & July # Months having maximum Continuous Rainfall June574.1 August 553.0 (mm) July 868.3 September Predominant Soil Cover Whether. Sandy, alluvial Alluvial & Loamy loamy etc: Land Use Patterns-All in Sq. Kms. 370 Inhabited area Agricultural area 277.5 75% Industrial area 18.5 5% Forest cover 41.0 11.69% Wastelands 33. 8.31% Drought prone areas Nil
FLOOD ASSESSMENT Sr. Name of the Flooding Location and Corresponding No. River frequency over Extent of Area Estimated Flood years Inundated Damage in Rs. (worst case in Sq. Kms.
1. Mithi River } Only in rainy 15 -
2. Dahisar River } Season 5 -
INDUSTRY RELATED INFORMATION
Number of Industrial Estates
Types of Industries Refineries, Chemicals & Fertilisers, Eletric companies Engg, printing, garments, plastic.etc
Total work force in industries 2,82,062
Number of chemical industries / tank 338 farms
18 Number of Pipelines carrying chemicals 29
Number of potentially hazardous 21 locations
Number of potentially hazardous raw materials for industries (during a month) 502
Number of vehicles carrying hazardous 27,599 finished products from industries (during Information not received More a month) details are given separately Number of vehicles passing through the district carrying hazardous materials for as per comments. industries (during a month)
Number of container terminals 2
No. of Industries in the estate 336
No. of Major Hazardous and Polluting 15 Industries
Total work force in industries 38,056
19 POPULATION CHARACTERISTICS
Sr. Name of the Urban Population Population Density No. Center
1. Nirmal Nagar 2,50,000 Mixed & Thickly populated
2. Kherwadi 3,50,000 -do-
3. Vakola 3,50,000 -do-
4. Vile-Parle 2,00,000 -do-
5. Kurla 7,00,000 -do-
6. Nehru Nagar 4,00,000 -do-
7. Tilak Nagar 3,13,440 -do-
8. Trombay 4,00,000 -do-
9. Deonar 2,50,000 -do-
10. Shivaji Nagar 4,00,000 -do-
11. Chembur 3,00,000 -do-
12. R.C.F. 3,50,000 -do-
13. Ghatkopar 9,00,000 -do-
14. Park Site 3,50,000 -do-
15. Vikhroli 4,00,000 -do-
16. Pant Nagar 6,00,000 -do-
17. Kanjur Marg 1,50,000 -do-
18. Mulund 3,87,000 -do-
20 19. Bhandup 8,00,000 -do-
20. Sahar 75,000 -do-
21. Air Port 12,000 -do-
22. Bandra 2,05,000 -do-
23. Khar 5,30,000 -do-
24. Santacruz 7,17,765 -do-
25. Juhu 1,18,232 -do-
26. D. N. Nagar 4,00,000 -do-
27. Oshiwara 5,00,000 -do-
28. Andheri 3,75,000 -do-
29. Sakinaka 5,50,000 -do-
30. M.I.D.C. 2,50,000 -do-
31. Jogeshwari 1,25,000 -do-
32. Meghwadi 4,00,000 -do-
33. Goregaon 5,50,000 -do-
34. Aarey Sub. 80,000 -do-
35. Dindoshi 12,00,000 -do-
36. Malad 8,00,000 -do-
37. Malvani 5,00,000 -do-
38. Kandivli 3,57,000 -do-
39. Samta Nagar 5,50,000 -do-
21 40. Borivli 6,00,000 -do-
41. Kastura Marg 4,00,000 -do-
42. Dahisar 6,00,000 -do-
SEASONAL MIGRATION Purpose Area (specify Period (Calendar Estimated population Talukas) Months) in/out migration
Salt Bhandup Taluka- May 680 Manufacture Kurla Trombay }Trombay }
HISTORICAL AND RELIGIOUS CENTRES Name of the Historical and Periods of Festive Estimated tourists or Religious centre and nearest Occasions. Months visiting population Urban or Major Rural Centre listed above
1. Mount Mary Temple Bandra 10 days in the 8,00,000 (West) month of September 2. Pandavkalin Gurnfa Majas 1 Day for 3,33,000 Village, Jogeshwari (E) Mahashivratri 3. Madh Devi Festval Madh, 1 day 50,000 Andheri (West) 4. Kaneri Caves Borivali (East) Daily 5,00,000 Yearly Daily 5. National Park Borivli (East) Daily 10,00,000 Yearly
6. Mandpeshwar Gumfa Daily 36,500 Yearly
22 CHAPTER 7 ORGANISATION FOR DISASTER MANAGEMENT, VARIOUS AGENCIES REQUIRED TO COMBAT A DISASTER
A. MUNICIPAL CORPORATION OF GREATER MUMBAI 1. Mumbai Fire Brigade 2. Municipal Medical Services 3. Hydraulic / Water Department 4. Transport Department E. E. T. (City / Suburbs) 5. B.E.S.T 6. Conservancy Service 7. Municipal Security Service 8. Equipment Manufactures 9. Health Department B. STATE GOVERNMENT SERVICE 1. Mumbai Police / Traffic Control 2. B. S. E. S. Co. Ltd. 3. Maharashtra State Road Transport Corporation 4. Public Health 5. State Civic Supply Department 6. Public Relations and Publicity 7. Communication Department 8. Public Works Department 9. Home Guards and Civil Defense 10. Equipment Manufacturers 11. Directorate of Industrial Safety & Health 12. Maharashtra Pollution Control Board C. CENTRAL GOVERNMENT 1. Defence service (Army, Navy & Airforce) 2. Publicity & Public awareness (Doordarshan, Akashwani, Newspaper) 3. M. N. T. Ltd. / Telecommunication Department 4. Railways (Central / Western) 5. Aviation Department 6. Post & Telegraph 7. Mumbai Port Trust - Coastal Guard 8. Medical Aids 9. Equipment Manufacturers 10. Controller of Explosives
D. PRIVATE AGENCIES 1. Private Ambulance Service 2. Private Transport Organisations - Tankers / Trucks / Lorries/ Terr Buses/Jeeps, etc.,
23 3. Indian Oxygen Co., / Mumbai Oxygen for Medicated Oxygen. 4. Labour Contractors 5. Private suppliers of various materials 6. Tata Power House / Companies. E. MUTUAL AID RESPONSE GROUPS (MARG)
24
25
26
27
28 DISTRICT CRISIS GROUP- MUMBAI SUBURBAN DISTRICT.
District Collector 2589 6160 Prashasakiva Bhavan, 10'h 2655 6806 Floor, Kala Nagar, Bandra (E)., Mumbai. Directorate of 2265 2558 Jt Director, Directorate Industrial 2265 2522 of Industrial Safety & Safety & Health 2265 2504 Health, Kamgar Bhavan, 2655 2509 Block E, Bandra Kurla Complex, Mumbai-51.
Dy Director, Directorate of Industrial Safety & Health, Kamgar Bhavan, Block E, Bandra Kurla Complex, Mumbai-51. District Energy 2647 2131 Chief Engg. (Gen) Officer 2642 2211 Environment Health & safety, M.S.E.B. Parkash Gad, Plot No. G-9, Prof, Anant Kanekar Marg, Bandra (E), Mumbai – 55
2610 0505 Electricity House, 3009 6999 Sanatacruz (E) Mumbai-55
4) Chief Fire 2307 6111 / 3 Chief Fire Officer, Officer 23074923 Municipal E Ward Office Shaikh Haffijuddin Marg, Byculla, Mumbai-88 District Information 2202 7956 Dy. Director (News) officer Officer 2202 3472 of director General of information & Public Relations, Got. Of Maharashtra Mantralya, Mumbai - 400 032
Controller of 2757 5946 Dy. Chief Controller of Explosives Explosives, West circle Mumbai A-1/A-2 wign, 5'h fir. C.G.O. Complex, CBD Belapur, Navi Mumbai-400 614
29 Chief of Civil 2261 0088 Controller of Civil Defence, Defense 2261 4092 3rd Flr, Shri Chatrapati Shivaji Maharaja Market, Mata Rarnab Ambedkar Marg, Mumhai — 400001 One Representative 2418 1742 President Petroleum of Trade Unions Workers Union, 773, Tel Rasayan Bhavan Tilak Road, Opp. BEST workshop, Dadar (East), Mumbai – 400 014 Deputy 2497 6960 C.P. Zone V, Tilak Nagar Superintendent of Police Station Bldg., 2nd Police Floor, Chembur, Mumbai – 400 089 Representative of 2262 0025 Chief Hydraulic Egnn. M. Department of 2262 0251 C.G. M. Head Quarter, Public health Engg. Mahapalika, Marg, Mumbai 2300 4721 Dy. Chief Engg. 2nd Floor 2306 1279 Engg. Services & project Municipal Bldgs, Near Byculla Cement Godown Bldg., N. M. Joshi Marg, Mumbai – 400 011 Representative of 2757 2740 Regional Officer MPCB pollution Controller 2492 3462 Regional Office 7th floor Board. Raigad Bhavan CBD Belapur, Navi Mumbai Four Experts in Expert on LPG Shri Rakesh Gupta Industrial Safety & 922 322 2429 Plant Manager. health to be 2554 2280 HPCL BDU Filling Plant,l nominated by Mumbai – 400 074 District Collector Experts on Ammonia Shri P.B.Asai, DGM(Tech. RCF, Methyle amines Ser) etc. Shri C.M.Bisen ,CE(Safety 2552 2347/ 2552 & Fire) 2265 R.C.F. Ltd. Chembur, 9987036436 Mumbai – 400 074
Experts on chlorine Shri Raghunanadan Singh
30 922 336 9431 Dy G. M. - OPerations 6717 5511 Tata Power Company Trombay Thermal Power Station, Chembur, Mumbai – 400 074 Expert of Chemicals. Shri Dilip Bheda 25541463 M/s Aegis Chemicals Inds 986 702 6221 Ltd, Mahul, Mumbai – 400 074 Commissioner of 2492 4734 Dy. Commissioner of Police Transport (Traffic) Traffic Police One Representative 2554 6434 Director (Refineries), of Industry BPCL Refinery, Mahul Road, Chembur, Mumbai – 400 074 Chairperson / 2651 3744 Additional Collector & Member Chairperson Local Crisis Secretary of Local Group, MMRDA Bldg, Crisis Group Bandra Kurla Complex, Bandra (E), Mumbai – 400 005
Dy. Collector & Chairperson M.S.D. 2nd Flr., MMRDA Bldg., Bandra Kurla Complex, Bandra (E), Mumbai – 400 005
2352 2230 / 1 / 2 Dy. Director & Member Secretary L.C.G. 5th flr. Commerce Center, 2352 2230 / 1 / 2 Tardeo, Mumbai. Dy. Director & Member Secretary of Kurla Mulund Local Crisis Group 5th Flr., Commerce Center Tardeo, Mumbai
31 LOCAL CRISIS GROUP
TROMBAY – CHEMBUR AREA Sub Divisional Chair Person Additional Collector, Magistrate / District Mumbai Suburban Emergency Authority District, Bandra, Mumbai
Inspector of Factories Member Secretary Dy. Director Industrial Safety & Health.
Industries in the Member MAH Factories in District / Indurstrial Chembur Area area / industrial pocket
Transporters of Member K. Transports, 11 hazardous chemicals (2 Majithia Ind. Estate, numbers) Near Dukes factory, Deonar, Chembur, Mumbai – 88
Pella Roadways, Opp. HPCL Refinery, Gowanpada Village, Chembur, Mumbai 74
Fire Officer Member Fire Officer Chembur, Mumbai – 74
Station house Officer Member Assistant (Police) commissioner of Police Basant Park Chembur,Mumbai– 74
Block Development Member M – Ward Officer 12th Officer Road, BMC Office, Mumbai-74
One Representative of Member Area co-ordinator for Civil Defense chembur Civil Staff College. Dhobitalao, Nr. Metro Cinema, Mumbai – 01
32 Primary Health Officer Member Medical Officer, Sion Hospital, Mumbai
Editor of local news Member Editor of Mid Day, paper tardeo, Mumbai – 34
Community leader / Member Municipal Corporator sarpanch / village of Chembur pradhan nominated by Chair person
One representative of Member Chairman, Mutual aid nos Government response Group Organisation to be nominated by the chair person
Two Doctors eminent in Member 1) Dr. S.V. Ingale, Chembur 2) Dr. V.C. Salvi, , Chambur
Two social workers to Member be nominated by the chair person
33 LOCAL CRISIS GROUP
KURLA – MULUND AREA Sub Divisional Chair Person Dy. Collector, Magistrate / District Emergency Authoriity Mumbai Suburban District, Bandra (E), Mumbai
Inspector of Factories Member Secretary Dy. Director,
Industrial Safety & Health, Mumbai
Industries in the Member Brihanmumbai District / Industrial Mahanagarpalika, Bhandup area / industrial pocket Complex, Water Treatment Plant, Bhandup
Empire Industries Ltd., (Vitrum Glass), Vikhroli (W), L.B.S. Marg
Techno Product P. Ltd., Opp. Jari Mari Pipe Line, Near St. Jude’s School Andheri Kurla Rd.
Larsen & Tourbro Ltd. (West), Saki Vihar Road, Powai.
Transporters of Member hazardous Chemicals(2 numbers)
Fire Officer Member Station Fire Officer, Mulund Fire Station, Mulund
Station fire Officer, Vikhroli, Fire Station, Vikhroli
Station House Officer Member Dy. Commissioner of Police (Police) Parimandal – 6, Mulund
Dy. Commissioner of Police, Kurla
34 Block Development Member Ward Officer of Bhandup, Officer Mulund, Vikhroli, Ghatkopar, Kurla
One Representative of Minister Dy. Controller of Civil Civil Defence Defence, S. V. Road, Andheri (W)
Primary Health Officer Member Medical Superitendent of
Sarvodaya Hospital , Ghatkopar, Ph :
E.S.I.C. Hospital, Mulund
Mulund General Hospital, Mulund
Editor of Local News Member Editor – Mid Day, Tardeo, Paper Mumbai – 34
Editor – Mahanagar, Mahim
Community leader / Member Corporators of Bhandup, Sarpanch / Village Mulund, Vikhroli, Ghatkopar Pradhan nominated by and Kurla area. Chair-person
One Representative of Member Co-ordinator, Non-Government Bhandup Mulund Mutual Aid
Organisation to be Response Group nominated by the Chairperson
35 Two Doctors eminent in Member the Local Area, to be nominated by Chair- person
Two Social Workers to Member be nominated by the Chairperson
LOCAL CRISIS GROUP
BANDRA - DAHISAR AREA Sub Divisional Chair Person Dy. Collector, Mumbai Magistrate / District Suburban District, Emergency Authoriity Bandra (E), Mumbai
Inspector of Factories Member Secretary Dy. Director, Industrial Safety & Health, Kandivli
Industries in the Member Director, Mahindra & District / Industrial Mahindra Ltd., (Jeep, area / industrial pocket Plant)
Director, Specials Steels Ltd., Borivali
Director, Parle Products Ltd., Vile Parle
Director, Borosil Glass Works, Marol Maroshi Road, Andheri (E)
Director, Mahindra & Mahindra Ltd., (Tractor Division)
Times of India Ltd., Suburban Press Kandivali
36 Transporters of Member hazardous Chemicals(2 numbers)
Fire Officer Member Dy. Fire Officer, Western Zone, Marol, Andheri (East), Ph. : 821 0940
Station Officer S.V. Road, Kandivali (W)
Station House Officer Member Asst. Commissioner of (Police) Police, S. V. Road, Kandivali (W)
Block Development Member Ward Officer Kandivali Officer (East) & (West)
Ward Officer, Kandivali (East)
One Representative of Minister Dy. Controller of Civil Civil Defence Defence, Area IV, Andheri Fire Station Compd, S. V. Road, Andheri (W)
Primary Health Officer Member Medical Superitendent of Cooper Hospital, Andheri, Ph. 6207254
Bhagawati Hospital, Borivali Ph : 8662461
ESIC Hospital, Kandivali Ph – 8877764
Editor of Local News Member Editor – Mid Day, Paper Sarvoday Mill Compd., Tardeo, Mumbai – 34
Editor – Mahanagar, Mahim
37 Community leader / Member Corporators, Borivali Sarpanch / Village (E) Pradhan nominated by Chair-person Corporators, kandivali (E)
Corporators, Andheri (E)
Corporators, Parle (E)
One Representative of Member Chairman, Mulund Aid Non-Government Response Group
Organisation to be nominated by the Chairperson
Two Doctors eminent in Member Dr. Bodhankar A. N., the Local Area, to be Connected with nominated by Chair- Industrial Health. person 701, Blue Bird, ‘C’, Opp. Rizvi College, Bandra (W), Ph 6494208
Dr. Yadav, Connected with Industrial health, Shree, 18/6, Pushtikar Society, Jogeshwari (W), Ph : 26247254
Two Social Workers to Member President, Lion Club be nominated by the of Marol, Andheri, Chairperson Kurla Road, Andheri (E), Mumbai – 59 Ph : 8326435
President, Rotary Club of India, Andheri (E), Ph – 8360048
MUTUAL AID RESPONSE GROUPS IN MUMBAI SUBURBAN DISTRICT
38
1. Mutual Aid Response Group Trombay Chembur Area
2. Mutual Aid Response Group Bhandup – Mulund Area
3. Mutual Aid Response Group Kurla – Ghatkopar – Vikhroli Area
4. Mutual Aid Response Group Bandra – Dahisar Area
39 CHAPTER 8: ROLES & RESPONSIBILITIES OF EMERGENCY COORDINATORS AND KEY AGENCIES ______
CRISIS MANEGMENT GROUP (CMG) This is the apex body for crisis management
• Municipal Commissioner of Mumbai • Commissioner of Police • Chief Executive Health Dept, BMC • Joint Director, Industrial Safety & Health, • Chief Fire Officer, Mumbai Fire Brigade • Additional Controller, Civil Defense • Public Relations Officer • Member Secretary, Pollution Control Board • City Engineer of BMC • Co-ordinator Mutual Aid & Response Group, • RTO Mumbai
The chairman of CMG may co-opt any other officer depending upon the situation, for each member of the CMG there is an alternate member. The telephone number and address of each member are given in the list.
The tasks of the CMG are as under :
• To exercise board control over emergency operations • To give guidance on matter of basic policy • To provide official information and instruction to the public • During normal times review the operational preparedness and take appropriate measures to rectify the defects • To co-ordinate inter zone emergency response
FIRST RESPONDER ON SCENE : The first senior official responding to an Emergency is the incident Controller and begins implementing the incident control system. All emergency responders and their communications are co-ordinated and controlled through the incident controller. As more senior official arrive the position of incident controller is passed up a previously established line of authority.
The first responder at the scene of a hazardous materials emergency should complete the task necessary to protect public health and responder safety, the environment, and the property. The order in which the following tasks are completed is incident priorities.
40 • Evaluate potential hazards to determine if the release or threaten release is an emergency. • Isolate the Scene and deny entry. • Establish control zones. • Identify spilled material or threatened release without subjecting responders to contamination. • Look for any casualties and identify other essential site conditions. • Implement Incident Command System, establishes a command post, and identifies a staging area for incoming resources. • Identify additional resources for operations beyond the capability of on- scene units. • Notify appropriate response and reporting agencies. • Designate a knowledgeable safety officer prior to engaging in operational activities. • Rescue victims from the hot zone using appropriate personal protective equipment. • Provide emergency decontamination to victims exposed to material having the potential for secondary contamination of emergency medical, personnel. • Determine necessary public protection action (evacuation or sheltering in place) • Initiate control and containment within capabilities of available resources and equipment
CHIEF EMERGENCY COORDINATOR (CEC) The Municipal Commissioner will be the Chief Emergency Coordinator (CEC) and will take over control room at MECR and will remain in command.
The first key person arriving at MECR will assume the responsibilities of the post till the arrival of the CEC. His responsibilities will be as follows :-
Immediately on being aware of the emergency the key person will proceed to MECR. On reaching he will, -
• Assume responsibilities of the post pending the arrival of CEC. • Ensure that key personnel have been called in. • Establish contact with SCR and assess the extent of emergency. • Keep a running record of development and information received from SCR. • Report all significant developments to the CEC on his arrival
Note : The above responsibilities will be discharged by the next senior key person on arrival at MECR and taking over charge so that pending the arrival of CEC the senior most key person present at MECR shoulders the responsibilities for overall main control.
41 RESPONSIBILITIES OF CEC Immediately on being a ware of the emergency CEC will proceed to MECR. On reaching, he will-
• Assume full responsibility for overall control • Assess extent of the emergency and likely development organise action in the following areas : • Immediate advise to OCE as to how to control the situation • Assistance in case of complete or partial evacuation if necessary. • Assistance in case of the evacuation if necessary. • Provision of equipment, material ad manpower etc tot control the situation. • Ensure that causalities and receiving adequate attention. • Ensure that all personnel at the factory are accounted for. • Arrange search and rescue of missing persons. • Arrange for a chronological record of the emergency to be maintained • Where the emergency is prolonged arrange for replacement of personnel and provision of catering facilities. • Authorise information to be given to media. • Ensure that proper consideration is given to the preservation of evidence. • Control rehabilitation of affected areas on cessation of emergency.
ONSITE EMERGENCY COORDINATOR (OEC) : At the scene of emergency the person notified under the contingency plan of the affected factory will take up the responsibilities of Onsite Emergency Coordinator (OEC) and will remain in command at the site control room.
A Primary task of the OEC is to go to the scene of the emergency make an informal assessment of the situation and decide whether a major emergency exists or is likely to develop soon. On his decision he will inform the CEC and activate the emergency procedure
RESPONSIBILITIES OF OEC :
• Immediately on being aware that a major emergency exist at the factory :- • He should ensure that the concerned agencies are notified in the prescribed manner • He will coordinate on scene emergency action as per in-house contingency plan. • He will proceed to SCR and assume responsibilities of the post and remain in command • He will keep MECR informed from time to time on – • Steps taken to fight the emergency. • Status of emergency at the time of reporting • Further actions necessary.
42
ROLE OF DISTICT COLLECTOR MUMBAI SUBURBAN DISTRICT • Exercise broad control on emergency operations • Give guidance / decision on measures of basic policy • Review operational preparedness of district emergency machinery • Hold periodic mock up / training exercise to ensure optimum operational preparedness. If necessary, invoke help from the Army, the Air Force, the Government and any private industries in the are of MSD. • Develop off-site scenarios based on-site Plans of the industries. • Relief Operation • o-ordination of all Local crisis Groups of the District • Act as Chief Controlling Authority of District Emergency plan. • Mobilise / Requisition / Pulling Together resources to Tackle emergencies. • Establish relationship between District Emergency plan (Crisis Group) and State Crisis Group. • To requisite the resource available from the public works departments • Assessing the requirements for transit cams on the occurance of disaster. • Assisting the ward officer in requisitioning vehicles and temporary shelters. • Setting up of transit camps and pandals of temporary accommodation. • Arranging for food distribution. • Arrangement for clothing • Providing gratuitous relief. • Enlist support of NGOs and private sector for resources and manpower for transit camps • Communicate to district control room details on the field activities including development and reinforcement of staff and resourced of staff and resourced of staff and resources and communicate nature and additional requirements.
RESIDENT DEPUTY COLLECTOR – MUMBAI SUBURBAN DISTRICT
• Acts as an Alternate leader, Liaison Officer, Agency Chief, in disaster. • Check in at the incident command post. Ensure that all agency resources have completed check-in. • Obtain briefing from liaison officer or incident controller. • Establish working location. Advise agency personnel on the incident that the agency representative position has been filled. • Attend planning meeting as required • Provide input on use of agency resources if no resources use advisors are assigned. • Co-operate fully with incident commander and general staff on agency’s involvement at the incident. • Overseas the well being and Safety of agency personnel assigned
43 • Advise liaison officer of any special agency need or requirements. • Determine, if any special reports or documents are require. • Report to agency dispatch or headquarters on prearranged. • Ensure that all agency personnel and / or equipment is properly accounted for and released departure from the incident. • Give debriefing session with liaison officer commander prior to departure.
POLICE :
LAW & ORDER • Maintenance of Law and order and control of anti social element. • Cordoning off the area to restrict movement of onlookers, vehicular and pedestrian traffic. • Shifting of injured to the hospitals on a priority and providing bandobast for crowd control at the hospital. • Guarding of property / valuables in affected area • Providing easy access to rescue and relief personnel / vehicles • Ensuring proper identification, inquest procedure and corpse disposal • Panchanamas will be prepared as per procedure • Extensive mobile patrolling • Arrangement for transporting / shifting of standard or affected persons through police vehicles and private vehicles • Use of public address system to provide information to the public Sign boards may be used to provide information and declare areas out of bounds • Enlist support of Mohalla committees for maintaining peace and for rumour control. • Information center to organize sharing of information with mass media and community • Communicate to police control room details on the field activities including deployment and reinforcement of staff and resources and communicate nature of additional requirements.
TRAFFIC • Control and monitor traffic • Diversion of traffic on alternate routes as and when necessary. • Provide information about traffic flow along various corridor especially heavy traffic or congested roads. • Mobilisation towing cranes and towing of standard breakdown or those vehicles obstructing movements. • Use PA system to provide information and direction to the public • Setting up of sign boards and display boards at strategic locations to give information regarding traffic movement. • Enlist support of RSP, NCC, NSS, NGOs and voluntary organisations for traffic management
44 • Provide and coordinate arrangements for transporting shifting of stranded or affected persons through police vehicles and private vehicles • Communicate to traffic control room details on the field activities including deployment and reinforcement of staff and resources and communicate nature of additional requirements. • Assist emergency services in the performance of their duties.
RTO • Ensure strict enforcement of regulations laid down improve safety in transportation of hazardous substances. • Organise Transportation, arrangement for evacuation. • Ensure TREMCARD is available in the tankers transporting hazardous chemicals. • Divert tankers transporting hazardous chemicals in associating with traffic police in case of disaster, Ganesh Chhaturthi / Chhaturdashi, any other festivals or Mass gathering to safer transport Route. • Train tanker drivers in respect of the hazards during the chemicals transportation in consultation with MARG.
FIRE BRIGADE
• Fire fighting operations in the affected area. • Rescue and Salvage operations. • Transport of injured to the hospitals on priority. • Evacuation of persons from the affected area . • Neutralisation and dilution of toxic environment . • Mobilisation of all fire fighting units from various Source. • Training of fire service personnel in chemical disaster operations. • Stocking of special fire fighting agents and equipment for chemical emergencies. • Adequacy of fire fighting / control measure at each industrial location. • Work out Mutual Aid Arrangement in the cluster. • Prepare Plan for Human Service required for the emergency response. • Formulate Chain of Command among the Fire Fighters. • Prepare Plan for Response Personal Safety. • Prepare Plan for Fire & Rescue. • List out of the Fire Fighters. • Communicate to fire brigade control room details on the field activities including deployment and reinforcement of staff an resources and communicate nature of additional requirements.
MEDICAL SERVICES • First aid arrangement and availability of On-site requirements of industries. • Set up mobile First Aid Posts at Assembly points
45 • Mobilization of emergency medical and health service of Causality Clearance Centers and Base Hospital • Public Health Service at. Reception Centres • Medical Supply of antidotes, special Medicine and life saving drugs. • Corpse disposal service. • Co-pt voluntary organization like Rotary Clubs and Lions Clubs • Prepare Plan for Health & medical • Training to Medical team Hospital staff for emergency response • Providing emergency treatment for the seriously injured at the hospital • Organising onsite treatment of injured with tagging and triage and transfer of injured. • Emergency supplies of medicines and first aid • Post mortem and corpse disposal • Demarcate an area in the hospital for receiving patients tagging an triage • Coordinate with blood banks for emergency supply of blood • Setting up an information centre at the hospital • Communicate to BMC control room details on the field activities including deployment and reinforcement of staff and resources and communicate nature of additional requirements.
BEST / MSTC/ RAILWAYS • Ensure availability of Buses / trains in case of evacuations. • Keep standby buses in readiness for deployment • Coordinate for transport arrangements of standard persons • Diversion of routes if necessary • Providing information to the public at bus depots regarding he cancellation rerouting delays of buses, temporary shelter locations, of BMC and the aesures being undertaken • Communicates to best control room details on the field activities including deployment and reinforcement o staff and resources and communicate nature of additional requirements.
TRANSPORT In case of Municipal Commissioner, Mumbai, takes the decision to evacuate persons of the nearby units and habitations to safer places, the services of the B.E.S.T. and M.S.R.T.C. in available number of buses at a short notice could be taken. The names and teleplone numbers are given with this note.
Vehicles can be mobilized by the Transport Commissioner, Government of Maharashtra on request.
BEST/BSES/TEC • Ensure electricity supply to all MAH units, streets, Police stations, Fire brigades, Emergency Control Centre & Other Offices of emergency Response Personnel
46 • Cutting off power supply if necessary • Alternatives arrangements for power supply for lighting • Illumination of affected area as well as the periphery • Restoration of power supply • Keeping emergency gangs in readiness for repair work • Repairs to damaged power breakdown or short circuits • Coordinating with Fire brigade in case of fires or short-circuiting • Communicate with respective control rooms details on the field activities including deployment and reinforcement of staff and resources and communicate nature of additional requirements.
EMERGENCY PLAN - COMMUNICATION SYSTEM If one were to examine closely and patiently the nature, variety and geographical sector of Chemical Industries in are in question, one would gradually perceive and visualise many problems that will simultaneously occur, should emergency arise inmost of these industrial units. Many incidents in the past 24 months have demonstrated these problems.
To meet an emergency, following a devastating fire, explosion, toxic release, corrosive spill, etc endangering community life and property, speedy response by emergency service authorities (i.e. Police, Fire, Brigade, Medical Services) is absolutely essential. Speedy emergency response by appropriate authority in good time and in correct sequence is often referred to as "first strike" is emergency parlance.
One single system on which speedy emergency response of "first strike" is critically dependent is communication.
In the area underquestion, the identified factories are communication with the Fire Brigade, Police and Medical Services by telephone system i.e. point - to - point voice communication. It is important to recognise a fundamental aspect right a t the outset that, fixed location office communication system cannot ensure speedy response by emergency services. However, we have to make optimum use oif the facilities available with us so as to reduce the time of "first Strike" as much as possible. It is seen that the hazardous factories are located in five Exchange areas i.e. Ghatkopar (2511, 512 and 513 ), Chembur (52); Powai, Vikhroli, Tagore Nagar and Kannamawar Nagar(58), Mankhurd (551, 555), Mulund (560, 561). In case of andy fault in the exchanges or instrument or any other urgent services required, the concerned Divisional Engineer can be directly contacted either at his office or at his residence at any time to seek his assistance.
In addition to the above, the important elephone Nos. Could also be identified as Emergency Numbers and the concerned Telephone Exchanges may be requested to consider the above numers as dedicated direct lines (DDL) so that, all such Telephone Numbers will be urgently tested regularly by the personnel in the Exchanges and maintained in working order at all time.
47 Considering the limitation of the point- to -point voice communication in the times of emergency, it is recommended as follows :-
• All the hazardous factories identified, should be connected by hot-line system with the concerned police stations, Fire Brigades and. Medical Institutions. • The Control Room of the Mumbai Municipal Corporation – Control Panel consisting of 32 hot-line is should also be connected by hot-lines individually to each hazardous unit so that the red light in the Control Room will give an indication of any emergency in any connected unit. • Control Room of the Mumbai Municipal Corporation should also be connected to the hot-line to police Authorities, Fire Bridge and Medical, Authorities, Evacuation agencies and various other concerned agencies so that first strike time can be reduced as much as possible. • During the time of emergency, it may be necessary to communicate with various agencies, which may be fixes / fixed, fixed / mobile and mobile / mobile units. It is therefore, suggested that special frequency mobile communication system may be worked out in consultation with the Telephone Department. CIVIL DEFENCE/HOME GUARDS To supplement the role of police and the salvage corps, additional man-power may be required and the same will be provided by Home guards Organisation There are 16 Offices of the honorary officers of the Home guards in Great Bombay. The services of the Home Guards can be utilised in case of an accident. Addresses and telephone numbers of various offices of the Horn Guards are given in this Note.
DISTRICT INFORMATION OFFICER The information officer, a member of the command staff is responsible for the formulation and release of information about the incident to the news media and other appropriate agencies and organizations.
• Obtain briefing from incident commander • Contact the jurisdiction agency to co-ordinate public information activities. • Establish single incident information center whenever possible • Arrange for necessary work space. Materials telephones, and staffing • Prepare initial information summary as soon as possible after arrival. • Obtain approval for release from incident commander • Obtain approval for release from incident commander • Release news to news media and post information in command post and other appropriate locations. • Attend meetings to update information releases. • Arrange for meeting between media and incident personnel • Provide escort service to the media and VIPS • Provide fire retardant clothing for media and VIP’S • Respond to special requests for information • Maintain and submit all records and logs.
48 DISTRICT SUPPLY OFFICER : He is responsible for detemining feeding requirements at all incident facilities, menu planning, determining cooking facilities required : and general maintenance of the food service areas.
CHIEF ENGINEER, BMC :
• Report to and obtain briefing and special instructions from RDC MSD. • Participate in the development of the Incident Action Plan, and review general control objectives including alternative strategies presently in effect. • Collect and validate water resource information within the incident actions. • Prepare information on available water resources. • Establish water requirements needed to support fire suppression actions. • Compare incident control objectives as stated in the plan with available water resources and report inadequancies or problems to RDC MSD. • Participate in the preparation of Incident Action Plan when requested. • Respond to requests for water Informations. • Collect & transmit records & logs to documentation unit at the end of each operational period. • Maintain & Submit all records and logs. CITY ENGINEER, BMC • Organise Reception Centers at Assembly points • Co-ordinate resource of voluntary organization • Prepare Plan for the public work • Assist to prepare Plan to Regional Officer MPCB of containment & Clean-up DIRECTORATE OF INDUSTRIAL SAFETY & HEALTH (DISH) • Ensure On-Site plans of industries are vetted and approved as per Act. • Visit industries to see that safety norms are being followed. • Ensure development of On-Site Plans, • Examination of risk evaluation study and Safety Audit • Ensure frequency of Safety Audit and Mock Drills (Fire) • Assist the District Collector in developing Off-Site scenarios. • Ensure Safety Education, Safety awareness. Discussion along with MARG. • Pre-emergency & Post emergency Task. • Assistance in supplying information to service agencies from factory management • Making enquiries to find out case of disaster. MAHARASHTRA POLLUTION CONTROL BOARD : • Monitor extent and quantum of pollution during the crisis • Declare hazardous area safe for re-occupation by population. • Prepare plan for the Containment & Clean-Up. • Prepare Plan for on-going incident assessment.
CONTROLLER OF EXPLSIVES (CCOE)
• Assistance in supplying information to service agencies from factory management • Making enquiries to find out cause of disaster.
