Extrasolar Cosmochemistry
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Lurking in the Shadows: Wide-Separation Gas Giants As Tracers of Planet Formation
Lurking in the Shadows: Wide-Separation Gas Giants as Tracers of Planet Formation Thesis by Marta Levesque Bryan In Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy CALIFORNIA INSTITUTE OF TECHNOLOGY Pasadena, California 2018 Defended May 1, 2018 ii © 2018 Marta Levesque Bryan ORCID: [0000-0002-6076-5967] All rights reserved iii ACKNOWLEDGEMENTS First and foremost I would like to thank Heather Knutson, who I had the great privilege of working with as my thesis advisor. Her encouragement, guidance, and perspective helped me navigate many a challenging problem, and my conversations with her were a consistent source of positivity and learning throughout my time at Caltech. I leave graduate school a better scientist and person for having her as a role model. Heather fostered a wonderfully positive and supportive environment for her students, giving us the space to explore and grow - I could not have asked for a better advisor or research experience. I would also like to thank Konstantin Batygin for enthusiastic and illuminating discussions that always left me more excited to explore the result at hand. Thank you as well to Dimitri Mawet for providing both expertise and contagious optimism for some of my latest direct imaging endeavors. Thank you to the rest of my thesis committee, namely Geoff Blake, Evan Kirby, and Chuck Steidel for their support, helpful conversations, and insightful questions. I am grateful to have had the opportunity to collaborate with Brendan Bowler. His talk at Caltech my second year of graduate school introduced me to an unexpected population of massive wide-separation planetary-mass companions, and lead to a long-running collaboration from which several of my thesis projects were born. -
Atomic and Molecular Laser-Induced Breakdown Spectroscopy of Selected Pharmaceuticals
Article Atomic and Molecular Laser-Induced Breakdown Spectroscopy of Selected Pharmaceuticals Pravin Kumar Tiwari 1,2, Nilesh Kumar Rai 3, Rohit Kumar 3, Christian G. Parigger 4 and Awadhesh Kumar Rai 2,* 1 Institute for Plasma Research, Gandhinagar, Gujarat-382428, India 2 Laser Spectroscopy Research Laboratory, Department of Physics, University of Allahabad, Prayagraj-211002, India 3 CMP Degree College, Department of Physics, University of Allahabad, Pragyagraj-211002, India 4 Physics and Astronomy Department, University of Tennessee, University of Tennessee Space Institute, Center for Laser Applications, 411 B.H. Goethert Parkway, Tullahoma, TN 37388-9700, USA * Correspondence: [email protected]; Tel.: +91-532-2460993 Received: 10 June 2019; Accepted: 10 July 2019; Published: 19 July 2019 Abstract: Laser-induced breakdown spectroscopy (LIBS) of pharmaceutical drugs that contain paracetamol was investigated in air and argon atmospheres. The characteristic neutral and ionic spectral lines of various elements and molecular signatures of CN violet and C2 Swan band systems were observed. The relative hardness of all drug samples was measured as well. Principal component analysis, a multivariate method, was applied in the data analysis for demarcation purposes of the drug samples. The CN violet and C2 Swan spectral radiances were investigated for evaluation of a possible correlation of the chemical and molecular structures of the pharmaceuticals. Complementary Raman and Fourier-transform-infrared spectroscopies were used to record the molecular spectra of the drug samples. The application of the above techniques for drug screening are important for the identification and mitigation of drugs that contain additives that may cause adverse side-effects. Keywords: paracetamol; laser-induced breakdown spectroscopy; cyanide; carbon swan bands; principal component analysis; Raman spectroscopy; Fourier-transform-infrared spectroscopy 1. -
The Chemical Origin of Behavior Is Rooted in Abiogenesis
Life 2012, 2, 313-322; doi:10.3390/life2040313 OPEN ACCESS life ISSN 2075-1729 www.mdpi.com/journal/life Article The Chemical Origin of Behavior is Rooted in Abiogenesis Brian C. Larson, R. Paul Jensen and Niles Lehman * Department of Chemistry, Portland State University, P.O. Box 751, Portland, OR 97207, USA; E-Mails: [email protected] (B.C.L.); [email protected] (R.P.J.) * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +1-503-725-8769. Received: 6 August 2012; in revised form: 29 September 2012 / Accepted: 2 November 2012 / Published: 7 November 2012 Abstract: We describe the initial realization of behavior in the biosphere, which we term behavioral chemistry. If molecules are complex enough to attain a stochastic element to their structural conformation in such as a way as to radically affect their function in a biological (evolvable) setting, then they have the capacity to behave. This circumstance is described here as behavioral chemistry, unique in its definition from the colloquial chemical behavior. This transition between chemical behavior and behavioral chemistry need be explicit when discussing the root cause of behavior, which itself lies squarely at the origins of life and is the foundation of choice. RNA polymers of sufficient length meet the criteria for behavioral chemistry and therefore are capable of making a choice. Keywords: behavior; chemistry; free will; RNA; origins of life 1. Introduction Behavior is an integral feature of life. Behavior is manifest when a choice is possible, and a living entity responds to its environment in one of multiple possible ways. -