Catalysis Laboratory; Inorganic and Physical Chemistry Division
Dr. Akula Venugopal M Sc, Ph D
Principal Scientist
Catalysis Laboratory; Inorganic and Physical Chemistry Division
CSIR – Indian Institute of Chemical Technology, Tarnaka, Hyderabad – 500 007, Telangana, India. Tel: +91-40-27193165 (Office), 27226703 (Residence),
Fax: +91-40-27160921; Emails: ,
Personal details
Education
B. Sc 1989 1st Class with distinction Kakatiya University, Warangal
M. Sc 1991 1st Class with distinction Kakatiya University, Warangal
Ph. D 1998 Osmania University, (IICT)
Hyderabad.
Life member: 1). Catalysis Society of India 2). Indian Council of Chemists
Date of birth: 12th June 1969
Supervisor
PhDs – 7 students working (CSIR-IICT) and 2 for (IICT-RMIT); 8 - awarded
M Sc (dissertation) – 19 awarded
M Tech (dissertation) – 6 awarded
B Tech (dissertation) – 1 awarded
Invited talks delivered: 17
Awards:
1) Best PhD thesis award presented by Director IICT on the occasion of IICT Golden Jubilee celebrations and CSIR foundation day, 1997.
2) Sistla Kamehswari Siddhanthi Young Scientist Award: Received for the year 2008 at Catsymp – 19, held at NCL, Pune during 18th Jan. 2009 to 21st Jan. 2009.
3) Best oral presentation award at NDCR, Saifabad Science College, OU Hyderabad, 2010.
4) Best poster presentation award at CATSYMP – 19, held at NCL, Pune.
5) Best paper presentation award received in Indo-German conference held at UICT Mumbai during November 2012.
6) Best paper presentation awarded at the 7th International Symposium on Recycling Feed stocks held at India Habitat Center New Delhi during 23rd to 26th November 2013.
7). Prof. Arvind Kumar Memorial award by Indian Council of Chemists (ICC) for the year 2013.
Professional experience
1. Postdoctoral Fellow at Surface Science and Catalysis Laboratory, University of Ulm, Germany.
2. Postdoctoral Fellow at Department of Chemistry, University of Witwatersrand, Johannesburg, South Africa.
3. Visiting scientist at Boreskov Institute of Catalysis, Novosibirsk, Russia.
4. Brainpool Visiting Scientist at Hydrogen Energy Research center, Korea Institute of Science and Technology, Seoul, Korea.
5. Visiting Scientist at Nacional Instituto de Tecnologia, Rio de Janeiro, Brazil.
6. Raman Research Fellow at Purdue Catalysis Center, School of Chemical Engineering, Purdue University, Indiana, USA during April 2015 to July 2015.
List of Publications
1. Dismutation of CFC-12 to CFC-13 over Chromia – Alumina Catalyst.
A Venugopal, K.S. Rama Rao, P.S. Sai Prasad and P. Kanta Rao.
J. Chem. Soc. Chem. Commun. (1995) 2377.
2. Influence of Method of Preparation on Pore structure and Dehydrogenation activity of Chromia Catalysts.
K.S. Rama Rao, K.V. Narayana, A. Venugopal, V. Venkat Rao, S. Khaja Masthan and P. Kanta Rao, Indian Journal of Chemistry. 35A (1996) 656.
3. Ammoxidation of 3-picoline over V2O5/TiO2 (anatase) system.
1. Relationship between ammoxidation activity and average oxidation state of vanadium.
K.V. Narayana, A. Venugopal, K.S. Rama Rao, V. Venkat Rao, S. Khaja
Masthan and P. Kanta Rao, Appl. Catal. A: Gen. 150 (1997) 269.
4. Ammoxidation of 3-picoline over V2O5/TiO2 (anatase) system.
2. Relationship between ammoxidation activity and dispersion of vanadia.
K.V. Narayana, A. Venugopal, K.S. Rama Rao, V. Venkat Rao, S. Khaja
Masthan and P. Kanta Rao, Appl. Catal. A: Gen. 167 (1998) 11.