49 CHAPTER 9 : WARNING SYSTEM ______
A good warning system is one of the most important pre-requisite of the emergency management system to save lives, prevent injuries and mitigate losses. As soon as incident controller determines that it is necessary to warn people of a threat to public safety, a strategy appropriate to the situation will be developed and immediately implemented to ensure coverage of the affected area. The dissemination of warning shall be effected by the MAH Factories.
TYPES OF WARNING :
Warning signal will be given as under :
DISASTER WARNING : The warning signal shall be high pitched long wailing siren followed by short wailing siren.
ALL CLEAR : Long continuous note
DISSEMINATION OF WARNING BY THE FACTORIES :
Depending on the nature of the hazard, the size of the population of the area threatened and the time available to react, one or more of the following methods would be used to warn the public.
• Outdoor warning siren • Public addressed system (Vehicle mounted) with the police • Remote public address system • Siren • Mass media i.e. Radio and Television • Door-to-door visits by Civil defence personnel using mask and relaying prerecorded cassette messages.
Telephone calls to sensitive locations like schools, organizations and institutions having a large number of employees.
In case of a toxic gas emanating from present area on to the neighboring area due to prevailing wind direction, the information will be relayed to the district Collectorates for warning the likely affected population under their jurisdiction.
50 CHAPTER 10: PERSONAL PROTECTION OF CITIZENS ______
PLANNING TEAM :
• Deputy Collector - In-charge • Additional Controller of Civil Defence Mumbai • DCP • Chief Executive Health Dept BMC, • Education Officer BMC • City Engineer BMC • Executive Engineer PWD • RTO Mumbai • District Information Officer Mumbai • General Manager Central/Western Railway • Depot Manager MSRTC/BEST • General Manager MTNL
These team members shall prepare detailed contingency plan :
Factors:
a) Vulnerable zones where Evacuation could be necessary & method for notifying these places b) Provisions for precautionary Evacuation c) Methods for controlling traffic flow and providing alternate traffic routes. d) Shelter location and other provisions for evacuations. e) Agreements with near by jurisdictions to receive evacuees. f) Agreements with Hospitals outside the local jurisdictions. g) Protective shelter for relocated populations. h) Reception and care of evacuates. i) Re-entry procedures. j) A system of working and advising the public protection and on expedient means to reduce ventilator. k) Relocation l) Water supply protection- to avoid contamination m) Sewage system protection: to avoid public Health threat Environment problems.
51 CHAPTER 11: EVACUATION PLAN ______
In a disaster situation, evacuation from hazardous areas may be the most effective way to obviate casualties. It is a complex exercise requiring multidisciplinary inputs. A comprehensive and co-ordinated preplanning is necessary to implement orderly evacuation of population. The weather conditions obtained through the meteorological department / Weather Monitoring Station would dictate to a large extent the area to be evacuated.
On hearing the disaster warning the population should quickly move to the assembly area as announced on the public address system and should wait for the transportation facility. If assembly area is not announced than they should move out of the threatened area at the right angle to the prevailing wind away from the industrial area. Those personnel who can move out of their homes are advised to stay indoors and cover their noses with the wet cloth.
Following steps would be taken before the crisis by the District Emergency Authority MSD :
• Public information and education on measures for chemical hazards. • Installations of siren or Remote public address system in likely affected area. • Formulations of detailed contingency plan of evacuation. • Working out evacuation plan of sensitive areas like Jail prisoners, Mental/other hospitals etc.
LIMITATIONS:
While in many cases evacuation is a needed life saving measure, it is not always necessary or practical. Lack of time is often the single most important limitation on the effectiveness. Large evacuation takes very long time to execute even if they are well planned in advance. The toxic cloud may pass through an area before everybody can get out when people are outside their homes, attempting to evacuate.
Keeping the area situation into account, it may be possible to stress more on the in Place Protection and attempting to reduce the airflow into their shelter. Public education on the protection provided by a structure should be a part of preparedness activities.
ASSEMBLY AREA:
52 The assembly points shall be the big open spaces around the area identified well before the accident happens. The assembly area shall also act as a Reception Centres, as the population will be displaced temporarily for a short duration.
Arrangements for water, first aid, and possibly food (if duration of emergency is long) shall also be made. Lighting arrangements also will be provided.-
Resident District Collector (Administration) shall ensure that all the Emergency response Agencies knows address & locations of Ail MAH units.
53 CHAPTER 12 : CONTAINMENT AND CLEANUP ______
PLANNING TEAM • Regional Officer MPCB – Incharge • Dy. Municipal Commissioner. • Chief Fire Officer Mumbai. • RTO Mumbai. • Coast Guard: • Chairman MARG • Expert From MAH industries • NGO. • D.C.P Navi Mumbai. • Ref. Of Transport Contractor.
TECHNIQUES FOR SPILL CONTAINMENT AND CLEANUP. Factors Responsibilities
Containment and mitigation action. Mumbai Cooperation
Cleanup methods LCG
Restoration of the surrounding District collector environment
Comment :- LCG will typically emphasize the containment and stabilisation of an incident state regularity agencies can focus on cleanup details. ECG can provide assistance during the cleanup process. It is the releaser legal and financial responsibility to clean up the minimize the risk to the health of the general public and workers that are involved. CCG and other government official should monitor the responsible party cleanup activities.
Workers that are involved. CCG and other government official should monitor the responsible party cleanup activities.
A clear and succinct list of containment and cleanup countermeasures should be prepared for each hazardous material present in the community in significant quantities. This section should coordinated with the section on "Response Personnel Safety" So that response team applicable to the hazardous material and terrain area. It may be helpful to include sketches an details on how cleanup should occur for certain area where spill are more likely.
54 CHAPTER 13 : TRANSPORT EMERGENCY ______Maharashtra is the first State in India which has introduced certain regulations for the transportation of hazardous chemicals and goods by Road Transport. Since large number of tankers and vehicles have to carry hazardous substances, it is necessary to take special precautions to avoid loss if life and property. In view of this, additional permit conditions on the vehicles used for carrying hazardous substances have been incorporated. These vehicles are required to prominently display labels and information regarding the hazardous materials under transport. The additional permit conditions and the order under these permit conditions are based on the recommendations of the Committee of U. N. Experts and these recommendations are accepted by almost all developed countries. The additional conditions to permit transportation of hazardous substances are :-
No public or private carrier should carry hazardous chemicals unless the following conditions are followed :-
• Special labels or notices should be prominently affixed on packages or on vehicles, bearing 'Emblems' specified by the Transport Commissioner of Maharashtra State, Mumbai, pictorially representing particular danger arising out of any hazardous chemicals. • Chemical names, descriptive names or prescribed 'correct technical names' should invariably be displayed on packages or vehicles carrying hazardous chemicals. • The drivers of all road vehicles carrying hazardous chemicals must carry with term instructions in Writing' relating to each dangerous substances or to each class of dangerous substance whether covered in packed form (i.e.) in tins, drums, etc.) or in bulk road vehicles. The instruction including First- aid treatments and advice for dealing with fire, accident, spillage or leakage must be written in English, Hindi and Marathi and in the language of the state of transit and destination. These instructions in writing should be obtained from the Company which load a hazardous chemical for transportation. • A Summary of these instructions in writing in a card from called 'A’ Transport Emergency Card (Tremcard)' should also be carried by the driver in his cabin. The tremcard should be provided by the party / supplier / chemical company loading the said material. • Special signs or plates denoting that dangerous goods are being conveyed should be displayed which will identify the substance and also reveal its hazardous properties and indicate what action should be taken in emergencies.
EMERGENCY PROCEDURE
55 The driver of the vehicles should be instructed that in the events of an emergency, prejudicing the safety of the load or of the public e.g. a traffic accident or a leaking tank, his first responsibility should be to arrange that the police and emergency services are alerted and that assistance is given to any person who is in immediate danger or who has suffered injury. Further action by the driver to tackle a fire or contain a spillage, should be undertaken only if it is considered safe to do so having regard to the circumstances of the emergency, the nature of the load being conveyed and the safety equipment available on the vehicle. The driver should also be instructed to carry out as appropriate and where safe to do so, the following procedures in such order as circumstances dictate :-
• Stop the engine; • Where fitted, turn off the battery isolating switch; • Operate the emergency warning flashing device, but only in such circumstances where there is no likelihood of it igniting any flammable vapour which may have escaped; • Move the vehicle to a place where any leakage would cause less harm or damage; • Where carried, place a hazard warning device, e.g. a red triangle, in position to the rear of the vehicle and of only spillage: • Wear appropriate protective clothing; • Keep people away form the same; • Prevent smoking and keep other vehicles out of any fire risk area; and • Remove the written information provided (i.e. the TREMCARD) from the cab if it is likely to be damaged by fire or later become in accessible. When the police and fire brigade arrive at the scene of the Incident they will take charge and the driver should be instructed to – • Show them the written information concerning the substance(s) being carried e.g. the TREM CARD; • Tell them all he can that is helpful concerning the load.
The driver should be acquaint the operator with particulars of the emergency at the earliest opportunity.
The drivers of road tankers and vehicles conveying tank containers should have sufficient knowledge of the properties and hazards of the dangerous substance(s) they are conveying to enable them to understand and appreciate the dangers and risk involved whilst undertaking the duties.
The Transport Department has also devised the various class labels to be provided on vehicles carrying hazardous chemical properties of the substances which are being transported.
These guidelines should be followed so as to avoid any mishap.
It is further suggested that in the events of any disaster during transportation of hazardous chemicals, a neutralisation squad should be established which would act immediately to minimise the consequences.
56 There should also be an effective communication system established between the manufacturer, transport user, police, fire brigade and medical services.
Such neutralisation squad consisting of-experts and trained personnel should work under the control of Fire Brigade. Formation of such squad could be finalised with consultation with transport department, users of hazardous chemicals and transporters.
While preparing off-site disaster control plan for the area under question where hazardous industries are situated, it was thought fit to include this chapter. Thick population on both sides of roads in these area emphasis the need for such plan.
57 CHAPTER 14 : TESTING AND UPDATING PLAN ______
PLANNING TEAM :
• District Collector Mumbai Suburban District • Jt/Deputy Director Industrial Safety & Health & Member Secretary Local Crisis Group • Chief Fire Officer Mumbai Fire Brigade • DCP Mumbai (Chembur / Mulund / Andheri / Borivali) • Additional Controller Civil Defence Mumbai • Member Secretory MPCB Mumbai • Chief Executive Health Dept BMC • District Health Officer MSD • Medical Superintendent BMC Hospitals • RTO Mumbai • All MAH Industries in the area • Commander, Coast Guard • Technical Experts in MSD • NGO's • District Information Officer MSD • Representative of TV/Radio • Editor of Prominent news Papers • Executive Engineer PWD • Co-ordinator MARG
TESTING THE PLAN
Factors :
Provision For Regular Table Top, Functional, Mock & Full Scale exercises Organisation In-charge Of the Exercise Types of the Exercise Frequency of Exercise
DRILLS AND SIMULATION EXCERCISES :
The regular drills and simulation exercises is a progressive commitment to ensuring that the personnel, Organisational structure, and resources identified in the area plan can function to achieve the most favourable outcome in the event of real accident. The terms used in this exercise are defined as:
Orientation Seminars : The orientation seminar is an informal activity which focuses on training and familiarizations with roles, procedures, responsibilities, and personalities in the management plan. The general purpose is for participants to review plans and procedures in a low stress no "real-time environment with little or no attempt at any simulation.
58 Table Top Exercise : The tabletop exercise provides a specific simulation exercise whose focus is on reviewing the plans and procedures unique to the situation. This exercise makes sure that all the participants have reviewed the plan details in an interactive fashion.
Functional Exercise : The exercise is designed to taste or evaluate individual function. Each function is exercised separately. As far as possible the functional exercises should be held near the site.
Full Scale Exercise : This is done by simulating an event.
Exercise Cycle : The exercise cycle is a calendar of events reflecting a series of exercise that moves the area in the direction towards preparedness. A good exercise cycle is updated regularly to account for changes in the area plan. A recommended exercise cycle may look as below.
Exercise Purpose Participants Time In-charge Type Orientation Review Planning Team Half Yearly District Plan Members Collector MSD
Tabletop Review Co- Emergency Quarterly Chief Fire ordination Management staff Officer & Responders \ MFB Orientation Evacuation Emergency Half yearly Chief Fire Procedures Management Staff Officer & responders, Addnll community leaders Controller Civil Defence & Police Authorities
Tabletop Risk Emergency Half Yearly District Communication Management Staff, Information Information Officer Officer, Media Functional Simulated Media Yearly District Evacuation Information Officer
Full Scale Simulated All emergency Half Yearly District toxic gas response system Collector release personnel and MSD volunteers
59 To make any specific comments and / or suggestions for Plan improvement following format can be used.
Format For Comments :
Name of the Department/Agency : Address :
Contact Name : Phone Number : Fax Number :
Suggestions for Plan improvement :
Errors or inaccuracies noted in this plan:
Signature :
Date :
60 CHAPTER 15 : GENERAL GUIDELINES IN DISASTER
(PERSONAL PROTECTION OF CITIZENS) ______
• Keep calm • Don’t Panic • Cover mouth and Nose with wet cloth • Don't spread rumour • Don't crowd at incident sight • Walk fast at right angle to the wind direction • Close doors and windows in case of toxic gas release • Turn off LPG gas in case of inflammable Gas leakage • Keep phone tines clear • Inform Police & Fire brigade • Follow direction from proper authority • Keep the road clear • Give way to Emergency vehicles immediately
61 CHAPTER 16 : SAFETY PRECAUTIONS (RESPONSE PERSONNEL SAFETY) ______
APPROACH CAUTIOUSLY FROM UPWIND: Resist the urge to rush in; others cannot be helped until the situation has been fully assessed.
SECURE THE SCENE: Without entering the immediate hazard area, isolate the area and assure the safety of people and the environment, keep people away from the scene and outside the safety perimeter. Allow enough room to move your own equipment.
IDENTIFY THE HAZARDS : Placards, container labels, shipping documents and / or expert persons on the scene are valuable information sources. Evaluate all available information and consult the recommended MSDS to reduce immediate risks.
ASSESS THE SITUATION : Consider the following: • Is there a fire, a spill or a leak? • What are the weather conditions? • What is the terrain like ? • Who/what is at risk: people, property or the environment ? • What actions should be taken:, Is an evacuation necessary ? • Is diking necessary ? What resources(human and equipment) are required and are readily Available ? • What can be done immediately ?
OBTAIN HELP : Advise your ECC notify responsible agencies and call for assistance from qualified personnel.
DECIDE ON SITE ENTRY : Any efforts made to rescue persons, protect property or the environment must be weighed against the possibility that you could become part of the problem. Enter the area only when wearing appropriate protective gear (see the MSDS on protective clothing and equipment).
RESPOND: Respond in an appropriate manner. Establish a command post and lines of communication. Rescue casualties where possible & evacuate if necessary. Maintain control of the site. Continually re-assess the situation & modify the response accordingly. The first duty is to consider the safety of the people in the immediate area, including your own.
ABOVE ALL: Don't walk into or touch spilled materials. Avoid inhalation of fumes, smoke & vapours, even if no dangerous chemicals are known to the involved. Don't assume that the gases or vapours are harmless because of lack of smell odourless gases or vapours may be harmful.
62 CHAPTER 17 : GUIDE ON ANTIDOTES ______
Antidotes are therapeutic agents used to counteract the toxic effects of specific xenobiotics. These are heterogeneous group of substances consisting pharmaceuticals, biological agents and immunoglobulin fragments. Different mechanisms of action are involved. Some specifically act at the receptor sites while others exert their effect by changing the metabolism of the poison, counteracting the toxic injury or just forming the inert complex with the poison. Antidotes should be given in adequate doses as early as possible in case of poisoning. Some antidotes cause serious adverse reactions. Hence, both the risk and the benefits of the antidotal therapy must therefore be carefully evaluated and the patient must be monitored regularly. At times the half-life of some antidotes like naloxone, atropine is much shorter than the toxin, in which cases the antidotal therapy must be continued till symptoms of the poisoning subside. Thus knowledge and expertise on the proper use of antidotes is mandatory for controlling the effects of poisoning. Some common chemical antidotes: - Common salt : it neutralizes silver nitrate to silver chloride. - Albumen : it precipitates mercuric chloride. - Dialysed Iron : it neutralizes arsenic. - Copper sulphate :precipitates phosphorous - Alkali : (alkaline hydroxide, milk of magnesia, ammonia) it neutralies acids. Do not use bicarbonates to neutralize acids as carbon dioxide is liberated and accumulated in stomach which may rupture the stomach. - Potassium permanganate (1:5000): at this concentration it loses its pink color. It oxidizes phosphorous strychnine, cyanide, atropine, barbituric acid. - Tincture Iodine or Lugols (15 drops of iodine in glass of warm water): it precipitates lead, mercury, silver, quinine. - Tannic acid (4% in water) of Tannin in strong tea : It precipitates nicotine, cocaine, aconite, lead, silver, cobalt, aluminum, copper, zink, mercury, nickel. UNIVERSAL ANTIDOTE - 2 parts of charcoal powder plus 1 part of tannic acid plus 1 part of magnesium oxide, mix 1 tablespoon in tumbleful of water and give to victim to drink, repeat 2- 3 times. CHELATING AGENTS - BAL (British Anti Lweisite, Dimercaprol) : it is an antidote for arsenic, lead, bismuth, copper, mercury, gold and heavy metals. 3-4 mg/kg deep IM 4 hourly for first 2 days then BD for 10 days - E.D.T.A. (Ethylene Diamine Tetra Acetic Acid) : It is used in lead, mercury, copper, cobalt, cadmium, iron and nickel poisoning. Use 25 mg/Kg in 500 ml of 5% glucose or saline twice a day for 5 days. - Penicillamine : Give orally 0.5 mg/day for 4 times a day for 7 days (30 mg/kg) for heavy metal poisoning.
63 ANTIDOTES COMMONLY USED AGAINST SPECIFIC AGENT
Specific Agents Symptoms requiring Antidotes Dosages Treatment
Acetaminophen Hepatotoxicity N‐acetylcysteine Oral: 140 mg/kg initial dose following by (Tylenol, Nebs#) (hepatocellular necrosis) 70 mg/kg every 8 hours for 17 doses.
Anticholinergic agents Central and/or peripheral Physostigmine Adults: 1 or 2 mg IV slowly (1 mg per min) Anticholinergic symptoms & Repeat in 20 minutes if no reversal Atleast one of the following Then 1 to 2 mg IV for recurrent symptoms. Hypertension Children: 0.5 mg IV (0.5 mg/min) Hallucinations Re‐administer at 5 minute intervals to Convulsions Maximum of 2 mg if symptoms persists. Coma Repeat with lowest effective trial dose if Arrhythmias Life threatening symptoms recur.
Cholinergic agents Cholinergic crisis Atropine Sulphate Adults : 2 mg IV Physostigmine Diaphoresis Children : 0.05 mg/kg IV, repeat until Neostigmine Lacrimation cessation of secretions. Pyridostigmine Bronchial secretions Pilocarpine Excessive unination/defcat Bethanechol Convulsions Methacholine Fasciculations
Cynide (potassium Cynosis Sodium nitrite Adults : 300 mg IV (10 ml of 3% solution) Cyanide Cardiopulmonary arrest Then Children : Dose based on serum Hydrocyanic acid Convulsions Sodium thiosulfate Hemoglobin. Laetrile Coma Adults: 12.5 grams IV (50 ml of 25% soln) Nitroposside sodium Cobalt E.D.T.A.
Ethylene Glycol Acidosis Ethanol Loading dose: 600 mg/kg (1 ml absolute Oxalate crystals in urine Alcohol =790mg) IV in D W over 15 minute Maintenance dose : to maintain blood Level of 100mg% it varies depending on Drinking history of patient
Neuroleptic agents Haloperidol Extrapyramidal symptoms Diphenhydramine 25 to 50 mg IV, IM (Haldo #1) Dystonia Or Or Loxapine succinate Dyskinesia Benztropine 1 to 2 mg IV, IM (Loxitane#) Oculogyric crisis Molindone Parkinsonian symptoms (Moban#) Phenothiazenis Chlorpromazine (thorazine#) Fluphenazine (Prolixin#) Thioridazine (Mellaril#)
64
ANTIDOTES COMMONLY USED AGAINST SPECIFIC AGENT
Specific Agents Symptoms requiring Antidotes Dosages Treatment
Iron salts (ferrous Hypotension Deferoxamine Shock and / or Coma : 15 mg/kg/hour IV Sulfate, ferrous Shock For 8 hours Gluconate) Coma Absence of shock or coma but SI TIBC: (free serum iron present) 90 mg/kg IM every 8 hours x 3 doses.
Methanol Acidosis Ethanol Loading dose: 600g mg/k (1 ml absolute Alcohol =790mg) IV in D W over 15 minute Maintenance dose : to maintain blood Level of 100mg % it varies depending on Drinking history of patient
Methemoglobin ‐ Methemoglobinemia Methylene blue 1 to 2 mg/kg IV (0.1 to 0.2 ml/kg) of 1 Producing agents (30%) Percent solution. Nitrates / Nitrites Not: Contraindicated in Phenazopyridine Methemoglobinemia secondary to Phenocetin Sodium nitrite in cyanide poisoning.
Narcotic analgesics Respiratory depression Naloxone Adults : 0.8 mg IV, IM, SC And related Hypotension Children : 0.01 mg/kg IV, IM, SC Coma Repeat at 10 x(times) origimal dose if no Response
Organophosphate Cholinergic crisis Atropine Sulfate Adults : 2 to 4 mg IV slowly; repeat every Insecticides Diaphoresis 10 to 30 minutes to attain and maintain Malathion Lacrimation Stropinization (decreased bronchial Bronchial secretions Secretions Excessive unination/defcat Children : 0.05 mg/kg IV. Slowly repeat Convulsions Every 10 to 30 minutes at attain and Fasciculations Maintain atropinization. Profound weakness Pralidoxine After atropine Muscular twitching Adults : 1 g IV (500 mg/minutes) Repeat x 3 at 8‐12 hour intervals if Muscle weakness not relieved Children : 25 to 50 mg/kg IV Repeat x 3 at 8‐12 hour intervals if Muscle weakness not relieved
65
ANNEXURE – I
CHEMICAL FACT SHEETS OF MAJOR HAZARD UNIT FACTTORIES MUMBAI SUBURBAN DISTRICT
66 AEGIES CHEMICALS INDIA LTD
1. FACTORY IDENTITY a) Name Aegies Chemicals Industries Ltd.
b) Address Plot No. : 72, Mahul Village, Trombay, Mumbai - 400 074. c) Telephone Nos. / Phone : 255448832, 2554163. Telex /Fax Nos. / Fax : 5541969 & 5541105. E-mail Address. E-Mail: egiscd(5)bom3.vsnl.net.in d) (Location) Railway Line / Highways, passing through / near the area. If so, details of rail / road, crossings / bridges and water way vicinity. e) Details of Human habitation None within a Km (village, City, Residential colony. Hospital etc. near the factory etc. near the factory within 1 Km.) 2. a) Contact personnel of the factory D. K. Bheda, General Manger their Office Phone: 25544975; Phone Nos., Designations, Mobile Mobile: 9821038819 Residence Phone – 27801427
P. H. Darji, Mgr, Chemical Storage, Office Phone: 25541105; Mobile: 982118909 Residence Phone: 27824455. b) Name of the technical experts Dr. S. K. Biswas, designation & their phOone Nos. Group Advisor (Safety & Environment) Office Phone: 22057076 / 2082242. Residence Phone- 2183288
S. K. Hazra, Managing Director, Phone: 22057076 / 22082242 Mobile: 9821018104; Residence : 22185743
D. J. Kulkarni, Advisor Fire fighting, Office Phone :2 7241740 Residence Phone: 25153548. c) Name & phone nos. of incident & D. K. Bheda, (LPG), Site Office Phone: 25544975: Controller. Residence Phone: 27801427. 3. Principal Manufacturing Activities It is not a manufacturing unit. It is a terminal for storing bulk liquidChemicals and liquefied petrochemical.
4. Total No. of workers employed 96 Nos.
5. Maximum No. of persons, who may 70 Nos. (General Shift) be present in the factory at any one
67 time.
6. No. of workers directly involved 7 Nos. with the hazardous chemicals / shift / total. 7. Maximum quantity of hazardous Liquid Chemicals: chemicals stored and their mode of Maximum quantity in storage at one storage (Raw Materials, time 40,000 T in atmospheric cone Intermediate products, bye- roof tanks with Nitrogen products, finished products). blanketing when required. LPG: Maximum Quantity 19,OOOT full containment, double wall atmospheric cryogenic storage tanks. 8. Maximum'Credible Loss Scenario:
a) TOXIC DISPERSION: Not Applicable.
Brief description of Maximum Credible Loss Scenario In case of:
i) Atmospheric Stability Stable Neutral Unstable
ii) Wind Velocity 2m/sec 4 m/sec 6 m/sec
b) IN CASE OF BLEVE, VCE, POOL FIRE AS APPLICABLE
Max. Credible Loss Scenario In case of VCE Pool Fire as BLEVE applicable Worst case scenario is fire in bund area due to LPG tank leak. It is a Non-Credible Scenario (Probability once in one billion years) Heat Radiation
a) Severe Damage to life and property (within cloud) b) 100% lethality (37.5 Kw/m2) None.
c) 50% Lethality (25 Kw/m2)
d) 1% Lethalitv (12.5 Kw/m2)
e) First Deciree 4.5 Kw/m2 No credible off-site effect
f) No discomfort 1.6 Kw/m2.
a) Damage distance due to 0.3 bar pressure 9. Consequences of Major Hazards No pressing activity involved. that are likely to occur in case of Fire inside the terminal because process of spillage, even it occurs wilt
68 upsets and storage. be contained within the terminals.
10. Resources Available
Details of fire fighting equipments available in the factory a) Fire tender / Trailer pump and its : TATA Model LPT 1612 / 42 FFC capacity Water Tank Capacity : 3000 Litres. Foam tank capacity : 1000 Litres. 2270 lpm at 7 kg/cm2. b) Maximum quantity of foam : 1000 Litres. available.
c) Water storage tank and its : 7000 m3 per day municipal make capacity up water. d) No. of hose reels and total length : 66Nos.X1bm.
h) No. of fire Suit : 01 Nos
11. Details of communication available to contact Police and Fire brigade in case of emergency a) Telephone : 5544832 / 55040709 / 5541463 / 5546734 / 5541961
b) Hot Line 1 Hotline to IPCL
c) Wireless Wireless connection with IPCL.
d)Walkie Talkies etc. 9 Nos. Walkie talkie.
12. Public Alert System and its Long distance Electrical Siren (5 procedure Km).
13. List of protective equipments available in Factory i) No. & type of emergency kit First Aid Box -4 Nos.
ii) No. of Self contained 1 Set. breathing apparatus iii) No. of air line respirators 1 Nos.
iv) No: of canister respirators : 10 Nos.
v) No. of acid suits. : PVC suit.
vi) Any other personal : Helmet, Face shield. Safety protective goggles, equipments. ear plugs, ear muffs, hand gloves, Safety shoes, blowman mask.
69 14. Medical facility available in factory : N. A.
i) Equipments available in Ambulance room. ii) Antidotes available : N. A.
iii) No. of first aiders available : 28 Nos.
iv) Ambulance Van or alternate : Jeep – 2 Nos arrangement v) Details of hospitals in the vicinity : Permanent arrangement with and any the up with them. Inlaks Hospital, Chembur Colony. 15. Provision of emergency lighting : Yes.
16. Hazardous chemicals transported
a) Quantity (MT / day) 400 1600 120
b) Name of the Chemical LPG Naphtha LPG
c) Type of carrier Pipeline Pipeline Tanker
d) Principal destination IPCL NOCIL
17. Site plan of factory showing internal : Attached as Annexure. roads, location of storages of hazardous chemicals, buildings etc. 22. Any other relevant information
70 BHARAT PETROLEUM CORP. LTD. – REFINERY DIVISION
1. FACTORY IDENTITY
a) Name BHARAT PETROLEUM CORP. LTD. REFINERY DIVISION
b) Address Mahul, Chembur
Mumbai – 400 074.
c) Telephone Nos. / Telephone : 2554 3151,
Telex / Fax Nos. 2554 2990, 55401
51, 25540390
E-mail Address Telex : 61058
Fax : 5542970
d)Details of Human habitation (Village, City East Side – HPCL, Gawanpada Residential colony, Hospital etc. near the factory etc. near the factory within 1 km.) West Side – Mahul Village North Side – HP Nagar
South Side – Tata Electric Company Aegis Chemicals
2. a) Contact personnel of the factory their b) KV Seshadri Phone Nos., Designations, Mobile Phone Nos. GM (Process) Off : 5540157 Resi : 5546069
c) CS Chakrabarti
DGM (Fire & Safety)
Off : 5543827 Resi : 3860751
3. Pricipal Manufacturing Activities : Processing of crude oil by various physical and chemical separation process to produce value added products
4. Total No. of workers employed : 3001
(Clerical – 235; Labour – 2099; Staff – 667)
71 5. Maximum No. of persons, who may be : 1272 present in the factory at any one time.
6. No. of workers directly involved with the : 1763 hazardous chemicals / shift / total.
7. Maximum quantity of hazardous chemicals Maximum quantity of hazardous stored and their mode of storage (Raw chemicals with a potential of causing Materials, Intermediate products, bye- Maximum Credible Loss Scenario poducts, finished products) Chemical (MT) Type of Storage
Propylene 275 Horton sphere
LPG 1537 Horton here
8. Maximum Credible Loss Scenario:
a) Toxic Dispersion Not Applicable
b) In case of BLEVE, VCE, POOL FIRE as applicable
Brief Dscription
BLEVE :
The worst accident as assessed by M/s. NEERI is attributed to BLEVE of C3 sphere
VCE :
The worst accident situation on account of explosion is attributable to the vapor cloud explosion (VCE) of C3 sphere
POOL FIRE :
There is no scenario for pool fire which have impact outside the refinery
Max. Credible Loss Scenario In case of BLEVE
(Damage Distances in Meters)
Heat Radiation NA
a) 50% Lethality (25 Kw/m2) 669 mts
b) 1% Lethality (12.5 Kw/m2) 843 mts
c) First Degree 4.5 Kw/m2 of burns 1150 mts
d) Damage distance due to 0.3 bar pressure wave In case of VCE 91 mts
72 9. Details of fire fighting equipments available in the factory
a) Fire tender / Trailor pump and its capacity Foam Tenders 5 Nos
3 Nos. 6000 LPM at 8-12 Kg/cm2
1 No. 4000 LPM at 7 kg/cm2
1 No. 3000 LPM at 7-12 kg/cm2
Dry Chemical Powder Tender 2 Nos.
1 Tender with two DCP vessel of 700 Kg Monnex DCP each.
1 Tender with two DCP vessel of 1000 Kg Monnex DCP each.
Foam Nurser 1 No 7600 Lits
Emergency Equipments Carrier 1 No.
b) Maximum quantity of foam available 95,500 Lit AFFF
(Aquenous Film forming Foam)
c) Water jet monitors Nos. : 4 Nos. (2 Nos. HVLR & 2 Nos. Super Jet
d) Water storage tank and its capacity Raw water 2 X 12,000 KL Tanks at LPG FF Pump House
Sea water basin 13,000 KL at SWPH with facilities for continuous replenishment
e) No. of hose reels and total length 300 Nos. Hoses (300 X 15 mtr. ) = 4500 mtr.
f) No. of fire Suit : 8 Nos.
4 Nos. = Proximity
2 Nos = Fire Suit
2 Nos. = low temp. Suits
11. Details of communication available to contact Police and Fire Brigade in case of emergency
73 a) Telephone
Crisis Control Room located near Fire Station having telephone facilities for communication during emergency to mutual aid members & out side agencies required as per Disaster Management Plan.
b) Hot Line
Mumbai Fire brigade – Chembur Fire Station
HPCL Refienry RCF Police Station
c) Wireless
VHF Network for internal communication and emergency handling:
VHF Hand Sets 65 Nos., Base Station 12 Nos., Mobile Vehicle Mounted 6 Nos.
12. Public Alert System and its procedure 1. PA System provided at security gates for. communication with out side public (Main Gate & North Gate). 2. Fire Siren: Fire sirens installed in Refinery & Staff Colony for alerting people during emergency. Refinery sirens can be sounded on Civil Defence mode as per requirement
13. List of protective equipments available in factory
i) No. & type of emergency kit emergency rescue tender having emergency kit of different types for handling emergency in refinery is available round the clock.
ii) No. of Self contained breathing apparatus : 40 BA Sets with spare cylinders (1200 Ltr. Capacity BA Sets 28 Nos. (600 Ltr. Capacity BA Sets 12 Nos.)
iii) No. of air line respirators : 22 Nos
iv) No. of canister respirators : 26 Nos and Canisters are regular stock items v) No. of acid suits : 20
14. Medical facility available in factory
i) Equipments available in Ambulance room Oxygen cylinders, Resuscitator, Suction Machines, I.V. Sets, Suturing sets, special burn dressing etc. for handling any emergency. X-Ray Unit, Autoclave machines for sterilization of various surgical. 8 beds with on line oxygen facility. ii) Antidotes available Injections Atropin, Adernalin, Soda-Bicarb, Abntisnake venom etc. iii) No. of first aiders available 13 Para Medical / Nursing Staf. (Minimum 2 Male nurses in each shift) iv) Ambulance Van or alternate arrangement
74 1. Place of availability : 2 Ambulances available inside the refinery at fire station 2. Capacity : 3 Persons in each ambulance
3. Facilities available in the van : Oxygen Cylinders, Suction machine, First aid dressing materials, splints antiseptic lotions & ointments, IV Set, Water tank etc. v) Details of hospitals in the vicinity and any tie up with them. 1.LTMG Hospital, Sion. 2. KEM Hospital, Parel. 3. Shatpadi Municipal Hospital, Govandi. 4. Rajawadi Municipal Gen. Hospital, Ghatkopar. 5. JJ Group of Hospital, Chembur. 6. Inlaks General Hospital, Chembur. 7. P. D. Hinduja Hospital, Mahim. 8. Diamond Poly Clinic and Nursing Home, Chembur. 9. Mangal Anand Hospital, Swastik Park, Chembur. 10. Dr. LCManek Hospital, Parvati Palace, Chembur. 11. Joy hospital, 1 'h Road, Chembur. 12. Hegade hospital, Sai Kripa, Road No. :1, Chembur. 13. Dr. Karmarkar Hospital, Dadar. 14. Lilavati Hospital, Bandra.