5. Effect of method of preparation on the dismutation activity of Cr2O3-MgO-Al2O3 catalysts.
A Venugopal, K.S. Rama Rao, P.S. Sai Prasad and P. Kanta Rao.
Stud. Surf. Sci. Catal. Vol. 113, (1998) 405.
6. Hydrodechlorination of 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113) over Pd supported on modified Al2O3.
S. Chandra Shekar, A. Venugopal, K. S. Rama Rao, P.S. Sai Prasad,
R. Srinivas and P. Kanta Rao.
Stud. Surf. Sci. Catal. Vol. 113, (1998) 391.
7. Physico-chemical characterization of V2O5-TiO2 (anatase) catalysts for ammoxidation of 3-picoline.
K.V. Narayana, A. Venugopal, K.S. Rama Rao, V. Venkat Rao, S. Khaja
Masthan and P. Kanta Rao.
Stud. Surf. Sci. Catal. Vol. 113, (1998) 947.
8. Characterization and Reactivity of Pd/MgO and Pd/g-Al2O3 Catalysts in the Selective Hydrogenolysis of CCl2F2.
Hari Padmasri Aytam, Venugopal Akula, Krishnamurthy Janmanchi, Seetha Rama Rao Kamaraju and Kanta Rao Panja. J. Phys. Chem. B 106 (2002) 1024.
9. Novel calcined Mg-Cr hydrotalcite supported Pd catalysts for the
hydrogenolysis of CCl2F2.
A.H. Padmasri, A. Venugopal, J. Krishnamurthy, K.S. Rama Rao and
P. Kanta Rao. J. Mol. Catal. A: Chemical 181 (2002) 73.
10. Calcined Mg-Al, Mg-Cr and Zn-Al hydrotalcite catalysts for tert-butylation of phenol with iso-butanol – a comparative study.
A.H. Padmasri, A. Venugopal, V. Durga Kumari, K.S. Rama Rao and
P. Kanta Rao. J. Mol. Catal. A: Chemical 188 (2002) 255.
11. Hydroxyapatite as novel support for Au and Ru: Behavior in water gas shift reaction.
Akula Venugopal and Mike S Scurrell
Appl. Catal. A: Gen. 245 (2003) 137.
12. Au-Ru/Fe2O3 catalysts for the low temperature water gas shift reaction.
Akula Venugopal, James Aluha, Daniel Mogano and Mike S. Scurrell.
Appl. Catal. A: Gen. 245 (2003) 149.
13. The Water-Gas Shift Reaction over Au-based Bimetallic Catalysts. The Au-M (M = Ag, Bi, Co, Cu, Mn, Ni, Pb, Ru, Sn, Tl) on Iron (III) Oxide System.
Akula Venugopal, James Aluha and Mike S. Scurrell.
Catal. Lett. 90 (1-2): (2003), 1.
14. Low temperature reductive pretreatment of Au/Fe2O3 catalysts, TPR/TPO
studies and behavior in the Water-Gas Shift Reaction
Akula Venugopal and Mike S Scurrell
Appl. Catal. A: Gen. 258 (2004) 241.
15. Advantage of Hydrotalcite Precursors as Supports for Pd Catalysts in
Hydrodechlorination of CCl2F2.
A.H. Padmasri, A. Venugopal, V. Siva Kumar, V. Shashikala, B.M.
Nagaraja, P. Seetharamulu, B. Sreedhar, B. David Raju, P. Kanta Rao and
K.S. Rama Rao. J. Mol. Catal. A 223 (2004) 329.
16. Promotional effect of magnesia addition to active carbon supported Pd
catalyst on the characteristics and hydrodechlorination activity of CCl2F2.
J Krishna Murthy, S Chandra Shekar, A H Padmasri, A Venugopal,
V Siva Kumar, B M Nagaraja, V Shashikala, B David Raju, P Kanta Rao
and K S Rama Rao.
Catalysis Communications vol. 3, no. 5, (2004) 161.
17. Influence of H2O and CO2 on the Selective CO Oxidation in H2-rich Gases
over Au/a-Fe2O3.
M M Schubert, A. Venugopal, M Kahlich, V Plzak, and R J Behm
J. Catal, 222 (2004) 32.
18. Reductive Routes to Stabilized Nano Gold and Relation to Catalysis by
Supported Gold.
D Boyd, S Golunski, G H R Hearne, T Magadzu, K Mallick, M C Raphulu,
A Venugopal, M S Scurrell
Appl. Catal. A: General. 292 (2005) 76.
19. Hydroxyapatite photocatalytic degradation of calmagite (an azo dye) in
aqueous Suspension.
M Pratap Reddy, A Venugopal and M Subrahmanyam
Appl. Catal. B: Environmental, 69 (2006) 164.
20. Hydrogen production by catalytic decomposition of methane over Ni/SiO2.
A. Venugopal, J. Ashok, S. Naveen kumar, D. Hari Prasad, V. Durga kumari, and M. Subrahmanyam.
International Journal of Hydrogen Energy 32 (2007) 1782.
21. Hydroxyapatite supported Ag-TiO2 as Escherichia coli disinfection
photocatalyst
M Pratap Reddy, A Venugopal and M Subrahmanyam
Water Research 41 (2007) 379.
22. COx-free H2 production via catalytic decomposition of CH4 over Ni supported on zeolite catalysts
J. Ashok, S. Naveen Kumar, A. Venugopal, V. Durga Kumari, M Subrahmanyam*
Journal of Power Sources 164 (2007) 809.
23. Effect of method of preparation of Cu-Zn-Al catalysts on DME synthesis.
Akula Venugopal, Jelliarko Palgunadi, Oh-Shim Joo, and Kwang Deog Jung*
Solid State Phenomena 124-126 (2007) 1741 - 1744. Advances in
Nanomaterials and Processing
24. Production of COX free hydrogen by catalytic decomposition of methane
over Ni/HY catalysts.
Jangam Ashok, Sathu Naveen Kumar, Machiraju Subrahmanyam and
Akula Venugopal* Catal. Lett. 118 (2007) 139.
25. COx free hydrogen by methane decomposition over activated carbons.
J. Ashok, S. Naveen Kumar, A. Venugopal, V. Durga Kumari, S. Tripathi,
M Subrahmanyam* Catalysis Communications 9 (2008) 164.
26. Decomposition of methane for hydrogen production over novel hydroxyapatite supported nickel catalysts.
J. Ashok, S. Naveen kumar, M. Subrahmanyam and A Venugopal*
Catal. Lett. 121 (2008) 283.
27. Cu-Zn-Cr2O3 catalysts for dimethyl ether synthesis: structure and activity relationship
Akula Venugopal*, Jelliarko Palgunadi, Kwang Deog Jung*, Oh-Shim Joo and Chae-Ho Shin
Catalysis Letters 123 (2008) 142 -149.
28. Catalytic decomposition of CH4 over Ni-Al2O3-SiO2 catalysts: Influence of pretreatment conditions for the production of H2
Jangam Ashok, Gangadhara Raju, Padigapati Shiva Reddy, Machiraju Subrahmanyam and Akula Venugopal*
Journal of Natural Gas Chemistry, 17 (2008) 113-119.
29. Hydrotalcite structure derived Ni-Cu-Al catalysts for the production of H2 by CH4 decomposition.
Jangam Ashok, Machiraju Subrahmanyam and Akula Venugopal*
International Journal of Hydrogen Energy 33(11) (2008) 2704 - 2713.
30. Catalytic Decomposition of CH4 over NiO-Al2O3-SiO2 Catalysts: Influence
of Catalyst Preparation Conditions on the Production of H2
Jangam Ashok, Padigapati Shiva Reddy, Gangadhara Raju, Machiraju Subrahmanyam and Akula Venugopal*
International Journal of Hydrogen Energy, 33 (2008) 4809-4818.
31. Development of methane decomposition catalysts for COx free hydrogen
Jangam Ashok, Machiraju Subrahmanyam and Akula Venugopal*
Catalysis Surveys from Asia, 12 (2008) 229 – 237.