15. Provision of emergency lighting Normally emergency lighting is fed through, normal power supply sources (either Gas Turbine Generators (20 MW each) or Tata Electric Company). However, we have three separate emergency lighting viz. Emergency Diesel Generator (1250 KVA), TG Set (25 KVA) & New Diesel Generator Set (1250 KVA) as source to feed emergency lighting in refinery in case of GT & Tata grid failure.
16. What other facilities are available Mutual Aid Scheme in Trombay-Chembur outside : the factory premises (Mutual area, 14 members including Mumbai Fire Aid Scheme) Brigade & Civil Defence. 18. Hazardous chemicals transported 1. Propylene 2.LPG 3. Crude oil 4. Motor Spirit 5. Naphtha 6. Benzene 7. Toluene 8.Hexane9.Xytol10.SBP(55-115) 11.MT012.ATF ,13. SK014. HSD Principal destination Mumbai, Thane, Pune, Raigad, Nagpur, Nasik & other major towns in Maharashtra, States ofGoa (Panjim), Gujrat (Surat, Vapi, Vadodara, Amdavad), Madhya Pradesh (Bhopal, Indore), Andhra Pradesh (Secundrabad, Vizag), Rajasthan (Jaipur, Kota, Udaipur), Uttar Pradesh (Agra, Mathura, Lucknow, Kanpur), Bihar (Patna), Delhi, Tamilnadu (Chennai, Mahurai, Coimabtore), Kerala (Kochi), Kamataka (Banglore), West Bengal (Calcutta), Chandigarh etc.
19. Site plan of factory showing internal roads, location of storages of hazardous chemicals, buildings etc. (Attached )
75 BHANDUP COMPLEX WATER TREATMENT PLANT
1. FACTORY IDENTITY : Bhandup Complex Water Treatment Plant (Municipal corporation of Greater Mumbai) a) Name : Khandipada, Darag Road, Mulund (W),Mumbai - 400 082. b) Address : Voice Mail: 25690703/25690704 Ext. 541,588. Direct No.:2 5616177. Fax No.: 25690702. b) Telephone Nos. / Telex / Fax Nos. /
E-mail Address.
d) (Location) Railway Line / Highways, passing through / near the area. If so,
details of rail / road, crossings / bridges and water way vicinity.
e) Details of Human habitation (Village, City, Residential colony, Hospital etc. near the factory etc. near the factory within 1 Km.)
2. a) Contact personnel of the factory their : Mr. T. R. Rane, Phone Nos., Designations, Mobile Dy. Hydraulic Engineer, Phone Nos. Direct: 225686154; Board : 5690703/04 Ext. : 551.
Mr. U. R. Divekar, Executive Engr. (Treatment, Chemical & Instrument) Direct: 25690702 Board Ext: 512.
Mr. D. R. Shejale, A. E. (Chemical) Direct: 25616179 Board Ext. : 541, 588. •
Mr. S. P. Chavan, Division Labour & Welfare Officer. Board Ext.: 527.
b) Name of the technical experts designation & their phone Nos. c) Name & phone nos. of incident & Site Controller 3. Principal Manufacturing Activities 4. Total No. of workers employed
5. Maximum No. of persons, who may be present in the factory at any one time 6. No. of workers directly involved with inc
76 hazardous chemicals / shift / total. 7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Materials, Intermediate products, bye products, finished products) 8. Maximum Credible Loss Scenario: a) TOXIC DISPERSION Brief description of Maximum Credible Loss Scenario In case of i) Atmospheric Stability Stable Neutral Unstable ii) Wind Velocity 2 m/sec. 4 m/sec. 6 m/sec. Radial distance around factory which could be affected in metres Toxicity a) LC 50 b) STEL c)TLV b) In case of BLEVE, VCE, POOL FIRE as applicable Brief Description Max. Credible Loss In case of VCE Pool Fire as Scenario BLEVE applicable (Damage Distances in Metres) Heat Radiation a) Severe Damage to life and property (within cloud) b) 100% lethality (37.5 Kw/m2)
c) 50% Lethality (25 Kw/m2)
d) 1% Lethality (12.5 Kw/m2) e) First Degree 4.5 Kw/m2 of bums f) No discomfort 1.6 Kw/m2 9. a) Damage distance due to 0.3 bar pressure wave b) Consequences of Major Hazards that are likely to occur in case of process upsets and storages.
10. Details of fire fighting equipments available in the factory a) No. of Fire fighting equipments and their capacity i) Soda acid type ii) C02 Type iii) DCP Type iv) Foam Type
77 b) Fire tender / Trailer pump and its capacity c) Maximum quantity of foam available. d) Water jet monitors Nos. e) Water storage tank and its capacity f) No. of Hydrant points g) No. of hose reels, and total length h) No. of fire Suit 11. Details of communication available to contact Police and Fire brigade in case of emergency a) Telephone b) Hot Line c) Wireless 12. Public Alert System and its procedure 13. List of protective equipments available in Factory i) No. & type of emergency kit ii) No. of Self contained breathing apparatus· iii) No. of air line respirators iv) No. of canister respirators v) No. of acid suits. vi) Any other personal protective equipments vii) Neutralisation facility provided for neutralising chemicals 14. Medical facility available in factory i) Equipments available in Ambulance room ii) Antidotes available iii) No. of first aiders available iv) Ambulance Van or alternate arrangement 1. Place of availability 2. Capacity 3. Facilities available in the van v) Details of hospitals in the vicinity and any the up with them. 15. Provision of emergency lighting 16. What other facilities are available outside the factory premises (Mutual Aid Scheme) 17. Available Meteorological data a) Wind Directions during part of the day b) Wind speed (Monthly) c) Rainfall (Average / Max. Record) d) Floods Etc.
78 18. Hazardous chemicals transported a) Quantity at a time b) Name of the chemical c) Type of carrier d) Principal destination 19. Demographic segment map showing the area around factory within the physical range of worst scenario. 20. Whether separate are specially earmarked for parking of tankers in factory / in the vicinity of factory is provided to avoid traffic congestion, if so details of thereof 21. Site.. plan of factory showing internal roads, location of storages of hazardous chemicals, buildings etc 22. Any other relevant information
79 CHEMICAL TERMINAL TROMBAY LTD
S No
1 Factory Identity.
a) Name Chemical Terminal Trombay Limited b) Address Pir Pau Installation, Near MBPT pump house, Behind Tata Electric Company
Trombay Mumbai 400074. c) Telephone No/ Telex No / Fax No/E-mail address. Tel fax No 67030114 / 15 / 16 / 17 /18 E- mail [email protected]
d) Details of Human Habitation Village Mahul ( Village, city, residential Taluke Kurla. colony, Hospitals etc near the factory within 1 Km Hospital Inlaks Hospital
2 a) Contact personnel of the Mr. S.H.Bengali factory their Phone Nos & Terminal Manager Designations Mobile phones Tel fax No 67030117 / 18
Mobile 9821349536. b) Name of the Technical Residence 26372074 experts designation & their Mr. P.D.Sahani phone No Health Safety & Environment Officer Tel fax No 67030114 / 15 / 16.. Mobile 9821336941 c) Name & phone No of Residence 24370424 incidental site controller Mr.P.D.Sahani.
Health Safety & Environment Officer 3 Principal Manufacturing Receiving, storage & redelivering of activities(Plant wise) chemicals, presently we store chemicals i.e. Methanol, Ethyl Acetate, Toluene Acetone, IPA, Cumene & Lube base oil
4 Total No of workers employed 34
5 Maximum No of persons, who may 50 be present in the factory at any one time
6 No of workers directly involved No manufacturing activity only storage with the hazardous chemicals. of chemicals in tanks.
80 7 Maximum quantity of hazardous Storage of A / B / C class products chemicals stored and their mode of 42132 K lit storage (Raw materials, Intermediate products, bye Stored in atmospheric tanksStock as on th products, finished products.) 10 May 2008 ( 14825 Kl )
8 Maximum credible loss scenario.
a) Toxic dispersion Not applicable i) Atmospheric stability Stable ii)Wind velocity 2 to 4 m/sec iii)Toxicity LC50 Non Toxic b) In case of BLEVE, VCE, POOL FIRE as applicable Not applicable Brief Description As in case of fire the area effected will Max Credible Loss scenario be within the factory premises only. i.e.
Heat radiation Chemical Name Methanol
a)Severe damage to life Failure Bottom nozzle of the and property tank
b)100% lethality Time 9062 seconds (37.5Kw/m2) Wind speed 1 m/sec c)50% lethality (25Kw/m2) Pool fire distance in meters d)1% lethality (12.5Kw/m2) 37.5 Kw/m2 27 meter
e)First degree (4.5Kw/m2) 12.5 Kw/m2 27 meter
f)damage distance due to 4 Kw/m2 40 meter 0.3 bar pressure wave
9 Consequences of major hazards Fire. that are likely to occur in case of process upsets and storage.
10 Details of Fire fighting equipments Hydrant line diesel pump 615 m3/hr at available in the factory. 105 MWC head three numbers Hydrant line diesel pump 171 m3/hr at a) Fire tender/ trailer pump 75MWC head one number and their capacity Hydrant line Jockey pump 40 m3/hr
Foam Line diesel pump 110 m3/hr Fire tender pump 110m3/hr. Co2 in fire tender 6 X 22 Kg DCP in fire tender 2 X 68 Kg
81 Foam in fire tender 500 Lit Water in fire tender 2750 Lit. AFFF Foam 5.5 m3 in SS foam tank
500 Lit in fire tender c) Maximum quantity of foam 30 Lit carboys 50 Nos. available Hydrant system 2050 m3 two tanks & Foam system 600 m3 one tank d) Water storage tank and its capacity. 1 X 30 meter in fire tender e) No of hose reels & total
length f) No of fire suit. 2 Nos 11 Details of communication available Telephone lines to contact police & fire bridge in case of emergency
12 Public address system and its Portable public address system. procedure Installation of one solar booth with public address system
13 List of Protective equipments available in factory
a) No & type of emergency kit. First aid.
b) No of self contained breathing apparatus. Two
c) No of Air line respirators
d) No of Canister respirators Nil
e) No of acid suits. Six
f) Any other personnel protective equipments g) Ventilation facility for We do not handle acids hence not installation applicable.
Helmets, safety shoes, gloves, goggles, PVC apron, face shield. etc.
Material stored in fixed roof tanks in open space..
82 14 Medical facilities available in factory.
Equipment available in ambulance room All equipments as listed in Factory rules
a) Antidotes available Antidotes mention in MSDS are b) No of first aiders available available
All workers are trained in first Aid c) Ambulance van or certificate course. alternate arrangement d) Details of hospitals in the Tie up with Inlaks Hospital. & Mutual vicinity and any tie up with aid scheme members. them Inlaks Hospital Chembur colony Mumbai 400074. Tel No 25204160-64
Fax 25204141
15 Provision of emergency lighting High powered Torches available
One solar booth light at night time.
16 What other facilities are available Member of mutual aid scheme. outside the factory premises (Mutual aid scheme)
17 Hazardous chemical transported Only storage facilities are available at terminal.
18 Site plan of the factory showing Attached. internal roads, locations of storages of hazardous chemicals.
19 Any other relevant information. ------
83 HINDUSTAN PETROLEUM CORP. LTD. REFINERY 1 FACTORY IDENTITY a) Name : Hindustan Petroleum Corpn. Ltd. b) Address : Mumbai Refinery Division, Bhikaji Damaji Patil Marg, Mahul, Mumbai – 400 074. c) Telephone Nos./ 25076000 Telex / Fax Nos./ 25542391 Fax 25542008 E-mail Address : d) (Location) Railway Line / Highways, : Old Corridor Road passing through / near the area. If so, details of rail / road, crossings / bridges and water way vicinity. e) Details of human habitation (Village, : North side : Calico Chemical City, Residential colony, Hospital etc. South side : Tata Electric Co. near the factory etc. near the factory West side : BPCL within 1 km.) East Side : Container Yard/Apar Ltd. 2. a) Contact personnel of the factory S C Mehta – ED,MR their Office : 25545061 Phone Nos., Designations, Mobile Residence : 23521583 Phone Nos. M D Pawde – General Manager - Oprns Office : 2554 0675 Residence : 2403 6365
K V Singh : Ch Manager (F&S) Office : 2507 6600 Residence : 9769026290 b) Name of the technical experts, V S Agashe -DGM (Opns..) –FR designation & their phone Nos. Office : 2554 1952 9819919330
V A Katne - DGM (Opns.) – LR Office : 25544258 9833268501 c) Name & Phone nos. of incident & S C Mehta – E D –MR Site Controller Office : 25545061 Residence : 23521583 3. Principal Manufacturing Activities (Plant Manufacturing / Refining of Petroleum wise) Products 4. Total No. of workers employed : 1850 5. Maximum No. of persons, who may be : 1250 present in the factory at any one time. 6. No. of workers directly involved with the : Plant operators are not directly hazardous chemicals/ shift/ total. involved in Hazardous chemicals as the system has closed system. 7. Maximum quantity of hazardous Crude : 267000 T (Tank) chemicals stored and their mode of LPG : 3300 T (Sphere) storage (raw Materials, Intermediate Naphtha : 37900 T (Tank) products, bye-products, finished Petrol : 35800 T (Tank) products). Hexane: 4800 T (Tank) Solvent: 1800 T (Tank) LDO : 18000 T (Tank) IFO : 39800 T (Tank) MTO : 1800 T (Tank) ATF : 5190 T(Tank) HSD : 94600 T(Tank) 8. Maximum Credible Loss scenario ; a) TOXIC DISPERSION : Brief description of Maximum Credible Loss Scenario: In case of i) atmospheric Stability Stable Neutral Unstable ii) wind Velocity 2 m/sec. 4 m/sec. 6 m/sec. Redial distance around factory which could be affected in meters. Toxicity Nil – Not applicable a) LC 50 b) STEL c) TLV d) In case of BLEVE, VCE, POOL FIRE as applicable Brief Description *As per DMI Risk Analysis study Max. Credible Loss the worst accident situation or Maximum credible loss scenario is identified as Tk-253, the Naphtha tank fire and loss of containment leading to vapor cloud. Delayed ignition vapor cloud explosion and pool fire. Appropriate Onsite measures have been taken by HPCL to minimize the damage preventing such accidents. In case of VCE Pool Fire as BLEVE applicable
(Damage distances in meters) Heat Radiation a) Severe Damage to life and property (within cloud) b) 100% lethality (37.5 Kw/m2) Not reached c) 50% lethality (25 Kw/m2) 47 d) 10% lethality (12.5 Kw/m2) 105 e) first degree 4.5 Kw/m2 of burns f) no discomfort 1.6 Kw/m2 g)Damage distance due to 0.3 bar 80 pressure wave 9. b) Consequences of Major Hazards that Fire, Explosion are likely to occur in case of process upsets and storages. 10. Details of fire fighting equipments available in the factory a) No. of Fire fighting equipments and their capacity
i) Soda acid type - ii) CO2 type 467
85 iii) DCP type 835 iv) Foam type - b) fire tender / Trailor pump and its 5 Fire / Foam tender, 4000 LPM, 3 capacity Trailor pump 1800 LPM c) Maximum quantity foam available. 90000 ltrs d) Water jet monitors Nos. : 20 jet/ 325 fix monitors. e) water storage tank and its capacity : 2 tanks, 18740 m3 f) No. of hydrant points : 824 g) No. of hose reels and total length : 100, Length -22.5 m each h) No. of Fire Suit : 02 & 10 Nos. of Water jel blanket 11. Details of communication available to : Telephone, pager system, hot line contact police and Fire brigade in case and Radio trunking. of emergency a) Telephone : 3 b) Hot line : BPCL & Chembur fire brigade c) wireless : 65 Sets.. 12. Public Alert system and its procedure : Mike System 13. List of protective equipments available Fire Proximity, PVC suit, water jel in factory i) No. & Type of emergency kit : 2 Nos rescue tools. ii)No. of Self contained breathing : 12 apparatus iii) No. of air line respirators : 02 iv) No. of canister respirators : 12 v) No. of acid suits : 10 vi) any other personal protective : All PPE are available in Central equipments. warehouse and given as and when required. vii) Neutralization facility provided for neutralizing chemicals. 14. Medical facility available in factory i) Equipments available in Ambulance : Full fledged 2 Nos. of Medical centre room available with 2 nos. of ambulance. Medical centre is manned round the clock. ii) Antidotes available : N/A iii) No. of First aiders available : First aiders are the medical staff, also the employees have trained in First aid. iv)Ambulance Van or alternate : 2 Nos. ambulance van available arrangement alternate on call. 1. Place of availability : Ambulance are in the refinery 2. Capacity : A/C two beds. 3. Facilities available in the van : Oxygen sets. v) Details of hospitals in the vicinity and : Inlak Hospital, Shushrut Hospital, any the up with them. Mangal Anand, Sion Hospital 15. Provision of emergency lighting :Available in case of Tata Power failure, we have power supply from Captive power plant. Also 2 emergency generator are available. 16. What other facilities are available : Mutual Aid Scheme is available
86 outside the factory premises (Mutual Aid scheme) 17. Available meteorological data a) wind Directions during part of the : N/W : September – March day S/W : April – August b) wind Speed (monthly) : Mean wind speed 6 knots. c) Rainfall (Average / Max. Record) 76 inch. d) Floods, Etc. : No. 18. Hazardous chemicals transported : No hazardous chemicals transported from the Refinery. a) Quantity at a time b) Name of the chemical c) type of carrier d) principal destination 19. Demographic segment map showing the : Refer attachment. area around factory within the physical range of worst scenario. 20 Whether separate area are specially : Traffic congestion is reduced in earmarked for parking of tankers in corridor road. Tanker have been factory / in the vicinity of factory is issued token are removed by traffic provided to avoid traffic congestion, if police. so details of thereof. 21. Site plan of factory showing internal : Refer attachment roads, location of storages of hazardous chemicals, buildings, etc. 22. Any other relevant information.
87 HINDUSTAN PETROLEUM CORPORATION LTD. MAHUL TERMINAL
1. FACTORY IDENTITY
a) Name : Hindustan Petroleum Corp. Ltd. b) Address Mahul Terminal, Old Corridor Road, Chembur, Mumbai – 400 074 c) Telephone Nos. / 25543280/81/82/83 Telex / Fax Nos. / Fax : 25546665
E-mail Address. d) (Location) Railway Line / Highways, passing through / never the area. If so, details of rail / road, crossings / bridges and water way vicinity e) Details of human habitation (Village, City, : Gawanpada Population – 9000 Residential colony. Hospital etc. near the factory etc. near the factory within 1 Km.) 2. a) Contact personnel of the factory their phone : Shri B P Jaisawal, Nos., Designations, Mobile Phone Nos. Sr. Instn. Manager Office : 25545168 25544323 b) Name of the technical experts destination & : Shri S. V. Rane their phone nos. Manager Instruments Office : 25546530 Residence :27579694 c) Name & Phone nos. of incident & Site Controller 3. Principal manufacturing Activities (Plant wise) : Products received from Refinery. Storage and distribution of finished petroleum 4. Total No. of workers employed : 155 5. Maximum No. of persons, who may be present : 120 in the factory at any one time. 6. No. of workers directly involved with the : Nil hazardous chemicals / shift / total 7. Maximum quantity of hazardous chemicals : Class – A : 6770 MT stored and their mode of storage (Raw Class – B : 22320 MT materials, Intermediate products, bye-products, Class – C : 13660 MT. finished products) LPG : 310 MT 8. Maximum Credible Loss Scenario : a) TOXIC DISPERSION : Net applicable as we are not handling any toxic chemicals Brief description of Maximum Credible Loss Scenario In case of i) Atmospheric Stable Neutral Unstable Stability ii) Wind Velocity 2m/sec 4m/sec. 6m/sec. Radial distance around factory which could be affected in metres Toxicity
88 a) LC 50 b) STEL c) TLV b) In case of BLEVE, VCE, POOL FIRE as applicable Brief Description Mx. Credible Loss Scenario In case of VCE Pool Fire BLEVE as applicable (Damage Distances in Metres) Heat Radiation a) Severe Damage to life and property (within Attachment cloud) b) 100 % lethality (37.5 Kw/m2) c) 50 % Lethality (25 Kw/m2) 23 d) 1 % Lethality (12.5 Kw/m2) 117 e) First Degree 4.5 Kw/m2 of burn 46 f) No discomfort 1.6 Kw/m2 g) Damage distance due to 0.3 bar pressure wave Consequnces of Major Hazards that are likely to occur in case of process upsets and storages 9. Details of fire fighting equipments available in the factory a) No. of Fire fighting equipments and their : Nil; Assisted capacity from HPFR i) Soda acid type ii) CO2 Type iii) DCP type iv) Foam Type b) Fire tender / Trailor pump and its capacity : Nil; Assisted from HPFR c) Maximum quantity of foam available : 2500 Ltd d) Water jet monitors Nos. e) Water storage tank and its capacity f) No. of Hydrant points g) No. of hose reels and total length : 100 nos. 150 Rm h) No. of fire Suit 10. Details of communication available to contact Police and Firebrigade in case of emergency a) Telephone :P & T Line – 10 Nos. b) Hot line : 2 nos.
89 c) Wireless : Nos. 12. Public alert System and its procedure : Provided at main entry gate and 2 nos. Electrical siren having available range pf 2 km. 13. List of protective equipments available in factory i) No. & type of emergency kit : 2 Nos. ii) No. of Self contained breathing apparatus : 2 Nos. iii) No. of air line respirators : Nil iv) No. of canister respirators : N.A. v) No. of acid suits : N.A. vi) Any other personal protective equipments : Hand gloves, Safety Shoes, Safety Belts, Rubber Hand gloves, ear muff. vii) Neutralisation facility provided for : Neutralisation facility is not neutralizing chemicals available. However, hydrocarbon detectors with alarm system has been provided in LPG area. 14. Medical facility available in factory i) Equipments available in Ambulance room : Assistance from HPFR. ii) antidotes available iii) No. of first aiders available iv) Ambulance Van or alternate arrangement 1. Place of availability : HPFR 2. Capacity : 2 Nos. 3. Facilities available in the van : With all necessary Equipments v) Details of hospitalism the vicinity and any the : Inlak / Sion Hospital up with them. 15. Provision of emergency lighting : 1. Tatal Electric 2. HPFR 3. BSEB 16. What other facilities are available outside the : We are member of Mutual Premises factory premises (Mutual Aid Scheme) (Mutual Aid Scheme) Aid Scheme, Chembur – Trombay Area. 17. Available Meterological data a) Wind direction during part of the day b) Wind speed (Monthly) c) Rainfall (Average / Max. Record) d) Floods Etc. 18. Hazaradous chemicals transported a) Quantity at a time : With varying capacity of 12 / 14 / 16 KLP per T. b) name of the chemical : Naphtha, Hexane c) Type of carrier : Tank truck
90 d) Principal destination : Industrial Customer and Upcountry location 19. Demographic segment map showing the area around factory within the physical range of worst scenario 20. Whether separate are specially earmarked for : Request for allotment of land west of parking of tankers in factory / in the vicinity of BPCR Refinery to BPC & HPC for factory is provided to avoid traffic congestion, if development of submitted to so details of thereof. Municipal Commission on 06.11.1996 21. Site plan of factory showing internal roads, : Attached location of storages of hazardous chemicals, buildings etc. 22. Any other relevant information : Nil
91 HPCL MAHUL LPG FILLING PLANT 1 FACTORY IDENTITY a) Name : Hindustan Petroleum Corpn. Ltd. b) Address : Mahul LPG Filling Plant, L U Gadkari Marg, Behind HPCL Refinery,Chemburl, Mumbai – 400 074. c) Telephone Nos./ 2554 2280 Telex / Fax Nos./ 25544159 Fax 25548677 E-mail Address : d) (Location) Railway Line / Highways, : L U Gadkari Marg passing through / near the area. If so, details of rail / road, crossings / bridges and water way vicinity. e) Details of human habitation (Village, : North side : Ganon Norton Co City, Residential colony, Hospital etc. South side : Bombay Indl Corp. near the factory etc. near the factory West side : L U Gadkari Marg within 1 km.) East Side : BARC 2. a) Contact personnel of the factory K Subramaniam – CRM (Occupier) their Office : 25548677 Phone Nos., Designations, Mobile 9920930963 Phone Nos. R L Jadhav – Plant Manager Office : 2554 2280 9975255818
Shabbir Azam– Exe Opr Officer Office : 25544159 9619189944 b) Name of the technical experts, Exe Opr Officer designation & their phone Nos. Office : 25544159 c) Name & Phone nos. of incident & Site Controller Site Controller Primary Plant Manager (2554 2280) Alternate – Safety Officer (25544159) Incident Controller Primary – Shift Incharge 2554 4159 Alternate Maintenance Officer 2554 4159 3. Principal Manufacturing Activities (Plant Bulk Storage, Bulk Dispatch in road wise) tanker & packed cylinder dispatch in trucks 4. Total No. of workers employed : 150 5. Maximum No. of persons, who may be : 200 present in the factory at any one time. 6. No. of workers directly involved with the : Plant operators are not directly hazardous chemicals/ shift/ total. involved in Hazardous chemicals as the system has closed system.
92 7. Maximum quantity of hazardous LPG – (3 x 200 MT) = 600 MT chemicals stored and their mode of Mounded STorage storage (raw Materials, Intermediate products, bye-products, finished products). 8. Maximum Credible Loss scenario ; a) TOXIC DISPERSION : Brief description of Maximum Credible Loss Scenario: In case of i) atmospheric Stability Stable Neutral Unstable ii) wind Velocity 2 m/sec. 4 m/sec. 6 m/sec. Redial distance around factory which could be affected in meters. Toxicity Nil – Not applicable a) LC 50 b) STEL c) TLV d) In case of BLEVE, VCE, POOL FIRE as applicable Brief Description *As per As per ALARP Risk Analysis principle using PHAST software (process Hazard Analysis Software) Max. credible Loss the worst accident situation is identified as Full Bore Rupture of LPG pipe line, Model (MAH- LPG-2) Distance of 89 Mtr shall be affected by heat radiation of 4.0 Kw/Sqm. The effect is minimized by green belt. We have mounded storage of LPG which has reduced the risk considerably. Appropriate Onsite measures have been taken by HPCL to minimize the damage preventing such accidents. In case of VCE Pool Fire as BLEVE applicable
(Damage distances in meters) Heat Radiation a) Severe Damage to life and property N/A (within cloud) b) 100% lethality (37.5 Kw/m2) 6.2 Mtr c) 50% lethality (25 Kw/m2) d) 10% lethality (12.5 Kw/m2) 44.7 Mtr e) first degree 4.5 Kw/m2 of burns 88.1 Mtr f) no discomfort 1.6 Kw/m2 g)Damage distance due to 0.3 bar pressure wave 9. b) Consequences of Major Hazards that Fire, Explosion are likely to occur in case of process upsets and storages. 10. Details of fire fighting equipments available in the factory a) No. of Fire fighting equipments and their capacity
i) Soda acid type -
93 ii) CO2 type 4 iii) DCP type 44 iv) Foam type - b) fire tender / Trailor pump and its Fixed type M V Sprinkler system is capacity available from all LPG areas c) Maximum quantity foam available. - d) Water jet monitors Nos. 19 DH Monitrs and 18 Jet monitors. e) water storage tank and its capacity : 2 x 2500 KL Tanks (5000 KL) f) No. of hydrant points :36 g) No. of hose reels and total length : 46, Length -15 m each h) No. of Fire Suit : 02 Low temp and 1 fire proximity 11. Details of communication available to : Telephone, pager system, Walky contact police and Fire brigade in case Talky stets. of emergency a) Telephone : 3 b) Hot line : c) wireless : 9 Walky talky 12. Public Alert system and its procedure Paging system with Amplispkers 13. List of protective equipments available Fire Proximity, Low temp suit & in factory gloves, helmets, rescuciters, Breathing Appratus, stretcher, electrical gloves etc i) No. & Type of emergency kit : 1 Nos rescue tools. ii)No. of Self contained breathing : 1 apparatus iii) No. of air line respirators : iv) No. of canister respirators : v) No. of acid suits : N/A vi) any other personal protective : All PPE are available in Central equipments. warehouse and given as and when required. vii) Neutralization facility provided for neutralizing chemicals. 14. Medical facility available in factory i) Equipments available in Ambulance : Have tie up with HP Refineries room medical group to handle medical emergency,. One jeep and a car is available for shifting casualty if any. ii) Antidotes available : N/A iii) No. of First aiders available : Five employees have trained in First aid. iv)Ambulance Van or alternate : One jeep and a car is avalable for arrangement shirting casualty if any. 1. Place of availability : In plant premises 2. Capacity : A/C two beds. 3. Facilities available in the van : stretchers. v) Details of hospitals in the vicinity and : Inlak Hospital, Shushrut Hospital, any the up with them. Mangal Anand, Sion Hospital 15. Provision of emergency lighting :One DG Set is available. 16. What other facilities are available : Mutual Aid Scheme is available outside the factory premises (Mutual Aid
94 scheme) 17. Available meteorological data a) wind Directions during part of the : N/W : September – March day S/W : April – August b) wind Speed (monthly) : Mean wind speed 6 knots. c) Rainfall (Average / Max. Record) 76 inch. d) Floods, Etc. : No. 18. Hazardous chemicals transported : No hazardous chemicals transported from the Refinery. a) Quantity at a time b) Name of the chemical c) type of carrier d) principal destination 19. Demographic segment map showing the : Refer attachment. area around factory within the physical range of worst scenario. 20 Whether separate area are specially : Parking space is available out side earmarked for parking of tankers in plant. factory / in the vicinity of factory is provided to avoid traffic congestion, if so details of thereof. 21. Site plan of factory showing internal : Refer attachment roads, location of storages of hazardous chemicals, buildings, etc. 22. Any other relevant information.
95 MAHINDRA & MAHINDRA (TRACTOR DIVISION) 1 FACTORY IDENTITY Mahindra & Mahindra Ltd. Tractor a. Name Division, (Farm Equipment Sector) Akurli Road, Kandivli (East). b. Address Mumbai – 400 101 c. Telephone / Tel: 2887 4651 to 2887 4670
Telex / Fax Nos. Fax: 2886 4670 d. (Location) Railway Line / Highways, Kandivli Station passing through / near the area. If so, Near NH-8 (Ahmedabad–Mumbai) details of Rail / Road, crossings / Village Poinsar, Town- Kandivli Bridges and water way vicinity North-Samata Nagar e. Details of Human Habitation (Village, South- Lokhandwala Complex City, Residential Colony, School, Public Lokhandwala Foundation School Pvt.
Place, Hospital etc.. near the Factory Garden of Lokhandwala Township within 1 Km. Dr. Vasa’s Hospital & Shopping Arcade
Mr. Sudhir Gharat , a. Contact Personnel of the Factory their 2 Controller of Operations Phone Nos. and Designation. Phone: b. Name of the Technical Experts, Mr. Arun Joshi Designation and their Phone Nos. Manager- Safety & Env. Residential No. Area of Specification. Phone : 9867038073 Manufacturing of Agricultural Tractors & 3 Principal Manufacturing Activities Equipments 4 Total No. of Workers Employed About, 5500 Maximum No. of persons, who may be 5 2500 present in the factory at any one time No. of workers directly involved with 6 95 the hazardous chemicals/shift total Maximum quantity of hazardous a) 32 tonnes of LPG in 3 bullets chemicals stored and their mode of (10+10+12) 7 storage (Raw Material, Intermediate b) 50 kg. of Ammonia stored in one Products, bye- Products, Finished cylinder. products) 8 Hazardous Analysis done Attach details Hazardous analysis done, details A with date attached. Maximum Credible Loss Scenario Effect of Accident release of LPG will a. TOXIC DISPERSION: depend on quantity of LPG and nearest Brief description of Maximum Credible location of ignition source. Toxicity Loss Scenario: index is 3.9. i.e. within specified range Chemical (S) involved:- of 6.oo. In Case of 8 i) Atmospheric Stable Neutral LPG ) B Stability ) Stable ii) Wind 2m/sec. Velocity Radial Ammonia ) distance around factory which could be affected in meters. -348 Metres iii) Toxicity a) DLH LPG AMMONIA
96 b) STEL 10% i.e.100000 PPM 5000 PPM c) TLV 1000 PPM 35 PPM 5000 PPM 46.8 PPM
b.IN CASE OF BLEVE,VCE, POOL L.P.G. – Explosive. FIRE AS APPLICABLE Ammonia – Difficult ignite.
Brief Description. If LPG vessel is involved in a Fire, it may overheat and rupture violently giving out intensely hog fire ball and may project pieces of the vessel over considerable distance. Max. credible BLEVE Loss Scenario Fire Ball Radius - 53 Mtr. Duration (Damage Distance in Metres) IV VCE Extensive Damage Duration -3.75 Sec. Heat Radiation a. Severe damage to life and property (within cloud) 57 Metres b. 100% Lethality (37.5 Kw/m2) 105.4 Metres c. 50 % Lethality (25 Kw/m2) 348 Metres d. 1% Lethality (12.5 Kw/m2) 500 Metres e. First Dogree 4.5 Kw/m2 600 Metres f. No. discomfort 1.6 Kw/m2 1000 Metres Demographic segment map showing the 9 area around factory within the physical Attached herewith range of worst scenario Details of Fire fighting equipments available in the factory a. No. of Fire equipments and their capacity 1. Soda Acid Type 9 ltrs.– 106 Nos, 22,5 kg –15 Nos. 10 2. Co2 Type 10 kg.–6 Nos. 3. DCP Type 7 Kg. –20 Nos. , 4.5 Kg. – 5 Nos. 4. Foam Type 6000 Lbs.–1 Nos., 45 Kg.–12 Nos. 10 Kg. – 62 Nos. 150 ltrs. – 15 Nos., 9 ltrs.- 135 Nos. b. Fire Tender/Trailor pump and its NIL (Exemption received) capacity c. Maximum quantity of FOAM available 100 Kg. 3 Nos. of Fixed Monitors on Hydrant d. Water Jet Monitors Nos. System e. Water Storage Tank and its capacity 1 Nos.-453000 lltrs.capacity f. No. of Hydrant Points 72 Nos. g. No. of hose reels and total length 72 Nos. Details of Communication available to 11 contact District Emergency Authority, Police & Fire Brigade and other agencies
97 in case of Emergency. a. Telephone b. Hot Line Yes c. Wireless - d. Mobile - e. Walky Talky etc... - Yes Yes speakers located on all the 5 Gates 12 Public Alert System and its Procedures Operated from Emergency Control Central List of Protective Equipment’s available in factory a. No. & Type of Emergency kit breathing apparatus Nil b. No. of self contained breathing apparatus Nil 13 c. No. of Air Line respirators Nil d. No. of Canister Respirators Nil e. No. of Acid Suits Nil f. Any other Personal Protective Hand gloves, Aprons, Shoes, Goggles Equipment required for routing work, g. Neutralisation facility available to Not Applicable Neutralise Chemicals (Aluminised Fire Suit available) Medical Facility available in Factory a. Equipments available in Ambulance b. Antidotes available in As per rule e.g. Oxygen, Stretcher & c. No. of First aiders available medicines. d. Ambulance Van or alternative Not Applicable arrangement 38 1. Place of availability 2 Nos. of Vans 14 2. Capacity 3. Facilities available in the Van Near Factory Gate e. Details of Hospitals in the vicinity and One injured each any tie up with them As above ESIS, Yashwant, Asha Parekh, Nanavati Hospital, with tie-up Dr. Vasa’s Hospital no tie-up. Emergency lights in key location e.g. 15 Provision of Emergency Lighting Dispensary, Emertgency Control of Centre. What Others Facilities are available Power driven Trailor Pump in Adjacent 16 outside the factory premises (Mutual Aid factory Scheme) Methods and Procedure to be followed by installation own, operators load Prescribed in “On Site Emergency Plan” 17 emergency and Medical, Personnel to & Practiced in Emergency Drills. respond to release of Hazardous Chemical. Hazardous Chemicals Incorporated : L.P.G. a. Quantity at a time 6 Tonnes is received in one trip 18 b. Name of the Chemical L.P.G. c. Type of carrier Tanker
98 d. Principal Destination e. Transporter’s Name L.J.Transport, Tel. No.- 556 6166 f. Contact Person M/s. Krishna Santosh & Tiwari Demographic segment map showing the 19 area around factory within the physical Attached herewith range of worst scenario. Whether separate area specially earmarked for parking of tankers in Suitable Area is earmarked outsid3e the 20 factory/ in the vicinity of factory is gate. provided to avoid traffic, If so details thereof. Site Plan of the factory showing internal 21 roads, location of storages of Hazardous Attached. chemicals, bldg. etc. Member-Chief Co-ordinator 22 Any other relevant information Mutual Aid Scheme Western region, Mumbai.
99 MAHINDRA & MAHINDRA LTD. (JEEP DIVISION) 1 FACTORY IDENTITY Mahindra & Mahindra Ltd., Central Jeep a. Name Plant, (Automotive Sector) Akurli Road, Kandivli (East). b. Address Mumbai – 400 101 c. Telephone / Tel: 2887 4601
Telex / Fax Nos. Fax: 2887 6739 d. (Location) Railway Line / Highways, Kandivli Station passing through / near the area. If so, Near NH-8 (Ahmedabad–Mumbai) details of Rail / Road, crossings / Village Poinsar, Town- Kandivli Bridges and water way vicinity e. Details of Human Habitation (Village, City, Residential Colony, School, Public North-Samata Nagar
Place, Hospital etc.. near the Factory South- Hanumannagar within 1 Km. Mr. V.K. Tuli a. Contact Personnel of the Factory their 2 Vice President - Operations Phone Nos. and Designation. Phone: 022 28467156 b. Name of the Technical Experts, Mr. G.M. Wagh Designation and their Phone Nos. Manager- Safety, Health & Env. Residential No. Area of Specification. Phone : 022 28467532 / 28467554 Manufacturing of Multi Utility Vehicles 3 Principal Manufacturing Activities (Jeeps) 4 Total No. of Workers Employed Around 3,500 Maximum No. of persons, who may be 5 2000 present in the factory at any one time No. of workers directly involved with 6 90 the hazardous chemicals/shift total Maximum quantity of hazardous a) 40 tonnes of LPG in 2 bullets chemicals stored and their mode of (10+30) 7 storage (Raw Material, Intermediate b) 50 kg. of Ammonia stored in four Products, bye- Products, Finished cylinders. products) 8 Hazardous Analysis done Attach details Hazardous analysis done, details A with date attached. Maximum Credible Loss Scenario Effect of Accident Leakage of LPG will a. TOXIC DISPERSION: depend on quantity of LPG and nearest Brief description of Maximum Credible location of ignition source. Toxicity Loss Scenario: index is 3.9. i.e. within specified range Chemical (S) involved:- of 6.oo. In Case of i) Atmospheric Stable Neutral LPG ) 8 Stability ) Stable B ii) Wind 2m/sec. Velocity Radial Ammonia ) distance around factory which could be affected in meters. -348 Metres iii) Toxicity d) DLH LPG AMMONIA e) STEL 10% i.e.100000 PPM 5000 PPM f) TLV 1000 PPM 35 PPM
100 5000 PPM 46.8 PPM
b.IN CASE OF BLEVE,VCE, POOL L.P.G. – Explosive. FIRE AS APPLICABLE Ammonia – Difficult to ignite.
Brief Description. If LPG vessel is involved in a Fire, it may overheat and rupture violently giving out intensely hog fire ball and may project pieces of the vessel over considerable distance. Max. credible BLEVE Loss Scenario Fire Ball Radius - 50 Mtr. Duration (Damage Distance in Metres) IV VCE Extensive Damage Duration 8.00 Sec. Heat Radiation a. Severe damage to life and property (within cloud) 57 Metres b. 100% Lethality (37.5 Kw/m2) 90 Metres c. 50 % Lethality (25 Kw/m2) 125 Metres d. 1% Lethality (12.5 Kw/m2) 160 Metres e. First Degree 4.5 Kw/m2 320 Metres f. No. discomfort 1.6 Kw/m2 510 Metres Demographic segment map showing the 9 area around factory within the physical Attached herewith range of worst scenario Details of Fire fighting equipments available in the factory a. No. of Fire equipments and their capacity 1. Soda Acid Type Nil.
2. Co2 Water Type 90 (9)
10 3. Foam Chemical Nil
4. Mechanical Foam 107 (9,45)
5.Dry Chemical Powder 387 (5,10,22.5,70)
6. Co2 Type 259 (2, 3.2, 4.5, 6.8, 9, 22.5)
b. Fire Tender/Trailor pump and its One capacity c. Maximum quantity of FOAM available 107 Fire Extinguishers (Foam) d. Water Jet Monitors Nos. 4 Nos. of Water Monitors. 50,000 gallons of water e. Water Storage Tank and its capacity Fire Tender 1250 Ltrs.
101 f. No. of Hydrant Points 66 Nos. g. No. of hose reels and total length 66 Nos., Length 7.5 Meter each
Details of Communication available to
contact District Emergency Authority,
Police & Fire Brigade and other agencies
in case of Emergency.
11 f. Telephone Yes g. Hot Line - h. Wireless - i. Mobile Yes j. Walky Talky etc... Yes Yes, Speakers located in the Product Units for internal communication and at 12 Public Alert System and its Procedures 22KV substation for external communication and Emergency Control Central List of Protective Equipment’s available in factory a. No. & Type of Emergency kit breathing apparatus 1 Ammonia Kit b. No. of self contained breathing apparatus 2 13 c. No. of Air Line respirators Nil d. No. of Canister Respirators Nil e. No. of Acid Suits Nil f. Any other Personal Protective Hand gloves, Aprons, Shoes, Goggles Equipment required for routing work, g. Neutralisation facility available to Not Applicable Neutralise Chemicals (Aluminized Fire Suit available) Medical Facility available in Factory a. Equipments available in Ambulance b. Antidotes available in AS PER RULE E.G. OXYGEN CYLINDER c. No. of First aiders available WITH MASK, STRETCHER & d. Ambulance Van or alternative MEDICINES. arrangement ANTI SNEAK VENOM. 1. Place of availability 129 2. Capacity 2 NOS. OF VANS 14 3. Facilities available in the Van e. Details of Hospitals in the vicinity and NEAR OCCUPATIONAL HEALTH CENTRE any tie up with them ONE INJURED EACH AS ABOVE ESIS HOSPITAL, SRI SAI HOSPITAL, SUCHAK HOSPITAL, BHAGWATI HOSPITAL NANAVATI HOSPITAL, Emergency lights in key location e.g. 15 Provision of Emergency Lighting OHC, Emergency Control Centre, HT Dept& other PU’s etc. What Others Facilities are available Power driven Trailor Pump in Adjacent 16 outside the factory premises (Mutual Aid factory of M&M, FES, who is also
102 Scheme) member of MARG
Methods and Procedure to be followed by installation own, operators load Prescribed in “On Site Emergency Plan” 17 emergency and Medical, Personnel to & Practiced in Emergency Mock Drills respond to release of Hazardous periodically. Chemical. Hazardous Chemicals Incorporated : L.P.G. g. Quantity at a time Around 12 Tonnes is received in one h. Name of the Chemical trip i. Type of carrier L.P.G.Tanker 18 j. Principal Destination Mahul k. Transporter’s Name SPN Transport l. Contact Person Tel. No.- 25066582 Mr. Y.A.Seth Demographic segment map showing the 19 area around factory within the physical Attached herewith range of worst scenario. Whether separate area specially earmarked for parking of tankers in Suitable Area is earmarked outside the 20 factory/ in the vicinity of factory is gate. provided to avoid traffic, If so details thereof. Site Plan of the factory showing internal 21 roads, location of storages of Hazardous Attached. chemicals, bldg. etc. Chief Convener- (M&M, A.S.) 22 Any other relevant information Mutual Aid Response Group (MARG) Western region, Mumbai.
103 PARLE PRODUCTS LIMITED.
1. FACTORY IDENTITY
a) Name : Parle Products Limited. b) Address Vile Parle (E), Mumbai - 400 057. c) Telephone NOS./ Telex / Fax Nos. / E-mail Address. d) (Location) Railway Line / Highways, Near Vile Parle north level passing through / near the area. If so, crossing. details of rail / road, crossings / bridges and water way vicinity. e) Details of Human habitation (Village, City, Residential colony. Hospital etc. near the factory etc. near the factory within 1 Km.) 2. a) Contact personnel of the factory their : B. K. Kotwal, Factory Manager, Phone Nos., Designations, Mobile Residence: 24361483 Phone Nos. R. S. Nevatia, Chief Engineer, Residence: 28320076 A. K. Gadiwala, Dy. Engineer, Residence: 26491972 G. Scares, Plant Services & Safety Manager Residence: 26406458 R. D. Panchal, Safety Officer. C. D. Kamat, Residence B. K. Nair, Manager Ptg. Residence:2 6127591 N. B. Patel, Manager (Pers & Admin.) R. Gopalan, Prod. Manager Confectionery Residence: 26211130 D. N. Shah, Manager Electrical Residence: 28374539 K. C. Gupta, Standard Executive, Residence: 25512753 S. S. Vichare, Prod. Manager Biscuits Residence:2 8324178 Mrs. Shelar, Nurse Residence: 4921786 Mrs. D'Souza, Jr. Officer - Medical Services. Residence: 6464996. Azad Gholkar, Personnel Officer, Residence: 5362512. D. B. Jha, Maintenance engineer. Residence: 8830541,
104 b) Name of the technical experts designation & their phone Nos. c) Name & phone nos. of incident & Site Controller. 3. Principal Manufacturing Activities Making Biscuits, Confectionery, Candies , Lozenges and Toffees. 4. Total No. of workers employed 5. Maximum No. of persons, who may be present in the factory at any one time. 6. No. of workers directly involved with the hazardous chemicals / shift / total. 7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Materials, Intermediate products, bye-products, finished products' Name of chemical Quantity stored Storage Quantity of method and chemical in the mode processing system Ammonia 20 Lts. Bullet LPG 81 Mt. Bullets Ethyl / Butyl 2400 Lts. MS Drums Acetate Toluene 20000 Lts. UG Tanks & drums Petrol 13600 Lts UG Tanks HSD 43600 Lts. UG Tank Furnace Oil 76000 Lts. UG Tank Caustic Soda 50 Kg. PVC Bag. 8. Maximum Credible Loss Scenario a) TOXIC DESPERSION : Brief description of Maximum Credible Loss Scenario : In case of i) Atmospheric Stability Stable Neutral Unstable ii) Wind Velocity 2 4 6 m/sec. m/sec. m/sec. Radial distance around factory which could be affected in metres Toxicity a) LC 50 b) STEL c) TLV b) In case of BLEVE, VCE, POOL FIRE as applicable Brief Description
105 Max. Credible Loss Scenario In case VCE Pool Fire of as BLEVE applicable (Damage distances in Metres) Heat Radiation Jet Flame The hazard is posed by storage of Liquefied Petroleum Gas (LPG) In case of leakage of LPG from the largest tank with a capacity of 30 Ton of LPG , the following scenarios are possible BLEVE VCE Jet Flame through the safety valve Pool fire is not considered as a possible event. A very preliminery step in any LPG storage is to have the ground below the tank slpoing so as to not to have any pool of LPG
The following tables give the damage distance in case of different possibilities. a) Severe Damage to life and property In case of In (within cloud) BLEVE caseof Jet flame b) 100% lethality (37.5 Kw/m2) 135 Met 16.30 c) 50% Lethality (25 Kw/m2) 170 Met 17.00 d) 1% Lethality (12.5 Kw/m2) 290 Met 19.30 e) First Degree 4.5 Kw/m2 of bums 440 Met 25.65 f) No discomfort 1.6 Kw/m2. 725 Met 38.30 g) Damage distance due to 0.3 bar pressure wave Over pressure bar Damage distance Effect (M) 745 High concentration of people e.g. Schools, Hospitals. 0.04 454 Domestic Housing 0.05 327 Public Road 0.07 254 Ordinary Plant Building 0.10 200 Building with shelter resistant windows, fixed roof tanks containing highly flammable or toxic materials 0.20 136 Floating roof tanks, other fixed roof tank, cooling towers, utility areas site roads. 0.30 091 Plant with large atmospheric pressure vessels 0.40 080 Other hazardous plants 0.70 058 Non-hazardous plants control room designed for blast resistance 9. Details of fire fighting equipments available in the factory
106 a) No. of Fire fighting equipments and their capacity i) Soda acid type : 9 Litres : 5 Nos. 45 Litres : 40 Nos. ii) CO2 Type : 2.0 Kg : 0.8 Kg : 10 Nos. 9.0 Kg : 20 Nos. 22.5 Kg. : 11 Nos. iii) DCP Type : 2.0 Kg. 10 Kg. : 42 Nos. iv) Foam Type : 9 Lts. : 20 Nos. 45 Lts. : 04 Nos. b) Fire tender / Trailor pump and its : 1000 GPM capacity c) Maximum quantity of foam available : 400 Lts. d) Water jet monitors Nos. : Fixed – 4 Nos. Mobile – 1 Nos. e) Water storage tank and its capacity : 105000 Gallons f) No. of Hydrant points : 37 Nos. g) No. of hose reels and total length h) No. of fire Suit : 02 Nos. 10. Details of communication available to contact Police and Firebrigade in case of emergency a) Telephone b) Hot Line c) Wireless 11. Public Alert System and its procedure 12. List of protective equipments available in factory i) No. & type of emergency kit : 2 Chemical Suits 1 Oxygen Kit ii) No. of self contained breathing apparatus iii) No. of air line respirators iv) No. of canister respirators v) No. of acid suits vi) Any other personal protective : 20 Ear plugs, Safety Belts. equipments vii) Neutralisation facility provided for : 12 Goggkes, 14 Helmets neutralizing chemicals 13. Medical facility available in factory i) Equipments available in Ambulance room ii) Antidotes available iii) No. of first aiders available
107 iv) Ambulance Van or alternate arrangement 1. Place of availability 2. Capacity 3. Facilities available in the van v) Details of hospitalsin the vicinity and any the up with them 14. Provision of emergency lighting 15. What other facilities are a available outside the factory premises (Mutual Aid Scheme) 16. Available Meterological data a) Wind Directions during part of the day b) Wind speed (Monthly) c) Rainfall (Average / Max. Record) d) Floods Etc. 17. Hazardous chemicals transported a) Quantity at a time b) Name of the chemical c) Type of carrier d) Principal destination 18. Demographic segment map showing the area around factory within the physical range of worst scenario. 19. Whether separate are specially earmarked for parking of tankers in factory / in the vicinity of factory is provided to avoid traffic congestion, if so details of thereof. 20. Site plan of factory showing internal roads, location of storages of hazardous chemicals, buildings etc. 21. Any other relevant information
108 RASHTRIYA CHEMICALS AND FERTILIZERS LTD, TROMBAY UNIT FACTORY IDENTITY
1. a) Name : Rashtriya Chemicals and Fertlisers Limited; Trombay Unit , Chembur. b) Address : Marvali, Chembur, Mumbai – 400 074. c) Telephone Nos./ : Phone : 2552 2201 – 10 Telex / Fax Nos./ Telex No. : 011-61037, 71228, 72250 RCF B - 1N Fax No. : 022 – 2552 2231 Telegram : Fertilizer d) (Location ) Railway Line / : Eastern Express Highway to the North Highways, passing through / near side RCF to Mahul Road to the South the area. If so , details of rail / side R C Marg , Kurla - Goods railway line to the East Side, creek at the West Side road, crossings / bridges and water way vicinity
e) Details of Human Habitation (Village, City, Residential colony, Hospitals etc. near factory within 1 Km.)
SCHOOLS OTHERS POPULATION
Swami Vivekandanda Chembur Police 65,000 Schools & College complex Station ( 3 school & 4 colleges) Mumbai Assembly of Good Day School,
Sind Cosmopolitan High Collector Colony, 85,000 School, Marvali Matta Urdu School , Loreto Convent Wadavali Village ,Golf High School, R.C.F. Colony Club, Ashish Theatre, Municipal Primary School, Chembur Colony, Municipal Primary School, R.C.F. Colony, R.C.F. Santan Dharma High Hospital, School, National Sarvodaya Inlak Hospital High School and Jr. College, Sadhu Vasvan High School
Jawahar Vidya Bhavan R.C.F Hospital, RCF 35,000 School and Jr. College Police Station Complex, Vashi Village , Vitta 35,000 St. Sebastian High School Sanchay Society
109 Vasant Dada Patil College of Stray Population 15,000 Engineering, Somaiya Trust Medical College
2. a) Contact Personnel of the factory, : Shri R. K. Jain, their Phone Nos., Designations, Mobile Exe. Director - Technical ,Occupier Office : 2552 2245 , Residence : 2766 0029
Shri Manoj Priya Chief General Manager (C), Manager Office : 2552 2260 , Residence : 2556 5041 b) Name of the Technical Experts, : Shri P.B.Asai, DGM(Tech. Services) Designation & their telephone Nos. Office : 2552 2347, Residence : 2558 3206
Shri C.M.Bisen ,CE(Safety & Fire) Office : 2552 2265 Residence : 2550 7624 Mobile : 9987036436 c) Name & phone nos. of Incident & Shri R. K. Jain, Site Controller Exe. Director - Technical ,Occupier Office : 2552 2245, Residence : 2766 0029 3 Principal Manufacturing Activities : Chemicals and Fertilisers
4. Total number of workers employed : 3000 ( RCF + Contactor + Temporary Contractor)
5. Maximum number of persons, who : 2000 may be present in factory at any one time
6. No. of workers directly involved with : Atmospheric Ammonia storage : 03 the storage of hazardous chemicals/ shift. Methyl amine storage : 05
110 7. Maximum quantity of hazardous Chemical Max. Mode of chemicals stored and their mode of Storage Storage Storage storage. (Raw materials, Intermediate (MT) products, By products, Finished Ammonia Double wall products) 5000 X 2 double integrated, dyked, Atmospheric, refrigerated storage tanks. Methanol 4930 (539 X 2) Fix Conical (2660 X 1) roof vertical (840 X 1) Tanks (260 X 1) (45 X 2)
Methyl 247 Vertical amine (50.5 X 2) Pressurized (Anhydrou (61 X 2) Storage s) (24 X 1) Tanks with relief valves
& header, connected to hot flare 8. Maximum Credible Loss Scenario :
A) TOXIC DISPERSION :
Brief description of Maximum Credible : Release through 6" NB outlet of New Loss Scenario : 5000 X 2 nos Atm. Ammonia storage tanks.
In case of
i) Atmospheric Stability Stable Neutral Unstable
ii) Wind velocity 2m/s 4m/s 6m/s
Radial distance and population around factory which could be affected in meters
Toxicity
a) LC 50 ( 4837 ppm ) 250 100 100
111 b) STEL ------c) TLV ------d) IDLH ( 300 ppm ) 1000 800 800
Brief description of Maximum Credible : Methylamine liquid leak from 1.5 “ Loss Scenario : pipeline from tank bottom..
In case of i) Atmospheric Stability Stable Neutral Unstable ii) Wind velocity 2m/s 4m/s 6m/s
Radial distance and population around factory which could be affected in meters
Toxicity (Anhydrous Ammonia) a) LC 50 : 4837 ppm ( mouse) 250 100 100 b) IDLH ( 500 ppm ) 1000 800 800 c) IDLH ( 100 ppm ) 663 573 NA
B) In Case of BLEVE, VCE, POOL FIRE as applicable
Brief Description
Maximum Credible Loss Scenario In Case of VCE POOL FIRE BLEVE as applicable (Damage Distances in Meters)
Heat Radiation a) Severe Damage to life and NA NA NA property ( within cloud ) b) 100% Lethality (37.5 Kw/m2) NA NA NA c) 50% Lethality (25 Kw/m2) NA NA NA d) 1% Lethality (12.5 Kw/m2) NA NA NA e) First Degree 4.5 Kw/m2 of burns NA NA NA f) No discomfort 1.6 Kw/m2. NA NA NA
112 9. a) Damage distance due to 0.3 bar Ammonia-V Chemical Damage pressure plant Distance in wave Meters(Pres sure wave 0.3 ) Primary Methane -- Reformer
Secondary Hydrogen 216 reformer
Methanator Hydrogen 389
Synthesis Hydrogen 837 Converter
1 Consequences of Major Hazards that No off-site consequences 0 are likely to occur in case of process upsets and storage. 1 Details of fire fighting equipments 1 available in the factory a) No. of fire fighting equipments and their capacity i) Soda acid type -- ii) CO2 type 500 iii) DCP type 600 iv) Foam type 050 b) Fire Tenders/Trailer pump with Foam Tenders - 2 Nos. with 1350 lts. capacity Foam & 2250 lts. Water and 2000 lts. Foam and 200 lts. Water capacities respectively. DCP cum foam tender - One number with 1000 lts. Foam , 2000 lts. water and 1000 kgs. DCP capacity. c) Max. Quantity of foam available : 3000 lts d) Water jet monitors nos. : 10 Nos. e) Water storage tank & its capacity : 0.33 million gallons
f) No. of Hydrant points : 273 g) No. of hose reels & total length : 60 hoses of 75 ft. Each h) No. of fire suits : 10 nos.
113 SANUJ STEELS PVT LTD 1 FACTORY IDENTITY a) Name Sanuj Steels Pvt Ltd. b) Address D R Container Yard Jeejamata Nagar Mahul Road, ,Chembur, Mumbai – 400 074. c) Telephone Nos./ 2553 8325 Telex / Fax Nos./ 9371160657
E-mail Address : [email protected] d) (Location) Railway Line / Highways, : Jeejamata Nagar passing through / near the area. If so, details of rail / road, crossings / bridges and water way vicinity. e) Details of human habitation (Village, : North side : BPT Road City, Residential colony, Hospital etc. South side : Mithul Enclave. near the factory etc. near the factory West side : Jijamata Nagar within 1 km.) East Side : BPCL Refinery 2. a) Contact personnel of the factory Nitin Kharg (Occupier) their 9371432000 Phone Nos., Designations, Mobile Phone Nos. Dharmesh Sampat 9371160657
Sachin Nair 9967292194 3. Principal Manufacturing Activities (Plant Bottling LPG Cylinders wise) 4. Total No. of workers employed : 50 5. Maximum No. of persons, who may be : 25 present in the factory at any one time. 6. No. of workers directly involved with the 25. hazardous chemicals/ shift/ total. 7. Maximum quantity of hazardous LPG – 20 MT chemicals stored and their mode of storage (raw Materials, Intermediate products, bye-products, finished products). 8. Maximum Credible Loss scenario ; Not Applicable a) TOXIC DISPERSION : 9. b) Consequences of Major Hazards that Fire, Explosion are likely to occur in case of process upsets and storages. 10. Details of fire fighting equipments 15 DCP Extingusiehes available in the factory 15 CO2 Extinguishers b) fire tender / Trailor pump and its Fixed type Sprinkler system in filling capacity shed and storage of LPG c) Maximum quantity foam available. - d) Water jet monitors Nos. Hosepipes. e) water storage tank and its capacity : 3 tanks 1 lac ltrs each
114 f) No. of hydrant points : g) No. of hose reels and total length : 6, hoses -15 m each h) No. of Fire Suit : to be procured 11. Details of communication available to : Telephone, several mobiles contact police and Fire brigade in case of emergency 12. Public Alert system and its procedure Fire siren installed at main gate 13. List of protective equipments available No equipment in factory 14. Medical facility available in factory A few wheeler in case of emergency A first aid kit Details of hospitals LTMG hospital sion KEM hospital, Satapdi Muni Hosp 15. Provision of emergency lighting :DG Set of 25 KV incase of power failure. 16. What other facilities are available : Mutual Aid Scheme in trombay, outside the factory premises (Mutual Aid chembur 14 members in cluding scheme) Mumbai fire brigade 18. Hazardous chemicals transported : Not applicable. 19. Demographic segment map showing the : Refer attachment. area around factory within the physical range of worst scenario. 22. Any other relevant information.
115 HINDUSTAN PETROLEUM CORP LTD : AVIATION FUEL STATION
1. FACTORY IDENTITY
a) Name Hindustan Petroleum Corpn Ltd
Aviation Fuel Station
b) Address Chatrapati Shivaji International Airport, Sahar, Mumbai
c) Telephone Nos. / Phone : 26156284
Telex / Fax Nos. / Fax: 26156285
E-mail Address Email : [email protected]
d) (Location) Railway Line / Highways, Sahar International Airport. passing through / near the area. Is so, details of rail / road, crossings / bridges and water way vicinity
e) Details of Human habitation (Village, Slum area, Airport activities. City, Residential colony, Hospital etc. near the factory etc. near the factory within 1 Km.)
2. a. Contact personnel of the Factory their Mr. Shamim Ahamad phone Nos. and Designation O-26156285 b) Name of the Technical Experts, Designation and their Phone Nos. 9004870093 Residential No. Area of Specification
3. Principal manufacturing Activities Storage of ATF and Fueling of Aircrafts
4. Total no. of workers employed 55
5. Maximum no. of persons who may be 25 present in the factory at any one time
6. No. of workers directly involved with the persons per shift hazardous chemicals shift total
7. Maximum quantity of hazardous ATF in atmospheric storage tanks chemicals stored and their mode of storage (Raw material, intermediate 17830KL
116 products, Bye products. Finished product)
8. Hazardous analysis done Yes/No Yes, Consequences analysis of Attach details with date storage 8. Maximum Credible loss Scenario Tank fire
a) TOXIC DISPERSION Not applicable
b) Consequences of Major Hazards that Not significant are likely to occur in case of process upsets and storages 9. Demographic segment map showing the Annexure 1 & Annexure – 1A area around factory within the physical range of worst scenario 10 Details of fire fighting equipments Hydrants available in the factory 11. Details of communication available to Telephone, walky talky contact police and firebrigade in case of emergency 12. Public Alert System and its procedure Yes
13. List of protective equipments available in SCBA, Suit factory 14 Medical facility available in factory
15. Provision of emergency lighting Yes
16. What other facilities are available outside IOCL, Airport Fire Station the factory premises (Mutual Aid Scheme) 17. Methods and procedures to be followed by installation own, operators load emergency and medical personnel to respond to release of hazardous chemical. 18. Hazardous Chemicals Transported - a) Quantity at a time b) Name of the chemical c) Type of carrier d) Principal destination 19. Demographic segment map showing the area around factory within the physical range of worst scenario 20. Whether separate area specially earmarked for parking of tankers in factory in the vicinity of factory is provided to avoid traffic. Is so details thereof. 21. Site plan of the factory showing internal roads, locations of storages of hazardous chemicals, bldg, etc. 22. Any other relevant information
117
INDIAN OIL CORP LTD : AVIATION FUEL STATION
1. FACTORY IDENTITY
a) Name Indian Oil Corporation Ltd
Aviation Fuel Station
b) Address Chatrapati Shivaji International Airport, Sahar, Mumbai
c) Telephone Nos. / Phone : 2682 8561
Telex / Fax Nos. / Fax: 2682 9301
E-mail Address Email : [email protected]
d) (Location) Railway Line / Highways, Sahar International Airport. passing through / near the area. Is so, details of rail / road, crossings / bridges and water way vicinity e) Details of Human habitation (Village, Slum area, Airport activities. City, Residential colony, Hospital etc. near the factory etc. near the factory within 1 Km.) 2. a. Contact personnel of the Factory their Mr. Vinayak Mokashi phone Nos. and Designation O-2682 8561 b) Name of the Technical Experts, 98209 18187 Designation and their Phone Nos. Residential No. Area of Specification 3. Principal manufacturing Activities Storage of ATF and Fueling of Aircrafts 4. Total no. of workers employed 55
5. Maximum no. of persons who may be 25 present in the factory at any one time 6. No. of workers directly involved with the persons per shift hazardous chemicals shift total 7. Maximum quantity of hazardous ATF in atmospheric storage tanks chemicals stored and their mode of storage (Raw material, intermediate 17830KL products, Bye products. Finished product) 8. Hazardous analysis done Yes/No Yes, Consequences analysis of Attach details with date storage
118 8. Maximum Credible loss Scenario Tank fire
a) TOXIC DISPERSION Not applicable
b) Consequences of Major Hazards that Not significant are likely to occur in case of process upsets and storages 9. Demographic segment map showing the Annexure 1 & Annexure – 1A area around factory within the physical range of worst scenario 10 Details of fire fighting equipments Hydrants available in the factory 11. Details of communication available to Telephone, walky talky contact police and firebrigade in case of emergency 12. Public Alert System and its procedure Yes
13. List of protective equipments available in SCBA, Suit factory 14 Medical facility available in factory
15. Provision of emergency lighting Yes
16. What other facilities are available outside IOCL, Airport Fire Station the factory premises (Mutual Aid Scheme) 17. Methods and procedures to be followed by installation own, operators load emergency and medical personnel to respond to release of hazardous chemical. 18. Hazardous Chemicals Transported - a) Quantity at a time b) Name of the chemical c) Type of carrier d) Principal destination 19. Demographic segment map showing the area around factory within the physical range of worst scenario 20. Whether separate area specially earmarked for parking of tankers in factory in the vicinity of factory is provided to avoid traffic. Is so details thereof. 21. Site plan of the factory showing internal roads, locations of storages of hazardous chemicals, bldg, etc. 22. Any other relevant information
119 SEA LORD CONTAINERS LIMITED
1. FACTORY IDENTITY a) Name Sea Lord Containers Ltd.
b) Address Ambapada, Mahul Village, Near BPCL Refinery main gate, Chembur, Mumbai - 74 c) Telephone Nos. / Phone : 2553 5523, 2553 5524. Telex /Fax Nos. / Fax : 25546093. E-mail Address. d) (Location) Railway Line / Highways, passing through / near the area. If so, details of rail / road, crossings /bridges and water way vicinity. e) Details of Human habitation None within a Km (village, City, Residential colony. Hospital etc. near the factory etc. near the factory within 1 Km.) 2. a) Contact personnel of the factory P P Kudchadkar – Vice President their Office Phone: 25535520; Phone Nos., Designations, Mobile Mobile: 9821118907
M A Bohari, Office Phone: 25544832; Mobile: 9987273489 . b) Name of the technical experts Dr. S. K. Biswas, designation & their phOone Nos. Group Advisor (Safety & Environment) Office Phone : 2057076 / 2082242. Residence Phone- 2183288
S. K. Hazra, Managing Director, Phone: 2057076 / 2082242 Mobile: 9821018104; Residence : 2185743
D. J. Kulkarni, Advisor Fire fighting, Office Phone : 7241740 Residence Phone: 5153548. c) Name & phone nos. of incident & D. K. Bheda, (LPG), Site Office Phone: 5544975: Controller. Residence Phone: 7801427. 3. Principal Manufacturing Activities It is not a manufacturing unit. It is a terminal for storing bulk liquid Chemicals and liquefied petrochemical.
120 4. Total No. of workers employed 50 Nos.
5. Maximum No. of persons, who may 30 Nos. (General Shift) be present in the factory at any one time.
6. No. of workers directly involved 7 Nos. with the hazardous chemicals / shift / total. 7. Maximum quantity of hazardous Liquid Chemicals: Methanol/Hexane chemicals stored and their mode of Maximum quantity in storage at one storage (Raw Materials, time 75,000 T in atmospheric tanks. Intermediate products, bye- products, finished products). 8. Maximum'Credible Loss Scenario:
a) TOXIC DISPERSION: Not Applicable.
Brief description of Maximum Credible Loss Scenario In case of:
i) Atmospheric Stability Stable Neutral Unstable
ii) Wind Velocity 2m/sec 4 m/sec 6 m/sec
b) IN CASE OF BLEVE, VCE, POOL FIRE AS APPLICABLE
Max. Credible Loss Scenario In case of VCE Pool Fire as BLEVE applicable Worst case scenario is fire in bund area due to LPG tank leak. It is a Non-Credible Scenario (Probability once in one billion years) Heat Radiation
a) Severe Damage to life and property (within cloud) b) 100% lethality (37.5 Kw/m2) None.
c) 50% Lethality (25 Kw/m2)
d) 1% Lethalitv (12.5 Kw/m2)
e) First Deciree 4.5 Kw/m2 No credible off-site effect
f) No discomfort 1.6 Kw/m2.
a) Damage distance due to 0.3 bar pressure
121 9. Consequences of Major Hazards No pressing activity involved. that are likely to occur in case of Fire inside the terminal because process of spillage, even it occurs wilt upsets and storage. be contained within the terminals.
10. Resources Available
Details of fire fighting equipments available in the factory a) Fire tender / Trailer pump and its Fire Tender Water Tank Capacity : capacity 3000 Litres. Foam tank capacity : 1000 Litres. 2270 lpm at 7 kg/cm2. b) Maximum quantity of foam : 5000 Litres. available. ATC
c) Water storage tank and its : 8600 m3 non-saline water. capacity
d) No. of hose reels and total length : 66Nos.X1bm.
h) No. of fire Suit : 01 Nos
11. Details of communication available to contact Police and Fire brigade in case of emergency a) Telephone : 25535523/25535524/64506793
b) Hot Line
c) Wireless
d)Walkie Talkies etc. 9 Nos. Walkie talkie.
12. Public Alert System and its Long distance Electrical Siren (5 procedure Km).
13. List of protective equipments available in Factory i) No. & type of emergency kit First Aid Box -4 Nos.
ii) No. of Self contained 1 Set. breathing apparatus iii) No. of air line respirators 1 Nos.
iv) No: of canister respirators : 10 Nos.
v) No. of acid suits. : PVC suit.
122 vi) Any other personal : Helmet, Face shield. Safety protective goggles, equipments. ear plugs, ear muffs, hand gloves, Safety shoes, blowman mask.