32. Solvent free aerobic oxidation of ethylbenzene over supported Ni catalysts using molecular oxygen at atmospheric pressure.
G Raju, P Shiva Reddy, J Ashok, B Mahipal Reddy and A Venugopal*
Journal of Natural Gas Chemistry, 17 (2008) 293 – 297.
33. Dimethyl ether synthesis on the admixed catalysts of Cu-Zn-Al-M (M=Ga, La, Y, Zr) and γ-Al2O3 : The role of modifier.
Akula Venugopal*, Jelliarko Palgunadi, Jung Kwang Deog*, Oh-Shim Joo and Chae-Ho Shin. J. Mol. Catal. 302 (2009) 20-27.
34. Catalytic decomposition of methane to hydrogen and carbon nanofibers over Ni-Cu-SiO2 catalysts
Jangam Ashok, Padigapati Shiva Reddy, Gangadhara Raju, Machiraju Subrahmanyam and Akula Venugopal*
Energy & Fuels 23(1) (2009) 5-13.
35. Hydrotalcite derived Cu-Zn-Cr catalysts admixed with g-Al2O3 for single step dimethyl ether synthesis from syngas: Influence of hydrothermal treatment.
Akula Venugopal*, Jelliarko Palgunadi, Jung Kwang Deog*, Oh-Shim Joo and Chae-Ho Shin. Catalysis Today 147 (2009) 94-99.
36. Low temperature steam reforming of bio-ethanol over Ni/CuO-Al2O3 catalysts.
A. Venugopal*, M. Sudhakar, R. Kishore, Reema Sarkari, J. Ashok, F. B. Noronha, S. M. de Lima, and A. Hari Padmasri.
Int. J Nanotechnol. 7 (2010) 1188-1203.
37. Methane decomposition catalysts for COX free hydrogen production.
Ashok Jangam, Reema Sarkari, Anjaneyulu Chatla, Subrahmanyam Machiraju, Venugopal Akula*
Rev. Chem. Eng. 26 (2010) 29-39.
38. Vapour phase synthesis of methylpyrazine using aqueous glycerol and
ethylenediamine over ZnCr2O4 catalyst: Elucidation of reaction mechanism.
Reema Sarkari, Ramineni Kishore, Medak Sudhakar, Chatla Anjaneyulu, Akula Venugopal*
Catalysis Communications, 12 (2011) 1067-1070.
39. Oxidative steam reforming of ethanol over La1-xCexNiO3 perovskite-type oxides for the production of hydrogen
Sania M. de Lima, Adriana M. da Silva, Lídia O.O. da Costa, José M. Assaf, Lisiane V. Mattos, Reema Sarkari, A. Venugopal, Fábio B. Noronha*
Applied Catalysis B, 121-122 (2012) 1-9.
40. Pd/MgLa Mixed Oxide Catalyzed Chemoselective Hydrogenation of C=C at Room Temperature
M. Lakshmi Kantam, R. Kishore, Jagjit Yadav, M. Sudhakar, A. Venugopal
Advanced Synthesis and Catalysis, 354 (2012) 663-669.
41. Ruthenium/Magnesium-Lanthanum mixed oxide: An efficient reusable catalyst for oxidation of alcohols by using molecular oxygen.
M. Lakshmi Kantam,* R. Sudarshan Reddy, Ujjwal Pal, M. Sudhakar, A. Venugopal, K. Jeeva Ratnam, F. Figueras, Venkat Reddy Chintareddy, and Yuta Nishina.
Journal of Molecular Catalysis A, 359 (2012) 1-7.
42. Synthesize 2-methylpyrazine using aqueous glycerol and ethylenediamine over zinc oxide-zinc chromite catalysts: structure activity relationship.
Akula Venugopal*, Reema Sarkari, Chatla Anjaneyulu, Vankaduth Krishna and Mandari Kotesh Kumar.
Applied Catalysis A: General 441-442 (2012) 108-118.