14. Medical facility available in factory : N. A.
i) Equipments available in Ambulance room. ii) Antidotes available : N. A.
iii) No. of first aiders available : 28 Nos.
iv) Ambulance Van or alternate : Jeep – 2 Nos arrangement v) Details of hospitals in the vicinity : Permanent arrangement with and any the up with them. Inlaks Hospital, Chembur Colony. 15. Provision of emergency lighting : Yes.
16. Hazardous chemicals transported
a) Quantity (MT / day) 400 1600
b) Name of the Chemical Methanol Hexane
c) Type of carrier Tanker tanker
d) Principal destination
17. Site plan of factory showing internal . roads, location of storages of hazardous chemicals, buildings etc. 22. Any other relevant information
123
ANNEXURE – II
OFFISTE PIPELINES CARRYING HAZARDOUS MAERIAL IN MUMBAI
SUBURBAN DISTRICT
124 AEGIS CHEMICAL INDUSTRIES LTD PETROCHEMICALS / POL PRODUCTS
S. DESCRIPTION DETAILS No.
1. NAME OF FACTORY Aegis Chemical Industries Ltd., Mahul
2. MATERIAL BEING TRANSPORTED / RECEIVED Petrochemicals / POL Products
3. PIPELINE DETAILS : 12” -2 No’s (From new jetty) & a) Diameter 6” – 1 No. (from old jetty) in b) Length all three pipelines
(applicable to Mumbai Suburban District) 4.6 Km 12” each & 22 Km 6” 5 Kg/cm2 g c) Operating Pressure 300 MT/Hr for 12” & 120 d) Flow/Hr MT/Hr for 6”
e) Above ground / Underground Above ground
4. ROUTE OF PIPELINE Schematic attached as annexure
5. TYPE OF EMERGENCY FIRE
6. POPULATION LIKELY TO BE AFFECTED None within one km.
7. SAFETY MEASURES TAKEN Continuous patrolling along the piping route is being down during ship unloading/loading to detect leakage. The following safety measures exists/undertaken :
a) Manually operated isolation valves provided on each lines in the jetties and at Terminal for stopping unloading/loading operation.
b) During ship unloading/loading of liquid cargoes, Security Personnel carry out patrolling of
125 pipeline.
8. EMERGENCY PREPAREDNESS In case any leakage is observed, patrolling personnel will inform Duty Officer at the Terminal promptly and also the officer at the jetty. Thereafter the following actions will be taken immediately.
a) Shutting of Manual valves at the jetty and terminal
b) Stop pumping from terminal or from the ship.
c) Cordon off the area. Avoid any spark/open flame. Restrict entry to people and vehicles engaged in controlling the situation.
d) Inform MBPT fire station. Rush aegis fire tender to affected area.
e) Spray Foam on the spilled product. Arrange for attending the leakage and collection of product.
9. CONTACT PERSONS AND THEIR PHONE NOS. Terminal Officer 5544832 : Extn 19
Mr. S.K. Sawant, Vice President 5546721, 5544832 Extn : 10
Mr. D.K. Bheda, General Mgr. 5544975, 5544832 Extn : 11
Mr. P. H. Darji, Chief Term. Mgr. 5541105, 5544832 Extn. 14
Mr. R. M. Mahajan, Dy Mgr. Ops Security Officer 5544832
5544832 Extn. 31
126 AEGIS CHEMICAL INDUSTRIES LTD– LPG/PROPANE
S. DESCRIPTION DETAILS No
1. NAME OF FACTORY Aegis Chemical Industries Ltd., Mahul
2. MATERIAL BEING TRANSPORTED / RECEIVED Petrochemicals / POL Products
3. PIPELINE DETAILS :
a) Diameter 12” Main unloading line with 6” chaling line b) Length 4.6 Km each (applicable to Mumbai Suburban District) 5 Kg/cm2 g
c) Operating Pressure
d) Flow/Hr 400 MT/Hr. Maximum
e) Above ground / Underground Above ground
4. ROUTE OF PIPELINE Attached as annexure
5. TYPE OF EMERGENCY Fire / Explosion
6. POPULATION LIKELY TO BE AFFECTED None within one km.
7. SAFETY MEASURES TAKEN Continuous patrolling by Engineering personnel during ship loading to detect any leak. The following safety measures exists/undertaken :
a) Automatic emergency shutdown by immediate closing of SOV at the new pirpau jetty in case of failure of unloading pipeline.
b) Remote controlled system (ESD) located far away from the unloading arm at jetty for closing of emergency so for immediate stopping of unloading operation.
c) Gas detectors are provided along the pipeline at specific
127 location as well as jetties.
d) Automatic emergency closure of SOV in case of gas detection.
e) Automatic emergency closure of SOV on unloading arm envelop going in red zone.
f) Interlinking of ship shore ESD whenever ship has interlinking facility, on agreement with ship master
g) During ship unloading engineers carry out patrolling of pipeline with portable gas detectors & communication devices
h) 2 Nos manually operated isolation valves in the jetty for isolation
8. EMERGENCY PREPAREDNESS In case any leakage is observed, engineer on patrolling duty will immediately inform,
a) Terminal Officer in Ship
b) Operator at unloading jetty
c) Terminal Control room personnel Sinultaneously following actions will be initiated
a) Automatic / Remote control closure of SOV at Jetty
b) Automatic stoppage of ship pump
c) Shutting of manual valves at the jetty and valve manifold
d) Cordon off the area Avoid any spark / open flame Restrict entry to people &
128 vehicles engaged in controlling the emergency
e) Inform MbPT fire station Rush Aegis fire tender to affected area
f) Disperse gas leak with water spray from fire tender and other water source
9. CONTACT PERSONS AND THEIR PHONE NOS. Control Room Operator : 2541514
25544832 Extn 30
Mr. S. K. Sawant, Vice President
25546721 25544832 Extn : 10
Mr. D. K. Bheda, General Mgr. 25544975, 25544832 Extn : 11
Security Officer 5544832 Extn 31
129 BHARAT PETROLEUM CORPORATION LTD- HSD / MS /KERO
S.NO. DESCRIPTION DETAILS
1. NAME OF FACTORY Bharat Petroleum Corporation Limited
2. MATERIALS BEING a. High Speed Diesel TRANSPORTED/RECEIVED b. Motor Spirit
c. Superior Kerosene
3. PIPELINE DETAILS :
a. Diameter 18 inches
b. Length 116 Km (Mumbai to Igatpuri taluka entry point) (Applicable to Mumbai suburban district)
c. Pressure 57.5 – 10 kg/cm2
d. Flow/Hr 650 – 700 M3/Hr
e. Above ground/below ground Burried line
4. ROUTE OF PIPELINE Route along with topography of the line enclosed
5. TYPE OF EMERGENCY Fire/Hydrocarbon leak
6. POPULATION LIKELY TO BE 500 Hutment at Sathe nagar area in AFFECTED Mankhurd
7. SAFETY MEASURES TAKEN : a) Catholic protection and 3 ply extruded polyethylene coating upto first 47 km and coal tar enamel coating for the rest to avoid external corrosion
b) Pumping of corrosion inhabitor to protect inner surface
c) Supervisory control and data acquisition system (SCADA) for on line monitoring and control of pipeline and to detect the leaks.
d) Round the clock surveillance of P/L in city region and single shift surveillance for the rest of pipeline.
e) Provision of sectionalizing valves between sensitive sections for isolating a particular section in case of any
130 emergency.
f) Quarterly line inspections are carried out by all officers to familiarize the route as well as to check for leak/pilferage, encroachments etc.
8. EMERGENCY a) Dedicated phones and hot lines PREPAREDNES between control rooms along the pipeline b) A dedicated emergency rescue vehicle with crew, kept at Mumbai control room round the clock. c) All engineers and selected higher officials of MMPL have been provided with pagers and mobile phones. Respectively to get them at short notice in the event of an emergency. d) All three control rooms are manned by engineers round the clock. e) Roles and responsibilities of each officers are laid down to tackle any emergency situation. f) All important Phone numbers such as Civil Police, Factories, Fire Brigade Authorities etc. are kept in all control rooms.
9. CONTACT PERSONS AND THEIR PHONE NOS.
a) Mr.G.S.Wankhede 25545540 (0) Chief Operations 25685363 (Resd.) Manager 9820048707
b) Mr. N. Manohar Rao 9820039527 Sr.Manager(M&C) 25543151 Extn. 3865 2554408 (Resd.) c) Mr.V.B.Sharma Sr. Mgr. Operations 25545540 (Office) 8402560 (Resd.) d) Control Room, Mumbai Extn 25545540 9820037151 e) Fire Station, BPCL(R) 25545480 f) Asst. Commandant, CISF, BPCL (R) 25543175
131 GAS AUTHORITY OF INDIA (GAIL) : NATURAL GAS
S.NO. DESCRIPTION DETAILS
1. NAME OF FACTORY Gas Authority of India Limited
2. MATERIAL BEING Natural Gas TRANSPORTED/RECEIVED
3. PIPELINE DETAILS
a) Diameter 1. Trombay – RCF pipeline = 18”
2. Trombay – MGL pipeline = 18”
b) Length 1. Trombay – RCF pipeline = 5.5 Kms 2. Trombay = MGL pipeline = 7.7 Kms.
Both 25 – 40 kg./Sq.cm c) Pressure 1. Trombay – RCF pipeline = 75000 SCM/Hr
2. Trombay – MGL pipeline = 16600 d) Flow/Hour SCM/Hr.
3. Trombay – RCF pipeline U/G 2.7, A/G:2.8
e) Above ground 1. Trombay – MGL pipeline U/G 7.1, A/G:0.6 (AG)/Underground (UG) (Kms.)
4. ROUTER OF THE PIPELINE Both the pipelines are routed between ONGCL, Trombay near BARC through BPT/BPCL areas and RCF. Route sketch attached as Annexure
5. TYPE OF EMERGENCY Fire only
6. POPULATION LIKELY TO BE Both pipelines are routed through AFFECTED industrial premises of BPT/BPCL and RCF through non-residential areas.
7. SAFETY MEASURES TAKEN 1. Both the pipelines are designed as per the Industry Code ANSI B 31.8 with due allowances for class locations and isolation valves at vantage points 2. Pipeline is provided with anti- corrosion coatings and supplemented with Impressed current Catholic Protection system. 3. Dedicated communication network and SCADA (Supervisory Control and Data Acquisition) for monitoring the
132 various parameters on real time basis. 4. Remote operated isolation valves are provided on both the pipelines for isolation and safe evacuation of line contents in case of emergency. 5. Routine Patrolling of pipeline is carried out to monitor and control any activity in the pipeline route. 8. EMERGENCY PREPAREDNESS a) Control room manned round the clock is functioning from City Gate station Opp. Anik Bus Depot, Wadala. This center is provided with Supervisory Control and Data Acquisition System (SCADA) to monitor pipeline operation and safety. Vehicle is also available at this centre round the clock. b) Emergency items such as leak champs hydrotested pipes, etc. are kept in stock to contain the leak online. c) GAIL has no process plants in the area and hence no dedicated fire brigade is envisaged. However, GAIL has joined the Mutual Aid Scheme of Trombay area industries for aid at times of emergencies. 9. CONTACT PERSONS AND Master Control Room THEIR PHONE NUMBERS 4070156 / 4070129 Mr. AK Purwaha General Manager 6542321 (O) 6542064 ® Mr. Shyam Sunder Sr Manager O & M 6541935 (O) 6508840 ® MBAA Sr Manager HR 6542373 (O) 6527464 ® Mr RK Kamra Manager Finance 6541731 (O) 6542385 ®
133 HINDUSTAN PETROLEUM CORPORATION (ATF) S NO DESCRIPTION DETAILS 1 NAME OF FACTORY Hindustan Petroleum Corporation Limited 2 MATERIAL BEING ATF (Aviation Turbine Fuel) TRANSPORTED / RECEIVED 3 PIPELINE DETAILS a. Diameter 10 inches O.D.
b. Length 19.65 km (applicable to Mumbai Suburban District)
c. Pressure 10 Kg.sq.cm.
d. Flow/Hr 250 KL/Hr
e. Above Underground ground/underground 4 ROUTE OF PIPELINE HPFR- BPCR-RCF-NERUNAGAR-KURLA – SANTACRUZ AIRPORT-SAHARAIRPORT Route sketch attached. 5. TYPE OF EMERGENCY Oil Spillage / Fire 6 POPULATION LIKELY TO BE Line passes through non-population / non AFFECTED residential area 7 SAFETY MEASURES TAKEN a. Line walkers provided in three shifts b. Pressure/Flow rates closely monitored during pumping at both the ends. c. Line is inspected and tested as per statutory norms. 8 EMERGENCY PREPAREDNESS a. marketing group has an emergency crew which can attend all the pipeline emergencies. b. Refinery also gives additional help as and when required 9 CONTACT PERSONS AND 1. Shift Terminal In-charge : THEIR PHONE NOS. 26156285/86/26156453/26156892
2. Dy Manager OM&S : 25544133
134 HINDUSTAN PETROLEUM CORPORATION LTD : MS/HSD/KERO
S NO DESCRIPTION DETAILS 1 NAME OF FACTORY 2 MATERIAL BEING MS/HSD/SKO TRANSPORTED / RECEIVED 3 PIPELINE DETAILS f. Diameter 14 inches O.D.
g. Length 162.17 + 342 km (applicable to Mumbai 12 Km (refinery to vashi bridge toll naka) Suburban District)
h. Pressure 58.0 Kg.sq.cm.
i. Flow/Hr 600 KL/Hr
j. Above Underground ground/underground 4 ROUTE OF PIPELINE Route sketch attached as annexure 5. TYPE OF EMERGENCY Fire / explosion 6 POPULATION LIKELY TO BE MPSPL AFFECTED 7 SAFETY MEASURES TAKEN All MPPL locations are provided with adequate nos of DCP extinguishers, CO2 extinguishers, fire hydrant, monitors, sand buckets and fire hoses. To take care of offsite, foam tender, gully emptier, compressor truck are available 8 EMERGENCY PREPAREDNESS Disaster control plan for Onsite and Offsite is prepared and responsibilities are assigned to individuals 9 CONTACT PERSONS AND THEIR PHONE NOS. OFFICE Residance A B Thosar – Gen Mgr 22614352 25306561
Suranjan Pal – Ch Mgr 25542184
V K Singh – Manager 25544266 27530628
S K Mohapatra – Mgr Maint 25540555
135 HINDUSTAN PETROLEUM CORPORATION LTD : FO / LDO
S NO DESCRIPTION DETAILS 1 NAME OF FACTORY Hindustan Petroleum Corporation Ltd 2 MATERIAL BEING FO / LDO (Fuel Oil / Light Diesl Oil) TRANSPORTED / RECEIVED 3 PIPELINE DETAILS k. Diameter 12 inches O.D.
l. Length 21 km (applicable to Mumbai Suburban District) m. Pressure 20 Kg.sq.cm. n. Flow/Hr 90 KL/Hr – 320 Kls/hr o. Above ground/underground Underground 4 ROUTE OF PIPELINE BOPL line passes in the same alignment but on the other side of the road. 5. TYPE OF EMERGENCY Fire 6 POPULATION LIKELY TO BE MPSPL AFFECTED 7 SAFETY MEASURES TAKEN All MPPL locations are provided with adequate nos of DCP extinguishers, CO2 extinguishers, fire hydrant, monitors, sand buckets and fire hoses. To take care of offsite, foam tender, gully emptier, compressor truck are available 8 EMERGENCY PREPAREDNESS Disaster control plan for Onsite and Offsite is prepared and responsibilities are assigned to individuals 9 CONTACT PERSONS AND THEIR PHONE NOS. OFFICE Residance A B Thosar – Gen Mgr 22614352 25306561
Suranjan Pal – Ch Mgr 25542184
V K Singh – Manager 25544266 27530628
S K Mohapatra – Mgr Maint 25540555
136 INDIAN PETROCHEMICALS CORP. LTD : PROPANE (LIQUID)
S. DESCRIPTION DETAILS NO 1. NAME OF FACTORY M/s Indian Petrochemicals Corp. Ltd., Nagothane 2. MATERIAL BEING Propane liquid TRANSPORTED/ RECEIVED 3. PIPELINE DETAILS a. Diametre 4” NB b. Length 2000 MTR Apprx. Upto Pirpau jetty and further 11.7 Km in Thane creek upto Shivaji Nagar Land fall point.
c. Pressure 74.00 KG/CM2
d. Flow/Hr. 15 T/HR.
e. Above ground/ Above ground upto Pirpau jetty and sub sea Underground (Kms) in the Thane creek 4. ROUTE OF PIPELINE Route sketch attached as Annexure 5. TYPE OF EMERGENCY Fire / explosion 6. POPULATION LIKELY Within the vicinity of BPCL Refinery. Tata TO BE AFFECTED Electrical and Mumbai Port Trust area. 7. SAFETY MEASURES 1. Catholic protection of the pipeline TAKEN 2. Dedicated telecommunications system from HALPG to MGCC. Nagothane 3. Installation of sectuibalising valve at Shivajinagar to get the portion HALPG to thane creek isolated 4. Off-shore security for round the clock in thane creek. 8. EMERGENCY For any fire fighting requirements M/s PREPAREDNESS BPCL, HALPG and Mumbai Port Trust can be requested as per mutual aid basis scheme of understanding 9. CONTACT PERSONSAND THEIR PHONENOS 021442 2280 2323 Extn. 2165 a. Mr. S. RAvikumar – ED (NC) b. Mr. J.L. Wazir – GM (O) 021442 2280 2317 Extn. 2301 c. Mr. M.A. Venkatraman – DGM (O) 021442 2280 2434 Extn. 2093 d. Mr. W.P. Vittal – Sr. Manager (GC) 021441 2280 2431 Extn. e. Mr. K.K. Jain – Mgr. Pipelines 021442 2280 2424 Extn 2095
137 MAHANAGAR GAS LTD.: NATURAL GAS
S. DESCRIPTION DETAILS NO
1. NAME OF FACTORY Mahanagar Gas Ltd. 2. ADDRESS Pay & Accounts Building Bandra Kurla Complex Bandra (East) Mumbai 400 051
Tel. : 6541708 / 6542675 / 6541705 Fax : 91-22-6542156 3. MATERIAL BEING Natural Gas TRANSPORTED/ RECEIVED 4. PIPELINE DETAILS The steel Grid mains system is constructed to British Gas and internationally accepted Diametre Length Pressure standards and is fully welded system. Flow/Hr. To date approximately 58 kms are laid at a Above ground/ diameters between 3” – 18” Underground The operating pressure of the steel Grid pipeline is 19 Bar All pipe is laid below ground at 1.2 m cover. For protection a sand surround is provided with protective marker tape above with warnings in two languages. The flow rate is dependent on the demand of the network and varies throughout the day and also day to day. 5. ROUTE OF PIPELINE Route sketch attached as Annexure 6. TYPE OF EMERGENCY The potential emergency situation from the 19 bar system is predominately i) release of natural gas ii) subsequent ignition fire To date no incidence of this nature has arisen 7. POPULATION LIKELY The population affected will be dependant TO BE AFFECTED on the type/location of any incident. Pipeline route planning takes considerations of dense population 8. SAFETY MEASURES Apart from the above safety precautions TAKEN mentioned, the system is fully protected from corrosion by a PE coating and catholic protection system. Isolation valves are positioned at a strategic positions to unable specific sections to be isolated in case of emergency. Mahanagar Gas ltd employs pipeline patrolman who continually survey the route of our system to ensure no third party works are being undertaken nearby and to educate other utilities in awareness regarding our plant.
138 As natural gas is odourless odour is added at our supply point to the network. Weekly checks at various system points ensure that correct levels are present. Safety awareness programmes are carried out in each gas supply area to ensure that customers and members of the public are educated in our product. 9. EMERGENCY Full emergency procedures are in place to PREPAREDNESS deal with any potential scenario that may occur on our system MGL has an emergency control Centre with one telephone contact number (4012400). This control centre is linked by a communication system to 3 emergency response locations. These locations have fully mobile emergency crew led by trained technicians. This emergency source operates 24Hrs X 365 days. 10. CONTACT PERSONS A rota system exists for all levels of AND THEIR PHONE attendance at emergency situations, up to NOS the Technical and Managing Director level. Again contact is through the one emergency telephone no 401 2400
139 RASHTRIYA CHEMICALS & FERTILIZERS LTD.: NATURAL GAS
S. DESCRIPTION DETAILS NO 1. NAME OF FACTORY Rashtriya Chemicals & Fertilizers Ltd., Trombay Unit 2. MATERIAL Natural Gas BEINGTRANSPORTED/RECEIVED 3. PIPELINE DETAILS a. Length of pipeline 5.5 Kms. (only 400 meters is along the Mahul road and remaining inside b. Dia of pipe line BPT/BPCL/Tata/RCF Trombay c. Pressure 18” d. Flow 26 Kg/cm2 to 36 kg/cm2 e. Above/Underground 2.5 MMCMD Line is above ground and under ground 400 meters outside R.C.F. is under ground
4. ROUTE OF PIPELINE Attached as Annexure 5. TYPE OF EMERGENCY Fire/Explosion 6. POPULATION LIKELY About 2500 people (Jeejamata Nagar and TO BE AFFECTED few hosuing societies adjacent to R.C.F.) 7. SAFETY MEASURES Inspection by gas detector. Under ground TAKEN section has been protected by Catholic Protection 8. EMERGENCY GAIL has no established Fire fighting PREPAREDNESS department. GAIL and ONGC are members of Mutual aid scheme for Chembur – Trombay region. During emergency Mutual aid scheme will be activated. Identification of source of leakage and its control and then appropriate measures like isolation of gas supply from ONGC/GAIL, evacuation of population etc. will be taken. (depending upon the nature and severity) 9. NAME AND PHONE NOS. OF From GAIL KEY PERSONS TO BE 1. Mr. Shyamsunder, Sr. O.M. CONTACTED IN CASE OF Off. 654 1935 Res. 650 8840 EMERGENCY 2. Shift in Charge M.C.R. Phone No. 407 0156/407 0129 Shift In Charge R.C.F. Terminal Phone No. 5585067 From R.C.F. Ltd. Fire Station : 558 0387 Work Manager : 556 5879 / 556 1780
140 RELIANCE INDUSTRIAL INFRA LTD: NAPHTHA / KERO
S. DESCRIPTION DETAILS NO
1. NAME OF FACTORY Reliance Industrial Infrastructure Limited 2. MATERIAL BEING Naphtha / Kerosene TRANSPORTED/ RECEIVED 3. PIPELINE DETAILS Between BPCL Mahul Refinery & RIL, PG
a. Diametre 200 mm NB Twin Pipelines
b. Length 10.5 KM (Total length 54 kms.) (applicable to Mumbai Suburban District) 55 Kg/cm2 c. Operating Pressure 200 M3/Hr d. Flow/Hr.
e. Above ground/ Underground Underground 4. ROUTE OF PIPELINE Route sketch attached as Annexure 5. TYPE OF EMERGENCY Fire 6. POPULATION LIKELY - TO BE AFFECTED 7. SAFETY MEASURES Periodical Check up and type of check up :- TAKEN Our pipelines are coated with coal tar coating plus pipelines are provided with Impressed current catholic protection system.
Reading of all the test points, where level of Cathodic Protection is reas, en route the pipeline and cathodic protection stations, are taken on every fortnight basis. The increase, decrease in current level, other steps are arranged on this feedback.
In addition to this, physical surveillance of the pipeline route is carried out daily on round the clock basis through foot patrol.
Detection of Leakage : Our pipelines are provided with Supervisory Control and Data Acquisition (SCADA) System, which shows the operating pressure, flow rate etc. Same is monitored in our Patalganga Control Room on 24 hrs.
141 Basis.
The system gives alarm if the pressure loss is 0.05 kg/cm2/sec. Or the volume difference is 5 m3/hr or 2m3/30min. Or 1 m3/6min. Between despatch and receiving end. 8. EMERGENCY PREPAREDNESS Emergency Tool Kit with on-line high pressure leak arresting clamp is kept ready at our JNPT Terminal. In case of any abnormal pressure drop / volume loss, the pumping is stopped immediately.
The pipelines are provided with isolation valves at intermediate stations which can be remotely operated from Control Room.
During emergency, these valves will be closed to isolate the section and identify the exact location. Meantime, team will arrest the leakage with high pressure clamp. In addition to above, Fire Tenders, Ambulance are available with our Patalganga Plant for 24 hours.
9. CONTACT PERSONS Patalganga Control Room : 91450705 AND THEIR PHONE JNPT Terminal C/R : 7242145 NOS JNPT Terminal Security : 7242143 BPCL C/R : 5540151
Extn.3491/3492/3497
Shri A.S. Desai, GM (B.M. & S) :- 7242141 (O), 6553461 ® Shri F.M.K. Gouda, Ops. Manager 91450705 (O), 7450016 ®
142 TATA POWER COMPANY LIMITED : NATURAL GAS
S. DESCRIPTION DETAILS NO
1. NAME OF FACTORY Tata Power Company Ltd, Trombay Thermal Generating Station, Mahul Road, Chembur, Mumbai – 400 074 2. MATERIAL BEING Natural gas being received via off-site TRANSPORTED/ pipeline from Gas Authority of India RECEIVED No hazardous material being transported via offsite pipeline 3. PIPELINE DETAILS For units 4, 5, & 6 For unit 7
a. Diameter 450 mm 300 mm
b. Length 150 m 200 m (applicable to Mumbai Approx. Approx. Suburban District)
c. Pressure 7 bar 30 to 40 bars
d. Flow per hour 110 tons/hr 30 tons/hr
e. Above ground/ Maximum Maximum Underground Underground Abovegound
4. ROUTE OF PIPELINE This pipeline is location near drainage channel (along Mumbai Port Trust road) entering in Tata Electric premises. Route sketch attached as Annexure 5. TYPE OF EMERGENCY Natural gas leak and subsequent fire : TOXIC RELEASE / FIRE / EXPLOSION 6. POPULATION LIKELY Since this pipeline is located near drainage TO BE AFFECTED channel (along Mumbai Port Trust road which lies within plots of Tata Electric Company, no external population is likely to be affected. 7. SAFETY MEASURES a. Relief valve and cold flare system TAKEN b. External visual inspection per quarter c. Thickness measurement per annum as per statutory requirement d. Provision of remote operated valve on one line. For another line, this system in being installed. 8. EMERGENCY a. Full fledged fire station with fire fighting PREPAREDNESS crew exists. b. On-site emergency management plan is practiced periodically c. Mutual aid scheme (MAS) exists within
143 major industries in Chembur Trombay area. Interactive meetings are held by members regularly.
9. CONTACT PERSONS AND THEIR PHONE OFFICE RESIDENCE NOS a. Ashok Sethi – 6717 5114 6717 4004 Vice President b. A P Wankhede – General Mgr. 6717 5104 25542194
144 ROLE OF FIREBRIGADE PREAMBLE
Section 359 to 364 of B. M. C. Act 1888 provide for maintenance of Fire Brigade by the Municipal Corporation of Greater Mumbai. It also provides that all the Municipal Officers and Police Officers to assist Fire Brigade while dealing with the fire emergencies all kind of emergencies which include House Collapses, Chemical Leakage's, Gas Leakage's, Rail, Road and Air Accidents, Floods and Earthquakes, or in short, in addition to the fire fighting, the brigade offers the services on humanitarian grounds, whenever and wherever any human life is in distress, expect in the cases of epidemics.
Throughout the world, over the period of time, large scale chemical industries have been established which contain potential fire as well as chemical and gas leakage's risk. There have been number of serious disaster resulting in death of thousands of people and also destruction of properties. It has become necessary to prepare for the disasters in advance so that loss of life and property can be minimized.
As is know, the magnitude of disasters cannot be anticipated nor the resources can be separately created for management of disasters. It is also a common knowledge that there are number of Government, Semi-Government agencies who have requisite equipment and manpower to deal with routine or normal anticipated emergencies. For preparedness to a major disaster, it would be therefore, necessary to co-ordinate the services of all these agencies under one umbrella upgrade the same wherever necessary and see that all the services are available to deal with the disaster within a shortest possible time Annexure - 'A' shows the agencies which are available in the City of Mumbai whose works need to be co- ordinated for attendance to a disaster.
Depending upon the type and seriousness of emergency as a matter of routine the services of Hydraulic Department, Sewerage Department, Buildin Department, Ward Office, Municipal Labour Contractors, Police, Homeguards Civil Defense, B.E.S.T., B.S.E. S., Municipal and Government Hospitals, Bomba Port Trust, Private Ambulances, Mutual - Aid - Schemes, Air-Port Fire Service and also the Fire services from Thane, Vashi etc. Are requisitioned by Mumbai Fire Bridgade in the event of an emergency. The enclosed Annexures 'A', 'B', 'C 'D', 'E', and 'F' give details information regarding the location of Fire Stations availability of various type of Fire Appliances, Fire Engines etc., names an addresses of senior officers, manpower posted at each fire station.
CONTROL ROOM : The Mumbai Fire Brigade has its Control Room situated at Fire Brigade Headquaters, Byculla which is manned with adequate number of staff coatinuously
145 for 24 hours and headed by Divisional Officer (Mobilization assisted by Duty Officer of the rank of Sub-Officer in each shift. The Control Room can be contacted in case of emergency on Telephone Nos. 101, 3095191 3076111 and 3086171.
HEALTH SERVICES ORGANISATION Introduction Mumbai is a major financial commercial and industrial City of India. It is linked with the world through air, sea and road. The people from all over India come to this city in search of livelihood. It is estimated that about 300 families migrate to city of Mumbai every day.
The land available is about 437.71 Square Kilometre and population is 99,26,000 as per 1991 census. The density of population is about 22,677 per Square Kilometer, which is very high. The cost of land and its development is exorbitant, which a common man cannot afford. Thus, slums have developed on almost all the available vacant lands including footpaths.
Greater Mumbai is divided in 3 welt-defined areas, viz. City Western Suburbs and Eastern (Central) Suburbs on account of its peculiar geographical position. The city consists of A, B, C, D, E, F, and G administrative municipal wards. Western suburbs consists H, K, P and R Wards while the Eastern Suburbs, also called as Central Suburbs, has L, M., N., and T., Wards.
21 hazardous chemical factories are located in Mumbai Suburban District. Chemical factories in Belapur - Thane -Raigad are also within easy reach of Mumbai. The population in the Eastern Suburbs is about 24,70,476 lakhs as per 1991 census and the land available is 156.93 Square Kilometres. The population in the Western Suburbs us about 42,80,526 lakhs and the land available is 212.99 Square Kilometer. Hence density of population in this suburbs is 13,237 Square Kilometer. Thus, the calamities affecting Eastern Suburbs (or for that matter any part of Mumbai) may result into extensive damage to the life and property.
The Municipal Commissioner, heads the administration of the Corporation. In this, he is assisted by two additional Municipal Commissioner and Deputy Municipal Commissioners. Executive Health Office remains at the helm of Public Health matters. He is responsible to additional Municipal Commissioner. He is assisted in his day-to- day work by four Deputy Executive Health Officers, nine Assistant Health Officers and many other assistants.
Since the disasters striking Mumbai - shall involve health and life of the public, Health Officer shall be in over all control of health management in case of disaster organisation Chart is put up at Annexure - 1.
INFRASTRUCTURE
146 The Mumbai Municipal Corporation provides the most comprehensive Health services to citizens. There are 3 major Hospitals with medical colleges and one Dental College, each one is under the charge of a Dean. One infectious Diseases Hospital one Tuberculosis Hospital, one E. N. T. Hospital and One Eye Hospital, all these hospitals are located in city area. There are 13 General Hospitals located in suburbs (Eastern and Western). Each Hospital is managed by either Medical Superintendents or medical Officers. The Director of Peripheral (Suburban) Hospital is in over all control of these Hospitals Total number of above general hospital beds is 7,318. These Hospitals provide general, special and super-special services to citizens in all the fields of medicines, surgery, maternal and child health etc. Detection and diagnosis of diseases is done by qualified, experience and skilled medical and para-medical staff. Each Hospital has well equipped laboratory, X-ray machines and most modem other equipment's like Sonography - CAT Scan, etc. Intensive Care Units for all sorts of emergencies are also available in these Hospitals. Treatments is given with advanced new generations drugs which also include chemo-theraphy, Radio-theraphy, Pnysio-theraphy, Occupational Therapy is also given to the patients. The major hospitals in the city have their own blood banks while in suburbs most of them have to depend upon private blood banks, list of blood banks is attached. At least one ambulance appropriately equipped with emergency kit is attached to each Hospital and most of the Hospitals have mortuary and hearse-. There are two Coroner's Court, one in J. J. Hospital Compound and another in Cooper Hospital in K/West Ward of Western Suburbs have 7 general Hospitals, located in different wards with bed strength of 1,281 beds. Each Hospital is given number of direct telephone lines and department within the hospital are connected with Inter-com system. Residential Medical Officers are also provided with telephone connection. There are about 150 Municipal dispensaries in Greater Mumbai which work like Out Patient Departments, of these 33 are located in Eastern Suburbs. AMBULANCE SERVICE : The list of Ambulance services in Eastern Suburbs with location and telephone number is given in the list. Each ambulance shall be equipped with :- • Stretcher • Blanket • Oxygen Cylinder • Incubation Kit • Pain Killers • V. Set • First Aid / Resuscitation Kit.
147
148
ANNEXURE – III
INFORMATION ON CHEMICALS AT THE MAJOR HAZRD UNIT FACTORIES IN MUMBAI SUBURBAN DISTRICT
149 CHEMICALS AT THE MAH FACTORIES IN MUMBAI SUBURBAN DISTRICT
NAME OF CHEMICAL 1. ACETONE 2. AMMONIA 3. ASPHALT 4. BENZENE 5. BUTADIENE 6. CHLORINE 7. DIESEL 8. DIMETHYLAMINE 9. GASOLENE 10. HEXANE 11. HYDROGEN 12. ISOPROPYL ALCOHOL 13. KEROSENE 14. LIQUEFIED PETROLEUM GAS 15. MONOMETHYLAMINE 16. METHANOL 17. NAPTHA, COAL TAR 18. NITRIC ACID 19. PARA-XYLENE 20. PROPANE 21. SULPHUR 22. STYRENE 23. SULPHURIC ACID 24. TURPENTINE OIL 25. TRIMETHYLAMINE 26. TOLUNE 27. XYLENE
Chemical Information Annexure - III : 1 ACETONE 0087 April 1994 CAS No: 67-64-1 2-Propanone RTECS No: AL3150000 Dimethyl ketone UN No: 1090 Methyl ketone EC No: 606-001-00-8 C3H6O / CH3-CO-CH3 Molecular mass: 58.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Highly flammable. NO open flames, NO sparks, and NO Powder, alcohol-resistant foam, smoking. water in large amounts, carbon dioxide.
EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, In case of fire: keep drums, etc., cool explosion-proof electrical equipment by spraying with water. and lighting. Do NOT use compressed air for filling, discharging, or handling.
EXPOSURE
Inhalation Sore throat. Cough. Confusion. Ventilation, local exhaust, or breathing Fresh air, rest. Refer for medical Headache. Dizziness. Drowsiness. protection. attention. Unconsciousness.
Skin Dry skin. Protective gloves. Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes Redness. Pain. Blurred vision. Safety spectacles or face shield. First rinse with plenty of water for Possible corneal damage. Contact lenses should not be worn. several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Nausea. Vomiting. (Further see Do not eat, drink, or smoke during Rinse mouth. Refer for medical Inhalation). (Further see Inhalation). work. attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Ventilation. Collect leaking liquid in sealable F Symbol containers. Absorb remaining liquid in sand or inert Xi Symbol absorbent and remove to safe place. Do NOT wash R: 11-36-66-67 away into sewer. Then wash away with plenty of S: (2-)9-16-26 water. Personal protection: self-contained breathing UN Hazard Class: 3 apparatus. UN Pack Group: II
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30S1090 Fireproof. Separated from strong oxidants. NFPA Code: H 1; F 3; R 0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 2 0087 ACETONE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation and through the skin. Physical dangers The vapour is heavier than air and may travel along the ground; Inhalation risk distant ignition possible. A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20/C ; on spraying or Chemical dangers dispersing, however, much faster. The substance can form explosive peroxides on contact with strong oxidants such as acetic acid, nitric acid, hydrogen Effects of short-term exposure peroxide. Reacts with chloroform and bromoform under basic The vapour irritates the eyes and the respiratory tract. The conditions, causing fire and explosion hazard. Attacks plastic. substance may cause effects on the central nervous system, liver, kidneys and gastrointestinal tract. Occupational exposure limits TLV: 500 ppm as TWA, 750 ppm as STEL; A4 (not classifiable as Effects of long-term or repeated exposure a human carcinogen); BEI issued; (ACGIH 2004). Repeated or prolonged contact with skin may cause dermatitis. MAK: 500 ppm 1200 mg/m3 Peak limitation category: I(2); The substance may have effects on the blood and bone marrow. Pregnancy risk group: IIc; (DFG 2004).
PHYSICAL PROPERTIES
Boiling point: 56/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.2 Melting point: -95/C Flash point: -18/C c.c. Relative density (water = 1): 0.8 Auto-ignition temperature: 465/C Solubility in water: miscible Explosive limits, vol% in air: 2.2-13 Vapour pressure, kPa at 20/C: 24 Octanol/water partition coefficient as log Pow: -0.24 Relative vapour density (air = 1): 2.0
ENVIRONMENTAL DATA
NOTES
Use of alcoholic beverages enhances the harmful effect. Card has been partly updated in October 2005. See sections Occupational Exposure Limits, EU classification.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2005 Chemical Information Annexure - III : 3 AMMONIA (ANHYDROUS) 0414 March 1998 CAS No: 7664-41-7 (cylinder)
RTECS No: BO0875000 NH3 UN No: 1005 Molecular mass: 17.03 EC No: 007-001-00-5
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Flammable. NO open flames, NO sparks, and NO In case of fire in the surroundings: smoking. use appropriate extinguishing media.
EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation, In case of fire: keep cylinder cool by explosion-proof electrical equipment spraying with water. and lighting.
EXPOSURE AVOID ALL CONTACT!
Inhalation Burning sensation. Cough. Ventilation, local exhaust, or breathing Fresh air, rest. Half-upright position. Laboured breathing. Shortness of protection. Artificial respiration may be needed. breath. Sore throat. Symptoms may Refer for medical attention. be delayed (see Notes).
Skin Redness. Skin burns. Pain. Blisters. Cold-insulating gloves. Protective ON FROSTBITE: rinse with plenty of ON CONTACT WITH LIQUID: clothing. water, do NOT remove clothes. FROSTBITE. Refer for medical attention.
Eyes Redness. Pain. Severe deep burns. Face shield or eye protection in First rinse with plenty of water for combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor. Ingestion
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! Ventilation. T Symbol NEVER direct water jet on liquid. Remove gas with N Symbol fine water spray. Personal protection: gas-tight R: 10-23-34-50 chemical protection suit including self-contained S: (1/2-)9-16-26-36/37/39-45-61 breathing apparatus. UN Hazard Class: 2.3 UN Subsidiary Risks: 8
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-20S1005 or Fireproof. Separated from oxidants, acids, halogens. Cool. Keep in a 20G2TC well-ventilated room. NFPA Code: H3; F1; R0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 4 0414 AMMONIA (ANHYDROUS)
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS COMPRESSED LIQUEFIED GAS, WITH The substance can be absorbed into the body by inhalation. PUNGENT ODOUR. Inhalation risk Physical dangers A harmful concentration of this gas in the air will be reached very The gas is lighter than air. quickly on loss of containment.
Chemical dangers Effects of short-term exposure Shock-sensitive compounds are formed with mercury, silver and The substance is corrosive to the eyes, the skin and the gold oxides. The substance is a strong base, it reacts violently respiratory tract. Inhalation of high concentrations may cause lung with acid and is corrosive. Reacts violently with strong oxidants oedema (see Notes). Rapid evaporation of the liquid may cause and halogens. Attacks copper, aluminum, zinc and their alloys. frostbite. Dissolves in water evolving heat.
Occupational exposure limits TLV: 25 ppm as TWA; 35 ppm as STEL; (ACGIH 2004). MAK: 20 ppm, 14 mg/m3; Peak limitation category: I(2); Pregnancy risk group: C; (DFG 2004).
PHYSICAL PROPERTIES
Boiling point: -33/C Vapour pressure, kPa at 26/C: 1013 Melting point: -78/C Relative vapour density (air = 1): 0.59 Relative density (water = 1): 0.7 at -33/C Auto-ignition temperature: 651/C Solubility in water, g/100 ml at 20/C: 54 Explosive limits, vol% in air: 15-28
ENVIRONMENTAL DATA
The substance is very toxic to aquatic organisms.
NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered. Turn leaking cylinder with the leak up to prevent escape of gas in liquid state. Card has been partly updated in October 2005. See sections Occupational Exposure Limits, Emergency Response.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2005 Chemical Information Annexure - III : 5 ASPHALT 0612 October 2004 CAS No: 8052-42-4 Bitumen RTECS No: CI9900000 Petroleum bitumen UN No: 1999
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Combustible. Dry powder, carbon dioxide, foam. NO water. EXPLOSION
EXPOSURE AVOID ALL CONTACT!
Inhalation Cough. Shortness of breath. Ventilation. Local exhaust or Fresh air, rest. breathing protection.
Skin On contact with heated material Heat-insulating gloves. Protective Rinse with plenty of water, do NOT serious skin burns. clothing. remove clothes. Refer for medical attention.
Eyes Redness. Pain. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Do not eat, drink, or smoke during work. Wash hands before eating.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Let solidify. Sweep spilled substance into containers. UN Hazard Class: 3 UN Pack Group: III
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30GF1-III (only for the hot product)
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 6 0612 ASPHALT
IMPORTANT DATA Physical State; Appearance Routes of exposure DARK BROWN OR BLACK SOLID. The substance can be absorbed into the body by inhalation of fumes. Occupational exposure limits TLV: asphalt (bitumen) fume as benzene-soluble aerosol, 0.5 Inhalation risk mg/m3 as TWA; A4 (not classifiable as a human carcinogen); Evaporation at 20/C is negligible; a harmful concentration of (ACGIH 2004). airborne particles can, however, be reached quickly when MAK: (vapour and aerosol) skin absorption (H); Carcinogen dispersed or when heated. category: 2; (DFG 2004). Effects of short-term exposure The substance is irritating to the eyes and the respiratory tract. The substance when heated causes burns on the skin.
Effects of long-term or repeated exposure Fumes of this substance are possibly carcinogenic to humans.
PHYSICAL PROPERTIES
Boiling point: above 300/C Solubility in water: none Melting point: 54-173/C Flash point: above 200/C c.c Relative density (water = 1): 1.0-1.18 Auto-ignition temperature: above 400/C
ENVIRONMENTAL DATA
NOTES
Do NOT take working clothes home. Card has been partly updated in October 2005. See section Occupational Exposure Limits.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2005 Chemical Information Annexure - III : 7 BENZENE 0015 May 2003 CAS No: 71-43-2 Cyclohexatriene RTECS No: CY1400000 Benzol
UN No: 1114 C6H6 EC No: 601-020-00-8 Molecular mass: 78.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Highly flammable. NO open flames, NO sparks, and Powder, AFFF, foam, carbon NO smoking. dioxide.
EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, In case of fire: keep drums, etc., Risk of fire and explosion: see explosion-proof electrical equipment cool by spraying with water. Chemical Dangers. and lighting. Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools. Prevent build-up of electrostatic charges (e.g., by grounding).
EXPOSURE AVOID ALL CONTACT!
Inhalation Dizziness. Drowsiness. Headache. Ventilation, local exhaust, or Fresh air, rest. Refer for medical Nausea. Shortness of breath. breathing protection. attention. Convulsions. Unconsciousness.
Skin MAY BE ABSORBED! Dry skin. Protective gloves. Protective Remove contaminated clothes. Redness. Pain. (Further see clothing. Rinse skin with plenty of water or Inhalation). shower. Refer for medical attention.
Eyes Redness. Pain. Face shield, or eye protection in First rinse with plenty of water for combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Abdominal pain. Sore throat. Do not eat, drink, or smoke during Rinse mouth. Do NOT induce Vomiting. (Further see Inhalation). work. vomiting. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Remove all ignition sources. Collect leaking and F Symbol Do not transport with food and spilled liquid in sealable containers as far as T Symbol feedstuffs. possible. Absorb remaining liquid in sand or inert R: 45-46-11-36/38-48/23/24/25-65 absorbent and remove to safe place. Do NOT wash S: 53-45 away into sewer. Do NOT let this chemical enter the Note: E environment. Personal protection: complete UN Hazard Class: 3 protective clothing including self-contained breathing UN Pack Group: II apparatus.
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30S1114 / Fireproof. Separated from food and feedstuffs oxidants and halogens. 30GF1-II NFPA Code: H2; F3; R0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2004 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 8 0015 BENZENE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation, through the skin and by ingestion. Physical dangers The vapour is heavier than air and may travel along the ground; Inhalation risk distant ignition possible. As a result of flow, agitation, etc., A harmful contamination of the air can be reached very quickly electrostatic charges can be generated. on evaporation of this substance at 20/C.
Chemical dangers Effects of short-term exposure Reacts violently with oxidants, nitric acid, sulfuric acid and The substance is irritating to the eyes, the skin and the halogens causing fire and explosion hazard. Attacks plastic and respiratory tract. Swallowing the liquid may cause aspiration into rubber. the lungs with the risk of chemical pneumonitis. The substance may cause effects on the central nervous system, resulting in Occupational exposure limits lowering of consciousness. Exposure far above the occupational TLV: 0.5 ppm as TWA; 2.5 ppm as STEL; (skin); A1; BEI issued; exposure limit value may result in unconsciousness and death. (ACGIH 2004). MAK: H; Carcinogen category: 1; Germ cell mutagen group: 3A; Effects of long-term or repeated exposure (DFG 2004). The liquid defats the skin. The substance may have effects on the bone marrow and immune system, resulting in a decrease of blood cells. This substance is carcinogenic to humans.
PHYSICAL PROPERTIES
Boiling point: 80/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.2 Melting point: 6/C Flash point: -11/C c.c. Relative density (water = 1): 0.88 Auto-ignition temperature: 498/C Solubility in water, g/100 ml at 25/C: 0.18 Explosive limits, vol% in air: 1.2-8.0 Vapour pressure, kPa at 20/C: 10 Octanol/water partition coefficient as log Pow: 2.13 Relative vapour density (air = 1): 2.7
ENVIRONMENTAL DATA
The substance is very toxic to aquatic organisms.
NOTES
Use of alcoholic beverages enhances the harmful effect. Depending on the degree of exposure, periodic medical examination is indicated. The odour warning when the exposure limit value is exceeded is insufficient. Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
©IPCS 2004 Chemical Information Annexure - III : 9 1,3-BUTADIENE 0017 April 2000 CAS No: 106-99-0 Divinyl RTECS No: EI9275000 Vinylethylene
UN No: 1010 (stabilized) C4H6 / CH2=(CH)2=CH2 EC No: 601-013-00-X Molecular mass: 54.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Extremely flammable. NO open flames, NO sparks, and Shut off supply; if not possible and NO smoking. no risk to surroundings, let the fire burn itself out; in other cases extinguish with water spray, powder, carbon dioxide.
EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation, In case of fire: keep cylinder cool by explosion-proof electrical equipment spraying with water. and lighting. Prevent build-up of electrostatic charges (e.g., by grounding) if in liquid state.
EXPOSURE AVOID ALL CONTACT! AVOID EXPOSURE OF (PREGNANT) WOMEN!
Inhalation Cough. Sore throat. Dizziness. Ventilation, local exhaust, or Fresh air, rest. Refer for medical Headache. Drowsiness. Blurred breathing protection. attention. vision. Nausea. Unconsciousness.
Skin ON CONTACT WITH LIQUID: Cold-insulating gloves. ON FROSTBITE: rinse with plenty FROSTBITE. of water, do NOT remove clothes. Refer for medical attention.
Eyes Redness. Pain. Blurred vision. See Safety goggles. First rinse with plenty of water for Skin. several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Do not eat, drink, or smoke during work.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! F+ Symbol Do not transport with food and Ventilation. NEVER direct water jet on liquid. T Symbol feedstuffs. Remove all ignition sources. Chemical protection R: 45-46-12 suit including self-contained breathing apparatus. S: 53-45 Note: D UN Hazard Class: 2.1
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-20S1010 Fireproof. Cool. Separated from food and feedstuffs. NFPA Code: H2; F4; R2
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 10 0017 1,3-BUTADIENE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS COMPRESSED LIQUEFIED GAS, WITH The substance can be absorbed into the body by inhalation. CHARACTERISTIC ODOUR. Inhalation risk Physical dangers A harmful concentration of this gas in the air will be reached The gas is heavier than air and may travel along the ground; very quickly on loss of containment. distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated. The vapours are Effects of short-term exposure uninhibited and may form polymers in vents or flame arresters of The substance irritates the eyes and the respiratory tract. Rapid storage tanks, resulting in blockage of vents. evaporation of the liquid may cause frostbite. The substance may cause effects on the central nervous system, resulting in Chemical dangers lowering of consciousness. The substance can under specific circumstances (exposure to air) form peroxides, initiating explosive polymerization. The Effects of long-term or repeated exposure substance may polymerize due to warming with fire or explosion The substance may have effects on the bone marrow, resulting hazard. Shock-sensitive compounds are formed with copper and in leukemia. This substance is probably carcinogenic to its alloys (see Notes). The substance decomposes explosively humans. May cause heritable genetic damage in humans. on rapid heating under pressure. Reacts vigorously with oxidants Animal tests show that this substance possibly causes toxic and many other substances, causing fire and explosion hazard. effects upon human reproduction.
Occupational exposure limits TLV: 2 ppm as TWA; A2 (suspected human carcinogen); (ACGIH 2004). MAK: Carcinogen category: 1; Germ cell mutagen group: 2; (DFG 2004).
PHYSICAL PROPERTIES
Boiling point: -4/C Relative vapour density (air = 1): 1.9 Melting point: -109/C Flash point: -76/C Relative density (water = 1): 0.6 Auto-ignition temperature: 414/C Solubility in water: none (0.1 g/100 ml) Explosive limits, vol% in air: 1.1-16.3 Vapour pressure, kPa at 20/C: 245 Octanol/water partition coefficient as log Pow: 1.99
ENVIRONMENTAL DATA
NOTES
Piping material for this gas must not contain over 63% of copper. Use of alcoholic beverages enhances the harmful effect. The odour warning when the exposure limit value is exceeded is insufficient. Card has been partly updated in October 2004 and April 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
©IPCS 2005 Chemical Information Annexure - III : 11 CHLORINE 0126 April 2000 CAS No: 7782-50-5 (cylinder)
RTECS No: FO2100000 Cl2 UN No: 1017 Molecular mass: 70.9 EC No: 017-001-00-7
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Not combustible but enhances NO contact with combustibles, In case of fire in the surroundings: combustion of other substances. acetylene, ethylene, hydrogen, use appropriate extinguishing Many reactions may cause fire or ammonia and finely divided metals. media. explosion.
EXPLOSION Risk of fire and explosion on In case of fire: keep cylinder cool by contact with combustible spraying with water but NO direct substances, ammonia and finely contact with water. divided metals.
EXPOSURE AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!
Inhalation Corrosive. Burning sensation. Breathing protection. Closed system Fresh air, rest. Half-upright position. Shortness of breath. Cough. and ventilation. Artificial respiration may be needed. Headache. Nausea. Dizziness. Refer for medical attention. Laboured breathing. Sore throat. Symptoms may be delayed (see Notes).
Skin ON CONTACT WITH LIQUID: Cold-insulating gloves. Protective First rinse with plenty of water, then FROSTBITE. Corrosive. Skin clothing. remove contaminated clothes and burns. Pain. rinse again. Refer for medical attention.
Eyes Corrosive. Pain. Blurred vision. Safety goggles or eye protection in First rinse with plenty of water for Severe deep burns. combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! T Symbol Special insulated cylinder. Marine Ventilation. NEVER direct water jet on liquid. N Symbol pollutant. Remove gas with fine water spray. Personal R: 23-36/37/38-50 protection: complete protective clothing including S: (1/2-)9-45-61 self-contained breathing apparatus. Do NOT let this UN Hazard Class: 2.3 chemical enter the environment. UN Subsidiary Risks: 8
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-20S1017 Separated from strong bases, combustible and reducing substances. Cool. NFPA Code: H 4; F 0; R 0; OX Dry. Keep in a well-ventilated room.
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 12 0126 CHLORINE
IMPORTANT DATA Physical State; Appearance Routes of exposure GREENISH-YELLOW GAS, WITH PUNGENT ODOUR. The substance can be absorbed into the body by inhalation.
Physical dangers Inhalation risk The gas is heavier than air. A harmful concentration of this gas in the air will be reached very quickly on loss of containment. Chemical dangers The solution in water is a strong acid, it reacts violently with Effects of short-term exposure bases and is corrosive. Reacts violently with many organic Tear drawing. The substance is corrosive to the eyes, the skin compounds, ammonia, hydrogen and finely divided metals and the respiratory tract. Inhalation of gas may cause causing fire and explosion hazard. Attacks many metals in pneumonitis and lung oedema, resulting in reactive airways presence of water. Attacks plastic, rubber and coatings. dysfunction syndrome (RADS) (see Notes). Rapid evaporation of the liquid may cause frostbite. Exposure far above the OEL Occupational exposure limits may result in death. The effects may be delayed. Medical TLV: 0.5 ppm as TWA; 1 ppm as STEL; A4 (not classifiable as a observation is indicated. human carcinogen); (ACGIH 2004). MAK: 0.5 ppm, 1.5 mg/m3; Peak limitation category: I(1); Effects of long-term or repeated exposure Pregnancy risk group: C; (DFG 2004). The substance may have effects on the lungs, resulting in chronic bronchitis. The substance may have effects on the teeth, resulting in erosion.
PHYSICAL PROPERTIES
Boiling point: -34/C Solubility in water, g/100 ml at 20/C: 0.7 Melting point: -101/C Vapour pressure, kPa at 20/C: 673 Relative density (water = 1): 1.4 at 20/C, 6.86 atm (liquid) Relative vapour density (air = 1): 2.5
ENVIRONMENTAL DATA
The substance is very toxic to aquatic organisms.
NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered. The odour warning when the exposure limit value is exceeded is insufficient. Do NOT use in the vicinity of a fire or a hot surface, or during welding. Do NOT spray water on leaking cylinder (to prevent corrosion of cylinder). Turn leaking cylinder with the leak up to prevent escape of gas in liquid state. Card has been partly updated in April 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
©IPCS 2005 Chemical Information Annexure - III : 13 DIESEL FUEL No. 2 1561 October 2004 CAS No: 68476-34-6 Fuels, Diesel, No. 2 RTECS No: LS9142500 Diesel oil No. 2 UN No: 1202 Gasoil - unspecified EC No: 649-227-00-2
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Flammable. Gives off irritating or NO open flames. Water spray, alcohol-resistant foam, toxic fumes (or gases) in a fire. dry powder, carbon dioxide.
EXPLOSION Above 52/C explosive vapour/air Above 52/C use a closed system, In case of fire: keep drums, etc., mixtures may be formed. ventilation, and explosion-proof cool by spraying with water. electrical equipment.
EXPOSURE
Inhalation Dizziness. Headache. Nausea. Ventilation, local exhaust, or Fresh air, rest. Refer for medical breathing protection. attention.
Skin Dry skin. Redness. Protective gloves. Rinse and then wash skin with water and soap.
Eyes Redness. Pain. Safety goggles, or eye protection in First rinse with plenty of water for combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion (See Inhalation). Do not eat, drink, or smoke during Rinse mouth. Do NOT induce work. vomiting. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Collect leaking and spilled liquid in sealable Xn Symbol containers as far as possible. Absorb remaining R: 40 liquid in sand or inert absorbent and remove to safe S: (2-)36/37 place. Personal protection: filter respirator for Note: H organic gases and vapours. UN Hazard Class: 3 UN Pack Group: III
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30S1202 Well closed. NFPA Code: H0; F2; R0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2004 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 14 1561 DIESEL FUEL No. 2
IMPORTANT DATA Physical State; Appearance Routes of exposure BROWN SLIGHTLY VISCOUS LIQUID, WITH The substance can be absorbed into the body by inhalation of CHARACTERISTIC ODOUR. its aerosol.
Occupational exposure limits Inhalation risk TLV: 100 ppm as TWA; (skin); A3; (ACGIH 2004). A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20/C.
Effects of short-term exposure The substance is irritating to the eyes, the skin and the respiratory tract. The substance may cause effects on the central nervous system. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.
Effects of long-term or repeated exposure The liquid defats the skin.
PHYSICAL PROPERTIES
Boiling point: 282-338/C Flash point: 52/C c.c. Melting point: -30 - -18/C Auto-ignition temperature: 254-285/C Density: 0.87 - 0.95 g/cm3 Explosive limits, vol% in air: 0.6 - 6.5 Solubility in water, g/100 ml at 20/C: 0.0005 Octanol/water partition coefficient as log Pow: > 3.3
ENVIRONMENTAL DATA
The substance is harmful to aquatic organisms.
NOTES
Additives to Diesel fuel in winter may change physical and toxicological properties of the substance. This card does not address Diesel exhaust.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
©IPCS 2004 Chemical Information Annexure - III : 15 DIMETHYLAMINE 0260 May 2003 CAS No: 124-40-3 Methanamine, N-methyl RTECS No: IP8750000 DMA UN No: 1032 (cylinder)
EC No: 612-001-00-9 (CH3)2NH / C2H7N Molecular mass: 45.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Extremely flammable. Gives off NO open flames, NO sparks, and Shut off supply; if not possible and irritating or toxic fumes (or gases) NO smoking. no risk to surroundings, let the fire in a fire. burn itself out; in other cases extinguish with water spray, alcohol-resistant foam, dry powder, carbon dioxide.
EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation, In case of fire: keep cylinder cool by explosion-proof electrical equipment spraying with water. Combat fire and lighting. Use non-sparking from a sheltered position. handtools.
EXPOSURE STRICT HYGIENE!
Inhalation Burning sensation. Cough. Ventilation, local exhaust, or Fresh air, rest. Half-upright position. Headache. Laboured breathing. breathing protection. Artificial respiration may be needed. Shortness of breath. Sore throat. Refer for medical attention. Symptoms may be delayed (see Notes).
Skin ON CONTACT WITH LIQUID: Cold-insulating gloves. Protective ON FROSTBITE: rinse with plenty FROSTBITE. clothing. of water, do NOT remove clothes. Refer for medical attention.
Eyes Redness. Pain. Blurred vision. Safety goggles, or eye protection in First rinse with plenty of water for combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Do not eat, drink, or smoke during work.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! F+ Symbol Ventilation. Remove all ignition sources. NEVER Xn Symbol direct water jet on liquid. Remove gas with fine R: 12-20-37/38-41 water spray. Do NOT let this chemical enter the S: (2-)16-26-39 environment. (Extra personal protection: complete UN Hazard Class: 2.1 protective clothing including self-contained breathing apparatus.)
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-20S1032 Fireproof. Cool. NFPA Code: H3; F4; R0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2002 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 16 0260 DIMETHYLAMINE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS COMPRESSED LIQUEFIED GAS, WITH The substance can be absorbed into the body by inhalation. PUNGENT ODOUR. Inhalation risk Physical dangers On loss of containment, a harmful concentration of this gas in The gas is heavier than air and may travel along the ground; the air will be reached very quickly especially in confined distant ignition possible. spaces.
Chemical dangers Effects of short-term exposure The substance decomposes on burning producing toxic fumes The substance is severely irritating to the eyes and the including nitrogen oxides. Reacts violently with strong oxidants respiratory tract. Inhalation of the substance at high levels may and mercury causing fire and explosion hazard. Attacks copper, cause lung oedema (see Notes). The effects may be delayed. zinc alloys, aluminium, galvanized surfaces, and plastic. The Medical observation is indicated. Rapid evaporation of the liquid solution in water is a strong base, it reacts violently with acid may cause frostbite. and is corrosive, see ICSC 1485 Dimethylamine, aqueous solution.
Occupational exposure limits TLV: 5 ppm as TWA; 15 ppm as STEL; A4; (ACGIH 2003). EU OEL: 2 ppm, 3.8 mg/m3 as TWA; 5 ppm, 9.4 mg/m3 as STEL; (EU 1998).
PHYSICAL PROPERTIES
Boiling point: 7.0°C Relative vapour density (air = 1): 1.6 Melting point: -92.2°C Flash point: Flammable Gas Relative density (water = 1): 0.7 Auto-ignition temperature: 400°C Solubility in water: 354 g/100ml Explosive limits, vol% in air: 2.8-14.4 Vapour pressure, kPa at 25°C: 203 Octanol/water partition coefficient as log Pow: -0.2
ENVIRONMENTAL DATA The substance is harmful to aquatic organisms.
NOTES Turn leaking cylinder with the leak up to prevent escape of gas in liquid state. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered. Do NOT spray water on leaking cylinder (to prevent corrosion of cylinder). See ICSC 1485 Dimethylamine, aqueous solution.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2002 Chemical Information Annexure - III : 17 GASOLINE 1400 October 2001 CAS No: 86290-81-5 Benzin RTECS No: DE3550000 UN No: 1203 EC No: 649-378-00-4
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Highly flammable. NO open flames, NO sparks, and Powder, AFFF, foam, carbon NO smoking. dioxide.
EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, In case of fire: keep drums, etc., explosion-proof electrical equipment cool by spraying with water. and lighting. Prevent build-up of electrostatic charges (e.g., by grounding).
EXPOSURE
Inhalation Confusion. Cough. Dizziness. Ventilation, local exhaust, or Fresh air, rest. Refer for medical Drowsiness. Dullness. Headache. breathing protection. attention.
Skin MAY BE ABSORBED! Dry skin. Protective gloves. Protective Remove contaminated clothes. Redness. clothing. Rinse and then wash skin with water and soap.
Eyes Redness. Pain. Safety spectacles or eye protection First rinse with plenty of water for in combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Nausea. Vomiting. (See Do not eat, drink, or smoke during Rinse mouth. Do NOT induce Inhalation). work. vomiting. Give plenty of water to drink. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! Remove T Symbol Marine pollutant. all ignition sources. Cover the spilled material with R: 45-65 dry earth, sand or non-combustible material. Do S: 53-45 NOT wash away into sewer. Do NOT let this Note: H, P chemical enter the environment. Personal protection: UN Hazard Class: 3 self-contained breathing apparatus. UN Pack Group: I
EMERGENCY RESPONSE SAFE STORAGE
NFPA Code: H1; F3; R0; Fireproof. Transport Emergency Card: TEC (R)-30S1203
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 18 1400 GASOLINE
IMPORTANT DATA Physical State; Appearance Routes of exposure MOBILE LIQUID The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. Physical dangers The vapour is heavier than air and may travel along the ground; Inhalation risk distant ignition possible. The vapour mixes well with air, A harmful contamination of the air can be reached very quickly explosive mixtures are easily formed. As a result of flow, on evaporation of this substance at 20/C. agitation, etc., electrostatic charges can be generated. Effects of short-term exposure Occupational exposure limits The substance is irritating to the eyes, the skin and the TLV: 300 ppm as TWA, 500 ppm as STEL; A3 (confirmed respiratory tract. If this liquid is swallowed, aspiration into the animal carcinogen with unknown relevance to humans); (ACGIH lungs may result in chemical pneumonitis. The substance may 2004). cause effects on the central nervous system.
Effects of long-term or repeated exposure The liquid defats the skin. The substance may have effects on the central nervous system and liver. This substance is possibly carcinogenic to humans.
PHYSICAL PROPERTIES
Boiling point: 20-200/C Flash point: <-21/C Relative density (water = 1): 0.70 - 0.80 Auto-ignition temperature: about 250/C Solubility in water, g/100 ml: none Explosive limits, vol% in air: 1.3-7.1 Relative vapour density (air = 1): 3 - 4 Octanol/water partition coefficient as log Pow: 2-7
ENVIRONMENTAL DATA
The substance is harmful to aquatic organisms.
NOTES
Depending on the degree of exposure, periodic medical examination is suggested. The product may contain additives which may alter the health and environmental effects. Card has been partly updated in April 2005. See section Physical properties.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
©IPCS 2005 Chemical Information Annexure - III : 19 n-HEXANE 0279 April 2000 CAS No: 110-54-3 Hexyl hydride
RTECS No: MN9275000 C6H14 UN No: 1208 Molecular mass: 86.2 EC No: 601-037-00-0
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Highly flammable. NO open flames, NO sparks, and NO Powder, AFFF, foam, carbon dioxide. smoking.
EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, In case of fire: keep drums, etc., cool explosion-proof electrical equipment by spraying with water. and lighting. Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools.
EXPOSURE
Inhalation Dizziness. Drowsiness. Dullness. Ventilation, local exhaust, or breathing Fresh air, rest. Refer for medical Headache. Nausea. Weakness. protection. attention. Unconsciousness.
Skin Dry skin. Redness. Pain. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes Redness. Pain. Safety goggles, face shield or eye First rinse with plenty of water for protection in combination with several minutes (remove contact breathing protection. lenses if easily possible), then take to a doctor.
Ingestion Abdominal pain. (Further see Do not eat, drink, or smoke during Rinse mouth. Do NOT induce Inhalation). work. vomiting. Rest. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Consult an expert! Remove all ignition sources. F Symbol Collect leaking and spilled liquid in sealable containers Xn Symbol as far as possible. Absorb remaining liquid in sand or N Symbol inert absorbent and remove to safe place. Do NOT R: 11-38-48/20-62-65-67-51/53 wash away into sewer. Do NOT let this chemical S: (2-)9-16-29-33-36/37-61-62 enter the environment. Personal protection: filter UN Hazard Class: 3 respirator for organic gases and vapours. UN Pack Group: II
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30S1208 Fireproof. Separated from strong oxidants. Well closed. NFPA Code: H 1; F 3; R 0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 20 0279 n-HEXANE
IMPORTANT DATA Physical State; Appearance Routes of exposure VOLATILE COLOURLESS LIQUID, WITH CHARACTERISTIC The substance can be absorbed into the body by inhalation of its ODOUR. vapour and by ingestion.
Physical dangers Inhalation risk The vapour is heavier than air and may travel along the ground; A harmful contamination of the air can be reached rather quickly distant ignition possible. on evaporation of this substance at 20/C.
Chemical dangers Effects of short-term exposure Reacts with strong oxidants causing fire and explosion hazard. The substance irritates the skin. Swallowing the liquid may cause Attacks some plastics, rubber and coatings. aspiration into the lungs with the risk of chemical pneumonitis. Exposure at high levels could cause lowering of consciousness. Occupational exposure limits TLV: 50 ppm, 176 mg/m3 as TWA; (skin); BEI issued; (ACGIH Effects of long-term or repeated exposure 2004). Repeated or prolonged contact with skin may cause dermatitis. MAK: 50 ppm, 180 mg/m3; Peak limitation category: II(8); The substance may have effects on the central nervous system Pregnancy risk group: C; (DFG 2004). and especially peripheral nervous system, resulting in polyneuropathy. Animal tests show that this substance possibly causes toxic effects upon human reproduction.
PHYSICAL PROPERTIES
Boiling point: 69/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.3 Melting point: -95/C Flash point: -22/C c.c. Relative density (water = 1): 0.7 Auto-ignition temperature: 225/C Solubility in water, g/100 ml at 20/C: 0.0013 Explosive limits, vol% in air: 1.1-7.5 Vapour pressure, kPa at 20/C: 17 Octanol/water partition coefficient as log Pow: 3.9 Relative vapour density (air = 1): 3.0
ENVIRONMENTAL DATA
The substance is toxic to aquatic organisms.
NOTES
Depending on the degree of exposure, periodic medical examination is suggested. Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2005 Chemical Information Annexure - III : 21 HYDROGEN 0001 March 2002
CAS No: 1333-74-0 H2 RTECS No: MW8900000 Molecular mass: 2.0 UN No: 1049 EC No: 001-001-00-9
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Extremely flammable. Many NO open flames, NO sparks, and Shut off supply; if not possible and reactions may cause fire or NO smoking. no risk to surroundings, let the fire explosion. burn itself out; in other cases extinguish with water spray, powder, carbon dioxide.
EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation, In case of fire: keep cylinder cool by explosion-proof electrical equipment spraying with water. Combat fire and lighting. Use non-sparking from a sheltered position. handtools. Do not handle cylinders with oily hands.
EXPOSURE
Inhalation Suffocation. Closed system and ventilation. Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
Skin Serious frostbite. Cold-insulating gloves. Refer for medical attention.
Eyes Safety spectacles.
Ingestion
SPILLAGE DISPOSAL PACKAGING & LABELLING
Remove all ignition sources. Evacuate danger area! F+ Symbol Consult an expert! Ventilation. Remove vapour with R: 12 fine water spray. S: (2-)9-16-33 UN Hazard Class: 2.1
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-20S1049 Fireproof. Cool. NFPA Code: H0; F4; R0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2002 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 22 0001 HYDROGEN
IMPORTANT DATA Physical State; Appearance Routes of exposure ODOURLESS, COLOURLESS COMPRESSED GAS The substance can be absorbed into the body by inhalation.