43. Nanocrystalline Magnesium Oxide- Stabilized Palladium(0): Heck Reaction with Heteroaryl Bromides in the Absence of Ligand and Base.
M. Lakshmi Kantam, P. Vishnuvardhan Reddy, P. Srinivas, A. Venugopal, Suresh Bhargava and Yuta Nishina.
Catalysis Science and Technology 3 (2013) 2550-2554.
44. N-Alkylation of amines with alcohols over nanosized zeolite Beta
Marri Mahender Reddy, Macharla Arun Kumar, Peraka Swamy, Mameda Naresh, Kodumuri Srujana, Lanka Satyanarayana, Akula Venugopal and Nama Narender*
Green Chemistry 15 (2013) 3474-3483.
45. Characteristics of La modified Ni-Al2O3 and Ni-SiO2 catalysts for COx free hydrogen production by catalytic decomposition of methane
Chatla Anjaneyulu, Velisoju Vijay Kumar, Suresh K. Bhargava, Akula Venugopal*
Journal of Energy Chemistry 22 (2013) 853-860.
46. Pd/Mg-La mixed oxide catalyzed oxidative sp2 C-H bond acylation with alcohols.
R. Kishore, M. Lakshmi Kantam*, J. Yadav, M. Sudhakar, S. Laha and
A. Venugopal*
Journal of Molecular Catalysis A 379 (2013) 213-218.
47. Effective utilization of bio-glycerol for the synthesis of 2-methylpyrazine over ZnO-ZnCr2O4 catalyst.
A. Venugopal*, R. Sarkari, M. Kotesh Kumar, S. Syed John, J. Krishna Reddy, and A. Hari Padmasri*
Journal of Chemical Sciences 126 (2014) 387-393.
48. Influence of acid-base sites on ZnO-ZnCr2O4 catalyst during dehydrocyclization of aqueous glycerol and ethylenediamine for the synthesis of 2-methylpyrazine: Kinetic and mechanism studies
Akula Venugopal*, Reema Sarkari, Chatla Anjaneyulu, Vankudoth Krishna, Mandari Kotesh Kumar and Aytam Hari Padmasri.
Applied Catalysis A 469 (2014) 398-409.
49. Selective CO oxidation over Fe5(PO4)3(OH)5 supported Pt catalyst: Kinetic and mechanistic studies.
A Hari Padmasri*, P Anil Kumar, S Naveen Kumar, A Venugopal, Sooboo Singh
Indian Journal of Chemistry 53A (2014) 511-515.
50. Synthesis and characterization of Pt supported on Fe5(PO4)3(OH)5 catalysts
P Anil Kumar, A Hari Padmasri*, S Naveen Kumar, A Venugopal*, Sooboo Singh.
Indian Journal of Chemistry 53A (2014) 566-571.
51. Vapour phase hydrogenation of nitrobenzene over metal (Ru, Ni, Pt, Pd) supported on Ca5(PO4)3(OH) catalysts
M. Sudhakar, M Lakshmi Kantam*, R Kishore, S Naveen Kumar and A Venugopal*.
Indian Journal of Chemistry 53A (2014) 550-552.
52. Hydroxyapatite as a novel support for Ru in the hydrogenation of levulinic acid to γ-valerolactone
M. Sudhakar, M. Lakshmi Kantam*, V. Swarna Jaya, R. Kishore, K.V. Ramanujachary and A. Venugopal*
Catalysis Communications 50 (2014) 101-104.
53. Bio-glycerol utilization: Synthesis of 2,6-dimethylpyrazine over MxOy-MCr2O4 (M = Mg, Fe, Co, Ni, Cu and Zn) catalysts.
V Krishnaa, S Naveen Kumara, S Reemaa, A Hari Padmasrib, KVR Charya and A Venugopal*,a
Applied Catalysis A: General 488 (2014) 275-284.
54. Selective hydrogenation of levulinic acid to g-valerolactone over Ru/Mg-LaO catalysts
V Swarna Jaya, M Sudhakar, S Naveen Kumar and A Venugopal