Physical dangers Inhalation risk The gas mixes well with air, explosive mixtures are easily On loss of containment, a harmful concentration of this gas in formed. The gas is lighter than air. the air will be reached very quickly.
Chemical dangers Effects of short-term exposure Heating may cause violent combustion or explosion. Reacts Simple asphyxiant. See Notes. violently with air, oxygen, halogens and strong oxidants causing fire and explosion hazard. Metal catalysts, such as platinum and nickel, greatly enhance these reactions.
Occupational exposure limits TLV: Simple asphyxiant (ACGIH 2002).
PHYSICAL PROPERTIES
Boiling point: -253°C Auto-ignition temperature: 500-571°C Relative vapour density (air = 1): 0.07 Explosive limits, vol% in air: 4-76 Flash point: flammable gas
ENVIRONMENTAL DATA
NOTES High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death. Check oxygen content before entering area. No odour warning if toxic concentrations are present. Measure hydrogen concentrations with suitable gas detector (a normal flammable gas detector is not suited for the purpose).
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2002 Chemical Information Annexure - III : 23 ISOPROPYL ALCOHOL 0554 March 1999 CAS No: 67-63-0 2-Propanol RTECS No: NT8050000 Propan-2-ol UN No: 1219 Isopropanol EC No: 603-117-00-0 Dimethylcarbinol C3H8O / CH3CHOHCH3 Molecular mass: 60.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Highly flammable. NO open flames, NO sparks, and NO Powder, alcohol-resistant foam, smoking. water in large amounts, carbon dioxide.
EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, In case of fire: keep drums, etc., cool explosion-proof electrical equipment by spraying with water. and lighting.
EXPOSURE
Inhalation Cough. Dizziness. Drowsiness. Ventilation, local exhaust, or breathing Fresh air, rest. Refer for medical Headache. Sore throat. (See protection. attention. Ingestion).
Skin Dry skin. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes Redness. Safety spectacles or eye protection in First rinse with plenty of water for combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Abdominal pain. Laboured Do not eat, drink, or smoke during Rinse mouth. Do NOT induce breathing. Nausea. work. vomiting. Rest. Refer for medical Unconsciousness. Vomiting. attention. (Further see Inhalation).
SPILLAGE DISPOSAL PACKAGING & LABELLING
Personal protection: filter respirator for organic gases F Symbol and vapours. Collect leaking liquid in sealable Xi Symbol containers. Absorb remaining liquid in sand or inert R: 11-36-67 absorbent and remove to safe place. S: (2-)7-16-24/25-26 Note: 6 UN Hazard Class: 3 UN Pack Group: II
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30S1219 Fireproof. Separated from strong oxidants. Cool. Well closed. NFPA Code: H1; F3; R0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 24 0554 ISOPROPYL ALCOHOL
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID The substance can be absorbed into the body by inhalation of its vapour. Physical dangers The vapour mixes well with air, explosive mixtures are easily Inhalation risk formed. A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20/C; on spraying or dispersing, Chemical dangers however, much faster. Reacts with strong oxidants. Attacks some plastic, rubber. Effects of short-term exposure Occupational exposure limits The substance is irritating to the eyes and the respiratory tract. TLV: 200 ppm as TWA; 400 ppm as STEL; A4 (not classifiable as The substance may cause effects on the central nervous system, a human carcinogen); (ACGIH 2004). resulting in depression. Exposure far above the OEL may result in MAK: 200 ppm, 500 mg/m3; Peak limitation category: II(2); unconsciousness. Pregnancy risk group: C; (DFG 2004). Effects of long-term or repeated exposure The liquid defats the skin.
PHYSICAL PROPERTIES
Boiling point: 83/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.05 Melting point: -90/C Flash point: 11.7/C c.c. Relative density (water = 1): 0.79 Auto-ignition temperature: 456/C Solubility in water: miscible Explosive limits, vol% in air: 2-12 Vapour pressure, kPa at 20/C: 4.4 Octanol/water partition coefficient as log Pow: 0.05 Relative vapour density (air = 1): 2.1
ENVIRONMENTAL DATA
NOTES
Use of alcoholic beverages enhances the harmful effect. Card has been partly updated in October 2004 and 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2005 Chemical Information Annexure - III : 25 KEROSENE 0663 November 1998 CAS No: 8008-20-6 Kerosine RTECS No: OA5500000 Light petroleum UN No: 1223 Lamp oil EC No: 649-404-00-4 Fuel oil no1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Flammable. NO open flames, NO sparks, and Powder, AFFF, foam, carbon NO smoking. dioxide.
EXPLOSION Above 37C explosive vapour/air Above 37C use a closed system, In case of fire: keep drums, etc., mixtures may be formed. ventilation, and explosion-proof cool by spraying with water. electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding).
EXPOSURE PREVENT GENERATION OF MISTS!
Inhalation Confusion. Cough. Dizziness. Ventilation. Fresh air, rest. Artificial respiration Headache. Sore throat. if indicated. Refer for medical Unconsciousness. attention.
Skin Dry skin. Roughness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes Redness. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Diarrhoea. Nausea. Vomiting. Do not eat, drink, or smoke during Do NOT induce vomiting. Rest. work. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Collect leaking liquid in sealable containers. Absorb Xn Symbol remaining liquid in sand or inert absorbent and R: 65 remove to safe place. Do NOT let this chemical S: (2-)23-24-62 enter the environment (extra personal protection: Note: H self-contained breathing apparatus). UN Hazard Class: 3 UN Pack Group: III
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-551 Fireproof. Separated from strong oxidants. Cool. NFPA Code: H 0; F 2; R 0;
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 1999 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 26 0663 KEROSENE
IMPORTANT DATA
Physical State; Appearance Routes of Exposure LOW VISCOSITY LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation of its vapour and by ingestion. Physical Dangers As a result of flow, agitation, etc., electrostatic charges can be Inhalation Risk generated. No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this Chemical Dangers substance at 20C. Reacts with oxidants. Effects of Short-term Exposure Occupational Exposure Limits The substance slightly irritates the skin and the respiratory TLV not established. tract. Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis. The substance may cause effects on the nervous system.
Effects of Long-term or Repeated Exposure The liquid defats the skin.
PHYSICAL PROPERTIES
Boiling point: 150-300C Relative vapour density (air = 1): 4.5 Melting point: -20C Flash point: 37-65C Relative density (water = 1): 0.8 Auto-ignition temperature: 220C Solubility in water: none Explosive limits, vol% in air: 0.7-5
ENVIRONMENTAL DATA The substance is harmful to aquatic organisms.
NOTES Physical properties vary, depending on the composition. Ingestion of kerosene (lamp oil) is a major cause of accidental poisoning in children.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
© IPCS 1999 Chemical Information Annexure - III : 27 METHANOL 0057 April 2000 CAS No: 67-56-1 Methyl alcohol RTECS No: PC1400000 Carbinol UN No: 1230 Wood alcohol
EC No: 603-001-00-X CH4O / CH3OH Molecular mass: 32.0
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Highly flammable. See Notes. NO open flames, NO sparks, and Powder, alcohol-resistant foam, NO smoking. NO contact with water in large amounts, carbon oxidants. dioxide.
EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, In case of fire: keep drums, etc., explosion-proof electrical equipment cool by spraying with water. and lighting. Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools.
EXPOSURE AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!
Inhalation Cough. Dizziness. Headache. Ventilation. Local exhaust or Fresh air, rest. Refer for medical Nausea. Weakness. Visual breathing protection. attention. disturbance.
Skin MAY BE ABSORBED! Dry skin. Protective gloves. Protective Remove contaminated clothes. Redness. clothing. Rinse skin with plenty of water or shower. Refer for medical attention.
Eyes Redness. Pain. Safety goggles or eye protection in First rinse with plenty of water for combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Abdominal pain. Shortness of Do not eat, drink, or smoke during Induce vomiting (ONLY IN breath. Vomiting. Convulsions. work. Wash hands before eating. CONSCIOUS PERSONS!). Refer Unconsciousness. (Further see for medical attention. Inhalation).
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Ventilation. Collect leaking F Symbol Do not transport with food and liquid in sealable containers. Wash away remainder T Symbol feedstuffs. with plenty of water. Remove vapour with fine water R: 11-23/24/25-39/23/24/25 spray. Chemical protection suit including S: (1/2-)7-16-36/37-45 self-contained breathing apparatus. UN Hazard Class: 3 UN Subsidiary Risks: 6.1 UN Pack Group: II
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30S1230 Fireproof. Separated from strong oxidants, food and feedstuffs. Cool. NFPA Code: H 1; F 3; R 0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 28 0057 METHANOL
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation and through the skin and by ingestion. Physical dangers The vapour mixes well with air, explosive mixtures are easily Inhalation risk formed. A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20/C. Chemical dangers Reacts violently with oxidants causing fire and explosion hazard. Effects of short-term exposure The substance is irritating to the eyes, the skin and the Occupational exposure limits respiratory tract. The substance may cause effects on the TLV: 200 ppm as TWA, 250 ppm as STEL; (skin); BEI issued; central nervous system, resulting in loss of consciousness. (ACGIH 2004). Exposure may result in blindness and death. The effects may be MAK: 200 ppm, 270 mg/m3; Peak limitation category: II(4); skin delayed. Medical observation is indicated. absorption (H); Pregnancy risk group: C (DFG 2004). Effects of long-term or repeated exposure Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the central nervous system, resulting in persistent or recurring headaches and impaired vision.
PHYSICAL PROPERTIES
Boiling point: 65/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.01 Melting point: -98/C Flash point: 12/C c.c. Relative density (water = 1): 0.79 Auto-ignition temperature: 464/C Solubility in water: miscible Explosive limits, vol% in air: 5.5-44 Vapour pressure, kPa at 20/C: 12.3 Octanol/water partition coefficient as log Pow: -0.82/-0.66 Relative vapour density (air = 1): 1.1
ENVIRONMENTAL DATA
NOTES
Burns with nonluminous bluish flame. Depending on the degree of exposure, periodic medical examination is suggested. Card has been partly updated in April 2005. See section Occupational Exposure Limits.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
©IPCS 2005 Chemical Information Annexure - III : 29 METHYLAMINE 0178 October 2002 CAS No: 74-89-5 Methanamine RTECS No: PF6300000 Aminomethane UN No: 1061 (anhydrous) Monomethylamine EC No: 612-001-00-9 (cylinder)
CH5N / CH3NH2 Molecular mass: 31.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Extremely flammable. Gives off NO open flames, NO sparks, and Shut off supply; if not possible and irritating or toxic fumes (or gases) NO smoking. no risk to surroundings, let the fire in a fire. burn itself out; in other cases extinguish with powder, carbon dioxide.
EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation, In case of fire: keep cylinder cool by explosion-proof electrical equipment spraying with water. Combat fire and lighting. Use non-sparking from a sheltered position. handtools.
EXPOSURE STRICT HYGIENE!
Inhalation Burning sensation. Cough. Ventilation, local exhaust, or Fresh air, rest. Half-upright position. Headache. Laboured breathing. breathing protection. Artificial respiration may be needed. Shortness of breath. Sore throat. Refer for medical attention. See Notes.
Skin ON CONTACT WITH LIQUID: Cold-insulating gloves. Protective ON FROSTBITE: rinse with plenty FROSTBITE. clothing. of water, do NOT remove clothes. Refer for medical attention.
Eyes Redness. Pain. Blurred vision. Safety goggles, or eye protection in First rinse with plenty of water for Severe deep burns. combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Do not eat, drink, or smoke during work.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! F+ Symbol Ventilation. Remove all ignition sources. NEVER Xn Symbol direct water jet on liquid. Remove vapour with fine R: 12-20-37/38-41 water spray. (Extra personal protection: complete S: (2-)16-26-39 protective clothing including self-contained UN Hazard Class: 2.1 breathing apparatus.)
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC 20S1061 Fireproof. Cool. NFPA Code: H3; F4; R0.
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2002 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 30 0178 METHYLAMINE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS COMPRESSED LIQUEFIED GAS, WITH The substance can be absorbed into the body by inhalation. CHARACTERISTIC ODOUR. Inhalation risk Physical dangers On loss of containment, a harmful concentration of this gas in The gas mixes well with air, explosive mixtures are easily the air will be reached very quickly. formed. Effects of short-term exposure Chemical dangers The substance is corrosive to the eyes and the respiratory tract. The substance decomposes on burning producing toxic fumes Inhalation of the substance at high levels may cause lung including nitrogen oxides. The solution in water is a strong base, oedema (see Notes). The effects may be delayed. Medical it reacts violently with acid and is corrosive. Reacts violently observation is indicated. Rapid evaporation of the liquid may with strong oxidants. Attacks plastic, rubber and coatings. cause frostbite. Attacks copper, zinc alloys, aluminium and galvanized surfaces.
Occupational exposure limits TLV: (as TWA) 5 ppm; (as STEL) 15 ppm; (ACGIH 2002). MAK: 10 ppm, 13 mg/m3; (DFG 2002). MAK: class Peak limitation category: I (1) ceiling; Pregnancy risk group: IIc; (2002)
PHYSICAL PROPERTIES
Boiling point: -6°C Relative vapour density (air = 1): 1.07 Melting point: -93°C Flash point: Flammable Gas Relative density (water = 1): 0.7 (liquid) Auto-ignition temperature: 430°C Solubility in water: at 25 °C very good Explosive limits, vol% in air: 4.9-20.7 Vapour pressure, kPa at 20°C: 304 Octanol/water partition coefficient as log Pow: -0.71
ENVIRONMENTAL DATA
NOTES Turn leaking cylinder with the leak up to prevent escape of gas in liquid state. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2002 Chemical Information Annexure - III : 31 NAPHTHA (PETROLEUM), HEAVY ALKYLATE 1382 March 2001 CAS No: 64741-65-7 Low boiling point modified naphtha RTECS No: Aliphatic HC's, iso-paraffins UN No: 1268 EC No: 649-275-00-4
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Flammable. NO open flames, NO sparks, and Water spray, alcohol-resistant NO smoking. foam, powder, carbon dioxide.
EXPLOSION Above 44°C explosive vapour/air Above 44°C use a closed system, In case of fire: keep drums, etc., mixtures may be formed. ventilation, and explosion-proof cool by spraying with water. electrical equipment.
EXPOSURE PREVENT GENERATION OF MISTS!
Inhalation Dizziness. Headache. Drowsiness. Ventilation, local exhaust, or Fresh air, rest. Refer for medical Nausea. Unconsciousness. breathing protection. attention.
Skin Dry skin. Protective gloves. Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes Redness. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Cough. Diarrhoea. Sore throat. Do not eat, drink, or smoke during Do NOT induce vomiting. Refer for Vomiting. (Further see Inhalation). work. medical attention. See Notes.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Ventilation. Collect leaking and spilled liquid in T Symbol sealable containers as far as possible. Absorb R: 45-65 remaining liquid in sand or inert absorbent and S: 53-45 remove to safe place. Do NOT wash away into Note: H, P sewer. (Extra personal protection: filter respirator for UN Hazard Class: 3 organic vapours of low boiling compounds.) UN Pack Group: III
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-30G35 Fireproof. Separated from strong oxidants. Well closed. NFPA Code: H1; F3; R0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2000 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 32 1382 NAPHTHA (PETROLEUM), HEAVY ALKYLATE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID The substance can be absorbed into the body by inhalation of its vapour and by ingestion. Physical dangers The vapour is heavier than air and may travel along the ground; Inhalation risk distant ignition possible. No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this Chemical dangers substance at 20°C. Reacts with strong oxidants, causing fire and explosion hazard. Effects of short-term exposure Occupational exposure limits The vapour is slightly irritating to the eyes. The substance may TLV not established. MAK not established. cause effects on the central nervous system. Exposure to high concentration of vapours may result in unconsciousness. Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis.
Effects of long-term or repeated exposure The liquid defats the skin. See Notes.
PHYSICAL PROPERTIES
Boiling point: 172-215°C Vapour pressure, kPa at 20°C: 0.1-0.2 Melting point: -30°C Flash point: = 44°C c.c. Auto-ignition temperature: 355 °C Density: 0.75-0.79 g/cm3 Explosive limits, vol% in air: 0.6-8.0 Solubility in water: none
ENVIRONMENTAL DATA The substance is toxic to aquatic organisms.
NOTES This is a mixture of C9-C14 iso- and n-paraffins. Neither the concentration of aromatics nor of hexane is greater than 0.1 % by volume. Note P: the EU classification as carcinogen (R45) does not apply if it can be shown that the benzene content is below 0.1% by volume. Depending on the raw material and the production processes, the composition and physical properties of this solvent can vary considerably. The symptoms of chemical pneumonitis do not become manifest until a few hours or even a few days have passed. Isopar G / L / M, Shellsol T / TK / TD, Soltrol 100 / 130, among others, are trade names.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2000 Chemical Information Annexure - III : 33 NITRIC ACID 0183 April 1994 CAS No: 7697-37-2 Concentrated Nitric Acid (70%)
RTECS No: QU5775000 HNO3 UN No: 2031 Molecular mass: 63.0 EC No: 007-004-00-1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Not combustible but enhances NO contact with flammable In case of fire in the surroundings: combustion of other substances. substances. NO contact with NO foam. Gives off irritating or toxic fumes combustibles or organic chemicals. (or gases) in a fire.
EXPLOSION Risk of fire and explosion on In case of fire: keep drums, etc., contact with many common organic cool by spraying with water. compounds.
EXPOSURE AVOID ALL CONTACT!
Inhalation Burning sensation. Cough. Ventilation, local exhaust, or Fresh air, rest. Half-upright position. Laboured breathing. breathing protection. Artificial respiration may be needed. Unconsciousness. Symptoms may Refer for medical attention. be delayed (see Notes).
Skin Corrosive. Serious skin burns. Protective clothing. Remove contaminated clothes. Pain. Yellow discolouration. Rinse skin with plenty of water or shower. Refer for medical attention.
Eyes Corrosive. Redness. Pain. Severe Face shield or eye protection in First rinse with plenty of water for deep burns. combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Corrosive. Abdominal pain. Do not eat, drink, or smoke during Do NOT induce vomiting. Give Burning sensation. Shock. work. Wash hands before eating. plenty of water to drink. Rest. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! O Symbol Unbreakable packaging; put Ventilation. Collect leaking liquid in sealable C Symbol breakable packaging into closed containers. Cautiously neutralize remainder with R: 8-35 unbreakable container. Do not sodium carbonate. Then wash away with plenty of S: (1/2-)23-26-36-45 transport with food and feedstuffs. water. Do NOT absorb in saw-dust or other Note: B combustible absorbents. Personal protection: UN Hazard Class: 8 complete protective clothing including self-contained UN Pack Group: II breathing apparatus.
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-80S2031-II or Separated from combustible and reducing substances, bases, food and 80GO1-I feedstuffs, organic chemicals. Cool. Dry. Keep in a well-ventilated room. NFPA Code: H 3; F 0; R 0; OX
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 34 0183 NITRIC ACID
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS TO YELLOW LIQUID, WITH PUNGENT The substance can be absorbed into the body by inhalation of ODOUR. its vapour and by ingestion.
Chemical dangers Inhalation risk The substance decomposes on warming producing nitrogen A harmful contamination of the air can be reached very quickly oxides. The substance is a strong oxidant and reacts violently on evaporation of this substance at 20/C. with combustible and reducing materials, e.g., turpentine, charcoal, alcohol. The substance is a strong acid, it reacts Effects of short-term exposure violently with bases and is corrosive to metals. Reacts very The substance is very corrosive to the eyes, the skin and the violently with organic chemicals (e.g., acetone, acetic acid, respiratory tract. Corrosive on ingestion as well. Inhalation of acetic anhydride), causing fire and explosion hazard. Attacks vapour may cause lung oedema (see Notes). some plastics.
Occupational exposure limits TLV: 2 ppm as TWA, 4 ppm as STEL; (ACGIH 2004). MAK: 2 ppm, 5.2 mg/m3; Peak limitation category: I(1); Pregnancy risk group: IIc; (DFG 2004).
PHYSICAL PROPERTIES
Boiling point: 121/C Vapour pressure, kPa at 20/C: 6.4 Melting point: -41.6/C Relative vapour density (air = 1): 2.2 Relative density (water = 1): 1.4 Relative density of the vapour/air-mixture at 20/C (air = 1): 1.07 Solubility in water: miscible
ENVIRONMENTAL DATA
NOTES
Depending on the degree of exposure, periodic medical examination is suggested. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Rinse contaminated clothes (fire hazard) with plenty of water. Other UN 2031 classification with more than 70% nitric acid, hazard class 8, subsidiary hazard 5.1, packing group I. Card has been partly updated in April 2005. See sections Occupational Exposure Limits, Emergency Response, Notes.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
©IPCS 2005 Chemical Information Annexure - III : 35 p-XYLENE 0086 March 2002 CAS No: 106-42-3 para-Xylene RTECS No: ZE2625000 1,4-Dimethylbenzene UN No: 1307 p-Xylol
EC No: 601-022-00-9 C6H4(CH3)2 / C8H10 Molecular mass: 106.2
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Flammable. NO open flames, NO sparks, and Powder, water spray, foam, carbon NO smoking. dioxide.
EXPLOSION Above 27°C explosive vapour/air Above 27°C use a closed system, In case of fire: keep drums, etc., mixtures may be formed. ventilation, and explosion-proof cool by spraying with water. electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding).
EXPOSURE STRICT HYGIENE! AVOID EXPOSURE OF (PREGNANT) WOMEN!
Inhalation Dizziness. Drowsiness. Headache. Ventilation, local exhaust, or Fresh air, rest. Refer for medical Nausea. breathing protection. attention.
Skin Dry skin. Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes Redness. Pain. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. Abdominal Do not eat, drink, or smoke during Rinse mouth. Do NOT induce pain. (Further see Inhalation). work. vomiting. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Ventilation. Remove all ignition sources. Collect Xn Symbol leaking and spilled liquid in sealable containers as R: 10-20/21-38 far as possible. Absorb remaining liquid in sand or S: (2-)25 inert absorbent and remove to safe place. Do NOT Note: C let this chemical enter the environment. (Extra UN Hazard Class: 3 personal protection: filter respirator for organic UN Pack Group: III gases and vapours.)
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-30S1307-III Fireproof. Separated from strong oxidants, and strong acids. NFPA Code: H 2; F 3; R 0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2002 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 36 0086 p-XYLENE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation, through the skin and by ingestion. Physical dangers As a result of flow, agitation, etc., electrostatic charges can be Inhalation risk generated. A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C. Chemical dangers Reacts with strong acids and strong oxidants. Effects of short-term exposure The substance is irritating to the eyes and the skin. The Occupational exposure limits substance may cause effects on the central nervous system. If TLV: 100 ppm as TWA; 150 ppm as STEL A4 (ACGIH 2001). this liquid is swallowed, aspiration into the lungs may result in BEI specified by (ACGIH 2001). chemical pneumonitis. EU OEL: 50 ppm as TWA; 100 ppm as STEL (skin) (EU 2000). Effects of long-term or repeated exposure The liquid defats the skin. The substance may have effects on the central nervous system. Exposure to the substance may enhance hearing damage caused by exposure to noise. Animal tests show that this substance possibly causes toxicity to human reproduction or development.
PHYSICAL PROPERTIES
Boiling point: 138°C Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02 Melting point: 13°C Flash point: 27°C c.c. Relative density (water = 1): 0.86 Auto-ignition temperature: 528°C Solubility in water: none Explosive limits, vol% in air: 1.1-7.0 Vapour pressure, kPa at 20°C: 0.9 Octanol/water partition coefficient as log Pow: 3.15 Relative vapour density (air = 1): 3.7
ENVIRONMENTAL DATA The substance is toxic to aquatic organisms.
NOTES Depending on the degree of exposure, periodic medical examination is indicated. The recommendations on this Card also apply to technical xylene. See ICSC 0084 o-Xylene and 0085 m-Xylene.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2002 Chemical Information Annexure - III : 37 PROPANE 0319 November 2003 CAS No: 74-98-6 n-Propane RTECS No: TX2275000 (cylinder)
UN No: 1978 C3H8 / CH3CH2CH3 EC No: 601-003-00-5 Molecular mass: 44.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Extremely flammable. NO open flames, NO sparks, and Shut off supply; if not possible and NO smoking. no risk to surroundings, let the fire burn itself out; in other cases extinguish with powder, carbon dioxide.
EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation, In case of fire: keep cylinder cool by explosion-proof electrical equipment spraying with water. Combat fire and lighting. Prevent build-up of from a sheltered position. electrostatic charges (e.g., by grounding) if in liquid state. Use non-sparking handtools.
EXPOSURE
Inhalation Drowsiness. Unconsciousness. Closed system and ventilation. Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
Skin ON CONTACT WITH LIQUID: Cold-insulating gloves. Protective ON FROSTBITE: rinse with plenty FROSTBITE. clothing. of water, do NOT remove clothes. Refer for medical attention.
Eyes ON CONTACT WITH LIQUID: Face shield. First rinse with plenty of water for FROSTBITE. several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! Remove F+ Symbol all ignition sources. Ventilation. NEVER direct water R: 12 jet on liquid. (Extra personal protection: S: (2-)9-16 self-contained breathing apparatus.) UN Hazard Class: 2.1
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-20S1978 Fireproof. Cool. NFPA Code: H1; F4; R0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2003 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 38 0319 PROPANE
IMPORTANT DATA Physical State; Appearance Routes of exposure ODOURLESS, COLOURLESS COMPRESSED LIQUEFIED The substance can be absorbed into the body by inhalation. GAS. Inhalation risk Physical dangers On loss of containment this liquid evaporates very quickly The gas is heavier than air and may travel along the ground; displacing the air and causing a serious risk of suffocation distant ignition possible, and may accumulate in low ceiling when in confined areas. spaces causing deficiency of oxygen. As a result of flow, agitation, etc., electrostatic charges can be generated. Effects of short-term exposure Rapid evaporation of the liquid may cause frostbite. The Occupational exposure limits substance may cause effects on the central nervous system. TLV: 2500 ppm as TWA; (ACGIH 2003). MAK: 1000 ppm, 1800 mg/m3; Peak limitation category: II(2); Pregnancy risk group: IIc; (DFG 2003).
PHYSICAL PROPERTIES
Boiling point: -42°C Relative vapour density (air = 1): 1.6 Melting point: -189.7°C Flash point: -104°C Relative density (water = 1): 0.5 Auto-ignition temperature: 450°C Solubility in water, g/100 ml at 20°C: 0.007 Explosive limits, vol% in air: 2.1-9.5 Vapour pressure, kPa at 20°C: 840 Octanol/water partition coefficient as log Pow: 2.36
ENVIRONMENTAL DATA
NOTES Check oxygen content before entering area. Turn leaking cylinder with the leak up to prevent escape of gas in liquid state. High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2003 Chemical Information Annexure - III : 39 STYRENE 0073 April 1994 CAS No: 100-42-5 Vinylbenzene RTECS No: WL3675000 Phenylethylene UN No: 2055 (styrene monomer, inhibited) Ethenylbenzene
EC No: 601-026-00-0 C8H8 / C6H5CH=CH2 Molecular mass: 104.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Flammable. Gives off irritating or NO open flames, NO sparks, and Powder, AFFF, foam, carbon toxic fumes (or gases) in a fire. NO smoking. dioxide.
EXPLOSION Above 31C explosive vapour/air Above 31C use a closed system, In case of fire: keep drums, etc., mixtures may be formed. See ventilation, and explosion-proof cool by spraying with water. Notes. electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding).
EXPOSURE AVOID ALL CONTACT!
Inhalation Dizziness. Drowsiness. Headache. Ventilation, local exhaust, or Fresh air, rest. Nausea. Weakness. breathing protection.
Skin Redness. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes Redness. Pain. Safety goggles or eye protection in First rinse with plenty of water for combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Abdominal pain (further see Do not eat, drink, or smoke during Rinse mouth. Do NOT induce Inhalation). work. Wash hands before eating. vomiting. Give plenty of water to drink. Rest.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Ventilation. Collect leaking and spilled liquid in Xn Symbol Airtight. Marine pollutant. sealable containers as far as possible. Absorb R: 10-20-36/38 remaining liquid in sand or inert absorbent and S: (2-)23 remove to safe place. Do NOT wash away into Note: D sewer. Do NOT let this chemical enter the UN Hazard Class: 3 environment (extra personal protection: UN Pack Group: III self-contained breathing apparatus).
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-101 Fireproof. Separated from incompatible materials (see Chemical Dangers). (monomer, inhibited) Cool. Keep in the dark. Store only if stabilized. NFPA Code: H 2; F 3; R 2;
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IMPORTANT DATA
Physical State; Appearance Routes of Exposure COLOURLESS TO YELLOW, OILY LIQUID. The substance can be absorbed into the body by inhalation and through the skin. Physical Dangers As a result of flow, agitation, etc., electrostatic charges can be Inhalation Risk generated. A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20C. Chemical Dangers The substance can form explosive peroxides. The substance Effects of Short-term Exposure may polymerize due to warming, under the influence of light The substance irritates the eyes, the skin and the respiratory and on contact with many compounds such as oxygen, tract. Swallowing the liquid may cause aspiration into the lungs oxidizing agents, peroxides and strong acids with fire or with the risk of chemical pneumonitis. Exposure could cause explosion hazard. The substance decomposes on burning lowering of consciousness. producing toxic fumes, styrene oxide. Attacks copper and copper alloys. Effects of Long-term or Repeated Exposure Repeated or prolonged contact with skin may cause dermatitis. Occupational Exposure Limits Repeated or prolonged contact may cause skin sensitization. TLV: 50 ppm; 213 mg/m3 Repeated or prolonged inhalation exposure may cause STEL: 100ppm; 426 mg/m3 (skin) (ACGIH 1993-1994). asthma. The substance may have effects on the central nervous system. This substance is possibly carcinogenic to humans. See Notes.
PHYSICAL PROPERTIES
Boiling point: 145C Relative density of the vapour/air-mixture at 20C (air = 1): 1.02 Melting point: -30.6C Flash point: 31C c.c. Relative density (water = 1): 0.9 Auto-ignition temperature: 490C Solubility in water, g/100 ml at 25C: 0.03 Explosive limits, vol% in air: 0.9-6.8 Vapour pressure, kPa at 20C: 0.7 Octanol/water partition coefficient as log Pow: 3.2 Relative vapour density (air = 1): 3.6
ENVIRONMENTAL DATA
NOTES Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of asthma often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Anyone who has shown symptoms of asthma due to this substance should avoid all further contact with this substance. An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. Check for peroxides prior to distillation; eliminate if found. Styrene monomer vapours are uninhibited and may form polymers in vents or flame arresters of storage tanks, resulting in blockage of vents.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
© IPCS 1999 Chemical Information Annexure - III : 41 SULFUR 1166 April 2000 CAS No: 7704-34-9 Flowers of sulfur RTECS No: WS4250000 Flour sulfur UN No: 1350 Brimstone
S or S8 Molecular mass: 256.5 (S8); Atomic mass: 32.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Combustible. NO open flames, NO sparks, and Water spray. Foam. Powder. Dry NO smoking. sand.
EXPLOSION Finely dispersed particles form Prevent deposition of dust; closed In case of fire: keep drums, etc., explosive mixtures in air. system, dust explosion-proof cool by spraying with water. electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding).
EXPOSURE PREVENT DISPERSION OF DUST!
Inhalation Burning sensation. Cough. Sore Local exhaust or breathing Fresh air, rest. Half-upright position. throat. protection. Refer for medical attention.
Skin Redness. Protective gloves. Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes Redness. Pain. Blurred vision. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. Diarrhoea. Do not eat, drink, or smoke during Rinse mouth. Refer for medical work. attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into containers; if UN Hazard Class: 4.1 appropriate, moisten first to prevent dusting. (Extra UN Pack Group: III personal protection: P2 filter respirator for harmful particles).
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-115A Fireproof. Separated from strong oxidants. NFPA Code: H 1; F 1; R 0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2000 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 42 1166 SULFUR
IMPORTANT DATA Physical State; Appearance Routes of exposure YELLOW SOLID IN VARIOUS FORMS The substance can be absorbed into the body by inhalation and by ingestion. Physical dangers Dust explosion possible if in powder or granular form, mixed Inhalation risk with air. If dry, it can be charged electrostatically by swirling, Evaporation at 20°C is negligible; a harmful concentration of pneumatic transport, pouring, etc. airborne particles can, however, be reached quickly when dispersed. Chemical dangers On combustion, forms toxic and corrosive gases of sulfur oxides Effects of short-term exposure including sulfur dioxide (see ICSC 0074). Reacts violently with The substance irritates the eyes, the skin and the respiratory strong oxidants causing fire and explosion hazard, especially if tract. Inhalation of powder of this substance may cause powdered. inflammation of the nose and the respiratory tract.
Occupational exposure limits Effects of long-term or repeated exposure TLV not established. Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the respiratory tract, resulting in chronic bronchitis.
PHYSICAL PROPERTIES
Boiling point: 445°C Solubility in water: none Melting point: (r-sulfur) 107°C, (beta-sulfur) 115°C, Flash point: 160°C c.c. (amorphous) 120)°C Auto-ignition temperature: 232°C Density: 2.1 g/cm3 Explosive limits, vol% in air: 35-1400 g/m3
ENVIRONMENTAL DATA
NOTES Often transported in molten state (UN 2448; TEC(R)-115). Molten sulfur reacts with hydrocarbons to form toxic and flammable gases. Depending on the degree of exposure, periodic medical examination is indicated.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2000 Chemical Information Annexure - III : 43 SULFURIC ACID 0362 October 2000 CAS No: 7664-93-9 Sulfuric acid 100% RTECS No: WS5600000 Oil of vitriol UN No: 1830 H2SO4 EC No: 016-020-00-8 Molecular mass: 98.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Not combustible. Many reactions NO contact with flammable NO water. In case of fire in the may cause fire or explosion. Gives substances. NO contact with surroundings: powder, AFFF, foam, off irritating or toxic fumes (or combustibles. carbon dioxide. gases) in a fire.
EXPLOSION Risk of fire and explosion on contact In case of fire: keep drums, etc., cool with base(s), combustible by spraying with water but NO direct substances, oxidants, reducing contact with water. agents or water.
EXPOSURE PREVENT GENERATION OF IN ALL CASES CONSULT A MISTS! AVOID ALL CONTACT! DOCTOR!
Inhalation Corrosive. Burning sensation. Sore Ventilation, local exhaust, or breathing Fresh air, rest. Half-upright position. throat. Cough. Laboured breathing. protection. Artificial respiration may be needed. Shortness of breath. Symptoms Refer for medical attention. may be delayed (see Notes).
Skin Corrosive. Redness. Pain. Blisters. Protective gloves. Protective clothing. Remove contaminated clothes. Serious skin burns. Rinse skin with plenty of water or shower. Refer for medical attention.
Eyes Corrosive. Redness. Pain. Severe Face shield or eye protection in First rinse with plenty of water for deep burns. combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Corrosive. Abdominal pain. Burning Do not eat, drink, or smoke during Rinse mouth. Do NOT induce sensation. Shock or collapse. work. vomiting. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Consult an expert! Evacuate danger area! Do NOT C Symbol Unbreakable packaging; put absorb in saw-dust or other combustible absorbents. R: 35 breakable packaging into closed Personal protection: complete protective clothing S: (1/2-)26-30-45 unbreakable container. Do not including self-contained breathing apparatus. Do NOT Note: B transport with food and feedstuffs. let this chemical enter the environment. UN Hazard Class: 8 UN Pack Group: II
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-80S1830 or Separated from combustible and reducing substances, strong oxidants, 80GC1-II+III strong bases, food and feedstuffs, incompatible materials. See Chemical NFPA Code: H 3; F 0; R 2; W Dangers. May be stored in stainless steel containers. Store in an area having corrosion resistant concrete floor.
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2005 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 44 0362 SULFURIC ACID
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS, OILY, HYGROSCOPIC LIQUID, WITH NO The substance can be absorbed into the body by inhalation of its ODOUR. aerosol and by ingestion.
Chemical dangers Inhalation risk The substance is a strong oxidant and reacts violently with Evaporation at 20/C is negligible; a harmful concentration of combustible and reducing materials. The substance is a strong airborne particles can, however, be reached quickly on spraying. acid, it reacts violently with bases and is corrosive to most common metals forming a flammable/explosive gas (hydrogen - Effects of short-term exposure see ICSC 0001). Reacts violently with water and organic materials Corrosive. The substance is very corrosive to the eyes, the skin with evolution of heat (see Notes). Upon heating, irritating or toxic and the respiratory tract. Corrosive on ingestion. Inhalation of an fumes (or gases) (sulfur oxides) are formed. aerosol of this substance may cause lung oedema (see Notes).
Occupational exposure limits Effects of long-term or repeated exposure TLV: 1 mg/m3 as TWA, 3 mg/m3 as STEL; sulfuric acid contained Lungs may be affected by repeated or prolonged exposure to an in strong inorganic acid mists A2 (suspected human carcinogen); aerosol of this substance. Risk of tooth erosion upon repeated or (ACGIH 2004). prolonged exposure to an aerosol of this substance. Strong MAK: (Inhalable fraction) 0.1 mg/m3; Peak limitation category: I(1); inorganic acid mists containing this substance are carcinogenic Carcinogen category: 4; Pregnancy risk group: C; (DFG 2004). to humans.
PHYSICAL PROPERTIES
Boiling point (decomposes): 340/C Solubility in water: miscible Melting point: 10/C Vapour pressure, kPa at 146/C: 0.13 Relative density (water = 1): 1.8 Relative vapour density (air = 1): 3.4
ENVIRONMENTAL DATA
The substance is harmful to aquatic organisms.
NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water. Other UN numbers: UN1831 Sulfuric acid, fuming, hazard class 8, subsidiary hazard 6.1, pack group I; UN1832 Sulfuric acid, spent, Hazard class 8, Pack group II. Card has been partly updated in October 2005. See sections Occupational Exposure Limits, Emergency Response.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2005 Chemical Information Annexure - III : 45 TOLUENE 0078 October 2002 CAS No: 108-88-3 Methylbenzene RTECS No: XS5250000 Toluol UN No: 1294 Phenylmethane
EC No: 601-021-00-3 C6H5CH3 / C7H8 Molecular mass: 92.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Highly flammable. NO open flames, NO sparks, and Powder, AFFF, foam, carbon NO smoking. dioxide.
EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, In case of fire: keep drums, etc., explosion-proof electrical equipment cool by spraying with water. and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools.
EXPOSURE STRICT HYGIENE! AVOID EXPOSURE OF (PREGNANT) WOMEN!
Inhalation Cough. Sore throat. Dizziness. Ventilation, local exhaust, or Fresh air, rest. Refer for medical Drowsiness. Headache. Nausea. breathing protection. attention. Unconsciousness.
Skin Dry skin. Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes Redness. Pain. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. Abdominal Do not eat, drink, or smoke during Rinse mouth. Do NOT induce pain. (Further see Inhalation). work. vomiting. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area in large spill! Consult an F Symbol expert in large spill! Remove all ignition sources. Xn Symbol Ventilation. Collect leaking liquid in sealable R: 11-38-48/20-63-65-67 containers. Absorb remaining liquid in sand or inert S: (2-)36/37-46-62 absorbent and remove to safe place. Do NOT wash UN Hazard Class: 3 away into sewer. Do NOT let this chemical enter the UN Pack Group: II environment. Personal protection: self-contained breathing apparatus in large spill.
EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-30S1294 Fireproof. Separated from strong oxidants. NFPA Code: H 2; F 3; R 0
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission © International IPCS 2004 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 46 0078 TOLUENE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation, through the skin and by ingestion. Physical dangers The vapour mixes well with air, explosive mixtures are formed Inhalation risk easily. As a result of flow, agitation, etc., electrostatic charges A harmful contamination of the air can be reached rather quickly can be generated. on evaporation of this substance at 20/C.
Chemical dangers Effects of short-term exposure Reacts violently with strong oxidants causing fire and explosion The substance is irritating to the eyes and the respiratory tract. hazard. The substance may cause effects on the central nervous system. If this liquid is swallowed, aspiration into the lungs may Occupational exposure limits result in chemical pneumonitis. Exposure at high levels may TLV: 50 ppm as TWA; (skin); A4; BEI issued; (ACGIH 2004). result in cardiac dysrhythmia and unconsciousness. MAK: 50 ppm, 190 mg/m3; H; Peak limitation category: II(4); Pregnancy risk group: C; (DFG 2004). Effects of long-term or repeated exposure The liquid defats the skin. The substance may have effects on the central nervous system. Exposure to the substance may enhance hearing damage caused by exposure to noise. Animal tests show that this substance possibly causes toxicity to human reproduction or development.
PHYSICAL PROPERTIES
Boiling point: 111/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.01 Melting point: -95/C Flash point: 4/C c.c. Relative density (water = 1): 0.87 Auto-ignition temperature: 480/C Solubility in water: none Explosive limits, vol% in air: 1.1-7.1 Vapour pressure, kPa at 25/C: 3.8 Octanol/water partition coefficient as log Pow: 2.69 Relative vapour density (air = 1): 3.1
ENVIRONMENTAL DATA
The substance is toxic to aquatic organisms.
NOTES
Depending on the degree of exposure, periodic medical examination is suggested. Use of alcoholic beverages enhances the harmful effect. Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
©IPCS 2004 Chemical Information Annexure - III : 47 TRIMETHYLAMINE 0206 October 2002 CAS No: 75-50-3 N,N-Dimethylmethanamine RTECS No: PA0350000 TMA UN No: 1083 (anhydrous) (cylinder)
EC No: 612-001-00-9 C3H9N / (CH3)3N Molecular mass: 59.1
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Extremely flammable. Gives off NO open flames, NO sparks, and Shut off supply; if not possible and irritating or toxic fumes (or gases) NO smoking. no risk to surroundings, let the fire in a fire. burn itself out; in other cases extinguish with powder, carbon dioxide.
EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation, In case of fire: keep cylinder cool by explosion-proof electrical equipment spraying with water. Combat fire and lighting. Use non-sparking from a sheltered position. handtools.
EXPOSURE STRICT HYGIENE!
Inhalation Burning sensation. Cough. Ventilation, local exhaust, or Fresh air, rest. Half-upright position. Headache. Sore throat. Laboured breathing protection. Artificial respiration may be needed. breathing. Shortness of breath. Refer for medical attention. Symptoms may be delayed (see Notes).
Skin ON CONTACT WITH LIQUID: Cold-insulating gloves. Protective ON FROSTBITE: rinse with plenty FROSTBITE. clothing. of water, do NOT remove clothes. Refer for medical attention.
Eyes Redness. Pain. Blurred vision. Safety goggles, or eye protection in First rinse with plenty of water for combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Do not eat, drink, or smoke during work.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! F+ Symbol Ventilation. Remove all ignition sources. NEVER Xn Symbol direct water jet on liquid. Remove vapour with fine R: 12-20-37/38-41 water spray. (Extra personal protection: complete S: (2-)16-26-39 protective clothing including self-contained UN Hazard Class: 2.1 breathing apparatus.)
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-20S1083 Fireproof. Cool. NFPA Code: H3; F4; R0.
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2002 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 48 0206 TRIMETHYLAMINE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS COMPRESSED LIQUEFIED GAS, WITH The substance can be absorbed into the body by inhalation. CHARACTERISTIC ODOUR. Inhalation risk Physical dangers On loss of containment, a harmful concentration of this gas in The gas is heavier than air and may travel along the ground; the air will be reached very quickly. distant ignition possible. Effects of short-term exposure Chemical dangers The substance is severely irritating to the eyes and the The substance decomposes on burning producing toxic fumes respiratory tract. Rapid evaporation of the liquid may cause including nitrogen oxides. The solution in water is a strong base, frostbite. Inhalation of the substance may cause lung oedema it reacts violently with acid and is corrosive. Reacts violently (see Notes). The effects may be delayed. Medical observation with oxidants, ethylene oxide. Attacks metal such as copper, is indicated. zinc, aluminium, tin, and their alloys.
Occupational exposure limits TLV: 5 ppm (as TWA); 15 ppm (as STEL); (ACGIH 2002). MAK: class IIb (see Notes) (2002)
PHYSICAL PROPERTIES
Boiling point: 3°C Relative vapour density (air = 1): 2 Melting point: -117°C Flash point: Flammable Gas Relative density (water = 1): 0.6 (liquid) Auto-ignition temperature: 190°C Solubility in water: very good Explosive limits, vol% in air: 2.0-11.6 Vapour pressure, kPa at 20°C: 187 Octanol/water partition coefficient as log Pow: 0.2
ENVIRONMENTAL DATA
NOTES Turn leaking cylinder with the leak up to prevent escape of gas in liquid state. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered. MAK value not established but full documentation is available (MAK IIb).
ADDITIONAL INFORMATION
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©IPCS 2002 Chemical Information Annexure - III : 49 TURPENTINE 1063 March 2002 CAS No: 8006-64-2 Turpentine, oil RTECS No: YO8400000 Spirits of turpentine UN No: 1299 Oil of turpentine EC No: 650-002-00-6 Steam distilled turpentine Gum spirits Wood turpentine
C10H16 (approx) Molecular mass: 136 (approx)
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Flammable. Gives off irritating or NO open flames, NO sparks, and Foam, dry powder, carbon dioxide. toxic fumes (or gases) in a fire. NO smoking.
EXPLOSION Above 30°C explosive vapour/air Above 30°C use a closed system, In case of fire: keep drums, etc., mixtures may be formed. ventilation, and explosion-proof cool by spraying with water. electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding). Use non-sparking handtools.
EXPOSURE PREVENT GENERATION OF MISTS! STRICT HYGIENE!
Inhalation Confusion. Cough. Headache. Ventilation, local exhaust, or Fresh air, rest. Artificial respiration Sore throat. Shortness of breath. breathing protection. may be needed. Refer for medical attention.
Skin Redness. Pain. Protective gloves. Protective Remove contaminated clothes. clothing. Rinse and then wash skin with water and soap.
Eyes Blurred vision. Pain. Redness. Safety spectacles, or eye protection First rinse with plenty of water for in combination with breathing several minutes (remove contact protection. lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. Abdominal Do not eat, drink, or smoke during Do NOT induce vomiting. Give pain. Nausea. Vomiting. work. plenty of water to drink. Refer for Confusion. Convulsions. medical attention. Diarrhoea. Unconsciousness.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Cover the spilled material with dry earth or sand or Xn Symbol Marine pollutant. other non-combustible material. Ventilation. N Symbol Remove all ignition sources. Do NOT wash away R: 10-20/21/22-36/38-43-51/53-65 into sewer. Sweep spilled substance into containers S: (2-)36/37-46-61-62 and then remove to safe place. (Extra personal UN Hazard Class: 3 protection: self-contained breathing apparatus.) Do UN Pack Group: III NOT let this chemical enter the environment.
EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-30S1299 Fireproof. Separated from strong oxidants, incompatible materials. See NFPA Code: H1; F3; R0 Chemical Dangers. Cool. Keep in a well-ventilated room.
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2002 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 50 1063 TURPENTINE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. Chemical dangers On combustion, forms toxic fumes including carbon monoxide. Inhalation risk The substance decomposes slowly under the influence of air or A harmful contamination of the air will be reached rather slowly light producing oxidation products that are more toxic or on evaporation of this substance at 20°C. irritating than turpentine itself. Reacts violently with oxidants, halogens, combustible substances, mineral acids. Attacks Effects of short-term exposure plastic and rubber. The vapour is irritating to the eyes, the skin and the respiratory tract. If this liquid is swallowed, aspiration into the lungs may Occupational exposure limits result in chemical pneumonitis. The substance may cause TLV: 100 ppm (as TWA); SEN Intended change; (ACGIH 2001). effects on the central nervous system, bladder and kidneys, resulting in irritability, convulsions and kidney impairment. Exposure at high levels may result in tachycardia, unconsciousness, respiratory failure, death.
Effects of long-term or repeated exposure Repeated or prolonged contact may cause skin sensitization. The liquid defats the skin.
PHYSICAL PROPERTIES
Boiling point: 149 to 180°C Relative vapour density (air = 1): 4.6 to 4.8 Melting point: -50 to -60°C Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01 Relative density (water = 1): 0.9 Flash point: 30 to 46°C c.c. Solubility in water: none Auto-ignition temperature: 220 to 255°C Vapour pressure, kPa at 20°C: 0.25 to 0.67 Explosive limits, vol% in air: 0.8-6
ENVIRONMENTAL DATA The substance is harmful to aquatic organisms. The substance may cause long-term effects in the aquatic environment.
NOTES The odour warning when the exposure limit value is exceeded is insufficient. Turpentine is obtained by distilling the gum from various species of pine. It is a mixture of isomeric terpene hydrocarbons. Composition varies with refining methods and the age, location and species of the softwood source.
ADDITIONAL INFORMATION
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©IPCS 2002 Chemical Information Annexure - III : 51 m-XYLENE 0085 March 2002 CAS No: 108-38-3 meta-Xylene RTECS No: ZE2275000 1,3-Dimethylbenzene UN No: 1307 m-Xylol
EC No: 601-022-00-9 C6H4(CH3)2 / C8H10 Molecular mass: 106.2
TYPES OF HAZARD/ ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING EXPOSURE
FIRE Flammable. NO open flames, NO sparks, and Powder, water spray, foam, carbon NO smoking. dioxide.
EXPLOSION Above 27°C explosive vapour/air Above 27°C use a closed system, In case of fire: keep drums, etc., mixtures may be formed. ventilation, and explosion-proof cool by spraying with water. electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding).
EXPOSURE STRICT HYGIENE!
Inhalation Dizziness. Drowsiness. Headache. Ventilation, local exhaust, or Fresh air, rest. Refer for medical Nausea. breathing protection. attention.
Skin Dry skin. Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes Redness. Pain. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. Abdominal Do not eat, drink, or smoke during Rinse mouth. Do NOT induce pain. (Further see Inhalation). work. vomiting. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Ventilation. Remove all ignition sources. Collect Xn Symbol leaking and spilled liquid in sealable containers as R: 10-20/21-38 far as possible. Absorb remaining liquid in sand or S: (2-)25 inert absorbent and remove to safe place. Do NOT Note: C let this chemical enter the environment. (Extra UN Hazard Class: 3 personal protection: filter respirator for organic UN Pack Group: III gases and vapours.)
EMERGENCY RESPONSE STORAGE
NFPA Code: H 2; F 3; R 0; Fireproof. Separated from strong oxidants and strong acids. Transport Emergency Card: TEC (R)-30S1307-III
Prepared in the context of cooperation between the International IPCS Programme on Chemical Safety and the European Commission International © IPCS 2002 Programme on Chemical Safety SEE IMPORTANT INFORMATION ON THE BACK. Chemical Information Annexure - III : 52 0085 m-XYLENE
IMPORTANT DATA Physical State; Appearance Routes of exposure COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. The substance can be absorbed into the body by inhalation, through the skin and by ingestion. Physical dangers As a result of flow, agitation, etc., electrostatic charges can be Inhalation risk generated. A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C. Chemical dangers Reacts with strong acids and strong oxidants. Effects of short-term exposure The substance is irritating to the eyes and the skin. The Occupational exposure limits substance may cause effects on the central nervous system. If TLV: 100 ppm as TWA; 150 ppm as STEL A4 (ACGIH 2001). this liquid is swallowed, aspiration into the lungs may result in BEI specified by (ACGIH 2001). chemical pneumonitis. EU OEL: 50 ppm as TWA; 100 ppm as STEL (skin) (EU 2000). Effects of long-term or repeated exposure The liquid defats the skin. The substance may have effects on the central nervous system. Exposure to the substance may enhance hearing damage caused by exposure to noise. Animal tests show that this substance possibly causes toxicity to human reproduction or development.
PHYSICAL PROPERTIES
Boiling point: 139°C Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02 Melting point: -48°C Flash point: 27°C c.c. Relative density (water = 1): 0.86 Auto-ignition temperature: 527°C Solubility in water: none Explosive limits, vol% in air: 1.1-7.0 Vapour pressure, kPa at 20°C: 0.8 Octanol/water partition coefficient as log Pow: 3.20 Relative vapour density (air = 1): 3.7
ENVIRONMENTAL DATA The substance is toxic to aquatic organisms.
NOTES Depending on the degree of exposure, periodic medical examination is indicated. The recommendations on this Card also apply to technical xylene. See ICSC 0084 o-Xylene and 0086 p-Xylene.
ADDITIONAL INFORMATION
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information
©IPCS 2002 Chemical Information Annexure - III : 53
ANNEXURE – IV
CONTACT INFORMATION EMERGENCY SERVICES
150 Telephone Nos. Of Control Rooms
Important Control Rooms Telephone nos. Fax No.
22694725, Dsaster Mangement Control Room 22694727 22694719
22620251 Ext MCGM 2062/2054 22704403
Disaster Helpline 108
24146533, Bus Running Control Officer 24184489 24146532
24137937, (BEST Traffic Control) 24146262 Ext-801
24143611, BEST Traffic Control Room 24136883
24137645, (Wadala) 24146162
24137924, BEST Bus Control 24127244
24129651, (For BEST bus breakdowns) 24111979
24145888, BEST Electric Supply -Dadar 24124242
- 22067893, Control Room Phathakwadi 22082875 22085888
Weather Bureau 22150431 22160824
22024243, Mantralaya Control Room 22854168
24937746, Traffic Police 24937755 24927234
24937747
22625020, Mumbai Police Headquarters 100 22621983 22633319
22641440, 22623054
141 Fire Brigade Control Room 101 23076111/12/13 23085993
23086181/82
Reliance Energy - Special Officer/ 30094920
Shri V.B.Sharma 9323551665
Santacruz 30099999 30099776
30096999, Andheri/Jogeshwari 30094302
30096999, Goregaon/Kandivili 30094900 30094844
30094500, Borivili/Bhayander 30093070 30094633
30096999, Chembur/Kurla/Vikhroli 30092040 30092022
26472131, M.S.E.D.C.L. - Bandra 26474211 26476749
25663408, Bhandup 25664323 25643990
Mulund(West) 25686666, 25653408
Mulund(East) 21636945
22017420, Western Railway Churchgate 22084287
23070564, Control Room 23720505
22622685, Central Railway CST 9821223724
22620173, Railway Police 22621695
27579969, Konkan Railway Control Room 27572015 27572420
MTNL - Head Office 24371900 24372033
142 CONTACT INFORMATION:
Fire Station:
FIRE STATION NAME & ADDRESS OF THE CONTACT NO. NO. FIRESTATIONS 1 COLABA 22043603 NARAYAN ATMARAM SAWANT MARG,COLABA,MUMBAI-400 005 2 FORT 22611942 RUSTOM SINDHVA MARG,FORT,MUMBAI-400 001 3 MEMONWADA 23478818 S.V.P.ROAD,MUMBAI-400 003 4 GOVALIYA TANK 223801118 AGUST KRANTI MARG,NANA CHOWK, MUMBAI-400 007
5 BYCULLA 23086181 BAPURAO JAGTAP MARG,BYCULLA,MUMBAI-400 008 6 WARALI 24300178 DR.ANNI BASANT ROAD,WARALI,MUMBAI-400 025 7 DADAR 224134200 DR.BABASAHEB AMBEDKAR MARG,DADAR,MUMBAI-400 008 8 SHIVAJII PARK 24457203 PRAKASH KOTNIS MARG, MAHIM,MUMBAI-400 016 9 INDIRA DOCK 22611589 P’DIMELO ROAD,KARNAK BUNDER,MUMBAI-400 038 10 MANDVI 23716694 S.V.P.ROAD,WADIBUNDER, MUMBAI-400 009 11 SEWARI 23775756 BARISTER NATH PAI MARG,COTTON GREEN MARG,MUMBAI-400 033 12 ANDHERI 26205301 S.V.ROAD,IRLA BIDGE,ANDHERI(W) MUMBAI-400 058
13 VIKHROLI 25170730 L.B.S.ROAD,VIKHROLI PARKSITE, VIKHROLI(W) MUMBAI-400 079 14 CEMBUR 25224824 V.N.PURAVMARG,CHEMBUR, MUMBAI-400 071 15 DHARAVI 24077868
87 RAJASHRI SHAHU NAGAR, MAHIM(E), MUMBAI-400 017 16 DEVNAR 25563391 5/4 SECTOR,NEW MUNICIPAL COLONY, DEVNAR,MUMBAI-400 043 17 MULUND 25687637 L.B.S. MARG,MULUND(W) MUMBAI-400 080 18 RAVALI CAMP 24077841 LEELABAI KASBE MARG,SARDAR NAGAR NO.4, MUMBAI-400 037 19 KANDIVLI 28050101 S.V.ROAD,KANDIVLI(W) MUMBAI-400 067 20 MAROL 28210940/41 AGNISHAMAN DAL MARG,MAROL NAKA, ANDHERI(E),MUMBAI-400 059 21 MALAD 28071010 MARVE ROAD,MALVANI,MALAD(W) MUMBAI-400 095 22 BANDRA 26435206 KRSHNA CHANDRA MARG, RECLAMATION, BANDRA(W),MUMBAI-400 058 23 NARIMAN POINT 22882787 V.V.RAO MARG,MUMBAI-400 020 24 WADALA 24122255 SHAIKH MISTRI DARGA ROAD, C.G.S.COLONY,SECTOR NO.7,ANTOP HILL,MUMBAI-400 037 25 GAVANPADA 25639191 SWATANRA VEER SAVARKAR MARG, MULUND(E),MUMBAI-400 081 26 BORIVLI 26112121 GORAI ROAD ROAD, BORIVLI(W) MUMBAI-400 104 27 VILEPAELE 28602848 AZAD ROAD,VILEPARLE(E) GOREGOAN, MUMBAI-400 057 28 KURLA KAMANI 25039200 ANDHERI KURLA RD. L.B.S. MARG JUNCTION, OPP MUCUND CO. LTD. MUMBAI 29 BANDRA KURLA COMPLEX, S.O. KAHRBADE OPP MTNL OFFICE, 26435260 KURLA -W MUMBAI 30 CHINCHLI S.O. MHASKE LINK ROAD, 9819751759 MALAD(W,)MUMBAI
88 31 DINDOSHI S.O. JADHAV ARUN KUMAR VAIDYA MARG, 9869331391 GOREGOAN (E) MUMBAI 32 DAHISAR, S.O. MAINKAR SHAILENDRA NAGAR, NEAR DAHISAR 9869532248 POST OFFICE, DAHISAR -E MUMBAI 33 GOREGOAN 28712869 BEST COLONY ROAD, GOREGOAN(W) MUMBAI-400 104
Brigade Senior Officers:
DISI NAME AND ADDRESS MOBILE NOS. .C.F.O (i/c) P.D.KARGUPPIKAR 9820702531 INDIRA DOCK FIRE STATION ” U.K.TATKARE 9930464805 NARIMAN POINT FIRE STATION ” A.N.SHINDE 9930464806 KANDIWILI FIRE STATION ” H.N.MUJAWAR 9930464807 BYCULLA FIRE STATION ” S.V.JOSHI 9930464808 COLABA FIRE STATION Dy. A.R.PATIL 9930464809 C.F.O.( i/c) BYCULLA FIRE STATION DFO R.B.KHOLKHUMBE 9930464810 IDOCK FIRE STATOPM ” J.A.H. MALIK 9930464811 MEMONWADA FIRE D.F.O. (i/c) A.N.VARMA 9930464812 CHEMBUR FIRE STATION A.D.F.O S.A.MALI. 9930464813 ANDHERI FIRE STATION ” M.R.KADAM 9930464814 BYCULLA FIRE STATION ” C.I.SHAIKH 9930464815 MULUND KAMANI ” V.R.KUVESKAR 9930464817 KANDIVALI FIRE STATION ” V.V.NIKAM. 9930464818 BYCULLA FIRE STATION ” S.K.RANE. 9930464819 MAROL FIRE STATION
89 DISI NAME AND ADDRESS MOBILE NOS. ” S.H.NESRIKAR 9930464823 CHEMBER FIRE STATION ” P.S. RAHANGDALE 9930464820 NARIMAN POINT FIRE STATION ” S.A.KALE 9930464822 WORLI FIRE STATION ” S.G.AMIN. 9930464821 FORT FIRE STATION ” V.N. PANIGRAHI 9930464824 R.CAMP FIRE STATION ” K.V. HIWARALE 9930464825 M.WADA ” H.D. PARAB 9930464826 MAROL ” A.V. KALE 9930464827 BANDRA A.D.O. ( Tech) R.A. CHAUDHARY 9930464828 BYCULLA
90 Annexure – VIII
List of MCGM Hospitals
Municipal Hospitals:
Sr. Telephone No. of Name of Police Name Address No. Number Beds Station 1 A.K.J. Banke 7, Maharshi Dadhichi 2204 3322100 Azad Maidan Bihari E.N.T. Marg, Flora Fountain, 2204 2526 Police Station Hospital Fort, Mumbai – 01 2204 5996 2202 1191 2 Nair Hospital B.Y.L. Nair Charitable 2308 14901229 Agripada Hospital, Dr. Nair Road, 2309 8150 Police Station Mumbai Central, 2308 1491 Mumbai - 400 008 2308 1758 2385 5555
3 Municipal Eye DO Tanki, Maulana 2309 636180 Nagpada Hospital Saukat Ali Road, 2308 2632 Police Station Byculla (West) Mumbai - 400 008 4 Kasturba Sane Guruji Marg, 2308 3901515 Byculla Police Hospital Chinch Pokli, Mumbai - 2308 3902 Station 400 011 2300 4323 2308 3991 2309 2458
5 K.E.M. Hospital Dr. E. Borges Road, 2413 49771800 Bhoiwada Parel, Mumbai - 400 2413 1419 Police Station 012 2413 6051 2413 1763 6 Group of T.B. Jerbai Wadia Road, 2414 67891000 Kidwai Nagar Hospitals Sewree, Mumbai - 400 2414 6790 Police Station 015 2414 6791 2414 6792 7 Lokmanya Tilak Sion Hospital, Sion 2407 63811422 Matunga Municipal Road, Sion (West), 24081504 Police Station General Hospital Mumbai - 400 022 24072020 8 Ackworth Near St. Joseph 2414 7256 Wadala Police Municipal Church, Wadala, Station Leprosy Hospital Mumbai - 400 031 9 Centenary Vaman Tukaram Patil 2556 4069210 Gowandi Hospital Marg, Near Dukes 2556 4071 Police Station Company, Gowandi, Mumbai – 400 043
95 10 K.B. Bhabha R.K. Patkar Road, 2642 2541 Bandra Police Hospital Bandra (West), Mumbai 2642 2542 Station - 400 050 2640 6787 2642 9828 11 V.N. Desai Golibar Road, T.P. S. 3, 2618 3018 Vakola Police Municipal 11th Road, Santacruze 2615 1506 Station General Hospital (East), Mumbai - 400 2618 2081 055 12 Cooper Hospital Dr. R.N. Cooper 2620 7254441 Juhu Police Memorial General 2620 5892 Station Hospital, Cooper 2620 7258 Hospital Road, Juhu, 2620 7447 Parle (West), Mumbai - 400 056 13 B.S.E.S. M.G. S.V. Road, Opp. Railway 5697 0707 Oshiwara Hospital Station, Andheri (West) 5697 0288 Police Station Mumbai - 400 058 5697 0289 14 Mahanagar Kandiwali (West) 2805 1509 Kandivali Palika Shatabdi Mumbai - 400 067 2805 0882 Police Station General Hospital 2805 0105 15 K.B. Bhabha Kurla Police Station 2650 0144320 Kurla Police Hospital Road, Takiyawad, Kurla 2650 0241 Station (West), Mumbai – 400 2650 3145 071 16 MAA Hospital Diwaliben Mafatlal 2522 033375 Basant Park Mehta Hospital, 2522 0334 (Chembur) Sarvodaya Estate, R.C. 2522 2084 Police Station Marg, Chembur, Mumbai - 400 071 17 Rajawadi Vadilal Chatrabhuj 2509 4149700 Tilak Nagar Hospital Gandhi & Sheth M.A. 2509 4150 Police Station Vora Municipal Gen. 2509 4153 Hospital, Rajawadi, 2509 4151 Ghatkopar (East), Mumbai - 400 077 18 M.T. Agarwal Dr. R.P. Road, Mulund 2564 0767233 Mulund (W) Municipal (West), Mumbai - 400 2560 5730 Police Station General Hospital 080 2560 5727 2560 5729 19 Vir Savarkar Mahatma Phule Road, 2561 6226100 Navghar Police Municipal Mulund (East), Mumbai 2568 6225 Station Hospital - 400 081 20 Mahatma Phule Kannamvar Nagar 2, 2578 2283148 Kannamwar Municipal Vikroli (East), Mumbai - 2577 1292 Nagar Police General Hospital 400 083 Station 21 Sant Muktabai Bhattwadi, S.G. Barve 2512 6088 Ghatkopar Municipal Gneral Nagar, Ghatkopar 2515 3771 Police Station Hospital (West), Mumbai - 400 086
96 22 Municipal Vaman Tukaram Patil 2556 4069210 Trombe Police Centenary Marg, Near Dukes 2556 4071 Station General Hospital Company, Gowandi, Mumbai – 400 043 23 Bhagwati S.V.Road, Tulsi Baug, 2893 2461375 M.H.B. Police Municipal Borivali (West), Mumbai 2893 2462 Station General Hospital - 400 092 2893 2463 2893 3740 24 S.K. Patil Daftary Road, Malad 2889 438150 Dindoshi Municipal (East), Mumbai - 400 2889 9447 Police Station General Hospital 097 25 M.W. Desai Govindnagar Hospital, 2877 4215162 Dindoshi Municipal Govindnagar, Haji Badu 2877 0007 Police Station General Hospital Road, Malad (East), Mumbai - 400 097 26 Siddharth Siddharth Nagar, 2876 6885100 Goregaon Hospital Goregaon (West), 2876 6886 Police Station Mumbai - 400 104
97 Telephone Nos. Of Control Rooms
Important Control Rooms Telephone nos. Fax No.
22694725, Dsaster Mangement Control Room 22694727 22694719
22620251 Ext MCGM 2062/2054 22704403
Disaster Helpline 108
24146533, Bus Running Control Officer 24184489 24146532
24137937, (BEST Traffic Control) 24146262 Ext-801
24143611, BEST Traffic Control Room 24136883
24137645, (Wadala) 24146162
24137924, BEST Bus Control 24127244
24129651, (For BEST bus breakdowns) 24111979
24145888, BEST Electric Supply -Dadar 24124242
- 22067893, Control Room Phathakwadi 22082875 22085888
Weather Bureau 22150431 22160824
22024243, Mantralaya Control Room 22854168
24937746, Traffic Police 24937755 24927234
24937747
22625020, Mumbai Police Headquarters 100 22621983 22633319
22641440, 22623054
141 Fire Brigade Control Room 101 23076111/12/13 23085993
23086181/82
Reliance Energy - Special Officer/ 30094920
Shri V.B.Sharma 9323551665
Santacruz 30099999 30099776
30096999, Andheri/Jogeshwari 30094302
30096999, Goregaon/Kandivili 30094900 30094844
30094500, Borivili/Bhayander 30093070 30094633
30096999, Chembur/Kurla/Vikhroli 30092040 30092022
26472131, M.S.E.D.C.L. - Bandra 26474211 26476749
25663408, Bhandup 25664323 25643990
Mulund(West) 25686666, 25653408
Mulund(East) 21636945
22017420, Western Railway Churchgate 22084287
23070564, Control Room 23720505
22622685, Central Railway CST 9821223724
22620173, Railway Police 22621695
27579969, Konkan Railway Control Room 27572015 27572420
MTNL - Head Office 24371900 24372033
142 Annexure – XVI
Civil Defence Corps, Brihanmumbai
Nodal Officers
Area BMC Ward Nodal Officer Telephone No.
Mr. Sanjeevan Joshi Off - 2261 0088 Addl. Controller Res - 2677 5090 Fax - 2261 4092 Brihan All Cell - 9969 012427 Mumbai e-mail - mumbaicivildefence@yah oo.co.in
Mr. P.V. Suresh Res - 6573 6419 Chief Warden Cell - 9323 199559
Mr. D.M. Khandare Off - 2261 1928 Sr. Asstt. Dy. Cell - 9969 504820 Controller
Smt. S.G. Makandar, Off - 2261 1910 Area-I A, B, C, D, E Dy. Controller Cell - 9819 917945 & G (S) Mr.C.D. Kadam, Off - 2261 1910 Asstt. Dy. Controller Cell - 9869 954685
Shri B.B. Kasbe, Off - 2308 5123 G(N), F(S), Dy. Controller 2309 8777 Area-II F(N), L, H(E) Cell - 9224 401670 & H(W) Mr. Anil Patil, Cell - 9969 341823 Dy. Chief Warden
Mr. V.R. Tehre, Off - 2561 5911 Dy. Controller Res - 2760 3831 Area-III M(E), M(W), Cell - 9867 617800 N, S & T Mr. A.H. Sonavane, Cell - 9322 249430 Dy. Chief Warden
K(E), K(W), Mr. V.H. Pawar, Off - 2620 6791 P(S), P(N), Dy. Controller Res - 2291 9495 Area-IV R(S), R(C) & Cell - 9892 099535 R(N) Mr. V,V, Waghmare, Cell - 9869 308299
166